Modelling & Experimental Study of Biomass Gasifier For

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    MODELLING & EXPERIMENTAL

    STUDY OF BIOMASS GASIFIERFOR ELECTRIC POWER

    APPLICATION

    By-

    Tarun Kumar (MEB11034)

    Ankur Gupta (MEB11040)

    Avinash K. Singh (MEB11044)

    Project Supervisor-

    Partha Pratim Dutta

    Assistant Professor

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    INTRODUCTION Biomass is biological material derived from living organisms. It most

    often refers to plants or plant-based materials.

    As an energy source, biomass can either be used directly viacombustion to produce heat, or indirectly after converting it tovarious forms of biofuel.

    Wood remains the largest biomass energy source to date.

    Gasification is a process that converts organic or fossilfuel based carbonaceous materials into carbonmonoxide, hydrogen ,carbon dioxide, methane and rest is Nitrogenin limited supply of air.

    The resulting gas mixture is called syngas (from synthesis gas orsynthetic gas) or producer gas and is itself a fuel.

    The power derived from gasification and combustion of the

    resultant gas is considered to be a source of renewable energy if thegasified compounds were obtained from biomass.

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    Objective of study

    Theoretical study of biomass gasification.

    Experimental study of biomass gasification

    for electrical application

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    DOWNDRAFT BIOMASS GASIFIER

    Sectional view

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    Experimental Setup

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    Literature Review

    Equivalence ratio ()

    =(Flow rate of air supply)(Duration of the run)

    (Mass input of wood)(A/F for = 1)

    (A/F) for = 1 is 5.22 m3of air/kg of wood.

    The equivalence ratio for the gasifier was found to be inthe range 0.2680.43, which was within the range for

    ideal and theoretical gasification (0.190.43).

    The average gas composition is:

    1.69% O2, 43.62% N2,

    14.05% H2, 24.04% CO,

    14.66% CO2, 2.02% CH4

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    Variation of percentage of

    oxygen with equivalence ratio[1]

    Variation of percentage ofnitrogen with equivalenceratio[1]

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    Variation of percentage of

    hydrogen with equivalence ratio

    [1]

    Variation of percentage of CO

    with equivalence ratio [1]

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    Variation of percentage of carbon

    dioxide with equivalence ratio. [1]Variation of percentage of methanewith equivalence ratio [1]

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    Variation of caloric value withequivalence ratio [1]

    Variation of gas production ratewith equivalence ratio [1]

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    Variation of gas production rate per unit weight of the

    fuel with equivalence ratio [1]

    Therefore the optimum equivalence ratio for the best

    performance of downdraft biomass gasifier is 0.388

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    The above experimental analysis and research

    led to the following results-

    Overall efficiency = 11.15 % (average)

    Maximum efficiency = 15.46 %

    Specific consumption of biomass material = 1.98

    kg/kWh Minimum consumptions of biomass material = 1.49

    kg/kWh

    Carbon content in ash is about 10% of carboncontent in feed at optimum equivalence ratio.

    Minimum carbon content at optimum equivalence

    ratio

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    Steps of GASIFICATION

    Drying (the moisture content of biomass we will usewill be 15%-20%)

    Pyrolysis

    Gasification

    Combustion

    BIOMASS to be used by us are---

    1) Jack Fruit (Artocarpus heterophyllus)wood

    2) Mango Tree (Mangifera indica) wood3) Drumstick (Moringa Oleifera) wood

    4) Ashok tree (Polyalthia Longifera) wood

    5) Jamun (Syzygium cumini) wood

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    MATHEMATICAL MODELLING [2]

    The main gasification reaction is

    n

    H2)

    H

    2

    + n

    CO)

    CO + n

    CO2)

    CO

    2

    + n

    H2O)

    H

    2

    O + n

    CH4)

    CH

    4

    +

    z/2+3.76m)N

    2

    All inputs on the left-hand side of the eq. are

    defined at 25C. On the right-hand side, niis thenumber of moles of the species i which areunknown.

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    Molar quantity of water per one kmol of biomass

    can be written as

    w = M

    bm

    x MC

    M

    H2O

    x 1-MC)

    where MC is moisture content

    Mbmandare the masses of biomass and

    water.

    Air/fuel ratio can be calculated as +0.25-0.5)

    for a fuel with a chemical formula of CHON.

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    The following simplified Chemical formulas describe the basic

    gasification process :

    1) Boudouard reaction : C + CO2 2CO

    2) Water-gas reaction : C+H2OCO + H2

    3)Hydrogenating gasification : C + 2H2CH4 (+75 KJ/mol)

    4)Water-gas shift : CO+H2OCO2+H2 (+41.2 KJ/mol)5)Steam reforming : CH4+ H2OCO+3H2

    Water gas shift reaction together with hydrogenating

    gasification is chosen to play the role of two

    independent equations.

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    These equations with their equilibrium constants generate

    two of five equations required to obtain the five unknown

    species of the produced syngas (H2, CO, CO2, H2O, and CH4).

    The remaining three equations are formulated by balancing

    each chemical element consisting of carbon, hydrogen and

    oxygen.

    where R is universal gas constant

    GT is the standard Gibbs function of formation

    Fi ll t

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    Finally we get

    dt + I

    where hfis the enthalpy/heat of formation

    ALSO

    where I is constant of integration

    J is a const.

    A, B, C and D are the coefficients for determining the

    specific heats.

    Having known the I and J constants together with hfandG, theequilibrium constant (k) can be determined.

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    For instance, the equilibrium constant for water-gas shift

    reaction is obtained as follows:

    If the temperature in the Gasification Zone is T and the inlet state

    is

    assumed to be 298 K , the enthalpy balance for this process can bewritten as

    nj ( h

    f,j+

    hT,j) =

    nj ( h

    f,i+

    h

    T,i)where h

    T

    represents the enthalpy difference between any given

    state and reference state.

    j= react i= prod

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    When the equilibrium constants are defined, a system of

    non linear equations are obtained which can be solved by

    NewtonRaphson method together with convergencestrategies.

    The equations are solved with the use of iterative

    methods.

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    References http://www.sciencedirect.com/science/article/pii/S0961953

    402000594

    [1] Zainal, Z.A,Rifau, Ali, Quadir, G.A , Seetharamu, K.N.

    Experimental investigation of a downdraft biomass gasifier ,

    Biomass and Bioenergy 23(4) ,2002

    profdoc.um.ac.ir/articles/a/1008098.pdf

    [2] Vaezi,M. ,Passandideh-Fard,M. ,Moghiman ,M. ,Charmchi,

    M. MODELING BIOMASS GASIFICATION:A NEW APPROACH

    TO UTILIZE RENEWABLE SOURCES OF ENERGY , Energy, 2008

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    THANK YOU