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2006 Germanium I 4700 Hydrothermal Synthesis and Structural Characterizations of Two New Ger- manates with a Novel Topological Framework and Unusual Ge4(OH)4 Cubane. — The new compounds (II) and (III) are characterized by single crystal XRD, powder XRD, TG, and IR spectroscopy. They crystallize in the cubic space group P4 3m with Z = 1. Both compounds exhibit the same topologically novel inorganic framework, which is assembled from Ge 4 (OH) 4 cubanes and chiral intertwinned Ge—O double he- lices. — (XU*, Y.; CHENG, L.; YOU, W.; Inorg. Chem. 45 (2006) 19, 7705-7708; Dep. Chem., Liaoning Norm. Univ., Dalian 116029, Peop. Rep. China; Eng.) — W. Pewestorf 50- 024

Hydrothermal Synthesis and Structural Characterizations of Two New Germanates with a Novel Topological Framework and Unusual Ge4(OH)4 Cubane

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2006

GermaniumI 4700 Hydrothermal Synthesis and Structural Characterizations of Two New Ger-

manates with a Novel Topological Framework and Unusual Ge4(OH)4 Cubane. — The new compounds (II) and (III) are characterized by single crystal XRD, powder XRD, TG, and IR spectroscopy. They crystallize in the cubic space group P43m with Z = 1. Both compounds exhibit the same topologically novel inorganic framework, which is assembled from Ge4(OH)4 cubanes and chiral intertwinned Ge—O double he-lices. — (XU*, Y.; CHENG, L.; YOU, W.; Inorg. Chem. 45 (2006) 19, 7705-7708; Dep. Chem., Liaoning Norm. Univ., Dalian 116029, Peop. Rep. China; Eng.) — W. Pewestorf

50- 024