3
MS-E10, Lead-acid battery MATERIAL SAFETY DATA SHEET PRODUCT NAME: LEAD-ACID BATTERY ELECTROLYTE Battery fluid, acid, 8, UN2796, PGII Saft America Inc. d/b/a Alcad Standby Batteries  3 Powdered Metals Drive North Haven, CT 06473 Information: Phone 203-985-2500 Fax 203-985-2539 For Chemical Emergency Spill, Leak, Fire, Exposure or Accident Call CHEMTREC - Day or Night 800-424-9300 Date 06/16/08 HMIS RATINGS 3 Health 1 Flammability 2 Reactivity NFPA RATINGS 3 Health 1 Flammability 2 Reactivity 1. HEALTH HAZARDS ROUTE(S) OF ENTRY: Inhalation, skin and Ingestion Will cause severe to permanent injury to eyes. May cause burns to human (and animal) tissue contacted, including eye corrosion and corneal ulceration. Toxic effects described in animals from single exposure by inhalation include respiratory irritation. Inhalation of mist may cause injury to entire respiratory tract. If ingested, may cause severe burns to the mucous membranes of t he mouth and esophagus. CARCINOGENICITY: NTP: No IARC: No OSH A regulated: No Overexposure by inhalation may include irritation of the upper respiratory passages or erosion of dental surfaces. Higher exposures may lead to temporary lung irritation. Individuals with pre-existing disease of the lungs may have increased susceptibility to the t oxicity of excessive exposures. 2. EMERGENCY FIRST AID If sulfuric acid is spilled, immediately flush skin or eyes with clean water for at l east 15 minutes and remove contaminated clothing and shoes. Wash clothing before re -use. If medical treatment must be delay ed, immerse the affected area in iced water or use compresses of iced water. AVOID FREEZING TISSUE. If swallowed, do NOT induce vomiting; drink large quantiti es of water or milk. In all cases, contact a physician immediately. 3. SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN DURING HANDLING AND STORAGE: Avoid rough handling. Do not store above 140°F. Always have water safety showers and eyewash fountains available. OTHER PRECAUTIONS: Wear full protective clothing when handling this material. 4. REACTIVITY HAZARDS Stable under normal conditions. INCOMPATIBILITIES (MATERIALS TO AVOID): Sulfuric acid reacts vigorously with alkaline solutions, metal powders, strong oxidizers, reducers and combustibles. HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: Reaction with most metals will produce explosive hydrogen gas. HAZARDOUS POLYMERIZATION: Will not occur. 

LeadAcid_ElectrolyteSDS_0608

Embed Size (px)

Citation preview

Page 1: LeadAcid_ElectrolyteSDS_0608

7/30/2019 LeadAcid_ElectrolyteSDS_0608

http://slidepdf.com/reader/full/leadacidelectrolytesds0608 1/3MS-E10, Lead-acid battery

MATERIAL SAFETY DATA SHEET

PRODUCT NAME: LEAD-ACID BATTERY ELECTROLYTEBattery fluid, acid, 8, UN2796, PGII

Saft America Inc.d/b/a Alcad Standby Batteries 3 Powdered Metals DriveNorth Haven, CT 06473Information: Phone 203-985-2500

Fax 203-985-2539

For Chemical Emergency Spill, Leak, Fire, Exposure or AccidentCall CHEMTREC - Day or Night800-424-9300Date 06/16/08

HMIS RATINGS 3 Health 1 Flammability 2 ReactivityNFPA RATINGS 3 Health 1 Flammability 2 Reactivity

1. HEALTH HAZARDSROUTE(S) OF ENTRY: Inhalation, skin and Ingestion

Will cause severe to permanent injury to eyes.

May cause burns to human (and animal) tissue contacted, including eye corrosion and corneal ulceration.Toxic effects described in animals from single exposure by inhalation include respiratory irritation. Inhalation of mist may causeinjury to entire respiratory tract.

If ingested, may cause severe burns to the mucous membranes of the mouth and esophagus.

CARCINOGENICITY: NTP: No IARC: No OSHA regulated: No

Overexposure by inhalation may include irritation of the upper respiratory passages or erosion of dental surfaces.

Higher exposures may lead to temporary lung irritation.

Individuals with pre-existing disease of the lungs may have increased susceptibility to the toxicity of excessive exposures.

2. EMERGENCY FIRST AID

If sulfuric acid is spilled, immediately flush skin or eyes with clean water for at least 15 minutes and remove contaminatedclothing and shoes. Wash clothing before re-use. If medical treatment must be delayed, immerse the affected area in icedwater or use compresses of iced water. AVOID FREEZING TISSUE.

If swallowed, do NOT induce vomiting; drink large quantities of water or milk.

In all cases, contact a physician immediately.

3. SPECIAL PRECAUTIONSPRECAUTIONS TO BE TAKEN DURING HANDLING AND STORAGE:

Avoid rough handling. Do not store above 140°F. Always have water safety showers and eyewash fountains available.

OTHER PRECAUTIONS:

Wear full protective clothing when handling this material. 

4. REACTIVITY HAZARDSStable under normal conditions.

INCOMPATIBILITIES (MATERIALS TO AVOID):

Sulfuric acid reacts vigorously with alkaline solutions, metal powders, strong oxidizers, reducers and combustibles.

HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:

Reaction with most metals will produce explosive hydrogen gas.

HAZARDOUS POLYMERIZATION:

Will not occur. 

Page 2: LeadAcid_ElectrolyteSDS_0608

7/30/2019 LeadAcid_ElectrolyteSDS_0608

http://slidepdf.com/reader/full/leadacidelectrolytesds0608 2/32 MS-E10, Lead-acid battery

5. FIRE AND EXPLOSION HAZARDSFLASH POINT: N/A FLAMMABLE LIMITS: LEL: N/A UEL: N/A

EXTINGUISHING MEDIA:

Water, dry chemical. Do not use carbon dioxide (CO2) extinguishers for fires in area. Use water only to cool containers. DONOT get water in containers.

SPECIAL FIRE FIGHTING PROCEDURES:Generates heat with addition of water. Wear full protective clothing. Use NIOSH/MSHA approved positive pressure self-contained breathing apparatus. Neutralize runoff with lime, soda ash, etc., to prevent corrosion of metals and formation ofhydrogen gas.

UNUSUAL FIRE AND EXPLOSION HAZARDS:

Sulfuric Acid can react with oxidizing or reducing materials and when heated it emits highly toxic fumes. Reacts with mostmetals to produce flammable and potentially explosive hydrogen.

6. HAZARDOUS INGREDIENTSSPECIFIC CHEMICAL IDENTITY; COMMON NAME(S) OSHA PEL ACGIH TLV OTHER LIMITS %

Sulfuric Acid; H2S04; Battery fluid, acid, electrolyte 1.00 MG/M3

28 - 32% 

7. PHYSICAL PROPERTIESBOILING POINT: N/A VAPOR PRESSURE (MM HG): N/A

VAPOR DENSITY (AIR=1): N/A SPECIFIC GRAVITY (WATER=1): N/A

SOLUBILITY IN WATER: N/A MELTING POINT: N/A

EVAPORATION REATE (BUTYLCETATE=1):

N/A

APPEARANCE AND COLOR: Clear and colorless and odorless. Sometimes cloudy.

8. ENVIRONMENTAL PROCEDURES

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:

Comply with federal, state and local regulations on reporting releases, containing spills and reparation. Contain spill to smallestpossible area and absorb as appropriate. Avoid splashing and misting redemption.

WASTE DISPOSAL METHOD:

Comply with federal, state and local regulations. If approved, neutralize with soda ash or lime and transfer to waste treatment

system.

9. INDUSTRIAL HYGIENE CONTROL MEASURESVENTILATION:

Adequate to meet TLV requirements.

RESPIRATORY PROTECTION:

Not normally required. If misting occurs, use proper acid canister-type full face piece (See MCA data sheet SD-201).

EYE PROTECTION:

Chemical splash goggles; full-length face shield.

HAND PROTECTION:

Rubber or plastic acid-proof gauntlet gloves.

OTHER PROTECTIVE EQUIPMENT:

Rubber or plastic apron and boots; long sleeve wool, acrylic or polyester clothing; acid-proof suit and hood.

WORK/HYGIENIC PRACTICES:Always use extreme care; wash thoroughly after handling.

Page 3: LeadAcid_ElectrolyteSDS_0608

7/30/2019 LeadAcid_ElectrolyteSDS_0608

http://slidepdf.com/reader/full/leadacidelectrolytesds0608 3/33 MS-E10, Lead-acid battery

10. ENVIRONMENTAL REPORTING REQUIREMENTS

EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT PF 1986 (EPCRA):Sulfuric acid is subject to the reporting requirements of EPCRA, sections 302, 311, 312 and 313 (40 CFR 372):

CAS# CHEMICAL NAME REPORTABLE QUANTITY

7664-93-9 Sulfuric acid 500 pounds*

*Battery electrolyte is a mixture of sulfuric acid and water. Only the amount of 100% sulfuric acid must be counted in thereportable quantity.

A copy of the MSDS may be required to be filed with the local emergency planning commission, state emergency responsecommission and local fire department in accordance with sections of EPCRA. 

Last Date Revised 06/16/08

Disclaimer: This information has been complied for sources considered to be dependable and is to the best of our knowledge and belief, accurate and reliable as of the datedcompiled. However, no representation, warranty (either expressed or implied) or guarantee is made to the accuracy reliability or completeness of the information contained

herein. This information relates to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. It isthe user’s responsibility to satisfy himself as to the suitability and completeness of this information for his own particular use. We do not accept liability for any loss or damagethat may occur, whether direct, indirect, incidental or consequential, for the use of this information nor do we offer warranty against patent infringement. Additional information isavailable by calling the telephone number above designated for this purpose.