Low Foam and Streak -Free Cleaning · 4/28/2020 · Low Foam Cleaning - Colonial ZF series: Alkaline stable low foam surfactant blends - Low foam surfactants stable in ultra concentrated

Dr. Andy Sun, Business Manager of HI&I ProductsApril 28, 2020

Low Foam and Streak-Free Cleaning

Content• Low Foam Cleaning

- Colonial ZF series: Alkaline stable low foam surfactant blends- Low foam surfactants stable in ultra concentrated caustic and acids- Low foam degreasing boosters

• Streak-Free Cleaning- ColaDol DG13: Non-VOC and Streak-free cleaners

CONFIDENTIAL USE ONLY 2

Alkaline Stable Low Foam Blends


Colonial ZF Series Alkaline stable low foam cleaning

Metal & Parts Auto Dish & CIP Steam & Carpet Laundry

Colonial ZF - 10, 15, 25 SeriesDESCRIPTION Low foam surfactant concentrateREGISTRATIONS USA (TSCA); Canada (NDSL); Korea (KECI); New Zealand (NZIOC),

ZF-10 & ZF-10P also EU (REACH), China(IECSC), Taiwan (NECI)ZF-15 also China(IECSC), Taiwan (NECI), Philippines - PICCS


ZF-10 ZF-15 ZF-25Appearance Clear liquid Clear liquid Clear liquid

% Active 50 50 50

pH (10%) 9.5 7.7 7.5

Specific gravity, g 1.07 1.18 1.25

Colonial ZF Series: Cloud Points @ 5% Active


% NaOH Colonial ZF-10

Colonial ZF-15

ColonialZF-25

5.0 63 oC 37 oC 28 oC

10.0 91 oC 56 oC 32 oC

15.0 INS 77 oC 32 oC

20.0 INS INS 41 oC

25.0 INS INS 88 oC

Colonial ZF Series: Dilution Properties, 1% ZF in 0.5% NaOH


Properties Colonial ZF-10

Colonial ZF-15

ColonialZF-25

Draves Wetting(seconds) 13 14 12

Cloud Point (oC) 31 32 32

Surface Tension(dynes/cm) 34.0 34.2 34.8

Ross Miles Foam(0.1% active), mm

0 min: 601min: 205mins: 10

0 min: 651min: 255mins: 5

0 min: 551min: 205mins: 5

Industrial Degreasing Test• Industrial grease soil

- Engine oil- Lithium grease- Oil soluble dye

• Cleaning solution- 0.5% active surfactant- 0.8% sodium hydroxide (50%)- 0.8% sodium metasilicate- 0.4% sodium carbonate- Water balance

• Process- Test soil was casted on 1x3 ins glass slides- The soil cased were aged for a few hours- The soiled slides were immersed in cleaning

solution at room temperature under magnetic stirring for 40 minutes and repeat to get averages


0102030405060708090

100

Pluronic LF-61

Colonial ZF-10

Colonial ZF-15

Colonial ZF-25

Industrial DegreasingSoil: engine oil and lithium grease

Paraffin Oil Removal Test

• % Detergency is measured using coated steel panels washed 10 minutes at 60°C in a solution containing 0.5% active surfactant and 2% of an alkaline base (comprised of 0.8% active sodium hydroxide, 0.8% sodium metasilicate, and 0.4% sodium carbonate)


Paraffin Oil Cleaning

0

10

20

30

40

50

60

70

80

90

100

Colonial ZF-10 Colonial ZF-15 Colonial ZF-25 Triton™ DF-20

% Detergency (Paraffinic

Soil)

Metal and Parts Spray Cleaning• Produce minimum foam, penetrate and loosen soil, emulsify greasy or oily soil, protect metal from

corrosion, promote reverse emulsification in storage tank


pH > 13

Chemical Name %

Water qs to 100.0Potassium Hydroxide (45%) 8.0Sodium Metasilicate Pentahydrate 3.0Tetrapotassium Pyrophosphate 10.0EDTA Tetrasodium 2.0Colonial ZF-10 or ZF-25 8.0Fragrance q.s.

Auto Dish Washing Liquid• Produce minimum foam, penetrate and loosen soil, suppress foam caused by protein soils such as

egg and milk, emulsify greasy or oily soil, minimizing water spots, protect china patterns and metals from the corrosive effects


pH > 13

Chemical Name %

Water qs to 100.0Sodium Silicate 8.0Sodium Hydroxide (50%) 3.0EDTA Tetrasodium 10.0Colonial ZF-10 2.0Fragrance 8.0

Low Foam Cleaning-In-Place• Cleaning interior surfaces of your plant equipment without disassembly, would require low-foam

cleaning and disinfecting to be completed at elevated temperature, pressure, and in strong alkaline or acid


pH > 13

Chemical Name %

Water qs to 100.0

Sodium Hydroxide (50%) 6.0

Sodium Gluconate 1.0

Colonial ZF-10 2.0

Fragrance q.s.

Low Foam Steam and Carpet Cleaning• Low foam cleaner with high enough cloud point to sustain steam cleaning temperature of 150-

300°F, with good wetting, soil penetration, and oil emulsification


pH > 9.5

Chemical Name %

Water qs to 100.0Sodium Carbonate 2.0Na4EDTA 1.0Cola®Dol DG13 3.0Colonial ZF-10 2.0Cola®Wet DOSS 70PG 1.0Fragrance q.s.

High Efficiency Laundry• High efficiency laundry required surfactants of low foam, fast wetting, ease in rinsing-off, good

emulsification and soil removal at low washing temperature at 30-50oC and with low water usage


Chemical Name %

Water qs to 100.0Cola®Dol DG13 5.0Colonial ZF-10 12.0Suga®Boost 050 8.0Acusol 505N 1.0Fragrance q.s.Sodium Hydroxide (50%) 1.0

Concentrated Caustic and Acids Cleaners

Surfactants Stable in Concentrated Caustic (>30%) & Acids SolutionsProduct Name Chemistry Activity Foam Function Stable Conc. in Caustic/Acid

Cola®Terge BCC Performance Blend 40% LowCIP

CleanerBrewery

50% NaOH, 45% KOH, Stable in most acids

Cola®Trope 522 Performance Blend 63% Low HydrotropeWetting

35% NaOH, 45% KOH, 45% TKPP, 20% SMS, Not stable in acids

Cola®Trope AHS Hydroxysultaine 50% Low WettingHydrotrope

50% NaOH, 45% KOH, 20% HNO3, 25% HCl

Cola®Teric AP PhosphoethylImidazoline 35% Low Hydrotrope

Antistatic40-45% KOH, NaOH Stable in acids like H3PO4

Suga®Fax D08NC APG Phosphate 40% Low HydrotropeWetting

50% NaOH, 45% KOH, Stable in acids like 25% H2SO4


Boosters for Low Foam Degreasing

Cola®Terge LWS Paraffin Wax Stripper and Degreasing Booster


Cola®Terge LWS PropertiesLISTINGS US (TSCA), Canada (DSL), Australia (AICS), New Zealand (NZIOC), Philippines (PICCS), Taiwan (TCSI)

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Typical Properties Cola®Terge LWSAppearance (@ 25°C ) Clear to LiquidpH (10% aqueous) 10.0 – 11.5Specific Gravity 0.995% Activity ~100Color, Gardner’98 4 MaxSurface Tension, 0.1% active, dyn/cm 32.4Cloud Point, oC @ 1% 57.0Flash Point, oC >94 Non-Flammable

Paraffin Wax Removal Tests


0

20

40

60

80

100

5% ColaTerge LWS 10% NP-9 10% EB 10% DPnB

Soil: Paraffin Waxes

PercentSoil

Removal

Cola®Terge LWS Benefits and ApplicationsBENEFITS• Effective paraffin wax stripping• Boost industrial degreasing• Fast wetting• Mid-low flash foam• Stable in wide pH range• Stable in high electrolyte and bring solution• Non-flammable• Expect to be readily biodegradable

APPLICATIONS• Paraffin wax removal in oilfield• Pipeline cleaning• Industrial degreasing• Floor wax stripping• Boosting stain removal in laundry and carpet

cleaning

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Formulations

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Paraffin Wax Remover for Oil and Gas Drilling(Remove scale, paraffins, tars, and other viscous constituents to improve flow of gas and oil)

DESCRIPTION %

1 Soy Methyl Ester 50-60

2 Cola®Dol DG13 20-25

3 Cola®Terge LWS 15-20

4 Preservative q.s.

Floor Wax Stripper(Strip waxes on hardwood floors and tiles without damaging substrate surfaces)

DESCRIPTION %

1 Water 85.0

2 Cola®Dol DG13 10.0

3 Cola®Terge LWS 3.0

4 MEA 2.0

5 Preservative q.s.

Non-VOC and Streak-Free Cleaning

Cola®Dol DG13Non-VOC Streak-Free Solvent Alternative

Low Temperature Degreasing Booster


Overview• Cola®Dol DG13 is a versatile, nonionic

degreaser, wetting agent, and solubilizer specifically

• Designed for boosting industrial and household cleaning where low foam and non-streaking are essential

• Streak-free rinse aid for auto dish washing• Can also be used as a non-VOC

alternative to VOC solvents• Is expected to be readily biodegradable• CleanGredient listed

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Cola®Dol DG13 PropertiesLISTINGS US (TSCA), Canada (DSL), Australia (AICS), Japan (ENCS), Korea (KECI),

China (IECSC), Philippines (PICCS), New Zealand (NZIoC), Taiwan (TCSI)

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Appearance (@ 25°C )F Clear Liquid% Active 100pH (as is) 10 - 11Moisture KF 2 Max.Color Gardner ‘98 1Specific Gravity 0.9856Viscosity 22Ross Miles Foam (0.1%) 20/0/0Flash Point, °C >94 Non-FlammableCloud Point, °C >90HLB 13

Cleaning Performance• Cola®Dol DG13 outperforms various solvents in immersion degreasing test.• Soil formula: Motor Oil, Li Grease


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100

4% EB 4% NP-9 1% ColaDol DG 13

% S

oil R

emov

al

Comparison with Competition*


ColaDolDG13

Bio-SoftLFS-04

Bio-SoftLFS-07

Bio-SoftDR-13

TomaKleenG-12*

DehypoundAdvanced

% Active 100 90 90 100 100 < 70

Cloud Point, °C > 90 46 34 56 36 _

Foam (0.1%)(Ross-Miles)mm, 25°C

0 min. 20 87 79 Mid-HighFoam

Mid-HighFoam

Mid-HighFoam

5 min. 0 82 33

Gel Tendency in Water No YesYes

Below RoomTemperature

NA No No

Streaking @ 1% No Streaking

LowStreaking

LowStreaking Streaking Streaking Streaking

* Bio-Soft - Stepan TomaKleen - Evonik Dehypound - BASF

Cola®Dol DG13 Benefits and ApplicationsBENEFITS• Low foam at low temperature• Streak-free• Fast surface wetting and penetration• Excellent degreasing at low temperature• Non-VOC• Non-hazardous for transport• Non-flammable• Expect to be readily biodegradable

APPLICATIONS• Non-emulsifying metal/parts cleaning• Streak-free glass cleaner• Solar panel cleaners• Graffiti remover• Auto dish rinse aid• Low temperature degreasing booster• Precision cleaning• Low foam replacement of glycol solvents

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Cola®Dol DG13 Formulations

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Non-VOC Graffiti Remover

DESCRIPTION %

1 Water 55-65


3 Soy Methyl Ester 10 -15

4 Preservative q.s.

Streak-Free Solar Panel and Glass Cleaner with Water Repellant

DESCRIPTION %1 Water Balance


3 Cola®Dry DAB 0.2-0.3

4 Preservative q.s.

Product Name ChemistryParing Low Foam Hydrotropes

ApplicationsAlkaline High Caustic (>30%) Acid

ColaCap MA139ColaCap MA259

End-capped alkoxylates

ColaTrope INC/INC-K*ColaTrope CA/OD* #ColaTeric ZF-50ColaTeric CYABColaTrope 1254*ColaTrope 555

ColaTrope AHSColaTrope 522ColaTeric APSugaFax D08SugaFax D04

ColaTrope AHSColaTeric APSugaFax D08SugaFax D04

Alkaline or acidMetal & parts CIP and breweryCarpet and steamHE laundryOffset EO-PO polymer

Colonial DF-20Colonial DF-16

Anionic polyetherEO-PO polymer Any above Any above Any above Offsets to Triton DF-20

Offsets to Triton DF-16Colonial ZF-10Colonial ZF-15Colonial ZF-25

Blend Not NeededAlkaline ONLYmetal & parts, CIPcarpet, laundry

ColaTerge BCC Blend Not Needed Alkaline or acidCIP cleaning

ColaTerge LWS Blend May not need, but if does, any above Degreasing booster in laundry and industrial

ColaDol DG13 Blend May not need, but if does, any aboveGlass, solar panel, Low temp degreasing booster

* Bleach and peroxide stable; # EPA Safer Choice Direct Release qualified

Questions! [email protected]

Thank you!

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Low Foam and Streak -Free Cleaning · 4/28/2020 · Low Foam Cleaning - Colonial ZF series: Alkaline stable low foam surfactant blends - Low foam surfactants stable in ultra concentrated