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www.jacobs.com | worldwide Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen Transfer: Elements of a Roadmap to Sustainable Energy Independence Julian Sandino, PE, PhD, BCEE, WEF & IWA Fellow MWEA Sustainable Energy & Process Joint Seminar Battle Creek, MI October 17, 2018

Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen ...... | worldwide Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen Transfer: Elements of a Roadmap to Sustainable

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Page 1: Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen ...... | worldwide Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen Transfer: Elements of a Roadmap to Sustainable

www.jacobs.com | worldwide

Nitrogen Shortcut, Carbon Redirection and

Enhanced Oxygen Transfer: Elements of a Roadmap

to Sustainable Energy Independence Julian Sandino, PE, PhD, BCEE, WEF & IWA Fellow

MWEA Sustainable Energy & Process Joint Seminar

Battle Creek, MI

October 17, 2018

Page 2: Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen ...... | worldwide Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen Transfer: Elements of a Roadmap to Sustainable

What is driving projects?

Addressing today’s issues…

– Aging infrastructure

– Service area changes

– Water stress

– Increased regulations

– Mitigating community and

environmental impacts

– Improve O&M efficiencies

While positioning for the

future...

Page 3: Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen ...... | worldwide Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen Transfer: Elements of a Roadmap to Sustainable

Energy optimization: essential for

sustainable wastewater management

• Energy consumption has

significant environmental &

social impacts

• Energy is 2nd to labour in cost

of “used” water management

• Energy requirements limit

recovery of some resources

• Energy optimization =

f(reducing consumption;

increasing recovery)

Page 4: Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen ...... | worldwide Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen Transfer: Elements of a Roadmap to Sustainable

Sustainable Energy

Management

A multi-pronged approach

to energy management

– Energy Use

Optimization

– Energy Recovery

Page 5: Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen ...... | worldwide Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen Transfer: Elements of a Roadmap to Sustainable

Balancing carbon in the wastewater holds

the key to energy optimization

• Effective primary treatment reduces carbon load

to subsequent processes reducing energy

consumption

• Redirected carbon offers potential of significant

energy recovery

• Conventional BNR relies on carbon for nitrogen

and phosphorus removal.

• Mainstream deammonification: alternative to

current energy intensive carbon driven

processes

Page 6: Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen ...... | worldwide Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen Transfer: Elements of a Roadmap to Sustainable

Deammonification: requires less energy

and allows for carbon redirection

1 mol Ammonia

(NH3/ NH4 +)

1 mol Nitrite(NO2

- )

1 mol Nitrate(NO3

- )

38% O2

1 mol Nitrite(NO2

- )

½ mol Nitrogen Gas(N2 )

25% O2

60% Carbon

NITRIFICATIONAerobic , Autotrophic

40% Carbon

Anammox

bacteria

DENITRIFICATIONAnoxic, Heterotrophic

Page 7: Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen ...... | worldwide Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen Transfer: Elements of a Roadmap to Sustainable

VandCenter Syd (VCS)

• Established in 1853 as first modern waterworks in

Denmark

• 3rd largest water and wastewater company in

Denmark. Headquartered in Odense.

• Adopted in 2010 goal of achieving energy and CO2

neutrality in 5 years

• Ejby Mølle WWTP: 410,000 PE BNR facility; energy

self-sufficient in 2014

• Beyond Energy Neutrality Program: Jacobs

developed approach and assisted in the

implementation of multiple projects that by 2016

resulted in 115% electrical power and 160% heat self-

sufficiency. Excess heat is being sold to District

Heating grid, with locations as far as 20 kms away.

• Awards: 2013 Water and Energy Exchange (WEX)

Global Innovation Award (Madrid); International

Water Association’s 2018 Project Innovation Award

Page 8: Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen ...... | worldwide Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen Transfer: Elements of a Roadmap to Sustainable

Ejby Mølle WWTP

Page 9: Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen ...... | worldwide Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen Transfer: Elements of a Roadmap to Sustainable

DEMONTM selected for sidestream N removal

Sidestream

deammonification

reactors at the EMWWTP

Operational 2014

Page 10: Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen ...... | worldwide Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen Transfer: Elements of a Roadmap to Sustainable

Mainstream deammonification was enabled by

adding hydrocyclones to the WAS flow

Dewatering

Centrate

Influent Primary

Clarifiers

WAS

Bioreactor (aerobic/anoxic)

Effluent

DEMON

Reactors

AOB Seed

Anammox

Seed

CEPT

Mainstream

hydrocyclones

Page 11: Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen ...... | worldwide Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen Transfer: Elements of a Roadmap to Sustainable

Nitrogen shortcut allows further carbon redirection

• Improving primary clarification removal

– Historically 65-70% TSS removal w/o chemicals

– How much more will CEPT remove?

• Optimizing the trickling filter process

– Kept alive for wet weather flow conditions (~ 20% PE)

– Maximize PE feed to meet minimum wetting rates

• Reduces carbon and ammonia to bioreactors (lower O2 demand = lower energy)

• Nitrified effluent fed to bioreactors; sufficient carbon

• Increases biogas production11

Page 12: Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen ...... | worldwide Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen Transfer: Elements of a Roadmap to Sustainable

Deammonification has contributed to net positive energy

status

12

0

5000000

10000000

15000000

20000000

25000000

2011 2012 2013 2014 2015 2016

En

erg

y,

kW

h

Electric Power Generated Heat Generated Electric Power Consumed Heat Consumed

En

erg

yO

pti

miz

ati

on

Stu

dy

Sid

es

tre

am

De

am

mo

nif

ica

tio

n

Co

ge

ne

rati

on

Ca

pa

cit

y E

xp

an

sio

n

Ele

ctr

ica

l P

ow

er

Su

rplu

s

Ma

ins

tre

am

De

am

mo

nif

icati

on

Ele

ctr

ical P

ow

er

Ne

utr

ali

ty

Page 13: Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen ...... | worldwide Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen Transfer: Elements of a Roadmap to Sustainable

Carbon redirection reduces energy consumption from

secondary processes and recovers energy from sludge

• Conventional primary

treatment

• Chemically enhanced primary

treatment

• “A” stage of A/B Process (high

rate biological contact)

Page 14: Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen ...... | worldwide Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen Transfer: Elements of a Roadmap to Sustainable

“A” Stage Dissolved Air Flotation

• Combines grit and FOG removal, biological contact, primary

treatment, P removal and sludge co-thickening

• Small footprint

Agua Nueva WRF, Pima Co., AZ

Page 15: Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen ...... | worldwide Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen Transfer: Elements of a Roadmap to Sustainable

Solids Processing is Key to Energy Recovery

Opportunities

Page 16: Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen ...... | worldwide Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen Transfer: Elements of a Roadmap to Sustainable

Brands Sands,

UK

Minworth, UK

DCWater, DC

Tuas WRP, SGP

Jurong WRP,

SGP

Bonnybrook WWTP,

AB

San Francisco

PUC, CA

Thermal Hydrolysis Process

HaarslevTM HCHS 2 operating facilities

Semi-continuous process

Lower complexity

17-22% TS pre-dewatering

Compact vacuum condenser

- overall smaller footprint

Lower heat requirements

Lower O&M costs

KC-based service center

ExelysTM

2 operating facilities

Continuous process

Lower complexity

18-24% TS pre-dewatering

Smaller systems

Dynamic steam mixer

Lower heat requirements

Lower O&M costs

Class A not proven

Cambi© THP >90% of all operating facilities

Batch process

Higher complexity

17% TS pre-dewatering

Oversized systems

Higher heat requirements

Higher O&M costs

Cooling footprint can be

significant

Modular- easy to install

Page 17: Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen ...... | worldwide Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen Transfer: Elements of a Roadmap to Sustainable

Summary of Energy/Mass Balances and Costs - EMWWTP

Scenario

Electricit

y Sold

(MWh/d)

Heat

Sold

(MWh/d

)

Total

Energy

Sold

(MWh/d)

Biosolids

to

Disposal

(Wet

ton/d)

Simple

Payback

(Years)

Baseline 23.7 16.4 40.1 53 -Full THP 29.1 22.9 52.0 32 9WAS Only THP 29.4 30.7 60.1 38 10

Post-Digestion THP 26.7 15.3 42.0 23 16

Intermediate THP 23.4 4.3 27.7 30 28

Full THP +

Incineration29.1 37.6 66.7 6 55

Page 18: Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen ...... | worldwide Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen Transfer: Elements of a Roadmap to Sustainable

Co-digestion maximizes use of existing assets –

potential for net positive energy condition!

• Fats, oil & grease (FOG)

• Food industry wastes

• Organic fraction of municipal

solid waste (OFMSW)

• Animal Manures

Page 19: Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen ...... | worldwide Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen Transfer: Elements of a Roadmap to Sustainable

Energy recovery/generation: The key to neutrality and

beyond

19

F. Wayne Hill Water

Resources Center

Solids processing Point Loma WWTP -1.35 MW

San Diego, CA (90 ft)

Hydropower

Effluent Heat Recovery Wind Turbines

ACUA WWTP, NJ - 7.5 MW

Solar Panels

Rogers Rd. WWTP, AZ – 1.1 MW

Page 20: Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen ...... | worldwide Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen Transfer: Elements of a Roadmap to Sustainable

MABR = Membrane Aerated Biofilm Reactor

• Bundles of hollow fibre gas permeable

membranes through which air (or oxygen) is

passed

• “Bubbleless” aeration – biomass directly

grows on membrane surface

• Technology that can be easily installed in

existing bioreactors to:

– Improve oxygen transfer efficiency and

reduce energy(3-4 times diffused aeration)

– Increase secondary treatment capacity

– Improve biological treatment performance

(e.g. ammonia removal)

Page 21: Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen ...... | worldwide Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen Transfer: Elements of a Roadmap to Sustainable

Desktop evaluation suggests significant

benefits of a MABR retrofit at Ejby Mølle

• 40% reduction in energy consumption in BNR process

• 45% increase in achievable peak flow secondary clarifier

capacity

• 20% reduction in annual nitrogen mass discharged

• 5% increase in biogas production due to lower SRT

operation

Page 22: Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen ...... | worldwide Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen Transfer: Elements of a Roadmap to Sustainable

Demonstration testing with full-scale units aimed at answering

several key questions for full scale implementation

• Biofilm management

– Is stuff going to get stuck?

– Is screening material an issue?

– What impact does mixing intensity and

scour have on performance?

• Taking advantage of the unique biofilm

– Shortcut nitrogen removal?

– Impacts on N2O emissions

• Response to dynamic flows and loads

Page 23: Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen ...... | worldwide Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen Transfer: Elements of a Roadmap to Sustainable

In and out of basin configuration allows testing

MABR for different goals

Effluent

RAS

Primary Effluent

MABR module

Zone 1 RAS Fermentation

Zone 2

Zone 3

Zone 4

Effluent

RAS

Primary Effluent

Zone 1 RAS Fermentation

Zone 2

Zone 3

MABR Zone

Page 24: Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen ...... | worldwide Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen Transfer: Elements of a Roadmap to Sustainable

In-basin MABR testing

• One of each manufacturer

in Zone 4

• Testing goals: biomass

accumulation, material

clogging (if any), O2

transfer rate

• Removal every 4 to 6

months for inspection

Page 25: Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen ...... | worldwide Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen Transfer: Elements of a Roadmap to Sustainable

Parallel MABR testing out of basins

• Specific rate testing

• Diurnal variation

impacts

• Flow fed at ~1% of total

influent flow

• N2O emissions

• Removal every 4 to 6

months for inspection

Page 26: Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen ...... | worldwide Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen Transfer: Elements of a Roadmap to Sustainable

MABR Demonstration Study – Collaborative

effort from key partners

Page 27: Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen ...... | worldwide Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen Transfer: Elements of a Roadmap to Sustainable

Some summary thoughts …

• Energy is only 2nd to labor in the cost of treatment/ reclamation of water

• After water, energy is the most cost-effective and environmentally beneficial

resource to be recovered in a C-constraint world

• Energy self-sufficiency (even net positive status) is possible with typical

“used” water

• Balancing nutrient removal, carbon management, energy conservation, and

energy production is key

• Carbon management through redirection is key in energy optimization

• Recent developments such as mainstream deammonification and MABRs

are now increasingly being considered to help utilities achieve external

energy independence

Page 28: Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen ...... | worldwide Nitrogen Shortcut, Carbon Redirection and Enhanced Oxygen Transfer: Elements of a Roadmap to Sustainable

www.jacobs.com | worldwide

Nitrogen Shortcut, Carbon Redirection and

Enhanced Oxygen Transfer: Elements of a Roadmap

to Sustainable Energy Independence

Julian Sandino, PE, PhD, BCEE, WEF & IWA Fellow

MWEA Joint Sustainable Energy & Process Seminar

Battle Creek, MI

October 17, 2018

Q & A