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ENVIRONMENTAL IMPACT ASSESSMENT
FOR
EXISTING – BULK DRUGS, PROPOSED EXPANSION –
ETHOXYLATES, METFORMIN & OTHER ORGANIC PRODUCTS
SYNTHETIC ORGANIC CHEMICALS INDUSTRY UNDER SCHEDULE - 5(f)
Gujarat Dyestuff Industries
(Pharma Unit)
PLOT NO. 133/4, 133/5, 133/6, GIDC NANDESARI, NANDESARI, AND DIST: VADODARA-391340
E C S
CONSULTANTS
ECO-CARE SOLUTIONS 306-307 DWARKESH COMPLEX, SUN PHARMA-ATLADARA ROAD.
VADODARA-390020, GUJARAT, INDIA
Gujarat Dyestuff Industries (Pharma Unit) Table of Contents
Rapid Environmental Impact Assessment Report 1
EXECUTIVE SUMMARY ....................................................................................................................................................11
INTRODUCTION: ...................................................................................................................................................................11
PURPOSE OF STUDY & REGULATORY FRAMEWORK ......................................................................................................11
PRODUCT DETAILS ..............................................................................................................................................................11
PROJECT COST ......................................................................................................................................................................13
SITE LOCATION ....................................................................................................................................................................13
POWER REQUIREMENT: .....................................................................................................................................................14
FUEL & EMISSIONS: ............................................................................................................................................................14
PROCESS EMISSIONS: ..........................................................................................................................................................14
WATER & WASTE WATER ENVIRONMENT ....................................................................................................................14
HAZARDOUS WASTE ...........................................................................................................................................................15
ENVIRONMENTAL MANAGEMENT ....................................................................................................................................16
JUSTIFICATION OF SELECTING THE PROPOSED PRODUCT & UNIT SIZE. ......................................................................16
TOR COMPLIANCES ...........................................................................................................................................................17
STANDARD - TOR COMPLIANCES ...............................................................................................................................18
CHAPTER – 1: INTRODUCTION ....................................................................................................................................29
1.1 PURPOSE OF STUDY & REGULATORY FRAMEWORK ...............................................................................................29
1.2 IDENTIFICATION OF THE PROJECT AND PROJECT PROPONENT ............................................................................29
1.3 PROJECT BRIEF: ............................................................................................................................................................30
1.4 NATURE AND SIZE OF THE PROJECT .........................................................................................................................32
1.5 PROJECT COST ..............................................................................................................................................................33
1.6 SITE LOCATION .............................................................................................................................................................33
1.7 INDIAN POLICIES REQUIRING REIA ..........................................................................................................................38
1.8 THE REIA CYCLE & PROCEDURES ............................................................................................................................38
1.9 SCOPE OF THE EIA STUDY ..........................................................................................................................................38
1.10 APPLICABLE ENVIRONMENTAL REGULATIONS & STANDARDS .........................................................................39
1.11 STRUCTURE OF EIA REPORT ...................................................................................................................................39
CHAPTER – 2: PROJECT DESCRIPTION .....................................................................................................................40
2.1 TYPE OF PROJECT & CAPACITY ..................................................................................................................................40
2.2 NEED FOR REIA ...........................................................................................................................................................40
2.3 COST OF THE PROJECT .................................................................................................................................................41
2.4 PROJECT LOCATION & SURROUNDING AREA...........................................................................................................41
2.5 APPROACH TO SITE ......................................................................................................................................................41
2.6 PLANT LAYOUT .............................................................................................................................................................45
2.7 MAGNITUDE OF THE PROJECT ....................................................................................................................................46
2.7.1 Details of Products ....................................................................................................................................................... 46
2.8 RAW MATERIAL STORAGE & HANDLING .................................................................................................................48
2.9 SOLVENT RECOVERY ....................................................................................................................................................66
2.10 METHODOLOGY FOR ZLD ........................................................................................................................................67
2.10.1 Details of UF-RO Plant ............................................................................................................................................. 67
2.10.2 Details of MEE Plant ................................................................................................................................................. 69
2.11 TECHNOLOGY / PROCESS DESCRIPTION ................................................................................................................70
2.11.1 Mass Balance................................................................................................................................................................ 70
2.12 PLANT INFRASTRUCTURE AND BASIC REQUIREMENTS ................................................................................... 122
Gujarat Dyestuff Industries (Pharma Unit) Table of Contents
Rapid Environmental Impact Assessment Report 2
2.12.1 Land................................................................................................................................................................................ 122
2.12.2 Plant Equipment/Machineries .......................................................................................................................... 122
2.12.3 Details of Utilities ..................................................................................................................................................... 125
2.12.4 Power Requirement ................................................................................................................................................ 126
2.12.5 Fuel ................................................................................................................................................................................. 126
2.12.6 Water ............................................................................................................................................................................. 126
2.12.7 Manpower ................................................................................................................................................................... 127
2.13 SOURCE OF POLLUTION & ITS MANAGEMENT ................................................................................................... 127
2.13.1 Waste Water Generation& its management ............................................................................................... 127
2.13.1.1 Details of wastewater generation with qualitative and quantitative analysis .. 131
2.13.1.2 Treatment Methodology .......................................................................................................... 131
2.13.1.3 Effluent treatment scheme ..................................................................................................... 133
2.13.2 Air Pollution and Control System ..................................................................................................................... 136
2.13.2.1 Details of Scrubber ..................................................................................................................... 137
2.13.3 Hazardous Waste Generations and Disposal System .............................................................................. 138
2.13.4 Noise Level and Control System ........................................................................................................................ 139
2.13.5 Soil................................................................................................................................................................................... 139
2.14 STATUS OF APPLICABLE RULES, ACTS, REGULATION: ..................................................................................... 140
2.15 PROPOSED SCHEDULE FOR APPROVAL AND IMPLEMENTATION .................................................................... 140
CHAPTER – 3: BASELINE ENVIRONMENTAL STATUS .................................................................................... 141
3.1 INTRODUCTION .......................................................................................................................................................... 141
3.2 METHODOLOGY ......................................................................................................................................................... 141
3.2.1 Study Period & Frequency of Sampling ............................................................................................................ 141
3.2.2 Method of Environmental Sampling & Analysis ........................................................................................... 142
3.2.3 Baseline Environmental Status ............................................................................................................................ 143
3.3 MICROMETEOROLOGY .............................................................................................................................................. 143
3.3.1 Temperature Details ................................................................................................................................................. 143
3.3.2 Relative Humidity (RH) ............................................................................................................................................ 143
3.3.3 Rainfall ............................................................................................................................................................................ 144
3.3.4 Wind Speed .................................................................................................................................................................... 144
3.3.5 Temperature, Relative Humidity & Wind Speed .......................................................................................... 145
3.3.6 Wind Rose ....................................................................................................................................................................... 145
3.4 AIR ENVIRONMENT ................................................................................................................................................... 147
3.4.1 Summary ......................................................................................................................................................................... 151
3.5 NOISE ENVIRONMENT .............................................................................................................................................. 151
3.6 WATER ENVIRONMENT............................................................................................................................................ 152
3.6.1 Methodology for Water Quality Monitoring .................................................................................................. 152
3.6.2 Baseline Ground water quality ............................................................................................................................. 156
3.6.3 Baseline Surface Water Quality ........................................................................................................................... 156
3.7 LAND ENVIRONMENT ............................................................................................................................................... 156
3.7.1 Soil Quality ..................................................................................................................................................................... 156
3.7.2 Summary of Soil Quality .......................................................................................................................................... 158
3.8 GEOLOGICAL & HYDROLOGICAL DATA ................................................................................................................ 158
3.8.1 Method of Preparation ............................................................................................................................................. 158
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Rapid Environmental Impact Assessment Report 3
3.8.2 Description of Geological Classification & Area Under Different Formations ............................... 158
3.8.3 Geological Map ............................................................................................................................................................ 158
3.9 LAND USE PATTERN ................................................................................................................................................. 159
3.9.1 Method of Data Preparation ................................................................................................................................. 159
3.10 TOPOSHEET ............................................................................................................................................................. 162
3.11 ECOLOGICAL INFORMATION ................................................................................................................................. 162
3.11.1 Flora ............................................................................................................................................................................... 164
3.11.2 Fauna ............................................................................................................................................................................. 165
3.12 SOCIO - ECONOMIC ENVIRONMENT ..................................................................................................................... 165
3.12.1 Demography ............................................................................................................................................................... 165
3.12.2 Literacy Rate .............................................................................................................................................................. 169
3.12.3 Occupational Structure ......................................................................................................................................... 170
3.12.4 Amenities ..................................................................................................................................................................... 171
CHAPTER – 4: ANTICIPATED ENVIRONMENTAL IMPACTS & MITIGATION MEASURES ................. 174
4.1 GENERAL..................................................................................................................................................................... 174
4.2 DETAILS OF ANTICIPATED ENVIRONMENTAL IMPACTS DUE TO PROJECT LOCATION, PROJECT DESIGN, PROJECT
CONSTRUCTION, REGULAR OPERATIONS OF A PROJECT. (IMPACT ASSESSMENT MATRIX) ...................... 175
4.3 ASSESSMENT OF SIGNIFICANCE OF IMPACTS (CRITERIA FOR DETERMINING SIGNIFICANCE, ASSIGNING
SIGNIFICANCE) & MITIGATION MEASURES ...................................................................................................... 175
4.4 OVERALL IMPACTS .................................................................................................................................................... 181
4.4.1 Impact on Air Environment ................................................................................................................................... 182
4.4.1.1 Fugitive emission .......................................................................................................................... 182
4.4.2 Ambient Air Quality Modelling ............................................................................................................................. 183
4.4.2.1 Details of Air Dispersion Model ............................................................................................... 183
4.4.2.2 Presentation of Result: ................................................................................................................ 184
4.4.3 Impact on Water Environment ............................................................................................................................ 195
4.4.4 Impact on Land/Soil Environment ..................................................................................................................... 195
4.4.5 Impact on Noise Levels ............................................................................................................................................. 196
4.4.6 Impact on Socio-Economy ...................................................................................................................................... 196
4.5 IRREVERSIBLE & IRRETRIEVABLE COMMITMENTS OF ENVIRONMENTAL COMPONENTS ............................. 197
4.6 INCREMENTAL CONCENTRATION ........................................................................................................................... 197
CHAPTER – 5: ANALYISIS OF ALTERNATIVES.................................................................................................... 199
5.1 ANALYSIS OF ALTERNATIVES .................................................................................................................................. 199
5.2 BEST AVAILABLE TECHNOLOGIES .......................................................................................................................... 200
CHAPTER –6: ENVIRONMENTAL MONITORING PROGRAM ......................................................................... 201
6.1 INTRODUCTION .......................................................................................................................................................... 201
6.2 IMPLEMENTATION ARRANGEMENT ....................................................................................................................... 201
6.3 ENVIRONMENTAL ASPECTS TO BE MONITORED .................................................................................................. 201
6.3.1 During Construction Stage ..................................................................................................................................... 202
6.3.2 During Operation Phase .......................................................................................................................................... 202
6.3.2.1 Ambient Air Monitoring Within Plant Area........................................................................ 202
6.3.2.2 Effluent Monitoring ...................................................................................................................... 202
6.3.2.3 Work Zone Noise Levels ............................................................................................................. 202
6.3.2.4 Ambient Noise ................................................................................................................................ 203
6.3.2.5 Solid / Hazardous Waste Disposal ......................................................................................... 203
Gujarat Dyestuff Industries (Pharma Unit) Table of Contents
Rapid Environmental Impact Assessment Report 4
6.3.2.6 Green Belt Development ............................................................................................................ 203
6.3.2.7 House Keeping ................................................................................................................................ 203
6.4 ENVIRONMENTAL MONITORING PLAN .................................................................................................................. 204
6.5 DOCUMENTS & RECORDS ......................................................................................................................................... 204
6.6 BUDGETARY PROVISIONS FOR ENVIRONMENTAL PROTECTION MEASURES ................................................... 205
6.7 UPDATING OF EMP ................................................................................................................................................... 205
CHAPTER – 7: RISK ASSESSMENT ............................................................................................................................ 206
7.1 RISK ASSESSMENT..................................................................................................................................................... 206
7.1.1 Introduction .................................................................................................................................................................. 206
7.1.2 Objective ......................................................................................................................................................................... 206
7.1.3 Approach to the Study .............................................................................................................................................. 206
7.2 QUANTITY OF HAZARDOUS CHEMICALS ................................................................................................................ 206
7.3 LIST OF HAZARDOUS CHEMICALS ALONG WITH THEIR TOXICITY LEVEL AS PER MSIHC RULES ................ 208
7.4 MSDS OF ALL THE PRODUCTS & RAW MATERIALS ............................................................................................ 212
7.5 HAZARD IDENTIFICATION & PREVENTIVE MEASURES ....................................................................................... 212
7.5.1 Process hazards and controls ............................................................................................................................... 212
7.5.2 General Hazards & Controls .................................................................................................................................. 213
7.6 FIRE & SAFETY .......................................................................................................................................................... 213
7.6.1 Safety Measures to be provided ........................................................................................................................... 214
7.6.2 Provisions for Human Health Hazards & Work Place ............................................................................... 215
7.7 LEAK DETECTION & REPAIR (LDAR) ................................................................................................................... 215
7.7.1 Following Methodology of LDAR Program will be followed: ................................................................. 215
7.7.2 Following shall be done to Prevent Leaks: ...................................................................................................... 216
7.7.3 Following shall be done in case of Spills: ......................................................................................................... 216
7.8 INFORMATION ON SOLVENT STORAGE AREA AND ASSOCIATED REACTORS .................................................... 217
7.9 ON SITE EMERGENCY PLAN .................................................................................................................................... 217
7.9.1 Purpose: .......................................................................................................................................................................... 217
7.9.2 PESO Permission: ........................................................................................................................................................ 217
7.10 WORST CASE SCENARIO ...................................................................................................................................... 217
7.10.1 Scope: ............................................................................................................................................................................. 217
7.11 CHECKLIST - DO’S & DON’TS FOR HANDLING OF CHEMICALS, WORKING IN CHEMICAL LABORATORY, WORKING ON MACHINES, MAINTAINING GOOD HOUSEKEEPING, WORKING ON HEIGHT, WORK IN
CONFINED SPACE, FIRE PREVENTION, IN CASE OF FIRE ............................................................................... 217
7.12 SOCIAL IMPACT ASSESSMENT R&R ACTION PLANS ......................................................................................... 223
7.13 MITIGATION MEASURES FOR SEEPAGE & SOIL CONTAMINATION ................................................................. 223
7.14 CHEMICAL SPILLAGE CONTROL MEASURES ....................................................................................................... 223
CHAPTER – 8: PROJECT BENEFITS .......................................................................................................................... 224
8.1 INTRODUCTION .......................................................................................................................................................... 224
8.2 ECONOMICAL BENEFITS ........................................................................................................................................... 224
8.3 SOCIO ECONOMIC DEVELOPMENT OF THE REGION ............................................................................................. 224
8.4 UN-SKILLED MANPOWER ........................................................................................................................................ 224
8.5 SOCIO ECONOMIC DEVELOPMENT ASPECTS ......................................................................................................... 225
CHAPTER – 9 ENVIRONMENTAL COST BENEFIT ANALYSIS ........................................................................ 226
CHAPTER – 10 ENVIRONMENTAL MANAGEMENT PLAN .............................................................................. 228
10.1 BACKGROUND .......................................................................................................................................................... 228
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Rapid Environmental Impact Assessment Report 5
10.2 OBJECTIVES OF ENVIRONMENTAL MANAGEMENT PLAN ................................................................................. 228
10.3 COMPONENTS OF EMP .......................................................................................................................................... 228
10.4 ORGANOGRAM OF ENVIRONMENTAL MANAGEMENT CELL ............................................................................. 229
10.4.1 Reporting system on non compliances/violations of Environmental Laws.................................. 230
10.5 ENVIRONMENT MANAGEMENT DURING CONSTRUCTION PHASE .................................................................. 230
10.6 ENVIRONMENT MANAGEMENT DURING OPERATION PHASE. ......................................................................... 231
10.6.1 Air Environment ....................................................................................................................................................... 231
10.6.1.1 Fugitive emission ........................................................................................................................ 232
10.6.1.2 VOC Monitoring Plan ................................................................................................................. 233
10.6.2 Water Environment ................................................................................................................................................ 233
10.6.2.1 Economical and Technical Viability of the Effluent Treatment System ............... 233
10.6.3 Hazardous Waste Management ........................................................................................................................ 234
10.6.3.1 Storage of Hazardous Waste: ................................................................................................. 234
10.6.3.2 Transportation of Hazardous Waste: ................................................................................. 234
10.6.3.3 Disposal of Hazardous Waste: ............................................................................................... 234
10.6.3.4 Methodology of Decontamination of drums/containers ........................................... 235
10.6.4 Noise Environment .................................................................................................................................................. 235
10.6.5 Odour Control Plan ................................................................................................................................................. 236
10.7 OCCUPATIONAL HEALTH & SAFETY .................................................................................................................... 237
10.8 GREEN BELT DEVELOPMENT ............................................................................................................................... 238
10.8.1 Plants / Trees Should be Selected for Green Belt Area ........................................................................... 238
10.9 RAIN WATER HARVESTING .................................................................................................................................. 239
10.10 CLEANER PRODUCTION....................................................................................................................................... 240
10.11 FLORA & FAUNA .................................................................................................................................................. 240
10.12 CAPITAL COST FOR ENVIRONMENTAL MANAGEMENT .................................................................................. 240
10.13 PREVENTION OF STORM WATER CONTAMINATION. ..................................................................................... 241
CHAPTER – 11 SUMMARY & CONCLUSION .......................................................................................................... 242
11.1 INTRODUCTION ....................................................................................................................................................... 242
11.2 LOCATION OF THE PROJECT .................................................................................................................................. 242
11.3 PRODUCT & CAPACITY........................................................................................................................................... 242
11.4 COST OF THE PROJECT ........................................................................................................................................... 244
11.5 BASELINE ENVIRONMENTAL ANALYSIS .............................................................................................................. 244
11.5.1 Ambient Air Quality ................................................................................................................................................ 244
11.5.2 Water Quality ............................................................................................................................................................ 245
11.5.3 Noise level .................................................................................................................................................................... 245
11.5.4 Soil Quality .................................................................................................................................................................. 246
11.6 ANTICIPATED ENVIRONMENTAL IMPACTS & MITIGATION MEASURES ........................................................ 246
11.6.1 Water Requirement, Waste Water Generation and Treatment: ....................................................... 246
11.6.2 Air Pollution source and Mitigation measure ............................................................................................ 246
11.6.3 Hazardous Waste Generations and Disposal .............................................................................................. 247
11.6.4 Noise Level and Mitigation Measure ............................................................................................................... 247
11.6.5 Soil & Geology ............................................................................................................................................................ 247
11.6.6 Impacts on Socio Economy & Mitigation measures: ................................................................................ 247
11.7 GREEN BELT: ........................................................................................................................................................... 248
Gujarat Dyestuff Industries (Pharma Unit) Table of Contents
Rapid Environmental Impact Assessment Report 6
11.8 ENVIRONMENTAL MONITORING PROGRAMME ................................................................................................. 248
11.9 ENVIRONMENTAL MANAGEMENT PLAN ............................................................................................................. 248
11.10 ADDITIONAL STUDIES ......................................................................................................................................... 248
11.11 PROJECT BENEFITS .............................................................................................................................................. 249
11.12 CONCLUSION ......................................................................................................................................................... 249
CHAPTER 12: DISCLOSURE OF CONSULTANTS ENGAGED ........................................................................... 250
12.1 DISCLOSURE OF CONSULTANT .............................................................................................................................. 250
Gujarat Dyestuff Industries (Pharma Unit) List of Tables
Rapid Environmental Impact Assessment Report 7
LIST OF TABLES
TABLE 1.1 PRODUCT DETAILS .....................................................................................................................................32
TABLE 2.1 BREAK-UP OF PROJECT COST ................................................................................................................41
TABLE 2.2 AREA CALCULATION FOR EXISTING & PROPOSED STRUCTURES .........................................46
TABLE 2.3 PRODUCT PROFILE .....................................................................................................................................46
TABLE 2.4 MEANS OF TRANSPORTATION OF RAW MATERIALS AND PRODUCTS ...............................48
TABLE 2.5 PHYSICAL & CHEMICAL PROPERTIES OF THE RAW MATERIAL & PRODUCTS ...............50
TABLE 2.6 STORAGE DETAILS ......................................................................................................................................65
TABLE 2.7 DETAILS OF PLANT MACHINERIES .................................................................................................. 122
TABLE 2.8 DETAILS OF UTILITIES ........................................................................................................................... 125
TABLE 2.9 FUEL STORAGE DETAILS ....................................................................................................................... 126
TABLE 2.10 FUEL SOURCE & TRANSPORTATION DETAILS ......................................................................... 126
TABLE 2.11 DETAILS OF WATER CONSUMPTION &W/W GENERATION ............................................... 128
TABLE 2.12 CHARACTERISTICS OF WASTEWATER ........................................................................................ 131
TABLE 2.13 ANALYSIS RESULTS AFTER CHEMICAL TREATMENT (LIME + ALUM): ......................... 131
TABLE 2.14 ANALYSIS RESULTS AFTER SECONDARY / BIOLOGICAL TREATMENT ......................... 131
TABLE 2.15 ANALYSIS AFTER TERTIARY TREATMENT ................................................................................ 131
TABLE 2.16 FINAL REDUCTIONS AFTER TREATMENT .................................................................................. 132
TABLE 2.17 FINAL REDUCTIONS AFTER TREATMENT .................................................................................. 132
TABLE 2.18 DETAILS OF ETP (NAME OF UNIT & CAPACITY) ...................................................................... 133
TABLE 2.19 DETAILS OF STACKS ............................................................................................................................. 136
TABLE 2.20 DETAILS OF HAZARDOUS WASTE AND ITS MODE OF DISPOSAL ..................................... 138
TABLE 3.1 FREQUENCY OF ENVIRONMENTAL MONITORING .................................................................... 142
TABLE 3.2 METHOD OF ENVIRONMENTAL SAMPLING & ANALYSIS ....................................................... 142
TABLE 3.3 TEMPERATURE DATA ............................................................................................................................ 143
TABLE 3.4 RELATIVE HUMIDITY DATA ................................................................................................................ 143
TABLE 3.5 RAINFALL DATA ........................................................................................................................................ 144
TABLE 3.6 WIND SPEED DATA .................................................................................................................................. 144
TABLE 3.7 SITE SPECIFIC METEOROLOGICAL DATA (PERIOD: OCTOBER 2018 TO DECEMBER, 2018) ............................................................................................................................................................ 145
TABLE 3.8 LOCATIONS OF THE AMBIENT AIR, NOISE, WATER AND SOIL ............................................ 149
TABLE 3.9 AMBIENT AIR QUALITY STATUS (OCTOBER, 2018 TO DECEMBER, 2018) .................... 149
TABLE 3.10 BACKGROUND NOISE LEVELS .......................................................................................................... 152
TABLE 3.11 GROUND & SURFACE WATER QUALITY ....................................................................................... 153
TABLE 3.12 PHYSICO-CHEMICALS CHARACTERISTICS OF SOIL ................................................................ 157
TABLE 3.13 LIST OF FLORA ........................................................................................................................................ 164
TABLE 3.14 LIST OF FAUNA ....................................................................................................................................... 165
TABLE 3.15 DEMOGRAPHIC DATA .......................................................................................................................... 166
TABLE 3.16 POPULATION DENSITY........................................................................................................................ 168
TABLE 3.17 LITERACY RATE ...................................................................................................................................... 169
TABLE 3.18 OCCUPATIONAL STRUCTURE ........................................................................................................... 170
TABLE 3.19 DETAILS OF AMMENITIES AVAILABLE IN STUDY AREA ...................................................... 172
TABLE 4.1 IMPACT IDENTIFICATION MATRIXES ............................................................................................. 175
TABLE 4.2ENVIRONMENTAL IMPACT ASSESSMENTS ................................................................................... 176
Gujarat Dyestuff Industries (Pharma Unit) List of Tables
Rapid Environmental Impact Assessment Report 8
TABLE 4.3 FLUE GAS STACK EMISSION RATES.................................................................................................. 184
TABLE 4.4. THE 1ST HIGHEST 24-HR AVERAGE CONCENTRATION OF PM, (µG/M3) ......................... 186
TABLE 4.5. THE 1ST HIGHEST 24-HR AVERAGE CONCENTRATION OF SO2, (µG/M3) .................... 189
TABLE 4.6. THE 1ST HIGHEST 24-HR AVERAGE CONCENTRATION OF NO2, (µG/M3) ................... 192
TABLE 4.7 MAXIMUM GLCS FROM THE DISPERSION MODEL ..................................................................... 195
TABLE 6.1: ENVIRONMENTAL MONITORING PROGRAMME (DURING CONSTRUCTION STAGE) 202
TABLE 6.2 PROJECT ENVIRONMENT MONITORING PLAN ........................................................................... 204
TABLE 6.3 COST OF ENVIRONMENTAL PROTECTION MEASURES ........................................................... 205
TABLE 7.1 STORAGE DETAILS OF RAW MATERIALS ...................................................................................... 207
TABLE 7.2 DETAILS OF HAZARDOUS CHARACTERISTICS OF PRODUCT – PROPOSED PRODUCTS ........................................................................................................................................................................ 208
TABLE 7.3 DETAILS OF HAZARDOUS CHARACTERISTICS OF RAW MATERIALS – PROPOSED PRODUCTS ................................................................................................................................................. 209
TABLE 7.4 TOXICITY INDEX AS PER MSIHC RULE 2000 ................................................................................ 211
TABLE 7.5 PROCESS HAZARDS AND CONTROLS ............................................................................................... 212
TABLE 7.6 GENERAL HAZARDS & CONTROLS .................................................................................................... 213
TABLE 7.7 PROPOSED FIRE EXTINGUISHERS AS PER IS 15683: ................................................................ 214
TABLE 8.1 BUDGETARY PROVISIONS FOR SOCIAL UPLIFTMENT/YEAR ............................................... 225
TABLE 9.1 BUDGET ALLOCATION FOR ENVIRONMENT MANAGEMENT ............................................... 226
TABLE 9.2 ECONOMICAL AND TECHNICAL VIABILITY OF THE EFFLUENT TREATMENT SYSTEM ........................................................................................................................................................................ 227
TABLE 10.1 ENVIRONMENT MANAGEMENT CELL .......................................................................................... 230
230
TABLE: 10.2 CONTROL MEASURES FOR CONSTRUCTION PHASE ............................................................. 230
TABLE 10.3 DETAILS OF AIR EMISSION ................................................................................................................ 232
TABLE 10.4 DETAILS OF HAZARDOUS WASTE AND ITS MODE OF DISPOSAL ..................................... 234
TABLE 10.5 SPECIES PROPOSED TO BE GROWN FOR GREENBELT DEVELOPMENT ....................... 239
TABLE 10.6 BUDGET FOR GREENBELT DEVELOPMENT ............................................................................... 239
TABLE 10.7 BUDGET ALLOCATION FOR ENVIRONMENT MANAGEMENT ............................................ 240
Gujarat Dyestuff Industries (Pharma Unit) List of Maps / Figures
Rapid Environmental Impact Assessment Report 9
LIST OF MAPS & FIGURES
MAP 1.1 PROJECT LOCATION ON INDIA/GUJARAT MAP ..................................................................................35
MAP 1.2 PROJECT LOCATION ON NANDESARI GIDC MAP ...............................................................................36
MAP 1.3 PROJECT LOCATION ON GOOGLE IMAGE ..............................................................................................37
MAP 2.1 PROJECT SITE INDICATING THE BOUNDARY OF THE SITE ..........................................................42
MAP 2.2 STUDY AREA .......................................................................................................................................................43
MAP 2.3 TOPOSHEET MAP OF THE STUDY AREA ................................................................................................44
FIGURE 2.1 LAYOUT PLAN .............................................................................................................................................45
FIGURE 2.2 UF & RO PLANT ...........................................................................................................................................68
FIGURE 2.3 WATER BALANCE DIAGRAM ............................................................................................................. 129
FIGURE 2.4 FLOW DIAGRAM OF ETP - EXISTING .............................................................................................. 135
FIGURE 2.5 APCM ............................................................................................................................................................ 137
FIGURE 3.1A WIND ROSE DIAGRAM ....................................................................................................................... 146
FIGURE 3.1B STABILITY CLASS DISTRIBUTION ................................................................................................ 146
FIGURE 3.2 LOCATIONS OF THE AMBIENT AIR, NOISE, WATER AND SOIL .......................................... 148
FIGURE 3.3 MAJOR GEOLOGICAL FEATURES ...................................................................................................... 159
FIGURE 3.4 LAND USE / LAND COVER ................................................................................................................... 161
FIGURE 3.5 TOPOSHEET .............................................................................................................................................. 162
FIGURE 3.6 POPULATION DENSITY ........................................................................................................................ 168
FIGURE 3.7 LITERACY DATA ...................................................................................................................................... 169
FIGURE 4.1 WIND ROSE DIAGRAM .......................................................................................................................... 185
FIGURE 4.2 (A) ISOPLETHS MAP FOR PM ............................................................................................................. 187
FIGURE 4.2 (B)ISOPLETHS IN GOOGLE MAP FOR PM ..................................................................................... 188
FIGURE 4.3(A) ISOPLETHS MAP FOR SO2 ............................................................................................................. 190
FIGURE 4.3(B) ISOPLETHS IN GOOGLE MAP FOR SO2 ..................................................................................... 191
FIGURE 4.4(A) ISOPLETHS MAP FOR NO2 ............................................................................................................ 193
FIGURE 4.4(B) ISOPLETHS IN GOOGLE MAP FOR NO2 ................................................................................... 194
Gujarat Dyestuff Industries (Pharma Unit) List of Annexures
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List of Annexure
ANNEXURE 1 – TOR LETTER ...................................................................................................................................... 251
ANNEXURE 2 – PLOT ALLOTMENT LETTER FROM GIDC .............................................................................. 252
ANNEXURE 3 – RISK ASSESSMENT REPORT ....................................................................................................... 253
ANNEXURE 4 – EMERGENCY MANAGEMENT PLAN ........................................................................................ 254
ANNEXURE 5 – UNDERTAKING ................................................................................................................................. 255
ANNEXURE 6 – SAFETY AUDIT ................................................................................................................................. 256
ANNEXURE 7 – MSDS RAW MATERIALS ............................................................................................................... 257
ANNEXURE 8 – MSDS FINISHED PRODUCTS ....................................................................................................... 258
ANNEXURE 9 – LAYOUT PLAN FACTORY PREMISES ....................................................................................... 259
ANNEXURE 10 – DETAILS OF CETP NANDESARI .............................................................................................. 260
ANNEXURE 11 – WATER SUPPLY LETTER FROM GIDC ................................................................................. 261
ANNEXURE 12 – MEMBERSHIP FOR HAZARDOUS WASTE .......................................................................... 262
ANNEXURE 13 – HON. HIGH COURT STAY ORDER ........................................................................................... 263
ANNEXURE 14 – MOEF CERTIFED COMPLIANCE REPORT ........................................................................... 264
ANNEXURE 15 – SOP INDEX ....................................................................................................................................... 265
ANNEXURE 16 – CETP NANDESARI PERMISSION FOR DISPOSAL OF TREATED EFFLUENT ......... 266
ANNEXURE 17 – PROJECT IMPLEMENTATION SCHEDULE .......................................................................... 267
ANNEXURE 18 – XGN GENERATED REPORTS .................................................................................................... 268
ANNEXURE 19 – ADEQUACY OF EXISTING EMS ................................................................................................ 269
ANNEXURE 20 – COPY OF EXISTING EC ................................................................................................................ 270
ANNEXURE 21 –BASELINE DATA CERTIFICATE ............................................................................................... 271
ANNEXURE 22 –EXISTING PESO LICENSE ............................................................................................................ 272
ANNEXURE 23 –PLI COPY ............................................................................................................................................ 273
ANNEXURE 24 –COPY OF CTE & CTO ..................................................................................................................... 274
ANNEXURE 25 – TRAFFIC SURVEY .......................................................................................................................... 275
Gujarat Dyestuff Industries (Pharma Unit) Executive Summary
Rapid Environmental Impact Assessment Report 11
EXECUTIVE SUMMARY
Introduction:
M/s. Gujarat Dyestuff Industries (Pharma Unit). located at Plot No. 133/4, 133/5, 133/6, GIDC
Nandesari, Dist: Vadodara-391340., Gujarat.
This is an existing unit into manufacturing of Bulk Drugs such as Cifixime Trihydrate, Cefuroxime
Axetil, Cefpodoxime Proxetil, Ampicilin, Amoxicillin Trydrydate, Clobetasole Propionate,
Betamethasone Dipropionate, Betamethasone Valerate, Betamethasone Sodium Phosphate,
Dexamethasone Sodium Phosphate, Beclomethasone Dipropionate, Mometasone Furoate,
Methylcobalamine, Ofloxacin, Levofloxacin, Quinon Sulphate, Cloxacillin Sodium, Oxacillin Sodium,
Di Cloxacillin Sodium, Flucoxacillin Sodium.
New products Ethoxylates, Metformin Hydrochloride, and additional Methylcobalamine that falls in
Schedule 5(f) are planned to be manufactured and hence the application for EC is being done.
Purpose of Study & Regulatory Framework
Environmental Impact Assessment Report has been prepared for obtaining Environmental Clearance
for M/s. Gujarat Dyestuff Industries (Pharma Unit). Located at Plot No. 133/4, 133/5, 133/6, GIDC
Nandesari, Dist: Vadodara-391340., State: Gujarat, India for Manufacturing of Synthetic Organic
Chemicals Category 5(f) and is included category of the Environmental Impact Assessment
Notification, issued in September-2006 and subsequent amendments. The industry is located within
the notified industrial area/estate GIDC Nandesari and therefore as per NGT Order dated 23.08.2019
in the matter of O.A.No.1038/2018-Reg GIDC Nandesari & PCCI Estate, Di. Vadodara it will fall in
category “A” of the Environmental Impact Notification requiring Environmental Clearance from
MoEF, New Delhi.
This is a “Existing Unit manufacturing Bulk Drugs”.
Product Details
The proposed products will be.
Product details
The New Product falls under Project activity5(f), Category A NGT Order dated 23.08.2019 in the matter of O.A.No.1038/2018-Reg GIDC Nandesari & PCCI Estate, Di. Vadodara
Sr. no.
Name of the Products CAS no. / CI no.
Quantity MT/Month*
End-use of the products
Existing (Products)
Proposed (Products)
1 CIFIXIME TRIHYDRATE or 79350-37-1 10 0 Used for manufacturing
of Antibiotic drug
formulation.
2 CEFUROXIME AXETIL or 64544-07-6 3 CEFPODOXIME PROXETIL or 87239-81-4 4 AMPICILIN or 69-53-4 20 0
5 AMOXICILLIN TRYDRYDATE or 61336-70-7 20 0
6 CLOBETASOLE PROPIONATE or
25122-46-7 0.5 0 Used for manufacturing of Steroid drug
formulation. 7 BETAMETHASONE
DIPROPIONATE or 5593-20-4 0.5 0
8 BETAMETHASONE VALERATE or
2152-44-5 0.5 0
Gujarat Dyestuff Industries (Pharma Unit) Executive Summary
Rapid Environmental Impact Assessment Report 12
9 BETAMETHASONE SODIUM PHOSPHATE or
151-73-5 0.5 0
10 DEXAMETHASONE SODIUM PHOSPHATE or
2392-39-4 0.5 0
11 BECLOMETHASONE DIPROPIONTE
4419-39-0 0.5 0
12 MOMETASONE FUROATE or 105102-22-5 0.5 0 13 METHYLCOBALAMINE or 13422-55-4 0.5 0.5 Used for
manufacturing of vitamin B-12
formulation. 14 OFLOXACIN or 82419-36-1 20 0 Used for
manufacturing of Antibiotic
drug formulation.
15 LEVOFLOXACIN or 100986-85-4 20 0 16 QUINON SULPHATE or 6119-70-6 20 0 17 CLOXACILLIN SODIUM or 7081-44-9 20 0 18 OXACILLIN SODIUM or 1173-88-2 20 0 19 DI CLOXACILLIN SODIUM or 7081-44-9 20 0 20 FLUCOXACILLIN SODIUM or 1847-24-1 20 0 21 ETHOXYLATES A POLYETHYLENE GLYCOL or 25322-68-3 0 1000 Manufacturing
in agro emulsifier,
cosmetics, soap, detergent,
textile
B HYDROGENATED CASTOR OIL or
8001-78-3 0
C CASTOR OIL ETHOXYLATES or 61791-12-6 0 D NONYL PHENOL
ETHOXYLATES or 68412-53-3 0
E OCTYL PHENOL ETHOXYLATES or
68987-90-6 0
F CARD PHENOL ETHOXYLATES or
37330-39-5 0
G STYRUNATED PHENOL ETHOXYLATES or
61788-44-1 0
H LAURYL ALCOHOL ETHOXYLATES or
68439-50-9 0
I TRIDECYL ALCOHOL ETHOXYLATES or
24938-91-8 0
J CESTOSTYRYL ALCOHOL ETHOXYLATES or
68439-49-6 0
K TALLOW ALCOHOL ETHOXYLATES or
37335-03-8 0
L STEARYL AMINE ETHOXYLATES or
26635-92-7 0
M COCO AMINE ETHOXYLATES or 61791-14-8 0 N OLEYL AMINE ETHOXYLATES
or 90367-28-5 0
O POLY SORBATE ETHOXYLATES or
9005-64-5 0
P STEARIC ACID ETHOXYLATES or
9009-90-9 0
22 METFORMIN HYDROCHLORIDE
1115-70-4 0 500 Used for manufacturing of diabetic drug
formulation. Total 20 1500.5
Gujarat Dyestuff Industries (Pharma Unit) Executive Summary
Rapid Environmental Impact Assessment Report 13
Project Cost
Gujarat Dyestuff Industries (Pharma Unit). shall spend Approximately Rs. 50 Lac for Existing
Products & Rs. 109 Lac for proposed Product as capital expenditure on environmental management.
With a total of 159 lac.
The recurring cost could be Approximately Rs. 15.5 Lac per annum for Existing Products & Rs. 96.5
lac for proposed Product. With a total of 112 lac/annum.
Break-up of Project Cost
Particulars Amount in INR
(crore)
Existing
Amount in INR
(crore)
Proposed
Amount in INR
(crore)
Total
Land 1.0 - 1.0
Factory Building 0.50 0.50 1.0
Plant & Machineries 1.0 2.50 3.50
Other Assets 1.50 1.00 2.50
Total 4.0 4.0 8.0
Site Location
The site is located at Plot No. 133/4, 133/5, 133/6, GIDC Nandesari, Dist: Vadodara-391340.
Vadodara district lies in the Eastern part of the Gujarat.
Other locational details are as follows:
The site is located:
o The site is located Approximately 14.0 km in North West of Vadodara city.
o Approximately 106 km South East of Ahmedabad.
o Nandesari Railway Station 1.8Km towards N
o Vadodara Railway Station – 13 Km towards SE
o Vadodara Airport – 15 Km towards SE approximately.
Geographical Location & Area of the Premises are displayed below
o 22°24'6.96"N, 73° 5'50.04"E
o 22°24'4.98"N, 73° 5'54.30"E
o 22°24'0.30"N, 73° 5'49.80"E
o 22°24'4.32"N, 73° 5'46.50"E
Elevation above Mean Sea Level: Approximately 35.5 meters.
Seismic Zone: 3
o The total area of the site Plot No. 133/4, 133/5, 133/6, GIDC Nandesari, is 3691.10
m2 (0.36911 Ha).
Sr No. Description of Area Area (Sq. m.) 1 Building Area (Production plant, Utilities & storage area, ETP) 1965
2 Road & Parking Area 250
4 Green Belt 1476 5 Open Area 0
Total Plot Area 3691
Gujarat Dyestuff Industries (Pharma Unit) Executive Summary
Rapid Environmental Impact Assessment Report 14
Power Requirement:
Power requirement for the project will be 1600KVA, for proposed product 1000KVA, for existing
Products 600 KVA which is supplied by DGVCL. DG Set of 385 KVA to be installed for backup.
Fuel & Emissions:
Sr. no.
Source of emission
With Capacity
Stack Height
(meter)
Type of Fuel
Quantity of Fuel
MT/Day
Type of emissions
i.e. Air Pollutants
Air Pollution Control
Measures (APCM)
Existing Flue Gas emissions
1 Thermic Fluid Heater
(20 Lac Kcal)
30 F.O / LDO 40 Lit/Hr. PM, SO2, NO2 Caustic Scrubber
Proposed Flue Gas emissions 1 Thermic Fluid
Heater (40 Lac Kcal)
30 Natural Gas 555Nm3/Hr. PM, SO2, NO2 Adequate Stack Height
2 DG Set (385 KVA)
5 HSD 90 Lit/Hr. PM, SO2, NO2 Adequate Stack Height
Process Emissions:
Existing – No Process Emissions
Proposed – No Process Emissions
Water & Wastewater Environment
Water Existing KLD
Proposed (Additional)
KLD
Total after Expansion
KLD
Remarks
(A) Domestic 5 5 10 - (B) Gardening 5 0 5 - (C) Industrial
Process 17 0 17 - Washing 1 3 4 -
Boiler 0 0 0 -- Cooling 10 240 250 -
Others (Scrubber) 0 1 1 -- Industrial Total 28 244 272
Grand Total (A+B+C) 38 249 287 - Recycled 39.6
Fresh Water Required 247.4
Gujarat Dyestuff Industries (Pharma Unit) Executive Summary
Rapid Environmental Impact Assessment Report 15
Wastewater Existing KLD
Proposed (Additional)
KLD
Total after Expansion
KLD
Remarks
(A) Domestic 4 4 8 Septic Tank & Soak Pit
(B) Industrial Process 18.4 1 19.4 - Washing 1.0 3 4 -
Boiler 0 0 0 -- Cooling 0.6 15 15.6 --
Others (Scrubber) 0 1 1 -- Total Industrial
wastewater 20 20 40 To RO Plant for
Recovery ETP RO Plant Product 20 Reused for Cooling
Tower Makeup ETP RO Plant Reject
Effluent 20 To MEE for
Evaporation. 19.6 KLD Condensate recovered reuse.
Existing Products - 38 KLD, Proposed Products 249 KLD, 40 KLD Treated Effluent from ETP to be
recycled after RO & MEE Plant hence 247.4 KLD fresh water will be used, which will be met through
GIDC Nandesari Industrial Estate water supply (attached as Annexure 11). Out of which, process (17
KLD), cooling tower (250 KLD), boiler (0 KLD), Scrubber (1 KLD), Washing (4 KLD) & Domestic (10
KLD). Total water requirement will be 287 KLD in which 20 KLD Treated Effluent from ETP to be
recycled after RO Plant & 19.6 KLD Condensate from MEE Plant. Hence freshwater requirement will
be 247.4 KLD.
Hazardous Waste
Sr. no
.
Type/Name of
Hazardous waste
Specific Source of generatio
n (Name of
the Activity, Product
etc.)
Category and
Schedule as per
HW Rules.
Quantity (MT/Annum)
Management of HW
Existing Products
Proposed Products
Total After
Expansion
1 ETP Sludge ETP Sch-I/ 35.3
12 MT/Annu
m
0 12 MT/Annu
m
Collection, storage,
treatment, transportation, and disposal at
Nandesari Environment Control Ltd
(NECL) TSDF 2 Discarded
Bags & Containers
Production plant
Sch-I/ 33.1
108 MT/ Annum
0 108 MT/ Annum
Collection storage &
Decontamination within
factory premises.
Gujarat Dyestuff Industries (Pharma Unit) Executive Summary
Rapid Environmental Impact Assessment Report 16
3 Used Oil From Machinery
and TFH
Sch-I/ 5.1
0.6 KL/Annu
m
0 0.6 KL/Annu
m
Collection, storage,
transportation, Disposal by
selling to registered re-
refiners 4 Distillation
residues From
Solvent Recovery
Sch-I/ 20.3
36 MT/Annu
m
30 MT/Annu
m
66 MT/Annu
m
CHWIF incinerator
facility of M/s. Nandesari
Environment Control Ltd.
(NECL) / Coprocessing
5 Spent Solvent for
recovery Process
Sch-I/ 20.2
252 MT/Annu
m
4116 MT/Annu
m
4368 MT/Annu
m
Captive In-house
Recovery.
6 MEE Salt
From Evaporatio
n of RO Reject
Sch-I/ 37.3
0 MT/Annu
m
144 MT/Annu
m
144 MT/Annu
m
Nandesari Environment Control Ltd
(NECL) TSDF
Environmental Management
Sr. No.
Description Capital cost (Rs.)
(Lac) Recurring cost (Rs.)
(Lac. /annum) Existing Proposed Total Existing Proposed Total
1 Air pollution
control 6.5 2.5 9 5 1.5 6.5
2 Water pollution
control 33 100 133 4.5 90.5 95
3 Hazardous
waste management 3 2.5 5.5 2.5 1.5 4
4 Environment monitoring & Management 5 3 8 2 1.5 3.5
5 Occupational
health 1 0.5 1.5 0.5 0.5 1
6 Greenbelt
development 1.5 0.5 2 1 1 2 Total 50 109 159 15.5 96.5 112
Justification of selecting the proposed product & unit size.
Existing products are Bulk drugs for manufacturing of Antibiotic Drugs, Steroid formulations, B-12,
& the proposed products i.e. ethoxylates are used for manufacturing of Agro emulsifier, Cosmetics,
Soap, Detergent, Textile, Also the proposed bulk drug Metformin is used for diabetic drug
formulation. These products have a good market demand. Due to the increasing demand we have
selected the products.
Process Effluent Generation during the manufacturing of Ethoxylates and Metformin Hydrochloride
is negligible. Major effluent contribution is Cooling Tower Blowdown & Washing. Existing 20 KLD &
Additional 20 KLD i.e. total of 40 KLD / 60 MTD of product manufactured.
Gujarat Dyestuff Industries (Pharma Unit) ToR Compliances
Rapid Environmental Impact Assessment Report 17
TOR Compliances
Sr. No. ToR point Compliance status 1. Compliance to MoEFCC’s OM Dated 01/05/2018
regarding “Corporate Environment Responsibility” (CER), Fund allocation for Corporate Environment Responsibility (CER) shall be made as per MoEFCC’s O.M. No 22-65/2017-IA.III dated 01/05/2018 for various activities therein. The details of fund allocation and activities for CER shall be incorporated in the EIA/EMP report.
Chapter 8, Point 8.5, Page 225.
2. Explore the use of renewable energy to the maximum extent possible. Details of provisions to make the project energy efficient through of energy efficient devices and adoption of methods of alternative eco-friendly sources of energy like solar water heater, solar lighting etc. Measures proposed for energy conservation.
Use of Common area Solar Lighting will be done for the proposed expansion. We are evaluating feasibility for use of solar energy.
3. PP Shall address spent solvent with details of storage, handling & re-use under the Hazardous & other waste (Management & Transboundary movement) Rules 2016.
Kindly refer Point 2.9, Chapter-2, Page No 66, Point No 2.13, Page No. 127 - 130.
4. PP Shall furnish status of all the applicable rules, acts, regulation, clearances in a tabular form.
Kindly refer Chapter 2, Point 2.14, Page 140.
5. Leak detection and Repairing Programme (LDAR) for all the volatile organic solvent proposed for use in-house with detailed chemical properties including vapor pressure. LDAR shall endeavor prevention of losses of solvents to the best minimum extent.
Chapter 7, Point 7.7, Page 215-217. Chapter 2, Table 2.5 Page 50.
6. Safety precautions including flame proof electrical electric fittings to be taken to avoid fire hazard during unloading, storage, transportation, handling, and processing of solvents.
Chapter 7, Point 7.5, Page 212-213, Point 7.6 Page 213-215.
Gujarat Dyestuff Industries (Pharma Unit) ToR Compliances
Rapid Environmental Impact Assessment Report 18
Standard - TOR Compliances
Sr. No.
ToR point Compliance status
1. A tabular chart with index for point-wise compliance of below mentioned TORs.
Complied
2. Executive summary of the project – giving a prima facie idea of the objectives of the proposal, use of resources, justification, etc. In addition, it should provide a compilation of EIA report, including EMP and the post project monitoring plan in brief.
Executive Summary Page 11-16. Chapter 6.0, Point 6.4, Page 204.
3. Justification for selecting the proposed product and unit size.
Executive Summary Page 16
4. Land requirement for the project including its breakup for various purposes, its availability and optimization.
Executive Summary Page 13, Chapter 2, Table 2.2 Page 46. No additional land to be procured.
5. Land Possession documents. Copy of NA order showing permission to use the project land for industrial purpose. If located in GIDC, copy of plot holding certificate to be obtained from GIDC Authority.
Copy of plot holding certificate obtained from Nandesari GIDC is given as Annexure-2.
6. Location of the project site and nearest habitats with distances from the project site to be demarcated on a toposheet (1:50000)
Kindly refer pages 159, 161 & 162
7. Topography details of the project area. Chapter 3, Page 160, 161 8. Geological features and geo-hydrological status of the
study area. Chapter 3, Point 3.8, Page 158, 159
9. In case of project located outside notified area: Legal undertaking stating that unit is complying the three conditions, [i.e. water consumption less than 25m3/day, Fuel consumption less than 25 TPD, and not covered in the category of MAH units as per the management, storage, Import of Hazardous Chemicals Rules (MSIHC Rules), 1989] as per the amendment to EIA Notification 2006 vide SO 1599(E) dated 25/06/2014.
Unit is located in the Notified area of Nandesari GIDC.
10. Present land use pattern of the study area shall be given based on satellite imagery.
Refer Chapter No 3, Point 3.9 Page 159- 161.
11. Layout plan of the factory premises clearly demarcating various units within the plant. Provision of separate entry & exit and adequate margin all-round the periphery for unobstructed easy movement of the emergency vehicle / fire tenders without reversing back. Mark the same in the plant layout.
Plant layout is given as figure no. 2.1, Page 45 in chapter 2, Page No 46. Also kindly refer Annexure 9.
12. Technical details of the plant/s along with details on best available technologies (BAT), proposed technology and reasons for selecting the same.
Point no. 5.2 of chapter 5 page no 200. Point 2.12 page 122 – 127.
13. Product spectrum (Proposed products along with production capacity) and processes.
2.7 of chapter 2 page no 46-48.
14. Chemical name of each proposed product to be manufactured. Details on end use of each product. (Provide CAS number of all the products and raw materials. In case of dyes CI number)
Pls. refer Chapter 2, Point No 2.7, table no. 2.3, Page 46-48. Table 2.5, Page 50-64.
Gujarat Dyestuff Industries (Pharma Unit) ToR Compliances
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ToR point Compliance status
15. Details on raw materials, source and storage within premises.
Refer Table 2.5 & 2.6 Page 50 to 65.
16. Details of manufacturing process / operations of each product along with chemical reactions, process flow diagram describing each unit process and unit operations along with mass balance, consumption of raw materials etc.
Kindly refer chapter 2. Point No 2.11, Page No 70 to 121.
17. Details on strategy for the implementation of cleaner production activities.
Pls. refer section 10.10 of chapter 10 for cleaner production. Page 240.
18. Assessment of source of the water supply with adequacy of the same to meet with the requirements for the project. Permission letter obtained from the concerned authority for supply of raw water.
Source of the water supply is Nandesari GIDC water supply. Water balance diagram is given as figure 2.3 page 129-130 & Table 2.11, Page 126 to 128 of chapter 2. letter from GIDC Nandesari for supply of water is given as Annexure-11.
19. Undertaking stating that no bore well shall be dug within the premises. (If project is located within the industrial estate).
Undertaking stating that no borewell shall be dug within the premises is given as Annexure 5.
20 Details on water balance including quality of effluent generated, recycled and reused. Details of methods to be adopted for water conservation.
Water balance diagram is given as figure 2.3 of chapter 2. Table 2.11, Page 126 to 128. Details of Qualitative and quantitative analysis of the waste stream from the processes is given in section 2.13.1.1-chapter 2 Page 131-135.
21. Efforts to minimize effluent discharge and to maintain quality of receiving water body.
For the proposed products there shall be optimum use of fresh water with evaluation of possibilities wherever to reduce the freshwater consumption. We shall maximize reuse, recover and recycle of the water. The Effluent Treatment Plant will treat the total effluent. Treated Effluent to be passed through RO Plant to recover 50% treated wastewater. 50% of ETP RO Reject to be taken to MEE. MEE Condensate to be recovered.
22. Explore the possibilities for Zero Liquid Discharge (ZLD) option for the proposed project.
40 KLD Treated Effluent to be passed through RO Plant to recover 50% treated wastewater. 50% of ETP RO Reject to be taken to MEE. MEE Condensate to be recovered Hence ZLD will be incorporated.
23. Segregation of waste streams, characterization and quality with specific treatment and disposal of each stream including action plan for maximum recycle of treated wastewater and minimum discharge for effluent.
Pls. refer Chapter 2, section 2.13.1, Page 127, 2.13.1.3 Page 133 to 135 for effluent treatment scheme For Qualitative analysis refer Chapter 2, Point No 2.13.1.1, Page 131-132.
24. Capacity of ETP in KL/Day. Details of ETP including dimensions of each unit along with schematic flow
Pls. refer Chapter 2, section 2.13.1.3, Page 133 to 135 for effluent treatment scheme
Gujarat Dyestuff Industries (Pharma Unit) ToR Compliances
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ToR point Compliance status
diagram. Inlet, transitional and treated effluent qualities with specific efficiency of each treatment unit in reduction in respect of all concerned/regulated environmental parameters. Inlet effluent quality should be based on worst case scenario considering production of most polluting products that can be manufactured in the plant concurrently.
For Qualitative analysis refer Chapter 2, Point No 2.13.1.1, Page 131-132. For Effluent Treatment Plant tank details refer Chapter 2, Table No 2.18. Point No 2.13.1.3, Page 133-134. Specific efficiency of treatment can be seen from qualitative analysis.
25. In case of discharge into GIDC Drainage / Pipeline 1. Copy of permission letter with quantity
(KL/Day) from the concern authority of drainage network pipeline with conformation for spare capacity available to take additional effluent.
2. Characteristics of the contained effluent and treated water to be sent to common pipeline with reference to the MoEFCC/CPCB/GPCB discharge norms.
3. Provision of continuous monitoring system for wastewater discharge.
Present existing permission from CETP is available for 20KLD. However, we have decided to incorporate ZLD Scheme.
26. In Case of wastewater sent to Common Facilities (CF) like CETP, MEE, Spray Dryer etc.
a. Details of Common facilities including (1) Total Capacity of the CF. (2) Copy of CC&A of the CF. (3) Actual load at present (Qualitative and Quantitative – KL per day). (4) Booked quantity & Spare capacity of CF. (5) Copies of XGN generated Inspection reports with analysis reports of the GPCB in last 2 year and point wise compliance thereof. (6) Copies of Show-Cause notices, closure notices etc. served by the GPCB and its compliance. (6) Recommendations and suggestions of the last two Environment Audit reports of CETP and its compliance report. (7) Common Facility Upgradation scheme if any.
b. Status of compliance to the 18(1) (b) direction issued by the CPCB with respect to CETP compliance & CEPI area action plan along with relevant supportive document.
c. Give status of compliance of Environmental norms of existing Common Infrastructure i.e. CETP, MEE & Spray Dryer (Whichever is applicable) in which you are a member.
d. Submit adequacy of Common Infrastructure i.e. CETP, MEE & Spray Dryer for additional load (Whichever is applicable) along with written conformation/membership certificate mentioning the same (Total consented
Present existing permission from CETP is available for 20KLD. However, we have decided to incorporate ZLD Scheme. For Points 1, 2, 3, 5 - Kindly refer Annexure – 10. For Point 4 - Kindly refer Annexure 16.
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Sr. No.
ToR point Compliance status
quantity, total quantity booked so far, quantity booked for the unit, spare quantity available).
27. In case of Zero Liquid Discharge (ZLD): I. Action plan for ‘Zero’ Discharge of effluent
shall be included, Notarized undertaking for assuring that underground drainage connection will not be taken in the unit and there shall be no effluent discharge outside the plan premises.
II. Economical and technical viability of the effluent treatment plant system to achieve Zero Liquid Discharge (ZLD).
III. Certification of adequacy of proposed ZLD scheme through credible institutes of National repute.
IV. To estimate & monitor ground water quality & its contamination status, piezometer wells, one on up gradient of the groundwater flow and other three on the down gradient side of the ground water flow of the proposed project at different depth based on available ground water depth shall be established and all the parameters mentioned in IS 10500 for potable water standard shall be mentioned.
Present existing permission from CETP is available for 20KLD. However, we have decided to incorporate ZLD Scheme.
1. For Action Plan of ZLD refer Table 2.11 Page 128 & water balance diagram Fig 2.3 Page 129. Point 2.10 Page 67-68 for details of UF & RO Plant, Point 2.10.2 Page 69 for details of MEE Plant.
2. For viability refer Point 10.6.2 Page No 233.
28. In case of In-house MEE/Spray dryer for wastewater treatment. Capacity of the MEE / Spray Dryer in KL/Hr. Technical details of MEE including evaporation capacity, steam required for evaporation, adequacy of the proposed boiler to supply steam for evaporation in addition to the steam required for the process etc. Techno-economic viability of the evaporation system. Control measures proposed for the evaporation system in order to avoid / reduce gaseous emission / VOC from evaporation of industrial effluent containing solvents & other chemicals.
Spray Dryer not to be installed. For MEE refer point 2.10.2 Page 69. Thermic Fluid to be used for MEE Operation. For viability refer Point 10.6.2 Page No 233. Solvent Recovery plant installed for solvent recovery and avoid evaporation in industrial effluent. For solvent recovery refer point 2.9 Page 66.
29. Technical Details of ATFD/Crystallizer/Spray Dryer, RO/NF system etc. (If any)
ATFD, Crystallizer, Spray Dryer not to be installed. RO Plant to recover 50% of the Treated Effluent will be Installed. 50% Reject will go to MEE Plant. Concentrate of the MEE will go to the ATFD. Refer Point 2.10 Page 67-68 for UF-RO Details.
30. Details of the treatability and feasibility of wastewater to be disposed off by means of spray dryer and its impact on environment & human health.
Treated Wastewater will not be disposed by spray dryer. RO & MEE to be installed. For Qualitative analysis refer Chapter 2, Point No 2.13.1.1, Page 131-132. For
Gujarat Dyestuff Industries (Pharma Unit) ToR Compliances
Rapid Environmental Impact Assessment Report 22
Sr. No.
ToR point Compliance status
Effluent Treatment Plant tank details refer Chapter 2, Table No 2.18, Page 133-134.
31. Undertaking stating that a separate electric meter will be provided for the wastewater treatment system viz. ETP, RO, MEE, Spray Dryer etc. (Whichever is applicable)
Undertaking stating that a separate energy meter will be provided for the ETP, RO, MEE is given as Annexure 5.
32. Economical & technical viability of the effluent treatment plant
Pls. refer point 10.6.2.1 of chapter 10, page no 233. Kindly also refer Chapter 9.
33. Plans for management, collection and disposal of waste streams to be generated from spillage, leakages, vessel washing, used container washing etc. Measures proposed for preventing effluent discharge during unforeseen circumstances.
Please refer 7.7.2 & 7.7.3, Page 216-217 of Chapter 7. Kindly refer Chapter 10, Point 10.13 page 241 for prevention of storm water contamination.
34. Action plan for reuse of liquid waste streams like spent acids, Poly Aluminum Chloride etc. within the premises to convert into valuable products instead of sending outside to actual end-users.
There will be no generation of Spent Acids or Byproducts.
35. Adequacy of the proposed EMS with respect to the pollution load envisaged in terms of Air, Water & Hazardous waste.
Kindly refer Point 2.13.1.3, Page 133-134, Point 2.13.2 page 136-137, Point 2.13.3 Page 138-139, Annexure-11 for water supply, Annexure-12 for Membership of Hazardous waste, Annexure-16 for CETP Membership.
36. One season Site-specific micro-meteorological data using temperature, relative humidity, hourly wind speed and direction and rainfall should be incorporated.
Details are covered in section 3.3 of chapter 3. Kindly refer windrose fig 3.1A, Page 146.
37. Anticipated environmental impacts due to the proposed project/production may be evaluated for significance and based on corresponding likely impacts VECs (Valued Environmental Components) may be identified. Baseline studies may be conducted within the study area of 10 km for all the concerned/identified VECs and likely impacts will have to be assessed for their magnitude in order to identify mitigation measures.
Anticipated environment impacts & mitigation measure due to the proposed projects are covered in chapter 4. Pls. refer chapter 3 for baseline monitoring data. Kindly refer chapter 10 Environmental Management.
38. One complete season baseline ambient air quality data (except monsoon) to be given along with the dates of monitoring. The parameters to be covered shall be in accordance with revised national ambient air quality standards as well as project specific parameters like NH3, HCL, Cl2, HBr, VOC etc. Locations of the monitoring stations should be so decided as to take into considerations the pre-dominant downwind direction, population zone & sensitive receptors. There should be at least one monitoring station in the upwind direction. There should be at least one monitoring station in the predominant downwind direction at a location where maximum ground level concentration is likely to occur.
One complete season base line ambient air quality data is covered in section 3.4 of chapter 3, page 147 to 151. Baseline data has been procured from Aqua-Air Environmental Engineers Pvt. Ltd. Surat, for the Period October 2018 to December 2018.
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39. Modeling indicating the likely impact on ambient air quality due to proposed activities. The details of model used, and input parameters used for modeling should be provided. The air quality contours may be shown on location map clearly indicating the location of sensitive receptors, if any, and the habitation. The wind rose showing pre-dominant wind direction should also be indicated on the map. Impact due to vehicular movement shall also be included into the prediction using suitable model. Results of Air dispersion modeling should be superimposed on google map / geographical area map.
Details of Modeling indicating the likely impact on ambient air quality due to proposed activities covered in chapter 4 Air quality contour superimposed on google map/geographical area map is given in figure 4.2(a) & 4.2(b) Page 187-188, Figure 4.3(a) & 4.3(b) Page 190-191, Figure 4.4(a) & 4.4(b) Page 193-194 of chapter 4.
40. Base line status of the noise environment, impact of noise on present environment due to the project and proposed measures for noise reduction including engineering controls.
Pls. refer Section 3.5, Page 151-152 & table no. 3.10 of Page 152 for Baseline noise level status of chapter 3.
41. Specific details of (a) Process gas emission of each unit process with its quantification (b) Air pollution control measures (APCM) for process gas emission. Adequacy of the Air pollution control measures for process gas emission, measures to achieve the GPCB norms. (c) Details of the utility required. (d) Type & quantity (MT/hr. & MT/Day) of fuel to be used for each utility. (e) Flue gas emission rate from each utility. (f) Air pollution control measures proposed to each of the utility along with its adequacy. (g) List the sources of fugitive emission along with its quantification & proposed measures to control it. (h) Details on tail gas treatment. (if any)
Kindly refer Point 2.13.2, Page 136-137. Utilities Point 2.12.3, Page 125-126. Fugitive emission Point 4.4.1.1 page 182, Table 4.3, Page 184.
42. Provision of CEMS (Continuous Emission Monitoring System).
Natural Gas to be used as fuel for the proposed TFH. Hence, we have not considered provision of CEMS. We have considered getting the stack monitoring done by recognized agency at regular intervals.
43. Action plan for odour control to be submitted. Please refer Point 10.6.5, Page 236 of Chapter 10.
44. Management plan for hazardous/solid wastes including storage, handling, utilization and safe disposal as per the Hazardous and Other Wastes (Management & Transboundary Movement) Rules 2016. CPCB guidelines in respect to specific treatment, such as solar evaporation, incineration, etc. Need to be followed.
Pls. refer Point no 2.13.3, Page No 138-139 of chapter 2. Refer point 10.6.3.3, Page 234-235, Point 10.6.3, page 234 to 237.
45. How the manual handling of the hazardous wastes will be minimized? Methodology of de-contamination and disposal of discarded containers and its record keeping.
Point 7.3 Page 212, Methodology of de-contamination and disposal of discarded containers is given in section 10.6.3.4, Page 235 of chapter 10.
46. Management plan for by-products which fall under the perview of the Hazardous and Other Wastes (Management & Transboundary Movement) Rules
No By-products will be generated.
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2016. as per the said rules and necessary permissions from the concerned authority.
47. Membership of Common Environmental Infrastructure including the TSDF / Common Incineration Facility (CHWIF), MEE, Spray Dryer etc.
Kindly refer Annexure 11 for document covering water supply & Annexure 16 for effluent disposal.
48. Name and quantity of each type of solvents to be used for proposed production. Details of in-house solvent recovery system including mass balance, solvent loss, recovery efficiency (% recovery), feasibility of reusing the recovered solvents etc. for each type of solvent.
Kindly refer Table 2.5, Page 50 of Chapter 2. Kindly see Point 2.9 Page 66.
49. Appropriate monitoring network has to be designed and proposed, to access the possible residual impact on VECs.
Anticipated environment impacts & mitigation measure due to the proposed projects are covered in chapter 4.
50. A detailed EMP including the protection and mitigation measures for impact on human health and environment as well as detailed monitoring plan and environmental management cell proposed for implementation and monitoring of EMP. The EMP should also include the concept of waste minimization, recycle/reuse/recover techniques, energy conservation, and natural resource conservation. Total capital cost and recurring cost/annum earmarked for environment pollution control measures.
Detailed EMP is given in separate chapter 10. Environmental Monitoring details are given Point 6.3 & 6.4, Page 201-204 in chapter 6. Total capital cost and recurring cost/annum earmarked for environment pollution control measures is given in table 6.3 page 205 of chapter 6.
51. Details of In-House monitoring capabilities and the recognized agencies if proposed for conducting monitoring.
Monitoring will be got done from Recognized agencies.
52. Permission from (PESO), Nagpur for storage of solvents, other toxic chemicals if any.
Permission attached vide Annexure 22. Layout plan attached vide Annexure 9.
53. Occupational health impacts on the workers and mitigation measures proposed to avoid the human hazards along with the personal protective equipment to be provided. Provision of industrial hygienist and monitoring of the occupational injury to workers as well as impacts to the worker. Plan for periodic medical checkup for the worker exposed. Details of workplace Ambient Air Quality monitoring plan as per Gujarat Factories rules.
Pls. refer point 10.7 page 237, Point 7.5.2 page 213.
54. Details on volatile organic compounds (VOCs) from the plant operations and occupational safety and health protection measures. Proposal for Leak Detection and Repair (LDAR) program as per the CPCB guidelines.
Pls. refer Point 10.6, 10.6.1.2, Page 233 of chapter 10 LDAR vide Point 7.7, Page 215-217,
55. Risk assessment including prediction of the worst-case scenario and maximum credible accident scenario should be carried out. The worst-case scenario should take in to account the maximum inventory of storage at site at any point of time. The risk contour should be plotted on the plant lay out map clearly showing which of the facility would be affected in case of any accident taking place. Based on the same, proposed safeguard measures including on site/off site plans should be provided.
Kindly refer Annexure 3 for Risk Assessment Report.
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56. MSDS of all the products & raw materials Kindly refer Annexure 7 for MSDS of Raw Materials. Kindly refer Annexure 8 for MSDS of Products.
57. Details of hazardous characteristics & toxicity of raw materials & products to be handled & the control measures proposed to ensure safety & avoid the human health impacts. this shall include the details of antidotes also
Kindly refer Annexure 3, Risk Assessment Report, Table 2.5, Page 50-64. Antidotes have been given in MSDS of Raw material & products.
58. Details of quantity of each hazardous chemicals (including solvents) to be stored, material of construction (MOC) of major hazardous chemical storage tanks, dyke details, threshold storage quantity as per schedules of the manufacture, storage & import of hazardous chemicals rules of major hazardous chemicals, size of the biggest storage tanks to be provided for each raw material & product etc. How the manual handling of the hazardous chemicals will be minimized?
Kindly refer Table 2.5, Page 50. Kindly refer Annexure 3, Risk Assessment report. Chapter 7, Point 7.3 Page 208-211. Page 214 for dyke.
59. Details of the separate isolated storage area for flammable chemicals. Details of flame proof electrical fittings, DCP extinguisher & other safety measures proposed. Detailed fire control plan for flammable substances & processes showing hydrant pipeline network, provision of DG Sets, fire pumps, jockey pumps, toxic gas detectors etc.
Point No 7.6, Page 213-215, BAT vide Pls. refer section 7.8 of chapter 7. Point No 7.6, Page 213, Point No 7.6.1, Page 214, Point No 7.7, Page 215-217
60. Submit checklist in the form of Do’s & Don’ts of preventive maintenance, strengthening of HSE, manufacturing utility staff for safety related measures.
Kindly refer Point 7.11 vide Page No 217 to 223.
61. Specify safety precautions to be taken for chemical storage, process, handling and transportation hazard.
Kindly refer Point 7.6 vide Page No 213-215.
62. Details of workers training before engaging work, periodical, in-house, outside etc.
Kindly refer Annexure 15
63. Details of various SOP to be prepared. SOP Index has been attached vide Annexure 15.
64. Details of safety audit to be carried out and their compliance status.
Kindly refer Annexure 6
65. Specific safety measures to be taken for general Public living in the vicinity.
Kindly refer Chapter 7, Point 7.6 page 213-215. Copy of PLI attached vide Annexure 23.
66. Details on hazard identification i.e. HAZOP, HAZEN, Fault Tree analysis, Event tree analysis, Checklist, Audit etc. to be adopted for the safety operation of the plant.
Hazop will be conducted after the design of the plant. Kindly find attached Annexure 4 Emergency
67. Detection and monitoring of VOC’s / gases. Please refer Chapter 6, point 6.4 page 204, Chapter 7, Point 7.6.2, page 215, Chapter 10, Point 10.6.1.2 Page 233.
68. Detailed five-year greenbelt development program including annual budget, planning schedule, species, width of plantation, number of trees to be planted, area under green belt development [with map], budgetary outlay etc. ; along with commitment of the
Please refer Point 10.8 vide Chapter 10. Page 238-239. Kindly refer Annexure 5 for commitment of management for green belt development.
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management to carry out the tree plantation activities outside the premises at appropriate places in the nearby areas and elsewhere.
69. Action plan for greenbelt development – species, width of plantations, planning schedule, etc. in accordance with CPCB published guidelines.
Please refer Point 10.8 vide Chapter 10. Page 238-239. Kindly refer Annexure 5 for commitment of management for green belt development.
70. Detailed socio-economic development measures including community welfare program most useful in the project area for the overall improvement of the environment. Submit a detailed plan for social corporate responsibilities, with appropriate budgetary provisions for the next five years and activities proposed to be carried out; specific to the current demographic status of the area.
Pls. refer point 8.5, page 225 of chapter 8.
71. (a) Does the company have a well laid down Environment Policy approved by its Board of Directors? If so, it may be detailed in the EIA report. (b). Does the Environment Policy prescribe for standard operating process / procedures to bring into focus any infringement / deviation / violation of the environmental or forest norms / conditions? If so, it may be detailed in the EIA.
Kindly refer Chapter 10, Page 230.
72. What is the hierarchical system or administrative order of the company to deal with the environmental issues and for ensuring compliance with the EC conditions? Details of this system may be given.
Pls. refer section 10.4, Page 229-230 of chapter 10.
73. Does the company have a system of reporting of non-compliances / violations of environmental norms to the Board of Directors of the company and / or shareholders or stakeholders at large? This reporting mechanism should be detailed in the EIA Report.
Pls. refer section 10.4.1, page 230 of chapter 10
74. Phase wise project implementation schedule with bar chart and time frame, in terms of development, infrastructure provision, EMS implementation etc.
Kindly find Annexure 17
75. Certificate of accreditation issued by the NABET, QCI to the environmental consultant should be incorporated in the EIA report.
Please refer Annexure 13 for stay order from Hon. High Court
76. An undertaking by the Project Proponent on the ownership of the EIA report as per the MoEF&CC OM dated 5/10/2011 and an undertaking by the consultant regarding the prescribed TORs have been complied with and the data submitted is factually correct as per the MoEF&CC OM dated 04/08/2009.
Please refer Annexure 5 for Undertaking.
77. All Documents to be properly referenced with index and continuous page numbering.
This has been done.
78. Where data are presented in the report especially in Tables, the period in which the data were collected, and the sources should be indicated.
Indicated
79. Project Proponent shall enclose all the analysis / testing reports of water, air, soil, noise etc. using the MoEF&CC/NABL accredited laboratories. All the
Baseline data has been procured from Aqua-Air Environmental Engineers Pvt.
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original analysis/testing reports should be available during appraisal of the project.
Ltd. Surat, for the Period October 2018 to December 2018. Annexure 21.
80. In case of expansion of the project. a. Need for the proposed expansion should be
justified in detail. b. Adequacy of existing EMS (Environmental
management System) c. Explore the Possibility to achieve Zero Liquid
Discharge (ZLD) for existing as well as proposed activity.
d. Records of any legal breach of Environmental laws i.e. details of show-cause notices, closure notices, etc. served by the GPCB to the existing unit in last five years and actions taken then after for prevention of pollution.
e. Copies of Environmental Clearances obtained for the existing plant, its point wise compliance report.
f. Environmental Audit reports for last 3 years and compliance of its recommendations/suggestions. (include latest audit report and its compliance)
g. Copy of Consent to operate (CC&A) obtained along with point wise compliance status of all the conditions stipulated therein.
h. Compliance of MoEFCC circulars vide No: J-11011/618/2010-IAII (I) dated 30/05/2012 and J-11013/41/2006-IA-II(I) dated 20/10/2009.
i. Copies of XGN generated inspection reports with analysis reports of the water/Air/Hazardous samples collected by GPCB (Last 2 year). Copies of instructions issued by GPCB in last 2 year and point wise compliance thereof.
a. Kindly refer Executive Summary
Page 16.
b. Kindly refer Annexure 19.
c. Permission for disposal of 20 KLD Existing + 20 KLD Proposed Treated wastewater to CETP Nandesari available. However, ZLD has been planned.
d. No Notices, Closures etc. received by the unit in last five years.
e. Copy of Environmental Clearance attached vide Annexure 20.
f. Environmental Audit not applicable.
g. CTE & CTO has been attached vide Annexure 24.
h. Copy of compliance attached vide Annexure 14.
i. XGN Generated reports attached vide annexure 18.
81. In case of project is located in Ankleshwar-Panoli, Vatva-Narol & Vapi GIDC.
A. Compliance of MoEFCC’s OM No J-11013/5/2010-IA. II (I) dated 25/11/2016 regarding lifting of moratorium on the consideration of projects for environmental clearance.
B. Compliance of direction under section 18 (1) (b) of the water (Prevention and Control of Pollution) act, 1974 issued by CPCB dated 31/03/2016 regarding compliance of CETP. a. Action initiated by GPCB, if any, against
proposed unit regarding non-compliance of prescribed standards under the various environmental laws.
b. Performance of CETP with respect to current hydraulic load and prescribed
Unit is located at GIDC Nandesari.
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standards with No-Objection Certificate of CETP regarding incorporation of the proposed unit for acceptance of wastewater.
c. Performance of TSDF site with respect to current load & prescribed standards with No Objection Certificate of TSDF site regarding incorporation of the proposed unit for acceptance of hazardous waste to the common infrastructure.
d. Copies of quarterly action report taken for the above points submitted to the CPCB.
e. Report of GPCB which have conducted monitoring as per the said direction by CPCB dated 31/03/2016.
Validity of ToR: • The ToRs prescribed for the project will be
valid for three years for submission of EIA & EMP report.
• The period of validity could be extended for a maximum period of one year provided an application is made by the applicant to the Regulatory Authority, at least three months before the expiry of validity period together with an updated Form-1, based on proper justification and also recommendation of the SEAC.
Noted
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CHAPTER – 1: INTRODUCTION
1.1 Purpose of Study & Regulatory Framework
Environmental Impact Assessment Report has been prepared for obtaining Environmental
Clearance for M/s. Gujarat Dyestuff Industries (Pharma Unit). located at Plot No. 133/4, 133/5,
133/6, GIDC Nandesari, Dist: Vadodara-391340, State: Gujarat, India for Expansion in the existing
Bulk Drug Manufacturing unit for Manufacturing of Ethoxylates & Metformin Hydrochloride i.e.
under Category 5(f) and is included category of the Environmental Impact Assessment Notification,
issued in September-2006 and subsequent amendments. The industry is located within the notified
industrial area/estate GIDC Nandesari and therefore as per NGT Order dated 23.08.2019 in the
matter of O.A.No.1038/2018-Reg GIDC Nandesari & PCCI Estate, Di. Vadodara it will fall in category
“A” of the Environmental Impact Notification requiring Environmental Clearance from MoEF, New
Delhi.
This is a “Existing Unit”. This is an existing unit into manufacturing of Bulk Drugs such as Cifixime
Trihydrate, Cefuroxime Axetil, Cefpodoxime Proxetil, Ampicilin, Amoxicillin Trydrydate,
Clobetasole Propionate, Betamethasone Dipropionate, Betamethasone Valerate, Betamethasone
Sodium Phosphate, Dexamethasone Sodium Phosphate, Beclomethasone Dipropionate,
Mometasone Furoate, Methylcobalamine, Ofloxacin, Levofloxacin, Quinon Sulphate, Cloxacillin
Sodium, Oxacillin Sodium, Di Cloxacillin Sodium, Flucoxacillin Sodium.
New products Ethoxylates, Metformin Hydrochloride, and additional Methylcobalamine that falls
in Schedule 5(f) are planned to be manufactured and hence the application for EC is being done.
1.2 Identification of the Project and Project Proponent
M/s. Gujarat Dyestuff Industries (Pharma Unit). located at Plot No. 133/4, 133/5, 133/6, GIDC
Nandesari, Dist: Vadodara-391340.
This is an existing unit into manufacturing of Bulk Drugs such as Cifixime Trihydrate, Cefuroxime
Axetil, Cefpodoxime Proxetil, Ampicilin, Amoxicillin Trydrydate, Clobetasole Propionate,
Betamethasone Dipropionate, Betamethasone Valerate, Betamethasone Sodium Phosphate,
Dexamethasone Sodium Phosphate, Beclomethasone Dipropionate, Mometasone Furoate,
Methylcobalamine, Ofloxacin, Levofloxacin, Quinon Sulphate, Cloxacillin Sodium, Oxacillin Sodium,
Di Cloxacillin Sodium, Flucoxacillin Sodium.
New products Ethoxylates, Metformin Hydrochloride, and additional Methylcobalamine that falls
in Schedule 5(f) are planned to be manufactured and hence the application for EC is being done.
• Project is located in GIDC Nandesari, which is an industrial area, so requirement of
industrial land is fulfilled. All other infrastructure facilities such as water, fuel, power, Storm
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water drainage, effluent disposal facilities, proper road network for transportation of raw
materials & products, skilled & unskilled manpower etc. are also easily available.
• Rehabilitation and resettlement will not be required, as project is in Industrial area.
• No national park or wildlife sanctuary within 10 radius of the project site.
• Vadodara is the nearest city, which is properly connected to all other cities by road & rail
networks.
Details of the Project Proponent / Directors is given below.
SH. D.C. SHARMA
Pattharwala Bungalows, Nr. Sri
Ram Society, Gotri Road,
Vadodara 390007
MO .NO: 9376210937
TEL NO: 0265-2397901
SH. OM PRAKASH C-22, Mahendra Enclave, Azadpur
Model Town, Delhi- 110033 TEL NO: 011-26515127
SHRIMATI SHAMMI
GARG
807, D.B. Gupta Road, Nr. Sheila
Cinema, New Delhi. TEL NO.: 0265-2326676
Detail of the Key Personnel is given below.
Name & Designation
Age (years)
Qualification Total No. of Years of
experience
Description of Experience
Atul Jayprakash Pathak Sr. Manage-
Production
36 MSC 12 Experience in production and facility improvement
in various pharma products
L.C Bhosle Manager-QA
44 BSc 18
Experience in Quality Assurance
Kaniyalal Manger-
Engineering
45 Diploma in Electrical
15 Rich Experience in Electrical and engineering
S.N Shukla Manager-
Commercial
55 MA 32 Experience in Excise and commercial
Sanjeev Kumar In charge-QC
30 M-Pharma 6 Experience in quality control lab
1.3 Project Brief:
M/s. Gujarat Dyestuff Industries (Pharma Unit) is located at Plot No. 133/4, 133/5, 133/6, GIDC
Nandesari, Dist: Vadodara-391340.
This is an existing unit into manufacturing of Bulk Drugs such as Cifixime Trihydrate, Cefuroxime
Axetil, Cefpodoxime Proxetil, Ampicilin, Amoxicillin Trydrydate, Clobetasole Propionate,
Betamethasone Dipropionate, Betamethasone Valerate, Betamethasone Sodium Phosphate,
Dexamethasone Sodium Phosphate, Beclomethasone Dipropionate, Mometasone Furoate,
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Methylcobalamine, Ofloxacin, Levofloxacin, Quinon Sulphate, Cloxacillin Sodium, Oxacillin Sodium,
Di Cloxacillin Sodium, Flucoxacillin Sodium.
New products Ethoxylates, Metformin Hydrochloride, and additional Methylcobalamine that falls
in Schedule 5(f) are planned to be manufactured and hence the application for EC is being done.
RLG Group began its journey in 1974, when the company was established and formed by Sh. Ram
Lal Goyal as a Plasticizer manufacturing company. Today, the company has grown into a large &
dynamic business house, which currently occupies a leading position in the field of Chemical
Manufacturing, Pharmaceutical’s Manufacturing, Power Plant, Marketing & Exports in the Domestic
as well as the International Market. The corporation also includes hard work & dedication by Mr.
Raman Goyal, and Mr. Rahul Goyal.
As a global manufacturer of pharmaceuticals, chemicals & power the vision and leadership of those
at the helm is critical to success. The team of approx. 800 people (as counted in the year 2015),
comprises of skilled and experienced professionals, who are technically sound and enterprising.
Foreseeing the standards that would be expected for manufacturing of world class quality, they
implement the same ahead of time. It is because of this focused dedication and hard work that RLG
had accounted total revenue of 60 Million Dollars in the year 2014-15.
The team in the organization has been carefully handpicked to provide right mix of diverse skills
that complement each other. Under the guidance of RLG’ management, the technical team and
support personnel have achieved exceptional levels of productivity and success in product
development, quality control, quality assurance and all aspects of business and operations.
The Corporate Headquarters at New Delhi, India, houses capable staff that is thoroughly dedicated
in understanding the requirements of RLG’s partners and provides realistic customer solutions.
With this balanced mix of young dynamism and experienced perspective, the company has unfurled
its flag across the globe and is doggedly stepping into new territories, widening the customer across
the globe.
Over a period of years, RLG has grown as a company and achieved greater heights. Today, the
business has 9 state-of-the-art manufacturing facilities which includes chemical manufacturing
units for production of Acetic Anhydride, Monochloro Acetic Acid, Acetanilide Flakes, Power
Alcohol, Aniline Oil, and Nitro Benzene.
The group has around 50% market share of total production of Acetic Anhydride in India and is one
of the top 10 manufacturers of Acetanilide Flakes in the world.
The group has a combined Cycle Power Plant of 225 MW at Kashipur is the 1st Gas Based power
Plant of Uttrakhand is one of the leading power suppliers to Uttrakhand government, the power
plant cost about Rs. 850.00 cr.
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1.4 Nature and Size of the Project
The Products fall under Project activity 5(f), Category A as per NGT Order dated 23.08.2019 in
the matter of O.A.No.1038/2018-Reg GIDC Nandesari & PCCI Estate, Di. Vadodara. The details
of proposed products are given in Table – 1.1.
TABLE 1.1 PRODUCT DETAILS
Sr. no.
Name of the Products CAS no. /
CI no.
Quantity MT/Month* End-use of the
products Existing (Products)
Proposed (Products)
1 CIFIXIME TRIHYDRATE or 79350-37-1 10 0 Used for
manufacturing of Antibiotic
drug formulation.
2 CEFUROXIME AXETIL or 64544-07-6 3 CEFPODOXIME PROXETIL or 87239-81-4
4 AMPICILIN or 69-53-4 20 0
5 AMOXICILLIN TRYDRYDATE or
61336-70-7 20 0
6 CLOBETASOLE PROPIONATE or
25122-46-7 0.5 0
Used for manufacturing of Steroid drug
formulation.
7 BETAMETHASONE DIPROPIONATE or
5593-20-4 0.5 0
8 BETAMETHASONE VALERATE or
2152-44-5 0.5 0
9 BETAMETHASONE SODIUM PHOSPHATE or
151-73-5 0.5 0
10 DEXAMETHASONE SODIUM PHOSPHATE or
2392-39-4 0.5 0
11 BECLOMETHASONE DIPROPIONTE
4419-39-0 0.5 0
12 MOMETASONE FUROATE or 105102-22-
5 0.5 0
13 METHYLCOBALAMINE or 13422-55-4 0.5 0.5
Used for manufacturing of vitamin B-12
formulation. 14 OFLOXACIN or 82419-36-1 20 0
Used for manufacturing
of Antibiotic drug
formulation.
15 LEVOFLOXACIN or 100986-85-
4 20 0
16 QUINON SULPHATE or 6119-70-6 20 0 17 CLOXACILLIN SODIUM or 7081-44-9 20 0 18 OXACILLIN SODIUM or 1173-88-2 20 0 19 DI CLOXACILLIN SODIUM or 7081-44-9 20 0 20 FLUCOXACILLIN SODIUM or 1847-24-1 20 0 21 ETHOXYLATES A POLYETHYLENE GLYCOL or 25322-68-3 0
1000
Manufacturing in agro
emulsifier, cosmetics,
soap, detergent,
textile
B HYDROGENATED CASTOR OIL or
8001-78-3 0
C CASTOR OIL ETHOXYLATES or
61791-12-6 0
D NONYL PHENOL ETHOXYLATES or
68412-53-3 0
E OCTYL PHENOL ETHOXYLATES or
68987-90-6 0
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F CARD PHENOL ETHOXYLATES or
37330-39-5 0
G STYRUNATED PHENOL ETHOXYLATES or
61788-44-1 0
H LAURYL ALCOHOL ETHOXYLATES or
68439-50-9 0
I TRIDECYL ALCOHOL ETHOXYLATES or
24938-91-8 0
J CESTOSTYRYL ALCOHOL ETHOXYLATES or
68439-49-6 0
K TALLOW ALCOHOL ETHOXYLATES or
37335-03-8 0
L STEARYL AMINE ETHOXYLATES or
26635-92-7 0
M COCO AMINE ETHOXYLATES or
61791-14-8 0
N OLEYL AMINE ETHOXYLATES or
90367-28-5 0
O POLY SORBATE ETHOXYLATES or
9005-64-5 0
P STEARIC ACID ETHOXYLATES or
9009-90-9 0
22 METFORMIN HYDROCHLORIDE
1115-70-4 0 500
Used for manufacturing
of diabetic drug
formulation. Total 20 1500.5
1.5 Project Cost
The Existing: Rs.4.0 Crore, Proposed: Rs.4.0 Crore, Total: Rs. 8.0 Crore. Gujarat Dyestuff Industries
(Pharma Unit). shall spend Approximately Rs. 50 Lac for Existing Products & Rs. 109 Lac for
proposed Product as capital expenditure on environmental management. With a total of 159 lac.
The recurring cost could be Approximately Rs. 15.5 Lac per annum for Existing Products & Rs. 96.5
lac for proposed Product. With a total of 112 lac/annum.
1.6 Site Location
M/s. Gujarat Dyestuff Industries (Pharma Unit) located at Plot No. 133/4, 133/5, 133/6, GIDC
Nandesari, Dist: Vadodara-391340. State: Gujarat, India. Vadodara district lies in the Eastern part
of the Gujarat.
Other locational details are as follows:
The site is located:
• The site is located Approximately 14.0 km in North West of Vadodara city.
• The site is located Approximately 14.0 km in North West of Vadodara city.
• Approximately 106 km South East of Ahmedabad.
• Nandesari Railway Station 1.8 Km towards N.
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• Vadodara Railway Station – 13 Km towards SE.
• Vadodara Airport – 15 Km towards SE approximately.
Geographical Location & Area of the Premises are displayed below
• 22°24'6.96"N, 73° 5'50.04"E
• 22°24'4.98"N, 73° 5'54.30"E
• 22°24'0.30"N, 73° 5'49.80"E
• 22°24'4.32"N, 73° 5'46.50"E
Elevation above Mean Sea Level: Approximately 35.5 meters.
Map 1.1 shows location of project site on India, Gujarat State map
Map 1.2 shows location of the unit in GIDC Map.
Map 1.3 shows location of the unit in satellite imagery.
Gujarat Dyestuff Industries (Pharma Unit) Chapter 1 Introduction
Rapid Environmental Impact Assessment Report 35
MAP 1.1 PROJECT LOCATION ON INDIA/GUJARAT MAP
Gujarat Dyestuff Industries (Pharma Unit) Chapter 1 Introduction
Rapid Environmental Impact Assessment Report 36
MAP 1.2 PROJECT LOCATION ON NANDESARI GIDC MAP
Gujarat Dyestuff Industries (Pharma Unit) Chapter 1 Introduction
Rapid Environmental Impact Assessment Report 37
MAP 1.3 PROJECT LOCATION ON GOOGLE IMAGE
Gujarat Dyestuff Industries (Pharma Unit) Chapter 1 Introduction
Rapid Environmental Impact Assessment Report 38
1.7 Indian Policies Requiring REIA
Environmental Impact Assessment Report has been prepared for obtaining Environmental
Clearance for M/s. Gujarat Dyestuff Industries (Pharma Unit). This is a “Existing Unit”. This is an
existing unit into manufacturing of Bulk Drugs such as Cifixime Trihydrate, Cefuroxime Axetil,
Cefpodoxime Proxetil, Ampicilin, Amoxicillin Trydrydate, Clobetasole Propionate, Betamethasone
Dipropionate, Betamethasone Valerate, Betamethasone Sodium Phosphate, Dexamethasone Sodium
Phosphate, Beclomethasone Dipropionate, Mometasone Furoate, Methylcobalamine, Ofloxacin,
Levofloxacin, Quinon Sulphate, Cloxacillin Sodium, Oxacillin Sodium, Di Cloxacillin Sodium,
Flucoxacillin Sodium.
New products Ethoxylates, Metformin Hydrochloride, and additional Methylcobalamine that falls in
Schedule 5(f) are planned to be manufactured and hence the application for EC is being done.
The site is located at Plot No. 133/4, 133/5, 133/6, GIDC Nandesari, Dist: Vadodara-391340., State:
Gujarat, India. The products fall under EIA Notification issued in September – 2006.
1.8 The REIA Cycle & Procedures
The general steps of the REIA process comprises of the following phases:
• Screening
• Scoping and consideration of alternatives (ToR)
• Baseline data collection
• Impact prediction
• Assessment of alternatives, delineation of mitigation measures and environmental impact
statement
• Environment Management Plan
• Decision making
• Monitoring the clearance conditions
1.9 Scope of the EIA Study
The project proponent has made an application in Form-I to the State Environmental Appraisal
Committee – Gandhinagar for seeking comprehensive Terms of Reference for addressing relevant
environmental concerns for the preparation of an Environmental Impact Assessment (EIA) Report
and Environmental Management Plan (EMP) in respect of the proposed expansion for Manufacture
of bulk drug Metformin Hydrochloride & Ethoxylates. Subsequently, our proposal was duly
considered by the Expert Committee in its 155th Meeting dated 28th December 2018. Sr. No 4 and
based on the discussion and details submitted, the committee has worked out the TORs for proposed
project. The project proponent has received the terms of reference vide letter vide the letter No:
Gujarat Dyestuff Industries (Pharma Unit) Chapter 1 Introduction
Rapid Environmental Impact Assessment Report 39
SEIAA/GUJ/TOR/5(f)/81/2019 Dated: 10th January 2019. TOR Letter is given as Annexure-1. TOR
with its compliance is given above on page no. 17-27.
1.10 Applicable Environmental Regulations & Standards
With respect to prevention and control of environmental pollution, the following Acts and Rules of
MoEFCC govern the proposed project:
• EIA Notification No. 1533(E) dtd. 14th September 2007 and its amendments.
• Water (Prevention and Control of Pollution) Act, 1974 as amended in 1978 and 1988:
• Air (Prevention and Control of Pollution) Act, 1981 as amended in 1987:
• Environment (Protection) Act, 1986 amended 1991 and Environment (Protection) rules,
1986 and amendments thereafter
• Hazardous & Other Waste (Management & Trans boundary Movement) Rules’2016
• The Noise Pollution (Regulation and Control) Rules, 2000 and as amended in 22.11.2000.
1.11 Structure of EIA Report
The structure of the EIA report has been made as per the requirements of Environmental Impact
Assessment (EIA) Notification 2006 (S. O. 1533).
The report consists of the following Chapters.
Executive Summary
• Chapter 1 Introduction
• Chapter 2 Project Description
• Chapter 3 Description of the Environment
• Chapter 4 Anticipated Environmental Impacts and Mitigation Measures
• Chapter 5 Analysis of Alternatives (Technology/site)
• Chapter 6 Environmental Monitoring Programme
• Chapter 7 Risk Assessment On/Off Site Emergency Plan and occupational health & safety
• Chapter 8 Project Benefits
• Chapter 9 Environmental Cost Benefit Analysis
• Chapter 10 Environmental Management Plan (EMP)
• Chapter 11 Summary and Conclusion
• Chapter 12 Disclosure of Consultant
Gujarat Dyestuff Industries (Pharma Unit) Chapter 2 Project Description
Rapid Environmental Impact Assessment Report 40
CHAPTER – 2: PROJECT DESCRIPTION
2.1 Type of Project & Capacity
M/s. Gujarat Dyestuff Industries (Pharma Unit). located at Plot No. 133/4, 133/5, 133/6, GIDC
Nandesari, Dist: Vadodara-391340., Gujarat.
This is an existing unit into manufacturing of Bulk Drugs such as Cifixime Trihydrate, Cefuroxime
Axetil, Cefpodoxime Proxetil, Ampicilin, Amoxicillin Trydrydate, Clobetasole Propionate,
Betamethasone Dipropionate, Betamethasone Valerate, Betamethasone Sodium Phosphate,
Dexamethasone Sodium Phosphate, Beclomethasone Dipropionate, Mometasone Furoate,
Methylcobalamine, Ofloxacin, Levofloxacin, Quinon Sulphate, Cloxacillin Sodium, Oxacillin Sodium,
Di Cloxacillin Sodium, Flucoxacillin Sodium.
New products Ethoxylates, Metformin Hydrochloride, and additional Methylcobalamine that falls in
Schedule 5(f) are planned to be manufactured and hence the application for EC is being done.
2.2 Need for REIA
Every anthropogenic activity has some impact on the environment. More often it is harmful to the
environment than benign. However, mankind as it is developed today cannot live without taking up
these activities for his food, security and other needs. Consequently, there is a need to harmonize
developmental activities with the environmental concerns. Environmental impact assessment
(REIA) is one of the tools available with the planners to achieve the above-mentioned goal.
It is desirable to ensure that the development options under consideration are sustainable. In doing
so, environmental consequences must be characterized early in the project cycle and accounted for
in the project design.
The objective of REIA is to foresee the potential environmental problems that would arise out of a
proposed development and address them in the project's planning and design stage. The REIA
process should then allow for the communication of this information to:
• The project proponent.
• The regulatory agencies; and,
• All stakeholders and interested groups.
REIA integrates the environmental concerns in the developmental activities right at the time of
initiating for preparing the feasibility report. In doing so it can facilitate the integration of
environmental concerns and mitigation measures in project development. REIA can often prevent
future liabilities or expensive alterations in project design.
Gujarat Dyestuff Industries (Pharma Unit) Chapter 2 Project Description
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2.3 Cost of the Project
TABLE 2.1 BREAK-UP OF PROJECT COST
Particulars Amount in INR (crore) Existing
Amount in INR (crore)
Proposed
Amount in INR (crore)
Total Land 1.0 - 1.0
Factory Building 0.50 0.50 1.0 Plant & Machineries 1.0 2.50 3.50
Other Assets 1.50 1.00 2.50 Total 4.0 4.0 8.0
2.4 Project Location & Surrounding Area
The topography of the land is flat. The site falls within the industrial area of GIDC Nandesari. The
main activities in this area are Industrial. The site lies in GIDC Nandesari, Vadodara. The location of
the project has been shown in Map 1.1 & 1.2.
The site is located Approximately 14.0 km in North West of Vadodara city.
Geographical Location & Area of the Premises are displayed below
o 22°24'6.96"N, 73° 5'50.04"E
o 22°24'4.98"N, 73° 5'54.30"E
o 22°24'0.30"N, 73° 5'49.80"E
o 22°24'4.32"N, 73° 5'46.50"E
Elevation above Mean Sea Level: Approximately 35.5 meters.
The total area of the site Plot No. 133/4, 133/5, 133/6 is 3691.10 m2 (0.36911 Ha).
2.5 Approach to Site
• The site is well connected with NH8. The site comes under Ta. Vadodara.
• Road: Site is 4km aerial distance away from NH-8. Via NH-8 site is well connected to
Bharuch, Surat, Mumbai, Vadodara, Ahmedabad.
• RAIL: The nearest railway station is Vadodara Junction, Nandesari Railway Station 1.8Km
towards N, Vadodara Railway Station – 13 Km towards SE. . Western Railway Connects from
Mumbai-Surat-Bharuch-Vadodara-Godhra-Ratlam-Kota-Delhi.
• AIRPORT: The nearest airport is Vadodara which is in approximately 15 Km (Aerial
Distance). Regular flights from Delhi and Mumbai are available.
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MAP 2.1 PROJECT SITE INDICATING THE BOUNDARY OF THE SITE
Gujarat Dyestuff Industries (Pharma Unit) Chapter 2 Project Description
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MAP 2.2 STUDY AREA
Gujarat Dyestuff Industries (Pharma Unit) Chapter 2 Project Description
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MAP 2.3 TOPOSHEET MAP OF THE STUDY AREA
Gujarat Dyestuff Industries (Pharma Unit) Chapter 2 Project Description
Rapid Environmental Impact Assessment Report 45
2.6 Plant Layout
The key plan and plant layout are shown in Figure 2.1.
FIGURE 2.1 LAYOUT PLAN
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TABLE 2.2 AREA CALCULATION FOR EXISTING & PROPOSED STRUCTURES
Sr. No. Structure Ground Floor
Area Coverage Proposed Proposed
1 Processing Area 388 470 858
2 QC Lab 87 0 87
3 Admin Building 250 0 250
4 Utility 200 50 250
5 Raw Material Storage 105 25 130
6 Tank Farm & Storage 150 0 150
8 Finished Goods Processing
Area 84 0 84
9 Finished Goods Storage 56 0 56
10 ETP Area 300 50 350
11 Green Belt Area 791 685 1476 Total Ground Floor Coverage 2411 1280 3691
Sr. No. Description of Area Existing Area Proposed Area (Sq.
m.)
Total Area
(Sq. m.) (Sq. m.)
1 Plant Facilities 720 495 1215
2 Utilities & Storage area 350 50 400
3 Other Building Area (Road &
Parking) 250 0 250
4 ETP Area 300 50 350
5 Green Belt 791 685 1476 Total 2411 1280 3691
2.7 Magnitude of the Project
2.7.1 Details of Products
The proposed products to be manufactured are listed in Table 2.3 with their respective capacities.
TABLE 2.3 PRODUCT PROFILE
The New Product falls under Project activity5(f), Category A as per NGT Order dtd 23.08.2019 in the matter of O.A.No.1038/2018-Reg GIDC Nandesari & PCCI Estate, Di. Vadodara
Sr. no.
Name of the Products CAS no. /
CI no.
Quantity MT/Month* End-use of the
products Existing (Products)
Proposed (Products)
1 CIFIXIME TRIHYDRATE or 79350-37-1 10 0 Used for
manufacturing of Antibiotic
drug formulation.
2 CEFUROXIME AXETIL or 64544-07-6 3 CEFPODOXIME PROXETIL or 87239-81-4
4 AMPICILIN or 69-53-4 20 0
5 AMOXICILLIN TRYDRYDATE
or 61336-70-7 20 0
6 CLOBETASOLE PROPIONATE
or 25122-46-7 0.5 0
Used for manufacturing of Steroid drug
formulation. 7
BETAMETHASONE DIPROPIONATE or
5593-20-4 0.5 0
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Sr. no.
Name of the Products CAS no. /
CI no.
Quantity MT/Month* End-use of the
products Existing (Products)
Proposed (Products)
8 BETAMETHASONE
VALERATE or 2152-44-5 0.5 0
9 BETAMETHASONE SODIUM
PHOSPHATE or 151-73-5 0.5 0
10 DEXAMETHASONE SODIUM
PHOSPHATE or 2392-39-4 0.5 0
11 BECLOMETHASONE
DIPROPIONTE 4419-39-0 0.5 0
12 MOMETASONE FUROATE or 105102-22-
5 0.5 0
13 METHYLCOBALAMINE or 13422-55-4 0.5 0.5
Used for manufacturing of vitamin B-12
formulation. 14 OFLOXACIN or 82419-36-1 20 0
Used for manufacturing
of Antibiotic drug
formulation.
15 LEVOFLOXACIN or 100986-85-
4 20 0
16 QUINON SULPHATE or 6119-70-6 20 0 17 CLOXACILLIN SODIUM or 7081-44-9 20 0 18 OXACILLIN SODIUM or 1173-88-2 20 0 19 DI CLOXACILLIN SODIUM or 7081-44-9 20 0 20 FLUCOXACILLIN SODIUM or 1847-24-1 20 0 21 ETHOXYLATES A POLYETHYLENE GLYCOL or 25322-68-3 0
1000
Manufacturing in agro
emulsifier, cosmetics,
soap, detergent,
textile
B HYDROGENATED CASTOR
OIL or 8001-78-3 0
C CASTOR OIL ETHOXYLATES
or 61791-12-6 0
D NONYL PHENOL
ETHOXYLATES or 68412-53-3 0
E OCTYL PHENOL
ETHOXYLATES or 68987-90-6 0
F CARD PHENOL
ETHOXYLATES or 37330-39-5 0
G STYRUNATED PHENOL
ETHOXYLATES or 61788-44-1 0
H LAURYL ALCOHOL ETHOXYLATES or
68439-50-9 0
I TRIDECYL ALCOHOL
ETHOXYLATES or 24938-91-8 0
J CESTOSTYRYL ALCOHOL
ETHOXYLATES or 68439-49-6 0
K TALLOW ALCOHOL ETHOXYLATES or
37335-03-8 0
L STEARYL AMINE ETHOXYLATES or
26635-92-7 0
M COCO AMINE ETHOXYLATES
or 61791-14-8 0
N OLEYL AMINE ETHOXYLATES
or 90367-28-5 0
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Sr. no.
Name of the Products CAS no. /
CI no.
Quantity MT/Month* End-use of the
products Existing (Products)
Proposed (Products)
O POLY SORBATE
ETHOXYLATES or 9005-64-5 0
P STEARIC ACID
ETHOXYLATES or 9009-90-9 0
22 METFORMIN
HYDROCHLORIDE 1115-70-4 0 500
Used for manufacturing of diabetic drug
formulation. Total 20 1500.5
2.8 Raw Material Storage & Handling
• Means of Transportation of raw materials and products at Gujarat Dyestuff Industries
(Pharma Unit). – Nandesari is tabulated in Table 2.4
• Physical & Chemical properties of Raw materials have been shown in table 2.5.
• A storage detail of raw materials to be used for the manufacturing and the products has been
shown in Table 2.6.
TABLE 2.4 MEANS OF TRANSPORTATION OF RAW MATERIALS AND PRODUCTS
Sr Raw
Materials
Physical & chemical
composition Source of Supply
Means of Transportation
Distance of the
supplier from
project site, km
Maximum Quantity
Transported Chemical Formula
State
Proposed
1 N-Butanol C4H10O Liquid J.K. Enterprise,
Nandesari road, Vadodara
Road transport 20 5 Ton
2 Di Ethelene
Glycol C4H10O3 Liquid
Bhagvati Petro, J.K. Enterprise,
Nandesari road, Vadodara
Road transport
30 20 Ton
3 Castor Oil C57H104O9 Liquid Hindprakash,
Laxmicastoroil Road transport
87 20 Ton
4 Lauryl Alcohol C12H26O Liquid Embry oleo,
Soofi Enterprise Road transport
456 20 Ton
5 Tridecyl Alcohol
C13H28O Liquid Ankit Polymers
Industries, Ahmedabad
Road transport 92 20 Ton
6 Ethylene
Oxide C2H4O Liquid
To be procured from GDI VS Plant that is within 100m in the common premises by pipeline linkage.
Existing
1 Butyle Acetate C6H12O2 Liquid J.K. Enterprise,
Nandesari road, Vadodara
Road transport 20 20 Ton
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Sr Raw
Materials
Physical & chemical
composition Source of Supply
Means of Transportation
Distance of the
supplier from
project site, km
Maximum Quantity
Transported Chemical Formula
State
2 Sulphuric
Acid H2SO4 Liquid
Panoli Intermediate Ind. Pvt. Ltd.,
Vadodara, Shreenathji Chemicals, Vadodara
Road transport 0.3 20 Ton
3 Acetone C3H6O Liquid Dayaram Chemical,
Anklehwar
Road transport 117 5 Ton
4 Tri ethyle
amine C6H15N Liquid
Tirupati Enterprise, Waghodia, Vadodara
Road transport 25 0.1 Ton
5 MDC CH2Cl2 Liquid Panshul
Enterprise, Vadodara
Road transport 16.7 2 Ton
6 Methanol CH3OH Liquid Gayatri
Industries, Vadodara
Road transport 28 20 Ton
7 Ethyle Acetate C4H8O2 Liquid GNFC, Baroda Road transport 21 2 Ton
8 Hydrochloric
acid HCL Liquid
Shreenathji Chemicals,
Gotri, Vadodara
Road transport 13 20 Ton
9 Formaldehyde CH2O Gas
Apurva acid & Chemicals, Padmala, Vadodara
Road transport 8.9 1 Ton
10 Di Methyle Formamide C3H7NO Liquid
J.K. Enterprise, Nandesari road,
Vadodara
Road transport 20 1 Ton
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TABLE 2.5 PHYSICAL & CHEMICAL PROPERTIES OF THE RAW MATERIAL & PRODUCTS
For Proposed Products
S. No. Raw Materials Physical & chemical composition
B. P F. P LEL UEL
TLV ppm or
mg/Nm3
LD50, mg/Kg LC50
mg/l
Sp. Gr. (water = 1) at
V.D. at
(air = 1)
Odour Threshold
ppm or mg/m3
No. of container
& size
Chemical Formula
State 0 C 0 C % 200 C 200 C
2 3 4 5 6 7 8 9 10 11 12
1. Ethoxylates
Di Ethelene Glycol VP-0.01 mm of Hg (@ 20°C)
C4H10O3 Liquid 245 138 2%-12.3%
-- LD50 – 2565 mg/kg
1.12 3.66 -- 25 MT
Hydrogenated Castor Oil VP-NA
-- Liquid >100 -- -- -- LD50 – 15000 g/kg
1 -- -- 25 MT
Castor Oil VP-NA
-- Liquid 313 230 -- -- -- 0.962 -- -- 25 MT
Nonyl Phenol VP-NA
-- Liquid -- 279 -- -- LD50 – 1410 mg/kg
1.055 1 -- 77.3 MT
Octyl Phenol VP-NA
(C8H17) C6H4OH Solid 175 -- -- -- LD50 – 4600 mg/kg
-- -- -- 74 MT
Card Phenol VP-NA
-- Liquid -- -- -- -- -- -- -- -- 84 MT
Styrunated Phenol VP-NA
C30H30O Liquid 250 182 -- -- -- 1.02 -- -- 72 MT
Lauryl Alcohol VP-0.1 hPa at 20 °C
C12H26O Solid 260 121 0.6%-4%
-- LD50 – 2.0 mg/kg
-- -- -- 25 MT
Tridecyl Alcohol VP-20.9KPa at 200 °C
C13H28O Liquid 254 130 -- -- LD50 – 4.75 mg/kg
0.846 6.9 -- 25 MT
Cetostyryl Alcohol VP-NA
-- Solid -- -- -- -- LD50 – 3200 mg/kg
0.82 9.5 -- 53 MT
Tallow Amine VP-NA
-- Liquid >200 >100 -- -- LD50 – 1950 mg/kg
0.812 >1 -- 69 MT
Stearyl Amine VP-NA
C18H39N Solid 346.8 148 -- -- LD50 – 2395 mg/kg
0.791-0.861
-- -- 88 MT
Coco Amine VP-NA
-- Liquid 180 150 -- -- LD50 – 2000 mg/kg
0.805 -- -- 112 MT
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Oleyl Amine VP-NA
C18H37N Liquid 300 154 -- -- LD50 – 1689 mg/kg
0.810 -- -- 38 MT
Sorbitian Mono Laurate VP-NA
C18H34O6 Liquid -- -- -- -- LD50 - 33600 mg/kg
-- -- -- 66 MT
Sorbitian Mono Stearate VP-NA
C24H46O6 Solid -- -- -- -- LD50 – 31000 mg/kg
1 -- -- 66 MT
Sorbitian Mono Oleate VP-NA
C24H44O6 Liquid >100 148.89 -- -- -- 1 -- -- 66 MT
Sorbitian Tri Oleate VP-NA
C60H108O8 Liquid -- -- -- -- -- 0.95 -- -- 66 MT
Stearic Acid VP-NA
C18H36O2 Solid 350 196.11 -- -- LD50 – 4640 mg/kg
0.9408 9.8 20 ppm 116 MT
CAUSTIC POTASH FLAKES KOH solid 1384 - -- LD50-273 mg/kg
2.044 -- -- 7 MT
Ethylene Oxide VP 1.4 mmHg @ 25 °C
2(CH2) O Liquid 10.7 <-18 3.% - 100%
- 72(LD) 0.87 1.49 900-1260 mg/m3
Pipeline from VS
Plant 2. Metformin
N-BUTANOL
VP-6.7 mbar @ 20 °C
CH3(CH2)2CH2OH Liquid 117.7 28.9 1.4%, 11.2%
-- 790 mg/kg 0.81 2.55 1.2 ppm 20 MT
DMA.HCL VP-NA
C2-H7-N.ClH Solid -- -- -- -- 1070 mg/kg -- -- -- 58 MT
DCDA VP-NA
C2H4N4 Solid -- -- -- 10 mg/m3
-- 1.40 -- -- 59 MT
N.A. Not Applicable, NA Not Available, VP-Vapor Pressure.
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For Existing Products
S. No.
Raw Materials Physical & chemical composition
B. P F. P LEL UEL TLV ppm or
mg/Nm3
LD50, mg/Kg LC50 mg/l
Sp. Gr. (water = 1) at
V.D. at
(air = 1)
Odour Threshold
ppm or mg/m3
No. of container
& size
Chemical Formula
State 0 C 0 C % 200 C 200 C MT / CUM
2 3 4 5 6 7 8 9 10 11 12 1. CEFIXIME
TRIHYDRATE
GCLE VP-NA
C24H23CIN2O5S Not specific
-- -- -- -- -- -- -- -- 3.4 MT
PHENOL VP-NA
C6H5OH Liquid 181.7 81 1.3%-9.5% 5 ppm -- 1.072 3.24 0.048 ppm 5.2 MT
BUTYL ACETATE
CH3COO(CH2)CH3 Liquid 126.5 37 1.7%, 7.6% -- LD50 – 17601 mg/kg
0.9 4.01 0.31 ppm 50 MT
SODIUM BI CARBONATE VP-NA
NaHCO3 Solid -- -- -- -- LD50-3360 mg/kg
2.159 -- -- 400 Kg
CARBON VP-NA
C Solid -- -- -- -- -- 1.8 -- odourless 70 Kg
EDTA VP-NA
C10H12N2Na4O8 .2H2O
Solid -- 93.3 -- LD50-2000 mg/kg
0.77 -- -- 34 Kg
SULPHURIC ACID VP-NA
H2SO4 Liquid 290 -- -- 1 ppm LC50-510 mg/m3/2H
1.84 3.4 -- 10 MT
ACETONE
VP-247 hPa (20 °C)
C3H60 Liquid 56.5 -20 2.5%-12.8%
500 ppm LC50-50, 100 mg/m3
0.79 2.0 -- 1400 Kg
MDC
VP-350 mbar @ 20°C
CH2Cl2 Liquid 39.8 -4 13%-22% 50 ppm -- 1.322 2.9 207-305ppm
8 MT
DMF
VP-0.3 kPa (@ 20°C)
HCON(CH3)2 Liquid 153 57 2.2%-15.2%
-- LD50-2800 mg/kg rat
0.949 2.51 100 ppm 2 MT
MICA ESTER VP-NA
C15H12N4O4S3 solid -- -- -- 3 LD50-15 g/kg -- -- -- 1.4 MT
ETHYL ACETATE VP-12.4 kPa (@ 20°C)
C4H802 Liquid 77 -4 2.1%-11.5%
400 ppm -- 0.902 3.04 0.006-0.686 mg/l
700 Kg
HCL VP-16 kPa (@ 20°C)
HCl Liquid 48.5 -- -- 5 ppm LC50-900 mg/kg
1.19 1.3 5 ppm 20 MT
SODIUM HYDROXIDE NaOH Solid 139 -- -- 2 -- 1.3 -- -- 260 Kg
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VP-NA METHANOL
VP- 12.3 kPa (@ 20°C) CH3OH Liquid 64.5 -- 6%, 36.5% -- LD50- 5628
mg/kg 0.7915 1.11 100 ppm 20MT x 3
Nos TRI ETHYL AMINE
VP-54 mm of Hg (@ 20°C)
(CH3CH2)3N Liquid 89.7 37.8 1.2%-8% -- LD50 – 460 mg/kg
0.73 3.48 -- 20 MT
SODIUM BROMIDE VP-NA
NaBr solid 1390 -- -- -- LD50-3500 mg/kg
3.21 -- -- 350 Kg
TRI PHENYL PHOSPHINE VP-NA
(C6H5)3P Solid -- -- -- -- -- -- -- -- 1 MT
FORMALDEHYDE VP- 2.4 kPa (@ 20°C)
HCHO Liquid 98 -- 6%, 36.5% -- LD50 – 42 mg/kg
1.08 1.03 100 ppm 20 MT
2. CEFUROXIME AXETIL 7ACA
VP-NA C10H12N2O5S Solid -- -- -- -- -- -- -- -- 1.9 MT
SIDE CHAIN -- -- -- -- -- -- -- -- -- -- -- METHANOL
VP- 12.3 kPa (@ 20°C) CH3OH liquid 64.5 16 -- -- LD50- 5628
mg/kg 0.7915 1.11 100 20MT x 3
Nos HCL
VP-16 kPa (@ 20°C) HCL Liquid 108.58 -- -- -- LD50 – 900
mg/kg 1.1 1.267 0.25 to 10 20 MT
CAUSTIC VP-NA
NaOH Liquid 1388 - -- -- -- 2.13 -- -- 300 Kg
ACETIC ACID
VP- 2.09 kPa at 25°C
C2H4O2 Liquid 56.5 -20 2.5%12.8% 500 ppm LC50-50,100mg/m3
0.79 2.0 7.7 ppm 90 Kg
ACETONE
VP-247 hPa (20 °C)
C3H6O Liquid 56.2 -9 2.6%, 12.8%
750 ppm LD50 – 5800 mg/kg
0.79 2 62 20 MT
CSIC ClSO2NCO Liquid 107 -- -- -- -- 1.624 4.88 -- 600 Kg DI METHYL
ACETAMIDE VP- 0.2 kPa (@ 20°C)
C4H9NO Liquid 163 66 1.8%-11.5%
-- 275 ppm 1H on Rat
0.942 3 21.4 ppm 2.9 MT
SODIUM CARBONATE Na2CO3 solid -- -- -- -- LD50-4090 mg/kg
2.532 -- -- 230 Kg
ACETOXY SIDE CHAIN C16H19NO5 ETHYL ACETATE
VP-12.4 kPa (@ 20°C) C4H802 Liquid 77 -4 2.1%-
11.5% 400 ppm -- 0.902 3.04 0.006-
0.686 mg/l 10 MT
SODIUM BI CARBONATE
NaHCO3 Solid -- -- -- -- LD50-3360 mg/kg
2.159 -- -- 500 Kg
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CARBON C solid -- -- -- -- -- 3.51 -- -- 50 Kg 3. CEFPODOXIME
PROXETIL
7ACA C10H12N2O5S Solid -- -- -- -- -- -- -- -- 2.3 MT SULFONALE C4H8O2S Solid 104 177 -- -- LD50 – 1.9
mg/kg -- -- -- 14 MT
SODIUM HYDROXIDE NaOH Solid 139 -- -- 2 -- 1.3 -- -- 300 Kg SODIUM CHLORIDE NaCl Solid 1413 -- -- -- LD50 – 3000
mg/kg 2.165 -- -- 1.7 MT
METHANOL VP- 12.3 kPa (@ 20°C)
CH3OH Liquid 64.5 -- 6%, 36.5% -- LD50- 5628 mg/kg
0.7915 1.11 100 ppm 20MT x 3 Nos
METHYLENE CHLORIDE
46.5 kPa (@ 20°C)
CH2Cl2 Liquid 39.7 -- 12%-19% 50 ppm LD50-1600 mg/kg Rat
1.326 2.93 214 ppm 20 MT
TRI ETHYL AMINE 54 mm of Hg (@ 20°C)
(CH3CH2)3N Liquid 89.7 37.8 1.2%-8% -- LD50 – 460 mg/kg
0.73 3.48 -- 20 MT
MAEM -- -- -- -- -- -- LD50 – 300 mg/kg
-- -- -- 1.7 MT
DI METHYL ACETAMIDE VP- 0.2
kPa (@ 20°C)
C4H9NO liquid 163 37.8 1.8% - 11.5 %
-- LD50 – 4300 mg/kg
0.9429 3 21.4 3.1 MT
SULPHURIC ACID VP-NA
H2SO4 Liquid 290 -- -- 1 ppm LC50-510 mg/m3/2H
1.84 3.4 -- 10 MT
IODO ETHYL ISO PROPYL CARBONATE
C6H11ClO3 -- 164.31 -- -- -- -- -- -- -- 1.4 MT
SODIUM THIOSULPHATE
Na2S2O3 Solid -- -- -- -- -- 1.73 -- -- 50 Kg
DBU C9H16N2 Liquid 80-83 116 1.1%-6.5% -- LD50 – 681 mg/kg
-- -- -- 550 Kg
CARBON C solid -- -- -- -- -- 3.51 -- -- 50 Kg AMMONIA SOLUTION
VP-48 kPa-20 °C -- Liquid -- -- -- -- LD50 – 350
mg/kg 0.898 -- 5-50 ppm 2.1 MT
ETHYL ACETATE VP-12.4 kPa (@ 20°C)
C4H802 Liquid 77 -4 2.1%-11.5%
400 ppm -- 0.902 3.04 0.006-0.686 mg/l
10 MT
4. AMPICILLIN FERMENTATION
PROCESS
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SODIUM CHLORIDE (LR GRADE)
NaCl Solid 1413 -- -- -- LD50 – 3000 mg/kg
2.165 -- -- 500 gr plastic bottle
COBALT CHLORIDE (LR GRADE)
-- Solid 100 -- -- -- LD50 – 766 mg/kg
1.01 0.62 -- 500 gr plastic bottle
FERROUS SULPHATE (LR GRADE)
FeSO4.xH2O Solid -- -- -- -- -- -- -- -- 500 gr glass bottle
CALCIUM CHLORIDE (LR GRADE)
CaCl2 Solid 1670 -- -- -- LD50 – 1000 mg/kg
2.15 -- -- 500 gr plastic bottle
MANGANAOUS SULPHATE (LR GRADE)
MnSO4.H2O Solid 850 -- -- -- -- 2.95 -- -- 500 gr plastic bottle
BACTERIOLOGICAL PEPTONE (LR GRADE HI
MEDIA)
-- Solid -- -- -- -- -- -- -- -- 500 gr plastic bottle
SUCROSE (SUGAR) (PHARMA GRADE)
C12H22O11 Solid -- -- -- -- LD50 – 29700 mg/kg
1.587 -- -- 50 kg bag
POTASSIUM DI HYDROGEN PHOSPHATE
(COMMERCIAL)
KH2PO4 Solid -- -- -- -- LD50 – 4640 mg/kg
2.34 -- -- 25 kg bag
AMMONIUM SULPHATE (COMMERCIAL)
(NH4)2SO4 solid -- 93.5 -- -- LD50 – 640 mg/kg
1.77 -- -- 25 kg bag
MAGNESIUM SULPHATE (COMMERCIAL)
MgSO4 Solid -- -- -- -- -- -- -- -- 25 kg bag
CALCIUM CARBONATE (COMMERCIAL)
CaCO3 solid -- -- -- -- LD50 – 6450 mg/kg
2.8 -- -- 25 kg bag
YEAST EXTRACT (COMMERCIAL)
-- Solid -- -- -- -- -- -- -- -- 25 kg bag
PPG 2000 (COMMERCIAL)
C3H8O2 Liquid 287.6 229.4 -- -- LD50 – 2.0 mg/kg
-- -- -- 50 ltr carboy
FORMALDEHYDE VP- 2.4 kPa (@ 20°C)
HCHO Liquid 98 -- 6%, 36.5% -- LD50 – 42 mg/kg
1.08 1.03 100 ppm 20 MT
SODIUM HYDROXIDE (COMMERCIAL)
NaOH Solid 139 -- -- 2 -- 1.3 -- -- 50 kg bag
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ACETIC ACID
VP- 2.09 kPa at 25°C
C2H4O2 Liquid 56.5 -20 2.5%12.8% 500 ppm LC50-50,100mg/m3
0.79 2.0 7.7 ppm 50 ltr carboy
POLYMIN -SK 25 (COMMERCIAL)
-- Liquid -- 100 -- -- LD50- 13400 mg/kg
1.06 -- -- 50 ltr carboy
GLUTARLDEHYDE 25% (COMMERCIAL)
-- Liquid 101 -- -- -- LD50 – 2500 mg/kg
1.062 1.05 0.04 ppm 220 ltr
AMMONIA SOLUTION VP-48 kPa-20 °C
-- Liquid -- -- -- -- LD50 – 350 mg/kg
0.898 -- 5-50 ppm 220 ltr drum
ACETIC ACID
VP- 2.09 kPa at 25°C
C2H4O2 Liquid 56.5 -20 2.5%12.8% 500 ppm LC50-50,100mg/m3
0.79 2.0 7.7 ppm 220 ltr drum
BEADS PREPARATION PROCESS
CHITOSAN -- solid -- -- -- -- -- 1.4 -- -- 50 ltr carboy
GELATIN -- solid 100 -- -- -- -- 1.2 -- --
BUTYL ACETATE
VP-Value: 15 kPa-
20°C
CH3COO(CH2)CH3 Liquid 126.5 37 1.7%, 7.6% -- LD50 – 17601 mg/kg
0.9 4.01 0.31 ppm 25 MT + 25 MT
VICAPOL 80 -- Liquid >100 >149.9 -- -- LD50 – 25000 mg/kg
1.06 -- -- 25 kg bag
VICAPOL 20 -- Liquid >100 >149.9 -- -- LD50 – 25000 mg/kg
1.06 -- -- 20 kl tanker
GLUTARLDEHYDE 25%
OHC(CH2)3CHO Liquid 101 -- -- -- LD50 – 2500 mg/kg
1.062 1.05 0.04 ppm 50 ltr carboy
ESTER PREPARATION PROCESS
50 ltr carboy
METHANOL VP- 12.3 kPa (@ 20°C)
CH3OH Liquid 64.5 -- 6%, 36.5% -- LD50- 5628 mg/kg
0.7915 1.11 100 ppm 20MT x 3 Nos
PHENYL GLYCIN BASE C8H9NO2 Solid -- -- -- -- -- -- -- -- 50 Kg
SULPHURIC ACID VP-NA
H2SO4 Liquid 290 -- -- 1 ppm LC50-510 mg/m3/2H
1.84 3.4 -- 10 MT
CAUSTIC LYE 47.5% NaOH Liquid 1388 - -- -- -- 2.13 -- -- 25 kg bag
Final AMPICILLIN PROCESS
20 KL tanker
6 APA C8H12N2O3S -- -- -- -- -- LD50 – 2000 mg/kg
-- -- -- 20 KL tanker
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HYFLO SUPER-CEL SiO2 Solid -- -- -- -- -- 2.3 -- -- 50 Kg
HCL 35% 16 kPa (@ 20°C)
HCL Liquid 108.58 -- -- -- LD50 – 900 mg/kg
1.1 1.267 0.25 to 10 20 MT
CAUSTIC LYE 47.5% NaOH Liquid 1388 - -- -- -- 2.13 -- -- 25 kg bag
EDTA C10H12N2Na4O8 .2H2O
Solid -- 93.3 -- LD50-2000 mg/kg
0.77 -- -- 20 kl tanker
5. AMOXICILLIN TRYDRYDATE
FERMENTATION PROCESS
SODIUM CHLORIDE (LR GRADE)
NaCl Solid 1413 -- -- -- LD50 – 3000 mg/kg
2.165 -- -- 500 gr plastic bottle
COBALT CHLORIDE (LR GRADE)
-- Solid 100 -- -- -- LD50 – 766 mg/kg
1.01 0.62 -- 500 gr plastic bottle
FERROUS SULPHATE (LR GRADE)
FeSO4.xH2O Solid -- -- -- -- -- -- -- -- 1 & 500 gr glass bottle
CALCIUM CHLORIDE (LR GRADE)
CaCl2 Solid 1670 -- -- -- LD50 – 1000 mg/kg
2.15 -- -- 5 & 500 gr plastic bottle
MANGANAOUS SULPHATE (LR
GRADE)
MnSO4.H2O Solid 850 -- -- -- -- 2.95 -- -- 4 & 500 gr plastic bottle
BACTERIOLOGICAL PEPTONE (LR GRADE
HI MEDIA)
-- Solid -- -- -- -- -- -- -- -- 0.5 & 500 gr plastic
bottle SUCROSE (SUGAR)
(PHARMA GRADE) C12H22O11 Solid -- -- -- -- LD50 – 29700
mg/kg 1.587 -- -- 96 & 50 kg
bag POTASSIUM DI
HYDROGEN PHOSPHATE
(COMMERCIAL)
KH2PO4 Solid -- -- -- -- LD50 – 4640 mg/kg
2.34 -- -- 30 & 25 kg bag
AMMONIUM SULPHATE
(COMMERCIAL)
(NH4)2SO4 solid -- 93.5 -- -- LD50 – 640 mg/kg
1.77 -- -- 13.8 & 25 kg bag
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MAGNESIUM SULPHATE
(COMMERCIAL)
MgSO4 Solid -- -- -- -- -- -- -- -- 5 & 25 kg bag
CALCIUM CARBONATE (COMMERCIAL)
CaCO3 solid -- -- -- -- LD50 – 6450 mg/kg
2.8 -- -- 1 & 25 kg bag
YEAST EXTRACT (COMMERCIAL)
-- Solid -- -- -- -- -- -- -- -- 1.5 & 25 kg bag
PPG 2000 (COMMERCIAL)
C3H8O2 Liquid 287.6 229.4 -- -- LD50 – 2.0 mg/kg
-- -- -- 1 & 50 ltr carboy
FORMALDEHYDE VP- 2.4 kPa (@ 20°C)
HCHO Liquid 98 -- 6%, 36.5% -- LD50 – 42 mg/kg
1.08 1.03 100 ppm 20 MT
SODIUM HYDROXIDE (COMMERCIAL)
NaOH Solid 139 -- -- 2 -- 1.3 -- -- 9.5 & 50 kg bag
ACETIC ACID
VP- 2.09 kPa at 25°C
C2H4O2 Liquid 56.5 -20 2.5%12.8% 500 ppm LC50-50,100mg/m3
0.79 2.0 7.7 ppm 2 & 50 ltr carboy
POLYMIN -SK 25 (COMMERCIAL)
-- Liquid -- 100 -- -- LD50- 13400 mg/kg
1.06 -- -- 2 & 50 ltr carboy
GLUTARLDEHYDE 25% (COMMERCIAL)
-- Liquid 101 -- -- -- LD50 – 2500 mg/kg
1.062 1.05 0.04 ppm 0.4 & 220 ltr drum
AMMONIA SOLUTION VP-48 kPa-20 °C
-- Liquid -- -- -- -- LD50 – 350 mg/kg
0.898 -- 5-50 ppm 0.05 & 20 kl tanker
ACETIC ACID
VP- 2.09 kPa at 25°C
C2H4O2 Liquid 56.5 -20 2.5%12.8% 500 ppm LC50-50,100mg/m3
0.79 2.0 7.7 ppm 12 & 50 ltr carboy
BEADS PREPARATION PROCESS
CHITOSAN -- solid -- -- -- -- -- 1.4 -- -- 0.48 & 25 kg bag
GELATIN -- solid 100 -- -- -- -- 1.2 -- -- 2.4 & 25 kg bag
BUTYL ACETATE CH3COO(CH2)CH3 Liquid 126.5 37 1.7%, 7.6% -- LD50 – 17601 mg/kg
0.9 4.01 0.31 ppm 25 MT + 25 MT
VICAPOL 80 -- Liquid >100 >149.9 -- -- LD50 – 25000 mg/kg
1.06 -- -- 0.12 & 50 ltr carboy
VICAPOL 20 -- Liquid >100 >149.9 -- -- LD50 – 25000 mg/kg
1.06 -- -- 0.024 & 50 ltr carboy
GULTARLDEHYDE 25% OHC(CH2)3CHO Liquid 101 -- -- -- LD50 – 2500 mg/kg
1.062 1.05 0.04 ppm 4.32 & 200 ltr drum
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ESTER PREPARATION PROCESS
METHANOL VP- 12.3 kPa (@ 20°C)
CH3OH Liquid 64.5 -- 6%, 36.5% -- LD50- 5628 mg/kg
0.7915 1.11 100 ppm 20MT x 3 Nos
PHPG-PARAHYDROXY
PHENYLGLYCINE BASE
C8H9NO3 -- -- -- -- -- -- -- -- -- 3.0 MT
SULPHURIC ACID VP-NA
H2SO4 Liquid 290 -- -- 1 ppm LC50-510 mg/m3/2H
1.84 3.4 -- 10 MT
CAUSTIC LYE 47.5% NaOH Liquid 1388 - -- -- -- 2.13 -- -- 20 kl tanker
FINAL AMOXYCILLIN PROCESS
6 APA C8H12N2O3S Solid -- -- -- -- LD50 – 2.0 mg/kg
-- -- -- 2.8 MT
HI FLOW SUPER CELL SiO2 Solid -- -- -- -- -- 2.3 -- -- 50 Kg
HCL VP-16 kPa (@ 20°C)
HCL Liquid 108.58 -- -- -- LD50 – 900 mg/kg
1.1 1.267 0.25 to 10 20 MT
CAUSTIC LYE 47.5% NaOH Liquid 1388 - -- -- -- 2.13 -- -- 20 kl tanker
EDTA C10H12N2Na4O8 .2H2O
Solid -- 93.3 -- LD50-2000 mg/kg
0.77 -- -- 50 Kg
6. CLOBETASOLE PROPIONATE
BETAMETHASONE BASE
C22H29FO5 Solid -- -- -- -- -- -- -- -- 800 & 25 kg bag
MDC
VP-350 mbar @ 20°C
CH2Cl2 Liquid 39.8 -4 13%-22% 50 ppm -- 1.322 2.9 207-305ppm
25 MT + 25 MT
TRIETHYL ORTHO PROPONATE (T.E.O.P.)
C7H8 Liquid -- -- -- -- -- -- -- -- 100 Kg
PARA TOLUENE SULPHONIC ACID
(PTSA)
-- Liquid 56.2 37.8 2.6%, 12.8%
-- LD50- 2840 mg/kg
0.82 2 62 ppm 50 Kg
ETHYL ACETATE 12.4 kPa (@ 20°C)
C4H802 Liquid 77 -4 2.1%-11.5%
400 ppm -- 0.902 3.04 0.006-0.686 mg/l
10 MT
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ACETONE
VP-247 hPa (20 °C)
C3H60 Liquid 56.5 -20 2.5%-12.8%
500 ppm LC50-50, 100 mg/m3
0.79 2.0 -- 20 MT
ORTHO PHOSPHORIC ACID (O.P.A.)
-- Liquid 158 -- -- -- -- -- -- -- 50 Kg
PYRIDINE VP-13,3 hPa at 13,2 °C
26,7 hPa at 25,0 °C
C5H5N Liquid 115 17 1.8%, 12.4%
-- 891 mg/kg -- -- -- 500 Kg
METHANSULPHONYL CHLORIDE (M.S.C.)
CH3ClO2S Liquid 161 110 -- -- LD50 – 50 mg/kg
1.4805 3 -- 100 Kg
LITHIUM CHLORIDE LiCl Solid 1360 -- -- -- LD50 – 526 mg/kg
2.07 -- -- 200 Kg
METHANOL VP- 12.3 kPa (@ 20°C)
CH3OH Liquid 64.5 -- 6%, 36.5% -- LD50- 5628 mg/kg
0.7915 1.11 100 ppm 20MT x 3 Nos
ACTIVATED CARBON C solid -- -- -- -- -- 3.51 -- -- 100 Kg
HYFLOW SUPER CELL SiO2 Solid -- -- -- -- -- 2.3 -- -- 50 Kg
DMF
VP-0.3 kPa (@ 20°C)
HCON(CH3)2 Liquid 153 -- 2.2%, 15.2%
-- LD50 – 4720 mg/kg
0.949 2.51 100 ppm 20 MT
DRY ICE CO2 Solid -109.3 F
-- -- -- -- 1.56 0.115 -- -
7. BETAMETHASONE DIPROPIONATE
BETAMETHASONE C22H29FO5 Solid -- -- -- -- -- -- -- -- 200 Kg
MDC
VP-350 mbar @ 20°C
CH2Cl2 Liquid 40 -- 13% - 23% -- LD50 – 873 mg/kg
1.33 2.93 -- 25 MT + 25 MT
TRIETHYL ORTHO PROPONATE (TEOP)
C9H20O3 Liquid 155 60 -- -- -- -- -- -- 100 Kg
PARA TOLUENE SULPHONIC ACID
(PTSA)
-- Liquid 56.2 37.8 2.6%, 12.8%
-- LD50- 2840 mg/kg
0.82 2 62 ppm 100 Kg
ACETONE
VP-247 hPa (20 °C)
C3H60 Liquid 56.5 -20 2.5%-12.8%
500 ppm LC50-50, 100 mg/m3
0.79 2.0 -- 20 MT
METHANOL VP- 12.3 kPa (@ 20°C)
CH3OH Liquid 64.5 -- 6%, 36.5% -- LD50- 5628 mg/kg
0.7915 1.11 100 ppm 20MT x 3 Nos
PYRIDINE VP-13,3 hPa at 13,2 °C
26,7 hPa at 25,0 °C
C5H5N Liquid 115 17 1.8%, 12.4%
-- 891 mg/kg -- -- -- 1.5 MT
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PROPIONIC ANHYDRIDE VP-NA
C6H10O3 Liquid 169 37.8 1.3%, 9.5% -- LD50-2360 mg/kg
-- 4.5 -- 200 Kg
ACTIVATED CARBON C solid -- -- -- -- -- 3.51 -- -- 50 Kg
HYFLOW SUPER CELL SiO2 Solid -- -- -- -- -- 2.3 -- -- 50 Kg
8. BETAMETHASONE VALERATE
BETAMETHASONE C22H29FO5 Solid -- -- -- -- -- -- -- -- 200 Kg
TRIMETHYL ORTHO VALERATE
C8H18O3 Liquid 165 41 -- -- -- -- -- -- 200 Kg
MDC
VP-350 mbar @ 20°C
CH2Cl2 Liquid 40 -- 13% - 23% -- LD50 – 873 mg/kg
1.33 2.93 -- 25 MT + 25 MT
PARA TOLUENE SULPHONIC ACID
-- Liquid 56.2 -20 -- -- LD50 – 2570 mg/kg
0.82 2 62 ppm 100 Kg
ORTHO PHOSPHORIC ACID (O.P.A.)
-- Liquid 158 -- -- -- -- -- -- -- 50 Kg
ACETONE
VP-247 hPa (20 °C)
C3H60 Liquid 56.5 -20 2.5%-12.8%
500 ppm LC50-50, 100 mg/m3
0.79 2.0 -- 20 MT
ACTIVATED CARBON C solid -- -- -- -- -- 3.51 -- -- 50 Kg
HYFLOW SUPER CELL SiO2 Solid -- -- -- -- -- 2.3 -- -- 50 Kg
9. DEXAMETHASONE SODIUM PHOSPHATE
DEXAMETHASONE C22H29FO5 Solid -- -- -- -- LD50 – 3.0 mg/kg
-- -- -- 200 Kg
TETRAHYDRO FURON C4H8O Liquid 65 -14.5 2% - 11.8%
-- LD50 – 1650 mg/kg
0.8892 2.5 20 – 50 ppm
1 MT
PYROPHOSPHORYL CHLORIDE
Cl4O3P2 Liquid 90 -- -- -- -- -- -- -- 100 Kg
CHLOROFORM VP-21.1 kPa (@ 20°C)
CHCl3 Liquid 61 -- -- -- LD50-36 mg/kg
1.484 4.36 85 ppm 50 Kg
METHANOL VP- 12.3 kPa (@ 20°C)
CH3OH Liquid 64.5 -- 6%, 36.5% -- LD50- 5628 mg/kg
0.7915 1.11 100 ppm 20MT x 3 Nos
ISOPROPYL ALCOHOL 4.4 kPa (@ 20°C)
C3H8O Liquid 82.5 37.8 2%, 12.7% -- LD50- 3600 mg/kg
0.785 2.07 22 ppm 15 & 20 kl tanker
CAUSTIC SODA FLAKES NaOH Solid 1388 - -- -- -- 2.13 -- -- 50 Kg
HYFLOW SUPER CELL SiO2 Solid -- -- -- -- -- 2.3 -- -- 50 Kg
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ACTIVATED CARBON C solid -- -- -- -- -- 3.51 -- -- 50 Kg
10. BETAMETHASONE SODIUM PHOSPHATE
BETAMETHASONE C22H29FO5 Solid -- -- -- -- -- -- -- -- 200 Kg
TETRAHYDRO FURAN 19.3 kPa (@ 20°C)
C4H8O Liquid 65 -14.5 2% - 11.8%
-- LD50 – 1650 mg/kg
0.8892 2.5 20 – 50 ppm
1 MT
PYROPHOSPHORYL CHLORIDE
Cl4O3P2 Liquid 90 -- -- -- -- -- -- -- 100 Kg
CHLOROFORM VP-21.1 kPa (@ 20°C)
CHCl3 Liquid 61 -- -- -- LD50-36 mg/kg
1.484 4.36 85 ppm 50 Kg
METHANOL VP- 12.3 kPa (@ 20°C)
CH3OH Liquid 64.5 -- 6%, 36.5% -- LD50- 5628 mg/kg
0.7915 1.11 100 ppm 20MT x 3 Nos
ISOPROPYL ALCOHOL 4.4 kPa (@ 20°C)
C3H8O Liquid 82.5 37.8 2%, 12.7% -- LD50- 3600 mg/kg
0.785 2.07 22 ppm 15 & 20 kl tanker
CAUSTIC SODA FLAKES NaOH Solid 1388 - -- -- -- 2.13 -- -- 50 Kg
HYFLOW SUPER CELL SiO2 Solid -- -- -- -- -- 2.3 -- -- 50 Kg
ACTIVATED CARBON C solid -- -- -- -- -- 3.51 -- -- 50 Kg
11. BECLOMETHASONE DIPROPIONTE
DB – XI C22H28O5 -- -- -- -- -- -- -- -- -- 200 Kg
HCL VP-16 kPa (@ 20°C)
HCL Liquid 108.58 -- -- -- LD50 – 900 mg/kg
1.1 1.267 0.25 to 10 20 MT
KOH KOH solid 1384 - -- LD50-273
mg/kg
2.044 -- -- 200 Kg
CHLOROFORM VP-21.1 kPa (@ 20°C)
CHCl3 Liquid 61 -- -- -- LD50-36 mg/kg
1.484 4.36 85 ppm 200 Kg
MDC (METHYLENE DICHLORIDE)
CH2Cl2 Liquid 39.8 -4 13%-22% 50 ppm -- 1.322 2.9 207-305ppm
1.5 MT
TEOP (TRIETHYL ORTHOPROPIONATE)
C9H20O3 Liquid 155 60 -- -- -- -- -- -- 100 Kg
PARA TOLUENE SULPHONIC ACID
(PTSA)
-- Liquid 56.2 37.8 2.6%, 12.8%
-- LD50- 2840 mg/kg
0.82 2 62 ppm 50 Kg
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O P A (ORTHO PHOSPHORIC ACID)
-- Liquid 158 -- -- -- -- -- -- -- 50 Kg
ACETONE
VP-247 hPa (20 °C)
C3H60 Liquid 56.5 -20 2.5%-12.8%
500 ppm LC50-50, 100 mg/m3
0.79 2.0 -- 20 MT
PYRIDINE VP-13,3 hPa at 13,2 °C
26,7 hPa at 25,0 °C
C5H5N Liquid 115 17 1.8%, 12.4%
-- 891 mg/kg -- -- -- 500 Kg
PROPIONIC ANHYDRIDE VP-NA
C6H10O3 Liquid 169 37.8 1.3%, 9.5% -- LD50-2360 mg/kg
-- 4.5 -- 200 Kg
ACTIVATED CARBON C solid -- -- -- -- -- 3.51 -- -- 50 Kg
HYFLOW SUPER CELL SiO2 Solid -- -- -- -- -- 2.3 -- -- 50 Kg
12. MOMETASONE FUROATE
8 D M -- Solid -- -- -- -- -- -- -- -- 200 Kg
ACETONE
VP-247 hPa (20 °C)
C3H60 Liquid 56.5 -20 2.5%-12.8%
500 ppm LC50-50, 100 mg/m3
0.79 2.0 -- 20 MT
Tri ethyl amine 0.0002
mmHg @ 21 °C
C6H15N Liquid 88.8 -14.9 8%, 12% -- LD50- 730 mg/kg
-- -- -- 20 MT
MSC CH3ClO2S Liquid 161 110 -- -- LD50 – 50 mg/kg
1.4805 3 -- 100 Kg
2-FUROYL CHLORIDE C5H3ClO2 Liquid 173 85 -- -- -- -- -- -- 50 kg
SODIUM BICARBONATE NaHCO3 Solid -- -- -- -- LD50-3360 mg/kg
2.159 -- -- 200 Kg
TETRAHYDRO FURAN 19.3 kPa (@ 20°C)
C4H8O Liquid 65 -- 2%, 11.8% -- LD50 – 1650 mg/kg
0.8892 2.5 20- 50 ppm
1 MT
ISOPROPYL ALCOHOL 4.4 kPa (@ 20°C)
C3H8O Liquid 82.5 37.8 2%, 12.7% -- LD50- 3600 mg/kg
0.785 2.07 22 ppm 8 & 20 kl tanker
HCL VP-16 kPa (@ 20°C)
HCL Liquid 108.58 -- -- -- LD50 – 900 mg/kg
1.1 1.267 0.25 to 10 20 MT
ACTIVATED CARBON C solid -- -- -- -- -- 3.51 -- -- 50 Kg
HYFLOW SUPER CELL SiO2 Solid -- -- -- -- -- 2.3 -- -- 50 Kg
13. METHYLCOBALAMINE
CYANOCOBAL AMINE (B12)
C63H88CoN14O14P Solid -- -- -- -- -- -- -- -- 500 Kg
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METHYL IODIDE
VP-544 hPa at 20 °C
CH3-I Liquid 42.5 -- -- -- LD50-76 mg/kg
2.28 4.89 -- 500 Kg
SODIUM BOROHYDRIDE
NaBH4 Solid -- -- -- -- LD50 – 160 mg/kg
1.074 1.3 -- 500 Kg
PHENOL VP-NA
C6H5OH Liquid 181.7 81 1.3%-9.5% 5 ppm -- 1.072 3.24 0.048 ppm 1.2 MT
CHLOROFORM VP-21.1 kPa (@ 20°C)
CHCl3 Liquid 61 -- -- -- LD50-36 mg/kg
1.484 4.36 85 ppm 4.4 MT
ACETONE
VP-247 hPa (20 °C)
C3H60 Liquid 56.5 -20 2.5%-12.8%
500 ppm LC50-50, 100 mg/m3
0.79 2.0 -- 20 MT
METHANOL VP- 12.3 kPa (@ 20°C)
CH3OH Liquid 64.5 -- 6%, 36.5% -- LD50- 5628 mg/kg
0.7915 1.11 100 ppm 20MT x 3 Nos
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TABLE 2.6 STORAGE DETAILS
Raw Material for Proposed Products
Sr. No. Raw Material CAS No Storage Quantity,
CUM/MT MOC
No. of Vessel / DRUMS
1 n-butanol 71-36-3 20 SS 304 1
2 Di Ethelene Glycol 111-46-6 25 SS 1
3 Castor Oil 8001-79-4 25 SS 1
4 Lauryl Alcohol 112-53-8 25 SS 1
5 Tridecyl Alcohol 112-70-9 25 SS 1
6 Ethylene Oxide 75-21-8 This will come by
Pipeline from our GDI VS plant
SS Pipeline -
Raw Material for Existing Products
Sr. No. Raw Material CAS No Storage Quantity, in
KL MOC
No. of Vessel / DRUMS
1 Butyl Acetate 123-86-4 25 MS 2 2 Sulphuric Acid 7664-93-9 10 MS 1 3 Acetone 67-64-1 20 MS 1 4 Tri ethyl amine 121-44-8 20 MS 1 5 MDC 75-09-2 25 MS 2 6 Methanol 67-56-1 20 MS 3 7 Ethyl Acetate 141-78-6 10 MS 1 8 HCL 7647-01-0 20 HDPE 1 9 Formaldehyde 50-00-0 20 SS 1
10 Di Methyl Formamide 68-12-2 20 MS 1
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2.9 Solvent Recovery
Spent solvent generated from the process - Captive In-house Recovery.
Existing Solvents: Methanol, Acetone, Chloroform etc.
Proposed Solvents: n-butanol,
Solvent recovery plant existing at site and % recovery is minimum 95%.
Name of Solvents
Total Solvent Input
Quantity of Solvent Recovered
Quantity of Solvent Loss
Solvent Recovery
Solvent Loss
Kg/Month Kg/Month Kg/Month % % Methanol 10843 10512 331 96.94 3.06 Acetone 200 191 9 95.5 4.5
Chloroform 9800 9486 314 96.79 3.20
*Note: Per Kg/Month Basis
Proposed Solvent Recovery:
Name of Solvents
Total Solvent Input
Quantity of Solvent Recovered
Quantity of Solvent Loss
Solvent Recovery
Solvent Loss
Kg/Month Kg/Month Kg/Month % % n-Butanol 350000 332000 18000 95 5
*Note: Per Kg/Month Basis
A highly efficient and full fledge solvent recovery system is installed to recover maximum possible
solvent and will be reused back in process. Detailed process is as described below:
For the efficient solvent recovery system, chilled water circulation jacketed, chilled water traps will
be installed on the vent for arresting any escape of vapors from the reaction and distillation unit.
The reactors will be connected to water condenser system. The receiver will also be jacketed with
circulation of water. The recovered solvents will then be stored and reused. Proper planning and
maintenance will enable to have an efficient solvent recovery from the system. The recovery
efficiency of every solvent used is approximately 95%.
Spent Solvent storage tanks are as follows
Name of Solvents Tank Volume No of Tanks MOC Methanol 5 MT 01 MS Acetone 5 MT 01 MS
Chloroform 5 MT 01 MS Mix Solvent 5 MT 01 MS
n-Butanol (Proposed) 10 MT 01 MS
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2.10 Methodology for ZLD
2.10.1 Details of UF-RO Plant
Ultra-Filtration followed by RO Plant to be provided for recovery of the Treated Effluent for reuse. RO Plant is designed for recovery of 70% however considering ETP RO and ageing of the membranes, and worst-case scenario recovery is displayed as 50%.
Details of UF Plant
Sr.No. Description of equipment Specs. Qty. 1 Raw water feed pump 5 m3/hr., 30 MWC 2 (1w +1s) 2 Pressure Sand Filter 5m3/hr. 01 3 Activated Carbon Filter 5m3/hr. 01 4 Bag filter housing 10 micron, 5 m3/hr. 01 5 UF skid 1,00,000 – 1,50,000 MWCO 03 6 Control panel & Control valve
with auto controls 1 set with PLC 01 set
7 Interconnection piping PVC Lot 01 set 8 Back wash pump 5 m3/hr., 30 MWC 01 9 Chemical dosing pump 0-4 LPH. 3.5 kg/cm2 03
10 Water Rota meter As per requirement 03 11 Online conductivity / TDS
Meter, As per Requirement 01
12 UF skid. MS base frame As per requirement epoxy painted 01 13 Scour Blower Twin Lobe, 2.0 HP 01
Details of RO Plant
Sr.No. Description of equipment Specs. Qty. 1 Raw water feed pump 3 m3/hr., 30 MWC 2 (1w +1s) 2 Micron filter housing 5 micron, 3 m3/hr. 01 3 Chemical dosing pump 0-4 LPH. 3.5 kg/cm2 02 4 High Pressure Pump 3 m3/hr., 150 MWC 01 5 RO Membranes AG4040C, Brine Water 2x4 + 1x4=12 6 RO Membrane Housing 600 PSI, FRP 2+1=3 7 Control panel & Control valve
with auto controls 1 set with PLC 01 set
8 Interconnection piping PVC Lot 01 set RO Cleaning pump & Tank 3 m3/hr., 30 MWC 01
9 Water Rota meter As per requirement 03 10 Online conductivity / TDS
Meter, As per Requirement 01
11 RO skid. MS base frame As per requirement epoxy painted
01
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FIGURE 2.2 UF & RO PLANT
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2.10.2 Details of MEE Plant
MEE Plant to be installed to evaporate 20KLD of RO Reject. Concentrate of the MEE Plant to be passed through Filter Press / Nutch Filter to filter the salts. Concentrate liquid will be taken back to feed for evaporation in the MEE Plant. MEE Condensate to be collected for reuse.
Details of MEE Plant
Sr. Particulars Unit Values
1 Water Evaporation Capacity Kgs/hr. 963
2 Feed Rate Kgs/hr. 1000
3 Concentrate Outlet Rate Kgs/hr. 38 4 Total Solids in Product Feed TDS % 1.50% 5 Total Solids in Concentrate Outlet TDS % 40% 6 Concentrate Outlet Temp. °C Approx. 65 to 60 7 Cooling water in let/outlet Temp. °C Approx. 32 to 40 8 Cooling Water Quantity m3 / hr. 33
9 Thermic Oil Flow
Thermic Oil Heat Require in Lacs Thermic Oil In/Out Temperature
M3/Hr. Kcal/Hr.
°C Approx.
05 1.00
175 to 165 10 Plant Power Requirement HP 40
11 Cooling Tower Power with fan HP 7.5
12 Vacuum Pump Power HP 7.5 13 Filter Press HP 2 14 Operating hours Hrs. / Day 20 15 Total Power Required HP/KWH 57 / 43
Sr. No. Particulars M.O.C. Three Stage
1 CALANDRIA: Tubes x 25.4 OD x 6.0 Mtr Long x 1.21 mm THK Tube Sheet Shell Dome
SS316Ti
SS316 SS304 SS316
03 NO
2 Vapor Separator SS316L 03 NO
3 Preheaters: Tubes Tube Sheet Shell
SS316Ti
SS316 SS304
03 NO
4 Surface Condenser: Tubes Tube Sheet Shell
SS304 SS304
CS
01 NO
5 PUMPS with Motors: Feed Pump Re circulation Pumps Transfer Pumps Condensate water Pump
SS316 SS316 SS316 SS316
01 NO 03 NO 01 NO 01 NO
6 Vacuum pumps with motor PSS316 01 NO
7 Pipes & Fittings: Process Piping Vapor Ducting Condensate Piping Non-Condensate Piping Seal Water Line Vacuum Line
SS316
CS SS304 SS304
CS CS
01 LOT
8 Thermo compressor SS304 NA 9 Balance Tank SS304 01 NO
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2.11 Technology / Process Description
The capacity along with the product manufacturing pattern has been shown in Table 2.3. The
detailed Manufacturing process has been described in this chapter along with the mass balance
diagram.
2.11.1 Mass Balance
Manufacturing Process
Manufacturing Process - Existing Products
1. CEFIXIME TRIHYDRATE
Step – I GVNE Formation
DMF is charged in the reactor, followed by HCL, GCLE, Sodium Bromide and Tri phenyl Phosphine and stirred at 35°C - 38°C for 1 hour. The Mass is cooled up to 15°C and Dichloro Methane is charged to the mass followed by formaldehyde and caustic solution and stirred for 15 minutes at 25°C - 30°C. HCL is charged to the reaction mass followed by Methanol and stirred for 1 hour at 25°C - 30°C. Dichloromethane and Methanol mixture is distilled under vacuum at 40°C. Cool the mass to 15°C and stirred for 60 minutes and material is filtered, filtered material obtained is GVNE. GVNE is dried and send for next step.
Step – II 7AVCA Formation
Phenol is charged in the Reactor followed by GVNE and stirred for 12 hrs. at 48°C. Butyl Acetate and Sodium Bi Carbonate solution is charged to the mass and stirred for 30 minutes at 35°C. Aqueous Layer is separated and Butyl Acetate layer & Phenol mixture is sent for distillation. Aqueous layer is reacted with Enzyme and transferred for carbon treatment. Solution is filtered and pH is adjusted with Sulphuric Acid to precipitate the material, after the material is precipitated, stir for 1 hour at 20°C. The material is filtered, and material obtained is 7AVCA, which is dried and send for next STEP.
Step – III – Methyl Ester Formation
Methanol is charged in the reactor followed by 7AVCA, Methyl Ester and Triethyl Amine and stirred for 2 hours at 10°C. DMW is charged to the reaction mass and pH is adjusted with HCL to precipitate the Material and stirred for 1 hour. Now the material is filtered, and material obtained is Methyl Ester, which is sent wet for next STEP.
Step – IV – Methyl Ester to Cefixime Trihydrate
DMW is charged to the reactor followed by Methyl Ester and caustic solution at 10°C and stirred for 10 minutes. pH is adjusted with HCL to precipitate the final product Cefixime Trihydrate and stirred for 60 minutes at 20°C. The material is filtered and dried.
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Step -4: PREPARATION OF CEFIXIME FROM ACMV
S
N
NH2
NO
COOMe
NH
O
N
S
COOH
CH2
O
S
N
NH2
NO
COOH
NH
O
N
S
COOH
CH2
O
SODIUM HYDROXIDE
PURIFIED WATER .3H2O
Step -3: 7-AVCA to Cefixime
(6R,7R)-7-amino-3-ethenyl-8-oxo-5-thia-1-azabicyclo[4.2.0]oct-2-ene-carboxylic acid (7-
AVCA) is condensation with 2-Mercaptobenzothiazolyl-(Z)-2-(2-aminothiazol-4-yl)-2-
(methoxycarbonyl)methoxyiminoacetate (MICA ESTER) in presence of Triethyl amine in
Tetrahydrofuran and water medium at low temperature to obtain ACMV . The ACMV
compound further hydrolysis with dilute sodium hydroxide solution in water medium at
pH 12.5-13.0 at low temperature for 5-6 min and followed by acidification up to pH 5.5
with dilute hydrochloric solution and filtered . The filtered mass and further acidification up
to pH 2.10-2.30 with dilute hydrochloric acid solution to obtain Cefixime trihydrate.
B.A.
TEA,THF
S
N
NH 2
NO
COOMe
N H
O
N
S
COOH
C H 2
O
NH 2
N
S
C H 2
O O H
O
S
N
NH 2
NO
COOMe
S
O
S
N+
Step -I
+ NaBr + HCHO + PPh3 + NaOH → + NaBr + NaCl + PPh3O + H2O
GCLE Sodium Bromide Formaldehyde TPP GVNE
486.97 102.89 30 262.29 40 464.53 102.89 58.5 278.28 18
Step -2
+ + 3H2O → + H2O + + +
GVNE Phenol AVCA Phenol Phenylacetic p-methoxy benzyl
acid alcohol
464.53 94.11 18 226.25 18 94.11 136.15 138.16
N
S
O
N
Cl
O O
O
CH3
H
O
N
S
O
N
CH2
O O
O
CH3
H
O
N
S
O
N
CH2
O O
O
CH3
H
O OH
N
S
O
NH2
CH2
O OH
OH O H
O
O
CH3 OH
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2. CEFUROXIME AXETIL:
Step – I 7ACA to Hydroxy Cefuroxime
DMW and Methanol mixture is charged in the reactor, followed by 7ACA & Caustic Solution at + 10°C and stirred for 2 hours and Acetic Acid solution is added. Prepared side chain is added to the reaction mass maintaining pH to 6.5 to 6.8 by Caustic solution. The reaction mass is stirred for 1 hour at 10°C and DMW is added to the mass and temperature is maintained to 25°C . The pH of reaction mass is adjusted to 2.8 by HCL solution and the mass is stirred for one hour and filtered. The filtered material obtained is Hydroxy Cefuroxime, which is dried and send for next step.
Step – II Hydroxy Cefuroxime to Cefuroxime Acid
Acetone is charged in the reactor, followed by Hydroxy Cefuroxime and cooled to 10°C. CSIC is added to the Reaction mass in 45 minutes at 10°C and stirred for 15 minutes. DMW is added to the reaction mass at + 5°C and stirred for 45 minutes. Intermediate is precipitated and filtered. This material is charged in the reactor containing Acetone. Caustic is added to adjust pH to 2.6 and stirred for 1 hour at 40°C. If the solution is clear than filter it and add DMW to the solution to precipitate the material. As soon as the material is precipitated, stir the mass for 1 hour at 10°C and filter. The filtered material obtained is Cefuroxime Acid which is dried and send for next step.
Step – III Cefuroxime Acid to Cefuroxime Axetil
DMAC is charged to the reactor, followed by Cefuroxime Acid, Sodium Bi Carbonate, Acetoxy side chain and the material is stirred for 4 hours at 10°C. Mixture of Ethyl Acetate and Sodium Carbonate solution is added to the reaction mass and stirred for 30 minutes at 25°C. Water layer is separated and send to E.T.P. Carbon is added to Ethyl Acetate layer and stirred for 30 minutes at 25°C. Carbon is filtered and Ethyl Acetate layer is charged to the next reactor. Ethyl Acetate is distilled under vacuum until precipitation is observed at 30°C. Methanol is charged to the reaction mass and stirred for 1 hour at 10°C. Material is filtered and obtained material is Cefuroxime Axetil, which is dried.
3. CEFPODOXIME PROXETIL:
Step – I 7AMCA to Formation
Sulfolane is charged in the reactor followed by Methanol at 25°C. The reaction mass is cooled to 15°C and BF3 gas is purged for 20 minutes. 7ACA is charged to the reaction mass at 45°C stirred for 1 hour. Chilled DMW is added to the reaction mass followed by Sodium Chloride and stirred for 40 minutes. Methylene Chloride is charged to the reaction mass and stirred for 10 minutes at 35°C. Settle the reaction mass send MDC layer for distillation. Add Tri Ethyl Amine to adjust pH to 1.0 at 15°C and stir the mass for 30 minutes. Again, adjust pH to 3.1 with Tri Ethyl Amine at 15°C and stir the mass for 40 minutes to precipitate the material. Filter the material and filtered material obtained is 7AMCA, which is sent wet for next step.
Step – II Cefpodoxime Acid Formation
DMAC is charged in the reactor followed by MDC and cooled to 15°C. MAEM is charged to the reaction mass at 15°C and pH is adjusted to 7.0 – 7.3 by Triethyl Amine and stirred for 2 hours. DMW is
Chemical Reaction:
----------->
Na2CO3
DMAc Ethyl acetate Cyclohexane
DM water Cefuroxime Axetil (M.W : 510.0) Methanol
Cefuroxime Acid (M.W : 424.4)
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added to the reaction mass and stirred for 25 minutes. The mass is settled, and organic layer is separated. The pH is adjusted to 6.0 to 6.5 of aqueous layer by Sulphuric Acid at 25°C. Adjust the pH of aqueous solution to 2.8 with Sulphuric Acid at 25°C and cool the mass to 5°C and stir for 90 minutes. Filter the material and filtered material obtained is CEFPODOXIME ACID, which is dried for next step.
Step – III Cefpodoxime Proxetil Formation
Dimethyl Acetamide is charged to the reactor at 18°C followed by Cefpodoxime Acid and the reaction mass is cooled up to -5°C. DBU is charged to the reaction mass at -5°C and stir for 30 minutes. Ethyl ISO Propyl carbonate is charged to the mixture and stirred for 50 minutes. DMW and Ethyl Acetate mixture is charged to the reaction mass and stir for 50 minutes. Charge Sodium Thiosulphate Solution to the reactor mass at 20°C and stir for 30 minutes. Give settling and separate aqueous layer to ETP. Charge carbon to the Ethyl Acetate layer and stir for 30 minutes. Filter the carbon and Ethyl Acetate is distilled under vacuum at 30°C to get precipitation. Methanol is added to the reaction mass and stirred for 30 minutes and distilled under vacuum. Add DMW to the reaction mass for clarity and filter the reaction mass. Add Ammonia solution to adjust pH to 3.0 to 4.0 for precipitation at 30°C. Cool the mass to 10°C stir for 60 minutes. Filter the material and filtered material obtained is CEFPODOXIME PROXETIL, which is dried.
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REACTION SCHEME FOR CEFPODOXIME PROXETIL
CH3OH
Methanol
1. DBU 2. DMAC 3. Cyclohexane 4. DMW 5. Eno carbon 6. Methanol
1. THF 2. DMW
3. Ethyl acetate 4. Triethylamine 5. H2SO4
CH2OCOCH3
+ BF3 Gas
AMCA
7-ACA
+
Sulfolane
CH2OCH3
CH2OCH3
AMCA
1. DMW 2. Triehtylamine 3. Sulphuric acid 4. Carbon
+
MAEM
Cefpodoxime Acid Pure
CH2OCH3
Cefpodoxime Acid
+ CH3
CH3CH -CO3 CH
I CH3
COOH
H
CH2OCH3
Cefpodoxime Acid Crude
CH2OCH3
Cefpodoxime Acid Crude
H
CH2OCH3
CH3
CH3CH -CO3 CH
COO CH3
Cefpodoxime Proxetil
+
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4. AMPICILIN:
5. AMOXICILLIN:
Process description
There are four steps to manufacture AMOXYCILLIN, i.e. Fermentation, Beads formation (Coagulation of Enzyme Sludge), Formation of Ester, Formation of AM (End Product)
Process description
Ampicillin
Phenyl Glycine Base
Sulphuric Acid
Methanol
Phenyl Glycine Ester
+
6-Amino Penicillinic Acid
Pen G Acylase (Enzyme)
HCl
NaOH
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6. CLOBETASOLE PROPIONATE
Process description
CLEANING & CHECKING OF GLASS FLASK, CHARGING OF MDC AT RT, CHARGING OF BETAMETHASONE AT RT HEAT UPTO REFLUX, ADDITION OF TEOP AT 40˚C, STIRRING, DISTILLATION OF MDC COMPLETELY. ADDITION OF ACETONE, COOLING. ADDITION OF OPA. QUINCHING IN D M WATER. CENTRIFUGING. DRYING M/C NMT 0.5%. CHARING OF PYRIDINE AT RT. ADDITION OF CLOBETA STAGE I AT RT. COOLING. ADDITION OF MSC. QUINCHING. CENTRIFUGING. DRYING. CHARGING OF DMF AT RT. CHARGING OF CLOBETA STAGE II AT RT. HEAT UPTO 60˚C. ADDITION OF LITHIUM CHLORIDE. STIRRING. QUINCHING IN DM WATER. CENTRIFUGING. DRYING. CHARGING OF MEHANOL AT RT. CHARGING OF CLOBETA CRUDE AT RT. HEAT UPTO CLEARITY. ADDITION OF ACTIVATED CARBON. FILTRATION OVER NUFLOW BED. COLLECT FILTRAE IN GLASS FLASK. CONCENTRATED UPTO THICK MASS. UNLOADING & COOLING. FILRATION. DRYING. MICRONIZATION. QUALITY CONTROL SAMPLE AS PER REQUIREMENT OF IP/BP/USP
Amoxicillin
Para Hydroxy Phenyl Glycine Base
Sulphuric Acid
Methanol
Para Hydroxy Phenyl Glycine Ester
+
6-Amino Penicillinic Acid
Pen G Acylase (Enzyme)
HCl
NaOH
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Stage: 1st
Stage: 2nd
Stage: 3rd
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Stage: 4th
7. BETAMETHASONE DIPROPIONATE
Process description
CLEANING & CHECKING OF GLASS FLASK, CHARGING OF MDC AT RT, CHARGING OF BETAMETHASONE AT RT, HEAT UPTO REFLUX, ADDITION OF TEOP AT 40˚C, ADDITION OF PTSA, STIRRING & CHECK TLC, DISTILLED OUT MDC, ADDITION OF ACETONE, COOLING, ADDITION OF OPA, STIRRING & CENTRIFUGING, DRYING M/C NMT 0.5%, CHARING OF PYRIDINE AT RT, CHARING OF STAGE I, COOLING, ADDITION PROPIONIC ANHYDRIDE, STIRRING & QUINCHING IN DM WATER, CENTRIFUGING, DRYING, CHARGING OF METHANOL, CHARGING OF STAGE II, HEAT UPTO CLEARITY, ADDITION OF ACTIVATED CARBON, FILTRATION OVER HYFLOW BED, COLLECT FILTRATE & ADDITION OF D M WATER, STIRRING & CENTRIFUGING, DRYING & MICRONIZATION
Stage: 1st
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Stage: 2nd
Stage: 3rd
8. BETAMETHASONE VALERATE
Process description
CLEANING & CHECKING OF GLASS FLASK, CHARGING OF MDC AT RT, CHARGING OF BETAMETHASONE AT RT, HEAT UPTO REFLUX, ADDITION OF TMOV, ADDITION OF PTSA, STIRRING FOR 30 MIUTES, CHECK TLC IF COMPLETED, DISTILLED OUT MDC COMPLETELY. ADDITION OF ACETONE , COOLING, ADDITION OF OPA, STIRRING, QUINCHNG IN D M WATER, STIRRING & CENTRIFUGING, DRYING M/C NMT 0.5%, CHARING OF ACETONE, CHARGING OF BETAMETHASONE VALERATE CRUDE, STIRRING, CHECK CLEARITY, ADDITION OF ACTIVATED CARBON, FILTRATION OVER HYFLOW BED, COLLECT FILTRATE & ADDITION OF D M WATER, STIRRING & CENTRIFUGING, DRYING M/C NMT 0.5%, QUALITY CONTROL SAMPLE AS PER REQUIREMENT.
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BETAMETHASONE SODIUM PHOSPHATE Process description
CLEANING & CHECKING OF GLASS FLASK, CHARGING OF THF, CHARGING OF BETAMETHASONE. COOLING, ADDITION OF PYROPHOSPHORYL CHLORIDE, STIRRING, QUINCHNG IN D M WATER, CHARGE ABOVE R/MASS IN GLASS FLASK, DISTILLATION OF THF, ADDITION OF CHLOROFORM, COOLING AND CENTRIFUGING, DRYING, CHARGING OF METHANOL AT RT, CHARING OF DEXA HYDROGEN PHOSPHATE RT, STIRRING & CHECK CLEARITY, ADDITION OF ACTIVATED CARBON, FILTRATION OVER HYFLOW BED, COLLECT FILTRATE IN GLASS FLASK, ADDITION OF CAUSTIC SODA SOLUTION, FILTRATION, DRYING M/C NMT 8.0%
Stage: 1st
Stage: 2nd
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9. DEXAMETHASONE SODIUM PHOSPHATE
PROCESS DESCRIPTION
CLEANING & CHECKING OF GLASS FLASK, CHARGING OF THF, CHARGING OF DEXAMETHASONE.
COOLING, ADDITION OF PYROPHOSPHORYL CHLORIDE, STIRRING, QUINCHNG IN D M WATER,
CHARGE ABOVE R/MASS IN GLASS FLASK, DISTILLATION OF THF, ADDITION OF CHLOROFORM,
COOLING AND CENTRIFUGING, DRYING, CHARGING OF METHANOL AT RT, CHARING OF DEXA
HYDROGEN PHOSPHATE RT, STIRRING & CHECK CLEARITY, ADDITION OF ACTIVATED CARBON,
FILTRATION OVER HYFLOW BED, COLLECT FILTRATE IN GLASS FLASK, ADDITION OF CAUSTIC
SODA SOLUTION, FILTRATION, DRYING M/C NMT 8.0%
Stage: 1st
Stage: 2nd
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10. BECLOMETHASONE DIPROPIONTE
Process description
CLEANING & CHECKING OF GLASS FLASK, CHARGING OF HCL, CHARGING OF DB-XI. STIRRING, QUINCHING DM WATER, FILTRATION, DRYING, CHARGING OF MDC AT RT, CHARGING OF BECLO STAGE – I. HEATING UPTO 40˚C, ADDITIO OF TEOP, ADDITION OF PTSA, STIRRING, DISTILALTION OF MDC, ADDITION OF ACETONE, COOLING & ADDITION OF OPA. FILTRATION, DRYING, CHARGING OF PYRIDINE CHARGING OF BECLO STAGE – II, COOLING, ADDITION OF PROPIONIC ANHYDRIDE, STIRRING & QUINCHING IN D M WATER, CENTRIFUGING, DRYING, CHARGING OF ACETONE, CHARGING OF BECLO CRUDE, HEATING & CHECK CLEARITY, ADDITION OF ACTIVATED CARBON, FILTRATION OVER HYFLOW CELL, COLLECT FILTRATE IN GLASS FLASK, CONCENTRATION UPTO THICK MASS, UNLOADING & COOLING, FILTRATION, DRYING, MICRONIZATION, QUALITY CONTROL SAMPLE
Stage: 1st
Stage: 2nd
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Stage: 3rd
Stage: 4th
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11. MOMETASONE FUROATE
Process description
CLEANING & CHECKING OF GLASS FLASK. CHARGING OF ACETONE AT RT, CHARGING OF TEA AT RT, COOLING, ADDITION OF MSC & STIRRING, HEATING, ADDITION OF LITHIUM CHLORIDE, STIRRING, QUINCHING D M WATER, STIRRING & FILTRATION, DRYING, CHARGING OF MDC, CHARGING MOMETASONE STAGE – I. CHARGING OF TEA, COOLING ADDITION OF 2-FUROYL CHLORIDE, STIRRING, ADDITION OF SODIUM BICARBONATE SOLUTION, LAYER SEPARATION, COLLECT LAYER GLASS FLASK, DISTILLATION OF MDC, ADDITION OF THF, CHARGING OF HCL (LR), COOLING, ADDITION OF THF PRODUCT, STIRRING, QUINCHING D M WATER, FILTRATION, DRYING, CHARGING OF ACETONE, CHARGING O MOMETASONE FUROATE CRUDE, HEATING, CHECK CLEARITY, ADDITION OF ACTIVATED CARBON, FILTRATION OVER HYFLOW CELL, COLLECT FILTRATE IN G. F. DISTILLATION OF ACETONE, ADDITION OF IPA, COOLING, DRYING, MICRONIZATION, QUALITY CONTROL SAMPLE AS PER IP/BP/USP
12. METHYLCOBALAMIN
Process description
Cyanocobalamin is charged in GLR with process water and allow to stir. Add cobalt chloride and isobutanol and cool. Add Sodiumboro hydrate for reduction of Cyanocobalamin. After reduction add trimethyl sulfoxonium Iodide for methylation of reduction mass. Give Phenol and Chloroform washing and finally distill out water from mass and get Methylcobalamin production in acetone. Filter the acetone and dry.
Process Flow Chart:
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Chemical Reaction:
13. OFLOXACIN
Process description
Cleaning and Checking of SSR, Charging of NMP in reactor, Charging of DMSO in same reactor, Charging of Q. Acid in same reactor, Charging of Methanol in same reactor, Heating up to 80-85 Centigrade, Check TLC, Addition of Methanol, Stirring and Cooling, Centrifuge- ML will go to Solvent Recovery/Sold to Buyer. Drying in FBD, milling of material, Packing in suitable container.
14. LEVOFLOXACIN
Process description
Cleaning and Checking of SSR, Charging of NMP in reactor, Charging of DMSO in same reactor, Charging of Levo Acid in same reactor, Charging of Methanol in same reactor, Heating up to 80-85 Centigrade, Check TLC
Addition of Methanol, Stirring and Cooling, Centrifuge- ML will go to Solvent Recovery/Sold to Buyer. Drying in FBD, milling of material, Packing in suitable container.
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15. QUINON SULPHATE
Process description
Cleaning and Checking of SSR, Charging of DM water in reactor, Charging of Quinon Sulphate Crude in same reactor, Charging of Sulphuric Acid in same reactor, Check Clarity, Addition of Activated Carbon. Filtration over Hiflow Bed. Collect filtrate in SSR, Addition of NaOH solution, Stirring and cooling for crystallization, Drying in FBD, milling of material, Packing in suitable container.
16. CLOXACILLIN SODIUM
Process description
6-APA is reacted with a solution of CMIC in Ethyl acetate and water medium to get a condensation solution. Separate the aqueous layer and wash the organic layer with Sodium bi carbonate and sodium chloride solutions for remove the impurities.
Condensate organic layer reacted with Sodium Hexonate in Ethyl acetate media to get a crystalline CLOXACILLIN in ethyl acetate media. Filter the Cloxacillin solid by centrifugation, following which the material is dried and put through a series of powder processing steps prior to final packing.
Chemical reaction:
+
Ethyl Acetate
Soda Ash Ammonia
Sodium Hexonate
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17. OXACILLIN SODIUM
Process description
6-APA is reacted with a solution of PMIC in Ethyl acetate and water medium to get a condensation solution. Separate the aqueous layer and wash the organic layer with Sodium bi carbonate and sodium chloride solutions for remove the impurities.
Condensate organic layer reacted with Sodium Hexonate in Ethyl acetate media to get a crystalline OXACILLIN in ethyl acetate media. Filter the Cloxacillin solid by centrifugation, following which the material is dried and put through a series of powder processing steps prior to final packing.
Process Flow Chart:
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Chemical Reaction:
18. DI CLOXACILLIN SODIUM
Process description
6-APA is reacted with a solution of DI CMIC in Ethyl acetate and water medium to get a condensation solution. Separate the aqueous layer and wash the organic layer with Sodium bi carbonate and sodium chloride solutions for remove the impurities.
Condensate organic layer reacted with Sodium Hexonate in Ethyl acetate media to get a crystalline DI CLOXACILLIN in ethyl acetate media. Filter the Di Cloxacillin solid by centrifugation, following which the material is dried and put through a series of powder processing steps prior to final packing.
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Chemical reaction:
+
Ethyl Acetate
Soda Ash Ammonia
Sodium Hexonate
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19. FLUCOXACILLIN SODIUM
6-APA is reacted with a solution of FLU CMIC in Ethyl acetate and water medium to get a condensation solution. Separate the aqueous layer and wash the organic layer with Sodium bi carbonate and sodium chloride solutions for remove the impurities.
Condensate organic layer reacted with Sodium Hexonate in Ethyl acetate media to get a crystalline FLU CLOXACILLIN in ethyl acetate media. Filter the Flu Cloxacillin solid by centrifugation, following which the material is dried and put through a series of powder processing steps prior to final packing.
CHEMICAL REACTION:
+
Ethyl Acetate
Soda Ash Ammonia
Sodium Hexonate
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Manufacturing Process - Proposed Products
1. POLYETHYLENE GLYCOL
Charge Di Ethelene Glycol in reactor. Add caustic potash flakes as a catalyst and start heating for
125 degree C achieve. Simultaneously in vacuum condition purge nitrogen. After that add Ethylene
Oxide in reactor as per mole calculation. And leave reactor for stirring for one hour. For
temperature reduction up to 50 degree C apply cooling water.
Chemical Reaction:
HOCH2OH + n(CH2CH2O) HO(CH2CH2O)n+1H
Where n: Average no of Oxyethylene group
2. HYDROGENATED CASTOR OIL ETHOXYLATE
Charge Hydrogenated Castor Oil in reactor. Add caustic potash flakes as a catalyst and start heating
for 125 degree C achieve. Simultaneously in vacuum condition purge nitrogen. After that add
Ethylene Oxide in reactor as per mole calculation. And leave reactor for stirring for one hour. For
temperature reduction up to 50 degree C apply cooling water.
Chemical Reaction:
C57H110O9 + n(CH2CH2O) C57H110O9(CH2CH2O)nH
Where n: No of moles of ethylene oxide
3. CASTOR OIL ETHOXYLATE
Charge Castor Oil in reactor. Add caustic potash flakes as a catalyst and start heating for 125 degree
C achieve. Simultaneously in vacuum condition purge nitrogen. After that add Ethylene Oxide in
reactor as per mole calculation. And leave reactor for stirring for one hour. For temperature
reduction up to 50 degree C apply cooling water.
Chemical Reaction:
C57H104O9 + n(CH2CH2O) C57H103O9(CH2CH2O)nH
Where n: No of moles of ethylene oxide
4. NONYL PHENOL ETHOXYLATES
Charge Nonyl Phenol in reactor. Add caustic potash flakes as a catalyst and start heating for 125
degree C achieve. Simultaneously in vacuum condition purge nitrogen. After that add Ethylene
Oxide in reactor as per mole calculation. And leave reactor for stirring for one hour. For
temperature reduction up to 50 degree C apply cooling water.
Chemical Reaction:
C15H24O + nC2H4O C9H19C6H4(OCH2)nOH
Where n: No of moles of ethylene oxide
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5. OCTYL PHENOL ETHOXYLATES
Charge Octyl Phenol in reactor. Add caustic potash flakes as a catalyst and start heating for 125
degree C achieve. Simultaneously in vacuum condition purge nitrogen. After that add Ethylene
Oxide in reactor as per mole calculation. And leave reactor for stirring for one hour. For
temperature reduction up to 50 degree C apply cooling water.
Chemical Reaction:
C12H22O + nC2H4O C9H19C5H2(OCH2CH2)n OH
Where n: No of moles of ethylene oxide
6. CARD PHENOL ETHOXYLATES
Charge Card Phenol in reactor. Add caustic potash flakes as a catalyst and start heating for 125
degree C achieve. Simultaneously in vacuum condition purge nitrogen. After that add Ethylene
Oxide in reactor as per mole calculation. And leave reactor for stirring for one hour. For
temperature reduction up to 50 degree C apply cooling water.
Chemical Reaction:
C21H30O + n(CH2CH2O) C9H19C12H10(CH2CH2O)nOH
Where n: No of moles of ethylene oxide.
7. STYRUNATED PHENOL ETHOXYLATES
Charge Styrunated Phenol in reactor. Add caustic potash flakes as a catalyst and start heating for
125 degree C achieve. Simultaneously in vacuum condition purge nitrogen. After that add Ethylene
Oxide in reactor as per mole calculation. And leave reactor for stirring for one hour. For
temperature reduction up to 50 degree C apply cooling water.
Chemical Reaction:
C30H30O + n(CH2CH2O) C9H19C21H10(CH2CH2O)nOH
Where n: No of moles of ethylene oxide
8. LAURYL ALCOHOL ETHOXYLATES
Charge Lauryl Alcohol in reactor. Add caustic potash flakes as a catalyst and start heating for 125
degree C achieve. Simultaneously in vacuum condition purge nitrogen. After that add Ethylene
Oxide in reactor as per mole calculation. And leave reactor for stirring for one hour. For
temperature reduction up to 50 degree C apply cooling water.
Chemical Reaction:
C12H26O + n(CH2CH2O) C12H25(OCH2CH2)NOH
Where n: No of moles of ethylene oxide
9. TRIDECYL ALCOHOL ETHOXYLATES
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Charge Tridecyl Alcohol in reactor. Add caustic potash flakes as a catalyst and start heating for 125
degree C achieve. Simultaneously in vacuum condition purge nitrogen. After that add Ethylene
Oxide in reactor as per mole calculation. And leave reactor for stirring for one hour. For
temperature reduction up to 50 degree C apply cooling water.
Chemical Reaction:
C13H28O + n(CH2CH2O) C13H27(CH2CH2O)nOH
Where n: No of moles of ethylene oxide
10. CESTOSTYRYL ALCOHOL ETHOXYLATES
Charge Cetostyryl Alcohol in reactor. Add caustic potash flakes as a catalyst and start heating for
125 degree C achieve. Simultaneously in vacuum condition purge nitrogen. After that add Ethylene
Oxide in reactor as per mole calculation. And leave reactor for stirring for one hour. For
temperature reduction up to 50 degree C apply cooling water.
Chemical Reaction:
C18H38O + n(CH2CH2O) C18H37(CH2CH2O)nOH
Where n: No of moles of ethylene oxide
11. TALLOW AMINE ETHOXYLATES
Charge Tallow Amine in reactor. Add caustic potash flakes as a catalyst and start heating for 125
degree C achieve. Simultaneously in vacuum condition purge nitrogen. After that add Ethylene
Oxide in reactor as per mole calculation. And leave reactor for stirring for one hour. For
temperature reduction up to 50 degree C apply cooling water.
Chemical Reaction
C18H32N + n(CH2CH2O) C18H30(C2H4O)nNH2
Where n: No of moles of ethylene oxide
12. STEARYL AMINE ETHOXYLATES
Charge Stearyl Amine in reactor. Add caustic potash flakes as a catalyst and start heating for 125
degree C achieve. Simultaneously in vacuum condition purge nitrogen. After that add Ethylene
Oxide in reactor as per mole calculation. And leave reactor for stirring for one hour. For
temperature reduction up to 50 degree C apply cooling water.
Chemical Reaction
C18H39N + n(CH2CH2O) C18H37(CH2CH2O)nNH2
Where n: No of moles of ethylene oxide
13. COCO AMINE ETHOXYLATES
Charge Coco Amine in reactor. Add caustic potash flakes as a catalyst and start heating for 125
degree C achieve. Simultaneously in vacuum condition purge nitrogen. After that add Ethylene
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Oxide in reactor as per mole calculation. And leave reactor for stirring for one hour. For
temperature reduction up to 50 degree C apply cooling water.
Chemical Reaction
R-NH2 + n(C2H4O) R(C2H4O)nNH2
Where n: No of moles of ethylene oxide
R: alkyl mainly C12-18
14. OLEYL AMINE ETHOXYLATES
Charge Oleyl Amine in reactor. Add caustic potash flakes as a catalyst and start heating for 125
degree C achieve. Simultaneously in vacuum condition purge nitrogen. After that add Ethylene
Oxide in reactor as per mole calculation. And leave reactor for stirring for one hour. For
temperature reduction up to 50 degree C apply cooling water.
Chemical Reaction
C18H37N + n(CH2CH2O) C18H35(CH2CH2O)nNH2
Where n: No of moles of ethylene oxide
15. POLY SORBATE ETHOXYLATES
Charge Sorbitian Mono Laurate in reactor. Add caustic potash flakes as a catalyst and start heating
for 125 degree C achieve. Simultaneously in vacuum condition purge nitrogen. After that add
Ethylene Oxide in reactor as per mole calculation. And leave reactor for stirring for one hour. For
temperature reduction up to 50 degree C apply cooling water.
Chemical Reaction
C18H34O6 + n(C2H4O) C18H34O6(C2H4O)n
Where n: No of moles of ethylene oxide
16. STREARIC ACID ETHOXYLATES
Charge Stearic Acid in reactor. Add caustic potash flakes as a catalyst and start heating for 125
degree C achieve. Simultaneously in vacuum condition purge nitrogen. After that add Ethylene
Oxide in reactor as per mole calculation. And leave reactor for stirring for one hour. For
temperature reduction up to 50 degree C apply cooling water.
Chemical Reaction
R-COOH + n(C2H4O) RCOO(C2H4O)nH
Where n: No of moles of ethylene oxide
R: alkyl Fatty chain
17. METFORMIN HYDROCHLORIDE:
Take pipe for charging n-butanol 300ml in clean and dry vessel under nitrogen atmosphere at 25-
35°C for 10 minutes. After charging of n-Butanol, Charge the Dicyandiamide (DCDA) 0.5075 MT in
reaction vessel then charge Di methyl amine Hydrochloride (DMA.HCL) 0.4974 MT and start
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stirring for 10 min continuously. Raise the temperature up to 80°C to 100°C and maintain that
temperature for 60 min and check for clear solution physically. Transfer the mass through
membrane filter to crystallizer up to 60 min then raise the temperature up to 100° C to 118°C for
30 min. Maintain the reaction mass & collect water azeotrpically after 120 min. Check moisture
content till it become <0.5 % after 240 min. Maintain the reaction under pressure (approx. 2 kg) &
slowly raise the temperature up to 132°C to136° C for 1200 min. Slowly cool the temperature of
reaction mass for 120 min. Further cool the temperature up to 20° C -25° C of reaction mass up to
90 min. Maintain the reaction mass with same temperature for 60 min. Centrifuge the wet cake &
slurry wash with n-butanol 200 ml up to 30 min. Spin the cake for 30 min. Again, slurry wash the
wet cake with n-butanol 200 ml up to 30 min. Unload the wet cake and Spin the cake. Dry the solid
in oven till LOD became NMT 0.5 % in 70° C - 80° C for 360 min. Unload the solid & submit the
sample for complete analysis.
Chemical Reaction
18. METHYLCOBALAMIN
Process description
Cyanocobalamin is charged in GLR with process water and allow to stir. Add cobalt chloride and
isobutanol and cool. Add Sodiumboro hydrate for reduction of Cyanocobalamin. After reduction
add trimethyl sulfoxonium Iodide for methylation of reduction mass. Give Phenol and Chloroform
washing and finally distill out water from mass and get Methylcobalamin production in acetone.
Filter the acetone and dry.
C2H4N4 + C2H8NCl C4H12N5Cl
Dicyandiamide Dimethyl amine Hydrochloride
Metformin Hydrochloride
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Process Flow Chart:
Gujarat Dyestuff Industries (Pharma Unit) Chapter 2 Project Description
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Chemical Reaction:
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Mass Balance – Existing Products
365 KG. HCL
1000 KG. METHANOL
740 KGS. WATER LAYER TO ETP
780 KG. GVNE
1500 KG. PHENOL
14600 KG. BUTYL ACETATE
10 KG. CARBON
2350 LTR. WATER
120 KG 3% SODIUM BI CARBONATE
25 KG. SULPHURIC ACID
400 KG. ACETONE
2835 KG. ML TO E.T.P. 10 KG. E.D.T.A.
200 KG. ETHYL ACETATE
125 KG. HCL
950 KG. Wet Methyl Ester
2450 KG. WATER
FLOW DIAGRAM AND MATERIAL BALANCING OF CEFIXIME TRIHYDRATE
STEP - I GVNE
STEP - II GVNE TO 7 AVCA
1000 WET GVNE
450 KG. ACETONE M.L. RECOVERY
16100 KG. BUTYL ACETATE + PHENOL
MIXTURE SEND FOR DISTILLATION
50 KG. SODIUM HYDROXIE
410 KG WET 7AVCA FOR DRYING
500 KGS MEOH ML FOR DISTILLATION
1000 KG. GCLE
600 KG. DMF
670 KG. DRY CEFIXIMETOTAL OUT : 34400 KG TOTAL IN : 34400 KG
400 KG. MICA ESTER
335 KG. 7AVCA
60 KG. HCL
950 KG. WET METHYL ESTER
100 KG. MDC LOSS
2745 KG. WATER LAYER TO ETP
1025 KG. WET CEFIXIME TRIHYDRATE
2535 KG. ML TO ETP
STEP - IV 7 METHYL ESTER TO CEFIXIME
25 KG. SODIUM HYDROXIDE
10 KG. CARBON
2800 KG. DMW
STEP - III 7 AVCA TO METHYL ESTER
1000 KG. M.D.C.
100 KG. TRI ETHYL AMINE
900 KG. MDC + 200 KG. ETHYL ACETATE
FOR RECOVERY
3610 KG MEOH + MDC + DMF FOR
RECOVERY
300 KG. MDC + MEOH DISTILLATION
LOSS
735 kg. DMW
100 KG. SOD. BROMIDE
300 KG. TPP
1333 KG. MDC
667 KG. FORMALDEHYDE
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70 KG. 10% HCL SOLUTION
1000 KG. WATER
500 KG. METHANOL
670 KG. DRY CEFUROXIME
AXETIL
FLOW DIAGRAM AND MATERIAL BALANCING OF CEFUROXIME AXETIL
STEP - I
550 KG. 7ACA
HYDROXY CEFUROXIME
600 KG.SIDE CHAIN
25.2 ACETIC ACID
TOTAL OUT : 10741 KG TOTAL IN : 10741 KG
12.5 KG. CARBON
825 KG. METHANOL
STEP - III
CEFUROXIME ACID TO AXETIL
1870 KG. ML TO E.T.P.
333 KG. ACETOXY SIDE CHAIN
145.8 KG. SODIUM BI CARBONATE
800 KG. DMW
3.O.H. CEFUROXIME ACID
880 KG. WET CEFUROXIME ACID
1200 KG. ML TO ETP
1166 KG. ETHYL ACETATE
200 KG ETHYL ACETATE VAPOUR LOSS
1792 KG. ETHYL ACETATE + DMAC FOR
RECOVERY
1333 KG. ACETONE
580 KG. CEFUROXIME ACID
900 KG. WET CEFUROXIME AXETIL833 KG. DMAC
66.7 KG. SODIUM CARBONATE
900 KG. WET 3.O.H. COMPOUND
650 KG. 3.O.H. COMPOUND
1000 KG. DMW
167.7 KG. CSIC
83.1 KG. CAUSTIC LYE
STEP - II
720 KG.METHANOL FOR DISTILLATION
1100 KG ML TO ETP
1179 KG ACETONE + WATER DISTILLED
AND SEND TO SOLVENT RECOVERY
FLOW DIAGRAM AND MATERIAL BALANCING OF CEFPODOXIME PROXETIL
STEP - I
950 KG. WET 7AMCA
7AMCA FORMATION
655 KG. 7ACA
1000 KG DMW
4000 KG.SULFOLANE
85 KG. SODIUM HYDROXIDE
200 KG. SODIUM CHLORIDE
6000 KG. MDC
9490 KG. MDC + SUFOLANE FOR
RECOVERY
300 KG. MDC VAPOUR LOSS
1200 KG ML TO ETP
730 KG. CEFPODOXIME PROXETIL WET
12575 KG.Ethyl Acetate + Methanol +
DMAC Layer for Distilaltion
300 KG. ETHYL ACETATE VAPOUR LOSS
TOTAL OUT : 33158 KG TOTAL IN : 33158 KG
1500 KG. Dimethyl Acetamide
600 KG. Ammonie Solution2800 KG. ML TO ETP
8000 KG. Ethyl Acetate
3000 KG. METHANOL
Propyl Carbonate
13 KG. Sodium Thiosulphate
150 KG. DBU
2200 KG. DMW
660 KG. DRY
CEFPODOXIME PROXETIL
CEFPODOXIME PROXETIL
STEP - II
15 KG. CARBON
STEP - III
527 KG. Cefpodoxime Acid
400 KG. Iodo Ethyl ISO
850 KG. WET 7 AMCA
2983 KG MEOH + TRI ETHYL AMINE +
DMAC MIXTURE FOR DISTILLATION
500 KG. MAEM
900 KG. DIMETHYL ACETAMIDE CEFPODOXIME ACID FORMATION
630 KG. WET CEFPODOXIME ACID
280 KG. TRIETHYL AMINE
83 KG. SULPHURIC ACID1200 KG. ML TO ETP
1200 MEOH
1000 KG. DMW
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166 KG CAUSTIC LYE 47 %
184 KG PHENYL GLYCIN ESTER
200 KG 6 APA
360 LTR DMW
70 KG DMW
FLOW DIAGRAM AND MATERIAL BALANCING OF AMPICILIN
STEP - I
217 KG PHENYL GLYCIN BASE
PHENYL GLYCINE ESTER FORMATION180 KG METHANOL
156 KG SULPHURIC ACID100 KG TO ETP
280 KGS MEOH ML FOR DISTILLATION
40 KG. DMW
744 KG REACTION MASS
379 Kg Wet PHENYL GLYCINE ESTER
936 KG REACTION MASS
0.3 KG EDTA
175 KG CAUSTIC LYE
STEP - III
744 KG REACTION MASS
160 KG HCl
30 KG DMW
STEP - II
ENZYMATIC REACTION FOR AMPICILIN
SYNTHESIS
332 KG DRY AMPICILIN
936 KG REACTION MASS
1.5 KG HYFLOW
STEP - IV
751 KG. WET AMPICILIN
CRYSTALLIZATION430 KG TO ETP
HYDROLYSIS
TOTAL OUT : 3620 KG TOTAL IN : 3620 KG
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166 KG CAUSTIC LYE 47 %
200 KG 6 APA
10 KG DMW
0.2 KG EDTA
TOTAL OUT : 2497 KG TOTAL IN : 2497KG
FLOW DIAGRAM AND MATERIAL BALANCING OF AMOXICILLIN TRIHYDRATE
STEP - I
280 Kg Wet HYROXY PHENYL GLYCINE
ESTER
HYDROXY PHENYL GLYCINE ESTER FORMATION
439 KGS MEOH ML FOR DISTILLATION180 KG METHANOL
156 KG SULPHURIC ACID
427 KG REACTION MASS
STEP - III
1.0 KG HYFLOW
STEP - IV
753 KG. WET AMOXICILLIN
CRYSTALLIZATION
588 KG REACTION MASS
10 KG TO ETP 175 KG CAUSTIC LYE
HYDROLYSIS588 KG REACTION MASS
427 KG REACTION MASS
160 KG HCl
332 KG DRY AMOXICILLIN
217 KG HYDROXY PHENYL GLYCIN BASE
217 KG HYDROXY PHENYL GLYCIN ESTER
STEP - II
ENZYMATIC REACTION FOR AMOXICILLIN
SYNTHESIS
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1200 KG MDC
85 KG TEOP
5.0 KG PTSA
600 KG ACETONE
0.83 KG ORTHOPHOSPHOEIC ACID
1000 KG METHANOL
10 KG ACTIVATED CARBON
TOTAL OUT :5758 KG TOTAL IN :5758 KG
400 KG DMW
STEP - II
200 KG WET STEP 2 110 KG DRY FROM STEP 1
STEP - III
10 KG HYFLOW
230 KG WET STEP 2
132 KG FROM STEP 2
600 KG DMF
FLOW DIAGRAM AND MATERIAL BALANCING OF CLOBETASOLE PROPIONATE
STEP - I
180 KG WET STAGE 1
1911 KGS MDC + ACETONE FOR
RECOVERY
300 KG TO ETP
100 KG DRY CLOBETASOLE
PROPIONATE
100.0 KG BETAMETHASONE BASE
450 KG DMW
300 KG PYRIDINE
60 KG METHANESULPHONYL CHLORIDE
115 KG LITHIUM CHLORIDE
450 KG DMW
720 KG TO ETP
580 DMF FOR RECOVERY
487 KG TO ETP
115 KG FROM STEP 3
STEP - IV
150 KG. WET WET CLOBETASOLE
15 KG ETHYL ACETATE
1000 KG METHANOL FOR RECOVERY
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1200 KG MDC
85 KG TEOP
5.0 KG PTSA
600 KG ACETONE
1000 KG METHANOL
5 KG ACTIVATED CARBON
180 KG WET STAGE 1
STEP - I
100 KG DRY
BETAMETHASONE DI
PROPIONATETOTAL OUT : 4730 KG TOTAL IN : 4730 KG
5 KG HYFLOW
STEP - III
140KG WET BETAMETAHSONE
DIPROPIONATE
990 KGS METHANOL FOR RECOVERY120 KG FROM STEP 2
FLOW DIAGRAM AND MATERIAL BALANCING OF BETAMETASONE DI PROPIONATE
STEP - II
330 KG WET STEP 2 110 KG DRY FROM STEP 1
150 KG PYRIDINE
100 KG PROPIONIC ANHYDRIDE630 KG TO ETP
600 KG DMW
650 KG DMW
730 KG TO ETP
1730KGS MDC FROM RECOVERY
100.0 KG BETAMETHASONE BASE
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1200 KG MDC
100 KG TEOV
5.0 KG PTSA
500 KG ACETONE
1000 KG ACETONE
10 KG ACTIVATED CARBON
10 KG HYFLOW
100 KG DRY
BETAMETHASONE
VALERATE
740 KG DMW800 KG TO ETP
120 KG FROM STEP 1
TOTAL OUT : 3790 KG TOTAL IN : 3790 KG
STEP - II
125 KG WET BETAMETHASONE
VALERATE
900 KG ACETONE FOR RECOVERY
115 KG VAPOUR LOSS
FLOW DIAGRAM AND MATERIAL BALANCING OF BETAMETASONE VALERATE
STEP - I
135 KG WET STAGE 1100.0 KG BETAMETHASONE BASE
1250 KGS MDC FROM RECOVERY
465 KG ACETONE FOR DISTILLATION
5.0 KG ORTHO PHOSPHORIC ACID
600 KG THF
80 KG PYROPHOSPHORYL CHLORIDE
10 KG CHLOROFORM
380 KG DMW
1500 KG ISO PROPYL ALCOHOL
25 KG ACTIVATED CARBON
10 KG HYFLOW
100 KG DRY BETAMETHASONE SODIUM
PHOSPHATETOTAL OUT : 3622 KG TOTAL IN : 3622 KG
STEP - II
125 KG WET BETAMETHASONE SODIUM
PHOSPHATE
115 KG FROM STEP 1
800 KG METHANOL
2327 KG IPA FOR RECOVERY
2 KG CAUSTIC
FLOW DIAGRAM AND MATERIAL BALANCING OF BETAMETHASONE SODIUM PHOSPHATE
STEP - I
170 KG WET STAGE 1
600 KGS THF FROM RECOVERY100.0 KG BETAMETHASONE BASE
400 KG TO ETP
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600 KG THF
80 KG PYROPHOSPHORYL CHLORIDE
10 KG CHLOROFORM
380 KG DMW
1500 KG ISO PROPYL ALCOHOL
25 KG ACTIVATED CARBON
10 KG HYFLOW
TOTAL OUT : 3622 KG TOTAL IN : 3622 KG
2 KG CAUSTIC
100 KG DRY DEXAMETHASONE SODIUM
PHOSPHATE
800 KG METHANOL
STEP - II
125 KG WET DEXAMETHASONE
SODIUM PHOSPHATE
115 KG FROM STEP 1
2327 KG IPA FOR RECOVERY
FLOW DIAGRAM AND MATERIAL BALANCING OF DEXAMETHASONE SODIUM PHOSPHATE
STEP - I
170 KG WET STAGE 1
100.0 KG DEXAMETHASONE BASE600 KGS THF FROM RECOVERY
400 KG TO ETP
800 KG HCl
100 KG CHLOROFORM
100 KG KOH
1000 KG ACETONE
10 KG ACTIVATED CARBON
110 KG FROM STEP 3
950 KG ACETONE FOR RECOVERY
10 KG HYFLOW
180 KG. WET WET BECLOMETHASONE
DI PROPIONATE
100 KG DRY BECLOMETHASONE DI PROPIONATETOTAL OUT : 5485 KG TOTAL IN : 5485 KG
100 KG DRY FROM STEP 1
85 KG TEOP (TRIETHYL ORTHOPROPIONATE)
STEP - III
260 KG WET STEP 2
600 KG TO ETP
300 KG PYRIDINE
100 KG DRY FROM STEP 2
100 KG PROPIONIC ANHYDRIDE
360 KG DMW
STEP - IV
5.0 KG O P A (ORTHO PHOSPHORIC ACID)
450 KG DMW
5.0 KG PTSA
500 KG ACETONE
1200 KG MDC
STEP - II
175 KG WET STEP 2
1315 KG MDC FOR RECOVERY
400 KG TO ETP
455 KG ACETONE FOR RECOVERY
FLOW DIAGRAM AND MATERIAL BALANCING OF BECLOMETHASONE DI PROPIONATE
STEP - I
195 KG WET STAGE 1
100.0 KG DB XI195 KG CHLOROFORM FOR RECOVERY
760 KG TO ETP
50 KG DMW
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600 KG ACETONE
200 KG TRI ETHYL AMINE
50 KG METHANE SULFONYL CHLORIDE
100 KG DRY MOMETASONE FUROATE
400 KG TRI ETHYL AMINE
20 KG 2-FUROYL CHLORIDE
TOTAL OUT : 5002 KG TOTAL IN : 5002 KG
160 KG WET STEP 2
772 KG IPA FOR RECOVERY 112 KG DRY FROM STEP 2
800 KG IPA
10 KG ACTIVATED CARBON
10 KG HYFLOW
500 KG THF
1500 KG HCl
200 KG DMW
STEP - III
STEP - II
175 KG WET STEP 2100 KG DRY FROM STEP 1
1775 KG TEA + THF FOR RECOVERY100 KG SODIUM BICARBONATE
870 KG TO ETP
FLOW DIAGRAM AND MATERIAL BALANCING OF MOMETASONE FUROATE
STEP - I
145 KG WET STAGE 1
855 KG ACETONE FOR RECOVERY100.0 KG 8 DM
250 KG TO ETP
300 KG DMW
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1400 KG ACETONE
220 KG METHANOL
TOTAL OUT : 5490 KG TOTAL IN : 5490 KG100 KG DRY METHYLCOBALAMIN
90 KG METHYL IODIDE
110 KG SODIUM BOROHYDRIDE
500 KG PHENOL
40 KG CHLOROFORM
210 KG DMW
100 KG DMW
STEP - II
140 KG WET METHYLCOBALAMIN
2550 KG CHLOROFORM LAYER FOR
RECOVERY
800 KG AQUOUS LAYER
1920 KG CHLOROFORM
1670 KG ACETONE FOR RECOVERY
80 KG TO ETP
FLOW DIAGRAM AND MATERIAL BALANCING OF METHYLCOBALAMIN
STEP - I
800 KG AQUOUS LAYER 100.0 KG CYANOCOBALAMIN
250 KG TO ETP
500 KG DRY OFLOXACIN
60 KG DMW
TOTAL OUT : 4620 KG TOTAL IN : 4620 KG
STEP - II
800 KG WET OFLOXACIN
1565 KG METHANOL FOR RECOVERY2155 KG REACTION MASS STEP 1
250 KG METHANOL
100 KG TO ETP
FLOW DIAGRAM AND MATERIAL BALANCING OF OFLOXACIN
STEP - I
2155 KG REACTION MASS
500 KG Q ACID (OFLOXACIN)
125 KG DMSO
1000 KG METHANOL
500 KG N-METHYL PIPERAZINE
30 KG DMW
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500 KG DRY LEVOFLOXACIN
2155 KG REACTION MASS
TOTAL OUT : 4620 KG TOTAL IN : 4620 KG
30 KG DMW
STEP - II
800 KG WET LEVOFLOXACIN
1565 KG METHANOL FOR RECOVERY2155 KG REACTION MASS STEP 1
250 KG METHANOL
100 KG TO ETP60 KG DMW
FLOW DIAGRAM AND MATERIAL BALANCING OF LEVOFLOXACIN
STEP - I
500 KG LEVO ACID
125 KG DMSO
1000 KG METHANOL
500 KG N-METHYL PIPERAZINE
90 KG DMW
TOTAL OUT : 1500 KG TOTAL IN : 1500 KG500 KG DRY QUINONE SULPHATE
27.5 KG SULPHURIC ACID
25 KG ACTIVATED CARBON
25 KG HYFLOW
100 KG DMW
STEP - II
622.5 KG WET QUINONE SULPHATE
677.5 KG CLEAR LAYER FROM STEP 1
55 KG CAUSTIC 200 KG TO ETP
FLOW DIAGRAM AND MATERIAL BALANCING OF QUINONE SULPHATE
STEP - I
500 KG QUINONE SULPHATE CRUDE
677.5 KG CLEAR LAYER
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500 KG CMIC
11.5 KG ETHYL ACETATE
500 KG LIQ AMMONIA
12.5 KG SODIUM CARBONATE
125 KG SODIUM SULPHATE
250 KG SODIUM CHLORIDE
STEP - III
1120 KG AQUOUS LAYER TO ETP
1029 KG ORAGANIC LAYER
250 KG NACL FOR RECYCLE
500 KG DMW
STEP - II
REACTION
500 KG 6 APA
TOTAL IN : 3963 KGTOTAL OUT : 3963 KG
CONDENSATION
800 KG WET DI CLOXACILLIN
449 KG TO RECOVERY
220 KG SODIUM HEXONATE
1029 KG ORGANIC LAYER FROM STEP 2
500 KG DRY CLOXACILLIN
SODIUM
FLOW DIAGRAM AND MATERIAL BALANCING OF CLOXACILLIN SODIUM
STEP - I
SODIUM 2 ETHYL HEXONATE FORMATION
50 KG 2-EHA
15 KG MIBK
15 KG MIBK FOR RECOVERY
220 KG SODIUM 2 ETHYL HEXONATE
80 KG TO ETP250 KG CAUSTIC LYE 47 %
500 KG PMIC
11.5 KG ETHYL ACETATE
500 KG LIQ AMMONIA
12.5 KG SODIUM CARBONATE
125 KG SODIUM SULPHATE
TOTAL IN : 3963 KG
500 KG DRY OXACILLIN
SODIUM
15 KG MIBK FOR RECOVERY
220 KG SODIUM 2 ETHYL HEXONATE
80 KG TO ETP
1029 KG ORAGANIC LAYER
250 KG NACL FOR RECYCLE
TOTAL OUT : 3963 KG
STEP - III
CONDENSATION
800 KG WET OXACILLIN
449 KG TO RECOVERY
220 KG SODIUM HEXONATE
STEP - II
1120 KG AQUOUS LAYER TO ETP500 KG 6 APA
250 KG SODIUM CHLORIDE
500 KG DMW
REACTION
1029 KG ORGANIC LAYER FROM STEP 2
FLOW DIAGRAM AND MATERIAL BALANCING OF OXACILLIN SODIUM
STEP - I
SODIUM 2 ETHYL HEXONATE FORMATION
50 KG 2-EHA
15 KG MIBK
250 KG CAUSTIC LYE 47 %
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500 KG DI CMIC
11.5 KG ETHYL ACETATE
500 KG LIQ AMMONIA
12.5 KG SODIUM CARBONATE
125 KG SODIUM SULPHATE
STEP - II
REACTION
1029 KG ORAGANIC LAYER STEP 2
1029 KG ORAGANIC LAYER
250 KG NACL FOR RECYCLE
TOTAL OUT : 3963 KG
1120 KG AQUOUS LAYER TO ETP
TOTAL IN : 3963 KG
STEP - III
CONDENSATION
800 KG WET DI CLOXACILLIN
449 KG TO RECOVERY
220 KG SODIUM HEXONATE
500 KG DRY DI
CLOXACILLIN SODIUM
500 KG 6 APA
250 KG SODIUM CHLORIDE
500 KG DMW
FLOW DIAGRAM AND MATERIAL BALANCING OF DI CLOXACILLIN SODIUM
STEP - I
SODIUM 2 ETHYL HEXONATE FORMATION
50 KG 2-EHA
220 KG SODIUM 2 ETHYL HEXONATE
80 KG TO ETP15 KG MIBK
250 KG CAUSTIC LYE 47 %
15 KG MIBK FOR RECOVERY
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500 KG F CMIC
11.5 KG ETHYL ACETATE
500 KG LIQ AMMONIA
12.5 KG SODIUM CARBONATE
125 KG SODIUM SULPHATE
500 KG DRY
FLUCLOXACILLIN SODIUMTOTAL OUT : 3963 KG TOTAL IN : 3963 KG
500 KG DMW
STEP - III
CONDENSATION
800 KG WET FLUCLOXACILLIN
449 KG TO RECOVERY
220 KG SODIUM HEXONATE
1029 KG ORGANIC LAYER FROM STEP 2
REACTION
1120 KG AQUOUS LAYER TO ETP500 KG 6 APA
1029 KG ORAGANIC LAYER
250 KG NACL FOR RECYCLE
250 KG SODIUM CHLORIDE
STEP - II
FLOW DIAGRAM AND MATERIAL BALANCING OF FLUCLOXACILLIN SODIUM
STEP - I
SODIUM 2 ETHYL HEXONATE FORMATION
15 KG MIBK FOR RECOVERY 50 KG 2-EHA
220 KG SODIUM 2 ETHYL HEXONATE15 KG MIBK
80 KG TO ETP250 KG CAUSTIC LYE 47 %
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Mass Balance – Proposed Products
Di Ethelene Glycol Charge
Catalyst Addition and Heating
Nitrogen Purging
Vacuum
Ethylene Oxide Condensation
Cooling
Poly Ethylene Glycol
PER KG
1 120.00
2 1.50
3 332.000
453.50
MASS BALANCE FOR POLY ETHYLENE GLYCOL
TOTAL TOTAL 453.50
*Note: Per Kg of Product Basis
Ethylene Oxide Poly Ethylene Glycol 453.5
Di Ethelene Glycol Waste Water 0
Catalyst Hazardous Waste 0
SR NO
INPUT OUTPUT
INPUT OUTPUT PER Kg
Hydrogenated
Castor OilCharge
Catalyst Addition and Heating
Nitrogen Purging
Vacuum
Ethylene Oxide Condensation
Cooling
Hydrogenated Castor
Oil Ethoxylate
PER KG
1 34.60
2 3.10
3 65.400
103.10
*Note: Per Kg of Product Basis
Ethylene Oxide Hydrogenated Castor Oil 103.1
TOTAL TOTAL 103.10
Hydrogenated Castor Oil Waste Water 0
Catalyst Hazardous Waste 0
MASS BALANCE FOR HYDROGENATED CASTOR OIL ETHOXYLATE
SR NO
INPUT OUTPUT
INPUT OUTPUT PER Kg
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Castor Oil Charge
Catalyst Addition and Heating
Nitrogen Purging
Vacuum
Ethylene Oxide Condensation
Cooling
Castor Oil Ethoxylate
PER KG
1 34.60
2 3.10
3 65.400
103.10
*Note: Per Kg of Product Basis
Ethylene Oxide Castor Oil Ethoxylates 103.1
TOTAL TOTAL 103.10
Castor Oil Waste Water 0
Catalyst Hazardous Waste 0
MASS BALANCE FOR CASTOR OIL ETHOXYLATE
SR NO
INPUT OUTPUT
INPUT OUTPUT PER Kg
Nonyl Phenol Charge
Catalyst Addition and Heating
Nitrogen Purging
Vacuum
Ethylene Oxide Condensation
Cooling
Nonyl Phenol
Ethoxylate
PER KG
1 53.22
2 0.80
3 106.460
160.48
*Note: Per Kg of Product Basis
Ethylene Oxide Nonyl Phenol Ethoxylates 160.48
TOTAL TOTAL 160.48
Nonyl Phenol Waste Water 0
Catalyst Hazardous Waste 0
MASS BALANCE FOR NONYL PHENOL ETHOXYLATES
SR NO
INPUT OUTPUT
INPUT OUTPUT PER Kg
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Octyl Phenol Charge
Catalyst Addition and Heating
Nitrogen Purging
Vacuum
Ethylene Oxide Condensation
Cooling
Octyl Phenol
Ethoxylate
PER KG
1 31.90
2 0.50
3 68.100
100.50
*Note: Per Kg of Product Basis
Ethylene Oxide Octyl Phenol Ethoxylates 100.5
TOTAL TOTAL 100.50
Octyl Phenol Waste Water 0
Catalyst Hazardous Waste 0
MASS BALANCE FOR OCTYL PHENOL ETHOXYLATES
SR NO
INPUT OUTPUT
INPUT OUTPUT PER Kg
Card Phenol Charge
Catalyst Addition and Heating
Nitrogen Purging
Vacuum
Ethylene Oxide Condensation
Cooling
Card Phenol
Ethoxylate
PER KG
1 36.20
2 0.50
3 63.800
100.50
*Note: Per Kg of Product Basis
Ethylene Oxide Card Phenol Ethoxylates 100.5
TOTAL TOTAL 100.50
Card Phenol Waste Water 0
Catalyst Hazardous Waste 0
MASS BALANCE FOR CARD PHENOL ETHOXYLATES
SR NO
INPUT OUTPUT
INPUT OUTPUT PER Kg
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Lauryl Alcohol
EthoxylatesCharge
Catalyst Addition and Heating
Nitrogen Purging
Vacuum
Ethylene Oxide Condensation
Cooling
Lauryl Alcohol
Ethoxylates
PER KG
1 38.10
2 0.60
3 61.900
100.60
*Note: Per Kg of Product Basis
Ethylene Oxide Lauryl Alcohol Ethoxylates 100.6
TOTAL TOTAL 100.60
Lauryl Alcohol Ethoxylates Waste Water 0
Catalyst Hazardous Waste 0
MASS BALANCE FOR LAURYL ALCOHOL ETHOXYLATES
SR NO
INPUT OUTPUT
INPUT OUTPUT PER Kg
Styrunated Phenol Charge
Catalyst Addition and Heating
Nitrogen Purging
Vacuum
Ethylene Oxide Condensation
Cooling
Styrunated Phenol
Ethoxylate
PER KG
1 31.25
2 1.00
3 68.750
101.00
*Note: Per Kg of Product Basis
Ethylene Oxide Styrunated Phenol Ethoxylate 101
TOTAL TOTAL 101.00
Styrunated Phenol Waste Water 0
Catalyst Hazardous Waste 0
MASS BALANCE FOR STYRUNATED PHENOL ETHOXYLATES
SR NO
INPUT OUTPUT
INPUT OUTPUT PER Kg
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Tridecyl Alcohol Charge
Catalyst Addition and Heating
Nitrogen Purging
Vacuum
Ethylene Oxide Condensation
Cooling
Tridecyl Alcohol
Ethoxylates
PER KG
1 36.20
2 0.50
3 63.800
100.50
*Note: Per Kg of Product Basis
Ethylene Oxide Tridecyl Alcohol Ethoxylates 100.5
TOTAL TOTAL 100.50
Tridecyl Alcohol Waste Water 0
Catalyst Hazardous Waste 0
MASS BALANCE FOR TRIDECYL ALCOHOL ETHOXYLATES
SR NO
INPUT OUTPUT
INPUT OUTPUT PER Kg
Cestostyryl
AlcoholCharge
Catalyst Addition and Heating
Nitrogen Purging
Vacuum
Ethylene Oxide Condensation
Cooling
Cestostyryl Alcohol
Ethoxylates
PER KG
1 23.00
2 0.50
3 77.000
100.50
*Note: Per Kg of Product Basis
Ethylene Oxide Cestostyryl Alcohol Ethoxylates 100.5
TOTAL TOTAL 100.50
Cestostyryl Alcohol Waste Water 0
Catalyst Hazardous Waste 0
MASS BALANCE FOR CESTOSTYRYL ALCOHOL ETHOXYLATES
SR NO
INPUT OUTPUT
INPUT OUTPUT PER Kg
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Tallow Amine Charge
Catalyst Addition and Heating
Nitrogen Purging
Vacuum
Ethylene Oxide Condensation
Cooling
Tallow Amine
Ethoxylates
PER KG
1 30.00
2 0.40
3 70.000
100.40
*Note: Per Kg of Product Basis
Ethylene Oxide Tallow Amine Ethoxylates 100.4
TOTAL TOTAL 100.40
Tallow Amine Waste Water 0
Catalyst Hazardous Waste 0
MASS BALANCE FOR TALLOW AMINE ETHOXYLATES
SR NO
INPUT OUTPUT
INPUT OUTPUT PER Kg
Stearyl Amine Charge
Catalyst Addition and Heating
Nitrogen Purging
Vacuum
Ethylene Oxide Condensation
Cooling
Stearyl Amine
Ethoxylates
PER KG
1 38.00
2 0.40
3 62.000
100.40
*Note: Per Kg of Product Basis
Ethylene Oxide Stearyl Amine Ethoxylates 100.4
TOTAL TOTAL 100.40
Stearyl Amine Waste Water 0
Catalyst Hazardous Waste 0
MASS BALANCE FOR STEARYL AMINE ETHOXYLATES
SR NO
INPUT OUTPUT
INPUT OUTPUT PER Kg
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Coco Amine I Charge
Catalyst Addition and Heating
Nitrogen Purging
Vacuum
Ethylene Oxide Condensation
Cooling
Coco Amine
Ethoxylates
PER KG
1 48.50
2 0.40
3 51.500
100.40
*Note: Per Kg of Product Basis
Ethylene Oxide Coco Amine Ethoxylates 100.4
TOTAL TOTAL 100.40
Coco Amine I Waste Water 0
Catalyst Hazardous Waste 0
MASS BALANCE FOR COCO AMINE ETHOXYLATES
SR NO
INPUT OUTPUT
INPUT OUTPUT PER Kg
Oleyl Amine I Charge
Catalyst Addition and Heating
Nitrogen Purging
Vacuum
Ethylene Oxide Condensation
Cooling
Oleyl Amine
Ethoxylates
PER KG
1 19.60
2 0.40
3 100.000
120.00
*Note: Per Kg of Product Basis
Ethylene Oxide Oleyl Amine Ethoxylates 120
TOTAL TOTAL 120.00
Oleyl Amine I Waste Water 0
Catalyst Hazardous Waste 0
MASS BALANCE FOR OLEYL AMINE ETHOXYLATES
SR NO
INPUT OUTPUT
INPUT OUTPUT PER Kg
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Sorbitian Mono
LaurateCharge
Catalyst Addition and Heating
Nitrogen Purging
Vacuum
Ethylene Oxide Condensation
Cooling
Poly Sorbate
Ethoxylate
PER KG
1 28.50
2 0.50
3 71.500
100.50
*Note: Per Kg of Product Basis
Ethylene Oxide Poly Sorbate Ethoxylate 100.5
TOTAL TOTAL 100.50
Sorbitian Mono Laurate Waste Water 0
Catalyst Hazardous Waste 0
MASS BALANCE FOR POLY SORBATE ETHOXYLATES
SR NO
INPUT OUTPUT
INPUT OUTPUT PER Kg
Stearic Acid Charge
Catalyst Addition and Heating
Nitrogen Purging
Vacuum
Ethylene Oxide Condensation
Cooling
Stearic Acid
Ethoxylate
PER KG
1 50.00
2 0.50
3 50.000
100.50
*Note: Per Kg of Product Basis
Ethylene Oxide Stearic Acid Ethoxylate 100.5
TOTAL TOTAL 100.50
Stearic Acid Waste Water 0
Catalyst Hazardous Waste 0
MASS BALANCE FOR STREARIC ACID ETHOXYLATES
SR NO
INPUT OUTPUT
INPUT OUTPUT PER Kg
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Mass Balance for Metformin Hydrochloride:
INPUT PER KG OUTPUT PER Kg
1 n-butanol 700 System loss 2% 686
2 Dicyandiamide (DCDA) 507.5 Metformin Hydrochloride 1000
3 Dimethyl amine
Hydrochloride (DMA.HCL) 497.4
Total 1000 1000
1400 KG ACETONE
220 KG METHANOL
TOTAL OUT : 5490 KG TOTAL IN : 5490 KG100 KG DRY METHYLCOBALAMIN
90 KG METHYL IODIDE
110 KG SODIUM BOROHYDRIDE
500 KG PHENOL
40 KG CHLOROFORM
210 KG DMW
100 KG DMW
STEP - II
140 KG WET METHYLCOBALAMIN
2550 KG CHLOROFORM LAYER FOR
RECOVERY
800 KG AQUOUS LAYER
1920 KG CHLOROFORM
1670 KG ACETONE FOR RECOVERY
80 KG TO ETP
FLOW DIAGRAM AND MATERIAL BALANCING OF METHYLCOBALAMIN
STEP - I
800 KG AQUOUS LAYER 100.0 KG CYANOCOBALAMIN
250 KG TO ETP
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2.12 Plant Infrastructure and Basic Requirements
The proposed project will require water, power, fuel, human resources, machineries & utilities etc.
The details of all major resources to be required for proposed project area described in subsequent
sections under respective headings.
2.12.1 Land
The total area available at the proposed project site is 3691.10 m2 (0.36911 Ha). The unit has &
will develop green belt area in 1476m2. Layout plan of the project site is given in Figure 2.1 area
calculation for proposed structures is given in Table 2.2.
2.12.2 Plant Equipment/Machineries
The list of plant machineries and utilities required to be installed for the proposed project is given
in Table 2.7 given below.
TABLE 2.7 DETAILS OF PLANT MACHINERIES
BLOCK A – Betalactum Sr. No Equipment Name Equipment ID MOC Capacity
1. Reactor R-101 SS 316 18000 L
2. Reactor R-102 SS 316 18000 L
3. Reactor R-103 SS 316 16000 L
4. Reactor R-104 SS 316 15000 L
5. Reactor R-105 SS 316 20000 L
6. Reactor R-106 SS 316 21000 L
7. Reactor R-107 SS 316 28000 L
8. Reactor R-108 SS 316 28000 L
9. Reactor R-109 SS 316 28000 L
10. Reactor R-110 SS 316 29000 L
11. Reactor R-111 SS 316 29000 L
12. Reactor R-112 SS 316 29000 L
13. Reactor R-113 SS 316 29000 L
14. Reactor R-114 SS 316 30000 L
15. Reactor R-115 SS 316 30000 L
16. Reactor R-116 SS 316 30000 L
17. Reactor R-117 SS 316 30000 L
18. Reactor R-118 SS 316 30000 L
19. Reactor R-119 SS 316 30000 L
20. Reactor R-120 SS 316 30000 L
21. Reactor R-121 SS 316 30000 L
22. Reactor R-122 MS 20000 L
23. Reactor R-123 MS 20000 L
24. Reactor R-124 MS 20000 L
25. Reactor R-125 SS 316 700 L
26. Reactor R-126 Glass Lined 5000 L
27. Reactor R-127 Glass Lined 5000 L
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28. Reactor R-128 SS 316 100 L
29. Receiver RC-101 SS 316 1000 L
30. Receiver RC-102 SS 316 1000 L
31. Receiver RC-103 SS 316 700 L
32. Fluid Bed Dryer FBD-101 SS 316 300 Kg
33. Fluid Bed Dryer FBD-102 SS 316 300 Kg
34. Fluid Bed Dryer FBD-103 SS 316 300 Kg
35. Fluid Bed Dryer FBD-104 SS 316 300 Kg
36. Centrifuge CF-101 SS 316 60’’
37. Centrifuge CF-102 SS 316 60’’
38. Centrifuge CF-103 SS 316 60’’
39. Multi Mill MM-101 SS 316 --
40. Multi Mill MM-102 SS 316 --
41. Multi Mill MM-103 SS 316 --
42. Sifter SFT-101 SS 316 --
43. Sifter SFT-102 SS 316 --
44. Compactor COM-101 SS 316 --
45. Compactor COM-102 SS 316 --
46. Blender BLE-01 SS 316 1500 Kg
47. Fermenter FER-101 SS 316 15000 L
48. Fermenter FER-102 SS 316 1500 L
49. SS Tank TK-101 SS 316 15000 L
50. SS Tank TK-102 SS 316 700 L
51. SS Tank TK-103 SS 316 700 L
52. SS Tank TK-104 SS 316 700 L
53. Separator SEP-101 SS 316 --
54. Homogenizer HMG-101 SS 316 --
55. Microfiltration MIF-101 SS 316 --
Utility Sr. No. Equipment Equipment ID Capacity
1 Air Handling Unit AHU-101 7500 CFM
2 Air Handling Unit AHU-102 7500 CFM
Block B - Methylcobalamin Sr. No Equipment Name Equipment ID MOC Capacity
1 Reactor R-201 Glass Lined 2000 L
2 Reactor R-202 Glass Lined 3000 L
3 Nutsche Filter NF-201 SS 316 30”
4 Bag Filter BF-201 SS 316 6”
5 Vacuum Tray Dryer VTD-201 SS 316 6 Tray
6 Sifter SFT-201 SS 316 12”
7 Blender BL-201 SS 316 100 L
8 Grinder GRD-201 SS 316 1 HP
9 Weighing Balance EB-201 SS 316 3.000 Kg
10 Weighing Balance EB-202 SS 316 10.000 Kg
11 Weighing Balance EB-203 SS 316 60.000 Kg
Utility
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Sr. No. Equipment Equipment ID Capacity
1 Air Handling Unit AHU-01 1000 CFM
2 Air Handling Unit AHU-02 1500 CFM
3 Air Handling Unit AHU-03 1700 CFM
4 Air Handling Unit AHU-04 3000 CFM
5 Cooling Tower CT-03 2000 TR
6 Chilling Compressor Unit CC-04 60 TR
7 Vacuum System VS-01 250 m3/hr.
8 Hot Water System HWS-01 12 KW
Block C – Steroids Sr. No Equipment Name Equipment ID MOC Capacity
1 Reactor R-301 SS 316 1200 L 2 Glass Assembly R-302 Glass 200 L 3 Glass Assembly R-303 Glass 200 L 4 Glass Assembly R-304 Glass 100 L 5 Vacuum Tray Drier VTD-301 SS 316 16 Tray 6 Tray Dryer TRD-301 SS 316 24 Tray 7 Nutsche Filter NF-301 SS 316 100 L 8 Micronizer MCZ-301 SS 316 6” Size (80 CFM) 9 Centrifuge CF-301 SS 316 - 10 Multi Mill MM-301 SS 316 - 11 Weighing Balance EB-301 SS 316 100 Kg
Utility Sr. No. Equipment Equipment ID Capacity
1 Air Handling Unit AHU-301 3000 CFM BLOCK D – Anticancer
Sr. No Equipment Name Equipment ID MOC Capacity
1 Rota Evaporator RER-401 Glass 20 L
2 Glass Assembly GLA-401 Glass 50 L
3 Vacuum Tray Dryer VTD-401 SS 316 4 Tray
4 Vacuum Tray Dryer VTD-402 SS 316 4 Tray
5 Nutsche Filter NTF-401 SS 316 50 L
6 UV Chamber UVC-401 Powder Coated -
7 Weight Balance WTB-401 - 300 grams
8 Grinder GRI-401 - -
Utility Sr. No. Equipment Equipment ID Capacity
1 Air Handling Unit AHU-401 2000 CFM
2 Air Handling Unit AHU-402 2000 CFM
3 Air Handling Unit AHU-403 2500 CFM
4 Forced Draft Ventilation FDV-401 2000 CFM
Ethoxylates Sr. No. Equipment MOC Capacity
1 EO Batch tank SS 316 3.5 KL
2 EO Batch tank SS 316 3.5 KL
3 EO Batch tank SS 316 3.5 KL
4 nitrogen plant 25 m3/hr.
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5 nitrogen receiver tank MS 10 KL
6 Vacuum pump CI 10 HP
7 Vacuum receiver MS 1 KL
8 RM Storage Aluminum 30 KL
9 RM Storage Aluminum 30 KL
10 Gear Pump CI 01 Metformin
Sr No. Name of Equipment MOC
1 GL Reactor Glass lined
2 Sparkler filter SS-316
3 GL Reactor Glass lined
4 Centrifuge SS-316
5 Storage Tank SS/HDPE
6 GL Reactor Glass lined
7 Storage Tank SS/HDPE
8 Dryer SS-316
9 Pin mill SS-316
10 Pulvriser SS-316
11 Sifter SS-316
2.12.3 Details of Utilities
Various utilities required for proper functioning of manufacturing plants. These utilities include
Thermic Fluid Heater, cooling tower, D. G. sets, etc. Details of utilities services required for the
proposed project are given in following Table 2.8.
TABLE 2.8 DETAILS OF UTILITIES
Sr. No. Name of utility Capacity Quantity
Existing
1 Thermic Fluid Heater 20 Lac K.Cal 1
2 Air Handling Unit 7500 CFM 2
3 Air Handling Unit 1000 CFM 1
4 Air Handling Unit 1500 CFM 1
5 Air Handling Unit 1700 CFM 1
6 Air Handling Unit 3000 CFM 2
7 Air Handling Unit 2000 CFM 2
8 Air Handling Unit 2500 CFM 1
9 Cooling Tower 600 TR 2
10 Chilling Compressor Unit 60 TR 1
11 Vacuum System 250 m3/hr. 1
12 Hot Water System 12 KW 1
13 Forced Draft Ventilation 2000 CFM 1
14 Chilling Compressor 240 TR 2
15 DM Water Unit 5000 LPH 1
16 Transformer 1500 K.V.A. 1
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17 Air Compressor 450 C.F.M 3
18 Air Dryer 150 CFM 1
19 Air receiver 2000 L 1
20 AHU (LAB) 800 C.F.M 1
21 Cold Room 0o to 5oC 1
22 Floating Aerator 5 KW 1
23 ETP 20 KL 1
24 Vacuum System 250 m3/hr. 2
Proposed
1 Thermic Fluid Heater 40 lac K Cal 1
2 DG Set 385 KVA 1
3 Cooling Tower 1000 TR 1
2.12.4 Power Requirement
Power requirement for the project will be 1600KVA, for proposed product 1000KVA, for existing
Products 600 KVA which is supplied by DGVCL. DG Set of 385 KVA installed for backup. No
additional D.G. sets to be installed.
2.12.5 Fuel
Existing Thermic Fluid Heater of 20Lac K.Cal 40 L/Hr. FO/LDO. For Proposed Thermic Fluid Heater
of 40 Lac K.Cal 555Nm3/Hr. Natural Gas & for 385 KVA DG Set 90 L/Hr. HSD will be used.
Fuel Storage & transportation details have been displayed in Table 2.9 & 2.10
TABLE 2.9 FUEL STORAGE DETAILS
Fuel Method of storage
Capacity & MOC Operating Condition Control Measures
Provided Press. Temp. 0C
FO/LDO Tank MS Atm Amb Fire Extinguisher provided. Isolated storage.
Natural Gas Pipeline Atm Amb Fire Extinguisher provided.
High Speed Diesel (HSD)
MS tank 20 KL Atm Amb Fire Extinguisher provided. Isolated storage.
TABLE 2.10 FUEL SOURCE & TRANSPORTATION DETAILS
Fuel Source of Supply Means of
Transportation Distance of supplier
from (Km)
FO/LDO IOCL, Vadodara Road Transport 10
Natural Gas Adani Gas Supply Pipeline 1
High Speed Diesel (HSD)
Mourvi Petroleum Road transport 2 km
2.12.6 Water
This is an existing unit manufacturing Bulk Drugs, Proposed products Ethoxylates & Metformin.
Existing Products - 38 KLD, Proposed Products 249 KLD, 40 KLD Treated Effluent from ETP to be
Gujarat Dyestuff Industries (Pharma Unit) Chapter 2 Project Description
Rapid Environmental Impact Assessment Report 127
recycled after RO Plant & MEE hence 247.4 KLD fresh water will be used, which will be met through
GIDC Nandesari Industrial Estate water supply (attached as Annexure 11). Out of which, process
(17 KLD), cooling tower (250 KLD), boiler (0 KLD), Scrubber (1 KLD), Washing (4 KLD) & Domestic
(10 KLD). Total water requirement will be 287 KLD in which 40 KLD Treated Effluent from ETP to
be recycled after RO Plant & MEE Condensate. Hence freshwater requirement will be 247.4 KLD.
2.12.7 Manpower
The manpower is one of the main resource requirements for the operation and maintenance of the
plant in a better and efficient way. Existing 30 + Additional 20 = Total 50 nos. of employees/workers
will be employed due to project activities. During the construction phase 30 persons to be working
at site.
2.13 Source of Pollution & its Management
Project activities will generate pollution many in terms of wastewater generation, gaseous
emission, generation of noise, hazardous waste generation etc. These sources of pollution & its
mitigation measures are described below.
2.13.1 Wastewater Generation& its management
The wastewater generated will be mainly from the washing, Scrubber, Process, Cooling Tower.
Total 40 KLD Industrial w/w will be generated from the existing & proposed manufacturing
activities. The effluent treatment plant shall be so designed that the effluent from the process will
come to the Equalization cum Neutralization tanks for chemical treatment, whereas the domestic
waste goes directly go to the Septic Tank & Soak pit for disposal.
Effluent Treatment Plant of to treat all the effluent generated from Production, Utilities and
Washing is proposed for the project. Cooling tower blowdown to be segregated & taken directly to
the Intermediate sump before filtration. Treated Effluent of 40 KLD will be passed through RO Plant
to recover 50% of the wastewater. 20KLD recovered ETP RO Permeate will be utilized for cooling
tower makeup & 20 KLD ETP RO Reject will be taken to MEE plant for evaporation. 19.6KLD
Condensate of MEE Plant to be recovered and reused.
Mode of discharge of treated effluent
Treated Effluent of 40 KLD will be passed through RO Plant to recover 50% of the wastewater.
20KLD recovered ETP RO Permeate will be utilized for cooling tower makeup & 20 KLD ETP RO
Reject will be taken to MEE plant for evaporation. 19.6 KLD MEE Condensate also to be recovered.
Sewage (domestic wastewater and sanitary wastewater)
8 KLD domestic wastewater will be generated, which will be disposed through Septic tank & Soak
Pit. Detail of water consumption and wastewater generation as per is given in below Table 2.11.
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TABLE 2.11 DETAILS OF WATER CONSUMPTION &W/W GENERATION
Water Existing KLD
Proposed (Additional)
KLD
Total after Expansion
KLD
Remarks
(D) Domestic 5 5 10 - (E) Gardening 5 0 5 - (F) Industrial
Process 17 0 17 - Washing 1 4 4 -
Boiler 0 0 0 -- Cooling 10 240 250 -
Others (Scrubber) 0 1 1 -- Industrial Total 28 244 272
Grand Total (A+B+C) 38 249 287 - Recycled 39.6
Fresh Water Required 247.4
Wastewater Existing KLD
Proposed (Additional)
KLD
Total after Expansion
KLD
Remarks
(C) Domestic 4 4 8 Septic Tank & Soak Pit
(D) Industrial Process 18.4 1 19.4 - Washing 1.0 3 4 -
Boiler 0 0 0 -- Cooling 0.6 15 15.6 --
Others (Scrubber) 0 1 1 -- Total Industrial
wastewater 20 20 40 To RO Plant for
Recovery ETP RO Plant Product 20 Reused for
Cooling Tower Makeup
ETP RO Plant Reject Effluent
20 To MEE for Evaporation &
19.6 KLD Condensate
Recovery & Reuse
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FIGURE 2.3 WATER BALANCE DIAGRAM
TOTAL WATER
REQUIREMENT
38.0 Total Water
19.8 Recycled
18.2 Fresh Water
PROCESS WASHING
COOLING
TOWER GARDEN DOMESTIC
17.0 1 10 5 5
SEWAGE TO
SEPTICK TK
4
PROCESS
EFFLUENT
WASHING
EFFLUENT Blowdown
18.4 1.0 0.60
REJECT TO
MEE
PRODUCT FOR
REUSE
10.0 10.0
9.8
*All figures in KLD
WATER BALANCE EXISTING
19.4
ETP
ETP INTERMEDIATE COLLECTION - RO FEED
20.0
MEE Condensate Recyceled
TOTAL WATER
REQUIREMENT
249.0 Total Water
19.8 Recycled
229.20 Fresh Water
PROCESS WASHING SCRUBBER
COOLING
TOWER GARDEN DOMESTIC
0.0 3 1 240 0 5
SEWAGE TO
SEPTICK TK
4
PROCESS
EFFLUENT
WASHING
EFFLUENT
SCRUBBER
EFFLUENT BLOWDOWN
1.0 3.0 1.0 15.0
REJECT TO
MEE
PRODUCT FOR
REUSE
10.0 10.0
9.8
*All figures in KLD
WATER BALANCE PROPOSED
5.0
ETP
ETP INTERMEDIATE COLLECTION - RO FEED
20.0
MEE Condensate Recycled
Gujarat Dyestuff Industries (Pharma Unit) Chapter 2 Project Description
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TOTAL WATER
REQUIREMENT
287.0 Total Water
39.6 Recycled
247.40 Fresh Water
PROCESS WASHING SCRUBBER
COOLING
TOWER GARDEN DOMESTIC
17.0 4 1 250 5 10
SEWAGE TO
SEPTICK TK
8
PROCESS
EFFLUENT
WASHING
EFFLUENT
SCRUBBER
EFFLUENT BLOWDOWN
19.4 4.0 1.0 15.6
REJECT TO
MEE
PRODUCT FOR
REUSE
20.0 20.0
19.6
*All figures in KLD
WATER BALANCE EXISTING + PROPOSED
ETP
24.4
ETP INTERMEDIATE COLLECTION - RO FEED
40.0
MEE Condensate Recycled
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2.13.1.1 Details of wastewater generation with qualitative and quantitative analysis
Company has an existing ETP that was designed for present products. During the proposed
expansion only 1KLD of process effluent is expected to be generated and remaining 4KLD & 15KLD
will be from Washing & Cooling Tower Blowdown. Hence it was decided to consider the existing
characteristics for ETP. This is given in Table 2.12.
TABLE 2.12 CHARACTERISTICS OF WASTEWATER
Sr. Parameters Analysis Results of Composite Effluent 1 pH 5.0
2 COD mg/L. 10,130
3 BOD mg/L 4990 4 Oil & Grease mg/L 50 5 Ammonical Nitrogen mg/L 150 6 Total Dissolved Solids mg/L 5000
2.13.1.2 Treatment Methodology
1. Chemical Treatment (Existing).
TABLE 2.13 ANALYSIS RESULTS AFTER CHEMICAL TREATMENT (LIME + ALUM):
Sr. Parameters Analysis Results of Composite Effluent 1 pH 7.5
2 COD mg/L. 6810
3 BOD mg/L 3305 4 Oil & Grease mg/L <10 5 Ammonical Nitrogen mg/L 89 6 Total Dissolved Solids mg/L 4480
2. Secondary Treatment (Activated Sludge Process - Existing)
TABLE 2.14 ANALYSIS RESULTS AFTER SECONDARY / BIOLOGICAL TREATMENT
Sr. Parameters Analysis Results of Composite Effluent 1 pH 7.91
2 COD mg/L. 1940
3 BOD mg/L 624 4 Oil & Grease mg/L <10 5 Ammonical Nitrogen mg/L 46 6 Total Dissolved Solids mg/L 4350
3. Tertiary Treatment (Polishing - Existing)
TABLE 2.15 ANALYSIS AFTER TERTIARY TREATMENT
Sr. Parameters Analysis Results of Composite Effluent 1 pH 7.86
2 COD mg/L. 1785
3 BOD mg/L 500 4 Oil & Grease mg/L <10 5 Ammonical Nitrogen mg/L 42.1
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Observations:
• Presently the treated effluent confirms with the disposal norms for CETP Nandesari.
However, it is planned to improve the Biological (Secondary) treatment for increasing the
reduction of COD & BOD as this is now proposed to be recovered from RO Plant.
TABLE 2.16 FINAL REDUCTIONS AFTER TREATMENT
Sr. Parameters Analysis Results of Composite Effluent
Analysis Results of Treated Effluent
1 pH 5.0 7.86
2 COD mg/L. 10,130 1785
3 BOD mg/L 4990 500 4 Oil & Grease mg/L 50 <10
5 Ammonical Nitrogen mg/L
150 <50
6 Total Dissolved Solids mg/L
5000 <4500
TABLE 2.17 FINAL REDUCTIONS AFTER TREATMENT
Sr. Parameters Analysis Results of Treated Effluent -
Existing
Analysis Results of Treated Effluent – After
Proposed 2nd Stage Biological Treatment
(Designed) 1 pH 7.86 6.5 – 8.5
2 COD mg/L. 1785 <250
3 BOD mg/L 500 <50 4 Oil & Grease mg/L <20 20 5 Ammonical Nitrogen mg/L 42.1 50 6 Total Dissolved Solids mg/L 4210 - 7 Suspended Solids mg/L < 100 <100
Treated Effluent is proposed to be recovered using RO Plant hence second stage biological
treatment has been proposed in the ETP to achieve better results.
GDI (Pharma Unit) have Existing capacity of 20KLD with the CETP. However, ZLD is planned.
Gujarat Dyestuff Industries (Pharma Unit) Chapter 2 Project Description
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2.13.1.3 Effluent treatment scheme
The process of the Effluent Treatment Plant based on the Treatability study conducted has been
described below:
• 24.4 KLD waste water (Except Cooling Tower Blowdown 15.6 KLD) from process shall pass
though Oil & Grease removal trap (B-101) where Oil & Grease shall be removed with help
of oil & grease removal belt and collected in Oil & Grease collection tank (B-114). Then
effluent shall be collected in Equalisation cum Neutralization tank (B-102) where lime
solution shall be added to neutralize the effluent from Lime Dosing Tank (B-111). Then
neutralized effluent is pumped to Filter Press (FP-103) where solids are removed. Filtrate
from filter press shall be collected in Holding Tank (B-104) and primary sludge to HWSA.
• The effluent from holding Tank shall be pumped to Aeration tank-1 (B-105) and then
Aeration Tank-2 (B-106) for biological treatment where nutrient shall be added from
Nutrient Dosing tank (B-112). Here biodegradation of organic matter of the wastewater
shall be carried out by bacteria (Suspended growth) and for that oxygen shall be supplied
by 2 nos. of air blowers (B-102) through diffusers. Air blowers also keep MLSS in
suspension.
• Then after, wastewater shall go to secondary settling tank (B-107), here the suspended
solids shall be settled. Activated sludge shall be removed from bottom of SST and pumped
to AT to maintain MLSS and excess Activated Sludge shall be sent to Sludge drying beds (B-
113), where dewatering is carried out before storage of sludge in Hazardous waste storage
area (HWSA) and ultimate disposal to TSDF.
• Then overflow (clear supernatant) of SST shall be collected in Intermediate Sump (B-108).
Here 15.6 KLD of cooling tower blowdown will come directly as this will not require
chemical treatment.
• Wastewater from the Intermediate sump is passed through Dual Media Filter (F-109) for
removal of remaining impurities and shall be collected in Treated Effluent Sump (B-110).
• Treated Effluent of 40 KLD from Treated Effluent Sump will be passed through RO Plant
to recover 50% of the wastewater. 20KLD recovered ETP RO Permeate will be utilized for
cooling tower makeup & 20 KLD ETP RO Reject will be taken to MEE plant for evaporation.
MEE Condensate of 19.6 KLD also to be recovered for reuse.
Refer Figure 2.4 for ETP flow diagram.
The disposal permission from CETP Nandesari has also been attached as Annexure-16.
Details of the units have been provided below for ETP design of 24.4 m3/day (1m3/hr.) + 15.6
m3/day Cooling Tower Blowdown to Intermediate collection sump:
TABLE 2.18 DETAILS OF ETP (NAME OF UNIT & CAPACITY)
Sr. No
Name of Unit No. Capacity (KL) D.T. Hrs. Adequacy
1 Oil & Grease Removal Tank (B-101) 1 2 1.6 Adequate 2 Equalization cum Neutralization
Tank (B-102) 1 20 16 Adequate
3 Filter Press (FP-103) 1 5m3/day 1 Adequate 4 Holding Tank (B-104) 1 5 4.2 Adequate
5 Aeration Tank – 1 (B-105) 1 55 45.8 In-
Adequate
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6 Aeration Tank – 2 (B-106) 1 55 45.8 In-Adequate
7 Secondary Settling Tank (B-107) 1 5 4.1 Adequate 8 Intermediate Sump (B-108) 1 5 4.1 Adequate 9 Dual media Filter (F-109) 1 1m3/hr. - In-
Adequate 10 Treated Effluent Sump (B-110) 1 20 16.6 In-
Adequate 11 Lime Dosing Tank (B-111) 1 1 - Adequate 12 Nutrient Dosing Tank (B-112) 1 1 - Adequate 13 Sludge Drying Beds (B-113) 2 3m x 4m - Adequate 14 Hazardous Waste Storage Area 1 - - Adequate
Note: 1. Presently ETP Design is of 20KLD. Treated BOD in existing for Aeration Tank is 624mg/L.
As RO plant for recovery is planned, second stage biological treatment is proposed.
2. Aeration tank -2 of 55 KL & Secondary Settling Tank – 2 of 5 KL is proposed for second stage biological treatment.
3. Dual Media Filter is of 1.0KL/Hr. This will need to be replaced with Pressure Sand & Activated Carbon Filter of Dual Media Filter of 3.0KL/Hr. to handle a flow of 40 KLD.
4. Presently the treated effluent sump is of 20KL. This will need to be increased based on the requirements of storage.
Gujarat Dyestuff Industries (Pharma Unit) Chapter 2 Project Description
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FIGURE 2.4 FLOW DIAGRAM OF ETP - EXISTING
Gujarat Dyestuff Industries (Pharma Unit) Chapter 2 Project Description
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2.13.2 Air Pollution and Control System
The main sources of air pollution will be flue gas emission. Flue gas emission will be from One
existing Thermic Fluid Heater & One proposed flue gas stacks of Thermic Fluid Heater & One
proposed flue gas stack of DG set. FO/LDO is being used as existing fuel & Natural Gas will be used
in the proposed Thermic Fluid Heater. Adequate Stack height to be provided as APCM on stack
attached to Thermic Fluid Heater. PM, SO2& NO2 are the main pollutants generated from the flue
gas stack.
Detail of flue gas emission & process gas emission along with stack height, type of fuel, expected
pollutants & air pollution control measures is given in below table 2.19.
TABLE 2.19 DETAILS OF STACKS
FLUE GAS EMISSION EXISTING FOR EXISTING & PROPOSED PRODUCTS
Sr. no.
Source of emission
With Capacity
Stack Height
(meter)
Type of Fuel
Quantity of Fuel
MT/Day
Type of emissions
i.e. Air Pollutants
Air Pollution Control
Measures (APCM)
Existing Flue Gas emissions
1 Thermic Fluid
Heater (20 Lac Kcal)
30 F.O / LDO 40 Lit/Hr. PM, SO2, NO2 Caustic Scrubber
Proposed Flue Gas emissions
1 Thermic Fluid
Heater (40 Lac Kcal)
30 Natural Gas 555Nm3/Hr. PM, SO2, NO2 Adequate Stack Height
2 DG Set
(385 KVA) 5 HSD 90 Lit/Hr. PM, SO2, NO2 Adequate
Stack Height
PROCESS EMISSIONS:
Existing – No Process Emissions
Proposed – No Process Emissions
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2.13.2.1 Details of Scrubber
FIGURE 2.5 APCM
Gujarat Dyestuff Industries (Pharma Unit) Chapter 2 Project Description
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2.13.3 Hazardous Waste Generations and Disposal System
Main sources of hazardous waste generation will be
• ETP Sludge will be Stored at site and then accumulated quantity disposed to TSDF M/s.
NECL Nandesari.
• Discarded containers / barrels / liners used for hazardous wastes/chemicals. will be
Collected, Stored, decontaminated & sold to approved vendor/ recycler.
• Used oil/Spent Oil will Collected, stored, transported, disposed by selling to registered re-
refiners.
• Distillation Liquid Residue - Collection, Storage, Transportation and Disposal at common
incinerator facility of M/s. Nandesari Environment Control Ltd. (NECL).
Hazardous waste generation quantity, physical characteristics and mode of disposal are given in
Table-2.20.
TABLE 2.20 DETAILS OF HAZARDOUS WASTE AND ITS MODE OF DISPOSAL
Sr. no
.
Type/Name of
Hazardous waste
Specific Source of generatio
n (Name of
the Activity, Product
etc.)
Category and
Schedule as per
HW Rules.
Quantity (MT/Annum)
Management of HW
Existing Products
Proposed Products
Total After
Expansion
1 ETP Sludge
ETP Sch-I/ 35.3
12 MT/Annu
m
0 12 MT/Annu
m
Collection, storage,
treatment, transportation, and disposal at Nandesari Environment Control Ltd
(NECL) TSDF 2 Discarded
Bags & Containers
Production plant
Sch-I/ 33.1
108 MT/ Annum
0 108 MT/ Annum
Collection storage &
Decontamination within
factory premises.
3 Used Oil From Machinery
and TFH
Sch-I/ 5.1
0.6 KL/Annu
m
0 0.6 KL/Annu
m
Collection, storage,
transportation, Disposal by
selling to registered re-
refiners 4 Distillation
residues From
Solvent Recovery
Sch-I/ 20.3
36 MT/Annu
m
30 MT/Annu
m
66 MT/Annu
m
CHWIF incinerator
facility of M/s. Nandesari
Environment
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Control Ltd. (NECL) /
Coprocessing 5 Spent
Solvent for recovery
Process Sch-I/ 20.2
252 MT/Annu
m
4116 MT/Annu
m
4368 MT/Annu
m
Captive In-house
Recovery.
6 MEE Salt
From Evaporation of RO
Reject
Sch-I/ 37.3
0 MT/Annu
m
144 MT/Annu
m
144 MT/Annu
m
Nandesari Environment Control Ltd
(NECL) TSDF
Hazardous waste will be stored in proper storage room and handed over to GPCB/CPCB approved
vendor for final disposal. The collection, Storage and disposal of hazardous waste will be done as
per Hazardous waste (Management and Handling) Rules 2016.
The unit will get the membership of common facility for TSDF, CHWIF.
2.13.4 Noise Level and Control System
Noise is considered as the unbearable acoustic phenomenon. The noise term is considered as the
increase in sound level above than hearing capacity. This can affect humans to a very large extent.
Due to loud noise, the hearing ability of a person may be damaged. This is also a very serious factor
which has to be considered. The two major categories of noise generating sources are divided in to
static and dynamic sources.
The static sources are including the construction equipment such as plant machineries, DG sets
&vehicular traffic etc. The noise levels were measured near the sources. It is expected that
construction activities will involve noise generation above 90-dB(A). The sound pressure level
generated by a noise source decreases with increasing distance from the source due to wave
divergence. Extensive oiling and lubrication and preventive maintenance will be carried out to
reduce noise generation at source to the permissible limit. However, at place where noise levels can
exceed the permissible limit, Earplugs and Earmuffs will be provided to those working in such area.
2.13.5 Soil
• The unit is located in notified industrial area and have occupied land area of 3691.10 m2
(0.36911 Ha) only there is no negative impact envisaged on soil & Geology of the study area.
• The unit will take full-proof measures to manage all types of hazardous wastes to mitigate
impacts on soil and geology.
• Maintain good green belt within premises.
Gujarat Dyestuff Industries (Pharma Unit) Chapter 2 Project Description
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2.14 Status of Applicable Rules, Acts, Regulation:
Sr.No Permission Approval No. date Authority
1 Consent to Establish
(CTE) CTE No. 55249 24.07.2013 GPCB
2 Environmental
Clearance SEIAA/GUJ/EC/5(f)/94/2014 01.08.2014 SEIAA Gujarat
3
Consent to Establish (CTE) Amendment
(Product Name Correction)
CTE No. 55249 27.01.2015 GPCB
4 Consent to Operate
(CCA) AWH 72360 12.05.2015 GPCB
5 Consent to Establish
(CTE) Product Change Mix
CTE No. 79671 28.06.2016 GPCB
6
Consent to Operate (CCA) – Amendment after Product Change Mix (For 12 Products
Only)
AWH 83065 31.01.2017 GPCB
7
Consent to Operate (CCA) – Amendment (For addition of one
product)
AWH 72360 10.04.2017 GPCB
2.15 Proposed Schedule for Approval and Implementation
This is an existing unit. Schedule Planned is shown in Annexure 17.
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CHAPTER – 3: BASELINE ENVIRONMENTAL STATUS
3.1 Introduction
The baseline status of environmental quality in the vicinity of project site serves as the basis for
identification, prediction and evaluation of impacts. The baseline environmental quality is assessed
through field studies within the impact zone for various components of the environment, viz. air,
noise, water, land and socio-economic. The baseline environmental quality has been assessed in the
post-monsoon season of October 2018 to December 2018 in a study area of 10 km radial distance
from the project site.
The environmental setting is considered to establish the baseline conditions which are described
with respect to following:
• Land environment
• Land Use Pattern
• Water Environment
• Air Environment
• Meteorology
• Noise Environment
• Ecology
• Topography
• Demography and Socio-economic Environment
3.2 Methodology
Following the guidelines of MoEFCC, the baseline environmental study was conducted. The
details of the study period, frequency of sampling & method of environmental sampling & analysis
are shown below in succeeding paragraphs under respective titles.
3.2.1 Study Period & Frequency of Sampling
The period of study determined was October 2018 to December 2018. The frequency of various
environmental sampling & analysis was determined following the guidelines provided by MoEF in
online EIA Manual. The details of frequency of environmental sampling considered for the study
are illustrated in Table – 3.1.
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TABLE 3.1 FREQUENCY OF ENVIRONMENTAL MONITORING
Attributes Sampling
Locations Frequency A. Air Environment
Meteorological Project Site 1 hourly continuous for Study
Period
Ambient Air Quality 10 locations in the study area
(10 km radius from project site) 24 hourly twice a week during
study period
B. Noise Various Locations within the study area
(10 Km radius from project site) Once during Study Period
C. Water
Ground Water Grab samples from 8 Locations from
Study Area (10 km radius from project site)
Once during Study Period
Surface Water
Grab samples from 1 Locations (10 km radius from project site)
Once during Study Period
D. Soil Quality Soil samples from 8 locations within
study area Once during Study Period
E. Land Use & Land Cover
Study area (10 km from Project Site) Once during Study Period
F. Ecological Data Study area (10 km from Project Site) Once during Study Period G. Socioeconomic Data Study area (10 km from Project Site) Once during Study Period
3.2.2 Method of Environmental Sampling & Analysis
The method adopted for environmental sampling & analysis is illustrated in following Table - 3.2.
TABLE 3.2 METHOD OF ENVIRONMENTAL SAMPLING & ANALYSIS
Attributes METHOD
Sampling / Preservation Analysis
A. Air Environment 1) Micro meteorological data 2) Ambient Air Quality
Mechanical/automatic 1) Spectrum weather station &
IMD 2) 2.5 Micron dust samplers &
RSPM samplers having the facility to collect the gaseous samples
-----
IS 5182 & CPCB
B. Noise Instrument : Noise level meter --
C. Water & Wastewater 1) Ground Water 2) Surface Water
Standard Methods for Examination of Water and
Wastewater Analysis, published by APHA 22nd edition, 2012
Standard Methods for Examination of Water and
Wastewater Analysis, published by APHA 22nd
edition, 2012
D. Soil Quality Laboratory Guide for Conducting
Soil Test & Plant Analysis, by J. Benton Jones, Jr.
Laboratory Guide for Conducting Soil Test & Plant Analysis, by J. Benton Jones,
E. Land Use & Land Cover Satellite Imageries (1:25,000), Secondary data from EIC, Delhi
As Secondary data-analysis by EIC, Delhi
F. Geology & Geo-Hydrology Secondary data from EIC, Delhi Secondary data from EIC, Delhi
G. Ecological Data Secondary data from EIC, Delhi Secondary data from EIC, Delhi
H. Socioeconomic Data Secondary data from EIC, Delhi Secondary data from EIC, Delhi
Gujarat Dyestuff Industries (Pharma Unit) Chapter 3 Baseline Environmental Status
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3.2.3 Baseline Environmental Status
The baseline environmental study was carried out for Ambient Air, Water, Land, Noise, Biological
& Socioeconomic environment. The study period was October 2018 to December 2018. The
environmental samples were collected from the selected location of the study area. The scenario of
environmental condition of the area revealed from the sample & data analysis is described below
in subsequent paragraphs.
3.3 Micrometeorology
The climate of Gujarat is varied, as it is moist in the southern districts and dry in the northern
region. The Arabian Sea and the Gulf of Cambay in the west and the forest-covered hills in the east
soften the rigors of climatic extremes, consequently reducing the temperature and render the
climate more pleasant and healthy. Surat lies along the southern part of the state and experiences
a climate with aridity index of 15 to 20 per cent indicating adequate moisture availability in the
soils for most part of the year.
3.3.1 Temperature Details
Minimum, Maximum and Average Temperatures for Vadodara Station of the year 2017 are given in
Table 3.3.
TABLE 3.3 TEMPERATURE DATA
Month (2017)
Minimum Temperature
(0C)
Maximum Temperature
(0C)
Average Temperature
(0C)
January 6.5 35.1 21.0 February 11.3 38.0 24.6
March 12.2 42.7 27.5 April 20.0 43.4 31.7 May 25.0 42.6 33.8 June 26.6 44.1 35.4 July 24.7 35.6 30.2
August 23.6 33.6 28.6 September 24.0 36.5 30.3
October 17.2 35.1 26.2 November 12.6 33.9 23.3 December 11.0 33.2 22.1
3.3.2 Relative Humidity (RH)
Minimum, Maximum and Average Monthly Relative Humidity for Vadodara Station of the year 2017
is given in Table 3.4.
TABLE 3.4 RELATIVE HUMIDITY DATA
Month (2017)
Minimum R.H.% Maximum R.H.% Average R.H.%
January 19 88 54 February 13 84 46
March 14 80 40
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April 6 87 42 May 13 86 48 June 25 91 59 July 51 98 78
August 49 98 82 September 45 98 73
October 30 98 68 November 24 83 54 December 21 88 54
3.3.3 Rainfall
Rainfall data for Vadodara Station of the year 2017 is presented in Table 3.5.
TABLE 3.5 RAINFALL DATA
Month (2017)
Monthly Total (mm)
Numbers of Rainy Days
January 0 0 February 0 0
March 0 0 April 0 0 May 1.8 1 June 66.8 4 July 172.2 21
August 313 23 September 129.8 8
October 23.4 5 November 0 0 December 0 0
Total 707 62 Total rainfall, during the monsoon period, has been recorded as 707 mm.
3.3.4 Wind Speed
Wind speed for Vadodara Station of the year 2017 is given in Table 3.6.
TABLE 3.6 WIND SPEED DATA
Sr. No. Month (2017)
Average Wind speed (KMPH)
1. January 8 2. February 9 3. March 8 4. April 12 5. May 14 6. June 16 7. July 13 8. August 13 9. September 11
10. October 6 11. November 6 12. December 7
Average 10.25
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3.3.5 Temperature, Relative Humidity & Wind Speed
The site-specific data were collected for October 2018 to December 2018. Data are tabulated in
Table 3.7.
TABLE 3.7 SITE SPECIFIC METEOROLOGICAL DATA (PERIOD: OCTOBER 2018 TO
DECEMBER 2018)
METEOROLOGICAL PARAMETER MONTH
OCTOBER, 2018 NOVEMBER, 2018
DECEMBER, 2018
Temperature (0C) Min. Max. Avg.
18.5 36.3 27.4
13.9 34.8 24.4
12.3 33.6 23.0
Relative Humidity (%) Min. Max. Avg.
35.0 99.0 67.0
26.0 88.0 57.0
23.0 92.0 57.5
Wind Speed (km/h) Min. Max. Avg.
0
10.2 4.0
0
11.7 4.5
0
13.7 5.0
There was no rainfall during the study period.
3.3.6 Wind Rose
Wind rose is a graphical representation of the magnitude and direction of wind speed considering
all the directions. With the help of wind rose diagram one can easily predict the direction and extent
of spreading of the gaseous and particulate matter from the source. Wind rose diagrams & stability
class distribution are prepared for the study area and presented in Figures - 3.1A & 3.1B
respectively.
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FIGURE 3.1A WIND ROSE DIAGRAM
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FIGURE 3.1B STABILITY CLASS DISTRIBUTION
3.4 Air Environment
The ambient air quality monitoring was carried out in accordance with National Ambient Air
Quality Standards (NAAQS) of CPCB. Ambient Air Quality Monitoring (AAQM) was carried out at
night locations during the study period.
The air quality status in the impact zone is assessed through a network of ambient air quality
monitoring locations. The tropical climatic conditions mainly control the transport and dispersion
of air pollutant emissions during various seasons.
The conventional and project specific parameters such as Suspended Particulate Matter, Respirable
Suspended Particulate Matter (RSPM-PM10), Respirable Suspended Particulate Matter (RSPM-
PM2.5), Sulphur Dioxide (SO2), Oxides of Nitrogen (NOx), Ammonia (NH3), Ozone (O3),
Lead (Pb), Arsenic (As), Nickel (Ni), Benzene (C6H6), Hydro Carbon (HC), HCl, Cl2 & Carbon
Monoxide (CO) were monitored at site.
The values for mentioned concentrations of various pollutants at all the monitoring locations were
processed for different statistical parameters like arithmetic mean, minimum concentration, and
25.5
61.9
9.7
2.80.2 0.0 0.0
0
10
20
30
40
50
60
70
%
Wind Class Frequency Distribution
Wind Class (m/s)
Calms 0.50 - 2.10 2.10 - 3.60 3.60 - 5.70 5.70 - 8.80 8.80 - 11.10 >= 11.10
10.8
9.7
7.26.6 6.5
16.9 16.9
6
8
10
12
14
16
18
20
%
Stability Class Frequency Distribution
Stability Class
A B C D E F G
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maximum concentration and percentile values. The baselines levels of Suspended Particulate
Matter, Respirable Suspended Particulate Matter (RSPM-PM10), Respirable Suspended Particulate
Matter (RSPM-PM2.5), Sulphur Dioxide (SO2), Oxides of Nitrogen (NOx), Ammonia (NH3), Ozone
(O3), Lead (Pb), Arsenic (As), Nickel (Ni), Benzene (C6H6), Hydro Carbon (HC), HCl, Cl2 & Carbon
Monoxide (CO) are expressed in terms of various statistical parameters.
To establish the baseline status around the project site of the study region monitoring was
conducted at 10 Ambient Air Quality Monitoring (AAQM) Stations in and around the study region
during October 1, 2018 to December 31, 2018.
FIGURE 3.2 LOCATIONS OF THE AMBIENT AIR, NOISE, WATER AND SOIL
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TABLE 3.8 LOCATIONS OF THE AMBIENT AIR, NOISE, WATER AND SOIL
Sr.No. Name of village
bearing w.r.t.
project site
Approximate radial
DISTANCE from Project
site (KM)
Ambient Air
Noise water Soil TYPE OF AREA
1. Project Site
-- -- A1 N1 GW1 S1 Industrial
2. Village: Nandesari
NW 2.09 A2 N2 GW2 S2 Residential
3. Village: Bhetasi
WSW 6.05 A3 N3 GW3 S3 Residential
4. Village: Ambali
W 6.40 A4 N4 GW4 S4 Residential
5. Village: Kotna
SW 6.16 A5 N5 GW5 S5 Residential
6. Village: Anagad
SW 2.44 A6 N6 GW6 S6 Residential
7. Village: Hathipura
SW 9.90 A7 N7 GW7 S7 Residential
8. Village: Undera
SE 7.21 A8 N8 GW8 S8 Residential
9. Village: Padamla
NE 3.49 A9 N9 GW9 S9 Residential
10. Village: Ajod
ENE 7.33 A10 N10 GW10 S10 Residential
11. Bhetasi Pond
WSW 6.05 -- -- SW1 -- --
12. Hathipura Pond
SW 9.90 -- -- SW2 -- --
13. Mahi River
-- -- SW3 -- --
14. Ajod Pond ENE 7.33 -- -- SW4 -- --
TABLE 3.9 AMBIENT AIR QUALITY STATUS (OCTOBER 2018 TO DECEMBER 2018)
SR. NO.
Sampling Location
Sampling DURATION
SPM PM10 PM2.5 SO2 NOx NH3 O3 Pb
g/m3 1. Project-site
(A1) 24 hours 121.6 77.35 47.49 22.19 19.15 BDL 14.33 BDL
2. Nandesari (A2)
24 hours 117.2 76.01 45.38 19.13 17.19 BDL 11.08 BDL
3. Bhetasi (A3)
24 hours 113.2 74.64 42.30 13.11 11.07 BDL 10.34 BDL
4. Ambali (A4)
24 hours 113.5 73.33 42.69 16.58 13.74 BDL 10.18 BDL
5. Kotna (A5) 24 hours 112.9 72.38 42.97 15.15 12.35 BDL 10.09 BDL 6. Anagad
(A6) 24 hours 116.8 75.78 44.52 18.46 15.49 BDL 11.06 BDL
7. Hathipura (A7)
24 hours 112.3 71.94 40.65 17.09 14.28 BDL 10.01 BDL
8. Undera (A8)
24 hours 114.2 74.96 42.80 13.57 11.49 BDL 10.46 BDL
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9. Padamla (A9)
24 hours 116.1 75.34 44.23 16.72 14.19 BDL 10.97 BDL
10. Ajod (A10) 24 hours 115.6 74.79 43.85 15.75 11.26 BDL 10.59 BDL NAAQS 500 100 60 80 80 400 180 1
SR. NO
.
Sampling
Location
As H2S Ni C6H6 BaP CO HC VOC
HCl Cl2
ng/m3
g/m3
ng/m3
g/m3
ng/m3
mg/m3
ppm g/m3
1. Project-site (A1)
BDL BDL BDL BDL BDL 1.32 BDL
0.9 BDL
BDL
2. Nandesari (A2)
BDL BDL BDL BDL BDL 1.29 BDL
0.9 BDL
BDL
3. Bhetasi (A3)
BDL BDL BDL BDL BDL 1.21 BDL
0.4 BDL
BDL
4. Ambali (A4)
BDL BDL BDL BDL BDL 1.22 BDL
0.5 BDL
BDL
5. Kotna (A5)
BDL BDL BDL BDL BDL 1.24 BDL
0.6 BDL
BDL
6. Anagad (A6)
BDL BDL BDL BDL BDL 1.27 BDL
0.8 BDL
BDL
7. Hathipura (A7)
BDL BDL BDL BDL BDL 1.23 BDL
0.4 BDL
BDL
8. Undera (A8)
BDL BDL BDL BDL BDL 1.23 BDL
0.6 BDL
BDL
9. Padamla (A9)
BDL BDL BDL BDL BDL 1.24 BDL
0.7 BDL
BDL
10. Ajod (A10)
BDL BDL BDL BDL BDL 1.23 BDL
0.4 BDL
BDL
NAAQS 6 -- 20 5 300 4 -- -- 200 100 Note: BDL = Below Detectable Limit The Minimum Detectable Limits for various parameters are as below:
Parameters Value Ammonia (as NH3) 1.0 g/m3
Lead (as Pb) 0.5 g/m3 Nickel (as Ni) 10 ng/m3
Benzene (as C6H6) 2 g/m3 Arsenic (as as) 2 ng/m3
Benzo (α) Pyrene (BaP) 0.5 ng/m3 Hydrocarbon (HC) 1 ppm
Carbon Monoxide (CO) 1.14 mg/m3
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3.4.1 Summary
The statistical interpretation of observed ambient air quality concentrations is presented in Table-
3.9. They represent the cross-sectional distribution of the baseline air quality status of the study
region.
The maximum concentration of SPM (121.6 g/m3), PM10 (77.35 g/m3), PM2.5 (47.49 g/m3),
SO2 (22.19 g/m3), NOx (19.15 g/m3), O3 (14.33 g/m3), CO (1.32 g/m3) & VOC (0.9 ppm) was
recorded in study area.
The minimum concentration of SPM (112.3 g/m3), PM10 (71.94 g/m3), PM2.5 (40.65 g/m3),
SO2 (13.11 g/m3), NOx (11.07 g/m3), O3 (10.01 g/m3), CO (1.21 g/m3) & VOC (0.4 ppm) was
recorded in study area.
The PM10 and PM2.5 concentrations at all the AAQM locations were primarily caused by local
phenomena including industrial & vehicular activities and natural dust getting air borne due to
manmade activities and blowing wind. PM10 and PM2.5 concentrations were observed below
stipulated standards of CPCB for Industrial, Residential, Rural and Other Area at all air quality
monitoring locations during the monitoring period. Results of all parameters are found within limit.
3.5 Noise Environment
The objective of the noise level survey around the project site was to identify existing -noise sources
and to measure background noise levels. Major noise sources in the study area are industries,
commercial, and vehicular movements. Major human settlement in the study area is Nandesari
which is about 2 km away from project site. The noise monitoring locations are given in Table - 3.8
and shown in Figure - 3.2 while the results of noise monitoring are given in Table - 3.10.
METHODOLOGY for Noise Monitoring
The noise monitoring was carried out at ten locations in day time during (6 am to 10 pm) and at
night time (10 pm to 6 am) in the study area covering all the areas i.e. industrial, commercial,
residential and silence zones as mentioned in Noise (Pollution and Control) Rules, 2000. CPCB
Recommendations for community noise exposure are attached as Annexure – 2. Hourly Equivalent
noise levels Leq (day) and Leq (night) were measured at each monitoring locations. One day
monitoring ranging from March 2, 2017 during day and nighttime was carried out at all the
locations.
INDIAN STANDARDS FOR NOISE LEVEL
Sr. No.
Locations Noise Level in
Day Time dB(A)
Noise Level in Nighttime
dB(A)
1 Industrial Area 75 65 2 Commercial Area 65 55 3 Residential Area 55 45
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4 Silence Zone i.e. Hospital, Educational institute etc. 50 45
TABLE 3.10 BACKGROUND NOISE LEVELS
Sr. No.
location Noise Level in dB(A) CPCB LIMIT dB(A)
Day TIME NIGHTTIME DAY TIME
NIGHT TIME
Min. max. Min. max. Max. max. RESIDENTIAL AREA
1. Project-site (N1) 61.7 63.9 58.7 60.2 <75 <65 2. Nandesari (N2) 47.8 49.9 41.8 43.3 <55 <45 3. Bhetasi (N3) 51.3 53.6 41.4 43.1 <55 <45 4. Ambali (N4) 49.6 52.7 41.1 42.8 <55 <45 5. Kotna (N5) 46.4 49.8 41.3 43.8 <55 <45 6. Anagad (N6) 50.2 53.5 39.9 41.4 <55 <45 7. Hathipura (N7) 50.7 53.8 40.9 42.7 <55 <45 8. Undera (N8) 50.4 52.3 40.7 42.5 <55 <45 9. Padamla (N9) 48.2 50.1 40.3 42.2 <55 <45
10. Ajod (N10) 52.4 54.7 42.5 44.2 <55 <45 COMMERCIAL AREA (TRANSPORTATION)
9. N1 (T): Near Bhetasi Chowkdi
59.8 64.4 49.3 53.2 <65 <55
10. N2 (T): Near Hathipura Chowkdi
57.4 62.5 48.6 51.3 <65 <55
11. N3 (T): Near Kotna Chowkdi 56.9 61.3 47.6 53.8 <65 <55 12. N4 (T): Near Anagad
Chowkdi 55.4 60.8 46.1 51.0 <65 <55
13. N5 (T): Near Padamla Chowkdi
61.8 63.9 52.4 54.1 <65 <55
14. N6 (T): Near Undera Chowkdi
58.7 63.4 51.9 53.8 <65 <55
3.6 Water Environment
The annual rainfall in the region was 707 mm. The baseline water quality status in the region is
established by analyzing surface water and ground water. Water requirement at site would be met
through GIDC water supply. Range of pre-monsoon water table is 20-25m & Post-Monsoon is 15-
20m as per secondary source.
3.6.1 Methodology for Water Quality Monitoring
10 nos. of ground water and 4 nos. of surface water samples were collected from the study area.
These samples were analyzed for physic-chemical parameters to ascertain the baseline status in
the existing surface water and ground water bodies. Samples were collected during the study
period of December 03 - 09, 2018 and analyzed as per the Standard Methods of Water and
Wastewater Analysis (APHA).
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TABLE 3.11 GROUND & SURFACE WATER QUALITY
WATER QUALITY- PHYSICAL PARAMETERS (OCTOBER-DECEMBER 2018)
SR. NO.
SAMPLING LOCATION
pH TEMPERATURE (0C)
turbidity (NTU)
TDS (mg/L)
T.S.S. (mg/L)
1 Project-site (GIDC Water)
6.96 25.0 2.2 156 8
2 Nandesari (GW1) 7.16 25.1 0.48 1902 22
3 Bhetasi (GW2) 7.81 24.9 0.17 590 10
4 Ambali (GW3) 7.99 25.1 3.2 426 18
5 Kotna (GW4) 7.80 25.0 1.9 1868 14
6 Anagad (GW5) 7.90 25.0 5.0 1334 16
7 Hathipura (GW6) 7.80 25.0 0.59 562 16
8 Undera (GW7) 7.45 25.1 31.6 640 32 9 Padamla (GW8) 7.77 25.0 4.6 1850 4
10 Ajod (GW9) 7.53 25.1 28.0 1022 62 11 Bhetasi Pond (SW1) 7.81 25.0 33.0 680 44
12 Hathipura Pond (SW2) 7.92 24.9 32.0 488 34
13 Mahi River (SW3) 8.24 25.0 1.4 144 18
14 Ajod Pond (SW4) 7.45 24.9 0.8 1426 8
GW= Ground water, SW= Surface water
WATER QUALITY - NUTRIENTS, OXYGEN DEMAND AND ORGANIC PARAMETERS
SR. NO.
SAMPLING LOCATION AMMONICAL NITROGEN
DO COD BOD327 OIL & GREASE
(mg/L) 1 Project-site (GIDC Water) <0.4 6.81 2.64 <1.0 <0.4 2 Nandesari (GW1) <0.4 6.72 9.92 <1.0 <0.4 3 Bhetasi (GW2) <0.4 6.72 1.98 <1.0 <0.4 4 Ambali (GW3) <0.4 6.90 3.96 <1.0 <0.4 5 Kotna (GW4) <0.4 6.80 7.27 <1.0 <0.4 6 Anagad (GW5) <0.4 6.81 6.61 <1.0 <0.4 7 Hathipura (GW6) <0.4 6.81 3.30 <1.0 <0.4 8 Undera (GW7) <0.4 6.90 5.29 <1.0 <0.4 9 Padamla (GW8) <0.4 6.81 7.98 <1.0 <0.4
10 Ajod (GW9) <0.4 6.53 5.95 <1.0 <0.4 11 Bhetasi Pond (SW1) <0.4 6.81 11.71 <1.0 <0.4 12 Hathipura Pond (SW2) <0.4 6.72 10.14 <1.0 <0.4 13 Mahi River (SW3) <0.4 6.90 8.45 <1.0 <0.4 14 Ajod Pond (SW4) <0.4 6.72 12.08 <1.0 <0.4
GW= Ground water, SW= Surface water
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WATER QUALITY - INORGANIC PARAMETERS
GW= Ground water, SW= Surface water
T.H. =Total Hardness, C.H. =Calcium Hardness, BDL= Below Detectable Limit
SR. NO.
SAMPLING LOCATION
Total ALKALINITY (as CaCO3)
T.H. (as
CaCO3)
C.H. (as
CaCO3)
Cl-
So4—2
Mg
(mg/L) 1 Project-site (GIDC
Water) 50 34.13 16.06 32.53 2.51 4.39
2 Nandesari (GW1) 395 908.04 419.4 578.71 199.78 118.6 3 Bhetasi (GW2) 415 433.72 114.4 76.38 58.1 77.59 4 Ambali (GW3) 410 355.41 50.2 34.41 23.12 74.16 5 Kotna (GW4) 655 672.68 100.4 673.23 127.66 139.06 6 Anagad (GW5) 765 210.84 100.4 297.03 23.76 26.80 7 Hathipura (GW6) 375 311.24 124.49 49.5 42.36 45.38 8 Undera (GW7) 1000 407.62 279.11 91.46 44.66 31.22 9 Padamla (GW8) 705 608.42 110.4 546.92 172.58 121.01
10 Ajod (GW9) 360 742.96 291.16 188.59 104.10 109.78 11 Bhetasi Pond (SW1) 350 277.10 50.2 144.44 49.52 55.13 12 Hathipura Pond
(SW2) 250 202.80 44.17 82.50 38.07 38.54
13 Mahi River (SW3) 160 148.98 68.27 33.47 23.76 19.02 14 Ajod Pond (SW4) 295 911.63 351.4 179.16 254.34 136.13
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WATER QUALITY - HEAVY METALS
SR. NO.
SAMPLING LOCATION
Na T-Cr+3
Cu Pb Fe Zn K Cd F-
(mg / L)
1 Project-site (GIDC Water)
8.20 <0.005 BDL <0.005 0.24 <0.022 0.94 <0.001 BDL
2 Nandesari (GW1)
175.35 <0.005 BDL <0.005 BDL <0.022 6.02 <0.001 BDL
3 Bhetasi (GW2)
30.66 <0.005 BDL <0.005 BDL <0.022 1.34 <0.001 BDL
4 Ambali (GW3) 16.33 <0.005 BDL <0.005 5.16 <0.022 0.88 <0.001 BDL 5 Kotna (GW4) 386.08 <0.005 BDL <0.005 0.16 <0.022 3.16 <0.001 BDL 6 Anagad
(GW5) 347.78 <0.005 BDL <0.005 1.80 <0.022
3.50 <0.001 BDL
7 Hathipura (GW6)
68.6 <0.005 BDL <0.005 BDL <0.022 3.4 <0.001 BDL
8 Undera (GW7)
47.68 <0.005 BDL <0.005 6.86 <0.022 8.77 <0.001 BDL
9 Padamla (GW8)
303.62 <0.005 BDL <0.005 1.34 <0.022 2.14 <0.001 BDL
10 Ajod (GW9) 31.89 <0.005 BDL <0.005 9.72 <0.022 2.79 <0.001 BDL 11 Bhetasi Pond
(SW1) 63.9 0.62 BDL <0.005 1.31 0.07 8.76 <0.001 BDL
12 Hathipura Pond (SW2)
24.46 <0.005 BDL <0.005 0.103 <0.022 8.75 <0.001 BDL
13 Mahi River (SW3)
11.23 <0.005 BDL <0.005 BDL 0.05 4.49 <0.001 BDL
14 Ajod Pond (SW4)
51.18 <0.005 BDL <0.005 BDL <0.022 8.70 <0.001 BDL
Minimum Detection Limit:
**Total
Chromium (as
Cr+3)
: 0.005
mg/L
Total Iron (as
Fe)
: 0.01 mg/L
Copper (as Cu) : 0.05
mg/L
**Zinc (as Zn) : 0.022 mg/L
Fluoride (as F-) : 0.05
mg/L
*Not in our NABL Scope, **Analyzed by Sub Contractor (Not in our NABL Scope)
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SUMMARY
The statistical interpretation of observed ground water & surface water quality is presented in
Table-3.11.
3.6.2 Baseline Ground water quality
pH of ground water samples varied from 6.96 to 7.99. Turbidity was found 0.17 to 31.6 NTU, Total
Dissolved Solids varied in the range of 156 to 1902 mg/L. DO and COD are found in range of 6.53
to 6.90 mg/L, and 1.98 to 9.92 mg/L respectively. BOD3 was found to be <1.0. Total Hardness (as
CaCO3) varied from 34.13 to 908.04 mg/L. Total Alkalinity varied from 50 to 1000 mg/L. Chlorides
and Sulfates are found in the range of 32.53 to 673.23 mg/L and 2.51 to 199.78 mg/L respectively.
3.6.3 Baseline Surface Water Quality
pH of surface water samples was found 7.45 to 8.24. Turbidity was found 0.8 to 33 NTU, Total
Dissolved Solids was found 144 to 1426 mg/L. DO and COD are found 6.72 to 6.90 and 8.45 to 12.08
mg/L respectively. BOD3 was found to be <1.0. Total Hardness (as CaCO3) are found 148.98 to
911.63 mg/L. Total Alkalinity varied from 160 to 350 mg/L. Chlorides and Sulfates are found 33.47
to 179.16 mg/L and 23.76 to 254.34 mg/L respectively.
3.7 Land Environment
3.7.1 Soil Quality
Soil samples were collected from 10 locations during December 03-09, 2018 within the study area
to assess its physico-chemical characteristics. The analysis results of soil samples are given in Table
3.12.
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TABLE 3.12 PHYSICO-CHEMICALS CHARACTERISTICS OF SOIL
Sr. No.
Parameters
Project Site
Nandesari
Bhetasi
Ambali
Kotna
Anagad
Hathipura
Undera
Padaml
a
Ajod
1 pH 8.58 7.59 7.89 7.89 8.34 7.88 7.67 7.83 7.49 7.15
2 Temper
ature (0C)
24.9 25.1 24.9 25.1 25.0 25.1 24.9 24.9 25.0 25.1
3 Moistur
e (%) 6.83 4.09 2.72 5.30 6.12 2.29 4.01 6.12 1.76 2.18
4 So4—2
(mg/kg) 2198
.1 523.8 970.8 3314.3 351.4 580.7 1714.
9 879.
2 1239.8
587.3
5 Chlorid
es (mg/kg)
130.8
69.76 113.5 34.88 436.0 174.4 17.44 174.4
17.44
8.72
6 Organic Matter
(%)
6.27 4.85 5.35 5.13 5.32 4.33 7.15 5.52 4.78 6.53
7 Bulk
density (g/cm3)
1.22 1.25 1.54 1.67 1.28 1.43 1.42 1.43 1.36 1.25
8 Calcium (mg/kg)
144.8
201.2 120.7 185.1 80.4 80.4 96.5 120.7
48.2 32.1
9 WHC (%)
41.8 53.32 50.80 49.69 52.41 46.24 42.43 61.81
51.33
51.28
10 Porosity
(%) 53.9
6 52.83 41.84 36.98 51.69 45.95 46.08 45.8
3 48.6
0 52.83
11 Grain
Size (%)
Gravel 02 00 02 00 02 03 00 01 01 00
Coarse
sand 03 03 00 00 01 02 00 03 03 01
Medium
sand 05 04 00 05 01 08 01 02 02 03
Fine sand
09 08 12 08 07 06 09 07 07 06
Silt + Clay
81 85 86 87 89 81 90 87 87 90
12 Na
(mg/kg) 1532
.7 229.2 97.10 22.10 343.5 94.5 35.6 136.
4 79.2 93.10
13 Cu+2
(mg/kg) BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL
14 Fe+3
(mg/kg) 66.3
3 53.85 64.82 152.7 38.15 46.32 99.14 54.6
1 112.10
46.97
15 Cd
(mg/kg) BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL
16 K
(mg/kg) 22.7 32.8 79.1 30.1 26.5 18.4 26.4 87.0 25.7 20.7
17 Ni+2
(mg/kg) BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL
18 Pb+2
(mg/kg) BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL
Note:
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Minimum Detectable Limit: Nickel – 0.1 mg/kg, Copper – 0.5 mg/kg, Cadmium – 0.001 mg/kg, Lead – 0.001 mg/kg
3.7.2 Summary of Soil Quality
Parameters like Porosity, Water Holding Capacity, Bulk Density, etc. were considered. Based on the
soil analysis report, the following can be concluded: The porosity of soils varied from 36.98% to
53.96% and can be considered as moderate to good for air and water movement in the soil. The
Water Holding Capacity varied from 41.8% to 61.81%. Bulk Density varied from 1.22 to 1.67 g/cm3.
The moisture content varied from 1.76% to 6.83%.pH varied from 7.15 to 8.58. Calcium varied from
32.1 to 201.2 mg/kg. Sodium varied from 22.10 to 1532.7 mg/kg. Organic Matter varied from 4.33
to 7.15 mg/kg. Total Iron varied from 38.15 to 152.7 mg/kg.
3.8 Geological & Hydrological Data
3.8.1 Method of Preparation
The geological classification map has been prepared by extracting the areas under different
geological classification from the 1:2 million scale maps prepared by Geological Survey of India
(GSI) for the State of Gujarat. The map text has been modified in consultations with the Department
of Geology. University of Delhi. The project site, towns and village locations have been added for
ease of spatial reference. Locations of towns and villages have been extracted from CoI maps, SoI
topographical maps and confirmed with satellite data.
3.8.2 Description of Geological Classification & Area Under Different Formations
Following Table provides the major geological features and area under different geological
formations within a distance of 10 km from the project site.
3.8.3 Geological Map
A map depicting the major geological features in the project area is presented in Figure 3.3. The
map also marks the area within 10 km with project site as a Centre. Town and village locations are
also depicted to facilitate ease of reference.
Description of Geological Classification & Area Under Different Formations
Stratigraphy Area
(Sq. km.) Age Description
Q = Undifferentiated fluvial/ Aeolian/
coastal sediments
313.96 Holocene in
Quaternary period (1 million year to
recent)
Some gypsum deposits are found in these Quaternary sediments.
High potential for yielding significant quantities of ground
water. (Courtesy: Environmental Information Centre, New Delhi)
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FIGURE 3.3 MAJOR GEOLOGICAL FEATURES
3.9 Land Use Pattern
Land use, in general, reflects the human beings’ activities on land, whereas the word land cover
indicates the vegetation, agricultural and artificial manmade structures covering the land surfaces.
Identification and periodic surveillance of land uses and vegetation covers, in the vicinity of any
developmental activity is one of the most important components for a comprehensive
environmental impact assessment, which would help to determine the impact of the project
development activity on the land use pattern.
To determine the baseline land use pattern, at and around the project site, the required data have
been obtained from Published land use data i.e. census and gazetteer books of Vadodara district,
issued by the State Government.
3.9.1 Method of Data Preparation
The satellite data has been processed using ERDAS Imagine software supported with ground checks
and ground truth verification by qualified and experienced professionals. Area and distance
calculations have been carried out using GIS software after geo-referencing the interpreted data
with the help of SoI topographical maps of 1:50,000 scale.
A map depicting major land use/ land cover classes comprising lands under agriculture, fallow land,
open/degraded vegetation; lands falling under water bodies, marshes and sand beds, open/rocky
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lands and lands under inhabitations is presented at Figure 3.4. The map also marks the area within
10 km of the project site as the region of interest.
PROCESS METHODOLOGY
AREAS UNDER DIFFERENT LAND USE
Courtesy: Environmental Information Centre, New Delhi
Procurement of
Satellite Imagery
Preparation of Base
Map using
Data Preparation
- Radiometric correction - Geometric correction
Preparation of
Signature Confusion
First Level Classification
Field
Verification/Ground
Updated information
from field
Second Level
Classification
Accuracy Estimation Area Estimation Map Output
Pre field process
Field process
Post field process
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FIGURE 3.4 LAND USE / LAND COVER
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3.10 Toposheet
FIGURE 3.5 TOPOSHEET
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3.11 Ecological Information
Nandesari is in the middle of Gujarat’s “Golden Corridor” a 400 km belt of industrial estates. It is
located at the bank of Mahi River. The main occupation of inhabitants besides industry is
agriculture.
Drainage Area - Mahi River is Interstate river and cover parts of Gujarat, Rajasthan and Madhya
Pradesh. The contribution of Gujarat state is about 11,694 sq. km (33.6%) of the total drainage area
34,842 sq. km of Mahi.
Topography – A majority of the area covered by Mahi River basin in Gujarat is plains having
elevation less than 300 meter above MSL, whereas less than 50 meter above MSL in the coastal
region.
Soils – The principal soil types found in the Basin of Mahi River are listed in below table. The
percentage distribution of the soil types is also included.
{Courtesy-CPCB Publication-Quality of Major Rivers Gujarat state (The Biennium 1979 & 1980 Survey)} Ground Water Availability – The summary of the ground water availability in the Mahi river basin within the state boundary of Gujarat is given in below table. However, reduction in yield is reported blaming the water and soil pollution from industries.
Pollution of Mahi River was first reported in 1968. Several incidences of death of fishes and cattle
because of consumption of contaminated water from tanks and wells have been reported. The
Government of Gujarat built a 56 km long effluent channel to divert industrial waste from Nandesari
and other estates into the Gulf of Cambay. But the source has been used as a free source of irrigation
water thus contaminating soil.
Sr. No. Type of Soil Mahi River Basin 1 Coastal Alluvial 3.5% 2 Deep Black 12.5% 3 Medium Black 78.0% 4 Grey Brown 6.0% 5 Lateritic Soil -
Total 100%
Sr. No. Classification of Aquifers Mahi River Basin 1 Fairly Extensive Thick Aquifers 10% 2 Aquifers of Limited extent 25% 3 Aquifers of Restricted extent 65% 4 Restricted Aquifers with Saline/Brackish water -
Total 100%
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3.11.1 Flora
Some of the flora found in area is listed below:
TABLE 3.13 LIST OF FLORA
Common name Scientific name Family
Kend Diospyros melanoxylon Ebenaceae
Salga Boswellia serrata Burseraceae
Palas Butea frondosa Fabaceae
Chihunt Butea superba Fabaceae
Kachnar Bauhinia purpurea Fabaceae
Bauhinia varigata Fabaceae
Chihor Bauhinia vahlii Fabaceae
Harre Terminalia chebula Combretaceae
Bahera Terminalia bellerica Combretaceae
Amla Embelica officinales
Red cotton tree Salmalia malabaricum
Van kapas Gossypium sp. Malvaceae
Karaunji Sterculia urens Sterculiaceae
Sabai grass Ischoemum augustifolium
Gular Ficus glomerata Moraceae
Mahua Madhuca latifolia Sapotaceae
Bamboo Dendracalamus strictus Poaceae
Ainthia dhamin Helicteres isora Sterculiaceae
Amaltas Cassia fistula Fabaceae
Karjani Abrus precatorius Fabaceae
Dudh koraiya Wrightia tomentosa
Dudhi Holarrhena antidysentrica Apocynaceae
Nepali liliac Hamiltoni suaveolens Fabaceae
Bhorkhorn Hymenodictyon excelsum
Asan Terminalia tomentosa Combretaceae
Kahua Terminalia arjuna Combretaceae
Dhaw Anogeissus latifolia Combretaceae
Silver/bridal creeper Porana paniculata
Mango Mangifera indica Anacardiaceae
Pipal Ficus religiosa Moraceae
Banyan Ficus bengalensis Moraceae
Pakur Ficus infectoria Moraceae
Babul Acacia arabica Fabaceae
Guhiya babul Acacia farnesiana Fabaceae
Sohora Streblus aspher Moraceae
Nim Melia azadirachta Meliaceae
Siris Albizzia lebbek Fabaceae
Jiyal Odina wodier Asteraceae
Palmyra Phoenix flabellifer Arecaceae
Jamun Eugenia jambolana Myrtaceae
Bel Aeglemarmelos Rutaceae
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Jackfruit Tree Artocarpus integrefolia Moraceae
Bagnai Capparis horrida Capparaceae
Madar Calotropis gigantea Asclepiadaceae
Samalu Vitex negundo Verbenaceae
Jasmine
Koa Rosa involucarta Rosaceae
Mexican poppy Argemone mexicana Papaveraceae
Source : Environmental Information Centre, New Delhi
3.11.2 Fauna
TABLE 3.14 LIST OF FAUNA
Scientific Name Common Name Suncus murinus House shrew
Cynopterus sphinx Short nosed fruit bat Taphozous longimanus Long armed seathed tailed bat Taphozous nudiventris Naked bellied tomb bat
Manis crassicaudata Indian Pangolin Vulpes bengalensis Common Indian fox Viverricula indica Indian civet Lepus nigricollis Indian hare
Fenambulus pennanti Northern Palm Squirrel Tatera indica Indian Gerbil
Bandicota bengalensis Indian mole rat Grus antigone Saras
Calotes versicolor Typhlops braminus Blind/worm snake
Eryx conicus Russell’s sand boa Chersydrus granulatus Elephant trunk snake
Ptyas mucosus Dhaman Rana cyanophlyctis Skipping frog
Hilsa ilisha Hilsa fish Chela cachius
Source : Environmental Information Centre, New Delhi.
3.12 Socio - Economic Environment
An assessment of socio - economic environment forms an integral part of an EIA study. Therefore,
baseline information for the same was collected during the study period. The baseline socio -
economic data collected for the study region, before the proposed expansion project is operational,
has been identified for the four major indicators viz. demography, civic amenities, economy and
social culture. The baseline status of the above indicators is compiled in forthcoming
sections.
3.12.1 Demography
The population details (i.e. population distribution and population density) of the Taluka Vadodara,
District Vadodara and the study area within 10 km radius are presented in Table-3.16 & its
graphical representation is given in Figure-3.6.
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TABLE 3.15 DEMOGRAPHIC DATA (1)
Sr.
No. Village Name
CD Block Name
No. of Househ
old
Total Populati
on
Total
Male
Total Fema
le
Population <06 years
Male<06
years Female<06 years
1 Fajalpur
(Sankarda) Vadoda
ra 950 4740 249
2 2248 604 326 278
2 Anagadh Vadoda
ra 2815 14780 765
0 7130 2112 1130 982
3 Nandesari (CT) Vadoda
ra 1717 8290 437
3 3917 1009 526 483
4 Vasad Vadoda
ra 780 3613 188
6 1727 349 194 155
5 Kanthariya Vadoda
ra 137 574 304 270 59 29 30
6 Bhanpura Vadoda
ra 124 1158 617 541 158 86 72
7 Ambali Vadoda
ra 206 934 487 447 102 53 49
8 Kanvadi Vadoda
ra 638 5214 275
9 2455 665 379 286
9 Amroli Vadoda
ra 444 2234 113
6 1098 297 152 145
10 Dodka Vadoda
ra 716 3724 196
9 1755 524 272 252
11 Rayaka Vadoda
ra 361 1981 102
6 955 262 131 131
12 Sankarda Vadoda
ra 1472 7460 390
8 3552 838 455 383
13 Ajod Vadoda
ra 526 2661 138
8 1273 316 170 146
14 Padmala Vadoda
ra 1059 5446 285
1 2595 676 352 324
15 Dhanora Vadoda
ra 255 1254 655 599 162 89 73
16 Dasharath Vadoda
ra 2349 11438 595
5 5483 1337 702 635
17 Kotna Vadoda
ra 594 2902 146
2 1440 394 207 187
18 Koyli Vadoda
ra 2193 10691 554
4 5147 1144 619 525
19 Ankaliya Vadoda
ra 240 1067 571 496 130 70 60
20 Rajupura Vadoda
ra 216 988 509 479 126 62 64
21 Sundarpura Vadoda
ra 283 1267 655 612 158 77 81
22 Sokhda Vadoda
ra 2454 12610 654
6 6064 1404 767 637
23 Sisva Vadoda
ra 533 2799 144
8 1351 362 185 177
24 Sherkhi Vadoda
ra 1841 9464 487
4 4590 1182 636 546
25 Ankodiya Vadoda
ra 937 4608 240
6 2202 466 260 206
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Sr. No. Village Name
CD Block name
Population
Schedule caste
Male Schedule caste
Female Schedule caste
Population
Schedule tribe
Male Schedule tribe
Female Schedule tribe
1 Fajalpur
(Sankarda) Vadoda
ra 154 86 68 24 12 12
2 Anagadh Vadoda
ra 490 260 230 76 41 35
3 Nandesari (CT) Vadoda
ra 211 105 106 107 52 55
4 Gavasad Vadoda
ra 311 162 149 28 15 13
5 Kanthariya Vadoda
ra 33 18 15 226 117 109
6 Bhanpura Vadoda
ra 48 28 20 35 19 16
7 Ambali Vadoda
ra 23 13 10 304 155 149
8 Kanvadi Vadoda
ra 256 168 88 147 79 68
9 Amroli Vadoda
ra 86 42 44 1951 989 962
10 Dodka Vadoda
ra 219 128 91 1 1 0
11 Rayaka Vadoda
ra 133 78 55 0 0 0
12 Sankarda Vadoda
ra 297 150 147 85 43 42
13 Ajod Vadoda
ra 267 150 117 166 87 79
14 Padmala Vadoda
ra 489 264 225 95 46 49
15 Dhanora Vadoda
ra 19 8 11 318 177 141
16 Dasharath Vadoda
ra 982 494 488 670 367 303
17 Kotna Vadoda
ra 14 6 8 0 0 0
18 Koyli Vadoda
ra 464 224 240 309 157 152
19 Ankaliya Vadoda
ra 160 86 74 68 40 28
20 Rajupura Vadoda
ra 103 49 54 209 110 99
21 Sundarpura Vadoda
ra 147 75 72 269 144 125
22 Sokhda Vadoda
ra 571 295 276 698 379 319
23 Sisva Vadoda
ra 212 114 98 125 69 56
24 Sherkhi Vadoda
ra 275 141 134 123 64 59
25 Ankodiya Vadoda
ra 661 342 319 556 286 270
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TABLE 3.16 POPULATION DENSITY
Name Population (Persons)
Population Density
(Person / sq. km.)
Sex ratio (No. of females per 1000
males)
Within 5 km Radius (2011)
1,03,532 362 886
Within 10 km Radius (2011)
1,21,897 426 902
Vadodara Taluka (2011) 20,09,434 488 919 Vadodara District (2011) 41,65,626 552 934
(Courtesy : Census Dept., GOI)
FIGURE 3.6 POPULATION DENSITY
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3.12.2 Literacy Rate
The literacy rate is a major factor, which influences the socio-cultural condition of a particular place.
Details of literacy rate in District Vadodara, Taluka Vadodara and within 10 km radius and 5 km
radius of project site are given in Table 3.17 while their graphical representation is shown in Figure
3.7. It is observed that the literacy rate of Vadodara District as per 2011 Census data is 69.45 %,
with 74.94 % among male and 63.57 % among female. Literacy rate in Taluka Vadodara as per 2011
Census data is 80.62 % with 83.59 % among males and 77.39 % among females. Within 10 km
radius of the study area, the literacy rate is 74.97 %, with 80.71 % among male and 68.73 % among
female. Literacy rate in 5 km study area as per 2011 Census data is 46.32 % with 62.14 % among
males and 54.56 % among females.
Literacy rate at District level (Vadodara) is observed lesser then that within 5 km of the study area,
within 10 km of the study area and Taluka Level (Vadodara). But literacy rate at Taluka level
(Vadodara) is observed higher than that within 5 km of the study area, within 10 km of the study
area and District Level (Vadodara).
TABLE 3.17 LITERACY RATE
Name Male Literacy (%)
Female Literacy (%)
Total Literacy (%)
Within 5 km Radius (2011) 62.14 54.56 46.32
Within 10 km Radius (2011)
80.71 68.73 74.97
Vadodara Taluka (2011) 83.59 77.39 80.62
Vadodara District (2011) 74.94 63.57 69.45
(Courtesy: Census Dept., GOI)
FIGURE 3.7 LITERACY DATA
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3.12.3 Occupational Structure
In economic development of the region its geographical location, natural resources, business and
employment, industries and manpower play vital role. Table 3.18 provides the occupational
patterns in all villages falling within the area of interest.
TABLE 3.18 OCCUPATIONAL STRUCTURE
Sr. No.
Village Name
CD Bloc
k nam
e
Total Work Population
Main worke
r Population
Main Cultivator
Population
Main Agriculture Population
Main Household
Population
Main Other Population
Marginal
Worker
Population
Non-Work
er Population
1 Fajalpur (Sankarda)
Vadodara
1941 1333 303 353 15 662 608 2799
2 Anagadh Vadodara
5048 4204 692 991 79 2442 844 9732
3 Nandesari (CT)
Vadodara
3200 2520 268 204 7 2041 680 5090
4 Gavasad Vadodara
1274 1206 215 599 37 355 68 2339
5 Kanthariya Vadodara
279 238 84 127 0 27 41 295
6 Bhanpura Vadodara
379 358 187 71 6 82 24 924
7 Ambali Vadodara
367 313 211 86 2 14 54 567
8 Kanvadi Vadodara
2786 2060 1101 653 30 276 726 3030
9 Amroli Vadodara
1225 553 138 310 5 100 672 1009
10 Dodka Vadodara
1403 1164 503 290 27 344 239 2321
11 Rayaka Vadodara
620 550 114 104 8 324 70 1361
12 Sankarda Vadodara
3178 2557 550 788 72 1147 621 4282
13 Ajod Vadodara
883 869 285 297 0 287 14 1778
14 Padmala Vadodara
1979 1638 161 730 10 737 341 3467
15 Dhanora Vadodara
614 338 166 137 1 34 276 640
16 Dasharath Vadodara
3886 3472 165 734 34 2539 414 7552
17 Kotna Vadodara
909 538 181 175 14 168 371 1993
18 Koyli Vadodara
3832 3225 253 838 25 2109 607 6859
19 Ankaliya Vadodara
648 493 52 394 9 38 155 419
20 Rajupura Vadodara
428 356 66 198 0 92 72 560
21 Sundarpura Vadodara
571 515 42 143 0 330 56 696
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22 Sokhda Vadodara
4915 4230 928 1905 30 1367 685 7695
23 Sisva Vadodara
1417 919 188 499 7 225 498 1382
24 Sherkhi Vadodara
3362 2940 1051 776 35 1078 422 6102
25 Ankodiya Vadodara
1736 1683 321 603 13 746 53 2872
3.12.4 Amenities
Infrastructure resource base of the surveyed villages with reference to education, medical, water
resources, post and telegraph, communication, power supply is presented in Table 3.19. There are
40 villages within study area of 10 km radius of plant site. Significant observations with respect to
availability of amenities in study area are as follows.
All of the villages have primary schools, 17 villages have both primary and secondary education
schools. 4 villages have adult education facility. All of the villages in the impact zone have
community health workers, 26 villages have primary health sub center, 27 villages have registered
private practitioners while 14 villages have family planning center, 3 villages have primary health
center. 2 maternity homes, 3 child welfare centers, 1 nursing home, 12 dispensaries and 1 hospital
are also available in the impact zone.
In the study area drinking water facilities are good as tap water and well water is available almost
in all the villages, 3 villages have hand pumps. Tank water is available in 22 villages, 16 villages get
water from tube well, 3 from canal and 1 from nallah also. Post office facility is available in almost
in all villages while 4 villages have post and telegraph facility. Telephone facility is available in 26
villages. 36 villages are well connected through a network of Pucca road. 25 villages have Kuccha
approach road. Bus is the main mode of transportation and is available in 39 villages, 4 villages are
connected with railways and 2 with Navigable waterway. All the villages get electricity for all
purpose i.e. domestic, agriculture and industrial.
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TABLE 3.19 DETAILS OF AMMENITIES AVAILABLE IN STUDY AREA Sr. No.
Village Educational Medical Drinking Water
Post & Telegraph
Communication
Approach to
Village
Nearest Town
Power Supply
1 Fajalpur (Sankarda)
P PHS, FPC, CHW T, W, TK, TW PO, Phone BS PR, KR Fertilizer Nagar-12
EA
2 Anagadh P(6), H, Ac MCW, PHS, D, FPC, RP(2), CHW
W, TW, R PO, Phone BS, NW PR, KR Jawahar Nagar-6
EA
3 Nandesari (CT)
P(3), H PHS, D, RP, CHW(3) T, W, TK, TW PO, Phone BS PR Ranoli-3 EA
4 Vasad P(3), H, PUC, Ac
H, PHC, D, RP, CHW T, W, TK, TW, HP, R, C
PTO, Phone BS, RS PR, KR Anand-20 EA
5 Kanthariya P(3) PHS, RP(2), CHW(2) T, W, TK PO, Phone BS PR, KR Borsad-5 EA
6 Bhetasi (Talpad)
P(3), H, PUC
PHS, RP, CHW T, W, C PO, Phone BS, RS PR, KR Borsad-14 EA
7 Bhetasi Ba Bhag
P, H, PUC RP(2), CHW(3) T, W PO, Phone BS PR, KR Borsad-15 EA
8 Bhanpura P CHW T, W, R PO BS PR Borsad-14 EA
9 Betasi Vanto P(2) PHS, RP, CHW T, W PO, Phone BS PR, KR Borsad-13 EA
10 Ambali P(2) RP(2), CHW T, W PO, Phone BS PR Borsad-20 EA
11 Kanvadi P(2), H PHS, CHW(3) T, W PO BS PR, KR Borsad-23 EA
12 Amrol P(3) PHS, CHW T, W PO, Phone BS PR, KR Borsad-15 EA
13 Dodka P, H D, FPC, CHW W, TK, TW PO BS PR, KR Ranoli-9 EA
14 Rayaka P(3), H PHS, D(2), RP(2), CHW W, TK, TW, HP, R
PO -(-5 Kms)
PR, KR Fertilizer Nagar-8
EA
15 Sankarda P PHS, FPC, RP(3), CHW T, W, TK, HP, R, N, O
PO, Phone BS PR Fertilizer Nagar-6
EA
16 Ajod P PHS, FPC, RP, CHW T, W, TK, TW PO BS PR, KR Fertilizer Nagar-2
EA
18 Padmala P PHS, D, FPC, RP(2), CHW
T, W, TK PO, Phone BS PR Fertilizer Nagar-5
EA
19 Dhanora P(2) RP(2), CHW(2) T, W, TK, R PO, Phone BS PR Jawahar Nagar-5
EA
20 Dasharath P(2), H, Tr PHS, D, FPC, RP(4), CHW(4)
T PO, Phone BS PR Fertilizer Nagar-1
EA
21 Kotna P PHS, CHW W, TK, TW, R PO BS PR Jawahar Nagar-8
EA
22 Koyli P(2), H MCW, MH, CWC, PHS, D, RP(7), CHW(8)
T, W, TK PTO, Phone BS PR Jawahar Nagar-1
EA
23 Ankalavdi P(2) PHS, FPC, CHW T, W, TK, TW, C
PO, Phone BS PR, KR Anand-12 EA
24 Rajupura P, O RP, CHW T, W, R PO BS PR, KR Anand-25 EA
25 Sundan P, H, Ac(3) PHS, FPC, RP, CHW T, W, TK PO, Phone BS, RS PR, KR Anand-18 EA
26 Mujkuva P(3) PHS, RP, CHW, O T, W PO, Phone BS PR, KR Borsad-12 EA
27 Anklav (Town)
P(6), H(2), PUC, Tr(2)
MCW, MH, CWC, PHC, D, FPC, NH, RP(5)
T, W, TW PTO, Phone BS, RS PR, KR Borsad-18 EA
28 Asarma P(2) PHS, CHW T, W, R PO, Phone BS PR, KR Borsad-20 EA
29 Hathipura P RP, CHW T, W -(-5 Kms) BS KR Borsad-16 ED, EAG
30 Umeta P, H PHS, D, FPC T, W, R PO, Phone BS PR Borsad-25 EA
31 Khadol (Umeta)
P(3) CHW T, W, TW, R PO BS, NW PR, KR Borsad-24 EA
32 Moksi P, H, Ac PHS, FPC, RP, CHW T, W, TK, TW PO, Phone BS KR Vadodara-28 EA
33 Poicha (Raniya)
P, H RP(2), CHW T, W, TK, TW, R
PO BS KR Vadodara-16 EA
34 Khandi P CHW T, W, R PO BS PR Vadodara-20 EA
35 Vasna-Kotariya
P PHS, CHW T, W, TK PO, Phone BS PR, KR Fertilizer Nagar-10
EA
36 Sokhda P(7), H, PUC
CWC, PHC, D, RP(4), CHW
T, W, TK, TW, R
PTO, Phone BS PR, KR Fertilizer Nagar-6
EA
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37 Sisva P PHS, FPC, RP, CHW T, W, TK, TW, O
PO, Phone BS PR, KR Fertilizer Nagar-2
EA
38 Sindrot P(6), H PHS, D, FPC, RP, CHW(3)
T, W, TK, TW, R
PO BS PR, NR Vadodara-24 EA
39 Sherkhi P(4) PHS, FPC, RP, CHW(3) T, W, TK, R PO BS PR Vadodara-8 EA
40 Ankodiya P PHS, RP(2), CHW T, W, TK PO, Phone BS PR Jawahar Nagar-6
EA
(Courtesy : Census Dept., GOI)
ABBREVIATIONS
1. Education P-Primary Elementary School H-Matriculation or Secondary O-Other Educational Institution PUC-Higher Secondary/Intermediate/pre-University/junior College Ac- Adult Literacy Class Tr-Training School
2. Medical Facilities RP-Registered Private Practitioner PHS-Primary Health Sub-Centre FPC-Family Planning Centre PHC-Primary Health Centre D- Dispensary CHW - Community Health Worker/Health Worker H - Hospital NH - Nursing Home MH - Maternity Home PHC - Public Health Centre CWC - Child Welfare Centre TB - T.B Clinic O – Others
3. Drinking Water T-Tap Water HP-Hand Pump TK-Tank Water W-Well Water R-River Water C-Canal N - Nallah S – Spring TW- Tube well Water
4. Post & Telegraph PO-Post Office PTO-Post & Telegraph Phone-Telephone Communication
5. Communication BS-Bus Station NW-Navigable Waterway
6. Approaches to Village PR-Pucca Road KR-Kuchcha Road
7. Power Supply EA-Electricity for all purposes EAG - Electricity for Agriculture ED - Electricity for domestic EO - Electricity for other purpose like Industrial, Commercial etc.
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CHAPTER – 4: ANTICIPATED ENVIRONMENTAL IMPACTS &
MITIGATION MEASURES
4.1 General
In this chapter, the anticipated environmental impacts and the proposed mitigation measures for
the proposed project have been described.
An impact can be defined as any change in Physical, Chemical, Cultural and/or Socioeconomic
environment that can be attributed to activities related to alternatives under study for meeting
project needs. Impact identification methodology provides an organized approach for prediction
and assessing these impacts. Scientific techniques and methodologies based on mathematical
modelling are available for studying impacts of various project activities on environmental
parameters.
Generally, the environmental impacts can be categorized as either primary or secondary. Primary
impacts are those, which are attributed directly by the project. Secondary impacts are those, which
are indirectly induced and typically include the associated investment and changed patterns of
social and economic activities by the proposed action.
Chemicals manufacturing Industry may cause adverse impacts on surrounding environment unless
proper Environmental Management Plan is implemented. Selecting suitable mitigative measures in
terms of site selection, technology, machinery and operations can minimize the possible negative
impacts.
In this chapter, an attempt has been made to identify and quantify possible impact on various
environmental parameters such as Air, water, land, Noise and socio-economic factors. The
following aspects of environment have been studied to identify the possible impacts due to the
industrial activities.
• Air Environment
• Noise Environment
• Water Environment
• Land Environment
• Occupational health
• Socio-economic Environment
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4.2 Details of anticipated environmental impacts due to project location,
project design, project construction, regular operations of a project.
(Impact Assessment Matrix)
Identification of impacts has been carried out by determination of impacting activities of the
proposed project. Then based on the outcome of the first part, further classification of impacts
based on types & nature has been carried out to identify all probable impacts in detail.
From the Table-4.1 significant impacts are identified. They are further elaborated with
characterization and assessment in Table-4.2.
TABLE 4.1 IMPACT IDENTIFICATION MATRIXES
Aspects
Environmental Attribute
Air
Noise
Water
Land & soil
Socio Economi
cs
Aesthetics
Construction Activity
Handling & Charging of Raw Materials
Operation of TFH & DG Operation of Domestic Utilities
Operation of ETP Isolated Storage Facilities Storage Facilities of Liquid Raw material/Products
Storage Facilities of Solid Raw material/Products
Transportation of Raw material/Products Development of Greenbelt
Employment Generation
The proposed project being an existing unit located in GIDC Nandesari, requires water, power, fuel,
human resources, machineries & utilities etc. Considering the details of resource requirements and
potentials of pollution as well as above tabulated identified impacts on environment; impact
statements have been prepared after necessary detailed study. The impacts statements for the
proposed project as predicted & assessed are described in subsequent section under respective
headings.
4.3 Assessment of Significance of Impacts (Criteria for Determining
Significance, Assigning Significance) & Mitigation Measures
For assessing the impact, the baseline data of environmental status were considered. The change
in the environmental parameters due to manufacturing activities of the industry has been
superimposed on the status data.
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TABLE 4.2ENVIRONMENTAL IMPACT ASSESSMENTS
Environmental Attributes
Cause / Source
Impact Characteristics
Nature Duratio
n Reversibilit
y
Significance, Mitigative Measures
ACTIVITY: Handling & Charging of Raw Materials/Products
Air Quality (Fugitive
Emissions)
Handling operations for
transfer, charging of
raw materials, final product- manually or
through pipeline: spillage,
fugitive dust / vapor
emission and leakage due to
improper flanges
connection or gland leaks.
Indirect Negativ
e
Long Term
Reversible
Low, management to ensure proper handling of the spillages during
transfer. Preventive
maintenance of flange connections
and glands of pumps.
Besides, the management will
also ensure proper usage of the Personnel Protective
Equipment by the workers.
Regular Workplace Monitoring,
Ambient Air, Stack Air Monitoring to be
done.
Water, Land
Generation of wastewater
from the cleaning of spilled Raw
Material.
Direct Negativ
e
Long Term
irreversible
Wastewater to be treated at the in-house ETP and
Treated Effluent of 40 KLD will be
passed through RO Plant to recover
50% of the wastewater. 20KLD recovered ETP RO Permeate will be
utilized for cooling tower makeup & 20 KLD ETP RO Reject
will be taken to MEE plant for
evaporation. MEE Condensate of
19.6KLD also to be recovered for reuse.
Hazardous Waste
Generation of Hazardous Waste from
the spilled raw materials
Direct Negativ
e
Long Term
Reversible
Hazardous waste to be collected, contained &
disposed as per the spill procedures &
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Environmental Attributes
Cause / Source
Impact Characteristics
Nature Duratio
n Reversibilit
y
Significance, Mitigative Measures
hazardous waste management rules.
ACTIVITY: Operation of Thermic Fluid Heater (TFH)
Air Quality
Emission of pollutants
(PM, SO2, NO2) along with flue
gas after combustion of
the fuel for operation of
the TFH
Direct Negativ
e
Long Term
Reversible
Adequate Stack height will be
provided as APCM.
The flue gas will be emitted into the
atmosphere through stacks of TFH each with height of 30 m & stack of DG with
height of 5 m.
Noise
Noise generation
due to operation of
TFH & DG set.
Direct Negativ
e
Long Term
Reversible
Noise Generation due to operation of the Pumps & Draft
Fans. Anti-Vibration pads will be
provided wherever necessary. Preventive
Maintenance to be done and PPE like
ear plugs to be provided. DG set to
be acoustically enclosed.
Hazardous Waste
Annual Maintenance for cleaning TFH - solid
waste generation during the
cleaning-up operation.
Direct Negativ
e
Long Term
Reversible
The solid waste generated will be
sent to TSDF/CHWI site for disposal along with other hazardous waste.
Co-Processing
ACTIVITY: Operation & maintenance of Domestic Utilities
Water
Operation of Washroom,
toilets - Wastewater generation
Direct Negativ
e
Long Term
Irreversible
Domestic effluent (sewage) will be
disposed through Septic Tank & Soak
Pit. ACTIVITY: Operation & Maintenance of ETP
Water Treatment of wastewater
Direct Negativ
e
Long Term
Reversible
Wastewater to be treated at the in-house ETP and
Treated Effluent of 40 KLD will be
passed through RO Plant to recover
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Environmental Attributes
Cause / Source
Impact Characteristics
Nature Duratio
n Reversibilit
y
Significance, Mitigative Measures 50% of the
wastewater. 20KLD recovered ETP RO Permeate will be
utilized for cooling tower makeup & 20 KLD ETP RO Reject
will be taken to MEE plant for
evaporation. 19.6 KLD MEE
Condensate to be recovered for reuse.
Air Quality Dosing of treatment chemicals
Direct Negativ
e
Long Term
Reversible
To ensure proper handling & dosing of
treatment chemicals.
Spent solvents to be recovered in the Solvent Recovery
plant.
Land
Storage of the treatment chemicals,
wastes, within the premises -
Separate storage area
provision
Direct Negativ
e
Long Term
Reversible
Designated storage area with proper
roof and impervious flooring to avoid soil contamination due
to leachate infiltration during
Monsoon. Leachate collection, conveyance to ETP. Hazardous wastes are to be disposed
as per the hazardous waste
authorization requirements.
Hazardous Waste
Generation of Haz. waste
Direct Negativ
e
Long Term
Reversible
The hazardous waste will be sent to
secured land fill facility for final
disposal ACTIVITY: Storage Facilities
Land
Handling operations of
the Raw material, solid
waste, unloading and
Direct Negativ
e
Long Term
Reversible
Management will ensure good
practices during transfer operations
to avoid any spillage of the solid wastes.
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Environmental Attributes
Cause / Source
Impact Characteristics
Nature Duratio
n Reversibilit
y
Significance, Mitigative Measures
loading. Collection of the spilled material,
storage and loading the
same into the trucks, for disposal.
Concreted area around storage
facilities to prevent seepage of the
spilled material to the soil.
Air quality
Emissions into the
atmosphere due to the storage of chemicals
during storage resulting in
odor nuisance
Direct Negativ
e
Long Term
Reversible
Chemicals to be kept covered and at
dedicated storage area.
Land
Transfer of material from
drums – spillage /
Leakage of material during
loading, unloading and transfer, due
to gland leakage of
pumps, flange leakage in
pipelines and due to manual
operation. - Generation of solid waste of Spillage clean-
up of the material using Water, sand / gypsum and treatment of
the wash water.
Direct Negativ
e
Long Term
Reversible
Regular maintenance of
pumps and flange connections in
pipelines should be ensured by the management.
Impervious flooring to be provided to avoid contact of
spilled material with soil.
Dyke walls to be constructed
ACTIVITY: Storage of Raw Materials/Products
Hazardous Waste
Storage of all the solid raw materials in
the plant area
Direct Negativ
e
Long Term
Reversible
Chemicals shall be stored, by taking
necessary measures to avoid
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Environmental Attributes
Cause / Source
Impact Characteristics
Nature Duratio
n Reversibilit
y
Significance, Mitigative Measures
in Drums / HDPE bags
and transfer to the
operational / processing
area – spillage, disposal of used bags.
contamination of Land & water during
monsoon. Ensure safe disposal of the empty containers &
liners to registered/approve
d recyclers. Relevant records to be maintained.
Land, Water
Storage of all the liquid raw
materials within the
plant area and transfer to the operational /
processing area – spillage
/ leakage, disposal of
used drums.
Direct Negativ
e
Long Term
Reversible
Chemicals shall be stored, by taking
necessary measures to avoid
contamination of Land & Water
during monsoon and ensure safe disposal of the empty drums
to registered/approve
d recyclers. Relevant records to be
maintained. Dyke Walls to be made at storage tanks with
valve & Pump arrangements to contain spillages
&Leakages. ACTIVITY: Transportation of Raw Materials/Products, Hazardous Wastes
Transportation
Transportation of all the raw
materials, finished
products and hazardous
wastes
Direct Negativ
e
Long Term
Reversible
Trained transporters to be
engaged for transport of hazardous
materials, spill control & other
emergency actions. MSDS of all raw
materials & finished products shall be kept available at
storage area & with the concerned departments.
The vehicles used for transporting
hazardous materials shall follow the
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Environmental Attributes
Cause / Source
Impact Characteristics
Nature Duratio
n Reversibilit
y
Significance, Mitigative Measures applicable
guidelines given in The Motor Vehicles
Act. Activity: Solvent Recovery
Water / Hazardous
waste
Generation of wastewater after solvent
recovery.
Direct Negativ
e
Long Term
Irreversible
Wastewater to be treated in the ETP,
The hazardous waste i.e. Distillation residue to be sent to
CHWI of NECL Nandesari / Co-
Processing
Air Quality
Emissions into the
atmosphere due to the
operation of Solvent
recovery plant.
Direct Negativ
e
Long Term
Reversible
95% solvent to be recovered. Fugitive
emissions to be controlled.
Activity: Employment Generation
Socio Economic Direct & Indirect
Employment
Direct Positive
Long Term
-
Positive Impact due to hiring of manpower.
Benefits in the form of contracts to local
agencies for different services
Employment generation in
transport sector as local conveyance trips and trucks loadings will be
handled regularly. Activity Green Belt Development
Green belt
Development of green belt
for mitigation of pollution, Plantation of
trees within & at periphery of
premises
Direct Positive
Long Term
-
Positive Impact due to development of a
good green belt along the
periphery& within the premises
4.4 Overall Impacts
The impacts arising out of the said projects have been listed and studied in depth.
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4.4.1 Impact on Air Environment
Impact due to Vehicular movement
Dust will be generated during excavation and hauling operation and vehicle transportation. Other
exhaust gases may be also slightly released into the local ambient air due to vehicular traffic
movement. Thus, the local ambient air quality may be temporarily affected. It will be confined
within the project boundary and is expected to be negligible outside the plant boundary.
Mitigation measure
Water sprinkling and provision of enclosures will allow the particles to settle down prior to
discharge.
Operation Phase Impacts & Mitigation Measures
The main sources of air pollution will be flue gas emission. Flue gas emission will be from One
existing Thermic Fluid Heater & One proposed flue gas stacks of Thermic Fluid Heater & One
proposed flue gas stack of DG set. FO/LDO is being used as existing fuel & Natural Gas will be used
in the proposed Thermic Fluid Heater. Adequate Stack height to be provided for proposed Thermic
Fluid Heater.
Mitigation measures
Adequate Stack Height to be provided to Thermic Fluid Heater stack. DG to be housed Acoustic
enclosure to attenuate noise.
To ensure that all the pollution control facilities envisaged at the design stage are have been
implemented and are functioning properly. Stack monitoring to ensure proper functioning of
different pollution control facilities attached to all stacks. Adequate plantation will be done in and
around premises. Thus, proposed plant activities will have negligible impact on the air
environment.
4.4.1.1 Fugitive emission
The emissions are normally defined as emissions to the atmosphere resulting from leaking piping
sources and equipment such as valves, flanges, pump seals, connections, and compressor seals
open end lines and pressure relief valves. The emissions are not visually observed but can be
measured in relatively low concentration at each area of source.
Fugitive emissions are expected to be generated during construction and operation stages of the
proposed project. During construction stage, main source of fugitive emission is dust which is
expected mainly due to movement of vehicles carrying construction material and vehicles used for
construction. During operation stage, leakage through valves, pumps, emission from open drum
containing chemicals, open feeding; storage tanks, etc. are the major sources of fugitive emissions.
Excess use of solvent may also result into fugitive emission from the process vessels.
Mitigation measure
General control measures like routine & regular inspection to identify leakage, preventive
maintenance and operational maintenance etc. will be implemented by the unit.
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• Management to ensure proper handling of the spillages during transfer, charging operation and provision of a Caustic Scrubber as APCM for existing TFH, the stacks attached to storage tank area wherever applicable.
• Preventive maintenance of flange connections and glands of pumps.
• Adequate ventilation will be provided.
• Regular maintenance of valves, pumps, flanges, joints and other equipment will be done to prevent leakages and thus minimizing the fugitive emissions of VOCs.
• Entire process will be carried out in the closed reactors with proper maintenance of pressure and temperature.
• Periodic monitoring of work area will be carried out to check the fugitive emission.
• To eliminate chances of leakages from glands of pumps, mechanical seal will be provided at all solvent pumps.
• To avoid fugitive emission during sampling, the standard operating procedure shall be followed to draw sample from the sample point valve. During raw material, in-process and final finish product sampling, the due care shall be taken to avoid fugitive emission.
Further, it is emphasized that the mitigation measures discussed in table 4.2 of this chapter and
summarized in the Environmental Management Plan should be followed to maintain the air quality
within norms in the future.
The detailed air modelling for calculation of Ground Level Concentration of various pollutants has
been carried out using AERMOD Model.
4.4.2 Ambient Air Quality Modelling
Introduction
Ambient Air quality impact assessment is an important study; Mathematical modelling is
established to find the impact on environment due to flue gas emission has been assessed with the
help of modelling following the Central Pollution Control Board’s Guidelines. The mathematical
model used for conducting the study is the latest version 8.8.9 of Lakes AERMOD View, which is
entirely in line with the requirements of Central Pollution Control Board, New Delhi.
Project Location
The project site is located at Plot No. 133/4, 133/5, 133/6, GIDC Nandesari, Dist: Vadodara-
391340., Gujarat.
• 22°24'6.96"N, 73° 5'50.04"E
• 22°24'4.98"N, 73° 5'54.30"E
• 22°24'0.30"N, 73° 5'49.80"E
• 22°24'4.32"N, 73° 5'46.50"E
4.4.2.1 Details of Air Dispersion Model
The air quality impact of a source or group of sources is evaluated by the use of mathematical
models. The widely accepted interpretation models simulate the relationships between air
pollutant emissions and its impact on air quality. For the present study, this model is used for the
prediction of maximum ground level concentration (GLC).
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Assessment of air pollution is carried out for proposed stacks attached to TFH. The “Aermod-View”
from lakes and Environment is an hour-by-hour steady state Gaussian Plume Model. This model is
widely recognized as predictive tool in impact assessment for air environment. The Aermod view
model has been applied with elevated + flat terrain, gradual plume rise and buoyancy induced
dispersion options in the present study.
The inputs to the model include data relating to emissions, which are determined by formulating
impact scenarios. The meteorology and atmospheric details like ambient temperature, wind speed,
wind direction etc. was taken from Aqua Air Surat for the Period of October 2018 to December
2018. The site specific and monitored details considered for input data for the software “AERMOD View”.
The major point source emissions are the flue/process gases stacks. Details of all the major stacks
are as follow shown in table 4.3:
TABLE 4.3 FLUE GAS STACK EMISSION RATES
Sr.
Stack/Vent
Dia. Height
(m)
Exit Velocity (m/sec)
Temp Emission Rates (After
APCM) (gm/sec)*
No. (m) (°C)
PM SO2 NO2
Flue gas Stacks – Proposed Products
1 TFH Proposed
0.45 30 10 130 0.0925 0.00185 0.468 (40 Lac Kcal)
2 DG Set 0.2 5 10 100 0.004 0.019 0.009
Note:
(*) Actual stack emissions will be well below the permissible stack emissions limits. To consider worst case scenario the emission rates are considered on maximum Stack Emission Limit.
PM Based on maximum expected concentration of PM-150 mg/Nm3
SO2 Based on maximum expected concentration of SO2-100 ppm
NO2 Based on maximum expected concentration of NO2-50 ppm
4.4.2.2 Presentation of Result:
The simulations were made to evaluate Particulate Matter, Sulphur Dioxide and Nitrogen oxides
incremental short-term concentrations due to proposed expansion. These results are based on
considering the emission due to One existing & one proposed stack for thermic fluid heater & one
DG set. In the short-term simulations, the incremental concentrations were estimated to obtain an
optimum description of variations in concentrations within study area of 10 km radius. Maximum ground level concentration will be observed at different distance for Particulate matter,
Sulphur Dioxide and Nitrogen oxides. The maximum ground level concentration for different
parameters is given in below Table for proposed project. Equal concentration contour plots for the
PM, SO2 & NO2 are given in below Figure 4.2(a) & (b), 4.3(a) & (b), 4.4(a) & (b) respectively for
proposed project.
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The wind rose diagram for the Month of October 2018 to December 2018 is shown in figure: 4.1
FIGURE 4.1 WIND ROSE DIAGRAM
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TABLE 4.4. THE 1ST HIGHEST 24-HR AVERAGE CONCENTRATION OF PM, (µG/M3)
Direction Degrees
Distance in Meters
500 2090 2440 3490 5000 6050 6160 6400 7210 7330 9900 10000
360 0.69083 0.11805 0.0949 0.05602 0.0321 0.02338 0.02267 0.02125 0.01735 0.01687 0.01004 0.00986
22.5 0.78425 0.18257 0.15022 0.09594 0.06472 0.05434 0.05352 0.05148 0.04927 0.04894 0.04125 0.04095
45 1.84999 0.38931 0.30898 0.18102 0.1122 0.09089 0.08927 0.08545 0.07481 0.07348 0.05424 0.05372
67.5 0.99617 0.34784 0.29272 0.19287 0.12689 0.10229 0.10021 0.09566 0.08258 0.08085 0.05354 0.05277
90 1.4156 0.38182 0.32066 0.24712 0.19586 0.16933 0.16693 0.16188 0.14647 0.14438 0.10437 0.10312
112.5 0.24873 0.04173 0.03238 0.02033 0.01328 0.01099 0.0109 0.0107 0.00996 0.00986 0.00814 0.00809
135 0.64882 0.19683 0.16181 0.0977 0.05711 0.04603 0.04506 0.04307 0.03773 0.03759 0.03223 0.03197
157.5 0.25283 0.26009 0.26855 0.26259 0.22853 0.20433 0.20192 0.19676 0.18019 0.17787 0.13617 0.13482
180 0.68256 0.18041 0.1796 0.17859 0.18452 0.18469 0.18428 0.18316 0.17603 0.17479 0.14594 0.14482
202.5 0.49305 0.18311 0.15509 0.10187 0.06405 0.0494 0.04818 0.04568 0.03862 0.03773 0.02448 0.02413
225 2.58814 0.66814 0.54985 0.34026 0.27264 0.24468 0.24213 0.23675 0.22016 0.21788 0.17631 0.17483
247.5 1.3654 0.35185 0.30586 0.21114 0.13742 0.10909 0.10877 0.10796 0.10435 0.10373 0.08864 0.08804
270 0.83414 0.14974 0.11054 0.05135 0.02463 0.01827 0.01775 0.01669 0.0138 0.01345 0.00846 0.00833
292.5 0.09839 0.03154 0.02688 0.01852 0.01272 0.01094 0.01085 0.01064 0.00991 0.00981 0.00812 0.00806
315 1.3426 0.57102 0.50245 0.35227 0.22972 0.1788 0.17448 0.16559 0.14018 0.13693 0.08769 0.08634
337.5 0.28103 0.03656 0.03067 0.02302 0.01739 0.01461 0.01436 0.01384 0.0123 0.0121 0.00882 0.00873
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FIGURE 4.2 (A) ISOPLETHS MAP FOR PM
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FIGURE 4.2 (B)ISOPLETHS IN GOOGLE MAP FOR PM
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TABLE 4.5. THE 1ST HIGHEST 24-HR AVERAGE CONCENTRATION OF SO2, (µG/M3)
Direction Degrees
Distance in Meters
500 2090 2440 3490 5000 6050 6160 6400 7210 7330 9900 10000
360 0.03816 0.00608 0.00491 0.00295 0.00173 0.00129 0.00125 0.00118 0.00098 0.00096 0.0006 0.0006
22.5 0.04127 0.01202 0.01026 0.00738 0.00611 0.00582 0.0058 0.00568 0.00527 0.00521 0.00425 0.00422
45 0.09206 0.019 0.01524 0.00993 0.00819 0.008 0.00799 0.00788 0.00752 0.00748 0.00669 0.00666
67.5 0.0621 0.01698 0.01433 0.00978 0.00709 0.00647 0.00642 0.00624 0.00568 0.0056 0.00415 0.0041
90 0.08072 0.02129 0.01863 0.01611 0.01573 0.01468 0.01448 0.01406 0.01275 0.01257 0.00939 0.00929
112.5 0.02796 0.00353 0.00275 0.00156 0.00097 0.00082 0.00081 0.00078 0.00071 0.0007 0.00055 0.00054
135 0.03926 0.01043 0.01052 0.01091 0.00841 0.00697 0.00684 0.00657 0.00577 0.00566 0.00461 0.00459
157.5 0.02402 0.0128 0.01312 0.01271 0.01101 0.00984 0.00972 0.00947 0.00867 0.00856 0.00656 0.00649
180 0.03663 0.00857 0.00853 0.00971 0.01242 0.01312 0.01314 0.01317 0.01273 0.01264 0.01055 0.01046
202.5 0.02772 0.0099 0.00874 0.00666 0.00502 0.0043 0.00424 0.00411 0.00372 0.00367 0.00284 0.00282
225 0.15096 0.03703 0.03077 0.01941 0.01374 0.01288 0.0128 0.01266 0.01222 0.01216 0.01098 0.01092
247.5 0.08158 0.01672 0.01453 0.01005 0.00671 0.00558 0.0055 0.00535 0.00497 0.00494 0.00466 0.00466
270 0.04044 0.00711 0.00525 0.00271 0.00153 0.00115 0.00112 0.00106 0.00089 0.00087 0.0006 0.00059
292.5 0.01371 0.00259 0.00212 0.00133 0.0009 0.00077 0.00075 0.00073 0.00066 0.00065 0.00053 0.00053
315 0.07108 0.02834 0.02483 0.01731 0.01126 0.00877 0.00856 0.00812 0.00725 0.00732 0.00816 0.00816
337.5 0.02276 0.0034 0.00276 0.00168 0.00101 0.00084 0.00083 0.0008 0.00071 0.0007 0.00054 0.00053
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FIGURE 4.3(A) ISOPLETHS MAP FOR SO2
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FIGURE 4.3(B) ISOPLETHS IN GOOGLE MAP FOR SO2
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TABLE 4.6. THE 1ST HIGHEST 24-HR AVERAGE CONCENTRATION OF NO2, (µG/M3)
Direction Degrees
Distance in Meters
500 2090 2440 3490 5000 6050 6160 6400 7210 7330 9900 10000
360 0.43686 0.06104 0.05303 0.03552 0.02203 0.01683 0.01639 0.01552 0.01307 0.01276 0.00924 0.00932
22.5 0.38668 0.22032 0.18623 0.12074 0.10589 0.10953 0.10995 0.10889 0.10382 0.10309 0.08887 0.08838
45 0.54224 0.10276 0.08657 0.09767 0.11127 0.13111 0.13295 0.13399 0.13618 0.1364 0.13589 0.1357
67.5 0.66855 0.14465 0.12411 0.10359 0.12527 0.13235 0.13161 0.12875 0.1189 0.11745 0.08942 0.08848
90 0.72389 0.22752 0.27707 0.334 0.27605 0.27637 0.27373 0.26791 0.24821 0.24534 0.1905 0.18866
112.5 0.5413 0.05603 0.04375 0.02676 0.01849 0.0153 0.01503 0.01448 0.01291 0.01271 0.00962 0.00953
135 0.53982 0.18251 0.19918 0.23161 0.1841 0.15432 0.15158 0.14584 0.12862 0.12633 0.09995 0.0994
157.5 0.49333 0.09166 0.08143 0.06607 0.05614 0.04989 0.04928 0.04798 0.04388 0.04331 0.03328 0.03296
180 0.4917 0.13478 0.15923 0.1786 0.15133 0.17219 0.17342 0.17564 0.17087 0.16967 0.14149 0.1404
202.5 0.46478 0.20214 0.18101 0.13851 0.10488 0.09011 0.08881 0.08611 0.07813 0.07708 0.05984 0.05932
225 1.42501 0.30948 0.26354 0.25245 0.21571 0.20003 0.19873 0.19605 0.18832 0.1873 0.17983 0.18063
247.5 0.81013 0.23218 0.18928 0.11504 0.08212 0.06941 0.06828 0.06593 0.05893 0.05799 0.06598 0.06671
270 0.56198 0.07985 0.06428 0.03851 0.02314 0.01784 0.01742 0.01656 0.01421 0.01392 0.00977 0.00966
292.5 0.29713 0.05597 0.04575 0.02823 0.01703 0.01409 0.01385 0.01335 0.01194 0.01176 0.00894 0.00886
315 0.67768 0.23655 0.2117 0.16112 0.12103 0.10356 0.10203 0.09885 0.11882 0.12182 0.16157 0.16212
337.5 0.4768 0.07488 0.0607 0.03674 0.02165 0.01623 0.01579 0.0149 0.01241 0.01211 0.00896 0.00888
Gujarat Dyestuff Industries (Pharma Unit) Chapter 4 Anticipated Environmental Impacts
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FIGURE 4.4(A) ISOPLETHS MAP FOR NO2
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FIGURE 4.4(B) ISOPLETHS IN GOOGLE MAP FOR NO2
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TABLE 4.7 MAXIMUM GLCS FROM THE DISPERSION MODEL
Description 1st Highest Value
Concentration ( µg/m3) Co-ordinates
X (m) Y (m)
PM 2.59 -353.55 -353.55
SO2 0.151 -353.55 -353.55
NO2 1.43 -353.55 -353.55
Note:
PM: Based on maximum expected concentration of SPM-150 mg/Nm3
SO2: Based on maximum expected concentration of SO2-100 ppm
NO2: Based on maximum expected concentration of NO2-50 ppm
4.4.3 Impact on Water Environment
Water environment may be affected by the proposed project in different ways. As project is in GIDC
Nandesari industrial estate, no ground water will be used for construction work. For operational
activities, water requirement will be fulfilled by GIDC water supply. (Kindly refer letter is attached
as Annexure-11). Water environment may be affected by industrial & domestic wastewater
generation.
Mitigation Measures
The wastewater generated will be mainly from the washing, Scrubber, Process & Cooling Tower.
Total 40 KLD Industrial w/w will be generated from the proposed manufacturing activities. The
effluent treatment plant shall be so designed that the effluent from the process will come to the
Equalization cum Neutralization tanks for treatment, whereas the domestic waste goes directly go
to the Septic tank & Soak Pit for disposal. Treated water from the ETP will be passed through ETP
RO Plant & 20KLD recovered Product to be used for Cooling Tower Makeup. 20 KLD Reject to be
evaporated in MEE. 19.6 KLD MEE Condensate to be recovered for reuse. 8 KLD domestic
wastewater will be generated, which will be disposed through Septic tank & Soak Pit. So, there is
no impact of water due to proposed activities on environment.
Proper storage facility will be provided for raw material and hazardous waste. Hence there will be
no impact on ground water and surface water quality. Proper care will be taken to prevent any
spillage/leakage.
4.4.4 Impact on Land/Soil Environment
Land pollution can be caused due to improper handling of hazardous wastes on the land
environment and spillage or leakage of chemicals.
Mitigation measures
The hazardous solid waste generated will be stored and disposed properly. The storage area will
be of RCC flooring with impervious lining. The unit will make its solid waste storage / treatment
areas impervious to water and leachate migration. This will prevent soil contamination.
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Since this is a notified industrial area, no major impact on land is envisaged due to the construction
activities. Hence, soil quality will not be adversely impacted by the plant operations.
Further, it is emphasized that all precautionary measures have to be strictly practiced as mentioned
in the mitigation measures discussed in Table 4.2 of this chapter and summarized in the
Environmental Management Plan given to prevent soil contamination in the future.
The existing land is in Nandesari GIDC, and is of Industrial Land use, this is being used and will be
utilized for Industrial Purpose only. Hence, this is going to cause no impact on land use.
4.4.5 Impact on Noise Levels
Major source of noise is vehicular traffic. The operation of the equipment will generate noise level
ranging between 75 to 90 dB (A). However, this noise level will be near the source only and is not
expected to create any noise pollution problem at places away / outside the plant premises. The
noise generated during the construction phase from different equipment may have some adverse
impact on the operators.
Equivalent sound pressure level, 8 hrs. average, (Leq. 8 hrs.), is used to describe exposure to noise
in workplaces. The damage risk criteria for hearing loss, enforced by Occupational Safety and
Health Administration, (OSHA) USA and stipulated by other organizations, mentions that noise
levels up to 90 dB(A) are acceptable for eight hours exposure per day. Ministry of Labour,
Government of India has also recommended similar criterion vide Factories Act
Mitigation Measures
Personnel Protective equipment such as earplugs, earmuffs etc. will be provided. It will be ensured
that all the equipment and vehicles used are in good working condition, properly lubricated and
maintained to keep noise within the permissible limits and engines turned off when not in use to
reduce noise.
The noise levels of high-speed machinery like DG set, compressors, fans and blowers are in the
range of 90-110 dB(A). Various measures proposed to reduce noise level at source are, acoustic
enclosures, hoods, acoustic lagging for the equipment and suction side silencers, vibration isolators,
selection of low noise equipment, isolation of noisy equipment from working personnel.
Machineries will be provided with silencers and the fan casing will be properly insulated. So that
the sound pressure level exposure in working areas is restricted below 90 dB(A) for 8 hours duty.
4.4.6 Impact on Socio-Economy
The is an existing project into manufacturing of Bulk Drugs, Expansion proposed - Ethoxylates &
Metformin falling under 5(f) & is located in GIDC Nandesari, which is notified industrial area.
Therefore, no displacement of person is envisaged. There may be chances of pollution of air,
pollution of water, pollution of soil and noise pollution in surrounding villages due to proposed
project activities and transportation. But unit will provide proper environmental management
Gujarat Dyestuff Industries (Pharma Unit) Chapter 4 Anticipated Environmental Impacts
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system to control anticipated impacts generated due to industrial activities & unit will also conduct
environment monitoring program at regular intervals. Unit has satisfied its water demand through
GIDC water supply, so there is no chance to affect ground water level. Employment of
unskilled/skilled labour, technical staff (like welder, electrician, plumber etc.) and managerial staff
for proposed construction, though it is less and temporary, will have some beneficial impacts on
economic condition of the local labour/people. Increase opportunities of business potential will
have beneficial impacts on economic condition of local contractors, supplier of construction
materials, transporter and small business owners. Regular CSR activities have been done by unit
for Social welfare & upliftment of local people.
4.5 Irreversible & Irretrievable Commitments of Environmental Components
The project is not expected to create any irreversible and irretrievable impacts because of the
following:
• All the impacts created by the project will be mitigated by adoption of suitable mitigation
measures.
• Relevant mitigation measures against each pollutant attributes have been elaborated above
with quantification; wherever possible.
4.6 Incremental Concentration
Considering above incremental concentration over the existing baseline concentration, total
resultant concentration would be as follows
Sr No.
Location Name
Angle Distance PM10, g/m3
Baseline concentration
Probable Incremental
concentration
Resultant concentration
1 Nandesari (A2) 315 2.09 76.01 0.57102 76.59 2 Bhetasi (A3) 247.5 6.05 74.64 0.10909 74.75 3 Ambali (A4) 270 6.40 73.33 0.01669 73.35 4 Kotna (A5) 225 6.16 72.38 0.24213 72.62 5 Anagad (A6) 225 2.44 75.78 0.54985 76.33 6 Hathipura (A7) 225 9.90 71.94 0.17631 72.12 7 Undera (A8) 135 7.21 74.96 0.03773 75.00 8 Padamla (A9) 45 3.49 75.34 0.18102 75.52 9 Ajod (A10) 67.5 7.33 74.79 0.08085 74.87
Sr No.
Location Name
Angle Distance SO2, g/m3
Baseline concentration
Probable Incremental
concentration
Resultant concentration
1 Nandesari (A2) 315 2.09 19.13 0.02834 19.16 2 Bhetasi (A3) 247.5 6.05 13.11 0.00558 13.12 3 Ambali (A4) 270 6.40 16.58 0.00106 16.58 4 Kotna (A5) 225 6.16 15.15 0.0128 15.16 5 Anagad (A6) 225 2.44 18.46 0.03077 18.49
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6 Hathipura (A7) 225 9.90 17.09 0.01098 17.10 7 Undera (A8) 135 7.21 13.57 0.00577 13.58 8 Padamla (A9) 45 3.49 16.72 0.00993 16.73 9 Ajod (A10) 67.5 7.33 15.75 0.0056 15.76
Sr No.
Location Name
Angle Distance NO2, g/m3
Baseline concentration
Probable Incremental
concentration
Resultant concentration
1 Nandesari (A2) 315 2.09 17.19 0.23655 17.43 2 Bhetasi (A3) 247.5 6.05 11.07 0.06941 11.14 3 Ambali (A4) 270 6.40 13.74 0.01656 13.76 4 Kotna (A5) 225 6.16 12.35 0.19873 12.55 5 Anagad (A6) 225 2.44 15.49 0.26354 15.75 6 Hathipura (A7) 225 9.90 14.28 0.17983 14.46 7 Undera (A8) 135 7.21 11.49 0.12862 11.62 8 Padamla (A9) 45 3.49 14.19 0.09767 14.29 9 Ajod (A10) 67.5 7.33 11.26 0.11745 11.38
Hence, above tables show that even after addition of incremental pollutant concentration (arrived
from Air Quality Modelling) to the baseline concentration, the resultant concentration remains
within the acceptable range of National Ambient Air Quality norms for respective pollutants.
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CHAPTER – 5: ANALYISIS OF ALTERNATIVES
5.1 Analysis of Alternatives
The site has several favorable factors for locating; summarized below:
• M/s. Gujarat Dyestuff Industries (Pharma Unit). located at Plot No. 133/4, 133/5, 133/6,
GIDC Nandesari, Dist: Vadodara-391340., Gujarat.
• This is an existing unit into manufacturing of Bulk Drugs such as Cifixime Trihydrate,
Cefuroxime Axetil, Cefpodoxime Proxetil, Ampicilin, Amoxicillin Trydrydate, Clobetasole
Propionate, Betamethasone Dipropionate, Betamethasone Valerate, Betamethasone
Sodium Phosphate, Dexamethasone Sodium Phosphate, Beclomethasone Dipropionate,
Mometasone Furoate, Methylcobalamine, Ofloxacin, Levofloxacin, Quinon Sulphate,
Cloxacillin Sodium, Oxacillin Sodium, Di Cloxacillin Sodium, Flucoxacillin Sodium.
• New products Ethoxylates, Metformin Hydrochloride, and additional Methylcobalamine
that falls in Schedule 5(f) are planned to be manufactured and hence the application for
Expansion EC is being done.
• Project is located in Nandesari GIDC, which is notified industrial area, so requirement of
industrial land is fulfilled. All other infrastructure facilities such as water, fuel, power,
proper road network for transportation of raw materials & products, skilled & unskilled
manpower etc. are also easily available.
• Uninterrupted availability of sufficient water from GIDC water supply.
• Treated effluent discharge facility.
• Uninterrupted supply of electricity
• No physical displacement of the members of the public.
• Connectivity of the site via road and train to procure the raw material and to dispatch the
products.
• No national park or wildlife sanctuary within 10 radius of the project site
• Rehabilitation and resettlement will not be required, as project is in notified Industrial area
• Vicinity of common environmental infrastructure; like TSDF, CHWIF etc.
The land located in the notified industrial area. So, there will be no alternative for site.
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5.2 Best Available Technologies
• Research & Development of Gujarat Dyestuff Industries (Pharma Unit). has done extensive
research on the available processes of manufacturing of the selected products. Safe design
of these equipment was studied and evaluated, appropriate MoC for this equipment was
selected based on the material to be handled by the process & project engineering team.
During the selection of the technology emphasis was made on minimal manual handling
and human interface thus the process was designed to be automated using PLC.
• All reactors will be fitted with a Rupture Disc and Pressure Relief Valve.
• Reactors will be fitted with a Rupture Disc and Pressure Relief Valve wherever required.
• The vents of the Rupture Disc, Pressure Relief Valve system will go to roof height.
• All vessels will be designed as per the requirement of different processes.
• All vessels will be pressure tested as per the design rating before use.
• Processes will be automated using Program Logic Controllers and recipe batch.
• A sophisticated IMCC will be used for power distribution to plant equipment.
• Emergency action plan will be in place to handle emergency situations.
• Specially trained personnel will be available in all shifts to handle emergencies.
• SOP’s will be available for all operations.
• Safety will be incorporated in the processes.
• Leak detectors will be placed at strategic locations in tank farm as well as in plant as
required.
• Portable leak detectors will be used by personnel working in the specified jobs.
• Appropriate utilities will be planned for safe operations.
• Emergency exits will be available for all structures.
• All Raw Material and Finished Goods tanks will have a dyke for containment.
• Tanks will be segregated as per statutory and plant requirement.
• Water / Caustic scrubbers with column, circulation / transfer pump provided.
• Chemicals will be handled using all required PPE’s as per their characteristics and
requirements.
• Proper areas will be demarcated for intermediate storages in plant.
Gujarat Dyestuff Industries (Pharma Unit) Chapter 6 Environmental Monitoring Program
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CHAPTER –6: ENVIRONMENTAL MONITORING PROGRAM
6.1 Introduction
The monitoring and evaluation of the mitigation measures envisaged are critical activities in
implementation of the Project. Monitoring involves periodic checking to ascertain whether
activities are going in according to the plans. It provides the necessary feedback for project
management to keep the program on schedule. The purpose of the environmental monitoring plan
is to ensure that the envisaged purpose of the project is achieved and results in desired benefits.
To ensure the effective implementation of the proposed mitigation measures, the broad objectives
of monitoring plan are:
• To evaluate the performance of mitigation measures proposed in the EMP.
• To assess the adequacy of Environment Management System
• To suggest improvements in management plan, if required
• To enhance environment quality.
• To implement and manage the mitigation measures defined in EMP.
• To undertake compliance monitoring of the proposed project operation and evaluation of
mitigation measure.
6.2 Implementation Arrangement
The various components of the environment need to be monitored on regular basis during
construction and operation phase of the project, as per the requirements of regulating agencies as
well as for trend monitoring of the pollutant’s levels in various environmental matrices.
6.3 Environmental Aspects to be Monitored
Several measures have been proposed for mitigation of adverse environmental impacts. These shall
be implemented as per proposal and monitored regularly to ensure compliance to environmental
regulation and also to maintain healthy environmental conditions.
A major part of the sampling and measurement activity shall be concerned with long term
monitoring aimed at providing an early warning of any undesirable changes or trends in the natural
environment that could be associated with the plant activity. This is essential to determine whether
the changes are in response to a cycle of climatic conditions or are due to impact of the plant
activities. In particular, a monitoring strategy shall be ensured that all environmental resources,
which may be subject to contamination, are kept under review and hence monitoring of the
individual elements of the environment shall be done.
The environmental aspects to be monitored to ensure proper implementation and effectiveness of
various mitigative measures envisaged/adopted during the design and commissioning stage of the
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project proponent are described here under. The frequency of monitoring schedule for different
parameters as mentioned below may increase depending on the requirement.
6.3.1 During Construction Stage
During construction stage, different issues / components involved in environmental monitoring
programme will be looked upon by Project proponent.
TABLE 6.1: ENVIRONMENTAL MONITORING PROGRAMME (DURING CONSTRUCTION
STAGE)
6.3.2 During Operation Phase
The environmental monitoring programme for different environmental components / indicators
which are to be monitored during the operation phase will be as given under different heads.
At the unit, an Environmental Management cell has been formed, which will review the
effectiveness of environmental management plan of the project during operation phase. The data
collected on various EMP measures would be reviewed by this cell and if needed, corrective action
will be formulated for implementation.
It will form short term & long-term plans for environmental issues, which are required for
monitoring and effective implementation. The environmental quality-monitoring program will be
carried out in the impact zone with suitable sampling stations.
6.3.2.1 Ambient Air Monitoring Within Plant Area
All the accessible areas of the plant will be monitored for ambient air.
6.3.2.2 Effluent Monitoring
Performance of Sewage treatment plant and Effluent Treatment Plant will be monitored regularly.
Following things would be monitored regularly.
-Inlet [Raw domestic wastewater] to STP as well as ETP.
-Outlet [Treated domestic wastewater] of STP as well as ETP.
6.3.2.3 Work Zone Noise Levels
The Industry will monitor the noise levels inside and around the plant on a quarterly basis.
Description Nos. of Locations and frequency
Work zone /Noise Cover all shift of operation once every quarter for all the selected
locations.
Component Parameters Location and Frequency of Monitoring
Air PM10, PM2.5, SO2, NOx Plant site.
One sample every month
Noise Noise Levels Leq
Four locations every month.
one at project site and three at 120 degrees
in nearest habitation
Soil As per standard practice Once before starting construction activity
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6.3.2.4 Ambient Noise
Ambient noise shall be monitored at eight locations in area surrounding the project, once in each
quarter. The locations selected for monitoring will cover the project site and the sensitive areas of
project study area.
6.3.2.5 Solid / Hazardous Waste Disposal
The hazardous wastes will be disposed as per applicable stipulations of statutory authorities.
Periodic surveillance monitoring will be conducted to ensure that the wastes will be disposed in
the manner as specified.
6.3.2.6 Green Belt Development
The following plan has been made for implementation of green belt at the project site.
• Regular periodic watering of the plants,
• Manuring,
• Weeding,
• Hoeing will be carried out for minimum 3 years after the plantation work.
6.3.2.7 House Keeping
The Industry will maintain housekeeping activities as per standard practice meeting hygienic
norms.
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6.4 Environmental Monitoring Plan
TABLE 6.2 PROJECT ENVIRONMENT MONITORING PLAN
6.5 Documents & Records
The environmental department in respect of operation of pollution control facility will maintain
following records.
• Instruction manual for operation and maintenance of pollution control equipment.
• Log sheet for self-monitoring of pollution control equipment.
• Instruction manual for monitoring of water, solid and gaseous parameter discharged from
the factory and also for various parameters of pollution control facilities.
• Statutory records as per the Environmental Acts.
• Monthly and annual progress reports.
• Submission of Compliance report to MoEF.
Sr. No. Activity Parameter Schedule Air Quality Monitoring
1 Ambient air monitoring of parameters specified by GPCB in their air consents from time to time within the M/s. Gujarat Dyestuff Industries (Pharma Unit). premises.
As prescribed by GPCB including PM2.5, PM10, SO2, NO2, HC & VOC.
Every Quarter Up-Wind & Down-Wind/ As per GPCB Consent (by NABL Lab)
2 Stack monitoring of flue gas stacks& process gas stack as given in air consent from time to time
Parameters prescribed by GPCB including PM, SO2, NO2
Every Quarter / As per GPCB Consent (by NABL Lab)
3 Fugitive emissions/ workplace monitoring within the plant side
VOC As per GPCB Consent.
Wastewater Quality Monitoring 1 Untreated & Treated Effluent Colour, pH, TDS,
TSS, Sulphates, Chlorides, O&G, BOD, COD, etc.
Every Quarter / As per GPCB Consent. (by NABL Lab)
Noise Monitoring 1 Noise Monitoring and maintaining records Noise level in dB(A) Every Quarter / As
per GPCB Consent. (by NABL Lab)
Solid Waste Generation Monitoring / Record Keeping 1 Records of generation of solid & Hazardous
waste and records of disposal. ETP waste, Residue/side products, discarded container/ bags/ Drums & Used oil/Spent Oil
To be updated on event basis
2 Records of generation, handling, storage, transportation and disposal of other solid, aqueous and organic hazardous wastes as required by hazardous waste authorization
To be updated on event basis
Soil monitoring 1
At plant site pH, TDS, Chlorides, COD.
Pre and post monsoon season
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6.6 Budgetary Provisions for Environmental Protection Measures
TABLE 6.3 COST OF ENVIRONMENTAL PROTECTION MEASURES
Sr. No.
Description Capital cost (Rs.)
(Lac) Recurring cost (Rs.)
(Lac. /annum) Existing Proposed Total Existing Proposed Total
1 Air pollution
control 6.5 2.5 9 5 1.5 6.5
2 Water pollution
control 33 100 133 4.5 90.5 95
3 Hazardous
waste management 3 2.5 5.5 2.5 1.5 4
4 Environment monitoring & Management 5 3 8 2 1.5 3.5
5 Occupational
health 1 0.5 1.5 0.5 0.5 1
6 Greenbelt
development 1.5 0.5 2 1 1 2 Total 50 109 159 15.5 96.5 112
6.7 Updating of EMP
The directives from MoEFCC and the regulations in force at any time shall govern the periodicity of
monitoring. However, it is suggested that the implementation of various measures recommended
in the EMP be taken as EMPs in the system to effectively implement the measures for continual
improvement in environmental performance.
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CHAPTER – 7: RISK ASSESSMENT
7.1 Risk Assessment
7.1.1 Introduction
Hazard analysis involves the identification and quantification of the various hazards (unsafe
conditions). On the other hand, risk assessment deals with recognition and computation of risks,
the equipment in the plant and personnel are prone to, due to accidents resulting from the hazards
present in the plant.
Risk assessment follows an extensive hazard analysis. It involves the identification and assessment
of risks the neighboring populations are exposed to as a result of hazards present. This requires a
thorough knowledge of failure probability, credible accident scenario, vulnerability of population
etc. Much of this information is difficult to get or generate. Consequently, the risk assessment is
often confined to maximum credible accident studies. It provides basis for what should be type and
capacity of its on-site and off-site emergency plan also what types of safety measures shall be
required.
7.1.2 Objective The main objective of the Risk Assessment study is to determine damage due to major hazards
having damage potential to life and property and provide a scientific basis to assess safety level of
the facility.
The secondary objective is to identify major risk in manufacture of chemicals, storage of chemicals
and provide control thorough assessment. To prepare on- site, off site, disaster management plan
for control of hazards.
7.1.3 Approach to the Study
Risk involves the occurrence or potential occurrence of some accidents consisting of an event or
sequence of events. The risk assessment study covers the following:
• Identification of potential hazard area.
• Identification of representative failure cases.
• Visualization of the resulting scenarios in terms of fire and explosion.
• Assess the overall damage potential of the identified hazardous events and the impact zones
form the accidental scenarios.
• Furnish the recommendations on the minimization of the worst accident possibilities
• Preparation of Disaster Management Plan.
7.2 Quantity of Hazardous Chemicals
Details of quantity of each hazardous chemical (including solvents) to be stored, Material of
Construction of major hazardous chemical storage tanks, dyke details, threshold storage quantity
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as per schedules of the Manufacture, Storage & Import of Hazardous Chemicals Rules of major
hazardous chemicals.
TABLE 7.1 STORAGE DETAILS OF RAW MATERIALS
Major Raw Material for Proposed Products
Sr. No. Raw Material Storage
Quantity, CUM/MT
MOC No. of Vessel /
DRUMS
1 n-butanol 20 SS 304 1
2 Di Ethelene Glycol 25 SS 1
3 Castor Oil 25 SS 1
4 Lauryl Alcohol 25 SS 1
5 Tridecyl Alcohol 25 SS 1
6 Ethylene Oxide
This will come by Pipeline
from our GDI VS plant
SS Pipeline -
Major Raw Material for Existing Products
Sr. No. Raw Material Storage
Quantity, in KL
MOC No. of Vessel /
DRUMS
1 Butyl Acetate 25 MS 2 2 Sulphuric Acid 10 MS 1 3 Acetone 20 MS 1 4 Tri ethyl amine 20 MS 1 5 MDC 25 MS 2 6 Methanol 20 MS 3 7 Ethyl Acetate 10 MS 1 8 HCL 20 HDPE 1 9 Formaldehyde 20 SS 1
10 Di Methyl Formamide 20 MS 1
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7.3 List of Hazardous Chemicals along with their Toxicity Level as per MSIHC rules
The Toxicity level of hazardous chemicals as per Manufacture, storage and import of Hazardous Chemical (Amendment) Rules, 2000 (MSIHC)
TABLE 7.2 DETAILS OF HAZARDOUS CHARACTERISTICS OF PRODUCT – PROPOSED PRODUCTS
Sr. No
Full Name of the Products
State solid, liquid or gas
Main properties (refer MSDS, Sch-9 of MSIHC Rules)
B.P. °C
F.P. °C
LEL UEL %
TLV mg/m3
LD50 mg/Kg
LC50 mg/l
Specific Gravity
(water =1)
Vapor density (air=1)
Odour threshold
ppm Flammability
1 POLYETHYLENE
GLYCOL or
Liquid - 176 - LD50 - 2000 mg/kg 1.128 - - 1
2 HYDROGENATED
CASTOR OIL or Solid >300 >310 - - LD50 – 10g/kg 0.93 - - -
3 CASTOR OIL
ETHOXYLATES or Liquid >100 257 - - LD50 - >6400 mg/kg 1.05 - - -
4 NONYL PHENOL
ETHOXYLATES or Liquid 271 150
1.0 % & 9.0%
- LD50 - >2000 mg/kg 0.9 - - -
5 OCTYL PHENOL
ETHOXYLATES or Liquid >200 - - - LD50 – 1800 mg/kg 1.06 >1 - -
6 CARD PHENOL
ETHOXYLATES or Liquid 293 >113 - - - - - - -
7 STYRUNATED
PHENOL ETHOXYLATES or
Liquid >250 100 - - - - - - -
8 LAURYL ALCOHOL ETHOXYLATES or
Liquid - 160 - - - 0.95 - -
9 TRIDECYL ALCOHOL
ETHOXYLATES or Liquid >253 180 - - LD50 – 10000 mg/kg - - - 1
11 CESTOSTYRYL
ALCOHOL ETHOXYLATES or
Solid - 110 - - - - - - -
12 TALLOW ALCOHOL ETHOXYLATES or
Liquid 230 123 - - LD50 – 5000 mg/kg - - - -
13 STEARYL AMINE ETHOXYLATES or
Liquid >572 >392 - - - 1.02 - - 0
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Sr. No
Full Name of the Products
State solid, liquid or gas
Main properties (refer MSDS, Sch-9 of MSIHC Rules)
B.P. °C
F.P. °C
LEL UEL %
TLV mg/m3
LD50 mg/Kg
LC50 mg/l
Specific Gravity
(water =1)
Vapor density (air=1)
Odour threshold
ppm Flammability
14 COCO AMINE
ETHOXYLATES or Liquid >100 >100 - - LD50 – 1.0 mg/kg - - - -
15 OLEYL AMINE
ETHOXYLATES or Liquid 348 120 - - - 0.84 - - 0
16 POLY SORBATE
ETHOXYLATES or Liquid >100 >149 - - LD50 – 38.9 g/kg 1.1 - - 1
17 STEARIC ACID
ETHOXYLATES or Solid 350 196.11 - - LD50 – 4640 mg/kg 0.94 9.8 20 1
18 METFORMIN
HYDROCHLORIDE Solid - - - - LD50 – 1 g/kg - - - -
TABLE 7.3 DETAILS OF HAZARDOUS CHARACTERISTICS OF RAW MATERIALS – PROPOSED PRODUCTS
S. No. Raw Materials
Physical & chemical composition
B. P F. P LEL UEL
TLV ppm or
mg/Nm3
LD50, mg/Kg LC50
mg/l
Sp. Gr. (water = 1) at
V.D. at
(air = 1)
Odour Threshold
ppm or mg/m3
No. of container
& size Chemical Formula
State 0 C 0 C % 200 C 200
C
2 3 4 5 6 7 8 9 10 11 12
1. Ethoxylates
Di Ethelene Glycol
VP-0.01 mm of Hg (@ 20°C) C4H10O3 Liquid 245 138
2%-12.3%
-- LD50 – 2565
mg/kg 1.12 3.66 -- 25 MT
Hydrogenated Castor Oil
VP-NA -- Liquid >100 -- -- --
LD50 – 15000 g/kg
1 -- -- 25 MT
Castor Oil
VP-NA -- Liquid 313 230 -- -- -- 0.962 -- -- 25 MT
Nonyl Phenol
VP-NA -- Liquid -- 279 -- --
LD50 – 1410 mg/kg
1.055 1 -- 77.3 MT
Octyl Phenol
VP-NA (C8H17)C6H4OH Solid 175 -- -- --
LD50 – 4600 mg/kg
-- -- -- 74 MT
Card Phenol -- Liquid -- -- -- -- -- -- -- -- 84 MT
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VP-NA
Styrunated Phenol
VP-NA C30H30O Liquid 250 182 -- -- -- 1.02 -- -- 72 MT
Lauryl Alcohol
VP-0.1 hPa at 20 °C C12H26O Solid 260 121
0.6%-4%
-- LD50 – 2.0
mg/kg -- -- -- 25 MT
Tridecyl Alcohol
VP-20.9KPa at 200 °C C13H28O Liquid 254 130 -- --
LD50 – 4.75 mg/kg
0.846 6.9 -- 25 MT
Cetostyryl Alcohol
VP-NA -- Solid -- -- -- --
LD50 – 3200 mg/kg
0.82 9.5 -- 53 MT
Tallow Amine
VP-NA -- Liquid >200 >100 -- --
LD50 – 1950 mg/kg
0.812 >1 -- 69 MT
Stearyl Amine
VP-NA C18H39N Solid 346.8 148 -- --
LD50 – 2395 mg/kg
0.791-0.861
-- -- 88 MT
Coco Amine
VP-NA -- Liquid 180 150 -- --
LD50 – 2000 mg/kg
0.805 -- -- 112 MT
Oleyl Amine
VP-NA C18H37N Liquid 300 154 -- --
LD50 – 1689 mg/kg
0.810 -- -- 38 MT
Sorbitian Mono Laurate
VP-NA
C18H34O6 Liquid -- -- -- -- LD50 - 33600
mg/kg -- -- -- 66 MT
Sorbitian Mono Stearate
VP-NA C24H46O6 Solid -- -- -- --
LD50 – 31000 mg/kg
1 -- -- 66 MT
Sorbitian Mono Oleate
VP-NA C24H44O6 Liquid >100 148.89 -- -- -- 1 -- -- 66 MT
Sorbitian Tri Oleate
VP-NA C60H108O8 Liquid -- -- -- -- -- 0.95 -- -- 66 MT
Stearic Acid
VP-NA C18H36O2 Solid 350 196.11 -- --
LD50 – 4640 mg/kg
0.9408 9.8 20 ppm 116 MT
CAUSTIC POTASH FLAKES KOH solid 1384 - -- LD50-273
mg/kg 2.044 -- -- 7 MT
2. Metformin
N-BUTANOL
VP-6.7 mbar @ 20 °C CH3(CH2)2CH2OH Liquid 117.7 28.9
1.4%, 11.2%
-- 790 mg/kg 0.81 2.55 1.2 ppm 20 MT
DMA.HCL
VP-NA C2-H7-N.ClH Solid -- -- -- -- 1070 mg/kg -- -- -- 58 MT
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DCDA VP-NA
C2H4N4 Solid -- -- -- 10
mg/m3 -- 1.40 -- -- 59 MT
Toxic Chemicals: Chemicals having the following values of acute toxicity and which owing to their physical and chemical properties are capable of producing
major accident hazards
TABLE 7.4 TOXICITY INDEX AS PER MSIHC RULE 2000 S.No. Toxicity Oral toxicity
LD50(mg/kg) Dermal toxicity
LD50(mg/kg) Inhalation
toxicity LC50(mg/l)
1. Extremely toxic >5 <40 <0.5 2. Highly toxic >5-50 >40-200 <0.5-2.0 3. Toxic >50-200 >200-1000 >2-10
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(i) Very highly flammable liquids: chemicals which have a flash point lower than or equal
to 23oC and initial boiling point higher than 35oC.
(ii) Highly flammable liquids: chemicals which have a flash point lower than or equal to
60oC but higher than 23oC.
(iii) Flammable liquids: chemicals which have a flash point higher than 60oC but lower
than 90oC.
Minimization the Manual Handling of Hazardous Chemicals & Hazardous Waste:
• Chemical Charging of liquids to be done by pumps
• Solids to be done by mechanical arrangement such as monorail hoist with load cell.
• Hazardous waste handling would be done through mechanical aid like forklift.
• Automatic filling of product.
• Providing proper training.
• Providing information, training, instruction and supervision.
• Avoiding spillage or overflow, including overflow protection on equipment and storage.
• PPE like hand gloves, nose mask, apron etc. i.e. suitable PPE will be used.
Kindly find attached the Risk Assessment Report vide Annexure 3.
7.4 MSDS of all the Products & Raw Materials
Details of hazardous characteristics and toxicity of raw materials and products to be handled and
the control measures proposed to ensure safety and avoid the human health impacts. This shall
include the details of Antidotes also. Detailed material handling plan to avoid / minimize human
exposure.
Details of Hazardous characteristics of products & raw materials are given in Table 7.3. Raw
materials & products are plenty in number, so it is not possible to attach MSDS of all products &
raw material with this EIA report. Hard copy of all products & raw materials is available with unit.
Kindly find attached the MSDS for Raw Material Annexure 7
Kindly find attached the MSDS for Finished Products Annexure 8
7.5 Hazard Identification & Preventive Measures
7.5.1 Process hazards and controls
The details of process hazards and controls are given in Table-7.5.
TABLE 7.5 PROCESS HAZARDS AND CONTROLS
Name of hazardous
process and
operation
Type of hazard possible
toxic gas release / fire /
explosion / run away
reaction / rupture, etc.
Control measured provided
Reactor Vessels
• Release of Heat
• Fire, Dust release and
Explosion
a) Raw Materials quantity must be controlled
either volumetrically or gravimetrically.
b) High Temperature indicator valve must be
provided
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c) The burner system will be provided with
automatic handling system and safety
control system.
d) Use skilled worker
e) Proper selection of MOC
7.5.2 General Hazards & Controls
The details of general hazards and controls are given in Table-7.6.
TABLE 7.6 GENERAL HAZARDS & CONTROLS
Type of Emergency
Possible Causes Preventive/ control Measures
Fire Fire due to
• Due to leakage
• Fire Protection system having extinguisher.
• Good housekeeping
• Hot work permit system
Explosion
• Burn
• Electrical short circuit
• Open flame
• A gas shut-off/isolation valve is provided
• Gas detector/automatic shut off mechanism
provided
• Hot work permit for hot working in the plant
• Foam fire extinguisher will be provided
• Good ventilated area for Flammable material
storage
Material
handling • Fire and health Hazards
• Trained employee
• Required PPE and Fire Protective equipment
Provided
• Good engineering practices
• Separate storage area as per compactibility of
material
Training to the worker will be provided under experienced person before hiring for process hazard,
general hazard, and chemical hazard. Periodical review of person through safety committee
meeting, safety audit and mock drill.
7.6 Fire & Safety
This includes details of the separate isolated storage area for flammable chemicals, details of flame
proof electrical fittings, DCP extinguishers and other safety measures proposed. Specific safety
details / provisions for various hazardous chemicals and detailed fire control plan for flammable
substances and processes showing hydrant pipeline network, provision of DG Sets, fire pumps,
jockey pump, toxic gas detectors etc.
(i) Firefighting system will be made available.
(ii) Automatic leak detection and fire alarm system will be provided for tanks.
(iii) Fire hydrant network will consist of
• Main electric operated fire Pump
• Diesel operated fire pump
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• Jockey pump
• Foam trolley
TABLE 7.7 PROPOSED FIRE EXTINGUISHERS AS PER IS 15683:
Sr.No. Type of Fire Extinguishers & Location Capacity Qty 1 ABC type 6 kg 10
2 Foam type 50 Lit 5
3 CO2 type 4.5 kg 5
4 DCP type 5 kg 5
7.6.1 Safety Measures to be provided
Following are the Safety measures Proposed for EO storage Area
• Reactors will be fitted with a Rupture Disc and Pressure Relief Valve wherever required. • All vessels will be designed as per the requirement of different processes. • All vessels will be pressure tested as per the design rating before use. • Processes will be automated using Program Logic Controllers and recipe batch. • A sophisticated IMCC will be used for power distribution to plant equipment. • Emergency action plan will be in place to handle emergency situations. • Specially trained personnel will be available in all shifts to handle emergencies. • SOP’s will be available for all operations. • Safety will be incorporated in the processes. • Leak detectors will be placed at strategic locations in tank farm as well as in plant as
required. • Appropriate utilities will be planned for safe operations. • Emergency exits will be available for all structures. • All Raw Material and Finished Goods tanks will have a dyke for containment. • Tanks will be segregated as per statutory and plant requirement. • Chemicals will be handled using all required PPE’s as per their characteristics and
requirements. • Proper areas will be demarcated for intermediate storages in plant. • Breather Valve with flame arrestor on tank • Level Indicator with high- and high-level alarm with trip system • Double valve on Tank outlet • Sensor within the dyke area with audio alarm • Double Earthing to tank with separate earth pit • Earthing to pipeline, Flange to flange earthing Jumper on pipeline • Dyke Height should be more than 1.45 Mtr • Flameproof electrical fittings for process and storage tank farm area • Pumps should be outside the Dyke Area • Water Sprinklers system around the tanks, Water cum Foam Monitor • Auto Fire Protection system • Earthing and Relay system for Tanker unloading • Display to Safe Unloading Procedure Health Hazard, Cautionary Notice • Regular Monitoring of Pipelines and Tank – Once in six months • Auto control system with alarm for Distillation Kettle with safety interlock on Temperature
and Flow • Sump and Dyke drain valve • Flange Guard on Flange joint • No Smoking zones • Safety Shower with Eye washer station
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7.6.2 Provisions for Human Health Hazards & Workplace
Provisions made to avoid human health hazards:
• Workplace monitoring is being done regularly.
• Periodical medical examination of worker being done regularly.
• Provision of Personal protective equipment.
• Consulting Doctor (Certified Industrial Hygienist) to site regularly.
7.7 Leak Detection & Repair (LDAR)
Source Leak from Control Measures
Pumps Occur at seal
Leak from pumps can also be reduced by using dual
seals with or without barrier fluid.
Valves Occur at stem area of valve caused by failure of valve
packing
Leak from open ended line, sampling connection,
compressors are usually fixed by modifying
equipment. emission from pumps and valves can be
reduced by use of leak less valves and seal less pumps
Connectors Caused from gasket failure, torque bolts on flange
Sampling Connection
Occur at outlet of sampling valve
Compressor Occur from seal
Pressure Relief Device
Occur if valve is not sealed, operating too close to set point, seal is damaged, leaks from rupture disks can
occur around the disk gasket if not installed properly
Open Ended Lines
Occur at point of the line open to atmosphere and controlled by using caps, plug, flanges,
Occur due to incorrect implantation of block and bleed procedure
7.7.1 Following Methodology of LDAR Program will be followed:
• GDI shall Integrate an awareness of the benefits of LDAR into the company’s operating & maintenance program.
• GDI shall prepare LDAR program that includes an overall, facility-wide leak rate goal, procedures for identifying leaking equipment within process units, procedures for repairing and keeping track of leaking equipment.
• GDI shall give training that provides LDAR personnel with technical understanding to implement the written LDAR program and educate LDAR team members on their individual responsibilities shall be provided to EHS team.
• GDI shall get done Internal and third-party audits of a facility LDAR program to ensure the LDAR program is correctly conducted and that issues are identified and corrected.
• GDI shall use internal leak definition for valves and pumps in light liquid or gas vapor service and monitor against that uniform definition. Leak detectors will be placed at strategic locations in tank farm as well as in plant as required.
• GDI shall Include a plan for more frequent component monitoring, especially of those that contribute most to equipment leak emissions. For the same. Portable leak detectors will be used by personnel working in the specified jobs.
• GDI shall ensure that can justify the equipment on the Delay of Repair list and have a plan in place to fix these components.
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• GDI shall utilize electronic monitoring and storage of LDAR data. Hence leak detectors will be placed at strategic locations in tank farm as well as plant, over and above Portable leak detectors will be used by personnel working in the specified jobs.
• GDI shall include procedures to ensure the QA/QC review of all data generated by LDAR monitoring technicians is completed on a daily basis or at the conclusion of each monitoring occurrence.
• GDI shall consistently calibrate LDAR monitoring equipment. • GDI shall follow all recordkeeping and reporting requirements and have organized records
readily available to demonstrate that the LDAR program is a component of the organization’s routine operation and management
7.7.2 Following shall be done to Prevent Leaks:
• Leak Free Pumps for transfer of solvents to be used. • MSW Gaskets in solvent pipelines to be used to prevent leakage from flanges. • Minimum number of flanges, joints and valves in pipelines. • To eliminate chances of leakages from glands of pumps, mechanical seal will be provided at
all solvent pumps. • Condenser with Cooling water & Chilled brine and scrubber post Distillation to recover the
solvent. • Sensor within the dyke area with audio alarm.
7.7.3 Following shall be done in case of Spills:
1. Spill of Solid Materials
• In case of spill of the solid Inform QA and EHS department for getting their advice refer the MSDS of the material for safety related guidance.
• Try to stop the source of leak immediately if possible. • Appropriate PPE to be used to prevent the breathing in /inhaling the solid, as per the
guidance given in the MSDS. • Collect the spilled solids material separately and do not mix with earlier collected solids. • Only after dry swiping and collection of spilled material clean the area by using the water
and contaminated water collected in a tank to transfer for treatment and disposal. • Analyse the collected material for reuse / disposal. Disposal to be done • If, the material found not reusable to discarded it and send with ETP Sludge.
2. Spillage/Leakage of Acids & Alkalis from Drum or Tank.
• In case of spill of the solid Inform QA and EHS department for getting their advice refer the MSDS of the material for safety related guidance.
• Use PPE such as Acid resistant suit, SCBA, Hand gloves, Safety shoes etc. . • In case the spillage or leakage observed, first pour the Sand on material and collect the
contaminated sand and send the socked material in the separate drums/bags after collection to ETP.
• In case the spillage or leakage is large, do not use water, as the reaction is highly exothermic. • Wash the area with water. • Inform the effluent treatment plant about additional load.
3. Spillage / Leakage of Flammable Liquids.
• In case of spill of the solid Inform QA and EHS department for getting their advice refer the MSDS of the material for safety related guidance regarding the nature of hazard during the spillage / leakage of solvent i.e. Pyridine is highly flammable & there is possibility of fire.
• In case the small spillage or leakage observed, first pour the sand on material and collect the contaminated sand and send to ETP.
• If the spillage is of inflammable liquid, switch off all the power supply in the area to prevent Electric Spark.
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• Do not use any vacuum cleaner or floor cleaning machine to collect the spilled material as the vapors of the spilled material may explode due to electrical circuits and rotating parts of these machine.
• Send the collected spilled material for Incineration.
7.8 Information on Solvent Storage Area and associated reactors
1. List of sensors provided in the system
1.1. Fire detection & alarm system shall be installed in solvent storage area and associated
reactor area.
1.2. Temperature transmitter for reaction vessel will be provided.
1.3. Level Transmitters shall be provided in the storage tank.
2. Rupture discs and PRV’s.
2.1. Reactor shall be provided with RD’s and PRV’s .
2.2. PLC system will be used for monitoring, controlling and maintaining all parameters at
defined values.
2.3. Sufficient freeboard shall be provided for solvent storage tanks.
7.9 On Site Emergency Plan
7.9.1 Purpose:
To develop awareness of potential emergency situation.
Contain & Control the emergency.
Rescue and treatment of causality.
Notify casualty to their relatives and render necessary help to them.
Rehabilitate area affected.
Provide information to media and government agency.
Preserve records for equipment for subsequent investigation.
7.9.2 PESO Permission:
This is attached vide Annexure 22.
7.10 Worst Case Scenario
Risk assessment including prediction of the worst-case scenario and maximum credible accident
scenarios should not be carried out. There is no storage of liquid chemical at site. Based on the same,
proposed safeguard measures including On-Site / Off-Site Emergency Plan should be provided.
7.10.1 Scope:
This plan is applicable for Gujarat Dyestuff Industries (Pharma Unit). at Nandesari.
Kindly find attached Emergency management Plan vide Annexure 4
7.11 Checklist - Do’s & Don’ts for Handling of Chemicals, Working in Chemical Laboratory, Working on Machines, Maintaining good Housekeeping, Working on Height, Work in Confined Space, Fire Prevention, In Case of Fire
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MFG, UTILITY, STAFF FOR RELATED SAFETY MEASURES
FIRE PREVENTION
Sr. Do's Sr.
Don’t's
1 Follow "No Smoking" Sign. 1 Do not leave any flammable material at the work area.
2 Deposit oily rags and waste combustible material in the identified containers and dispose them suitably.
2 Do not allow wild grass growth around storage of flammable chemicals and gas cylinders
3 Keep minimum inventory of flammable and combustible substances.
3 Do not obstruct accessibility to the firefighting equipment
4 Take permission before breaking or removal of fire barrier and ensure subsequent relocation of fire barrier
4 Do not destroy the inspection tag provided with the fire equipment
5 Check periodically the operability of firefighting systems
5 Do not misuse the firefighting equipment other than intended purpose
6 Provide earthing or bonding to prevent accumulation of static charges to tanks where flammable chemicals are stored or handled
6 Do not store the flammable material in the open container
IN CASE OF FIRE
Sr. Do's Sr. Dont's
1
On seeing fire please inform control room and warn people nearby by shouting,” Fire”, "Fire" 1 Do not runaway in case of fire but act on it.
2 Tell exact location and place of the occurrence clearly 2 Do not become the hindrance to the fire crew
3 Try to extinguish the fire if you are aware about the firefighting operation. 3 Do not spread rumor in case of fire.
4 Guide the fire crew to the correct location. 4 Do not leave place unattended if possible, till the fire crew arrive.
5 Keep the emergency escape route clear of materials 5 Do not stay there if you feel unsafe.
6 Try to remove the combustible material from the vicinity of the fire if possible. 6
Do not touch any electrical equipment under the influence of fire.
7
Cover the electrical equipment that is situated near or below the area of fire before applying water. 7
Do not use the extinguisher if not in a good condition.
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HANDLING OF GAS CYLINDERS
Sr Do's SR Don’t's
1
Use soft pad or ramp for unloading the gas cylinder and avoid knocking / impact while handling and transport. 1 Do not roll the cylinder while handling.
2 Use cylinder cap while handling and transporting the cylinder. 2 Do not use cylinder without pressure gauge.
3
Segregate inert, toxic, non-flammable & flammable cylinders during storage. 3 Do not expose the cylinders to heat and light.
4 Store 'empty' and 'full' cylinder separately, duly marked. 4 Do not change the color of the cylinder.
5 Label the area of storage. 5 Do not strike a cylinder valve with hammer for reopening.
6 Use a cradle while shifting gas cylinder. 6
Do not transfer the gas from one cylinder to another.
7
Keep cylinders always in upright position and round bottomed cylinders horizontally. 7
Do not store the cylinder near elevator or gangways.
8 Display "No Smoking" sign at gas cylinder storage area. 8 Do not store cylinder in locker or cupboard.
9
Store flammable gas cylinders away from the gas cylinder which support combustion. 9
Do not apply force for connecting the cylinder that does not fit.
10 Use trolley for transporting and handling of gas cylinders. 10
Do not transport cylinder on bicycle or two-wheeler.
11
Cylinders should be kept separately chained at the place of storage and 'addition station' 11
Do not start using a gas cylinder without proper identification.
12
Valve caps should be fixed on the valve neck when not connected to 'addition banks'. 12 Do not use cylinder as rollers.
13 Do not store gas cylinders under direct sunlight.
14 Do not use a lifting magnet for loading or unloading of gas cylinder.
HANDLING OF CHEMICALS Sr Do's
Sr Don’t's
1
Use proper lifting tool and tackle having adequate capacity.
1
Do not use the equipment for the purpose other than its design intention.
2
Only authorized persons should operate material handling equipment.
2
Do not allow personnel to move underneath lifted load.
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3
Each tool, tackle or equipment should have identification number and safe working load marked on it.
3
Do not load the equipment above its safe working load.
4
Assess weight of the material, distance to be carried, and hazards etc. before lifting the load.
4
Do not use makeshift arrangement for lifting the material.
5
Store the lifting tools and tackles at its designated place.
5
Do not use defective tool and tackles.
6
Inspect and test all the lifting tools and tackles regularly.
6
Do not use altered or repaired lifting equipment without inspection and test.
7
Wear safety boots with metal toe while handling of materials.
7
Do not drag chains, ropes or cables etc. on the floor.
8
When placing a sling of a load, ensure all Sharp corners are covered with pad or soft material.
8
Keep the tools & tackles free from adverse effect of atmosphere by applying suitable protective coating.
9
Bend knees, keep back straight, keep the load close to the body and lift the load.
9
Do not hold the load with tip of the fingers, grasp the load firmly with palm.
HOUSE KEEPING Sr Do's
Sr Don’t's
1
Assign places for everything and maintain things at its assigned place.
1
Do not leave combustible materials in the work area.
2 Clean the area after completion of work. 2 Do not smoke in the area of work
3 Use aisle space free for personnel and material movement. 3 Do not allow dustbin to overflow
4 Ensure adequate illumination and ventilation for the job. 4 Do not generate extra waste
5
Drop paper, plastic, glass, metal and bio- medical waste in a separate bin kept for this purpose. 5
Do not disturb the safety equipment from assigned location
6
Know the emergency equipment where Emergency equipment like first aid box, SCBA, firefighting equipment, stretchers are kept. 6
Do not block emergency switches and on / Off switches of the equipment by storing of materials in front of work
7 Arrest all type of spills such as water, oil, gas, steam etc. and clean up the area immediately 7
Do not leave cleaning agent like acetone, Isopropyl alcohol, kerosene etc. at the work area after completion of work
8 Material and equipment needed for future usage are to be tagged and arranged in order. 8
Do not block fire exit point by storing materials or by means
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9 Assign a periodicity for the documents to be weeded out and follow it scrupulously 9 Do not leave a spillage unattended
10
Ensure exits are indicated/ Painted for use during emergency.
WORK IN CONFINED SPACE Sr Do's
Sr Don’t's
1
Isolate, drain, wash, dry and purge for a sufficient time to ensure safe atmosphere inside. 1
Do not work without supervision in a confined space.
2 Obtain a safety work permit and follow the instruction provided in the permit. 2 Do not work if you are medically unfit.
3 Purge the confined space and ensure continuous ventilation on the area 3 Do not smoke in the confined space.
4 Ensure continuous communication with the person standing outside 4
Do not enter in to confined space, if the oxygen concentration is less than 19%
5 Use non-sparking tools in explosive environment 5
Do not enter in to confined space without checking for presence of toxic, explosive or asphyxiating gases.
6 Keep all manholes open and the lowest drain point open. 6
Do not rely on closed valves for isolation. The isolation should be supplemented by suitable banking.
7
The man entering into the tank should be supplied with a safety belt and lifeline, the free end of which is held by a person standing outside. 7
Do not use equipment of voltage more than24V inside a confined space.
8 Get clearance from the competent person before entering in the confined space.
8
Do not take large quantity of cleaning chemicals into the tank than the required quantity of chemicals for a day work.
9 Number of persons entering and leaving the confined space should be counted and tallied. 9
Do not encourage more than one type of work at a time in the confined space.
10
Put up a danger board as "men working in the tank"
10
Do not carry matches / lighter into the confined area.
11
Use SCBA, if the oxygen concentration is less than 19%.
WORK AT HEIGHT Sr Do's Sr Don’t's
1
When any person has to work at height from where he is likely to fall, provision shall be made by fencing or otherwise, to ensure the safety of the person so working. 1
Don't work at unguarded height if you are physically / mentally unfit.
2 Safe means of access and platform should be ensured for working at height. 2
Do not allow two jobs, one above the other simultaneously.
3 keep tools in a safe bag / toolkit 3
Don’t tie safety belt at lower elevation than the working level of person.
4 Use safety belt and safety helmet while working in unguarded area at height. 4
Do not keep loose material on the platform.
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5
When person is working at height, warn people below through display of caution board and cordon off the area if necessary. 5
Do not drop material from higher elevation.
6 Entry to areas above the false ceiling should be controlled through work permits. 6
Do not use pipeline and equipment as means of approach to work spot.
7 Ropes, slings, or bucket used for carrying materials to or from an elevated place should be inspected before use. 7
Do not work at height without taking valid safety permit.
8 Work at height should be performed in good day light, preferably when strong winds not existing. 8
Do not use damaged rope for lifting material to higher elevations.
9 Ensure that the persons employed to work at height are medically fit. 9
Do not work without protection near overhead line or uninstalled bus bars.
10
Obtain height pass/safety work permit for working on unguarded height. 10
Do not work without protection near high pressure / steam line.
11
Do not use portable ladder as platform or platform support.
12 Do not use cable tray as portable ladder.
MATERIAL HANDLING Sr Do's
Sr Don’t's
1 Use proper lifting tool and tackle having adequate capacity. 1
Do not use the equipment for the purpose other than its design intention.
2 Only authorized persons should operate material handling equipment 2
Do not allow personnel to move underneath lifted load.
3
Each tool, tackle or equipment should have identification number and safe working load marked on it. 3
Do not load the equipment above its safe working load.
4
Assess weight of the material, distance to be carried, and hazard etc. before lifting the load. 4
Do not use makeshift arrangement for lifting the material.
5 Store the lifting tools and tackles at its designated place. 5 Do not use defective tool and tackles.
6 Wear safety boots with metal toe while handling material. 6
Do not use altered or repaired lifting equipment without inspection and test.
7 Inspect and test all lifting tools and tackles regularly as per factories Act. 7
Do not drag chains, ropes, or cables etc. on the floor.
8
When placing a sling on a load, ensure all sharp corners are covered with pad or soft material. 8
Keep the tools and tackles free from adverse effect of atmosphere by applying suitable protective coating.
9 Whenever possible, mechanical material handling shall be adopted. 9
Do not allow male and female adult to lift a load manually higher than 55 kgs and 30 kgs. Respectively.
10
While lifting a load physically, keep the load as possible to the body with feet properly placed for body balance.
10
Do not hold the load with tip of the fingers; grasp the load firmly with palm.
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11
Bend knees, keep back straight, keep the load close to the body and lift the load.
11 Never carry a glass sheet with bare hands.
7.12 Social Impact Assessment R&R Action Plans
The proposed project will have a positive impact on the social and economic conditions of the
people of the region in terms of direct and indirect employment, skill diversification, infrastructure
development, business development etc.
The proposed unit is located in GIDC notified area so there will be no direct impact on Rehabilitation
and Resettlement.
7.13 Mitigation Measures for Seepage & Soil Contamination
• The flooring of manufacturing premises has been made impervious by RCC construction, hence
there is no possibility of soil contamination.
• Any spillage shall be collected in drum/carboy and can be used in next batch.
• Further, following mitigation measures will be taken.
7.14 Chemical Spillage Control Measures
During Storage
• Chemicals are stored within easy reach of everyone and no higher than eye level.
• Do not store chemical bags directly on the floor where they might be knocked over and broken.
• Minimize the number of chemicals and size of containers stored.
• That lighting and ventilation is adequate is the storage area.
• Do not store chemicals in unsuitable bags.
• Regularly inspect chemicals in storage to ensure there are no spillage or torn bags. Some items
to note:
• Keep the bags clean and free of spills and stains.
• Do not store incompatible chemicals together (e.g. acids with bases). Chemicals must be stored
by hazard category and not alphabetically (except within a hazard group).
Handling & Use
• If possible, keep highly toxic or corrosive gases in a fume hood or other ventilated enclosure.
• Ensure you have access and know the location of a suitable chemical spill kit before you start
working with chemicals.
Contaminated soil (accidental outside premises):
• Waste should be disposed of properly to avoid soil pollution. It suggests that acidic and alkaline
waste be neutralized before they are disposed of so they will not contaminate the soil. Waste
that is biodegradable should be broken down in a controlled environment before being disposed
of because it is a much faster, resource-saving method.
• Contaminated soil should be neutralized, and it will be packed in HDPE bag and finally it is
disposed.
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CHAPTER – 8: PROJECT BENEFITS
8.1 Introduction
M/s. Gujarat Dyestuff Industries (Pharma Unit). located at Plot No. 133/4, 133/5, 133/6, GIDC
Nandesari, Dist: Vadodara-391340., Gujarat. India is an existing unit into manufacturing of Bulk
Drugs such as Cifixime Trihydrate, Cefuroxime Axetil, Cefpodoxime Proxetil, Ampicilin, Amoxicillin
Trydrydate, Clobetasole Propionate, Betamethasone Dipropionate, Betamethasone Valerate,
Betamethasone Sodium Phosphate, Dexamethasone Sodium Phosphate, Beclomethasone
Dipropionate, Mometasone Furoate, Methylcobalamine, Ofloxacin, Levofloxacin, Quinon Sulphate,
Cloxacillin Sodium, Oxacillin Sodium, Di Cloxacillin Sodium, Flucoxacillin Sodium.
New products Ethoxylates, Metformin Hydrochloride, and additional Methylcobalamine that falls
in Schedule 5(f) are planned to be manufactured and hence the application for EC is being done
The project benefits will be significant in terms of benefit to the local socio-economic status as well
as economic conditions of state & country. The proposed project site is well linked with national
highway and is situated in the Industrial estate of GIDC Nandesari having all required
infrastructures. Therefore, infrastructural development because of proposed project will not be
major but improvement in public infrastructure due to CSR is anticipated.
8.2 Economical Benefits
The development of project plays a key role in the economic growth of any country. The important
factors affecting the operating economics of power generating technologies are capital cost, debt
equity pattern, and interest during construction, discount rate and fuel choice.
8.3 Socio Economic Development of the Region
Skilled and Semi-skilled employment potential in terms of indirect employment of the proposed
project will be non-marginal and will usually remain widespread across a long region. The
proposed project will cause generation of income and employment opportunities the ancillaries
and service units which will came in the vicinity of the plant, specifically, in transport and
manufacturing sectors. The project has generated & expected to generate indirect employment in
other sectors. Overall assessment of the employment and income effects indicates that the project
has strong positive direct as well as indirect impact on employment and income generation of the
area.
8.4 Un-Skilled Manpower
The project has employment generation potential by way of recruiting local people directly for
different activities of the project, specifically at the construction phase. It is expected that
Gujarat Dyestuff Industries (Pharma Unit) Chapter 8 Project Benefits
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substantial portion of the investment in this project will trickle down to the local people in the form
of employment and income.
8.5 Socio Economic Development Aspects
1 There will be more employment generated due to the proposed project both during the
construction phase and operation phase. On the basis of technical knowledge acquired by the
local village youths, they will be providing with suitable employment Opportunity in the
company.
2 The labour force required during construction and operation phase shall be sourced from
nearby area.
3 Supporting infrastructure requirement in nearby village schools.
4 Skill & Livelihood development program.
5 Health related program.
6 Sports development program.
TABLE 8.1 BUDGETARY PROVISIONS FOR SOCIAL UPLIFTMENT/YEAR
Sr. No.
Activity Yearly Estimated budgetary provision (Rs)
1 Supporting Infrastructure requirement in nearby village schools.
During the last three FY: 2016-19 the unit had spent
around Rs. 17.55 Lac in 2016-17 and Rs. 14.85 Lac in
2017-18. on the above-mentioned CSR programs.
Proposed
2 Skill & Livelihood development programme 3 Health Related Programme 4 Sports development Programme
CER – Proposed Activity Yearly
Estimated budgetary provision (Rs) We shall allocate Rs. 6.00 Lac (i.e. 2.0 % on the CER based on the additional investment
of 3 Crores
Year 2020 Year 2021 Year 2022 Year 2023
Year 2024
Skill Development Program 10000 10000 10000 10000 10000 Avenue plantation, plantation
in community areas, 10000 10000 10000 10000 10000
Health Related Programme 10000 10000 10000 10000 10000 Education Related Programme 10000 10000 10000 10000 10000
Awareness to local villagers to waste management
4000 4000 4000 4000 4000
Infrastructure development (Toilet Blocks and Sanitation)
0 0 30000 0 30000
rainwater harvesting, soil moisture conservation
programs 0 0 200000 0 0
Infrastructure creation for drinking water supply at
community (RO Plant) 0 0 0 120000 0
Year Total 44000 44000 274000 164000 74000
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CHAPTER – 9 ENVIRONMENTAL COST BENEFIT ANALYSIS
Total existing production is 20MT / Month & Production planned for expansion is 1500.5 MT /
Annum. Total production will be 1520.5 MT/Month. Hence the Environmental cost benefit analysis
has been calculated based on the total Proposed Organic Product and Proposed In-Organic Products
as well as existing In-Organic products.
The management will spend approx. Rs. 112 lacs. as recurring cost per annum on the pollution
control measure, green belt development and other environment management. Recurring cost is
estimated as below:
TABLE 9.1 BUDGET ALLOCATION FOR ENVIRONMENT MANAGEMENT
Sr. No.
Description Capital cost (Rs.)
(Lac) Recurring cost (Rs.)
(Lac. /annum) Existing Proposed Total Existing Proposed Total
1 Air pollution
control 6.5 2.5 9 5 1.5 6.5
2 Water pollution
control 33 100 133 4.5 90.5 95
3 Hazardous
waste management 3 2.5 5.5 2.5 1.5 4
4 Environment monitoring & Management 5 3 8 2 1.5 3.5
5 Occupational
health 1 0.5 1.5 0.5 0.5 1
6 Greenbelt
development 1.5 0.5 2 1 1 2 Total 50 109 159 15.5 96.5 112
Gujarat Dyestuff Industries (Pharma Unit). has spent Approximately Rs. 50 Lac for Existing
Products & proposes Rs. 109 Lac for proposed Product as capital expenditure on environmental
management. With a total of 159 lac.
The recurring cost could be Approximately Rs. 15.5 Lac per annum for Existing Products & Rs. 96.5
lac for proposed Product. With a total of 112 lac/annum.
Considering 112 Lac. / Annum spent on overall environmental management for manufacturing of
1520.5 MT / Month of Product, the loading on the product cost with respect to Environmental
Management works out to be INR 7366/- Per MT of product Manufactured.
Total 40 KLD Industrial w/w will be generated. Generated Industrial w/w will be sent to in house
ETP for treatment. Treated water from the ETP will be passed through ETP RO Plant & 20KLD
recovered Product to be used for Cooling Tower Makeup. 20 KLD Reject to be evaporated in MEE.
MEE Condensate of 19.6 KLD to be recovered for reuse.
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TABLE 9.2 ECONOMICAL AND TECHNICAL VIABILITY OF THE EFFLUENT TREATMENT
SYSTEM
Sr. No. Description Utilities/day Rate Rs. /unit Amount Rs/day
1 Electrical 1000 KWH 7.5 7500
2 Solid waste disposal - NA NA
3 Manpower 5 600 3000
4 Chemical
Consumption 2 kg 5 10
Total 10510
Note: Monthly expenditure for effluent treatment will be around Rs. 3.15 Lac. The total production
capacity will be approximately 1520.5 MT/Month. Expenditure for ETP to the tune of 207.3 Rupees
/ MT of product Manufactured.
MEE Plant to be installed for evaporation of the RO Reject. Operation cost / day of MEE will be
approximately 30,000/- per day. Expenditure to the tune of 592/MT of product Manufactured.
Being Bulk Drug & ethoxylates, the profit margins in the products are fair enough to incorporate
the expenditure for environment management to the tune of 799.3 Rupees / MT of product
Manufactured.
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CHAPTER – 10 ENVIRONMENTAL MANAGEMENT PLAN
10.1 Background
The Environment Management Plan (EMP) is required to ensure sustainable development in the
area surrounding the proposed project. Hence, it needs to be an all en-compassive plan for which
the industry, Government, Regulating agencies; like Pollution Control Board working in the region
and the local residents of the area need to extend their co-operation and contribution.
M/s. Gujarat Dyestuff Industries (Pharma Unit). located at Plot No. 133/4, 133/5, 133/6, GIDC
Nandesari, Dist.: Vadodara-391340., Gujarat. India is an existing unit into manufacturing of Bulk
Drugs such as Cifixime Trihydrate, Cefuroxime Axetil, Cefpodoxime Proxetil, Ampicilin, Amoxicillin
Trydrydate, Clobetasole Propionate, Betamethasone Dipropionate, Betamethasone Valerate,
Betamethasone Sodium Phosphate, Dexamethasone Sodium Phosphate, Beclomethasone
Dipropionate, Mometasone Furoate, Methylcobalamine, Ofloxacin, Levofloxacin, Quinon Sulphate,
Cloxacillin Sodium, Oxacillin Sodium, Di Cloxacillin Sodium, Flucoxacillin Sodium.
New products Ethoxylates, Metformin Hydrochloride, and additional Methylcobalamine that falls
in Schedule 5(f) are planned to be manufactured and hence the application for EC is being done
10.2 Objectives of Environmental Management Plan
The aim of environment management plan is to conserve natural resources and water, to prevent
pollution of environment, to ensure effectiveness of control measures and monitoring programme,
to ensure safety, welfare and good health of worker, to minimize generation of waste.
It has been evaluated that the project will have no major impacts on the surrounding areas.
Mitigation measures at the source level and an overall Management Plan at the site level are elicited
so as to preserve the surrounding environment.
Gujarat Dyestuff Industries (Pharma Unit). Carries out & shall carry out the regular monitoring in
future as well as ensure that pollution is limited below prescribed limits and shall take corrective
action by providing new pollution control equipment if required. In case the monitored results of
environment pollution are found to exceed the prescribed limits, remedial actions are taken
through the concerned plant authorities. The actual operation and maintenance of pollution control
equipment of each department is under respective department heads.
10.3 Components of EMP
The following mitigation measures are recommended in order to synchronize the economic
development of the project area with the environmental protection of the region. The construction
phase impacts are mostly short term, restricted to the plot area and not envisaged on the larger
scale. In the operational phase, the environmental impacts are due to continuous operation of the
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project; hence, the emphasis in the Environment Management Plan (EMP) is to minimize such
impacts. The emphasis on the EMP development is on the following:
• Mitigation measures for each of the activities causing the environmental impact
• Monitoring plans for checking activities and environmental parameters and monitoring
responsibilities
• Role responsibilities and resource allocation for monitoring
• Implementation schedule and reporting procedures
All the necessary controls w.r.t. management of Liquid / Hazardous / Gaseous pollutants will be
exercised.
For all liquid effluents, full-fledged effluent treatment plant consisting of primary, secondary and
tertiary treatment will be installed to ensure adequate treatment prior to discharge.
DG Set to be housed in Acoustic enclosure. Adequate stack height provided. To handle hazardous
waste as per Hazardous Waste (Management, Handling and Trans-boundary Movement) Third
Amendment Rules, 2016 of Environment Protection Act, 1986. Hazardous waste will be disposed
off at the common Incinerator / secured land fill facility available in the nearby vicinity.
• Workplace monitoring will be carried out regularly through monitoring systems and
periodic checking.
• Ambient air quality will be monitored regularly.
• Good green belt will be maintained inside and outside the premises by planting trees,
developing lawns.
• To work in R&D for continuous improvement in process to reduce Pollution Load & moving
towards adopting cleaner production technology.
10.4 Organogram of Environmental Management Cell
Apart from having an environmental management plan, it is also necessary to have a permanent
organizational set up charged with the task of ensuring effective implementation. In this effect,
Gujarat Dyestuff Industries (Pharma Unit) has assigned responsibilities to coordinate the activities
concerned with management and implementation of environment control measures.
An environment management cell is created to manage all environmental issues. The Head Plant
Operations is responsible for environmental issues at plant. The responsibilities of the various
members of the environment management cell are given in Table 10.1 as follows.
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TABLE 10.1 ENVIRONMENT MANAGEMENT CELL
10.4.1 Reporting system on non-compliances/violations of Environmental Laws
Company has developed reporting systems of non-compliances/ violations of environmental
norms to the Board of Directors as follow.
• Identify non-compliance/ violation of environmental norms, which are mentioned
in Consent to operate and letter of Environmental clearance.:
• EHS executive identifies non-compliance/ violation from failure to comply & timely
response to concerned authority for this noncompliance/violation & also inform
about this to technical head of the industry.
• General manager takes it into action, discusses this in Management meeting and
gives necessary guideline to the concerned executives to comply to this non-
compliance/ violation of environmental norms.
• EHS executive takes measures against these non-compliances/violations of
Environmental laws & takes care not to have such violations in the future.
10.5 Environment Management During Construction Phase
The Environment Management plan is meant for mitigation/ management of the adverse impacts
and the strengthening positive impacts during proposed project.
During Construction Phase sanitation facilities will be required. Temporary sanitation facilities will
be provided. Environment Management Plan is tabulated in Table: -10.2
TABLE: 10.2 CONTROL MEASURES FOR CONSTRUCTION PHASE
Activity Environmental
Impacts Mitigation Remarks
Site Clearing, • Air Water Spraying Will be carried out
by GDI PPE’s will be used
Gujarat Dyestuff Industries (Pharma Unit) Chapter 10 Environmental Management Plan
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Activity Environmental
Impacts Mitigation Remarks
Construction & Erection of Plant
Activity
• Land • Water • Noise
Proper Maintenance of Vehicle will be done
Construction hazardous materials such as lubricating oils, compressed
gases (for welding), paints, varnishes, etc. shall be stored as per the
prescribed / accepted safety norms To mitigate noise generation,
construction labor would be provided with noise protection devises like earmuffs and occupational safety ware, as per requirement. Noise
generating equipment & vehicular movement shall be stopped during
night hours Construction wastes shall be
disposed off by adopting environmentally compatible
methodology
Toilets • Water
Ensure proper sewage collection, conveyance & disposal.
Will be carried out by GDI
domestic wastewater to be disposed through septic tank & soak pit.
Direct / Indirect Employment
• Socio-economic issue
Continue policy of local employment
The hazardous materials used during the construction may include petrol, diesel, welding gas and
paints. These materials would be stored and handled according to the guidelines. Some of the
precautions of storage and handling of the hazardous materials and waste includes the following:
• Dyke enclosures would be provided where-ever necessary for storage of hazardous
materials.
• Diesel and other fuels would be stored in separate dyke enclosures.
• Separate storage for waste paints and thinners, contaminated rags and brushes to facilitate
recycling and reuse.
• Vehicle maintenance area to be selected properly, to prevent contamination of soil and
ground water by accidental spillage of oil, and other wastes
10.6 Environment Management during Operation Phase.
10.6.1 Air Environment
The main sources of air pollution will be flue gas emission from existing & Proposed Thermic Fluid
Heaters & DG Set. DG Set to be housed in Acoustic Enclosure to attenuate noise as pollution control
measure. SPM, SO2 & NO2 are the main pollutants generated from the flue gas stack.
Moreover, proper stack height will control emission from flue gas stack.
Gujarat Dyestuff Industries (Pharma Unit) Chapter 10 Environmental Management Plan
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TABLE 10.3 DETAILS OF AIR EMISSION
FLUE GAS EMISSION FOR EXISTING AND PROPOSED PRODUCTS
Sr. no.
Source of emission
With Capacity
Stack Height
(meter)
Type of Fuel
Quantity of Fuel
MT/Day
Type of emissions
i.e. Air Pollutants
Air Pollution Control
Measures (APCM)
Existing Flue Gas emissions
1 Thermic Fluid
Heater (20 Lac Kcal)
30 F.O / LDO 40 Lit/Hr. PM, SO2, NO2 Caustic Scrubber
Proposed Flue Gas emissions
1 Thermic Fluid
Heater (40 Lac Kcal)
30 Natural Gas 555Nm3/Hr. PM, SO2, NO2 Adequate Stack Height
2 DG Set
(385 KVA) 5 HSD 90 Lit/Hr. PM, SO2, NO2 Adequate
Stack Height
Process Emissions:
Existing – No Process Emissions
Proposed – No Process Emissions
10.6.1.1 Fugitive emission
The emissions are normally defined as emissions to the atmosphere resulting from leaking piping
sources and equipment such as valves, flanges, pump seals, connections, and compressor seals open
end lines and pressure relief valves. The emissions are not visually observed but can be measured
in relatively low concentration at each area of source.
Fugitive emissions are expected to be generated during construction and operation stages of the
proposed project. During construction stage, main source of fugitive emission is dust which is
expected mainly due to movement of vehicles carrying construction material and vehicles used for
construction. During operation stage, leakage through valves, pumps, emission from open drum
containing chemicals, open feeding; storage tanks, etc. are the major sources of fugitive emissions.
Excess use of solvent may also result into fugitive emission from the process vessels.
Mitigation measure
General control measures like routine & regular inspection to identify leakage, preventive
maintenance and operational maintenance etc. will be implemented by the unit.
• Preventive maintenance of flange connections and glands of pumps.
• Management will also ensure proper usage of the Personnel Protective Equipment by the
workers.
Gujarat Dyestuff Industries (Pharma Unit) Chapter 10 Environmental Management Plan
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• Regular Workplace Monitoring, Ambient Air, Stack Air Monitoring to be done
10.6.1.2 VOC Monitoring Plan
Regular Workplace monitoring as per the Factories Act will be conducted and the details
maintained in Form 37.
• Regular Monitoring at workplace to be done for VOC.
• Handy LEL meters will be available at site for various chemicals and this will be
monitored on regular basis in house.
10.6.2 Water Environment
This is existing unit manufacturing Bulk Drugs, Additional products Ethoxylates & Metformin are
planned to be manufactured. Existing Products - 38 KLD, Proposed Products 249 KLD, 20 KLD
Treated Effluent from ETP to be recycled after RO Plant & 19.6 KLD Condensate from MEE Plant.
hence 247.4 KLD fresh water will be used, which will be met through GIDC Nandesari Industrial
Estate water supply (attached as Annexure 11). Out of which, process (17 KLD), cooling tower
(250 KLD), boiler (0 KLD), Scrubber (1 KLD), Washing (4 KLD) & Domestic (10 KLD). Total water
requirement will be 287 KLD in which 20 KLD Treated Effluent from ETP to be recycled after RO
Plant & 19.6 KLD Condensate from MEE Plant. Hence freshwater requirement will be 247.4 KLD.
Total 40 KLD Industrial w/w will be generated. Generated Industrial w/w will be sent to in house
ETP for treatment. Treated water from the ETP will be passed through ETP RO Plant & 20KLD
recovered Product to be used for Cooling Tower Makeup. 20 KLD Reject to be evaporated in MEE &
19.6 KLD condensate to be recovered. 8 KLD domestic wastewater will be generated, which will be
disposed through Septic tank & Soak Pit.
10.6.2.1 Economical and Technical Viability of the Effluent Treatment System
Sr. No. Description Utilities/day Rate Rs. /unit Amount Rs/day
1 Electrical 1000 KWH 7.5 7500
2 Solid waste disposal - NA NA
3 Manpower 5 600 3000
4 Chemical
Consumption 2 kg 5 10
Total 10510
Note: Monthly expenditure for effluent treatment will be around Rs. 3.15 Lac. The total production
capacity will be approximately 1520.5 MT/Month. Expenditure for ETP to the tune of 207.3 Rupees
/ MT of product Manufactured.
MEE Plant to be installed for evaporation of the RO Reject. Operation cost / day of MEE will be
approximately 30,000/- per day. Expenditure to the tune of 592/MT of product Manufactured.
Being Bulk Drug & ethoxylates, the profit margins in the products are fair enough to incorporate
the expenditure for environment management to the tune of 799.3 Rupees / MT of product
Manufactured.
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10.6.3 Hazardous Waste Management
Main sources of hazardous waste generation will be ETP Sludge, Residue, discarded container/
bags/ Drums & Used oil/Spent Oil, Spent Solvent for recovery.
10.6.3.1 Storage of Hazardous Waste:
Hazardous waste shall not be stored for a period more than 90 days. And shall maintain records
and make them available for inspection. Store at a designated Onsite-secured area with impervious
floor that affords protection from sun & rain fall, spreading of leachate, mixing of wastes etc.
10.6.3.2 Transportation of Hazardous Waste:
Properly packed & labeled waste transport through dedicated vehicle to a captive facility/
authorized TSDF/CHWI facility.
10.6.3.3 Disposal of Hazardous Waste:
• ETP Sludge will be Stored at site and then accumulated quantity disposed to TSDF M/s.
NECL Nandesari.
• Discarded containers / barrels / liners used for hazardous wastes/chemicals. will be
Collected, Stored, decontaminated & sold to approved vendor/ recycler.
• Used oil/Spent Oil will Collected, stored, transported, disposed by selling to registered re-
refiners.
• Distillation Liquid Residue - CHWIF incinerator facility of M/s. Nandesari Environment
Control Ltd. (NECL) / Coprocessing.
Hazardous waste will be stored in proper storage room and handed over to GPCB/CPCB approved
vendor for final disposal. The collection, Storage and disposal of hazardous waste will be done as
per Hazardous waste (Management and Handling) Rules 2016.
Record of hazardous waste generation and disposal shall be maintained on printed logbook. All
necessary precautions shall be taken during handling, loading and unloading of hazardous wastes.
Hazardous waste generation quantity, physical characteristics and mode of disposal are given in
Table-10.4.
TABLE 10.4 DETAILS OF HAZARDOUS WASTE AND ITS MODE OF DISPOSAL
Sr. no
.
Type/Name of
Hazardous waste
Specific Source of generatio
n (Name of
the Activity, Product
etc.)
Category and
Schedule as per
HW Rules.
Quantity (MT/Annum)
Management of HW
Existing Products
Proposed Products
Total After
Expansion
1 ETP Sludge
ETP Sch-I/ 35.3
12 MT/Annu
m
0 12 MT/Annu
m
Collection, storage,
treatment, transportation, and disposal
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at Nandesari Environment Control Ltd
(NECL) TSDF 2 Discarded
Bags & Containers
Production plant
Sch-I/ 33.1
108 MT/ Annum
0 108 MT/ Annum
Collection storage &
Decontamination within
factory premises.
3 Used Oil From Machinery
and TFH
Sch-I/ 5.1
0.6 KL/Annu
m
0 0.6 KL/Annu
m
Collection, storage,
transportation, Disposal by
selling to registered re-
refiners 4 Distillation
residues From
Solvent Recovery
Sch-I/ 20.3
36 MT/Annu
m
30 MT/Annu
m
66 MT/Annu
m
CHWIF incinerator
facility of M/s. Nandesari
Environment Control Ltd.
(NECL) / Coprocessing
5 Spent Solvent for recovery
Process Sch-I/ 20.2
252 MT/Annu
m
4116 MT/Annu
m
4368 MT/Annu
m
Captive In-house
Recovery.
6 MEE Salt
From Evaporation of RO
Reject
Sch-I/ 37.3
0 MT/Annu
m
144 MT/Annu
m
144 MT/Annu
m
Nandesari Environment Control Ltd
(NECL) TSDF
10.6.3.4 Methodology of Decontamination of drums/containers
Guideline provided by the Gujarat Pollution Control Board will be followed to decontaminate
drums/Containers/ Barrels.
• For disposal Containers/drums will be totally emptied.
• Containers/drums will be washed properly, checked for pH. This ensures
containers/drums are cleaned before disposal.
• Removal of label & content of product or raw material will be done.
• Then it will be labelled as clean & deposited in the area which demarked for disposal
• Then the drums/containers will be inspected by the authorized agency approved by the
GPCB. Then they check quality of cleaned drums/containers.
• Then the containers are disposed off to actual raw material supplier or to Other Approved
recyclers.
10.6.4 Noise Environment
The sound pressure level generated by a noise source decreases with increasing distance from the
source due to wave divergence. The propagation and attenuation of noise pressure wave is
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dependent on many parameters amongst which, the medium of travel and the ambient conditions
are the most significant parameters. In order to minimize adverse impact on the noise environment,
due attention shall be given for implementing noise control measures. Comprehensive measures
shall be taken at design stage for noise from proposed unit. The measures are as under:
• The noise level at the plant boundary shall be restricted to 75 dB (A) during daytime and
70 dB(A) during nighttime.
• Noise level shall be specified for various rotating equipment as per Occupational Safety and
Health Association (OSHA) standards.
• Equipment lay-out shall be done considering segregation of high noise generating sources.
Erection of suitable enclosure, if required, to minimize the impact of high noise generating
sources.
• There may be some addition to the ambient noise level, due to the increased transportation
activities. This creates a slight adverse impact on the sound environment.
• Regular oiling, lubrication and maintenance of the equipment shall be carried out to
minimize noise generation.
The sources of noise generation will be transportation activities, DG Set, cooling tower, plant
machinery etc. The unit will take following measures to control noise pollution.
• Acoustic laggings, enclosures and silencers shall be provided wherever necessary for high
noise generating equipment.
• Soundproof glass paneling shall be provided for all operating stations / control rooms as
well as for shift rooms at critical places.
• Strict implementation/ compliance of all statutory norms w.r.t. noise generation,
occupational exposure shall be done.
• Use of personal protective devices such as earmuffs and earplugs shall be strictly enforced.
• Acoustic barriers / shelter shall be developed in noisy workplaces.
• The company shall develop a green belt around the periphery of the premises, which shall
act as a barrier to the propagation of noise
• Noise generating sources in the plant areas shall be monitored regularly. Monitoring of
ambient noise levels should also be carried out regularly both inside the premises as well
as outside the greenbelt.
• Periodic monitoring for Audiometry in periodic health checkup.
However, due to the attenuation of noise level within the factory and due to the fact that the project
site is situated in a well-developed industrial estate and not in the immediate vicinity of human
settlement, significant impact is not expected in the nearest present human settlement.
10.6.5 Odour Control Plan
Reactors will be closed, charging of chemicals will be mechanized. LDAR will be followed, however
if any spillage or leakage of such chemicals are taken place then following material handling
procedure will be followed to reduce the odor and release of chemical vapor in atmosphere.
Storage & Handling of Hazardous Chemicals:
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• Storage of hazardous chemicals will be kept as per requirements.
• All drum / barrels with hazardous chemicals have labels indicating the contents and warning of the hazard.
• Necessary information on safe handling and first aid measures will be available on the label.
• Workers dealing with hazardous chemicals will be trained on health risk and safe handling.
• Direct Exposures to hazardous chemicals will be minimized.
• Hazardous chemicals will be transferred through closed piping system.
• Separate storage section for storage of hazardous and non – hazardous raw materials will be provided.
Process Vessel and other Equipment related:
• Checking of process vessels and equipment will be carried out regularly.
• Records related to equipment maintenance and its planning schedules will be maintained.
Safety related:
• Adequate types of personal protective equipment will be provided and also safety
training will be provided.
• Emergency shower and eye wash station will be available at the worksite.
• Arrangement for 24 hr. medical facilities by contact with nearest health care center
/ hospital.
• Pre – employment medical check – up and annual medical checkup will be carried
out and its records will be maintained.
• Monitoring of occupational hazards like noise, ventilation, chemical exposures etc.
will be carried out regularly and its records will be maintained.
10.7 Occupational Health & Safety
Company will ensure to conduct all business operations in compliance with applicable laws,
regulations and standards related to occupational Health, Safety and Environment.
• An emergency plan has been prepared, rehearsed regularly through periodic mock drills &
fire drills, to deal with firefighting.
• Fire protection system will be provided.
• Portable Fire Extinguishers of CO2 & DCP type are provided.
• Fire hydrant system to be provided.
• Fire Alarm & smoke detectors system is installed.
• Employees are provided with Personal Protective Equipment like earplugs, nose mask,
safety shoes, helmet, earmuffs, body aprons etc. wherever required.
• Training on industrial safety and health shall be conducted periodically for workers and
staff for reinforcement of safety SOP’s.
• Physical and chemical properties of raw materials and products as MSDS are provided in
plant area.
• Good housekeeping will be ensured within the factory premises
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• Pre-employment medical check-up at the time of employment & periodic health check-up
of regular employee will be carried out.
10.8 Green Belt Development
Implementation of greenbelt program is prime importance for any development. The total area of
the plot is 3691.10 m2 (0.36911 Ha) . Out of which, 1476 m2 will be greenbelt area of 1m width. It
is around 40% of plot area. Moreover, to fulfill the total greenbelt development area, the company
has planned to develop green belt in surrounding area of Industrial park and nearby villages.
Trees will also help in attenuate the ambient noise level, prevent soil erosion. This will also act as
a barrier between inside & outside environment. This will help in preventing outside pollution to
come in the factory premises.
Purposes:
The stated objectives of our green belt policy are to:
(1) Protect and develop natural or semi natural environments.
(2) Improve air quality within our industry and surrounding areas.
Advantages:
• Green belts are compensatory plantation to restore the ecological balance.
• Green belts insure a minimum distance between the industrial sources of pollution and the
receptors/ residential areas, prone to the health hazards of industrial pollution.
• Green belts can absorb the air and water pollution caused by the industry.
• For Example, Noise can be decreased by up to 10 decibels by green belts.
• Trees not only assimilate carbon dioxide and release oxygen but also play an important role
in trapping some obnoxious gases and particulate matters in the air change green belt
functions both as filter and sink for contaminants.
• Green belts can improve the local microclimate. These occur mainly through their influence
on wind, temperature and humidity.
• Green belts provide picnic spot and recreation grounds.
• In the dryer part of the area, the trees reduce the effect of dryness and desiccate hot wind
and increase the availability of soil moisture
10.8.1 Plants / Trees Should be Selected for Green Belt Area
For the development of greenbelt, plants having simple big leaves are preferred with compound or
pinnate leaves. Native trees are preferable. The plants are suitable for green belt development
based on gaseous exchange capacity of foliage which is ascertained by various characteristics and
hence the following aspects are important while selecting the plant species:
• The species should be fast growing and having thick canopy cover
• It should be perennial and evergreen and should have large area index
• It should be indigenous and suitable to local climatic conditions
• It should be efficient in absorbing pollutants without significant effects on plant growth.
• It should be fruit yielding trees, if possible, especially in wasteland areas.
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TABLE 10.5 SPECIES PROPOSED TO BE GROWN FOR GREENBELT DEVELOPMENT
Common name Family Scientific name Neem Meliaceae Azadirachtaindica Gulmohar Fabaceae Delonixregia Champo Apocynaceae Plameria Badam Combretaceae Terminalia Piplo Moraceae Ficus religiosa Papaya Caricaceae Carica papaya Gando baval Mimosaceae Prosopis DC Piludi Salvadoraceae Salvadora persica Bougainvel Nyetaginaceae Bougainvillea spectabilis Daturo Solanaceae Datura metel L Arduso Simaroubaceae Ailanthus excesia Lal Karen Apocynaceae Nerium indicum Jasud Malvaceae Hibiscus rosasinensis Chiku Sapotaceae Achrassapota
Dust Absorbers For Air Pollution Attenuation
Azadirachtaindica (Neem) Terminaliatomentosa (Asan) Meliaazaderach (Mahaneem) Acacia auriculiformis (Babul)
Terminaliaarjuna (Arjun) Polyalthialongifolia (Debdari) Cassia fistula (Amaltas) Ficusbenghalensis (Banyan)
Bauhinia variegate (Kachnar) Mangiferaindica (Aam) Neriumodorata (Kaner) Ficuselastica
TABLE 10.6 BUDGET FOR GREENBELT DEVELOPMENT
Year Budget amount in INR Nos. of trees 1st year 10,000 100 2nd year 10,000 100 3rd year 10,000 100 4th year 10,000 100 5th year 10,000 100
The measures like properly designed greenbelt areas, irrigation facilities, Sapling storage &
maintenance area and storage for greenbelt development resources/tools etc. shall be provided for
the management of greenbelt area in the plant premises. The necessary maintenance shall be done
throughout the extent of operation phase.
10.9 Rainwater Harvesting
Rainwater Harvesting is a way to capture rainwater when it rains, store that water above ground
or charge underground water table with it. Rain water harvesting refers to the collection and
storage of rain water and also other activities aimed at harvesting surface and ground water,
prevention of losses through evaporation and seepage and all other hydrological studies and
engineering interventions, aimed at conservation and efficient utilization of the limited water
endowment of physiographic unit such as a watershed.
Advantages of rainwater harvesting.
Gujarat Dyestuff Industries (Pharma Unit) Chapter 10 Environmental Management Plan
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• Effective rise in ground water levels
• Prevent evaporation and runoff of rainwater
• Solution to water scarcity problems
• It’s economical and energy saving
• Easy operation and maintenance.
However, as the unit is located in GIDC Nandesari, it would not be permitted to dig well for
rainwater harvesting. However, the unit would consult the local authority and look out the possible
contribution to undertake rainwater recharging / harvesting in the nearby area.
10.10 Cleaner Production
The following objective would be adopted for effective implementation of Cleaner Production (CP):
• The concept of Four -R’s- reduce, reuse, Recover and recycle would be implemented as
much as possible.
• Industrial effluent will be generated from the proposed project activities, which will be
treated in in-house ETP. Total 40 KLD Industrial w/w will be generated. Generated
Industrial w/w will be sent to in house ETP for treatment. Treated water from the ETP will
be passed through ETP RO Plant & 20KLD recovered Product to be used for Cooling Tower
Makeup. 20 KLD Reject to be evaporated in MEE, 19.6KLD MEE Condensate to be recovered.
8 KLD domestic wastewater will be generated, which will be disposed through Septic tank
& Soak Pit.
• The feeding of solid raw material would be done by hopper so that there is least spillage
due to fugitive emission.
• Liquid raw materials would be fed through metering pumps to reduce manual contact.
• Reuse of solvent after recovery.
• Optimum operating conditions would be maintained to get maximum yield.
• Housekeeping will be regularly maintained. Dedicated staff for the purpose will be
employed.
10.11 Flora & Fauna
The proposed project is situated within the GIDC Nandesari & looking to the Environmental
Management Plan, there shall not be any significant impact on the flora and fauna of surrounding
area
10.12 Capital Cost for Environmental Management
Environment Management The management will spend approx. Rs. 112 lacs. as recurring cost per
annum on the pollution control measure, green belt development and other environment
management. Recurring cost is estimated as below:
TABLE 10.7 BUDGET ALLOCATION FOR ENVIRONMENT MANAGEMENT
Sr. No.
Description Capital cost (Rs.)
(Lac) Recurring cost (Rs.)
(Lac. /annum) Existing Proposed Total Existing Proposed Total
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1 Air pollution
control 6.5 2.5 9 5 1.5 6.5
2 Water pollution
control 33 100 133 4.5 90.5 95
3 Hazardous
waste management 3 2.5 5.5 2.5 1.5 4
4 Environment monitoring & Management 5 3 8 2 1.5 3.5
5 Occupational
health 1 0.5 1.5 0.5 0.5 1
6 Greenbelt
development 1.5 0.5 2 1 1 2 Total 50 109 159 15.5 96.5 112
10.13 Prevention of Storm Water Contamination.
1 The ETP tanks shall have sufficient freeboard to prevent overflowing of effluent &
contamination of storm water.
2 pH Sensor at storm water outlet has been provided to constantly monitor the pH of outgoing
storm water from the premises.
3 Gate arrangement at the storm water outlet provided to stop outflow of contaminated storm
water outside the premises.
4 Pump at the storm water outlet will be provided to convey the contaminated storm water to
the ETP for treatment.
5 No raw material & sludge to be kept in open during rainy days.
6 Sludge drying beds will be covered with rain protection shed to prevent rainwater directly
falling on the sludge.
7 Storm water drains will be kept dry and the outlet gates closed during except during monsoon
season.
8 Close monitoring will be done to prevent any contamination of the storm water.
9 ETP area, Sludge handling area, Material Handling area, Plant & premises housekeeping will be
maintained all year round.
10 CCTV observation will be practiced within the premises.
11 Storm water treatment plant has been made by the unit for the contingency measures.
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CHAPTER – 11 SUMMARY & CONCLUSION
11.1 Introduction
M/s. Gujarat Dyestuff Industries (Pharma Unit). located at Plot No. 133/4, 133/5, 133/6, GIDC
Nandesari, Dist: Vadodara-391340., Gujarat.
This is an existing unit into manufacturing of Bulk Drugs such as Cifixime Trihydrate, Cefuroxime
Axetil, Cefpodoxime Proxetil, Ampicilin, Amoxicillin Trydrydate, Clobetasole Propionate,
Betamethasone Dipropionate, Betamethasone Valerate, Betamethasone Sodium Phosphate,
Dexamethasone Sodium Phosphate, Beclomethasone Dipropionate, Mometasone Furoate,
Methylcobalamine, Ofloxacin, Levofloxacin, Quinon Sulphate, Cloxacillin Sodium, Oxacillin Sodium,
Di Cloxacillin Sodium, Flucoxacillin Sodium.
New products Ethoxylates, Metformin Hydrochloride, and additional Methylcobalamine that falls
in Schedule 5(f) are planned to be manufactured and hence the application for EC is being done.
11.2 Location of the Project
The Project is located at coordinates
• 22°24'6.96"N, 73° 5'50.04"E
• 22°24'4.98"N, 73° 5'54.30"E
• 22°24'0.30"N, 73° 5'49.80"E
• 22°24'4.32"N, 73° 5'46.50"E
Distance from the project site
• The site is well connected with NH8. The site comes under tehsil Ta. Vadodara.
• Road: Site is 4km aerial distance away from NH-8. Via NH-8 site is well connected to
Bharuch, Surat, Mumbai, Vadodara, Ahmedabad.
• RAIL: The nearest railway station is Vadodara Junction, Nandesari Railway Station 1.8Km
towards N, Vadodara Railway Station – 13 Km towards SE. Western Railway Connects from
Mumbai-Surat-Bharuch-Vadodara-Godhra-Ratlam-Kota-Delhi.
• AIRPORT: The nearest airport is Vadodara which is in approximately 15 Km (Aerial
Distance). Regular flights from Delhi and Mumbai are available.
11.3 Product & Capacity
The proposed products to be manufactured are listed in Table below with their respective
capacities.
List of Products along with their Production Capacity
The Products fall under Project activity5(f), Category A as per NGT Order dated 23.08.2019 in the matter of O.A.No.1038/2018-Reg GIDC Nandesari & PCCI Estate, Di. Vadodara
Sr. no.
Name of the Products CAS no. /
CI no. Quantity
MT/Month* End-use of the
products
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Existing (Products)
Proposed (Products)
1 CIFIXIME TRIHYDRATE or 79350-37-1 10 0 Used for
manufacturing of Antibiotic
drug formulation.
2 CEFUROXIME AXETIL or 64544-07-6 3 CEFPODOXIME PROXETIL or 87239-81-4
4 AMPICILIN or 69-53-4 20 0
5 AMOXICILLIN TRYDRYDATE
or 61336-70-7 20 0
6 CLOBETASOLE PROPIONATE
or 25122-46-7 0.5 0
Used for manufacturing of Steroid drug
formulation.
7 BETAMETHASONE DIPROPIONATE or
5593-20-4 0.5 0
8 BETAMETHASONE
VALERATE or 2152-44-5 0.5 0
9 BETAMETHASONE SODIUM
PHOSPHATE or 151-73-5 0.5 0
10 DEXAMETHASONE SODIUM
PHOSPHATE or 2392-39-4 0.5 0
11 BECLOMETHASONE
DIPROPIONTE 4419-39-0 0.5 0
12 MOMETASONE FUROATE or 105102-22-
5 0.5 0
13 METHYLCOBALAMINE or 13422-55-4 0.5 0.5
Used for manufacturing of vitamin B-12
formulation. 14 OFLOXACIN or 82419-36-1 20 0
Used for manufacturing
of Antibiotic drug
formulation.
15 LEVOFLOXACIN or 100986-85-
4 20 0
16 QUINON SULPHATE or 6119-70-6 20 0 17 CLOXACILLIN SODIUM or 7081-44-9 20 0 18 OXACILLIN SODIUM or 1173-88-2 20 0 19 DI CLOXACILLIN SODIUM or 7081-44-9 20 0 20 FLUCOXACILLIN SODIUM or 1847-24-1 20 0 21 ETHOXYLATES A POLYETHYLENE GLYCOL or 25322-68-3 0
1000
Manufacturing in agro
emulsifier, cosmetics,
soap, detergent,
textile
B HYDROGENATED CASTOR
OIL or 8001-78-3 0
C CASTOR OIL ETHOXYLATES
or 61791-12-6 0
D NONYL PHENOL
ETHOXYLATES or 68412-53-3 0
E OCTYL PHENOL
ETHOXYLATES or 68987-90-6 0
F CARD PHENOL
ETHOXYLATES or 37330-39-5 0
G STYRUNATED PHENOL
ETHOXYLATES or 61788-44-1 0
H LAURYL ALCOHOL ETHOXYLATES or
68439-50-9 0
I TRIDECYL ALCOHOL
ETHOXYLATES or 24938-91-8 0
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J CESTOSTYRYL ALCOHOL
ETHOXYLATES or 68439-49-6 0
K TALLOW ALCOHOL ETHOXYLATES or
37335-03-8 0
L STEARYL AMINE ETHOXYLATES or
26635-92-7 0
M COCO AMINE ETHOXYLATES
or 61791-14-8 0
N OLEYL AMINE
ETHOXYLATES or 90367-28-5 0
O POLY SORBATE
ETHOXYLATES or 9005-64-5 0
P STEARIC ACID
ETHOXYLATES or 9009-90-9 0
22 METFORMIN
HYDROCHLORIDE 1115-70-4 0 500
Used for manufacturing
of diabetic drug
formulation. Total 20 1500.5
11.4 Cost of the Project
Break-up of Project Cost
Particulars Amount in INR (crore) Existing
Amount in INR (crore)
Proposed
Amount in INR (crore) Total
Land 1.0 - 1.0 Factory Building 0.50 0.50 1.0
Plant & Machineries 1.0 2.50 3.50 Other Assets 1.50 1.00 2.50
Total 4.0 4.0 8.0
11.5 Baseline Environmental Analysis
The Environmental Impact Assessment Report, Environmental Management Plan have been
prepared based on the studies carried out during the Winter Season (October 2018 to December
2018). Baseline data is available with us for our other industry manufacturing organic chemicals
located at an aerial distance of 200m for 1 complete season for 10Km Radius between October 2018
to December 2018. The parameters done are PM2.5, PM10, SO2, NO2, NH3, HCL, Cl2, CO, HC, VOC, etc.
The environmental attributes (ambient air, water, soil, noise) selected for the study are those,
which are likely to be affected by the project. The study area is defined as an area within 10 KM
radius around the site located at GIDC Nandesari.
11.5.1 Ambient Air Quality
The air quality status in the impact zone is assessed through a network of ambient air quality
monitoring locations. The tropical climatic conditions mainly control the transport and dispersion
of air pollutant emissions during various seasons. Ambient air quality of the study area has been
Gujarat Dyestuff Industries (Pharma Unit) Chapter 11 Summary & Conclusion
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assessed through a network of 10 ambient air quality stations designed keeping in view the
meteorological conditions of the study region.
The maximum concentration of SPM (121.6 g/m3), PM10 (77.35 g/m3), PM2.5 (47.49 g/m3),
SO2 (22.19 g/m3), NOx (19.15 g/m3), O3 (14.33 g/m3), CO (1.32 g/m3) & VOC (0.9 ppm) was
recorded in study area.
The minimum concentration of SPM (112.3 g/m3), PM10 (71.94 g/m3), PM2.5 (40.65 g/m3),
SO2 (13.11 g/m3), NOx (11.07 g/m3), O3 (10.01 g/m3), CO (1.21 g/m3) & VOC (0.4 ppm) was
recorded in study area.
The PM10 and PM2.5 concentrations at all the AAQM locations were primarily caused by local
phenomena including industrial & vehicular activities and natural dust getting air borne due to
manmade activities and blowing wind. PM10 and PM2.5 concentrations were observed below
stipulated standards of CPCB for Industrial, Residential, Rural and Other Area at all air quality
monitoring locations during the monitoring period.
Conclusions:
Results of all parameters are found within limit.
11.5.2 Water Quality
pH of ground water samples varied from 6.96 to 7.99. Turbidity was found 0.17 to 31.6 NTU, Total
Dissolved Solids varied in the range of 156 to 1902 mg/L. DO and COD are found in range of 6.53
to 6.90 mg/L, and 1.98 to 9.92 mg/L respectively. BOD3 was found to be <1.0. Total Hardness (as
CaCO3) varied from 34.13 to 908.04 mg/L. Total Alkalinity varied from 50 to 1000 mg/L. Chlorides
and Sulfates are found in the range of 32.53 to 673.23 mg/L and 2.51 to 199.78 mg/L respectively.
Surface water quality
pH of surface water samples was found 7.45 to 8.24. Turbidity was found 0.8 to 33 NTU, Total
Dissolved Solids was found 144 to 1426 mg/L. DO and COD are found 6.72 to 6.90 and 8.45 to 12.08
mg/L respectively. BOD3 was found to be <1.0. Total Hardness (as CaCO3) are found 148.98 to
911.63 mg/L. Total Alkalinity varied from 160 to 350 mg/L. Chlorides and Sulfates are found 33.47
to 179.16 mg/L and 23.76 to 254.34 mg/L respectively.
11.5.3 Noise level
A variety of sources produce noise, potentially hazardous to hearing depending upon the intensity
and duration of exposure. These include transportation systems, construction equipment,
industrial activities and many common appliances.
The noise levels during daytime varied from 46.4-61.7 dB (A) Leq to 49.8-63.9 dB (A) Leq in the
study area. The noise level in the study area is within the permissible Limits.
The nighttime noise level in the study area is in the range of 40.3-58.7 dB (A) Leq to 41.4-60.2 dB
(A) Leq. The nighttime noise was also within stipulated standards of CPCB.
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11.5.4 Soil Quality
Soil samples were collected from 10 locations during December 03-09, 2018 within the study area
to assess its physico-chemical characteristics. The analysis results of soil samples are given in Table
3.12.
11.6 Anticipated Environmental Impacts & Mitigation Measures
11.6.1 Water Requirement, Wastewater Generation and Treatment:
This is existing unit manufacturing Inorganic products; Additional inorganic products are planned
to be manufactured. Existing Products - 38 KLD, Proposed Products 249 KLD, 20 KLD Treated
Effluent from ETP to be recycled after RO Plant, & 19.6 KLD condensate from MEE Plant hence
247.4 KLD fresh water will be used, which will be met through GIDC Nandesari Industrial Estate
water supply (attached as Annexure 11). Out of which, process (17 KLD), cooling tower (250 KLD),
boiler (0 KLD), Scrubber (1 KLD), Washing (4 KLD) & Domestic (10 KLD). Total water requirement
will be 287 KLD in which 20 KLD Treated Effluent from ETP to be recycled after RO Plant & 19.6KLD
from MEE Condensate. Hence freshwater requirement will be 247.4 KLD.
Total 40 KLD Industrial w/w will be generated. Generated Industrial w/w will be sent to in house
ETP for treatment. Treated water from the ETP will be passed through ETP RO Plant & 20KLD
recovered Product to be used for Cooling Tower Makeup. 20 KLD Reject to be evaporated in MEE &
19.6 KLD MEE Condensate to be recovered for reuse. 8 KLD domestic wastewater will be generated,
which will be disposed through Septic tank & Soak Pit.
11.6.2 Air Pollution source and Mitigation measure
The main sources of air pollution will be flue gas emission. Flue gas emission will be from Existing
& Proposed Thermic Fluid Heaters & DG Set. FO/DLO is being used as fuel & Natural Gas will be the
fuel proposed for the proposed Thermic Fluid Heater. PM, SO2& NO2 are the main pollutants
generated from the flue gas stack.
Detail of flue gas emission & process gas emission along with stack height, type of fuel, expected
pollutants & air pollution control measures is given in below table.
FLUE GAS EMISSION FOR EXISTING AND PROPOSED PRODUCTS
Sr. no.
Source of emission
With Capacity
Stack Height
(meter)
Type of Fuel
Quantity of Fuel
MT/Day
Type of emissions
i.e. Air Pollutants
Air Pollution Control
Measures (APCM)
Existing Flue Gas emissions
1 Thermic Fluid
Heater (20 Lac Kcal)
30 F.O / LDO 40 Lit./Hr. PM, SO2, NO2 Caustic Scrubber
Proposed Flue Gas emissions
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1 Thermic Fluid
Heater (40 Lac Kcal)
30 Natural Gas 555 Nm3/Hr. PM, SO2, NO2 Adequate Stack Height
2 DG Set
(385 KVA) 5 HSD 90 Lit/Hr. PM, SO2, NO2 Adequate
Stack Height
Process Emissions:
Existing – No Process Emissions
Proposed – No Process Emissions
11.6.3 Hazardous Waste Generations and Disposal
• ETP Sludge will be Stored at site and then accumulated quantity disposed to TSDF M/s.
NECL Nandesari.
• Discarded containers / barrels / liners used for hazardous wastes/chemicals. will be
Collected, Stored, decontaminated & sold to approved vendor/ recycler.
• Used oil/Spent Oil will Collected, stored, transported, disposed by selling to registered re-
refiners.
• Distillation Liquid Residue - CHWIF incinerator facility of M/s. Nandesari Environment
Control Ltd. (NECL) / Coprocessing).
The collection, Storage and disposal of hazardous waste will be done as per Hazardous waste
(Management and Handling) Rules 2016.
11.6.4 Noise Level and Mitigation Measure
The noise will generate due to activities of TFHs, cooling towers, compressors, Generator set and
other plant machineries. Regular oiling and lubrication and preventive maintenance will be carried
out to reduce noise generation at source to the permissible limit. However, at place where noise
levels can exceed the permissible limit, Earplugs and Earmuffs will be provided to those working in
such area.
11.6.5 Soil & Geology
The unit is located in notified industrial area & have occupied land area of 3691.10 m2 (0.36911
Ha). There is no negative impact envisaged on soil & Geology of the study area. The unit will take
full-proof measures to manage all types of hazardous wastes to mitigate impacts on soil and
geology.
11.6.6 Impacts on Socio Economy & Mitigation measures:
There is a potential for direct/indirect employment for the locals due to the proposed project. The
project is located in notified industrial area of Nandesari GIDC, so no rehabilitation or resettlement
is required.
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11.7 Green Belt:
The total area of the green belt is 1476m2. It is around 40 % of plot area. Moreover, to fulfill the
total greenbelt development area, the company has planned to develop green belt in surrounding
area of Industrial area and nearby villages.
11.8 Environmental Monitoring Programme
A detailed monitoring schedule has been prepared to ensure effectiveness of the environmental
management plan.
11.9 Environmental Management Plan
ENVIRONMENT ISSUE/COMPONENT REMEDIAL MEASURES Hazardous waste generation & Disposal
Proper collection, Safe Handling, Storage within premises and disposal of waste at approved TSDF, CHWI, re-cyclers, re-processors.
Effluent generation and Treatment
Total 40 KLD Industrial w/w will be generated. Generated Industrial w/w will be sent to in house ETP for treatment. Treated water from the ETP will be passed through ETP RO Plant & 20KLD recovered Product to be used for Cooling Tower Makeup. 20 KLD Reject to be evaporated in MEE & 19.6 KLD MEE Condensate to be recovered.
Emission from stack Adequate pollution control system will be provided for control of gaseous emission.
➢ Adequate stack height for better dispersion of pollutants.
➢ Caustic Scrubber provided as APCM for existing TFH.
Noise Acoustic enclosure on Generator sets, engineering control at high noise level areas like compressors etc, wherever feasible, proper oiling, lubrication and maintenance of equipment, development of greenbelt around plant boundary and inside plant
Greenbelt Around 40% of the plant area will be developed as greenbelt.
Information and awareness about hazardous chemicals plant
Awareness training to workers on safe operating procedures and periodic reinforcement. Personal hygiene practice training shall be provided.
Preparedness to handle onsite & offsite emergency
Onsite Emergency Management Plan prepared
Monitoring of Environmental parameters
Regular monitoring of various environmental parameters will be carried out to check the effectiveness of the control system.
11.10 Additional Studies
EIA study conducted with reference to the following
• Hazard identification
• Assessment of risk on the basis of the necessary evaluations
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• Preparation of an onsite Emergency Plan.
• Consequence analysis of failures and accidents resulting in fire, explosion,
hazardous releases etc.
11.11 Project Benefits
Project will assisted many local and some skilled persons from surrounding villages and give
stability for their growth. They are financially benefited for the same. With more increase in such
processing units more local people will get employment opportunities in future.
11.12 Conclusion
The study brings out the following points:
• Ambient air quality, ground water quality and noise levels shall remain within acceptable
limits after commencement of proposed project activities due to effective design and
implementation of environmental management plans.
• Risk to flora/fauna and soil is negligible due to effective management and handling of
hazardous wastes and wastewater.
• Socio-economic benefits due to creation of direct / indirect employment.
Thus, it can be concluded on a positive note that after the implementation of the mitigation
measures and Environmental Management Plan, the regular operations of M/s. Gujarat Dyestuff
Industries (Pharma Unit). will have negligible impact on environment and will benefit the local
people.
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CHAPTER 12: DISCLOSURE OF CONSULTANTS ENGAGED
12.1 Disclosure of Consultant
The EIA report has been prepared by ECO-CARE SOLUTIONS (ECS) Vadodara; providing specialty-
consulting services in Environment Management solutions. The company has a team of professional
engineers and scientists, with extensive accumulated experience in diversified fields such as
Environmental Engineering, Civil Engineering, Chemical Engineering, Analytical Chemistry,
Microbiology, Safety & Health. An extensive complement of specialized instrumentation and
computing facilities supports the engineering and scientific staff. This, along with the technical and
managerial experience of the Principals, ensures the firm’s clients of the highest quality of
professional service.
ECO-CARE SOLUTIONS is working in this field since the year 2005. ECS is in the field of
environmental consultancy for environment clearance from MoEF & SEAC, Consent to Establish
(NOC) and Consent to Operate (CCA) from GPCB, Effluent Treatment Plant Design, Sewage
Treatment Plants, ETP & STP trouble shooting solutions, Packaged plants etc.
ECS has installed testing laboratory, for monitoring and analysis in the areas of ambient air, water,
soil and hazardous waste. For establishing the confidence in the work done, the laboratory has
received reorganization as Schedule – II Auditor from GPCB for Water/ Waste water, Ambient Air,
Stack and Noise. ECS is 17025:2005 Accredited Laboratory.
The extended branch of ECS is in the field of Designing, supply and installation of air pollution
control equipment and pollution control chemicals.
J.H.Bhavnani B.E (Civil), ME Environmental Engineering (MSU)
Gaurang V. Parmar
B.E (Chemical), PG Diploma in Industrial Env. Management, Diploma in Industrial Safety.
Rinal Patel M.Sc. Environmental Science Uchit Padariya M.Sc. Environmental Science Hitesh Umletiya BE Environmental Engineering
Mayur Vaghela B.E., CSP, DIS, PGDIEM, MISNT, FIV, Competent Person,
Chartered Engineer, Industrial Safety Consultant. Deepak Chanchad Expert On Site Emergency Plan & Safety Audit
Note: Baseline data has been procured from Aqua-Air Environmental Engineers Pvt. Ltd. Surat, for
the Period October 2018 to December 2018. for an adjacent industry.
ECO-CARE SOLUTIONS has obtained Hon. High Court Stay Order. The details of the stay order has
been enclosed herewith vide Annexure 13.
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Annexure 1 – ToR Letter
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Annexure 2 – Plot Allotment Letter from GIDC
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Annexure 3 – Risk Assessment Report
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Annexure 4 – Emergency Management Plan
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Annexure 5 – Undertaking
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Annexure 6 – Safety Audit
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Annexure 7 – MSDS Raw Materials
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Annexure 8 – MSDS Finished Products
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Annexure 9 – Layout Plan Factory Premises
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Annexure 10 – Details of CETP Nandesari
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Annexure 11 – Water Supply Letter from GIDC
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Annexure 12 – Membership for Hazardous Waste
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Annexure 13 – Hon. High Court Stay Order
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Annexure 14 – MoEF CERTIFED COMPLIANCE REPORT
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Annexure 15 – SoP Index
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Annexure 16 – CETP NANDESARI Permission for Disposal of Treated
Effluent
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Annexure 17 – Project Implementation Schedule
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Annexure 18 – XGN Generated Reports
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Annexure 19 – Adequacy of Existing EMS
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Annexure 20 – COPY OF EXISTING EC
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Annexure 21 –Baseline Data Certificate
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Annexure 22 –Existing PESO License
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Annexure 23 –PLI Copy
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Annexure 24 –COPY OF CTE & CTO
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Annexure 25 – Traffic Survey