l6 Ion Implantation

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    ION-IMPLANTATION

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    BASICS

    Ionized impurity atoms areaccelerated by anelectrostatic field and

    made to strike the surfaceof wafer

    By measuring ion currentand adjusting electrostaticfield, the penetrationdepth and dose can becontrolled

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    SYSTEM SET-UP

    Consists of:

    Ion source,Acceleration

    tube, MassAnalyzer,End station

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    MASS ANALYZER The ion beam is passed through a magnetic sector that

    selects a particular ionic species An ion of mass Mand charge qmoving at a velocity vin a

    circular path will experience a force:

    According to the mass, the trajectory will bedifferent a slit is used at the appropriateplace to extract desired species

    The kinetic energy of the ion is given by its extractionvoltage:

    rMv

    qB B

    M

    q

    V 1

    2 extE qV Mv vqV

    M

    extext1

    2

    22

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    Ions are accelerated after mass separation.

    Acceleration done in vacuum to avoid collisions.

    Neutral species undesirable as they cannot be

    deflected by electrostatic potential duringscanning will get implanted near center ofwafer.

    Each species will have a different mass.

    Neutral species are removed by deflecting theions (or bending the ion beam) so that the neutralswill not respond to the electrostatic field and willtravel straight and strike a beam stop.

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    BASIC ARRANGEMENT:

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    Vertical projected range The total distance traveled

    by the ion before it stops iscalled range R.

    Rp is the average vertical

    distance for a uniformbeam= vertical projectedrange

    Energy loss due to twomechanisms Interaction of incidentions with electrons of

    target atom Interaction with lattice

    ions

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    Implantation Profile

    Total distance traversed by ion is called Range, R. The average penetration depth of the ions is called

    projected range Rp. Due to a distribution, there is a statistical fluctuation along

    the direction of the projected range, called straggle, Rp.

    The statistical fluctuation perpendicular to incidentdirection is called lateral straggle, R.

    RpR

    Ion Beam

    Rpx

    z

    y

    Log (ionConcentration)

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    TARGET-ION INTERACTION:

    Energy loss due to two mechanisms Electronic stopping interaction with

    electron cloud around target atom Collisions with electrons around atoms

    transfers momentum and results in localelectronic stopping

    Nuclear stopping interaction withnucleus of target

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    Nuclear stopping

    Collision with nuclei of the lattice atoms

    Scattered significantly

    Causes crystal structure damage.

    Electronic stopping

    Collision with electrons of the lattice atoms

    Incident ion path is almost unchanged Energy transfer is very small

    Crystal structure damage is negligible

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    THEORY OF STOPPINGMECHANISM:

    Total rate of energy loss = sum of energy lossper unit length due to each mechanism

    Total projected range is given by

    [ dE/dx ]total = Sn(E) + Se(E)

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    Stopping profile:

    Ec: Critical energy

    dE/dx : Energy lost

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    Peak concentration:

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    Dopant concentration can be expressedas a function of depth:

    Where is the dose.

    2

    2

    2exp

    2 p

    p

    pR

    RxR

    xN

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    Ion channeling: When the ion direction is such

    that it orients itself along majorcrystallographic direction, ionstravel a great distance beforestopping

    Results in Deep junctions For each species such as B, P,

    etc, there is a critical anglewhen this begins

    Avoided by implanting at smallangle ~ 7 tilt

    By using a thin screening layer ofPR or SiO2

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    Implant damage:

    Light ions and heavy ions cause different

    type of damage profiles

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    Annealing: Removes implant damage Restores crystalline structure Activates dopants Done usually at 850 1000C in N2 ambient Long times (>30min) help remove defects

    completely But cause significant dopant diffusion

    Secondary defects start forming at

    about 500-600C

    Removed at 850 1000C

    Amorphous layer recrystallizes when

    annealed at 600C for 30min (called

    solid phase epitaxy)

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    RTA

    High temperature attained in short time.

    Two methods

    Array of lamps

    Laser

    High throughput

    No change in implantation profile.

    2

    2

    ( )

    2( 2 )2

    ( , )2 ( 2 )

    x Rp

    Rp DtN x tRp Dt

    e