Igcse Chemistry Topic 10 Metals Ans

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    Paper 3

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    NR NR NR

    NRNR

    R R

    R

    R

    Sn + 2Ag+ 2Ag + Sn

    2+

    Zn + 2AgNO3 Zn(NO3)2+ 2Ag

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    There is electron loss / oxidation no. increases

    Aluminium oxide makes aluminium unreactive.

    Potassium loses one electron / has one valency electron

    Calcium loses 2 electrons/ has 2 valency electrons

    No reaction

    Calcium oxide + water

    2KNO2 O2

    2CaO 4NO2 O2

    Sn2+

    is the oxidizing agent.

    There is electron gain / oxidation no. decreases

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    X

    W

    Z

    Y

    Z

    Y

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    5

    Give a pop sound with burning splint.

    Test with pH paper/ universal indicatorturn blue

    I

    Electrolysis of molten state of ore of X

    Zinc + waterhydrogen + zinc hydroxide

    Heat, steam

    Sn + 2H2O H2 + Sr(OH)2

    Cold water

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    2

    5

    Oct/Nov 2004

    Ca Ca2+ 2e-

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    Zn(OH)2 ZnO + H2O

    It will melt but does not decompose / does not react

    The solid changes from blue to black, and brown gas is evolved.

    metal hydroxide / hydroxide ions + hydrogen

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    Paper 6

    Oct/Nov 2009

    (gas) syringe

    conical flask

    glowing splint ; relights

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    0

    18

    30

    33

    42

    45

    46

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    All points plotted (2)

    Smooth line (1)

    6 minutes

    37 cm3

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    24 56

    25 41

    23 69

    32

    16

    46

    magnesium

    Greatest temp.difference

    Gas evolved rapidly

    hydrogen

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    0

    15

    45

    61

    73

    74

    80

    80

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    hydrochloric acid

    zinc

    measuring cylinder

    flask

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    Uses of Metals

    Paper 1

    Oct/Nov 2009

    D

    B

    D

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    C

    C

    D

    D

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    A

    B

    D

    D

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    A

    D

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    B

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    Oct/Nov 2004

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    D

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    Water / moisture, oxygen /air

    Cover with plastic / alloying / anodic protection / sacrificial

    protection / galvanising

    Carbon /hydrogen / carbon monoxide

    2Fe2O3+ 3C3CO2+ 4Fe

    2 x 56 + 3 x 16 + 2(2+16) = 196

    112 / 196 x 100 % = 57.14%

    Form carbon dioxide

    Form silica /silicon(IV) oxide

    CaO + SiO2 to form slag.

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    good electrical conductor,

    ductile or malleable

    corrosion resistance / good heat conductor /

    high m.p./ b.p. / non-toxic

    alloy

    boiling, condensation

    To get maximum yield of zinc by removing carbon dioxide and in

    turn shifting equilibrium to the right.

    galvanizing / sacrificial protection

    make brass / alloy / dry cell

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    5

    It cannot lose electrons because it receives electrons from the battery.

    Sacrificial protection needs a more reactive metal in contact with

    iron/steel, this metal corrodes instead of steel.

    Cathodic protection needs an inert electrode and electricity.

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    alumina sodium aluminate

    iron(III) oxidefiltration

    carbon

    cathode

    aluminium

    cryolite

    900-1000oC

    Al3+

    + 3e-Al

    Oxygen formed at anode reacts with the carbon anode to

    from carbon dioxide.

    low density / light

    Malleable / ductile / corrosion resistance

    For greater strength

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    zinc

    limestone

    slag

    iron ore

    To make carbon monoxide

    To burn/ provide heat

    Machinery / cars / fridges

    Cutlery / chemical plants

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    May/Jun 2005

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    Heat zinc blende in air to form oxide,

    then reduce oxide with carbon

    To make brass (alloy) / sacrificial protection / galvanizing

    battery roof

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    2Fe2O3 + 3C 4Fe + 3CO2

    Or, Fe2O3 + 3C 2Fe + 3CO

    (ii) (higher in furnace) no oxygen left, carbon dioxide reacts with carbon (to give

    carbon monoxide)

    Or, incomplete combustion of carbon

    Or, CO2+ C2CO / 2C + O22CO

    Or, carbon dioxide reacts with carbon

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    Paper 6

    Oct/Nov 2007

    Brown / red-brown / orange

    Take the place of oxygen

    100% x (150-125) / 150 = 16.67%

    No effect

    slower formation of rust

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    Faster formation of rust / more rust / water further up the tube

    Brown / red-brown / orange

    Take the place of oxygen

    100% x (150-125) / 150 = 16.62%