For inspection purposes only. · PDF fileCompany Name: KMK Metals Recycling Ltd Licence No: W0113-04 Year: 2016, Visit No: 2 Report No: 016-058 Page 2 of 14

Company Name: KMK Metals Recycling Ltd Licence No: W0113-04 Year: 2016, Visit No: 2 Report No: 016-058

Page 1 of 14 Glenside Environmental Services Doc No: GEN2-001rev8

Rev Date: 08/09/2014 Issued by: QM

Cuil Greine House Ballincollig Commercial Park

Link Road Ballincollig

Cork T: 021 4810016 M: 086 3819387 [email protected] www.glenenv.ie

_______________________________________________________________

Quarter 2 of 2016

Stack Emissions Monitoring Report

for

KMK Metals Recycling Ltd

Cappincur Industrial Estate, Daingean Road, Tullamore, Co. Offaly

EPA Waste Licence REF: W0113-04

_______________________________________________________________

Report No: 016-058

Monitoring Date: 27th April 2016

Test report shall not be reproduced except in full, without written approval of the laboratory.

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http://www.glenenv.ie/




Report Summary:

Job Quotation No: QGE15-009

Operator Licence No: W0113-04

Operator Name: KMK Metals Recycling Ltd

Installation: Cappincur Industrial Estate, Daingean Road, Tullamore, Co. Offaly

Contact Name: Clare Donnellan

Phone No: 087 122 1422

Monitoring dates: 27th April 2016

Monitoring Organisation: Glenside Environmental, Cuil Greine House Link Road, Ballincollig, Cork

Phone No: (021) 4810016

Email: [email protected]

Report Date: 27th May 2016

Report written by: Ewa Piatek

MCERTS reg No: MM07 799

Competency: Level 2

Function: Team Leader

Endorsements: TE1, TE2, TE3, TE4

Report approved by: Ewa Piatek

MCERTS reg No: MM07 799

Competency: Level 2

Function: Team Leader

Endorsements: TE1, TE2, TE3, TE4

Signed by: Quality Manager

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TABLE OF CONTENTS

PAGE

1. INTRODUCTION........................................................................................................................ 4

2. OBJECTIVES .............................................................................................................................. 4

2.1. SUBSTANCES TO BE MONITORED AT EACH EMISSION POINT ..................................................... 4 2.2. SPECIAL REQUIREMENTS ........................................................................................................ 4

3. MATERIALS AND METHODS ................................................................................................ 5

3.1. PARTICULATES - ISO9096:2006 (HIGH) OR IS EN 13284:2004 (LOW) .................................... 5 3.2. METALS – IS EN 14385:2004 ................................................................................................. 5 3.3. VOLUMETRIC FLOW RATE – ISO 16911-1:2013 ..................................................................... 5

4. MONITORING RESULTS ......................................................................................................... 6

4.1. MONITORING RESULTS ........................................................................................................... 6 4.2. MONITORING RESULTS ........................................................................................................... 7 4.3. REFERENCE CONDITIONS ........................................................................................................ 8 4.4. VOLUMETRIC FLOW RATE ...................................................................................................... 8 4.5. METHODS AND ACCREDITATION STATUS................................................................................ 9

5. OPERATING INFORMATION............................................................................................... 10

6. MONITORING DEVIATION .................................................................................................. 10

7. ANNEX 1 .................................................................................................................................... 12

7.1. PERSONNEL ........................................................................................................................... 12 7.2. EQUIPMENT USED .................................................................................................................. 12

8. ANNEX 2 .................................................................................................................................... 13

8.1. DIAGRAMS OF THE STACK ..................................................................................................... 13 8.2. SAMPLING MEASUREMENTS .................................................................................................. 13

9. ANNEX 3 .................................................................................................................................... 14

9.1. RESULTS AND UNCERTAINTY CALCULATIONS FOR STACK A2-5 – TOTAL OF 18 PAGES ......... 14 9.2. SAL LABORATORY CERTIFICATES – TOTAL OF 2 PAGES ....................................................... 14 9.3. NORTHUMBRIAN WATER LABORATORY CERTIFICATES – TOTAL OF 7 PAGES ....................... 14

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1. Introduction

Glenside Environmental was commissioned by KMK Metals Recycling Ltd to perform air emission monitoring at the facility in Cappincur Industrial Estate, Daingean Road, Tullamore, Co. Offaly. The monitoring was carried out as required by Waste Licence W0113-03. This report presents details of this monitoring programme.

2. Objectives

2.1. Substances to be monitored at each emission point

Sample Locations Parameter

A2-5 Particulates

Metals (Total of Cd+Tl)

Metals (Total of Sb, As, Pb, Cr, Co, Cu, Mn, Ni, V, Be)

Chromium

Lead

Mercury

Aluminium

Arsenic

Cadmium

Copper

Iron

Nickel

Zinc

2.2. Special Requirements There were no special requirements for this monitoring campaign.

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3. Materials and Methods This section provides brief details of the methodologies employed to perform the air emission monitoring.

3.1. Particulates - ISO9096:2006 (high) or IS EN 13284:2004 (low) A sample stream of gas is extracted from the main gas stream at representative sampling points for 30 minutes, with an isokinetically controlled flow rate and measured volume. The dust entrained in the gas sample is separated by a pre-weighed filter, which is then dried and reweighed. Deposits upstream of the filter in the sampling equipment are also recovered and weighed. The increase of mass of the filter and the deposited mass upstream of the filter are attributed to dust collected from the sampled gas, which allows the dust concentration to be calculated.

3.2. Metals – IS EN 14385:2004 A known volume of flue gas is extracted representatively from a duct or a chimney during a certain period of time at a controlled flow rate following EN13284-1:2004 (Particulates Standard). The dust in the sampled gas volume is collected on a filter. Thereafter, the gas stream is passed through a series of absorbers containing absorption solutions and the filter passing fractions of the specific elements are collected within these solutions. The results are calculated from the laboratory results divided by air volume sampled and are converted to mg/m3. Results in kg/h are calculated from concentration of pollutant and stack flow rate. All results are corrected to Standard Temperature and Pressure and if required to Reference Oxygen and Dry conditions. LOD values are obtained from laboratory LOD and the same calculations as per results.

3.3. Volumetric Flow Rate – ISO 16911-1:2013 The volumetric airflow rate was determined from stack velocity measurements calculated in accordance with ISO 16911-1:2013. Airflow rate and temperature profiles were performed at pre-calculated intervals across the stack in order to determine the average velocity profile across the stack diameters.

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4. Monitoring Results Tables 4.1 and 4.2 presents the results of the air emission monitoring sampling program carried out at the emission stacks listed below.

4.1. Monitoring Results Results reported are corrected to reference conditions as per IPPC Licence requirements.

Emission Point Substances ELV

mg/m3 CEMS

Results LOD

mg/m3 Results mg/m3

Results kg/h

Uncertainty mg/m3

Date of Monitoring

Start –End Time of Monitoring

A2-5 Particulates 10 n/a 0.58 <0.58 <0.01 0.02 27/04/2016 11:08-11:40

Blank Particulates n/a n/a 0.58 <0.58 n/a 0.02 27/04/2016 10:35-10:40

A2-5 Metals (Total of Cd+Tl) n/a n/a 0.0016 0.0017 0.00003 n/a 27/04/2016 12:01-12:33

Blank Metals (Total of Cd+Tl) n/a n/a 0.0016 <0.0016 n/a n/a 27/04/2016 12:56-13:01

A2-5 Metals (Total of Sb, As, Pb, Cr, Co, Cu, Mn, Ni, V, Be) n/a n/a 0.0131 0.0445 0.0009 n/a 27/04/2016 12:01-12:33

Blank Metals (Total of Sb, As, Pb, Cr, Co, Cu, Mn, Ni, V, Be) n/a n/a 0.0131 0.0158 n/a n/a 27/04/2016 12:56-13:01

Results for Particulates and Metals are within INAB accreditation range.

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4.2. Monitoring Results Results reported are corrected to reference conditions as per IPPC Licence requirements.


mg/m3 CEMS

Results LOD

mg/m3 Results mg/m3

Results kg/h

Uncertainty mg/m3

Date of Monitoring


A2-5 Aluminium n/a n/a 0.1647 <0.1647 <0.0020 n/a 27/04/2016 12:01-12:33

Blank Aluminium n/a n/a 0.1647 <0.1647 n/a n/a 27/04/2016 12:56-13:01

A2-5 Arsenic n/a n/a 0.0011 <0.0011 <0.00002 n/a 27/04/2016 12:01-12:33

Blank Arsenic n/a n/a 0.0011 <0.0011 n/a n/a 27/04/2016 12:56-13:01

A2-5 Cadmium n/a n/a 0.0004 0.0006 0.00001 n/a 27/04/2016 12:01-12:33

Blank Cadmium n/a n/a 0.0004 <0.0005 n/a n/a 27/04/2016 12:56-13:01

A2-5 Chromium n/a n/a 0.0009 0.0026 0.00005 n/a 27/04/2016 12:01-12:33

Blank Chromium n/a n/a 0.0009 <0.0009 n/a n/a 27/04/2016 12:56-13:01

A2-5 Copper n/a n/a 0.0012 0.0104 0.0002 n/a 27/04/2016 12:01-12:33

Blank Copper n/a n/a 0.0012 0.0032 n/a n/a 27/04/2016 12:56-13:01

A2-5 Lead n/a n/a 0.0005 0.0027 0.0001 n/a 27/04/2016 12:01-12:33

Blank Lead n/a n/a 0.0005 0.0011 n/a n/a 27/04/2016 12:56-13:01

A2-5 Iron n/a n/a 0.0210 0.0473 0.0010 n/a 27/04/2016 12:01-12:33

Blank Iron n/a n/a 0.0210 0.0270 n/a n/a 27/04/2016 12:56-13:01

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mg/Nm3 CEMS

Results LOD

mg/m3 Results mg/m3

Results kg/h

Uncertainty mg/m3

Date of Monitoring


A2-5 Nickel n/a n/a 0.0034 <0.0034 0.00005 n/a 27/04/2016 12:01-12:33

Blank Nickel n/a n/a 0.0034 <0.0034 n/a n/a 27/04/2016 12:56-13:01

A2-5 Zinc n/a n/a 0.0024 0.0501 0.0004 n/a 27/04/2016 12:01-12:33

Blank Zinc n/a n/a 0.0024 0.0052 n/a n/a 27/04/2016 12:56-13:01

A2-5 Mercury n/a n/a 0.0002 0.0006 0.00001 n/a 27/04/2016 12:01-12:33

Blank Mercury n/a n/a 0.0002 <0.0002 n/a n/a 27/04/2016 12:56-13:01

4.3. Reference Conditions

Emission Point Reference Temperature Reference Pressure Reference Moisture Reference Oxygen

A2-5 273 K 101.3 kPa No correction No correction

4.4. Volumetric Flow Rate

Emission Point Actual Moist Flow Rate

Moist Flow Rate at STP

Dry Flow Rate at STP Emission Limit Value Units

A2-5 18690.23 17933.31 n/a 40,000 m3/h

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4.5. Methods and Accreditation Status

Sampling Point: Determinant Reference

Method Accreditation

Status Analytical Method

Description Subcontracted

Laboratory Laboratory Accreditation Status

A2-5 Flow, Temperature, Pressure

ISO 16911-1:2013 INAB n/a n/a n/a

A2-5 Mercury IS EN 13211:2011 INAB AFS Northumbrian Water UKAS

A2-5 Metals IS EN 14385:2004 INAB ICP MS Northumbrian Water

Aluminium, Antimony Arsenic,

Cadmium, Calcium, Cobalt, Chromium, Copper, Iron, Lead,

Manganese, Nickel,

Selenium, Thallium, Vanadium, Zinc

A2-5 Particulates low IS EN 13284:2002 INAB Gravimetric Analysis SAL UKAS

Substances were monitored as per monitoring objectives. Substances were monitored in accordance with the requirements stated in AG2 (Air Emissions Monitoring Guidance Note#2)

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5. Operating Information

Emission Point

Process Status Load

/Feedstock Process Details Fuel

/Feedstock Abatement

System Status of

Abatement System

A2-5 Normal Operation Full Load n/a Bag Filter In Operation

6. Monitoring Deviation Requirements of IS EN 15259 for sampling

points A2-5

Measuring plane is located as far downstream and upstream from any disturbances, which could change direction of flow (bends, fans, partially

closed dumpers).

Yes, measuring plane is located as far downstream and upstream from any disturbances.

Measuring Plane is located in a section of duct with at least five hydraulic diameters of straight duct

upstream of the sampling plane.

Yes, measuring plane of duct is located in a section of duct with five hydraulic diameters of straight duct

upstream of the sampling plane. Measuring Plane is located in a section of duct with

at least two hydraulic diameters of straight duct downstream of the sampling plane (five hydraulic

diameters from top of the stack).

No, measuring plane is not located in a section of duct with five hydraulic diameters from top of stack.

Measuring Plane is located in a section of duct with constant shape and cross-sectional area.

Yes, measuring plane is located in a section of duct with constant shape and cross-sectional area.

Measurement section is clearly identified and labelled.

Yes, measuring section is clearly identified and labelled.

Requirements of IS EN 15259 for platform, working space and ports size. A2-5

Appropriate working area. Yes, platform has appropriate size.

Safe access to monitoring point. Yes, ladder is safe. Sufficient ports number

Small stacks(<0.7) – 1 port 0.7-1.5m – 2 ports

>1.5m – 4 ports

1 port available.

Appropriate port size. Yes, 100mm. Requirements of ISO 16911-1:2013 for flow,

temperature and pressure profile of the stack A2-5

Required number of points were sampled as per ISO 16911-1 requirements. Yes, 4 point sampled.

No negative flow. Yes, no negative flow found in the stack flue gasses.

All points sampled swirl check was below 15° Yes, all points sampled swirl check result were below 15°

Differential pressure higher than 5Pa measured with pitot tube. Yes, differential pressure result was above 5 Pa.

The ratio of highest to lowest local gas velocity is within (< 3:1) requirements Yes, Ratio of highest to lowest gas velocity was 1:1.

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Requirements of IS EN 13248-1 for Particulates A2-5 The LOD is less than 10% of ELV (MID 13248-

1section 10.6) Yes, LOD is below 10% of ELV.

The blank reading meet the required target of <10% of the daily limit value (for ELV >10 mg/m3) (section

10.6)

Yes, Blank reading meet the requirements.

All points sampled swirl check was below 15°. If any of the point not in compliance with this requirement

the point should not be sampled. All points sampled swirl check was below 15°. All

points were sampled.

Sampling location requirements are not met.

Sample location requirements were not met particulates results were not produced in

compliance with the standard. Measuring plane is not located in a section of duct with five hydraulic

diameters from top of stack. Requirements of IS EN 14385 for Metals A2-5

Probe temperature should be kept at or above 180°C. Yes, probe temperature was kept at 184°C +/-5°C

Absorbers temperature shall be kept below 30°C Yes, absorbers temperature was kept below 30°C +/-2°C.

Absorbers efficiency requirement: If one of the individual metals elements in the last impinger is more than 10% of the total combined

result for that element. (not applicable if the result is less than 1% of the result of total mass of metals or

if the result is less than 30% of the ELV)

n/a

Requirements of IS EN 13211 for Mercury A2-5 Probe temperature should be kept at or above

180°C. Yes, probe temperature was kept at 184°C +/-5°C

The amount of mercury collected in the second absorber shall correspond to less than 5 % of the total amount of mercury in both absorbers or less

than 2 µg/m3, whichever is the greatest.

The amount of Mercury collected is 0.6 µg/m3.

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7. Annex 1

7.1. Personnel

Scientist/Technician Name Position Qualification Technical

Endorsements MCERTS Number

Ewa Piatek Team Leader Level 2 TE1, TE2, TE3, TE4 MM07 799

Patrick Power Technician Trainee - MM12 1183

7.2. Equipment used

Equipment GEN Equipment No

Millenium 5 Console EQ069

Millenium Nozzle Set EQ087

Millenium Probe EQ071

Millenium Pitot tube EQ081

Millenium Impingers EQ072

Filters SAL Laboratory supplied GFA Filters 47mm

Distance Meter EQ089

KIMO Pitot Tube EQ080

KIMO Flow Meter EQ079

Caliper EQ082

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8. Annex 2

8.1. Diagrams of the stack

8.2. Sampling measurements

Determinant Result Units

Number of Ports Sampled 1 -

Number of Points Sampled 4 -

Average Velocity v'a 10.49 m/s

Average Pressure 101.826 kPa

Average Temperature 13.0 °C

Stack Diameter 0.794 m

T Reference 273 Deg K

P Reference 101.3 kPa

Isokinetic condition Particulates – 1.05 Metals 0.38 %

Oxygen n/a %

CO2 n/a %

Water vapour 2.5 %

Nozzle Size 6.01 mm

Velocity, temperature and pressure measurements are within INAB accreditation range.

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9. Annex 3

9.1. Results and uncertainty calculations for Stack A2-5 – Total of 20 pages

9.2. SAL Laboratory Certificates – Total of 2 pages

9.3. Northumbrian Water Laboratory Certificates – Total of 6 pages

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Page1of20

Company Name: Doc NoLicence No: Rev Date:Year: 2016 Issued by:Sampling Date:Report No: Flow Calculations for A2-5

Equipment Used:

Millenium 5 console: EQ069 Rule: EQ083

Probe: EQ071 Pitot Tube: EQ081Laser Distance

Meater: EQ089

KIMO - Flow Test: EQ079 Kimo Pitot Tube : EQ080

Stack Circular with central pointCircular no central point (tangential)

Diameter Measurements 0.7940.7940.794

Diameter Average: 0.794 m

Stack Area 0.50 m2Sampling Line 1Sampling Points 4

Port Depth (m): Port 1: 0.12 Port 2:Wall thicknes (m): 0.02

Ciruclar with central point Circular no central point

Point NumberPoint position in

stack (m)Points to be marked

on probe Point position as %1 0.05 0.19 6.72 0.20 0.34 25.03 0.60 0.74 75.04 0.74 0.88 93.3 Note: Sampling point should be located either >3% of th

Unc of static pressure calculationsStatic Pressure: mmH2O Pa mmH2O Line 2 Note: At least once per line. St Dev: 0.00 0.00Reading 1 8 76.00 0.00 Pa 0.00 0.00Reading 2 8 76.00 0.00 Pa Unc 1.52 1.52 1.08Reading 3 8 76.00 0.00 PaReading 4 8 76.00 0.00 PaReading 5 8 76.00 0.00 PaAverage: 7.8 76 0.00 Pa

Pitot Tube Checks: CommentsKIMO Pitot EQ080 Mill 5 Pitot EQ081None None

Inernal Leakage Check

Pressuriezed pressure: 500 Pa 12 mm H2O

GEN2-002rev179/18/2015QM

Deformities, Burrs, Damage

Note: blow through the pitot impact opening until at least 7.6 cm (3.0 in.) H20 velocity head registers on the manometer; then, close off the impact

KMKW0113-04Visit No: 2

4/27/2016

Points Calculations

016-058

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Page2of20


GEN2-002rev179/18/2015QM


4/27/2016016-058

Time of leak check: 15 s 15 s

Leak Check Result: Pass Pass

<10Pa <10Pa

Swirl Check: ° Within requirements <15°Point 1 1.00 YesPoint 2 0.00 YesPoint 3 0.00 YesPoint 4 0.00 Yes

Absolute pressure of the stack gas:The absolute pressure in the duct is given by the measurement of the atmospheric pressure on the siteand the static pressure measured in the duct.

Barometric (Atmospheric Pressure)Pb 763.1877622 mmHg Note: 1mb = 0.75 mmHg (Since1 atmosphere=1013.25 mb = 760 mmHg)Pstatic 7.752637552 mmH2O 760 mmHg = 101325 Pa

Conversion form mmH2O to mmHg 13.6 Atmospheric Press 101750 Pa

Atmospheric Temperature: 13.00 C°

Ps = 763.757809 mmHg Absolute Pressure101826 Pa of stack

Molecular Weigh of Dry Gas Stream: Molecular weight of stack gas (wet):

Bwo 0.040Md 28.85

CO2 0.06 % Molecular weight of 18O2 20.90 %CO 0.0015 % CO ppm 15 Ms= 28.41N2 79.04 %

Md= 28.85

Pitot CooficiencyCalibration Date: 7/29/2015EQ080 KIMO EQ081 Mill 5m/sec Cp m/sec Cp

3.02 0.8065.2 0.806

10.38 0.8315.6 0.838

20.43 0.82925.8 0.832

0.8060

S-tupe pitot tube shall be positioned perpendicular to the direction of the flow. The static pressure is than measured using both taps. The difference in

the measured static pressure should be < 10PaCheck on stagnation and reference pressure taps:

opening. The pressure shall remain stable for at least 15 seconds; (2) do the same for the static pressure side, except using suction to obtain the

minimumof 7.6 cm (3.0 in.) H20.

Pitot Cooficiency used for calculations:

If Swirl Check is outside requiremnts the correction has to be applied.

𝑃𝑃𝑠𝑠 = 𝑃𝑃𝑏𝑏 +𝑃𝑃𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆13.6

𝑀𝑀𝑑𝑑 = 44%𝐶𝐶𝐶𝐶𝐶

100+ 3𝐶

%𝐶𝐶𝐶100

+ 𝐶8%𝐶𝐶𝐶𝐶 + %𝑁𝑁𝐶

100𝑀𝑀𝑠𝑠 = 𝑀𝑀𝑑𝑑 1− 𝐵𝐵𝑤𝑤𝑤𝑤 + 18(𝐵𝐵𝑤𝑤𝑤𝑤)

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Page3of20


GEN2-002rev179/18/2015QM


4/27/2016016-058

Time Start: 10:12 Time End: 10:16

Velocity by Mill 5 Velocity Temperature Pressure of Stack

ΔPs Pa ΔPs mmH2O √ΔPs mmH2O m/s kPaDynamic Pressure Velocity

Temperature Pressure

Point 1 102.93 10.5 3.240 10.5 13 101.826 102.93 Pa 0.00 Std Dev 20.29 2√ΔPPoint 2 102.93 10.5 3.240 10.5 13 101.826 102.93 Pa 0.00 10.15 √ΔPPoint 3 102.93 10.5 3.240 10.5 13 101.826 102.93 Pa 1.52 UΔp ##### U2ΔpPoint 4 102.93 10.5 3.240 10.5 13 101.826 102.93 Pa 102.93 10.49 13 101.826 0.71 Uvi 0.006 U2Δp/4ΔpPoint 5 102.93 10.5 3.240 10.5 13 101.826 102.93 Pa 0.19Point 6 102.93 10.5 3.240 10.5 13 101.826 102.93 Pa 0.00 Std Dev 20.29 2√ΔPPoint 7 102.93 10.5 3.240 10.5 13 101.826 102.93 Pa 0.00 10.15 √ΔPPoint 8 102.93 10.5 3.240 10.5 13 101.826 102.93 Pa 1.52 UΔp 2.32 U2ΔpPoint 9 102.93 10.5 3.240 10.5 13 101.826 102.93 Pa 102.93 10.48531 13 101.826 0.71 0.006 U2Δp/4ΔpPoint 10 102.93 10.5 3.240 10.5 13 101.826 102.93 Pa 0.19Point 11 102.93 10.5 3.240 10.5 13 101.826 102.93 Pa 0.00 Std Dev 20.29 2√ΔPPoint 12 102.93 10.5 3.240 10.5 13 101.826 102.93 Pa 0.00 10.15 √ΔPPoint 13 102.93 10.5 3.240 10.5 13 101.826 102.93 Pa 1.52 UΔp 2.32 U2ΔpPoint 14 102.93 10.5 3.240 10.5 13 101.826 102.93 Pa 102.93 10.48531 13 101.826 0.71 0.006 U2Δp/4ΔpPoint 15 102.93 10.5 3.240 10.5 13 101.826 102.93 Pa 0.19Point 16 102.93 10.5 3.240 10.5 13 101.826 102.93 Pa 0.00 Std Dev 20.29 2√ΔPPoint 17 102.93 10.5 3.240 10.5 13 101.826 102.93 Pa 0.00 10.15 √ΔPPoint 18 102.93 10.5 3.240 10.5 13 101.826 102.93 Pa 1.52 UΔp 2.32 U2ΔpPoint 19 102.93 10.5 3.240 10.5 13 101.826 102.93 Pa 102.93 10.48531 13 101.826 0.71 0.006 U2Δp/4ΔpPoint 20 102.93 10.5 3.240 10.5 13 101.826 102.93 Pa 0.19Total Average: 10.5 3.240370349 10.5 13.00 101.826 102.93 Pa 10.48531 13 101.826 0.023 ∑U2Δp/4ΔpHiges to Lowest flow ratio: 1.0 :1 Max flow: 10.49 1647 (∑√Δp)2Requirement is Duct Flow ratio of max. to min. <3:1 Min. Flow: 10.49

Pitot Tube Checks: CommentsKIMO Pitot EQ080 Mill 5 Pitot EQ081None None

Inernal Leakage Check

Pressuriezed pressure: 11mmH2O 12 mm H2OTime of leak check: 15 sec 15 sec

Leak Check Result: Pass Pass

<10Pa <10PA

S-tupe pitot tube shall be positioned perpendicular to the direction of the flow. The static pressure is than measured using both taps. The difference in

the measured static pressure should be < 10PaCheck on stagnation and reference pressure taps:

Deformities, Burrs, Damage

Uncertainty Calc

Note: blow through the pitot impact opening until at least 7.6 cm (3.0 in.) H20 velocity head registers on the manometer; then, close off the impact

opening. The pressure shall remain stable for at least 15 seconds; (2) do the same for the static pressure side, except using suction to obtain the

minimumof 7.6 cm (3.0 in.) H20.

Uncertainty Calculations

Differencial Pressure

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GEN2-002rev179/18/2015QM


4/27/2016016-058

Results:

Circular StackStak Diameter: 0.794 m WAF Wall effect correction factor:

Average flow: 10.49 m/s Smooth walled ducts 0.995Wall effect correction factor: 1Average Flow corrected for wall effect: 10.49 m/s Rough Walled ducts 0.99 bricks, mortar Average Temperature: 286.00 KAverage Pressure: 101.826 kPaAverage Moisture: %Average Oxygen: %

Reeference Conditions:Reference Temperature: 273.15 KReference Pressure: 101.325 kPa

Reference Moisture: 0 %Reference Oxygen: 0 %

Mass Emissions Calculations:Volumetric Flow Rate 5.19 m3/s

Volumetric Flow Rate 18690.23 m3/h

Volumertic Flow Rate corrected to STP 17933.31 m3/h17933.31 m3/h17933.31 m3/h

Uncertainty Calculations:Input Quantities:

UnitDiameter of Stack 0.794 m 2 % Max permissible errorNumber of points measured: 4Temperature: 286 K 1 % AccuracyAtmospheric Pressure: 10182.6 Pa 300 Pa Max permissible error estimated at 20 PaOxygen content: 20.90 % dry 6 ± % Volume fraction on d 20.1 % wetCO2 content: 0.06 % dry 6 ± % Volume fraction on d 0.1 % wetH2O content 4 % 20 ± % Volume fraction on dry gasDensity of Gas 1.22 kg/m3Absolute pressure 101826 Paaverage Velocity 10.48531102 m/sPitot Tube characteristic 1.01 K 0.02 ±Standard unc on the coefficient ot th 0.01 u(K)Range: 0 1000 PaResolution 1 PaCalibration Uncertainty 2 Pa 2 coverage factorDrift 0.1 % of the range between 2 calibrationLack of fit 0.06 % of the rangeMollar Mass Wet (M 0.284456 kg/molunc H2O 0.4 %unc O2 0.61 %unc CO2 0.00 %unc Molar Weight 0.00006 Kg/molunc Temp 1.43 KAbs press unc 174.38 Paunc Patm 173.30 Pastd unc associated with the density u(ρ) 0.0045 kg/m3

0.25 m/sExpanded uncertaexpressed with a level of confidence of 9 0.49 ±m/sExpanded uncertaexpressed with a level of confidence of 9 4.71 ±%

Volumertic Flow Rate corrected to STP O2 ref and MoistureVolumertic Flow Rate corrected to STP and O2 ref

Note: The correction of average velocity for wall effect is not required for measurements to support

isokinetic sampling.

A default wall effect adjustments factors may be used without without taking wall effect measurements.

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Company Name: KMK Doc No GEN2-002rev17Licence No: W0113-04 Rev Date: 9/18/2015Year: 2016 Visit No: 2 Issued by: QMSampling Date: 4/27/2016Report No: 016-058 Isokinetic Samplin for A2-5

Millenium 5 consEQ069 Filter Holder: EQ084 Glass Filter Holder EQ085Probe: EQ071 Pitot Tube: EQ081 Notes: Do not sample point with higher th Impingers: EQ072 Nozzle: EQ087 If the negative flow was founs poin Sampling Line: EQ070 Run Filter Number: Blank Filter Number: If the suitable sampling location co

Determination of Nozzle size: K factor:

ΔH@ 56.6 mmHg calculated on the 14/08/2015Tm 21 °C Meter Temperature estimated

Vdessired 0.5 m3Ts 13 °C K= 3.88Ps 763.757809 mmHgCp 0.806 S-type pitot tube constant Eastimated Volume Metered:θ 30 minutesBwo 0.04(√(∆𝑃𝑃)) 𝑎𝑎𝑎𝑎𝑎𝑎 3.24ΔP 10.5 mmH2O

Dn2= 36.63 mm2 EstVmstd= 0.49361 m3

Estimated sampling rate: 16.5 l/min 0.9872 m3/hr

Note: Max sampling flow rate is 23l/min

Availlable Nozzle sizes

Dn (calculated nozzle size 6.05 mm 2.7

6.08 mm 4.385.95 mm 6.016.01 mm 7.56

Dn= Used nozzle size 6.01 mm 11.00Cross sectional Area of the nozzle: 28.40 mm2 12.45

Nozzle Measurements:

𝐷𝐷𝑛𝑛2 =𝑉𝑉𝑑𝑑𝑑𝑑𝑠𝑠𝑆𝑆𝑑𝑑𝑑𝑑𝑑𝑑

𝑀𝑀𝑠𝑠(𝑇𝑇𝑠𝑠 + 𝐶73)𝑃𝑃𝑠𝑠

(5.9195 ∗ 10−4)𝐶𝐶𝑝𝑝𝜃𝜃(1 − 𝐵𝐵𝑤𝑤𝑤𝑤)( ∆𝑃𝑃)𝑎𝑎𝑎𝑎𝑎𝑎

𝐾𝐾 = 8.04 ∗ 10−5 ∗ 𝐶𝐶𝑝𝑝2 ∗ ∆𝐻𝐻𝐻𝑇𝑇𝑚𝑚 + 𝐶73𝑇𝑇𝑠𝑠 + 𝐶73

∗𝑃𝑃𝑠𝑠𝑃𝑃𝑏𝑏

∗𝑀𝑀𝑑𝑑

𝑀𝑀𝑠𝑠∗ (1 − 𝐵𝐵𝑤𝑤𝑤𝑤)(𝐷𝐷𝑛𝑛)4

𝐸𝐸𝐸𝐸𝐸𝐸𝑉𝑉𝑚𝑚𝑠𝑠𝑆𝑆𝑑𝑑 = 5.9195 ∗ 10−4 ∗ 𝐶𝐶𝑝𝑝𝑃𝑃𝑠𝑠

𝑀𝑀𝑠𝑠 273+𝑇𝑇𝑠𝑠∗ ( ∆𝑃𝑃)𝑎𝑎𝑎𝑎𝑎𝑎 ∗ 𝐷𝐷𝑛𝑛2𝜃𝜃(1 −𝐵𝐵𝑤𝑤𝑤𝑤)

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mailto:%CE%94H@

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0.329072906 L/min

Calibration Date:

Leak Check: Filter pre-heated temp 161 Nominal Flow RatesCorrection Factor

Vacum PressuL/min Time Pass/Fail m3/hrBefore Blank -13 0 2 min Pass 0.25After Blank -10 0 2 min Pass 0.5Before Run: -9 0 2 min Pass 1Afrer Run: -10 0 2 min Pass 1.5

Sampling: 2

Stack Diameter 0.794 m Start Time: 11:08:00 AM End Time: 2.5Cross sectional Area of the stack: 0.495 m2

Volume Correction Factor 1

Points number 4 Sampling time at each po 8 min.

Traverse point number Clock Time Pump Vacuum Velocity Heads Sqr roots Velocity

Heads

Orfice Settings

Calculated

Orfice Settings

Readings

Gas Sample Volume

Stack Temp

Probe Temp

Impinger Temp Tc Filter Temp

K Factor Calculat

edVelocity of the stack

Actual Flow Of Stack

Vmstd at the time of measuring

Isokinetic Ratio

mmHg ΔPs √ΔPs ΔH ΔHVm

(m3/1000) (liters)

°C °C °C °C Inlet °C Outlet °Cm/s m3/min m3 %

0 -3 10.5 3.240 38.896 40 2345 13 161 4 8 8 3.70 10.49 311.501 4 -3 10.5 3.240 38.896 40 2411 13 161 4 8 8 3.70 10.49 311.50 0.0646 98.281 8 -3 10.5 3.240 38.896 40 2479 13 161 4 8 8 3.70 10.49 311.50 0.1312 99.772 12 -3 10.5 3.240 38.896 40 2542 13 161 4 8 8 3.70 10.49 311.50 0.1929 97.792 16 -3 10.5 3.240 38.896 40 2611 13 161 4 8 8 3.70 10.49 311.50 0.2605 99.033 20 -3 10.5 3.240 38.896 40 2674 13 161 4 8 8 3.70 10.49 311.50 0.3222 97.983 24 -3 10.5 3.240 38.896 40 2735 13 161 4 8 8 3.70 10.49 311.50 0.3819 96.794 28 -3 10.5 3.240 38.896 40 2803 13 161 4 8 8 3.70 10.49 311.50 0.4485 97.434 32 -3 10.5 3.240 38.896 40 2876 13 161 4 8 8 3.70 10.49 311.50 0.5200 98.84

Average: 10.50 3.24 40.00 13.00 161.00 4.00 #DIV/0! 8.00 8.00 10.49 311.50 -1.16531.00

Moisture: The temperature at the outlet of trapping unit shall not be greater than 4 °C or by checking visually the amount of silica gel having

faded in the last impinger or cartridge. This

Gas Sample Temperature at Dry Gas

Meter

Allowable leak check less than:

Particulates: When using in-stack filtration, to prevent condensation forming on the filter, the filtration device should be externally pre-heated to a temperature above

the stack gas temperature or preheated in stack

Metals: When using titanium equipment the temperature shall be maintained at 180°C or

higher. Impinger should be kept below 30°C. Note: The length of connections (tubing) from sampling

probe to the absorbers shall be <1 m.

11:40:00 AM

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Circular StackStak Diameter: 0.794 m

Average Flow corrected for wall effect: 10.49 m/s

Average Temperature: 286.00 K

Average Pressure: 101.826 kPaAverage Moisture: %Average Oxygen: %

Reeference Conditions:Reference Temperature: 273.15 KReference Pressure: 101.325 kPaReference Moisture: 0 %Reference Oxygen: 0 %

Mass Emissions Calculations:Volumetric Flow Rate 5.19 m3/sVolumetric Flow Rate 18690.23 m3/hVolumertic Flow Rate corrected to STP 17933.31 m3/h

17933.31 m3/h17933.31 m3/h

Volumertic Flow Rate corrected to STP and O2 refVolumertic Flow Rate corrected to STP O2 ref and

Note: If the results of isokinetic sampling are to be reported as mass emission, than the flow rate used during isokinetic sampling shall be used.

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Company Name: KMK Doc No GEN2-002rev17Licence No: W0113-04 Rev Date: 9/18/2015Year: 2016 Visit No: 2 Issued by: 0 QMSampling Date: 4/27/2016Report No: 016-058 Moisture Record and Calculations for A2-5

Millenium 5 console: EQ069 Balance: EQ056Probe: EQ071 Pitot Tube: EQ081Impingers: EQ072 Nozzle: EQ087Sampling Line: EQ070 Weights: EQ063Balance Check:Initial Weight: Balance Reading:100g 100.1500g 499.9800g (combined 100g,200g,500g) 800

Before

Readings:Impinger 1 + Connection

Impinger 2+Connection


Impinger 4+Connection Sum:

1 865.4 863.2 643.6 1039.8 34122 865.4 863.2 643.6 1039.8 34123 865.4 863.2 643.6 1039.8 34124 865.4 863.2 643.6 1039.8 34125 865.4 863.2 643.6 1039.8 34126 865.4 863.2 643.6 1039.8 34127 865.4 863.2 643.6 1039.8 34128 865.4 863.2 643.6 1039.8 34129 865.4 863.2 643.6 1039.8 3412

10 865.4 863.2 643.6 1039.8 3412Standard Deviation: 0 0 0 0 0Averge: 865.4 863.2 643.6 1039.8 3412

After

Readings:Impinger 1+Connection



Impinger 4+Connection Sum:

1 873.6 865.3 644.1 1039.9 3422.92 873.6 865.3 644.1 1039.9 3422.93 873.6 865.3 644.1 1039.9 3422.94 873.6 865.3 644.1 1039.9 3422.95 873.6 865.3 644.1 1039.9 3422.96 873.6 865.3 644.1 1039.9 3422.97 873.6 865.3 644.1 1039.9 3422.98 873.6 865.3 644.1 1039.9 3422.99 873.6 865.3 644.1 1039.9 3422.9

10 873.6 865.3 644.1 1039.9 3422.9Standard Deviation: 0 0 0 0 0Averge: 873.6 865.3 644.1 1039.9 3422.9

The temperature at the outlet of trapping unit shall not be greater than 4 °C or by checking visually the amount of

silica gel having faded in the last impinger or cartridge. This amount shall not exceed 50 %.

Note: If balance is moved to other location balance check has to be repeated.

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Air Volume corrected to STP: 0.520027603 m3

Efficiency: 99.08 %

Stack Conditions

Average Temperature: 286 KAverage Pressure: 101.826 kPaAverage Moisture: 0 %Average Oxygen: 0 %

17933.31 m3/hr

Reference Conditions:Reference Temperature: 273.15 KReference Pressure: 101.325 kPaReference Oxygen: 0 %Reference Moisture: 0 %

Results :At Standard

Temperature and Pressure

corrected O2 ref Uncertainty

g/m3 21.0 21.0 2.9 Overall uncertainty is 13.66 % of the measured value% 2.5 2.5 0.3

Note: Overall uncertainty should be lower than +/-20% of the measured value

Volumertic Flow Rate corrected to STP O2 ref and Moisture

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Moisture Uncertainty CalculationsMeasured concentration 2.5 % (at STP)Measured Quantities Symbol Value Standard uncertainty UnitsSampled Volume Vm 0.520027603 uVm 0.001 m3Sampled gas Temperature Tm 286 uTm 2 kSampled gas Pressure ρm 101.826 uρm 1 kPaEfficiency Ɛ 99.08 %Oxygen content O2,m 0 uO2,m 0.1 % by volumeWater collected in condensation stage 10.90Water collected in adsorption stage 0Wate collected in addidional unit 0.1Water collected in trapping unit m 11.00 um 0.00 gIntermediate calculationsVwc 152.0027603 ^2

13.5 181.2 Efficiency uncertainty 0.08-1.5 2.2 support 0.08-1.9 3.4 calculations 0.00

√water in trapping unit 3.3

water in adsorption stage 0.0Uncertainty Efficiency^2 0.1Volume ^2 0.7Sensityvity coefficiency 603.6Uncertainty efficiency 0.00

Repatability standard devWeight in the field st 0.0 0.0Sampled Volume 0.002 0.0Sampled gas Temperature 0.02 0.0Sampled gas Pressure 0.3 0.2Combined measurement uncertainty 0.17 %

Expanded uncertainty as percentage of measured value 13.66 % measured of value expressed with a level of confidence of 95%(Using a coverage factor k=2)

Expanded uncertainty in units of measurement 0.35 % of water vapour

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Company Name: KMK Doc No GEN2-002rev17Licence No: W0113-04 Rev Date: 9/18/2015Year: 2016 Visit No: 2 Issued by: QMSampling Date: 4/27/2016Report No: 016-058 Particulates Results Calculations for A2-5

Paticulates Data:

Certs Results: mg Date analysis completed:LOD Filter: 0.05 5/6/2016

LOD Nozzle Wash: 0.3SAL Sample reference

number:Blank Filter: 0.05 566545 002Blank Nozzle Wash: 0.3 566545 004Run Filter: 0.05 566545 001Run Nozzle Wash: 0.3 566545 003

0.35Blank 0.35Run 0.35

Dry Air Volume corrected to STP: 0.520027603 m3

Stack ConditionsAverage Temperature: 286 KAverage Pressure: 101.826 kPaAverage Moisture: 0 %Average Oxygen: 0 %

17933.31 m3/h

Reference ConditionsReference Temperature: 273.15 KReference Pressure: 101.325 kPaReference Oxygen: 0 %Reference Moisture: 0 %

Particulates Results :mg/m3 mg/m3 kg/hr Uncertainty

corrected to O2 mg/m3 Note: Blank result should be < 10% of ELVLOD 0.67 0.67 0.01 n/a <20% for ELV 5mg/m3 or lowerBlank 0.67 0.67 0.01 0.02 Blank result is: 7 % of ELVRun 0.67 0.67 0.01 0.02 If the blank result is higher than requirements of ELV result should be rejected

Volumertic Flow Rate corrected to STP O2 ref and Moisture

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Particulates Uncertainty Run CalculationsUncertainty calculation for EN 13284 Determination of low range mass concentration of dust, Manual Gravimetric Methodv14Limit value (ELV) 10 mg.m-3 Reference oxygen 0 % by volumeMeasured concentration 0.67 mg.m-3 (at reference conditions)Measured Quantities Symbol Value Standard uncertainty Units Uncertaint Uncertaint Requirement of stdSampled Volume Vm 0.520027603 uVm 0.001 m3 0.19 <=2%Sampled gas Temperature Tm 286 uTm 2 k 0.70 <=1%Sampled gas Pressure ρm 101.826 uρm 1 kPa 0.98 <=1%Sampled gas Humidity Hm 0 uHm 1 % by volume 1.00 <=1%Oxygen content O2,m 0 uO2,m 0.1 % by volume #DIV/0! <=5%Mass particulate m 0.35 um 0.00 mg 0.00 0.00 <5% of limit valueNote - Sampled gas humidity, temperature and pressure are values at the gas meterLeak L 0 % 0.00 <=2%Uncollected Mass UCM 0 mg 0 <=10%(Instack filter - no rinse)Intermediate calculationsFactor for std conds fs 0.96uncertainty components symbol sensitivity coeff u (in units of fs)

ρm 0.009 0.009Hm 0.010 0.010Tm 0.003 0.007ufs 0.015 1.57

Corrected volume V 0.50 uV 0.008 m3 1.58

Factor for O2 correction fc 1.00uncertainty components symbol sensitivity coeff u

O2,m 0.05 0.005Factor for O2 Correction ufc 1.00 0.005 0.48Parameter Value Units Sensitivity c Uncertainty contribution Uncertainty as %Corrected Volume (standard con V 0.50 m3 1.35 0.01 mg.m-3 0.11 %Mass m 0.35 mg 1.92 0.00 mg.m-3 0.00 %Factor for O2 Correction fc 1.00 0.67 0.00 mg.m-3 0.03 %Leak L 0.00 mg.m-3 1.00 0.00 mg.m-3 0.00 %Uncollected mass UCM 0.00 mg 1.92 0.00 mg.m-3 0.00 %Combined measurement uncertainty 0.01 mg.m-3


Expanded uncertainty in units of measurement 0.02 mg.m-3Requirement in standard is for uncertainty to be < 30% at ELV at standard conditions

Expanded uncertainty as percentage of limit value 0.2 % ELV

sm fVV =

m

refc O

Of

,2

,2

2121

−

−=

cfVmc =

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Particulates Uncertainty Blank CalculationsUncertainty calculation for EN 13284 Determination of low range mass concentration of dust, Manual Gravimetric Methodv14Limit value (ELV) 1 mg.m-3 Reference oxygen 0 % by volumeMeasured concentration 0.7 mg.m-3 (at reference conditions)Measured Quantities Symbol Value Standard uncertainty Units Uncertaint Uncertaint Requirement of stdSampled Volume Vm 0.520027603 uVm 0.001 m3 0.19 <=2%Sampled gas Temperature Tm 286 uTm 2 k 0.70 <=1%Sampled gas Pressure ρm 101.826 uρm 1 kPa 0.98 <=1%Sampled gas Humidity Hm 0 uHm 1 % by volume 1.00 <=1%Oxygen content O2,m 0 uO2,m 0.1 % by volume #DIV/0! <=5%Mass particulate m 0.35 um 0.00 mg 0.00 0.00 <5% of limit valueNote - Sampled gas humidity, temperature and pressure are values at the gas meterLeak L 0 % 0.00 <=2%Uncollected Mass UCM 0 mg 0 <=10%(Instack filter - no rinse)Intermediate calculationsFactor for std conds fs 0.96uncertainty components symbol sensitivity coeff u (in units of fs)

ρm 0.009 0.009Hm 0.010 0.010Tm 0.003 0.007ufs 0.015 1.57

Corrected volume V 0.50 uV 0.008 m3 1.58

Factor for O2 correction fc 1.00uncertainty components symbol sensitivity coeff u

O2,m 0.05 0.005Factor for O2 Correction ufc 1.00 0.005 0.48Parameter Value Units Sensitivity c Uncertainty contribution Uncertainty as %Corrected Volume (standard con V 0.50 m3 1.35 0.01 mg.m-3 1.06 %Mass m 0.35 mg 1.92 0.00 mg.m-3 0.00 %Factor for O2 Correction fc 1.00 0.67 0.00 mg.m-3 0.32 %Leak L 0.00 mg.m-3 1.00 0.00 mg.m-3 0.00 %Uncollected mass UCM 0.00 mg 1.92 0.00 mg.m-3 0.00 %Combined measurement uncertainty 0.01 mg.m-3


Expanded uncertainty in units of measurement 0.02 mg.m-3

Expanded uncertainty as percentage of limit value 2.2 % ELV

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Millenium 5 consEQ069 Filter Holder: EQ084 Glass Filter Holder EQ085Probe: EQ071 Pitot Tube: EQ081 Notes: Do not sample point with higher th Impingers: EQ072 Nozzle: EQ087 If the negative flow was founs poin Sampling Line: EQ070 Run Filter Number: Blank Filter Number: If the suitable sampling location co

Determination of Nozzle size: K factor:

ΔH@ 56.6 mmHg calculated on the 14/08/2015Tm 21 °C Meter Temperature estimated

Vdessired 0.5 m3Ts 13 °C K= 3.86Ps 763.757809 mmHgCp 0.806 S-type pitot tube constant Eastimated Volume Metered:θ 30 minutesBwo 0.04(√(∆𝑃𝑃)) 𝑎𝑎𝑎𝑎𝑎𝑎 3.24ΔP 10.5 mmH2O

Dn2= 36.63 mm2 EstVmstd= 0.49252 m3

Estimated sampling rate: 16.4 l/min 0.985 m3/hr

Note: Max sampling flow rate is 23l/min

Availlable Nozzle sizes

Dn (calculated nozzle size 6.05 mm 2.7

5.89 mm 4.386.05 mm 6.016.08 mm 7.56

Dn= Used nozzle size 6.01 mm 11.00Cross sectional Area of the nozzle: 28.34 mm2 12.45

Nozzle Measurements:

𝐷𝐷𝑛𝑛2 =𝑉𝑉𝑑𝑑𝑑𝑑𝑠𝑠𝑆𝑆𝑑𝑑𝑑𝑑𝑑𝑑

𝑀𝑀𝑠𝑠(𝑇𝑇𝑠𝑠 + 𝐶73)𝑃𝑃𝑠𝑠

(5.9195 ∗ 10−4)𝐶𝐶𝑝𝑝𝜃𝜃(1 − 𝐵𝐵𝑤𝑤𝑤𝑤)( ∆𝑃𝑃)𝑎𝑎𝑎𝑎𝑎𝑎

𝐾𝐾 = 8.04 ∗ 10−5 ∗ 𝐶𝐶𝑝𝑝2 ∗ ∆𝐻𝐻𝐻𝑇𝑇𝑚𝑚 + 𝐶73𝑇𝑇𝑠𝑠 + 𝐶73

∗𝑃𝑃𝑠𝑠𝑃𝑃𝑏𝑏

∗𝑀𝑀𝑑𝑑

𝑀𝑀𝑠𝑠∗ (1 − 𝐵𝐵𝑤𝑤𝑤𝑤)(𝐷𝐷𝑛𝑛)4

𝐸𝐸𝐸𝐸𝐸𝐸𝑉𝑉𝑚𝑚𝑠𝑠𝑆𝑆𝑑𝑑 = 5.9195 ∗ 10−4 ∗ 𝐶𝐶𝑝𝑝𝑃𝑃𝑠𝑠

𝑀𝑀𝑠𝑠 273+𝑇𝑇𝑠𝑠∗ ( ∆𝑃𝑃)𝑎𝑎𝑎𝑎𝑎𝑎 ∗ 𝐷𝐷𝑛𝑛2𝜃𝜃(1 −𝐵𝐵𝑤𝑤𝑤𝑤)

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mailto:%CE%94H@

Page15of20


0.328343659 L/min

Calibration Date:

Leak Check: Filter pre-heated temp 180 Nominal Flow RatesCorrection Factor

Vacum PressuL/min Time Pass/Fail m3/hrBefore Blank -12 0 2 min Pass 0.25After Blank -11 0 2 min Pass 0.5Before Run: -10 0 2 min Pass 1Afrer Run: -10 0 2 min Pass 1.5

Sampling: 2

Stack Diameter 0.794 m Start Time: 12:01:00 PM End Time: 2.5Cross sectional Area of the stack: 0.495 m2

Volume Correction Factor 1

Points number 4 Sampling time at each po 8 min.

Traverse point number Clock Time Pump Vacuum Velocity Heads Sqr roots Velocity

Heads

Orfice Settings

Calculated

Orfice Settings

Readings

Gas Sample Volume

Stack Temp

Probe Temp

Impinger Temp Tc Filter Temp

K Factor Calculat

edVelocity of the stack

Actual Flow Of Stack

Vmstd at the time of measuring

Isokinetic Ratio

mmHg ΔPs √ΔPs ΔH ΔHVm

(m3/1000) (liters)

°C °C °C °C Inlet °C Outlet °Cm/s m3/min m3 %

0 -4 10.5 3.240 38.724 80 2885 13 184 8 8 8 3.69 10.49 311.501 4 -4 10.5 3.240 38.724 80 2953 13 184 8 8 8 3.69 10.49 311.50 0.0669 101.881 8 -4 10.5 3.240 38.724 80 3024 13 184 8 8 8 3.69 10.49 311.50 0.1367 104.122 12 -4 10.5 3.240 38.724 80 3089 13 184 8 8 8 3.69 10.49 311.50 0.2006 101.882 16 -4 10.5 3.240 38.724 80 3154 13 184 8 8 8 3.69 10.49 311.50 0.2645 100.753 20 -4 10.5 3.240 38.724 80 3228 13 184 8 8 8 3.69 10.49 311.50 0.3372 102.773 24 -4 10.5 3.240 38.724 80 3299 13 184 8 8 8 3.69 10.49 311.50 0.4070 103.374 28 -4 10.5 3.240 38.724 80 3368 13 184 8 8 8 3.69 10.49 311.50 0.4748 103.374 32 -4 10.5 3.240 38.724 80 3421 13 184 8 8 8 3.69 10.49 311.50 0.5269 100.38

Average: 10.50 3.24 80.00 13.00 184.00 8.00 #DIV/0! 8.00 8.00 10.49 311.50 0.38536.00

Allowable leak check less than:

Particulates: When using in-stack filtration, to prevent condensation forming on the filter, the filtration device should be externally pre-heated to a temperature above

the stack gas temperature or preheated in stack

Metals: When using titanium equipment the temperature shall be maintained at 180°C or

higher. Impinger should be kept below 30°C. Note: The length of connections (tubing) from sampling

probe to the absorbers shall be <1 m.

Moisture: The temperature at the outlet of trapping unit shall not be greater than 4 °C or by checking visually the amount of silica gel having

faded in the last impinger or cartridge. This

12:33:00 PM

Gas Sample Temperature at Dry Gas

Meter

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Page16of20


Circular StackStak Diameter: 0.794 m

Average Flow corrected for wall effect: 10.49 m/s

Average Temperature: 286.00 K

Average Pressure: 101.826 kPaAverage Moisture: %Average Oxygen: %

Reeference Conditions:Reference Temperature: 273.15 KReference Pressure: 101.325 kPaReference Moisture: 0 %Reference Oxygen: 0 %

Mass Emissions Calculations:Volumetric Flow Rate 5.19 m3/sVolumetric Flow Rate 18690.23 m3/hVolumertic Flow Rate corrected to STP 17933.31 m3/h

17933.31 m3/h17933.31 m3/hVolumertic Flow Rate corrected to STP O2 ref and

Note: If the results of isokinetic sampling are to be reported as mass emission, than the flow rate used during isokinetic sampling shall be used.

Volumertic Flow Rate corrected to STP and O2 ref

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Company NamKMK Doc No GEN2-002rev17Licence No: W0113-04 Rev Date: 9/18/2015Year: 2016 Visit No: 2 Issued by: QMSampling Date 4/27/2016Report No: 016-058 Metals Results Calculations for A2-5

Run Lab Results LOD Filter LOD Probe W LOD Impingers Filter Rince Impinger 1&2 Impinger 3 Impinger 5 Impnger 6

µg µg µg/l µg µg µg/l µg/l µg/l µg/lAluminium 50 50 0.4 50 4 16 25 n/a n/aAntimony 0.4 0.4 0.4 0.4 0.4 0.4 0.4 n/a n/aArsenic 0.3 0.3 0.2 0.3 0.2 0.2 0.2 n/a n/aBerylium 0.7 0.7 0.3 0.7 0.3 0.3 0.3 n/a n/aCadmium 0.1 0.1 0.2 0.1 0.2 0.2 0.2 n/a n/aChromium 0.2 0.2 0.6 0.2 0.6 0.6 7.2 n/a n/a

Cobalt 0.2 0.2 0.2 0.2 0.2 0.2 0.2 n/a n/aCopper 0.3 0.4 0.1 0.3 5.4 0.62 5.5 n/a n/a

Iron 5 5 10 5 10 23 100 n/a n/aLead 0.1 0.1 0.4 0.1 0.3 0.98 11.2 n/a n/a

Manganese 0.2 0.2 0.3 0.2 12 0.64 0.3 n/a n/aNickel 0.9 0.9 0.4 0.9 0.4 0.95 0.4 n/a n/a

Selenium 0.4 0.4 0.3 0.4 0.3 0.3 0.3 n/a n/aThallium 0.3 0.36 0.3 0.3 0.3 0.3 0.3 n/a n/a

Vanadium 0.2 0.2 0.3 0.2 0.3 0.3 0.3 n/a n/aZinc 0.4 0.4 2 5.5 2 60 100 n/a n/a

Mercury 0.1 0.00648 0.0108 0.1 0.00648 1.314 0.024 0.00000022 0.00000059Run Blank

Solutions Volume Rinse Impinger 1 Impinger 2 Impinger 3 Impinger 4 Impinger 5 Rinse Impinger 1 Impinger 2 Impinger 3ml 108 180 96 84 98 94 142

Metals Mercury0.526939474 m3 0.526939474 m3

Average Temperature: 286 KAverage Oxygen: 0 %

17933.31 m3/hrVolumertic Flow Rate corrected to STP O2 ref and Moisture

Dry Air Volume corrected to STP:

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Company NamKMK Doc No GEN2-002rev17Licence No: W0113-04 Rev Date: 9/18/2015Year: 2016 Visit No: 2 Issued by: QMSampling Date 4/27/2016Report No: 016-058 Metals Results Calculations for A2-5

Reference Conditions:Reference Temperature: 273.15 KReference Pressure: 101.325 kPaReference Oxygen: 0 %Reference Moisture: 0 %

Results :mg in sampling train

mg in sampling train

mg in sampling train

mg/m3 at STP/Dry

mg/m3 at STP/Dry

mg/m3 at STP/Dry

Corrected to reference oxygen



LOD Run Blank LOD Run Blank LOD Run BlankAluminium 0.1001 0.0593 0.0792 0.1900 0.1125 0.1503 0.1900 0.1125 0.1503Antimony 0.0009 0.0009 0.0013 0.0017 0.0017 0.0025 0.0017 0.0017 0.0025Arsenic 0.0007 0.0006 0.0006 0.0012 0.0011 0.0012 0.0012 0.0011 0.0012Berylium 0.0015 0.0011 0.0014 0.0028 0.0021 0.0027 0.0028 0.0021 0.0027Cadmium 0.0003 0.0004 0.0002 0.0005 0.0007 0.0004 0.0005 0.0007 0.0004Chromium 0.0006 0.0016 0.0005 0.0011 0.0030 0.0009 0.0011 0.0030 0.0009Cobalt 0.0005 0.0005 0.0004 0.0009 0.0009 0.0008 0.0009 0.0009 0.0008Copper 0.0007 0.0063 0.0020 0.0014 0.0120 0.0037 0.0014 0.0120 0.0037Iron 0.0128 0.0287 0.0164 0.0242 0.0545 0.0312 0.0242 0.0545 0.0312Lead 0.0003 0.0017 0.0007 0.0006 0.0031 0.0013 0.0006 0.0031 0.0013Manganese 0.0005 0.0123 0.0005 0.0009 0.0234 0.0009 0.0009 0.0234 0.0009Nickel 0.0019 0.0015 0.0019 0.0036 0.0029 0.0035 0.0036 0.0029 0.0035Selenium 0.0009 0.0008 0.0008 0.0017 0.0015 0.0016 0.0017 0.0015 0.0016Thallium 0.0007 0.0007 0.0007 0.0014 0.0013 0.0013 0.0014 0.0013 0.0013Vanadium 0.0005 0.0006 0.0004 0.0009 0.0011 0.0007 0.0009 0.0011 0.0007Zinc 0.0014 0.0279 0.0029 0.0026 0.0529 0.0055 0.0026 0.0529 0.0055Mercury 0.0001 0.0003 0.0001 0.0002 0.0007 0.0002 0.0002 0.0007 0.0002

Total of Metals 0.1241 0.1448 0.1099 0.2355 0.2747 0.2086 0.2355 0.2747 0.2086

Total of Cd and Tl 0.0010 0.0010 0.0009 0.0019 0.0020 0.0018 0.0019 0.0020 0.0018

Total of Sb, As, Pb, Cr, Co, Cu, Mn, Ni, V, Be 0.0080 0.0270 0.0096 0.0152 0.0513 0.0182 0.0152 0.0513 0.0182

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Company NamKMK Doc No GEN2-002rev17Licence No: W0113-04 Rev Date: 9/18/2015Year: 2016 Visit No: 2 Issued by: QMSampling Dat 4/27/2016Report No: 016-058 Metals Results Calculations for A2-5

BlankLab Results Filter Rince Impinger 1 Impinger 2 Impinger 3 Impinger 5 Impnger 6

µg µg µg/l µg/l µg/l µg/l µg/lAluminium 50 28 8.6 n/a n/aAntimony 0.4 0.86 0.4 n/a n/aArsenic 0.3 0.3 0.2 n/a n/aBerylium 0.7 0.7 0.3 n/a n/aCadmium 0.1 0.1 0.2 n/a n/aChromium 0.2 0.2 0.6 n/a n/a

Cobalt 0.2 0.2 0.2 n/a n/aCopper 0.3 1.1 3.9 n/a n/a

Iron 5 10 10 n/a n/aLead 0.1 0.52 0.3 n/a n/a

Manganese 0.2 0.23 0.3 n/a n/aNickel 0.9 0.9 0.4 n/a n/a

Selenium 0.4 0.4 0.3 n/a n/aThallium 0.3 0.36 0.3 n/a n/a

Vanadium 0.2 0.12 0.3 n/a n/aZinc 0.4 2.2 2 n/a n/a

Mercury 0.1 0.00564 0.0000003 0.00000006

Impinger 4 Impinger 5 170

Note: Blank result should be < 10% of ELVIf the blank result is higher than requirements of ELV result should be rejected

If one of the metal elements in the last impinger is more than 10% of the total combined

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Company NamKMK Doc No GEN2-002rev17Licence No: W0113-04 Rev Date: 9/18/2015Year: 2016 Visit No: 2 Issued by: QMSampling Dat 4/27/2016Report No: 016-058 Metals Results Calculations for A2-5

metals (i.e. the filter, probe rinse and impingers) collected then the result shall berejected, unless the total result is less than 30% of the ELV.

Efficiency Check

kg/hr kg/hr kg/hr Efficiency

Efficiency

Requirements ELV

Result as percentage

of ELV

Blank Result as percentage of ELV

LOD Run Blank %0.0034 0.0020 0.0027 4.05 10 #DIV/0! #DIV/0!0.0000 0.0000 0.0000 4.22 10 #DIV/0! #DIV/0!0.0000 0.00002 0.0000 3.46 10 #DIV/0! #DIV/0!0.0001 0.0000 0.0000 2.66 10 #DIV/0! #DIV/0!0.0000 0.00001 0.0000 5.41 10 #DIV/0! #DIV/0!0.0000 0.00005 0.0000 43.22 10 #DIV/0! #DIV/0!0.0000 0.0000 0.0000 4.22 10 #DIV/0! #DIV/0!0.0000 0.0002 0.0001 8.33 10 #DIV/0! #DIV/0!0.0004 0.0010 0.0006 33.40 10 #DIV/0! #DIV/0!0.0000 0.0001 0.0000 65.10 10 #DIV/0! #DIV/0!0.0000 0.0004 0.0000 0.23 10 #DIV/0! #DIV/0!0.0001 0.00005 0.0001 2.54 10 #DIV/0! #DIV/0!0.0000 0.0000 0.0000 3.68 10 #DIV/0! #DIV/0!0.0000 0.0000 0.0000 4.22 10 #DIV/0! #DIV/0!0.0000 0.0000 0.0000 4.94 10 #DIV/0! #DIV/0!0.0000 0.0009 0.0001 34.41 10 #DIV/0! #DIV/0!0.0000 0.00001 0.0000 0.00 5 #DIV/0! #DIV/0!

0.0042 0.0049 0.0037 For example ELVs for metals may be:• Cd and Tl combined – 0.05 mg/m3

0.0000 0.00004 0.0000 • Sb, As, Pb, Cr, Co, Cu, Mn, Ni, V combined – 0.5 mg/m3• mercury – 0.05 mg/m3

0.0003 0.0009 0.0003 If one of the individual metal elements in the last impinger (e.g. Sb) is more than 10% of the

However, for each group the requirement to pass the absorber efficiency check shall not apply:• to individual metal element(s), where the individual mass of the element in the final result is less than 1%

of the result for the total mass of metals in the group; or• if the total combined result for the metals in the group is less than 30% of the ELV.

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Scientific Analysis Laboratories Ltd

Certificate of Analysis

Hadfield HouseHadfield Street

CornbrookManchester

M16 9FETel : 0161 874 2400Fax : 0161 874 2404

Report Number: 566545-1

Date of Report: 06-May-2016

Customer: Glenside EnvironmentalCuil Greine HouseBallincollig Commercial ParkLink RoadBallincollig.CO. CORK.

Customer Contact: Mr Ewa Piatek

Customer Job Reference: 016-058 KMK StackCustomer Purchase Order: 016-058 KMK StackCustomer Site Reference: KMK Metals

Date Job Received at SAL: 29-Apr-2016Date Analysis Started: 03-May-2016

Date Analysis Completed: 06-May-2016

The results reported relate to samples received in the laboratory and may not be representative of a wholebatch.Opinions and interpretations expressed herein are outside the scope of UKAS accreditationThis report should not be reproduced except in full without the written approval of the laboratoryTests covered by this certificate were conducted in accordance with SAL SOPsAll results have been reviewed in accordance with Section 25 of the SAL Quality Manual

This document has been printed from a digitally signed master copy

Scientific Analysis Laboratories is a

limited company registered in England and

Wales (No 2514788) whose address is at

Hadfield House, Hadfield Street, Manchester M16 9FE

1549

Report checkedand authorised by :Mary HughesCustomer Service Manager

Issued by :Mary HughesCustomer Service Manager

Page 1 of 2

566545-1

Digitally signed by Mary HughesDate: 2016.05.06 16:29:45 BSTReason: IssueLocation: SAL

Signature Not Verified

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Index to symbols used in 566545-1

SAL Reference: 566545

Project Site: KMK Metals

Customer Reference: 016-058 KMK Stack

Wash(Acetone) Analysed as Wash(Acetone)

Miscellaneous

SAL Reference 566545 003 566545 004

Customer Sample Reference 058-03PARTICULATESNOZZLE WASH

058-04PARTICULATESNOZZLE WASH

BLANK

Test Sample AR AR

Date Sampled 27-APR-2016 27-APR-2016

Determinand Method LOD Units Symbol

Particulates (Total) Grav 0.3 mg U <0.3 <0.3

SAL Reference: 566545

Project Site: KMK Metals

Customer Reference: 016-058 KMK Stack

Filter GFA 47mm Analysed as Filter GFA 47mm

Miscellaneous

SAL Reference 566545 001 566545 002

Customer Sample Reference 058-01PARTICULATES

FILTER RUN

058-02PARTICULATESFILTER BLANK

Test Sample AR AR

Date Sampled 27-APR-2016 27-APR-2016

Determinand Method LOD Units Symbol

Particulates (Total) Grav (5 Dec) 0.05 mg U <0.05 <0.05

Value Description

AR As Received

U Analysis is UKAS accredited

This document has been printed from a digitally signed master copy

Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 2 of 2

566545-1

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1181

Analytical Report

Client: Glenside EnvironmentalEwa Piatek Northumbrian Water Scientific ServicesCuil Greine House Northumberland Dock Road

Contract: GLEN_ENV-02604Link Road WallsendBallincollig Tyne & Wear

AIR MONITORINGCork NE28 0QDSouthern Ireland Tel. 0191 2968366 Fax. 0191 2968535

Method H191 H191 H191 H191 H191

Sample Date Time Date Date aluminium antimony arsenic beryllium cadmium

ID Number Description Taken Taken Received Started ug ug ug ug ug

1212249 016-058-01 METALS FILTER FILTER QMA 47MM 27/04/16 12:00 03/05/16 03/05/16 <50 <0.40 <0.30 <0.70 <0.10

1212253 016-058-05 METALS FILTER BLANK FILTER QMA 47MM 27/04/16 12:00 03/05/16 03/05/16 <50 <0.40 <0.30 <0.70 <0.10

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4of1PageIan Barnabas - Scientific Support Laboratory Manager

Authorised by:

This report was compiled by Customer DepartmentIn the event of a query please contact them on the above numberOpinions and interpretations expressed herein are out side the scope of UKAS accreditationResults relate only to the items tested

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1181

Analytical Report




Method H191 H191 H191 H191 H191

Sample Date Time Date Date chromium cobalt copper iron lead


1212249 016-058-01 METALS FILTER FILTER QMA 47MM 27/04/16 12:00 03/05/16 03/05/16 <0.20 <0.20 <0.30 <5.0 <0.10

1212253 016-058-05 METALS FILTER BLANK FILTER QMA 47MM 27/04/16 12:00 03/05/16 03/05/16 <0.20 <0.20 1.1 <5.0 <0.10

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Method H191 H191 H191 H191 H191

Sample Date Time Date Date manganese mercury nickel selenium thallium


1212249 016-058-01 METALS FILTER FILTER QMA 47MM 27/04/16 12:00 03/05/16 03/05/16 <0.20 <0.10 <0.90 <0.40 <0.30

1212253 016-058-05 METALS FILTER BLANK FILTER QMA 47MM 27/04/16 12:00 03/05/16 03/05/16 <0.20 <0.10 <0.90 <0.40 <0.30

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Analytical Report




Method H191 H191

Sample Date Time Date Date vanadium zinc

ID Number Description Taken Taken Received Started ug ug

1212249 016-058-01 METALS FILTER FILTER QMA 47MM 27/04/16 12:00 03/05/16 03/05/16 <0.20 5.5

1212253 016-058-05 METALS FILTER BLANK FILTER QMA 47MM 27/04/16 12:00 03/05/16 03/05/16 <0.20 <0.40

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Analytical Report




Method H108 H163 H191 H191 H191

*

Sample Date Time Date Date mercury volume of sample aluminium antimony arsenic

ID Number Description Taken Taken Received Started mg/l ml ug ug ug

1212252 016-058-04 METALS RINSE RINSE SOLUTION 5% HNO3 27/04/16 12:00 03/05/16 04/05/16 <0.000060 108.00 <50 <0.40 <0.30

1212255 016-058-07 METALS RINSE BLANK RINSE SOLUTION 5% HNO3 27/04/16 12:00 03/05/16 04/05/16 <0.000060 94.000 28 0.86 <0.30

Tests marked "*" in this report areNOT included in the UKASaccreditation schedule for thislaboratory.

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Analytical Report




Method H191 H191 H191 H191 H191

Sample Date Time Date Date beryllium cadmium chromium cobalt copper


1212252 016-058-04 METALS RINSE RINSE SOLUTION 5% HNO3 27/04/16 12:00 03/05/16 04/05/16 <0.70 <0.10 <0.20 <0.20 0.40

1212255 016-058-07 METALS RINSE BLANK RINSE SOLUTION 5% HNO3 27/04/16 12:00 03/05/16 04/05/16 <0.70 <0.10 0.35 <0.20 1.1


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Method H191 H191 H191 H191 H191

Sample Date Time Date Date iron lead manganese nickel selenium


1212252 016-058-04 METALS RINSE RINSE SOLUTION 5% HNO3 27/04/16 12:00 03/05/16 04/05/16 <5.0 0.10 <0.20 <0.90 <0.40

1212255 016-058-07 METALS RINSE BLANK RINSE SOLUTION 5% HNO3 27/04/16 12:00 03/05/16 04/05/16 10 0.52 0.23 <0.90 <0.40


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1181

Analytical Report




Method H191 H191 H191

Sample Date Time Date Date thallium vanadium zinc

ID Number Description Taken Taken Received Started ug ug ug

1212252 016-058-04 METALS RINSE RINSE SOLUTION 5% HNO3 27/04/16 12:00 03/05/16 04/05/16 0.36 <0.20 <0.40

1212255 016-058-07 METALS RINSE BLANK RINSE SOLUTION 5% HNO3 27/04/16 12:00 03/05/16 04/05/16 <0.30 0.12 2.2


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1181

Analytical Report




Method H108 H163 H191 H191

*

Sample Date Time Date Date mercury volume of sample aluminium antimony

ID Number Description Taken Taken Received Started mg/l ml ug/l ug/l

1212250 016-058-02 METALS IMPINGER 1+2 SOLUTION 3.3% HNO3 1.5% H2O2 27/04/16 12:00 03/05/16 04/05/16 0.0073 180.00 16 <0.40

1212251 016-058-03 METALS IMPINGER 3 SOLUTION 3.3% HNO3 1.5% H2O2 27/04/16 12:00 03/05/16 04/05/16 0.0079 96.000 25 <0.40

1212254 016-058-06 METALS IMPINGERS BLANK SOLUTION 3.3% HNO3 1.5% H2O2 27/04/16 12:00 03/05/16 04/05/16 <0.000060 142.00 8.6 <0.40


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EPA Export 29-08-2016:02:52:10

1181

Analytical Report




Method H191 H191 H191 H191

Sample Date Time Date Date arsenic beryllium cadmium chromium

ID Number Description Taken Taken Received Started ug/l ug/l ug/l ug/l

1212250 016-058-02 METALS IMPINGER 1+2 SOLUTION 3.3% HNO3 1.5% H2O2 27/04/16 12:00 03/05/16 04/05/16 <0.20 <0.30 <0.20 <0.60

1212251 016-058-03 METALS IMPINGER 3 SOLUTION 3.3% HNO3 1.5% H2O2 27/04/16 12:00 03/05/16 04/05/16 <0.20 <0.30 <0.20 7.2

1212254 016-058-06 METALS IMPINGERS BLANK SOLUTION 3.3% HNO3 1.5% H2O2 27/04/16 12:00 03/05/16 04/05/16 <0.20 <0.30 <0.20 <0.60


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1181

Analytical Report




Method H191 H191 H191 H191

Sample Date Time Date Date cobalt copper iron lead


1212250 016-058-02 METALS IMPINGER 1+2 SOLUTION 3.3% HNO3 1.5% H2O2 27/04/16 12:00 03/05/16 04/05/16 <0.20 0.62 23 0.98

1212251 016-058-03 METALS IMPINGER 3 SOLUTION 3.3% HNO3 1.5% H2O2 27/04/16 12:00 03/05/16 04/05/16 <0.20 5.5 100 1.2

1212254 016-058-06 METALS IMPINGERS BLANK SOLUTION 3.3% HNO3 1.5% H2O2 27/04/16 12:00 03/05/16 04/05/16 <0.20 3.9 <10 <0.30


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1181

Analytical Report




Method H191 H191 H191 H191

Sample Date Time Date Date manganese nickel selenium thallium


1212250 016-058-02 METALS IMPINGER 1+2 SOLUTION 3.3% HNO3 1.5% H2O2 27/04/16 12:00 03/05/16 04/05/16 0.64 0.95 <0.30 <0.30

1212251 016-058-03 METALS IMPINGER 3 SOLUTION 3.3% HNO3 1.5% H2O2 27/04/16 12:00 03/05/16 04/05/16 6.2 6.8 <0.30 <0.30

1212254 016-058-06 METALS IMPINGERS BLANK SOLUTION 3.3% HNO3 1.5% H2O2 27/04/16 12:00 03/05/16 04/05/16 <0.30 <0.40 <0.30 <0.30


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1181

Analytical Report




Method H191 H191

Sample Date Time Date Date vanadium zinc

ID Number Description Taken Taken Received Started ug/l ug/l

1212250 016-058-02 METALS IMPINGER 1+2 SOLUTION 3.3% HNO3 1.5% H2O2 27/04/16 12:00 03/05/16 04/05/16 <0.30 60

1212251 016-058-03 METALS IMPINGER 3 SOLUTION 3.3% HNO3 1.5% H2O2 27/04/16 12:00 03/05/16 04/05/16 <0.30 100

1212254 016-058-06 METALS IMPINGERS BLANK SOLUTION 3.3% HNO3 1.5% H2O2 27/04/16 12:00 03/05/16 04/05/16 <0.30 <2.0


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1181

Analytical Report




Method H108 H163

*

Sample Date Time Date Date mercury volume of sample

ID Number Description Taken Taken Received Started mg/l ml

1212256 016-058-08 MERCURY IMPINGER 1 2%KMNO4/10%H2SO4 27/04/16 12:00 03/05/16 04/05/16 0.22 84.000

1212257 016-058-09 MERCURY IMPINGER 2 2%KMNO4/10%H2SO4 27/04/16 12:00 03/05/16 04/05/16 0.059 98.000

1212258 016-058-10 MERCURY IMPINGER BLANK 2%KMNO4/10%H2SO4 27/04/16 12:00 03/05/16 04/05/16 <0.000060 170.00


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Documents

For inspection purposes only. · PDF fileCompany Name: KMK Metals Recycling Ltd Licence No: W0113-04 Year: 2016, Visit No: 2 Report No: 016-058 Page 2 of 14