IATA Connect

IATA Dangerous Goods by

Air Training Course

DGM Training Institute ©

Experts on International Rules & Regulations for Training, Packing, Storage & Transport of Hazardous Goods

Phone: 281-821-0500 u Fax: 281-821-9801 u Email: [email protected]: www.dgmti.com / www.dgm-usa.com

1813 Greens Road u Houston uTexas u 77032

mailto:[email protected]

mailto:[email protected]

http://www.dgmti.com

http://www.dgmti.com

http://www.dgm-usa.com

http://www.dgm-usa.com

Table of ContentsReference Guide 4

Unit 1 - Applicability 5

Responsibilities 8

Revision Questions 14

Unit 2 - Limitations 15


Unit 3 - Classification of Dangerous Goods 30


Unit 4 - Identification 56


Unit 5 & 6 - Packing Dangerous Goods 68


Unit 7 - Marking and Labeling 80


Unit 8 - Documentation 87


Unit 9 - Handling 97

Unit 10 - Safety and Security 102

Workbook Overview 109

DGM Training Institute

Dangerous Goods By Air Training Course

D G M T R A I N I N G I N S T I T U T E! I ATA D a n g e r o u s G o o d s b y A i r Tr a i n i n g

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N o p a r t o f t h i s w o r k b o o k m a y b e r e p r o d u c e d w i t h o u t t h e e x p r e s s w r i t t e n p e r m i s s i o n o f D G M Tr a i n i n g I n s t i t u t e

1

Workbook SummaryForward

DGM Training Institute Inc. is committed to the accurate instruction of the safe transportation of dangerous goods materials.

We aim to stress the importance that each person engaged in the transportation of hazardous materials is responsible, and it is imperative that they become thoroughly familiar with the dangerous goods (hazmat) regulations.

This guide is not intended in any manner, shape or form to replace any Dangerous Goods Regulations, but it is rather, intended only to assist you during the training course.

It is the responsibility of the shipper, and any companies acting on their behalf to ensure that shipments of hazardous materials are packed, marked, labeled, classified etc. in accordance with the regulations.

Failure to comply with all regulations and requirements, may be in breach of the applicable national and governmental regulations and may be subject to legal penalties and fines.

Due to the ever-changing nature of the dangerous goods regulations, DGM Training Institute shall not be responsible for the absolute accuracy of the material contained in this workbook. Therefore DGM Training Institute will not assume any responsibility for omissions, errors, misprinting, or ambiguity contained within this guide and shall not be held liable in any degree for any loss or injury caused by such.

No part of this workbook may be reproduced, scanned, distributed or sold without the express written permission of the DGM Training Institute.




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2

Course Objectives

This training course is an in-depth training course offering candidates a comprehensive insight into the regulations, specifically, for the movement of dangerous goods in accordance with ICAO, IATA and the 49 CFR.

Using the IATA Dangerous Goods Regulations

Define Dangerous Goods

Responsibilities involved

Understanding the Limitations

Excepted Quantities and Limited Quantities

Classification and Identification of Dangerous Goods

UN Specifications Packaging and Testing

Correct Packaging of Dangerous Goods

Marking and Labeling of Dangerous Goods Cargoes

Shipping Papers for Dangerous Goods

Handling, storage and segregation of Dangerous Goods




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3

IATA DGR - The RegulationsReference Guide

† The dagger symbol indicates a brief description in Appendix A. (Please note - this symbol does not form part of the Proper Shipping Name)

★ A technical name or chemical group name(s) are required to be shown in parentheses directly after the Proper Shipping Name. (Please note - this symbol does not form part of the Proper Shipping Name)

The IATA DGR is in compliance with ICAO Regulations, but for operational reasons, there are differences, these differences are more restrictive than ICAO, and are noted with this symbol.

> Greater than

≥ Greater than or Equal to < Less than ≤ Less than or Equal to

⬜ Indicates a new item in this edition of the IATA DGR.

△ Indicates a change to this item.

X Indicates a cancellation or deletion of the item previously shown in this space.

☢ This symbol indicates the item relates entirely to Radioactive shipments.




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4

Unit 1 - Applicability

Objectives

Understanding the definition of dangerous goods

Review the basis of the regulations

Applicability of IATA Regulations

Understanding the Responsibilities of Shipping Hazmat

Ensuring that Training Requirements are met

Security requirements




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5

Definition of Dangerous GoodsIATA Ref. 1.0

Dangerous Goods are articles or substances which are capable of posing a risk to health, safety, property or the environment and which are shown in

the list of dangerous goods in the regulations, or which are classified according to the regulations.

This means any cargo that would meet the definition of one or more of the 9 hazard classes as defined in Unit 3 of the regulations would be classified as “dangerous goods”, and therefore, regulated for air transport.

Dangerous goods cargo or hazardous materials, otherwise known as “HazMat” are also defined and regulated by the US Department of Transportation when they are transported to, from or within the United States. The requirements for these regulations for the safe transportation and handling of dangerous goods cargo are found in the Code of Federal Regulations, Title 49, or more commonly referred to as the 49 CFR.

Local competent authority regulations and requirements must always be adhered to when, identifying, classifying, packing, marking, placarding, and handling as well as documentation of any dangerous goods freight.

Basis of the RegulationsIATA Ref. 1.1

The UN Subcommittee of Experts on the Transport of Dangerous Goods develop the recommendation for procedures for the transport of all types of dangerous goods (except radioactive materials), these procedures are then applicable for all modes of transport and are published in the Recommendations on the Transport of Dangerous goods.




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Applicability IATA Ref. 1.2

Dangerous Goods regulations need to be adhered to when:

Transporting hazardous materials from, to, through or within any ICAO member country.

All IATA members or Associate Members Airlines.

All shippers and or their agents who offer consignments of dangerous goods to these airlines.

All additional local competent authority regulations and requirements must also be adhered to. For Example - In the United States, the US Department of Transport (DOT) regulates the movement of hazardous materials, and according to the 49 CFR apply to any company and it’s employees, who perform any function in any way regulated by the US DOT. This would include any company who has any role in the logistical process of transportation of cargo potentially containing hazardous materials, for example:

Offers hazardous materials for transportation.

Packages, marks, or labels dangerous goods cargo for transport.

Loads, Unloads, or Placards hazmat transport vehicles.

Transports any hazardous materials.

Receives or forwards packages that may contain hazardous materials.

Manufactures packaging for use in transporting hazardous materials.

Involved in the testing of hazardous material packaging.

No exemptions are made for small businesses.

www.phmsa.dot.gov




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7

http://www.phmsa.dot.gov

http://www.phmsa.dot.gov

ApprovalsIATA Ref. 1.2.5

Whenever provided in the Regulations, the States concerned may grant an approval to permit the transport of dangerous goods. This is of course, provided that the overall level of safety is achieved without compromise.

Acceptance of dangerous goods offered for transport under the provisions of an approval is at the discretion of the operators concerned.

Shippers are encouraged to make advanced arrangements with the operators as part of the planning process associated with any approval application.

Responsibilities IATA Ref. 1.3 & 1.4

Shipperso Fully Comply with the regulationso Provide information to their employeeso Correctly identify, classify, pack, mark, label, and document according to the

regulationso Training

Operatorso Acceptanceo Storageo Loadingo Inspectiono Provision of information (incl. emergency response)o Reportingo Retention of recordso Training




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Specific Responsibilities IATA Ref. 1.3.2 & 1.4

It is the Responsibility of the Employer to ensure the Employee has received the correct function specific training, and all other relevant information to perform their job functions safely and according to all domestic and international regulations.

It is the responsibility of all individuals in the transport chain to:

Fully comply with the applicable regulations.

Correctly classify and identify “Hazardous Materials”.

Determine Proper Shipping Names, UN Numbers, and Class or Division.

Ensure the correct Packaging, Markings and Labels have been used.

Ensure the Shipping Papers have been correctly completed.

Ensure vehicles and containers are correctly placarded.

Provide Emergency Response Information and Telephone Numbers.

Provide information to employees, vendors and third party logistics.

Provide suitable and adequate training to employees.

To correctly offer, accept or store dangerous goods.

Ensure goods are compatible and correctly blocked and braced.

Adhere to strict safety and security policies.

Retain records and report incidents or accidents.




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Training Requirements IATA Ref. 1.5

It is the LAW!!

All hazmat employees are to receive job specific training. Training meeting these requirements will increase the employees’ awareness and ultimately ensure maximized safety and reduce hazmat incidents.

All training is to include:

General Awareness / Familiarization The hazmat employee must receive training that is designed to provide the familiarity of the hazmat requirements which will enable them to recognize dangerous goods materials, they would then identify the hazards that the cargo presents based upon any markings, labels, shipping papers or placards on the cargo.

Function-specific training Each hazmat employee must be trained in the regulations, which directly applies to the job function or specific job responsibility that the employee performs.

Safety Each hazmat employee must receive awareness safety training to include; emergency response information, measures to protect the employee from the hazards associated with hazardous materials to which they may be exposed in the work place, including any specific measures the hazmat employer has implemented to protect employees from exposure; as well as the methods and procedures for avoiding accidents.

Security Training Security training must include company security objectives, organizational security structure, specific security procedures, specific security duties and responsibilities for each employee, and specific actions to be taken by each employee in the event of a security breach. Training may vary from employee to employee based on job function and responsibility.




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Record keeping A record of current training, inclusive of the preceding three years, must be maintained and retained by each hazmat employer for as long as that employee is employed by that employer as a hazmat employee and for 90 days thereafter.

Training records must include:

Hazmat Employee’s Name.

The Date of the most recent Training Completed.

A description, copy, or the location of the training materials used to meet the

training requirements.

The Name and Address of the person providing the training course.

Certification that the hazmat employee has been trained and tested.

Training is valid for 24 months from completion and the following categories of personnel will require Initial and Recurrent training programs which must be established and maintained by, and on behalf of:

Operators, and

Operators that are “No Carry” Operators, in other words do not carry dangerous goods

Flight Crew, Crew Members and Load Planners

Ground Handlers and agencies performing:

Acceptance of cargo, passengers baggage and COMAT

Handling, loading, unloading and transfer or the processing of cargo, mail, baggage, stores, or checking in of passengers.

Freight forwarders

Shippers of dangerous goods, including packers and agents or organizations undertaking the responsibilities of the shipper

Any persons or agencies engaged in the security screening of passengers and baggage and/or cargo, mail or stores.

Designated Postal Operators




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SecurityIATA Ref. 1.6

Any person involved in the transport of dangerous goods should consider security requirements for dangerous goods as part of their responsibilities. Dangerous goods should only be offered to operators that have been appropriately identified.

High Consequence Dangerous GoodsIATA Ref. 1.6.3.1.

High consequence dangerous goods are products or materials, which may have the potential for misuse in a terrorist incident and which could, as a result, produce serious consequences such as mass causalities or even mass destruction.

The following is not an all-inclusive list, but rather indicative list of high consequence dangerous goods:

Explosives

Division 2.3 Toxic gases (excluding aerosols)

Class 3 Desensitized explosives

Division 4.1 Desensitized explosives

Division 6.1 of Packing Group 1 (except when transported under Excepted Quantity

Provisions 2.6)

Division 6.2 of Category A (UN2814 & UN2900)




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Security PlansIATA Ref. 1.6.4

Specific allocation of responsibilities for security, to competent and qualified persons with the appropriate authority to carry out their responsibilities.

Records of dangerous goods or types of dangerous goods transported.

Review of current operations and assessments of vulnerabilities including inter modal transfer, temporary transit storage, handling and distribution as appropriate.

Clear statement of measures, including the training policies.

Effective and up to date procedures, for reporting and dealing with security threats, breaches of security, and/or security incidents.

Procedures for the evaluation and testing of security plans, and procedures for periodic re-views and update of plans.

Measures to ensure the security of transport information is contained in the plan.

Note: United States regulations specify Security Plan requirements in 49 CFR Part 172.800.




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Revision Questions

1. What is the meaning of the following symbols?

≥

†

★

<

2. Provide the reference number in the IATA DGR where the definition of dangerous goods can be found.

3. Dangerous Goods by Air Certificates are valid for what period of time?Circle the correct answers.

a) Two yearsb) Three years c) Indefinitely d) Until management require recurrent training

4. List 3 articles or substances that are listed as High Consequence Dangerous Goods.




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Unit 2 - Limitations

Objectives

Understand the definition of Forbidden Dangerous Goods

Understanding how to identify hidden dangerous goods

Review allowances for Passengers and Crew Members

Restrictions of shipping hazmat in Air Mail

Dangerous Goods in Operators Properties

Limitations of moving Excepted Quantities

Restrictions of shipping Limited Quantities

Ensuring State Variations are adhered to

Ensuring Operator Variations are adhered to




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Forbidden Dangerous Goods IATA Ref. 2.1

Any article or substance which, when presented for transport, may be liable to explode, dangerously react, produce a flame, or dangerous evolution of heat, or dangerous emission of toxic, corrosive or flammable gases, or vapors under conditions normally encountered in transport must not be carried on aircraft under any circumstance.

Certain hazardous materials are known to meet the description above have been included in the List of Dangerous Goods (IATA Ref. 4.2), however, they have been entered in light type and without a UN Number along with the word “forbidden” in Columns G/H, I/J, and K/L.

It is important to note, that it is impossible to list all dangerous goods that are forbidden in aircraft, it is therefore essential that necessary care be taken to ensure that no such goods are offered for transport.

This includes any articles or products that are being returned to the manufacturer for safety reasons, for example, any defective or damaged lithium batteries.




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Hidden Dangerous GoodsIATA Ref. 2.2

Dangerous goods are occasionally declared under a general or generic description, these cargoes may contain hazardous materials, which may not be initially apparent.

Obtaining information and confirmation from the shippers and/or manufactures is imperative to ensure dangerous goods do not go undeclared.

The list in 2.2.4 of the IATA DGR gives a brief summary of typically undeclared or wrongly declared cargoes.

Examples include:

AUTOMOBILES, AUTOMOBILE PARTS - (car, motor, motorcycle) which may contain ferro-magnetic material which may not meet the definition for magnetized material but which may be subject to special stowage requirements due to the possibility of affecting aircraft instruments. May also contain engines, carburetors, or fuel tanks, which contain or have contained fuel, wet batteries, compressed gases in tyre (tire) inflation devices, fire extinguishers, shock / struts with nitrogen, air bag inflators / air bags modules, etc.

MACHINERY PARTS – may contain adhesives, paints, sealants, solvents, wet and lithium batteries, mercury, or cylinders of compressed or liquefied gas etc.

REPAIR KITS – may contain organic peroxides and flammable adhesives, solvent-based paints, resins, etc.

It is important to note, that even articles or substances, which perhaps do not fall into the definitions of dangerous goods as shown in the Regulations, but may however, in the event of leakage cause a serious cleanup problem or corrosion to aluminum on a long term basis, be checked by the shipper to at least ensure that the packaging is adequate to prevent leakage during transportation, these may include, brine, powdered or liquid dyes, pickled foodstuffs etc.




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Dangerous Goods Carried by Passenger and Crew IATA Ref. 2.3

Provisions for Dangerous Goods Carried by Passengers or Crew are provided in Table 2.3.A.

NOTE: There may be additional restrictions that might be implemented by local authorities in the interest of aviation security.

Dangerous Goods, must not be carried by passengers or crew: As or in checked baggage

As or in carry-on baggage, or

On their person

Except as noted in the regulations, and Table 2.3.A.

Forbidden for Passengers and Crew Attaché Cases, Cash Boxes or Bags

Disabling Devices

Liquid Oxygen Devices

Electro Shock Weapons

Acceptable only with the Operators Approval, as Checked Baggage ONLY Ammunition

Wheelchairs with Non-Spillable or with Spillable batteries or with lithium Batteries

Camping Stoves and fuel containers

Security-Type Equipment

Acceptable with Operators Approval as Carry-On Baggage ONLY Mercury Barometer or Thermometer

Lithium Ion Batteries powered equipment




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Acceptable with Operators Approval as Baggage Medical Oxygen

Non-Flammable Gas Cylinders fitting into a life jacket

Insulated packages containing refrigerated liquid nitrogen (Dry Shipper)

Avalanche Rescue Backpack

Chemical agent monitoring equipment

Carbon Dioxide, Solid (Dry Ice)

Heat producing articles

Portable medical electronic devices

Accepted without the Operator’s Approval Medicinal or toiletry articles

Aerosols (Non-flammable)

Cylinders for mechanical limbs

Cardiac Pacemakers/Radio-pharmaceuticals

Medical or Clinical thermometer

Safety matches or cigarette lighters

Alcoholic Beverages

Hair Curlers

Portable Electronic Devices containing lithium metal or lithium ion cells or batteries

Fuel Cell systems contained in portable electronic devices

Energy efficient light bulbs

Portable Electronic Equipment Containing Non-Spillable Batteries

Non Infectious Specimens packed with small Quantities of Flammable Liquids (must

comply with SP A180)

Internal combustion or Fuel cell Engines (must comply to SP A70)

Permeation Devices (must comply with A41)




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Air Mail / PostIATA Ref. 2.4

Dangerous goods may not be shipped as Air Mail (Post), unless meeting the criteria of Subsection 2.4.2. of the IATA DGR. These articles or substances, may be accepted in mail for air carriage, subject to the provisions of the appropriate national authorities concerned, and the parts of these Regulations which relate to such materials:

Infectious substances assigned to Biological substances, Category B (only when packed in accordance with the requirement of Packing Instructions 650, and carbon dioxide, solid when used as a refrigerant.)

Patient SpecimensRadioactive materials Lithium ion Batteries contained in EquipmentLithium metal batteries Contained in Equipment

Dangerous Goods in Operators PropertyIATA Ref. 2.5

The following are exceptions, and are permitted in the Operators Property and explained in the regulations in IATA 2.5:

Aircraft EquipmentConsumer GoodsCarbon Dioxide, Solid (Dry Ice)Battery-Powered Electronic Equipment Aircraft Spares




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Excepted Quantities IATA Ref. 2.6

Excepted Quantities, are exceptionally small quantities of dangerous goods meeting the provisions of this subsection of the regulations, and are not subject to the other provision of these Regulations except for the following:

Training Air Mail Classification & Packing Group criteria Packing Requirements Loading Restrictions Reporting of accidents, incidents or occurrences Requirements for radioactive material in excepted packages Definitions

Dangerous goods, which may be carried as excepted quantities in accordance with the regulations, are shown in Column F of the List of Dangerous Goods (Blue Pages) by means of an alphanumeric code which is then cross referenced to Table 2.6.A

Code Max net qty per inner package Max net qty per outer packagingE0 Not permitted as Excepted Qty Not permitted as Excepted QtyE1 30g/30mL 1kg/1LE2 30g/30mL 500g/500mLE3 30g/30mL 300g/300mLE4 1g/1mL 500g/500mLE5 1g/1mL 300g/300mL




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Packing, Marking, and Documentation of Excepted Quantities IATA REF. 2.6.5

Although not in UN Tested packaging, packages must be in compliance with the regulations, which would include:

Must be in an inner packaging which is held securely in place with wire, tape or other positive means; the inner package must have a leak proof threaded type cap, and the closure must be resistant to contents.

Inner packaging must be securely packed in an intermediate packaging with cushioning material in such a way, that under normal conditions of transport, they cannot break, be punctured or leak, and must completely contain the contents regardless of package orientation. For liquid dangerous goods, the intermediate packaging must contain sufficient absorbent material to absorb the entire contents of the inner packaging. Dangerous goods must not react dangerously with the absorbent material.

The intermediate packaging must be securely packed in a strong rigid outer packaging.

Packages must be of such a size that there is adequate space to apply all necessary markings.

Packages must be marked with the following label.

No Shippers Declaration is required. AWB or BOL must include the statement “Dangerous Goods in Excepted Quantities”.




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Figure 2.6.BLabel must be 100mm x 100mm (4 inches.)

* The primary class or division number.** The name of the shipper or the consignee

De Minimis Quantities IATA REF. 2.6.10

Hazmat that is assigned the codes E1, E2, E4 or E5 in Column F of the dangerous goods list (blue pages), are NOT subject to the regulations when carried as cargo, provided the following provisions are met:

The maximum net quantity of the material per inner packaging is limited to 1 mL for liquids and gases, and 1 g for solids.

The provisions of 2.6.5 are met, except that an intermediate packaging is not required if the inner packagings are securely packed in an outer packaging with cushioning material in such a way that, under normal conditions of transport, they cannot break, be punctured, or leak their contents, and for liquid dangerous goods, the outer packaging contains sufficient absorbent material to absorb the entire con-tents of the inner packagings.

The provisions of 2.6.6 are complied with, and

The maximum net quantity of dangerous goods per outer packaging does not exceed 100 mL for liquids and gases or 100 g for solids.




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Limited Quantities IATA Ref. 2.7

Some dangerous goods may be safely shipped in good quality combination packaging in Limited Quantities. These inner and outer packagings must meet certain construction standards, and be capable of withstanding a drop test, and stacking test when packed for transport, as per 2.7.6.

They also require marking to indicate that they are Limited Quantity packages. Packing Instructions with the prefix “Y” in the List of Dangerous Goods Column G (Blue Pages) indicate that a limited quantity package may be used.




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Figure 7.1.A

State and Operator Variations IATA Ref. 2.8

For each shipment of dangerous goods, the Variations for any State (Country) the cargo is flying from, through or to, must be checked.

State / Country• 2.8.2 • Additional Country Variations or Restrictions which will affect the Shipments being sent FROM that particular country

Operator / Airline• 2.8.4• Additional Airline Variations or Restrictions, which will affect the Shipments movement on a particular airline.

State / Country• 2.8.2• Additional Country Variations or Restrictions which will affect the Shipments being sent THROUGH and TO that particular country

The Operator (Airline) and their specific Variations must also be checked before cargo is offered for carriage.

State Variations are identified by a three-letter code, the last letter is always “G” (Government Restrictions).

The three-letter codes are then always followed by a two-digit number, which represents the “Variation”.

The codes are listed in an alphanumeric sequence.

Example: AEG (United Arab Emirates) Three-Letter code identifying the country

AEG – 01 Transportation of dangerous goods, to, from, or within the UAE must be subject to compliance with the provisions of these Regulations and the UAE Civil Aviation Regulations. Requests for obtaining a copy of the UAE Civil Aviation Regulations can be applied for online using the GCAA official website. i.e. www.gcaa.ae




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http://www.gcaa.ae

http://www.gcaa.ae

Operator Variations are identified by a two-letter alphanumeric code. The two-letter codes are followed by a two-digit number, which represents the “variation”.

The codes are then listed in an alphanumeric sequence.

Example: FX (Federal Express) Two-Letter code identifying the Operator

FX – 14 when a shipper’s Declaration is required, three (3) copies must be provided with each shipment at the origin location. At least two copies must have the diagonal hatchings printed vertically in the left and right margins and must be printed in red.

NOTE:

When there is a “Trefoil” symbol next to the State or Operator variation it means that is ONLY related to Radioactive Material.

It is very important to check each year for new variations that may have been removed / changed or are NEW. (⬜ or △)




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Revision Questions

1. Using the IATA DGR, state why Swimming Pool Chemicals may present a danger when being transported by air.

2. Is a passenger permitted to carry matches in a handbag or briefcase when boarding an aircraft.

Please provide a reference number to support your answer.

3. Using the information found in the IATA DGR, determine the maximum quantity permitted per inner package and per outer package when transporting Gas Oil in Excepted Quantities.

Maximum Quantity permitted per inner package -

Maximum Quantity permitted per outer package -




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4. Determine if the following statement is True or False. Circle the correct answer.

“Dangerous Goods Shipping Papers or Documentation is only required for Limited Quantities when specifically requested by the airline” True False

5. What is the three-letter code for the following states?

United Kingdom

Spain

Sri Lanka

Vanuatu

6. Do the following states have variations?

Mexico

Canada ________________________________________

Botswana

Fiji

7. An Excepted Quantities shipment is being transported on board a Hong Kong Airlines flight. Are there any restrictions?

Circle the correct answer and provide a reference number.

Yes / No IATA DGR Ref.

8. A shipment of airbag modules (UN 3268) are being transported to Belgium. Are there any restrictions?

Circle the correct answer and provide a reference number.

Yes / No IATA DGR Ref.




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Notes




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Unit 3 - Classification of Dangerous Goods

Objectives

Understand the classification criteria for all nine classes of dangerous goods.

Determine Proper Shipping Names, UN Numbers and Packing Groups for substances that have not been listed by name

Determining primary and secondary hazards using the Multi-hazards table

Classification of Samples

Understanding SDS’s




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Classes

Dangerous Goods are broken into one of nine classes, some classes are further broken down into divisions.

The class number does not indicate the degree of danger.

Class 1 Explosives

Class 2 Flammable Gas Non-Flammable Non-Toxic Gas Toxic Gas

Class 3 Flammable Liquid

Class 4 Flammable Solids Spontaneously combustible Dangerous when wet

Class 5 Oxidizers Organic Peroxides

Class 6 Toxic Infectious Substances

Class 7 Radioactive

Class 8 Corrosive

Class 9 Miscellaneous

Packing Groups

Packing Groups are written using roman numerals.

I HIGH DANGER II MEDIUM DANGER III LOW DANGER

Packing Groups refer to the degree of danger within the class. Not all classes of dangerous goods are assigned packing groups.




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Class 1 - ExplosivesIATA Ref. 3.1

Explosive articles or substances are assigned to one of six divisions, depending on the type of hazard present in the article or substance.

Division 1.1 Mass Explosive hazard: Instantaneous explosion of virtually the entire package or shipment. Example: Mines, grenades, nitroglycerin

Division 1.2 Projection hazard but not a mass explosive: Fragments projected outward at some distance. Example: Rockets, warheads

Division 1.3 Fire hazard and either a minor explosive or projection hazard: Fire or minor blast, possible projection of fragments outward at some distance. Example: smoke signals, projectiles, commercial fireworks.

Division 1.4 No significant hazards: Explosion largely confined to the package and No projection of fragments of any appreciable size or range is expected. Example: Airbags, sporting ammunition, model rocket motors

Division 1.5 Very insensitive substances, having a mass explosion: Mass explosion hazard, but low probability of initiation or detonation while in transit. Example: blasting agents.

Division 1.6 Extremely insensitive articles, with no mass explosion hazard: Negligible probability of accidental initiation or propagation. Example: military uses

Class 1 articles are not assigned Packing Groups.




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Explosive substance or article are assigned to one of 13 compatibility groups (Table 3.1.A), these are intended to be mutually exclusive, in other words, not loaded, packed, stored or transported near an explosive with another compatibility group. Except for an article or substance, which qualifies for Compatibility Group S, and because of testing criteria these are only 1.4 S explosives.

A Primary Explosive.B Primary explosive substance that does not have two or more effective protective features.C Propellant explosive or other deflagrating explosive.D Secondary detonating explosive substance.E Secondary explosive substance, without initiation, with a propelling charge.F Secondary detonating substance, with its own means of initiation. G Pyrotechnic substance.H Contains both an explosive substance and white phosphorus.J Contains both an explosive substance and a flammable liquid or gel. K Contains both an explosive substance and a toxic chemical agent.L Contains an explosive substance and presenting a special risk. N Contains only extremely insensitive detonating substances.S Articles or substances so packed or designed that any hazardous effects arising from accidental functioning are confined within the package unless the package has been degraded by fire, in which case all blast or projection effects are limited to the extent that they do not significantly hinder or prohibit fire fighting or other emergency response efforts in the immediate vicinity of the package.

Note - Any explosive materials in the US must be approved before transport, and is assigned an “EX” number. The “EX” approval must be entered on the shipping papers, and/or marked on the package, this is referenced in USG-05.




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Class 2 - GasesIATA Ref. 3.2

Substances of Class 2 are assigned to one of three divisions based on the primary hazard of the gas during transport.

Class 2 also includes “AEROSOLS”, and for the purpose of the DG Regulations, an aerosol means any non-fillable receptacle made of metal, glass or plastic and containing a gas compressed, liquefied or dissolved under pressure, with or without a liquid, paste or powder and fitted with a self-closing release device allowing the contents to be ejected.

Division 2.1 Flammable GasGases, which at 20°c and standard pressure will ignite when in mixture of 13% or less by volume with air. Or have a flammable range with air of at least 12 percentage points regardless of the lower flammable limit.

Example: Lighters, butane

Division 2.2 Non-Flammable, Non-Toxic GasThese gases are an asphyxiant or can be oxidizing, or do not come under the other divisions.

Example: Oxygen or Liquefied Gases

Division 2.3 Toxic GasGases which are known to, or to be presumed to, be so toxic or corrosive to humans as to pose a hazard to one’s health.

Example: Bromine Chloride

Class 2 articles or substances are not assigned Packing Groups.




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Assignment of Hazard Zone49 CFR Ref. § 173.116

The hazard zone of a Class 2, Division 2.3 material is assigned in column 7 of the Hazardous Materials Table in the 49 CFR. When the Hazardous Material table provides more than one hazard zone for a Division 2.3 material, or indicates that the hazard zone be determined on the basis of the grouping criteria for Division 2.3, the hazard zone shall be determined by applying the following criteria:

Hazard Inhalation toxicity zone

A .............. LC50 less than or equal to 200 ppm. B .............. LC50 greater than 200 ppm and less than or equal to 1000 ppm. C .............. LC50 greater than 1000 ppm and less than or equal to 3000 ppm. D .............. LC50 greater than 3000 ppm or less than or equal to 5000 ppm.

There are no hazard zones for Divisions 2.1 and 2.2.




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Class 3 – Flammable Liquids IATA Ref. 3.3

Flammable liquids are classified into Packing Groups based on the information gathered during the testing of the flammable vapor at temperatures of not more than 60°c (closed cup), or not more than 65.6°c (open-cup test), otherwise called a Flash Point.

Examples: Alcohols, Petroleum’s, Paints, and Adhesives

Steps to determine the Packing Group of a Flammable Liquid

Review the SDS and establish the Flash Point (F.P.) and Initial Boiling Point (B.P.)

Consult Table 3.3.A

Packing Group Flash Point (Closed Cup) Boiling PointI - ≤ 35°cII <23°c > 35°cIII ≥23°c but ≤60°c > 35°c

Once the Packing Group has been established; the Proper Shipping Name (PSN) and UN Number can be determined.




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36

Revision Questions

1. Determine the PG for the following:

Flash Point Boiling Point Packing Group18°c 100°c23°c 37°c22°c 37°c22°c 35°c65°c 100°c60°c 100°c

2. Using the excerpt from a SDS, please determine the correct PG.

Circle the correct PG a. Packing Group I

b. Packing Group II

c. Packing Group III

d. None

e. Unable to determine




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Class 4 - Flammable Solids, Spontaneous Combustion and Dangerous When WetIATA Ref. 3.4

Division 4.1 – Flammable Solids

These are substances, or articles, which under conditions encountered in transport, are readily combustible or may cause or contribute to fire through friction, self-reactive substances, which are liable to undergo a strongly exothermic reaction, desensitized explosives, which may explode if not diluted sufficiently. Although called “Flammable Solids” this class also includes, powdered, granular or pasty substances.

ALWAYS check the SDS, as metal powders can be especially dangerous because of the difficulty of extinguishing a fire, as normal agents such as carbon dioxide or water can react with these metal powders, and will increase the hazard. Example: Sodium, Matches, and Celluloid

Division 4.2 – Spontaneous Combustion

These substances are liable to spontaneous heat up when they come in contact with air and then are likely to catch on fire. These conditions can be encountered during transport. Read the SDS to check if there is any mention of this possibility.

Example: Fabrics or Fibers Animal or Vegetable, and Carbon Paper

Division 4.3 – Dangerous when Wet

These are substances, which, in contact with water could become spontaneously flammable, or, by interaction with water, are liable to give off flammable gases in dangerous quantities.

Example: Lithium, Sodium, and Calcium Carbide




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Class 5 - Oxidizers and Organic PeroxidesIATA Ref. 3.5

Division 5.1 – Oxidizing Substances

Oxidizing substances are in themselves not necessarily combustible, but may cause or perhaps contribute to the combustion of other material by yielding oxygen.

Example: Calcium Nitrate, Ammonium nitrate based fertilizer

Division 5.2 – Organic Peroxides

Organic peroxides (liquids or solids) are thermally unstable substances, which may undergo, self-accelerating decomposition. In addition, they may have one or more of the following properties: -

Be Liable to explosive decompositionBurn rapidlyExtreme risk of an explosion from exposure to impact or frictionReact dangerously with other substancesCause damage to eyes

Example: Powerful Bleaching agents, Methyl ethyl ketone peroxide (MEKP which is a hardening agent for fiberglass)




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Class 6 - Toxic and Infectious SubstancesIATA Ref. 3.6

Division 6.1 – Toxic

These are substances, which are likely to cause death or injury or to harm human health if swallowed, inhaled or by contact with the skin.

To be declared as “Toxic”, the substance must meet the criteria set out in Table 3.6.A to determine the Packing Group.

Classification is based on information provided in Paragraph 11 of the SDS. The LD50 (Lethal Dosage) or LC50 (Lethal Concentration) is determined by the exposure to the substance either by:

Oral ingestionDermal contactInhalation of dust, mist or vapors

Example: Pesticides, Nicotine, Cyanide




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Steps to determine the Packing Group of a Toxic Substance

Review the SDS and establish the LD50 or LC50

Consult Table 3.6.A

Packing Group Oral Toxicitymg/kg

Dermal Toxicitymg/kg

Inhalation Toxicitymg/L

I ≤ 5.0 ≤ 50 ≤ 0.2II > 5.0 but ≤ 50 > 50 but ≤ 200 >0.2 but ≤ 2.0III > 50 but ≤ 300 > 200 but ≤ 1,000 > 2.0 but ≤4.0

Once a Packing Group has been established; the Proper Shipping Name (PSN) and UN Number can be determined.




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Revision Questions

1. Determine the PG for the following:

LD50 PGOral 150mg/kg

Dermal 50mg/kgOral 20mg/kg

Inhalation 0.50 mg/LDermal 1000mg/kg

Oral 500mg/kg

2. Using the except from a SDS, please determine the correct PG.

Section 11 - Toxicological Information

LD50/LC50: Oral, mouse: LD50 = 3340 ug/kg; Oral, rat: LD50 = 50 mg/kg; Skin, rabbit: LD50 = 50 mg/kg; Skin, rat: LD50 = 140 mg/kg;

Circle the correct PG a. Packing Group I

b. Packing Group II

c. Packing Group III

d. None

e. Unable to determine




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Division 6.2 – Infectious Substances

These are substances, which are known to, or are reasonably expected to contain pathogens. Pathogens are defined as micro-organisms (including bacteria, viruses, parasites, fungi) and other agents, which can cause disease in otherwise healthy humans or animals.

Category A – an infectious substance which is transported in a form that, when exposure to it occurs, is capable of causing permanent disability, life-threatening or fatal disease in otherwise healthy humans or animals. Refer to Table 3.6.D for examples of Infectious Substances (This table is not all inclusive)

These infectious substances are assigned to either

UN 2814 Infectious Substances affecting humans, or UN 2900 Infectious Substances affecting animals

Category B – This is an infectious substance, which does not meet the criteria for inclusion in Category A.

These Category B substances are assigned to UN 3373 Biological Substances Category B




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Class 7 – RadioactiveIATA Ref. 3.7 and 10.3.2.

Radioactive materials are any material, which contains radionuclides, where both the activity concentration, and the total activity in the consignment, exceeds the values, which are specified in the regulations.

Example: Smoke detectors, X-rays




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Class 8 – CorrosiveIATA Ref. 3.8

For the purposes of the regulations, "Corrosive Material" (Class 8) means a liquid or solid that causes full thickness destruction of living tissue, and/or could damage or destroy materials at the site of contact within a specified period of time.

For Example: Mercury, Batteries acids, potassium hydroxide

Steps to determine the Packing Group of a Corrosive Substance

Information should be provided in the SDS as to the Packing Group Assigned. Although not generally used when reviewing the SDS, the manufactures will use Table 3.8.A to determine the PG assigned.

Packing Group Exposure Time Observation Time Corrosion rate on steel/aluminum

I ≤ 3 min ≤ 60 min -II > 3 min ≤ 60 min ≤ 14 d -III > 60 min ≤ 4 h ≤ 14 d >6.25 mm a year at a

test temp of 55°c (130°F)




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Class 9 – MiscellaneousIATA Ref. 3.9

These are articles or substances, which during transport may present a danger that is not covered by the previous 8 classes.

Class 9 products includes, but is not limited to, some of the following substances and articles:

Aviation Regulated SubstancesThese items may be narcotic, noxious, irritating or present other properties that, in the event of spillage or leakage on an aircraft, may cause extreme annoyance or discomfort to crew, which would prevent the correct performance of assigned duties.

Environmentally Hazardous SubstancesSubstances or mixtures, which would be dangerous to the aquatic environment but do not present a danger covered by other classes.

Genetically Modified Organisms and Micro-Organisms

Lithium Batteries

Cells or batteries, either carried separately, or carried in or contained in equipment in any form MUST be assigned to one of the following UN Numbers :

UN 3090 UN 3091 UN 3480 UN 3481

Other examples: Asbestos, Carbon Dioxide, Solid (Dry Ice), Consumer Commodities, Chemical and First Aid Kits, Life-saving Appliances, Vehicles




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Multi - HazardsIATA 3.10

When an article or substance is not specifically listed by it’s name in the list of dangerous goods (Blue Pages), and has two hazards, the primary hazard must be determined.

Steps to determine Packing Groups, Primary and Secondary Hazards

Review the SDS

Determine hazards and packing group as per the classification criteria of each hazard.

Consult Table 3.10.A

To use the table, the classes and packing groups are found along the top and down the left hand side of the table. Where the two classes meet in the body of the table will reveal the primary hazard and the correct packing group.

Determine Proper Shipping Name, UN Number, and Packing Group.




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Steps to determine the Proper Shipping Name if the substance is NOT listed by name in the Dangerous Goods List.

Once the primary hazard, secondary hazard and PG have been established.

Consult the List of DG (Blue Pages) to determine if the substance has been specifically listed.

If Not listed, the proper shipping name can be determined as follows:

Description of hazard (Alcohol, Pesticide, Hydrocarbon etc.)

State (Liquid, Solid or Gas)

Primary Hazard (Description of the hazard class - Toxic, etc.)

Secondary Hazard (If applicable)

Additional information (Organic, Inorganic, if applicable)

If no descriptive text is given, the Primary hazard is then used to describe the dangerous goods cargo.

For Example: Flammable Liquid, Toxic n.o.s. ★ Pesticide, solid, Toxic n.o.s. ★

As a reminder the ★ indicates that a technical name is required in parenthesis.

SamplesIATA Ref. 3.11

When the hazard class of a substance is uncertain, and it is to be transported for further testing, a tentative hazard class, proper shipping name and UN Number must be assigned on the basis of the shipper’s knowledge of the substance and its application.

The most severe packing group possible for the proper shipping name chosen must be used.

The proper shipping name must be supplemented by the word “SAMPLE”.

For example: Flammable liquid n.o.s. sample (PG I)




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Using the SDS

Previously known as the MSDS, the SDS, or Safety Data Sheet, is the sole responsibility of the manufacturers of the products, substances or materials.

The SDS should be made available upon request, to anyone involved in the handling, the use, or shipping the chemical substances.

The SDS gives valuable information of chemical properties, such as Flash Point, and Transport Information, as well as immediate first aid, handling and storage etc.

The SDS are used globally, so they should follow a similar format, however, it is important to note that slight variations in format and layout may be found in SDS’s.

# Heading Explanation

1

2

3

4

Identification of substance or mixture and of the supplier

Product Identification Recommended use of the chemical and restrictions on use. Suppliers details Emergency phone numbers

Hazards Identification

Classification of the substance/mixture, symptoms and side effects. Label elements, including precautionary statements. (Hazard symbols for

example - flame, skull, crossbones etc.) Other hazards which may not be covered by the regulations.

Composition / information on ingre-dients

SubstanceChemical identity, Common name, synonyms, etc.CAS number, EC number, etc.Additional impurities and stabilizing additives

Mixture The chemical identity and concentration or concentration ranges of all ingredients which are hazardous

NOTE: For information on ingredients, the competent authority rules take priority over the rules for product identification.

First Air Measures

Description of necessary measures, explained according to the different methods of exposure

(Example - inhalation, ingestion, skin or eyes.) Most important symptoms or effects, acute and delayed. Indication of immediate medical attention and special treatment needed, if necessary.




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5

6

7

8

9

10

11

Firefighting measures

Suitable and unsuitable extinguishing methods. Specific hazards arising from the chemical (Example - additional hazards if water is used as a means of extinguishing a fire. )Special protective equipment and precautions for firefighters.

Note - the Initial Flash Point may be located in this paragraph.

Accidental release measures

Methods and materials for containment and cleaning up spill or accidental release. Personal and environmental precautions, protective equipment and emergency procedures.

Handling and Storage Precautions for safe handling, storage and any additional incompatibility considerations.

Exposure controls / personal protection.

Individual protection measures, such as personal protective equipment. Control parameters for exposure limits etc.

Physical and Chemical Properties

AppearanceOdor / Odor thresholdpHMelting point / freezing point Initial boiling point and boiling rangeFlash pointEvaporation rateFlammability (solid, gas) Upper and lower flammability or explosive limitsVapor pressure and densityRelative density / specific gravitySolubility

Stability and reactivity

Chemical stability and possible hazardous reactions and incompatible materials

Conditions to avoid (Example - static discharge, shock or vibration) Results of hazardous decomposition

Toxicological information

Toxicological or LD50 descriptions. Symptoms related to the physical, chemical and toxicological

characteristics both delayed and immediate effects and also chronic effects from short and long term exposure




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50


12

13

14

15

16

Ecological InformationEco toxicity, persistence and degradabilityThe bio accumulative potential and mobility in soil Additional adverse effects

Disposal considerations

Description of waste residues and information on their safe handling and methods of disposal packaging.

Transport information

UN Number Proper Shipping Name Transport Hazard classes Packing group (If applicable) Marine pollutant (If applicable) Additional precautions

Regulatory information Safety, health and environmental regulations specific for the product in question.

Other information including information on preparation and recision of the SDS. Other information including information on preparation and recision of the SDS.




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Revision Questions1. Determine the packing groups for the following:

Flash Point Boiling Point Packing Group14°c 300°c23°c 100°c100°c 200°c

2. Using the information from the SDS, complete the missing information.

General Information from the SDS

FLASH POINT (METHOD USED – CLOSED CUP) 65° F (18.3° C )BOILING POINT 869° F (465° C)GENERAL HAZARDS Products of combustion include compounds

of carbon, hydrogen and oxygen, including carbon monoxide

Technical Name: Xyloproxaprine

SECTION 14 - TRANSPORT INFORMATION

PROPER SHIPPING NAME: ___________________

HAZARD CLASS DIVISION

PACKING GROUP

IDENTIFICATION NUMBER: ____________________




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3. Determine the packing groups for the following:

LD50 PGOral 74mg/kg

Dermal 27mg/kgInhalation 3mg/kg

4. Complete the table below, determine the Packing Group, Proper Shipping Names and UN Numbers

Chemical Description

LD50 PG UN Number Proper Shipping Name

Liquid Pesticide Dermal25mg/kg

OrganicSolid

Dermal350mg/kg

InorganicLiquid

Oral35mg/kg




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5. From the SDS attached determine if the following Pesticide would be declared as hazardous material

Circle the correct answer. HAZARDOUS / NOT REGULATED

TOXICOLOGICAL INFORMATIONAcute Oral LD50 (Rat): 550mg/kg Acute Dermal LD50 (Rabbit): >2000mg/kgEye irritation (Rabbit): Slight Skin Irritation (Rabbit): None

6. Complete the table below:

Class or Division

Packing Group

Class or Division

Packing Group

Primary Class or Division

Sub – Risk Packing Group

3 II 6.1 (oral) I 6.1 (i) II 8 liquid III

3 I 8 III




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NOTES




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Unit 4 - Identification

Objectives

Have a working knowledge of the List of Dangerous Goods, otherwise known as the Blue Pages.

Selecting the correct

o Proper Shipping Name

o UN / ID Numbers

o Hazard Class and / or Division and (If applicable) Sub Risk(s)

o Packing Groups (if applicable)

Using the UN Numerical Cross Reference List

Using the N.O.S. Entries

Understanding Special Provisions

Understanding Reportable Quantities (RQ) (49 CFR/US DOT requirement)




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Understanding the List of Dangerous Goods (Blue Pages)IATA Ref. 4.2

UN/ID No. (A)

Proper Shipping Name /

Description (B)

Class or Div. (Sub Risk) (C)

Hazard Label(s)

(D)PG (E)

Passenger and Cargo

Aircraft Passenger and Cargo



Aircraft Cargo Aircraft Cargo Aircraft

SP. See 4.4 (M)

ERG Code(N)

UN/ID No. (A)


Description (B)


Hazard Label(s)

(D)PG (E)

LTD QTYLTD QTY

SP. See 4.4 (M)

ERG Code(N)

UN/ID No. (A)


Description (B)


Hazard Label(s)

(D)PG (E)

EQ see 2.6 (F)

Pkg Inst (G)

Max Net Qty/Pkg (H)

Pkg Inst (I)

Max Net Qty/Pkg (J)

Pkg Inst (K)

Max Net Qty/Pkg (L)

SP. See 4.4 (M)

ERG Code(N)

A) UN or ID NumberThis is the serial number assigned to an article or substance under the UN Classification System. Whenever this number is used, it must be prefixed by the letters “UN” or “ID”.

UN numbers are always 4 digits long starting with either a 0, 1, 2 or 3. Any UN Number starting with a UN 0XXX will indicate an Explosive product.

ID Numbers start with an ID8XXX, for example, ID 8000 Consumer Commodities.

B) Proper Shipping Name / DescriptionThis is an alphabetical listing of dangerous goods articles and substances, the Proper Shipping Name is identified by the BOLD font, the Proper Shipping Name is sometimes supplemented with qualifying descriptive text in light print. Light print does not constitute part of the Proper Shipping Name.

Light text is also used for articles or substances which may be known by another name, the light font then cross references the article or substance to the correct proper shipping name, shown in BOLD font.

Names of articles or substances which are forbidden for carriage by air under any circumstances will be shown in light print.

Some names of substances and articles in light print may be considered not restricted.

Numerals, single letters, and prefixes are ignored when arranging the List of Dangerous Goods




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UN/ID No. (A)


Description (B)


Hazard Label(s)

(D)PG (E)

Passenger and Cargo





SP. See 4.4 (M)

ERG Code(N)

UN/ID No. (A)


Description (B)


Hazard Label(s)

(D)PG (E)

LTD QTYLTD QTY

SP. See 4.4 (M)

ERG Code(N)

UN/ID No. (A)


Description (B)


Hazard Label(s)

(D)PG (E)

EQ see 2.6 (F)

Pkg Inst (G)

Max Net Qty/Pkg (H)

Pkg Inst (I)

Max Net Qty/Pkg (J)

Pkg Inst (K)

Max Net Qty/Pkg (L)

SP. See 4.4 (M)

ERG Code(N)

C) Class or Div (Sub Risk) Column C contains the class or division number assigned to the article or the substance according to the classification criteria. Where a product has a subsidiary risk(s) this is shown in parenthesis.

D)Hazard Label(s) The hazard label column lists the name of the hazard label that would need to be applied to the outside of the individual package, and overpacks for the substance or article shown in column B.

The primary hazard label is listed first followed by any subsidiary risk labels required.

In addition, handling labels such as, “Cryogenic Liquid”, “Keep away from heat”, and the “Magnetized Material” labels, are shown in this column.

E) PGThis lists the Packing Groups which been assigned to an article or substance. (Remember not all articles or substances will have a packing group)

PG l High Danger PG ll Medium Danger PG lll Low Danger

F) EQColumn F lists the Excepted Quantity Codes assigned to the substance or article when packed in accordance to the requirements of Subsection 2.6.




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UN/ID No. (A)


Description (B)


Hazard Label(s)

(D)PG (E)

Passenger and Cargo





SP. See 4.4 (M)

ERG Code(N)

UN/ID No. (A)


Description (B)


Hazard Label(s)

(D)PG (E)

LTD QTYLTD QTY

SP. See 4.4 (M)

ERG Code(N)

UN/ID No. (A)


Description (B)


Hazard Label(s)

(D)PG (E)

EQ see 2.6 (F)

Pkg Inst (G)

Max Net Qty/Pkg (H)

Pkg Inst (I)

Max Net Qty/Pkg (J)

Pkg Inst (K)

Max Net Qty/Pkg (L)

SP. See 4.4 (M)

ERG Code(N)

G / I & K) Pkg Inst

Column G indicates the Packing Instruction for an article or substance packed in accordance to the requirements of a Limited Quantity Package on a Passenger or Cargo aircraft. These Packing Instructions are always preceded with the letter (Y).

Column I indicates the Packing Instruction for an article or substance on a Passenger or Cargo Aircraft.

Column K indicates the Packing Instruction for an article or substance which is packed in accordance to the requirements of being transported on a Cargo Aircraft Only.

The Packing Instruction Numbers are listed numerically in Unit 5 (Yellow Pages) of the IATA DGR.

H / J & L) Max. Net Qty / Pkg

Column H is the maximum net quantity permitted per package when the cargo is prepared in accordance to the requirements of a Limited Quantity shipment. Column J Indicates the maximum net quantity permitted per package for an article or substance on a Passenger or Cargo Aircraft.

Column L indicates the maximum net quantity permitted per package on Cargo Aircraft Only.

The quantities listed in Columns H, J and L are ALWAYS in the metric system, either KG or L. Whenever the letter G is used after the weight (30kgG), this indicates that this is the maxi-mum permitted GROSS weight.

Note - Where the word “Forbidden” is shown in a column, the article or substance cannot be carried under that provision.

Where the words “No Limit” are listed in the column, the quantity must be described as required by 8.1.6.9.2.(c)




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UN/ID No. (A)


Description (B)


Hazard Label(s)

(D)PG (E)

Passenger and Cargo





SP. See 4.4 (M)

ERG Code(N)

UN/ID No. (A)


Description (B)


Hazard Label(s)

(D)PG (E)

LTD QTYLTD QTY

SP. See 4.4 (M)

ERG Code(N)

UN/ID No. (A)


Description (B)


Hazard Label(s)

(D)PG (E)

EQ see 2.6 (F)

Pkg Inst (G)

Max Net Qty/Pkg (H)

Pkg Inst (I)

Max Net Qty/Pkg (J)

Pkg Inst (K)

Max Net Qty/Pkg (L)

SP. See 4.4 (M)

ERG Code(N)

M) S.PSpecial Provisions are listed in Column M, these codes are preceded by the letter “A”. The Special Provisions are listed numerically in Subsection 4.4 of the IATA DGR.

It is important to note that some Special Provisions (For example “A1” and “A2”) are in essence “approvals” which may be granted by the State to carry dangerous goods which otherwise are normally forbidden for carriage. These “approvals” are not regarded as “State Exemptions”.

N) ERGThe Emergency Response Drill Code is found in the ICAO “Emergency Response Guidance for Aircraft Incidents Involving Dangerous Goods”.

The ERG Code is provided for the benefit of operators and is normally only shown on the NOTOC.




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Numerical Cross ListIATA Ref. 4.3

If only the UN Number has been provided, the UN Numerical “Cross-Reference” List is used, this is located directly after the “Blue Pages.”

The UN Numbers are listed numerically in table 4.3, and show the Proper Shipping Name in BOLD font, this is followed by the page number where the article or substance can be found in the blue pages.

UN or Name and Description (ERG Code) PageID No. No. 0004 Ammonium Picrate dry or wetted with less than 10% water, by weight ............................... 1900005 Cartridges for weapons † with bursting charge .................................................... 209

Special ProvisionsIATA Ref. 4.4

The “Special Provisions” codes are found in Column M of the List of Dangerous Goods, and cross reference to subsection 4.4 of the IATA DGR. The information contained therein, provides additional information or requirements for that particular relevant entry.

Where the wording of the special provision is equivalent to that in the UN Model Regulations the UN special provision number is shown in parentheses immediately following the air mode special provision number.

Example UN 3364 Trinitrophenol, wetted

A40 (28) This substance may be transported under provisions of Division 4.1 only if it is so packed that the percentage of diluent will not fall below that stated at any time during transport.




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N.O.S. Entries

n.o.s. Refers to substances that are “Not Otherwise Specified”.

When an article or substance is not listed by name in the List of Dangerous Goods, the shipper must:

Determine that the article or substance is not forbidden

Classify it by comparing its properties with the classification criteria described in Section 3

Use the generic or n.o.s. proper shipping name, which most accurately describes the article or substance.

When indicated by the inclusion of the “★” symbol the Proper Shipping Name must be

supplemented with the technical or chemical group name in parentheses ( )




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Appendix A of the 49 CFR - Reportable Quantities IATA Ref. USG - 04 and 49 CFR §172.101

Hazardous substance

Reportablequantity (RQ)

pounds(kilograms)

A2213 5000 (2270)Acenaphthene 100 (45.4)Acenaphthylene 5000 (2270)Acetaldehyde 1000 (454)Acetaldehyde, chloro- 1000 (454)

Column 1 of TABLE 1, entitled “Hazardous substance” contains the names of those elements or materials determined to have a Reportable Quantity,

Column 2 of TABLE 1, entitled “Reportable quantity (RQ)”, contains the amount that, should it be met or exceeded is determined to have a (RQ). This quantity is listed in pounds and kilograms.

The Reportable Quantity or RQ, is a quantity of hazardous substances that meets or exceeds the amounts laid out in the Appendix A of the 49 CFR §172.101. If a substance exceeds its RQ, the spill or release must be reported to the National Response Center, and Community Emergency Coordinators for areas likely to be affected.

Reportable Quantities must be included with the basic description on shipping papers / documentation and the non-bulk package markings.

If the technical name of the substance is not found in the Hazardous Materials Table, or is classified as a generic hazard class, or n.o.s. Entry, but is listed in the Appendix A, and meets or exceeds the RQ, it must be shipped using the Proper Shipping Name “Environmentally Hazardous Substance”




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Revision Questions

1. The quantity limitations shown in Columns H, J and L are Per .... (circle the correct answer).

Aircraft Package Shipment

2. State the applicable UN or ID Number for the following items:

Substance UN or ID Number

1-Chloro-2,2,2-trifluoroethane

Motor Spirit

N,N-Diethylaniline

Acetic acid solution (90% acid by weight)

3. The following substances are also known by another name. Determine the proper shipping name and UN Number:

Substance UN Number Proper Shipping Name

Resinates, liquid

Lead tetramethyl

Arsenic, fuming liquid




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4. State the applicable proper shipping name for the following items:

UN Number Proper Shipping Name

UN 1794

UN 1977

UN 3083

5. What is the applicable UN number for Lead trinitroresorcinate (dry)?

6. Under what circumstances could UN 2189 be transported on a Cargo Aircraft (Circle the correct answer)

a) Special Provision A1 b) Special Provision A2 c) Under NO circumstances

7. What would be the correct hazard label to affix to a Vehicle, Flammable Liquid Powered, which has not been crated. (Circle the answer – and provide a reference to substantiate your answer.)

a) Class 9 Miscellaneous b) Class 3 Flammable Liquid c) None

IATA Ref No.




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8. Can 3L of UN 2561 packed into one package be transported on a Passenger Aircraft? (Circle the correct answer)

YES NO

9. Can 2 L of UN 2656 packed in one package be transported as Limited Quantities? (Circle the correct answer)

YES NO

10. Determine the correct Packing Instruction to be used when shipping one package containing 30KG of Calcium sillicide (PG III) Circle the correct answer.

a) Y477

b) 484

c) 486

d) 490

e) 491

11. What is the meaning of RQ? Circle the correct answer. a) Road Quantity b) Required Quantity c) Reportable Quantity d) All of the Above




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Notes




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Unit 5 & 6 - Packing Dangerous Goods

Objectives

Difference between UN Specification, Limited Quantities and other types of packages.

Understanding the UN Specification codes.

Locate, read and have a working knowledge of the packing instructions.

Selecting the correct type of packaging materials.

Identifying the maximum quantities permitted per inner packaging.

Ensuring the packaging materials meet the requirements of the general provisions.

Correctly calculate the Q-Value.

Understanding the requirements and regulations for Overpacks.




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Definitions

Packagings are a receptacle/s, as well as any other components, which are necessary for the receptacle to perform its containment function in conformance with the minimum packaging requirements.

A Package or Outer Package is the packaging along with its contents.

Limited Quantities - Are packages which have not been tested to the UN specification standards, and do NOT bear the Specification Markings. The shipper is responsible for the testing of the package and ensuring it is suitable transport. (Testing requirements are found in subsection 6.6)

UN Tested Packages - These packaging have been tested to meet the UN Specification requirements and are marked with a UN Specification marking in a circle along with the package limitations and specifications.

! 4G!/!X40!/!S!/!99!ZA!DGM!10!

Single Packaging - Consists of only one layer of packaging. Example - Drum or Jerrican.

Combination Packaging - Consists of an inner and an outer packaging to make up the package.

IBC - Intermediate Bulk Container (Tote), means a rigid or flexible portable package, other than a cylinder or portable tank, and is designed for mechanical handling. In airfreight these totes are used for transporting Environmentally Hazardous Solids only.




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Overpacks - is an enclosure that is used by a single consignor to provide protection or convenience in handling of a package, or to consolidate 2 or more packages of hazardous materials. Overpacks do not include transport vehicles or freight containers. The most common types of overpacks are shrink wrapped pallets, or protective boxes or crates. Overpacks do not bear the UN Specification markings, as these are located on the individual packages within the overpack. All other marks and labels are duplicated onto the outside of the overpack.

Specification Packaging IATA Ref. 6.0.4.2

These packages have been tested to UN Specification Standards and bear the UN Specification Markings.




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Type CodeIATA Ref. 6.0.3.4

The Number indicates the type of Package.The Letter indicates the construction material.

For Example:

1 Drum A Steel 1 Non-Removable Head2 Reserved B Aluminum 2 Removable Head3 Jerrican C Natural Wood4 Box D Plywood5 Bag F Reconstituted Wood (Particle Board)6 Composite Package G Fiberboard H Plastic L Textile M Paper, multi-wall N Metal (other than steel or Aluminum) P Glass, porcelain or stoneware

Packing GroupIATA Ref. 6.0.4.2.1 (c)

During performance testing, packages are tested to meet the criteria of Packing Groups.

X = l, ll, lll Y = ll, lll Z = lll only

When choosing the correct package for a material, it is important to take note of both the Package Group listed in the “Blue Pages”, as well as the additional information found in the applicable Packing Instructions.




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Year of ManufactureIATA Ref. IATA Ref. 6.0.B & 5.0.2.1.5

Plastic single and inner packages are only valid for a five year period, after which time it is no longer suitable for hazardous materials.

Responsibilities IATA Ref. 5.0.1

The shipper is responsible for all aspects of the packaging of dangerous goods in compliance with the Regulations.

When a Shipper is preparing a package of dangerous goods for transport, they must:

Use only the packages permitted by the applicable packing instruction.

Restrict the overall quantity per package to the limits specified in the List of Dangerous Goods (Blue pages).

The quantity per inner packaging must not exceed the limits specified in the applicable packing instruction.

Assemble and secure all components of the package exactly in the manner intended.

Ensure external surfaces of assembled package are clean of contamination.

Ensure that their responsibilities for packing are completely fulfilled when the package is presented to the operator for shipment.




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Packing InstructionsIATA Ref. 5.1

Packaging Instructions are listed numerically in the “Yellow Pages” of the IATA DGR (Column G, I and K)

The first number of the Packing Instruction indicates the class number.

Shipments packed in accordance to the requirements of Limited Quantities (Packages which do not bear UN Specification markings) will have Packing Instructions with a “Y” prefix. (Example Y373.)

Following is a break down of a Packing Instruction :

The Packing Instruction Number, State and Operator Variations applicable to this PKG INST. What articles or substances apply to this PKG INST.

The requirements of 5.0.2 must be met, as well as the additional: Compatibility Requirements Closure requirements, and Additional PKG Requirements. The PKG INST will include a statement that will indicate if Single Packages are, or are not permitted.

Permitted PKGs are listed here. The inner pkg will provide the max qty PER inner pkg, included and the max. net qty permitted per package - the same qty in the blue pages. The outer pkg listed are permitted for use for that particular article or substance. UN Specification codes are shown, these are NOT listed onPKG INST used for LTD QTY.




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Overpacks IATA Ref. 5.0.1.5

An Overpack is an enclosure used by a single shipper to contain one or more packages and to form one handling unit for the convenience of handling and stowage.

For cooling purposes an overpack may contain Carbon dioxide, solid (dry ice), provided that it meets the requirements in the applicable packing instruction.

The shipper must ensure that where an overpack is used to enclose packages of dangerous goods the following requirements are met:

Must not contain packages of different substances, which may react dangerously with each other or packages of dangerous goods that require segregation according to the segregation table 9.3.A, and/or the SDS.

Each package contained within an overpack must be properly packed, marked labeled and be free of any indication of damage or leakage, and in all respects in proper condition for transport in accordance to the regulations.

The overpack must not contain packages bearing the “Cargo Aircraft Only” label except where

Only one package is contained in the overpack.Two or more packages are contained in the overpack and the packages are assembled in such a way that clear visibility and easy access to them is possible.The package contains substances of

§ Class 3 packing group II other than those with a sub risk of Class 8§ Class 6§ Class 7§ Class 9

The intended function of each package must not be impaired by the overpack.




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Additional Packaging Requirements IATA Ref. 5.0.2

Each package must be designed, constructed, maintained, filled, closed, and the contents limited, so that under normal transport conditions:

There is no release of hazardous materials

Effectiveness of packaging will not be reduced,

No mixture of gases or vapors in the package which could, through any credible spontaneous increase of heat or pressure, significantly reduce the effectiveness of the packaging.

No residue on outside of packaging

A packaging can be used if it is:

Prescribed by the Packing Instruction

Conforms to Additional Packing Requirements

Specification Packagings and UN Standard packagings must always:

Be compatible with contents

Properly closed

Properly filled (filling limits)

Properly vented, if authorized

Sufficient ullage is provided

Be temperature and pressure resistant




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Q-ValuesIATA Ref. 5.0.2.11

A Q-Value is determined when two or more different dangerous goods, which do not react dangerously together, or require segregation, are packed into one suitable outer package. The Q-Value determined cannot exceed 1 when the calculation is done.

Steps for determining Q-Values

1. Determine the following for each of the products, which is to be packed in the outer package.

a. UN Number and Proper Shipping Nameb. Class or Divisionc. Maximum permitted Net Quantity per package

2. Check the Segregation Table – Table 9.3.A

3. “Q” is calculated using the following formula The NET qty you physically have n1 + n2 = QThe MAX qty permitted in the blue pages m1 m2

4. “Q” cannot exceed 1.




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Revision Questions

1. In the UN Specification markings what is the meaning of the following

X

Y

Z

2. Proper Shipping Name Amyl Nitrite UN Number UN 1113 Quantity 1L Packaging 1 Plywood box - bears NO UN specification markings

Determine the following: Packing Instruction Number

Max qty per pkg permitted

3. The item: Isobutyl acetate Net Quantity: 15 L (Shipped on a Passenger Aircraft) Inner Packaging: Glass packagings x 0.5 L each Outer Packaging: UN Specification fiberboard box (4G)

a) What is the applicable:

i) Packing Instruction Number

ii) Maximum net quantity per outer package

iii) Minimum number of outer packages required




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4. You have 50 pieces Tear Gas Grenades each with a weight of 1kg. Determine the following:

a) UN Number

b) Proper Shipping Name

c) Is a 4G (Fiberboard Box) Permitted

d) Min. number of packages required

5. Item Matches, Safety Quantity 15KG Packaging 1 Plywood Box

What PG Performance standards must the package meet?

Circle the correct answer.

a) PG II (Y)b) PG III (Z)

6. Determine the Q – Value for the following:

UN 2802 x 15 KG UN 2713 x 25 KG

7. Is it possible to pack the following two packages into one enclosed Crated Overpack?

UN 1298 5 L packed into a UN 1H2

UN 2503 5 KG packed into a UN 4D

Circle the correct answer YES NO

IATA Ref.




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Notes




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Unit 7 - Marking and Labeling

Objectives

Understand the marking required on a dangerous goods packaging.

Understand the labeling required on a dangerous goods packaging.

Understand the marks and labels required on an Overpack.

Marking and labeling is referred to as Hazardous Communications, and for good reason. The marks and labels indicate, or communicate the risks inherent to the cargo inside the package or overpack to any persons handling the freight. The shipper is responsible for all necessary marking and labeling of each package or overpack containing dangerous goods.

Definitions

Marking Identify the use of a particular packaging. Identify the design or specification of a packaging.

Labeling Hazard Labels indicating the danger present inside the packaging.Handling labels are required, either alone or in addition to hazard labels and dictate any additional requirements for handling of the product.

Overpack A package used by a single shipper to contain one or more completed, marked and labeled packages, which will form one handling unit for convenience of handling, transport and stowage.




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MarkingsIATA Ref. 7.1

All markings must be:

Durable

Visible

Legible

Withstand normal weather conditions

Displayed on a background of contrasting color

In English (May be accompanied by another language)

Markings include:

Shipper Details (In Full)

Consignee Details (In Full)

UN Number(s) (Size - IATA Ref. 7.1.4.4.)

Proper Shipping Name(s) (Size - IATA Ref. 7.1.4.4.)

Net Quantity of each product (Gross weight if applicable.)

UN Specification Markings (If Applicable)

Limited Quantity Marking (If Applicable)

OVERPACK (If Applicable)

Where required, the Special Permit packaging “DOT-SP” followed by the permit number.




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Labeling IATA Ref. 7.2

A shipper must remove or obliterate any irrelevant labeling already on a package.

Must be durable and weather resistant. A label on a package must be able to withstand, normal transport conditions, without deterioration or a substantial change in color.

The size must be a minimum of 10 cm x 10 cm. (approximately 4 inches on each side)

Both color and size of handling and hazard labels must be as prescribed.

The hazard class number, or division number, must be in the bottom corner on the hazard label.

Must affix the label(s) in the correct location and in a secure manner.

Text may be used – Must be in English.

Labels include:

Hazard Label(s) as indicated in Column D of the Blue Pages.

MUST be located on the same surface of the package near the Proper Shipping Name marking.

Primary and Subsidiary risks are required to be affixed adjacent to each other.

Handling Labels, as required, to indicate additional handling requirementso Magnetized Materialo Cargo Aircraft Onlyo Cryogenic Liquidso Package Orientation – “Upright” o Keep Away from Heato Lithium Batteries




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Package Marking and Labeling examples

Dangerous Goods in a UN Specification Packages

Hazmat packed into an Overpack

Hazmat packed into Limited Quantities




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Revision Questions1. Check the following package, circle any errors or omission that are found.

2. What marks and labels would be required on a single package of 10 L of UN 2309?




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3. What markings and labels would be required to pack a limited quantity shipment of Acetone (0.1L)

4. A package of the following two products is packed into an overpack where the labels on the individual packages are not readily visible. Indicate what marks and labels would need to be on the overpack.

UN 1230 0.5 LUN 2661 5 L

5. Is the statement below TRUE or FALSE? (Circle the correct answer)

TRUE / FALSE

“When space or size does not permit a label to be placed on one side of a package, it is permitted to be folded over the edge of the box.”




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Notes




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Unit 8 - Documentation

Objectives

Understand the responsibility of the Shippers Declaration / Shipping Papers.

Be able to complete a Shippers Declaration.

Completing the relevant portions of the Airway Bill.

Identify errors and omissions on documentation or shipping papers.

Shipping Papers

Shipping Papers are an essential part of the Hazardous Communication process as it provides the important and relevant information to everybody involved in the transport chain.

Every shipment containing hazardous materials must be accompanied by Shipping Papers which provide a basic description of the materials.




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Responsibility IATA Ref. 8.0.2

The shipper is responsible for providing the information to complete the Shippers Declaration.

Ensure that the information on the declaration is accurate, easy to identify, legible and durable.

Ensure that the form is correctly signed.

Ensure that the shipment has been prepared in accordance to the Regulations.

Ensure that the declaration is kept for a minimum period of three months or longer as required by the local Competent Authorities.

Ensure that at least two copies of the Shippers Declaration are provided, or, subject to any State or Operators variation requires.

All Shipping Papers:

Must be legible.

Must be printed in English.

Must not contain codes or abbreviations (unless specifically authorized).

If required by the State and Operator Variation (USG - 12) it must include an Emergency Response Telephone Number.

Warning - Failure to comply in all respects with the applicable Dangerous Goods regulations may be in breach of the Applicable law, subject to legal penalties.

Shippers Declaration - I hereby declare that the contents of this consignment are fully and accurately described above by the proper shipping name, and are classified, packaged, marked and labeled/placarded, and are in all respects in proper condition for transport according to applicable international and national governmental regulations. I declare that all of the applicable air transport requirements have been met.




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Steps to complete the Shippers DeclarationIATA Ref. 8.1.6

SHIPPER’S DECLARATION FOR DANGEROUS GOODSShipper

1

Shipper

1

Shipper

1

Air Waybill No. 3 Page of Pages 4 Shipper’s Reference Numbers 5 (optional)

Air Waybill No. 3 Page of Pages 4 Shipper’s Reference Numbers 5 (optional)

Consignee

2

Consignee

2

Consignee

2(Optional logo)

Two completed and signed copies of this Declaration must be handed to the operatorTwo completed and signed copies of this Declaration must be handed to the operatorTwo completed and signed copies of this Declaration must be handed to the operator WARNING

Failure to comply in all respects with the applicable Dangerous Goods regulations may be in breach of theApplicable law, subject to legal penalties.

WARNING


TRANSPORT DETAILSTRANSPORT DETAILSTRANSPORT DETAILSWARNING


WARNING


This shipment is within the limitations prescribed for(delete non-applicable) 6

This shipment is within the limitations prescribed for(delete non-applicable) 6

Airport of Departure

7

WARNING


WARNING


PASSENGER AND CARGO AIRCRAFT

CARGO AIRCRAFT ONLY

Airport of Departure

7

WARNING


WARNING


Airport of Destination 8 Airport of Destination 8 Airport of Destination 8

Shipment type (delete non-applicable) 9Shipment type (delete non-applicable) 9Airport of Destination 8 Airport of Destination 8 Airport of Destination 8 NON-RADIOACTIVE RADIOACTIVE

1. Full name and address of the shipper

2. Full name and address of the consignee

3. Air Waybill number (May be entered by the agent or the carrier without the original signature.)

4. Number of pages (e.g. 1 of 2)

5. Shipper’s Reference Number (optional)

6. Passenger and Cargo Aircraft or Cargo Aircraft Only (delete non-applicable)

7. Full name of the Airport or City of Departure(May be entered by the agent or carrier – 3 Letter codes are not permitted)

8. Full name of the Airport of City of Destination (May be entered by the agent or carrier – 3 Letter codes are not permitted)




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9. Shipment type (Delete the non- applicable) NATURE AND QUANTITY OF DANGEROUS GOODS NATURE AND QUANTITY OF DANGEROUS GOODS NATURE AND QUANTITY OF DANGEROUS GOODS NATURE AND QUANTITY OF DANGEROUS GOODS NATURE AND QUANTITY OF DANGEROUS GOODS NATURE AND QUANTITY OF DANGEROUS GOODS NATURE AND QUANTITY OF DANGEROUS GOODS

Dangerous Goods IdentificationDangerous Goods IdentificationDangerous Goods IdentificationDangerous Goods Identification

UN or ID Number

Proper Shipping Name Class or Division

(Sub-risk)

PackingGroup Quantity and

Type of Packing

PackingInst.

Authorization

1 2 3 4 5&6 7 8

1. UN or ID number (with the prefix UN or ID)

2. Proper Shipping Name (bold characters from the blue pages, and when an ★ is shown with the proper shipping name, also the chemical/technical name in parentheses)

3. Class or Division (Sub-risks are shown in parentheses)

4. Packing Group in Roman numerals (as indicated in the blue pages)

5&6. Quantity and Type of Packing (indicated by how many packages, the description of the package and the quantity, e.g. 1 fiberboard box x 1 L)

L = LitersKG = Kilogramskg G = Kilograms Gross

7. Packing Instruction number as shown in the blue pages. (NOTE – Limited Quantity packages will have a “Y” packing instruction number.)

8. Authorizations (e.g. exemptions, approvals, special provisions etc. For example – A1, A2, A51, A81, A88, A99 or A130)




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Additional Handling Information

1

Additional Handling Information

1

I hereby declare that the contents of this consignment are fully and accurately described above by the proper shipping name, and are classified, packaged, marked and labeled/placarded, and are in all respects in proper condition for transport according to applicable international and national governmental regulations. I declare that all of the applicable air transport requirements have been met

Name/Title of Signatory 2 Place and Date 3

Signature 4(see warning above)

1. Additional Handling Information (e.g. An Emergency Response Telephone Number, may be required for some states and operators, e.g. State Variation USG – 12 or Operator Variation AC – 02Special Provision A20 statement “UN xxxx must be protected from direct sunlight and all sources of heat and placed in an adequately ventilated area.”

2. Name and Job Title of Signatory

3. Place and Date of Signatory (Preferred format for the date is YYYY-MM-DD or DD/MM/YYYY or written out in full so as to avoid misunderstanding.)

4. Signature (Any alterations or amendments must be signed with the same signature as used at the bottom of the document.)

Shippers Declarations are NOT required for the following:

Excepted QuantitiesUN 3373 – “Biological substances, Category B”UN 2807, Magnetized Material UN 1845, Carbon Dioxide, Solid (Dry Ice) with non-hazardous materialsUN 3245, GMO’sLithium ion or lithium metal batteries meeting the provisions of Sections II of Packing Instructions 965 - 970. (Please ensure State and Operator Variations have been reviewed) Radioactive material, excepted packages




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Air WayBillIATA Ref. 8.2.7

The following instructions for the completion of the Air Waybill cover only the information pertaining to dangerous goods consignments.

Completed in the “HANDLING INFORMATION STATEMENT” portion of the Air WayBill

“Dangerous Goods as per attached Shipper’s Declaration”

or,

“Dangerous Goods as per attached DGD”

or, if the cargo is only permitted on a Cargo Aircraft

“Dangerous Goods as per attached DGD – CAO”

or,

“Dangerous Goods as per attached Shippers Declaration – Cargo Aircraft Only”




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Revision Questions

1. Complete the attached Shippers Declaration with the following information.

Shipper ConsigneeABC Chemicals Acme Stores1717 Uphill Road 2810 Kings RoadHouston, Texas, USA London, England77073 LH4 R21

Emergency Telephone Number: 1.555.234.5645 (Mr. B. Boss)

Air Waybill # 77668876543Shippers Ref RTM 557

Products

1. Technical Name “Hynoteinstien” Flash Point 28°c Initial Boiling Point 100°c Quantity 5 Liters Packaging 1 UN Tested Plywood box

2. Product Name Paint Related Materials Flash Point 45°c Initial Boiling Point 100°c Quantity 1 Liter Packaging 1 Fiberboard box (No UN Specification Markings)




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2. Check the following Shippers Declaration. Circle errors or omissions found.




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Notes




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Unit 9 - Handling

Understand the importance and the responsibility for accepting.

Ensure correct segregation has been adhered to.

Review correct handling of dangerous goods cargo.

Understanding the responsibilities and requirements for storage, loading and handling of damaged packages.

Review the requirements for reporting any dangerous goods incidents and / or accidents.

AcceptanceIATA Ref. 9.1

An operator, or agents acting on their behalf, must not accept a package, or overpack containing dangerous goods that does not meet the requirements of the regulations.

Operators are to complete an Acceptance Checklist prior to acceptance.

Acceptance Checklists must include all reasonable steps to ensure that:

The packages, overpack(s) or freight container(s) as applicable are correctly marked and labeled.

The shipper’s Declaration is correctly completed.

The Acceptance requirements in the Regulations are met.




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Segregation IATA Ref. 9.3.2

Packages containing dangerous goods, which may react dangerously with one another, must not be stowed next to each other or in a position that would allow interaction between the packages in the event of, leakage or damage.

To establish and maintain acceptable segregation between packages containing dangerous goods with different hazard classes, the segregation requirements shown in Table 9.3.A must be used, and the SDS must be checked for additional segregation requirements.

The segregation requirements pertain to all hazard labels applied on the package, irrespective of whether the hazard is the primary or subsidiary risk.

Table 9.3.AClass

or DivisionOf primary hazard

1 excl. 1.4S 1.4S 2 3 4.2 4.3 5.1 5.2 8

1 excluding 1.4S Note 1 Note 2 X X X X X X X1.4S Note 2 - - - - - - - -

2 X - - - - - - - -3 X - - - - - X - -

4.2 X - - - - - X - -4.3 X - - - - - - - X5.1 X - - X X - - - -5.2 X - - - - - - - -8 X - - - - X - - -

X = Segregation is required

- = Segregation is not required unless stated on the SDS

Division 4.1 and Classes 6,7 and 9 are not included in Table 9.3.A as they DO NOT require segregation from the other classes of dangerous goods.

Excerpt of an SDS




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Handling Dangerous Goods

LiquidsIATA Ref. 9.3.3

During the course of normal transport, packages bearing the package orientation or “This Way Up” labels, must be loaded, stowed, and handled at all times, in accordance with the orientation of the “Up Right” handling label.

Single packagings with end closures, containing liquid dangerous goods must be loaded and stowed aboard an aircraft with such closures upwards.

General Storage, Loading and Securing Requirements IATA Ref. 9.3.4

Must protect the packages of dangerous goods from being damaged.

Must ensure segregation has been observed and adhered to.

Must secure hazardous materials in a manner that will prevent any movement, which would change the orientation of the packages during “normal” transport.

Damaged Packages of Dangerous Goods IATA Ref. 9.3.6

Must ensure that a package is not accepted into the facility if damage is found.

Must ensure that at the time of loading, unless it has been inspected immediately before handling, the packages are to be free from visible leaks or damage.

Reporting IATA Ref. 9.6

An Operator must report dangerous goods accidents or incidents to the appropriate authorities of the State of the operator and the State in which the accident or incident occurred, in accordance with the reporting requirements of those authorities.

An operator must report any occasion when undeclared or mis-declared dangerous goods are discovered in cargo or mail to the appropriate authorities of the State of the operator and the State in which this occurred. The Operator must also report any dangerous goods not permitted in Passenger and Crew Members baggage, which are discovered.

Such a report must be made to the appropriate authority of the State in which this occurred.




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Revision Questions

1. The following two substances are loaded onto the same pallet, is this permitted? (Circle the correct answer)

UN 2280UN 1390

YES NO

2. A shipper is organizing the shipment of the following items, which are to be packed into one outer package, is this permitted?

(Circle the correct answer)

UN 1057 0.5 KGUN 1616 1 KG

YES NO

3. Determine if the following items require segregation. (Circle the correct answer) Segregation Segregation not requiredUN 1155 & UN 0503 YES NO

UN 0432 & UN 1922 YES NO




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Notes




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Unit 10 - Safety and Security

Review the requirements for Emergency Response Information and ER Telephone Number.

Understand the required components and elements for Security.

Emergency Response Information §172.604

Many State variations require that Emergency Response Information be provided and maintained during transport.

Emergency response information must be immediately available at all times that the hazardous material is present and should be immediately available to any authorities responding to an incident or conducting an investigation involving a hazardous material.

The Emergency Response Information must contain, at a minimum:

Basic description of the material, including technical names.

Immediate risks to health.

Any risks of fire and / or explosion.

Immediate precautions for accidents and incidents.

Immediate methods of containing a fire.

Initial methods for spills and leaks with no fire.

Preliminary first aid.




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This information is of vital importance to the mitigation of an accident involving dangerous goods, the Emergency Response Information must be:

Printed in English

Legible

Available for use away from the package containing the hazardous materials.

Must be Present:

On Shipping Papers

On a document, such as an SDS that may contain all the required

information, or

On a separate document that cross-references the description with the emergency information. (For Example the North American Emergency Response Guidebook - ERG)

Applicability

The requirements for providing Emergency Response Information applies to any Persons who:

Offer dangerous goods for transport

Accept hazmat for transport

Transfer or otherwise handle hazardous materials during transportation.

No person may offer, accept, transfer, store or otherwise handle dangerous goods during transport unless:

The Emergency Response Information is immediately available at all times.

The Emergency Response Information, including the Emergency Response Telephone Number is immediately available to the authorities at the incident or investigation.




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ER Telephone Number

A 24 hour telephone number must be provided for hazmat freight moving, from, through, within and to the USA, South Africa, United Arab Emirates, Canada, to name but a few.

In most cases the Telephone number must be:

Monitored at all times the hazardous material is in transport.

The number of a person, agency or organization with knowledge about the hazmat, or with the access to the comprehensive emergency response information; or

The number of a person who has immediate access to a knowledgeable person with comprehensive emergency response information.

The telephone number must include the international dialing code.

In a clearly visible location and identified as the Emergency Contact details on documentation.

For Shipments to, from and through the United States, the following applies:

The 24 Hour telephone number must meet the requirements of 49 CFR §172.604

The telephone line cannot be “broken” during a call, and a call back or answering services will not meet the requirements.

A unique identifier must accompany the telephone number, this may be a persons name, Contract number or Company Details.




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Security §172.800

In the USA, shippers and carriers of certain quantities and types of hazardous materials are required to develop and implement a Security Plan for the transport of hazardous materials in commerce.

Any person, individual, company or society requiring a security plan MUST train their hazmat employees, based on their need to know, in the details and implementation of the plan.

A Security Plan is required if the following is transported or offered for transport.

A Highway route-controlled quantity of Class 7 (Radioactive) in a motor vehicle, rail car or freight container.

More than 25 KG (55 lb.) of a Division 1.1; 1.2; or 1.3 (Explosives) in a motor vehicle, rail car, or freight container.

More than 1 L (11.06qt) per package of a material with a Poison Inhalation meeting the Hazard Zone A criteria.

A shipment of a quantity of hazardous materials in a bulk packaging.

A toxin regulated by the CDC.

A quantity of hazardous material that requires placarding.




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Components and Elements §172.802

The first component of the Security plan must include an assessment of the security risks associated with the transportation of the hazardous materials.

The security plan must be:

In Writing.

Retained for as long as it remains effective.

Available to the employees responsible for implementation.

Revised and updated as necessary to reflect changing circumstances.

Only shared with employees who are required to be trained in specific elements of the plan, or who have responsibilities under the plan.

Although each facility will require a different security plan, the elements of the plan must include:

Personnel Security.

Unauthorized access to hazardous materials covered by the plan.

En route security for shipments of hazardous materials covered by the plan.

Measures to confirm information provided by job applicants are true and correct.

Regulations, standards, protocols or guidelines issued by other Federal agencies, international organizations, or industry body (For Example, IMO, ICAO etc.) may be included.




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Responsibilities

It is the responsibility of the facilities to ensure the Security Plan: -

Analyze the surrounding area (population, emergency response resources, etc.)

Nature and quantity of hazardous materials

Physical barriers to entry of the facility

Means of detecting unauthorized persons

Methods of screening new hazmat employees

Inventory control and reporting

Carrier selection and verification

Employees of the facility must:

Keep storage areas locked

Keep an updated and accurate inventory

Perform security spot checks of personnel and vehicles

Watch for unusual purchases or odd behavior

Restrict access of non-employees

Keep a list of emergency contacts on hand.

Report suspicious activity

Check loading orders and other documents

Check drivers identification

Write down the driver’s license number on shipping orders / Bill-of-Lading, and have the driver print and sign their name

Verify the driver’s proper hazmat endorsement

Limit access to the facility




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Notes




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Workbook Overview

Steps to Classification

SDS Classification / Information SDS Reference IATA DGR Ref.

F.P. (Flash Point) I.B.P. (Initial Boiling Point)

Paragraph 5 or 9Paragraph 9

3.3.A.

LD50 Paragraph 11 3.6.A.

Full Thickness Destruction 3.8.A

Steps to checking State and Operator Variations

Procedures IATA Ref.

Check the Country the freight is moving FROM. 2.8.1.3.

Check the Country the freight is moving THROUGH. 2.8.1.3.

Check the Country the freight is moving TO. 2.8.1.3.

Check the Airline the freight is on. 2.8.3.4.

Check the Country the aircraft is registered to. 2.8.1.3.




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Steps to using the List of Dangerous Goods

Steps DGR 4.2 Ref.

1. Locate The applicable UN or ID Number The proper shipping name

Column A Column B

2. Determine The applicable Class or Division Number The subsidiary risk (if any)

Column CColumn C

3. Note the Hazard Labels Required Column D

4. Note the Applicable Packing Group (if any) Column E

5. Determine the Excepted Quantity Code (if any, or if required) Column F

6. Determine the Packing Instructions and Maximum Net Quantity per package for transport on: Both Passenger and Cargo Aircraft

Limited Quantity Provisions Standard Packing Instructions

Cargo Aircraft Only

Columns G & HColumns I & JColumns K & L

7. Check if any Special Provisions Apply Column M & Ref. 4.4

8. For Operators ONLY The Emergency Response Drill Code for NOTOC purposes Column N




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Steps for using Packing Instructions

STEP 1 Refer to the List of Dangerous Goods

Locate the Proper Shipping Name and UN/ID Number

Note the Packing Group

Determine if the article or substance is permitted on a Passenger and Cargo Aircraft or Cargo Aircraft Only and note the applicable Packing Instruction Number. If Non-UN Specification Packaging is being used note the Limited Quantity Packing Instruction Number. (Y)

Note any special provisions (Column M), which may apply to the packaging of the item.

STEP 2 Locate the applicable Packing Instruction

Note that the first number of the Packing Instruction indicates the class number or primary risk of the substance.

STEP 3 Read the Packaging Instruction

Ensure that the packaging meets all the requirements according to the Packaging Instruction. Including:

o General Packing Requirements of 5.0.2.o State and Operator Variationso Compatibility Requirements o Closure Requirementso Additional Packing Requirements

Based upon the quantity to be shipped, the availability of packaging etc, the shipper decides which of the packages permitted will be used. This could be either UN Specification packaging as required by the standard three digit Packing Instruction, or Limited Quantity Packaging as per the Packing Instruction indicated by the Y packing instruction.




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STEP 4 Ensure that the quantity limitations are not exceeded

Locate and read the Packing Instruction to ensure that the limits pertaining to the Inner Package Quantities (where applicable) have NOT been exceeded.

Locate and read the Packing Instruction to ensure that the Outer or Single Packaging limits have NOT been exceeded.

STEP 5 Ensure all package limitations have been met

Locate and read on the Package Specification markings and ensure that:

The packing group requirements are correct§ X = I, II, III§ Y = II, III§ Z = III

The limits, for example, the gross tested weights are not exceeded (Either Kilograms or Liters)




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Steps to Marking and Labeling

Marks and Labels Required

Marking RequirementsA) Proper shipping name and UN or ID

NumbersB) Full Name and Address of the shipper

and consignee

For all packages containing dangerous goods.

Net Quantity / Gross weight All classes of dangerous goods including Carbon dioxide, solid (dry ice) except:

Class 7Consumer Commodity Consignments with multiple packages with identical dangerous goods contents (in other words same UN, PSN, PG & QTY) the net quantity or gross weight is not mandatory.

UN Specification Package Markings When UN Specification packaging is being used

Limited Quantity Package Markings When a Limited Quantity package and packing instruction are being used.

Additional Markings As required forSome gasesInfectious substancesUN3373Chemical Oxygen generatorsEnvironmentally hazardous substances.

Hazard Label(s) For all classes of dangerous goods. As listed in Column D of the Blue Pages.

Cargo Aircraft Only For items which are not acceptable for transport on a passenger aircraft, or packed according to PKG INST shown in Column K

Orientation labels / This Way Up On combination packages and overpacks containing liquids

OVERPACK When packages are brought together for transport, the package use markings and labels need to be reproduced on the outside of the overpack.




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Questions

1. Complete the following table

Proper Shipping Name UN / ID Number

Class or Div (Sub-risk)

Pkg Inst for a Passenger

Aircraft

Max. Qty on a Passenger

AircraftCymenes

UN 1104Consumer Commodity

UN 1332n-Propanol

UN 1707Hay

UN 0507Anisole

2. The item is : Nitrobenzenesulphonic, acid Net Quantity : 10 L Inner Packaging : Plastic bottle, 0.5L capacity Outer Packaging : UN-Specification plywood box(s) (4D) Only a PASSENGER AIRCRAFT serves the destination.

(a) What is the applicable:

i. UN Number

ii. Class or Division

iii. Maximum net quantity per outer package

iv. Packing Instruction

(b) How many outer packages will be required?

(c) How many inner packages will be required?




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3. From the information taken from the SDS it is determined the product is not listed in the Blue Pages, but the technical name given to the Alcohol is Dryiscol, it has a Closed Cup Flash Point of 43°c and an Initial Boiling Point of 100°c.

Determine the following:

Proper Shipping Name

UN Number

Packing Group

4. From the information taken from the SDS it is determined that the Pesticide, Xylopes has an LD50 (Dermal) 140mg/kg. The shipment consists of 5KG.


Proper Shipping Name

UN Number

Packing Group

5. A shipment consisting of 5 KG of UN 1944 is packed, marked and labeled according to the regulations, and are being transported from Nigeria to Mexico onboard a Jet Airways flight.

Are there any restrictions? Provide a reference number.




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6. A liquid mixture of Isopropanol and a substance which is not subject to these Regulations, has a Flash Point of 12°c and an Initial Boiling Point of 80°c


i. Packing Group

ii. UN Number

7. A solid substance (Nicotine) has an oral toxicity LD50 of 50 mg/kg.


i. Packing Group

ii. UN Number

8. Which one of the following packages can we use to pack 15kgs of UN 2507 on a passenger aircraft?




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9. Which one of the following packages would you chose to pack 20 kilograms of UN 2213?

Give a reason for each:

a) UN 4G / X10 / S / 10 ______________________________________

b) UN 4D / Z100 / S / 10 ______________________________________

c) UN 4G / Y40 / S / 10 ______________________________________

d) UN 1A1 / Y1.3 / 150 /10 ______________________________________

e) LIMITED QUANTITIES ______________________________________

10. In one UN 4D (Plywood Box) outer packaging the following samples are packed:

5 L UN 3434 10 KG UN 2876 0.25 L UN 1296

By determining the Q-Value, is this permitted?




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11. What marks and labels would be required to pack 5 KG of UN 2214 into a plywood box that bears NO UN specification markings?

12. What marks and labels would be required on an overpack consisting of 5 Plywood boxes each with 1L of Acetone.




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13. Check the following package for any errors or omissions.




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14. Complete the following Shippers Declaration.

Shipper ConsigneeHigh Jinx Robocor 15121 High Road 7181 Viking RoadHouston, Texas, USA Oslo, 11, Norway77073

Emergency Telephone Number: 1.555.8477.1003 (Mr. C. Heck)

Air Waybill # 11223344556Shippers Ref HJK 13782

All the products are to be overpacked into ONE WOOD CRATE.

1. Product Methanol Quantity 1 Liter each Packaging 10 UN Tested Plywood box




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