Outagamie County Landfill

S a m p l i ng a n d A n a l y s i s P l a n

Outagamie County Landfill

Prepared for

Outagamie County, Wisconsin 1419 Holland Road

Appleton, WI 54911-8985

July 2013

Suite 400

135 South 84th Street Milwaukee, WI 53214-1456

S a m p l i ng a n d A n a l y s i s P l a n


Submitted to

Outagamie County, Wisconsin

July 2013

ES081011134121MKE III

Contents

Section Page Contents .............................................................................................................................................. iii Acronyms and Abbreviations ....................................................................................................... vii 1 Introduction ......................................................................................................................... 1-1 2 Sampling and Analysis Procedures ................................................................................ 2-1

2.1 Onsite Activities ......................................................................................................... 2-1 2.2 Field Measurements .................................................................................................. 2-1 2.3 Analysis ....................................................................................................................... 2-1 2.4 Quality Assurance/Quality Control ....................................................................... 2-2

2.4.1 Laboratory Quality Assurance/Quality Control ..................................... 2-2 2.4.2 Field Quality Assurance/Quality Control ................................................ 2-2

2.5 Sample Custody ......................................................................................................... 2-4 2.6 Reports ........................................................................................................................ 2-4

2.6.1 Hard Copy Data and Reports ..................................................................... 2-5 2.6.2 Electronic Data Deliverable Reports .......................................................... 2-5 2.6.3 Data Management ........................................................................................ 2-6 2.6.4 Laboratory Limits of Detection/Limits of Quantitation ......................... 2-6

3 Private Wells Sampling and Analysis ............................................................................ 3-1 4 Groundwater Monitoring Wells Sampling and Analysis ......................................... 4-1

4.1 Sampling Procedure .................................................................................................. 4-1 4.2 Groundwater Monitoring Programs ....................................................................... 4-2

4.2.1 Baseline Monitoring ..................................................................................... 4-2 4.2.2 Detection Monitoring ................................................................................... 4-3 4.2.3 Assessment Monitoring ............................................................................... 4-3

5 Sedimentation Basin Sampling and Analysis .............................................................. 5-1 6 Gas Sampling and Analysis ............................................................................................. 6-1

6.1 Gas Probe Monitoring ............................................................................................... 6-1 6.2 Gas Monitoring in Buildings .................................................................................... 6-1

6.2.1 Onsite Buildings with Continuous Monitors............................................ 6-1 6.3 Gas Extraction System Monitoring ......................................................................... 6-2

6.3.1 Gas Collection Station .................................................................................. 6-2 7 Leachate Systems Sampling and Analysis .................................................................... 7-1

7.1 WDNR Leachate Sampling Requirements ............................................................. 7-1 7.1.1 Leachate Pump Station Sampling............................................................... 7-1 7.1.2 Leachate Level Measurements .................................................................... 7-2

7.2 Appleton WWTP Requirements .............................................................................. 7-2 7.3 Heart of the Valley Metropolitan Sewerage District Requirements ................... 7-3

8 Other Sampling ................................................................................................................... 8-1

SAMPLING AND ANALYSIS PLAN OUTAGAMIE COUNTY LANDFILL

IV ES081011134121MKE

Attachments

A Tables

1 Frequency of Monitoring and Reporting 2 Method, LOD, Bottle, and Preservation Requirements for Water Matrices 3 Laboratory QC Requirements 4 Reporting Requirements 5 Private Well Locations 6 Private Well Analytical List 7 Landfill Volatile Organic Compound List 8 Groundwater Monitoring Well Information 9 Groundwater Monitoring Wells Sampling Frequency for Group 1 and Subtitle D Wells 10 Baseline Monitoring Requirements for Groundwater Monitoring Wells 11 Detection Groundwater Monitoring Well Analytical List 12 Sedimentation Basin Sampling 13 Gas Probe Locations 14 Gas Extraction Well Sampling List 15 Annual Parameters to be Analyzed at the Inlet Pipe to the Gas Blower 16 Leachate Pump Station Analytical List 17 Base/Neutral and Acid Extractable Compounds 18 Locations for Monthly Leachate Level Measurements 19 Pesticide, Herbicide, and PCB Parameter List

B Figures 1 Groundwater Monitoring Network 2 Gas Monitoring Network 3 Leachate Monitoring Network C Field Operating Procedures 1 Equipment Calibration 2 Equipment Decontamination 3 Sample Custody 4 Private Well Sampling 5 Water Level and Leachate Level Measurements 6 Monitoring Well Sampling Procedure 7 Gas Probe Monitoring Procedure 8 Leachate Sampling Procedure D Reporting Formats 1 Groundwater Elevation Collection Form 2 Field Groundwater, Sedimentation Basin, and Leachate Monitoring Form 3 Field Gas Probe Monitoring Report Form 4 Example Outline for Analytical Reports

CONTENTS

ES081011134121MKE V

5 PAL/ES Exceedance Letter Format 6 Example of Summary Groundwater Report E WDNR-Approved Well-Specific PALs and ACLs F WDNR Reporting Environmental Monitoring Results Instructions

ES081011134121MKE VII

Acronyms and Abbreviations

ACL alternative concentration limit

BOD biochemical oxygen demand

the County Outagamie County

EC environmental consultant

ES enforcement standard

FOP field operating procedure

LOD limit of detection

LOQ limit of quantitation

MS matrix spike

MSD matrix spike duplicate

PAL preventive action limit

QA quality assurance

QC quality control

SA Sampling and Analysis

SAP Sampling and Analysis Plan

SB sedimentation basin

TSS total suspended solids

USEPA U.S. Environmental Protection Agency

VOC volatile organic compound

WDNR Wisconsin Department of Natural Resources

WWTP waste water treatment plant

ES081011134121MKE 1-1

SECTION 1

1 Introduction

Outagamie County Landfill is a municipal solid waste facility (License No. 2484) that serves surrounding residents, commercial establishments, and industries. Outagamie County (the County) has been operating the facility since 1976. The facility is located in Section 17, T21N, R18E, in the Town of Grand Chute and the Village of Little Chute, Outagamie County, Wisconsin. The primary contact information for the landfill is as follows:

Mr. Philip P. Stecker Director of Solid Waste Outagamie County Department of Solid Waste 1419 Holland Road Appleton, WI 54911-8985 Phone: 920-832-1521 Fax: 920-788-4130

This Sampling and Analysis Plan (SAP) describes the specific sampling practices and analytical protocols that shall be followed during groundwater, sedimentation basin, gas probe, building air, gas compressor, and leachate sampling at the Outagamie County Landfill. The sampling and analysis is being performed to comply with the Wisconsin Department of Natural Resources (WDNR) and local wastewater treatment plant monitoring requirements. The monitoring network designed for the Outagamie county landfill consists of existing monitoring wells that currently monitor the West Landfill, East Landfill, or Northeast Landfill. Currently, the East Landfill and the Northeast Landfill are open and operating.

In accordance with these requirements, private well, groundwater monitoring well, sedimentation basin, gas probe, gas compressor, and leachate pump station samples shall be routinely collected and analyzed (Table 1, Attachment A). Analysis of samples collected under this plan must be conducted by a WDNR-certified laboratory as defined in the Wisconsin Administrative Code, Department of Natural Resources Chapter NR 149. Sampling procedures must follow those cited in the Groundwater Sampling Desk Reference, WDNR Publication DG-037-96, September 1996, and Groundwater Sampling Procedures Field Manual, Wisconsin Department of Natural Resources, DG-038-96, September 1996.

This SAP contains five attachments:

Attachment A of this plan contains the tables.

Attachment B contains site figures.

Attachment C contains the field operating procedures (FOPs).

Attachment D contains the reporting formats for analytical data and analytical reports.

Attachment E contains WDNR-approved, well-specific preventive action limits (PALs) and alternative concentration limits (ACLs).


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Attachment F contains the instructions for electronic reporting of the data.

Questions regarding items presented in this SAP should be addressed to the County at the address on page 1-1 of this SAP.

Payment will be based on the actual quantities of work performed based on the unit prices set forth in the proposal. The number of sampling locations, types, and frequencies may vary because of pending regulatory agency approvals (PALs and ACLs) and other site conditions. Sampling activities not identified in this document may be required at the site over the contract period. WDNR, Heart of the Valley Metropolitan Sewerage District, Appleton Waste Water Treatment Plant (WWTP), the County’s environmental consultant (EC), or the County may request additional sampling to be conducted at the facility. These non-routine items cannot be identified for this document and will be addressed as requests are made.

ES081011134121MKE 2-1

SECTION 2

2 Sampling and Analysis Procedures

This section discusses the common sampling and analysis requirements for the private wells, groundwater monitoring wells, sedimentation basins, gas probes, building air, gas compressor, and leachate pump stations. The locations of the site groundwater monitoring wells and private wells are shown in Figure 1 of Attachment B. Leachate system risers, leachate pump stations, leachate head wells, and leak detection manholes are shown in Figure 2 of Attachment B. Gas probes are shown in Figure 3 of Attachment B. All groundwater sampling can be performed using either bailer or low-flow methods. Table 1 provides a summary of the sampling schedule.

2.1 Onsite Activities All field sampling personnel shall sign in every day at the Department of Solid Waste Office located at 1419 Holland Road upon arrival at the site.

The 450-acre facility may be accessed using all-terrain vehicles as long as the facility grounds are not damaged. The cost of repair of any facility ground damages resulting from environmental monitoring activities shall be the responsibility of the sampling and analysis (SA) Firm.

2.2 Field Measurements Field parameters (such as color, conductivity, odor, pH, oxidation reduction potential, turbidity, and temperature) to be measured at private wells, groundwater monitoring wells, sedimentation basins, gas probes, and leachate pump stations must be analyzed in the field. Analysis of field pH, conductivity, and oxidation reduction potential must be measured in situ (down well) or from a flow-through cell during low-flow purging/sampling of groundwater monitoring wells. All field instruments shall be calibrated according to the procedures in FOP 1, Equipment Calibration, found in Attachment C, and to specification as stated in the instrument manual. Field instruments should be calibrated at least once per day during monitoring activities. Field data and results are to be recorded on the appropriate Field Monitoring Report Form (Attachment D, Forms 1 through 3). Exact copies of the completed forms are to be provided as part of the analytical report. Reporting formats are discussed later in this section.

2.3 Analysis Water samples (that is, from groundwater, leachate, and the sedimentation basins) shall be analyzed by a Wisconsin-certified laboratory using the methods referenced in Table 2. In order to obtain data of sufficient quality and with low enough detection limits, only the methods in Table 2 shall be allowed. The procedures for calculating and reporting limits of detection (LODs) and limits of quantitation (LOQs) should be obtained from the WDNR


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guidance Analytical Detection Limit Guidance and Laboratory Guide for Determining Method Detection Limits (PBL-TS-056-96).

For all aqueous volatile organic compound (VOC) samples, a purge and trap extraction (U.S. Environmental Protection Agency [USEPA] Method 5030B) shall be used. Except for private wells (which use Methods 504 and 524), VOC analyses shall be completed using USEPA Solid Waste Method 8260B, as described in Test Methods for Evaluating Solid Waste, Third Edition, November 1986, with revisions in December 1987, November 1990, July 1997, and April 1998 (USEPA document SW-846). To allow for reanalysis for validation of initial results, the laboratory shall implement laboratory procedures to ensure that sufficient VOC sample volume is retained in a secure, uncompromised manner for subsequent analysis.

If sample hold times are exceeded, resampling and analysis shall occur at no expense to the County.

2.4 Quality Assurance/Quality Control Quality assurance/quality (QA/QC) control implementations are discussed in the following subsections.

2.4.1 Laboratory Quality Assurance/Quality Control Laboratory QC requirements must follow those outlined in NR 149, Section 149.14, of the Wisconsin Administrative Code. Table 3 contains a summary of the required laboratory QC for the parameters analyzed at Outagamie County Landfill.

2.4.2 Field Quality Assurance/Quality Control A brief definition of the field QC sampling requirements is presented in the following subsections.

Equipment Blanks An equipment blank is a sample of reagent-grade water that is processed through the sampling equipment in the same manner as the actual well sample to assess whether field sampling and equipment cleaning procedures are adequate. The equipment blanks should be collected and analyzed for the same analytical parameters as the field samples. Contaminants should not be detected in the equipment blanks. If contaminants are detected, a judgment on the validity of that day’s samples must be made by the laboratory in consultation with the County. Equipment blanks shall be taken at a minimum of 1 blank per sampling round or 1 every 10 samples, whichever is more frequent. Equipment blanks are not required if you use dedicated sampling equipment or disposable sampling equipment, but are recommended during sampling of VOCs in groundwater. The equipment blank sampling results must be recorded and reported on the field monitoring report form. Equipment blanks shall be collected in association with both private and groundwater monitoring well sampling.

Equipment blanks are not required for leachate, sedimentation basin, or gas blower inlet pipe samples.

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Field Duplicates A field duplicate is a sample taken to assess precision in the sampling and analytical procedures. Field duplicates shall be collected at a frequency of 1 per sampling round or 1 for every 10 field samples collected, whichever is more frequent. At a minimum 1 field duplicate sample will be collected during each sampling event (every sampling mobilization). The samples must be collected and processed using the same procedures used for the regular samples. Field duplicate analysis data and results must be recorded on the field monitoring report forms. Field duplicates shall be collected as part of the private well, groundwater monitoring well, sedimentation basin, leachate pump station, and gas blower inlet pipe sampling and analysis.

Leachate and sedimentation basin field duplicate samples shall be collected twice per year (does not need to coincide with May and November annual and semi-sampling events). A duplicate gas sample will be collected during the annual sampling event at the inlet to the gas blower.

MS and MS Duplicates Matrix spikes (MSs) and MS duplicates (MSDs) are laboratory QC samples that are performed on field samples. MSs and MSDs are included in the laboratory QC table (Table 3) and are described below.

An MS is an intra-laboratory spike of a sample obtained from the site with a known concentration of target analytes. An MS shall be performed for all parameters, with the exception of chemical oxygen demand, biochemical oxygen demand (BOD), total suspended solids (TSS), alkalinity, and the parameters measured in the field. The spiking occurs before sample preparation and analysis. An MS is used to document analytical accuracy, given the bias of the sample matrix. Samples from the site for MS analysis shall be collected at a frequency of 1 per sampling round or 1 for every 20 field samples collected, whichever is more frequent. Samples from the site for MS analysis must be collected and processed using the same sample procedures used for the regular samples. Samples from the site for MS analysis will be collected with private well and groundwater monitoring well samples. MSs are not required for sedimentation basin or leachate sampling.

An MS duplicate is an additional sample volume to that of the MS sample that is also spiked with a known concentration of target analytes. The spiking occurs before sample preparation and analysis. An MS duplicate shall also be performed for all parameters, with the exception of chemical oxygen demand, BOD, TSS, alkalinity, and the parameters measured in the field. The MS duplicate is used to document analytical precision and accuracy, given the bias of the sample matrix. Samples from the site for MSD analysis shall be collected at a frequency of 1 set per sampling round or 1 set for every 20 field samples collected, whichever is more frequent. At a minimum, 1 sample for MSD analysis will be collected during each sampling event (every sampling mobilization). Samples from the site for MSD analysis must be collected and processed using the same sample procedures used for the regular samples. Samples from the site for MSD analysis will be collected with private well and groundwater monitoring well samples. MSDs are not required for sedimentation basin, leachate, or gas blower inlet pipe sampling.


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Trip Blanks Trip blanks are used to detect VOC cross-contamination during sample shipping and handling. Trip blanks are filled at the laboratory, transported to the sampling site, and returned to the laboratory with the associated samples. Trip blanks are not opened in the field. The frequency for trip blanks is one trip blank per shipment containing water or gas samples for VOC analysis. A trip blank shall be included with water samples collected for VOC analysis or with gas samples collected at the inlet pipe to the gas blower.

Trip blanks to be included with water samples are 40-milliliter VOC vials of American Society for Testing and Materials Type II water.

Trip blanks to be included with gas samples are canisters filled with nitrogen gas.

Decontamination Procedures Decontamination of sampling and monitoring equipment will follow the procedures presented in FOP 2, Equipment Decontamination. The potable water to be used in all equipment decontamination can be obtained from a public water supply system located at the mobilization area.

2.5 Sample Custody Sample custody including sample labeling, chain-of-custody procedures, and transport should be performed as indicated in FOP 3, Sample Custody.

2.6 Reports Final reports must be submitted to the County’s EC in hard copy and electronic form (using WDNR format for all data, including data not required by WDNR) as indicated in Tables 1 and 4. Although the reporting requirements to WDNR are specified in Table 4, the analytical laboratory will not perform direct reporting to WDNR. WDNR-required analytical reports shall be submitted to the County’s EC in hard copy and electronic form within 40 business days after the last day of the sampling period. A sampling period means the month in which a sample is collected. For the sedimentation basin monitoring and leachate level monitoring, multiple sample events are performed within a reporting period. For these cases, the results shall be submitted to the County’s EC 40 business days after the last sampling period from the last sampling event. For example, the sedimentation basin is monitored monthly, but the results are submitted quarterly. The sedimentation basin results shall be submitted 40 business days after February, May, August, and November. Leachate monitoring results for the Appleton WWTP and Heart of the Valley Metropolitan Sewerage District shall be submitted to the County and the County’s EC according to Table 4.

The County’s EC will perform an initial and/or final review of the data before WDNR submittal, except where noted in Table 4. Errors, mistakes, omissions, and formatting issues found on the initial data report submittal will be identified and reported to the laboratory by the County’s EC. These issues must be corrected in the reports and resubmitted as final to the County’s EC within 5 business days of receipt of the corrections to be made. If a report is resubmitted to the County’s EC with an error or mistake that was not corrected

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ES081011134121MKE 2-5

and that was identified by the County’s EC to be corrected during the first review, a $100 fee will be assessed on the submittal. This fee incorporates additional consultant costs incurred by the County for the subsequent review. In addition, late submittals to the County’s EC will be assessed a penalty of $100 per business day.

The County’s EC will coordinate the submittal of final reports, except where noted in Table 4. The laboratory will submit the required number of final hard copy reports and electronic deliverables to the County’s EC. A summary of the number of reports, types, and due dates is presented in Table 4.

2.6.1 Hard Copy Data and Reports An outline of the general format to be used in the analytical hard copy reports is presented in Attachment D, Form 4. The reports must include, but not be limited to, the following items:

Exact copies of the field monitoring report forms. The forms (Attachment D, Forms 1 through 3) are to contain, at a minimum, the sampling date and time, general observations and weather conditions, sampler’s initials, and the field measurement data and results.

Copies of the chain-of-custody forms.

Analytical results, including results for associated field blanks, laboratory blanks, instrument blanks, reagent blanks, field duplicates, laboratory duplicates, MS samples, MSD samples, and any known standard spikes.

LOD and LOQ for all parameters except field parameters and groundwater elevation values.

If the PALs or enforcement standards (ESs) are exceeded in private well or groundwater monitoring well samples, the County’s EC must be immediately notified because additional sampling and analyses may need to be performed.

As part of the hard copy reporting requirements, exceedances of PALs, ESs, and ACLs must be tabulated for groundwater monitoring well and private well data (NR 140 and Attachment E). Well-specific standards (PALs and ACLs) listed in Attachment E supersede the standards (PALs and ESs) listed in NR 140. The tabulation of the PAL, ES, and ACL exceedances must be contained in an exceedance letter in the format shown in Form 5. The cause and significance of each PAL/ES exceedance need not be addressed in the exceedance letter. The exceedances will be addressed by the County’s EC, with input from the laboratory, in an annual Summary Groundwater Monitoring Report. An example of the format used for tabulating analytical groundwater data for the annual Summary Groundwater Monitoring Report is shown in Form 6. Data submissions to the County’s EC must be accompanied by an Environmental Monitoring Data Certification form as shown in Attachment F.

2.6.2 Electronic Data Deliverable Reports All data must be provided on a CD-ROM and comply with WDNR Reporting Environmental Monitoring Results Instructions (Attachment F). A signed Groundwater Monitoring Data Certification Form (Attachment F) shall be included with each WDNR electronic deliverable. The County’s EC shall be responsible for ensuring that the most


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recent version of the data certification form is being used. In addition to WDNR sample results, electronic deliverable reports shall be submitted to the County’s EC for all other sampling performed at the facility (that is, Appleton WWTP requirements, Heart of the Valley Metropolitan Sewerage District, and County-implemented sampling). The electronic data deliverables for non-WDNR-required sampling should be formatted according to WDNR requirements (Attachment F).

2.6.3 Data Management All raw data must be retained for a period of time in accordance with state requirements, or a minimum of 5 years, whichever is longer. The data shall be made accessible to Outagamie County upon request. The laboratory shall transfer all project-related data to Outagamie County upon completion of the project.

2.6.4 Laboratory Limits of Detection/Limits of Quantitation The procedures for calculating and reporting LODs and LOQs should be obtained from the WDNR guidance Analytical Detection Limit Guidance and Laboratory Guide for Determining Method Detection Limits (PBL-TS-056-96).

ES081011134121MKE 3-1

SECTION 3

3 Private Wells Sampling and Analysis

The private wells (listed in Table 5 and shown in Figure 1) should be sampled and analyzed in May of each year. Samples are to be collected in accordance with Chapter 3 of the Groundwater Sampling Desk Reference, Wisconsin Department of Natural Resources, Publication DG-037-96, September 1996 and FOP 4, Private Well Sampling. The samples are not to be filtered and should be taken directly out of a faucet. Tables 6 and 7 provide the private well analytical parameter list. Private well samples shall not be shipped in the same batch with leachate samples. Private well owners are to be notified at least 48 hours in advance that their well is to be sampled. All reasonable efforts shall be made to accommodate the residences’ requested sampling times. Private well results are to be sent to the respective private well owners listed in Table 5. Draft copies of the private well documentation shall be sent to the County’s EC before being sent to each owner.

One private well, PW-003 (WDNR No. 81), is infrequently used and should be purged by purging the well for 30 minutes prior to sampling. During purging, a hose should be used to prevent drainage of water back to the well or pooling of water around building foundations. The hose should be long enough to divert water to the nearest drainage ditch.

VOC detections in private wells shall be automatically verified by the laboratory within 1 day of VOC analysis and the results reported to the County and County’s EC within 1 week of the VOC analysis. At the discretion of the County, the County may request resampling of the private wells with VOC detects within 15 calendar days of original analysis.

ES081011134121MKE 4-1

SECTION 4

4 Groundwater Monitoring Wells Sampling and Analysis

There are 128 groundwater monitoring wells at Outagamie County Landfill. Several different types of groundwater sampling programs may be occurring at the same time at the facility, and include routine semiannual sampling performed at the majority of the wells, baseline sampling for new and replacement wells, and assessment monitoring required for confirmed exceedances at Subtitle D wells. Each groundwater sampling program is described in Section 4.2 and well construction details are presented in Table 8.

Some wells may likely be purged dry because of the fine-grained nature of the soils beneath the facility. Intermediate wells (depths of 30 to 40 feet below ground surface) are most frequently observed to have dry conditions or produce low volumes of recoverable groundwater. A well would be considered dry (reported as WDNR Parameter Code No. 00006), if the well is accessed and no water is present within the casing or screen zone at the time of water level measurement. For slow recovering wells that purge dry, ample time for water recovery should be allowed before collecting samples. For the slow-recovering wells, the water level should be checked every 24 hours for at least 3 days to determine if water recovery is sufficient for sample collection. During routine monitoring, if groundwater recovery is insufficient for sample collection after 72 hours, the well can be declared as unable to be sampled (reported as WDNR Parameter Code No. 00007) and precluded from sampling until the next scheduled round. During baseline monitoring, the well must be sampled (provided the well was not originally dry) in order to provide baseline data, so the well should be revisited daily for up to 3 days until enough water can be collected for samples. If only partial total sample volume is available by the third day, then sample collection should be prioritized in this order: (1) VOCs, (2) conventional/ general chemistry parameters, and (3) dissolved metals.

All monitoring wells have been clearly marked with permanent identification information. Markings on any wells that do not remain clear must be reported to the County and the County’s EC. The marking shall include common well names, as well as WDNR well numbers. The conditions of each well, including damages, shall be noted (Attachment D—Form 2) during each sampling event and should be sent to the County and County’s EC.

4.1 Sampling Procedure Monitoring wells may be sampled using either bailer or low-flow methods. Samples are to be collected in accordance with FOPs 5 and 6, Water Level Measurements and Monitoring Well Sampling Procedure. For wells sampled using low-flow methods, sampling should begin immediately upon stabilization of field parameters (FOP 6). For wells sampled using the bailer method, sampling should begin on the same day as purging, provided recharge rates are ample (static water level recovers within hours). In the case of wells where


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recharge rates are on the order of days, the water level should be checked every 24 hours for at least 3 days to determine if water recovery is sufficient for sample collection.

After sampling each well, all non-dedicated and non-disposable equipment including water level measurement equipment, purging devices, sampling devices, and filtration devices will be decontaminated according to Chapter 2, Sections 8 and 10, Groundwater Sampling Desk Reference, WDNR Publication DG-037-96, September 1996.

Should any monitoring wells become impacted by landfill activities, the wells across the landfill should be sampled from background or “least impacted” to “most impacted.” If multiple impacted wells are present, then they should also be sampled in a sequence from “least impacted” to ”most impacted,” determined from the groundwater concentration from the most recent round of sampling. VOCs are consistently detected in the following wells and should be sampled last: P-9C (022), OW-307B (104), OW-317A (137), OW-318A (138), and P-705B (242).

4.2 Groundwater Monitoring Programs The locations of the groundwater monitoring wells are shown in Figure 1. There are three separate but interrelated monitoring programs with various objectives that will be performed for Outagamie County Landfill wells and one potential sampling program including:

Detection monitoring per NR 507.19 for Group 1 and Subtitle D wells Semiannual monitoring for Group 2 wells Baseline monitoring per NR 507.18 for newly installed or replacement wells Assessment monitoring for Subtitle D wells per NR 508.05

The wells included in each program are specified in Table 9 and more specific requirements for each program are described in the sections that follow. Note that, on a sitewide basis, six monitoring wells have been designated as Subtitle D wells per federal compliance requirements.

4.2.1 Baseline Monitoring All new and replacement wells must be sampled for the parameters listed in Table 10, per NR 507.18. If a new or replacement well is designated as a Subtitle D well, the well must be sampled and analyzed for six additional metals as indicated in Table 10. Baseline monitoring is required to be performed on new and replacement wells prior to entering the detection groundwater monitoring program.

Some of the existing Northeast Landfill wells need to complete monthly baseline monitoring. Five monitoring wells shown in Table 9 (P-801C [272], P-802C [252], P-1011B [258], P-1011C [259], and P-1015D [271]) have not initiated monthly baseline monitoring due to consistently dry conditions at these locations. Baseline monitoring for the Northeast Landfill wells will be performed and reported monthly for the parameters and number of rounds specified in Table 9. Additional baseline sampling on a monthly basis may be necessary if exceedances of PALs and ESs are observed during baseline monitoring rounds of some parameters per NR 507.18. Upon completion of baseline sampling at a given well, the

SECTION 4—GROUNDWATER MONITORING WELLS SAMPLING AND ANALYSIS

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new and/or replacement wells will be incorporated into the detection groundwater monitoring program.

4.2.2 Detection Monitoring Once a well has completed all the required rounds of baseline monitoring per NR 507.18, it will enter the detection monitoring program per NR 507.19. The Subtitle D compliance wells and Group 1 wells must be sampled and analyzed semiannually in May and November (Table 1 and Table 9) of each year for inorganic and field parameters (Table 11).VOCs (Table 7) will be analyzed semiannually at Subtitle D wells and annually in May at Group 1 wells.

Group 2 wells listed in Table 9 must be monitored for groundwater elevation (WDNR Parameter No. 04189) semiannually (May and November), and analyzed for field conductivity, corrected to 25 degreesCelsius (WDNR Parameter No. 00094) annually (May). The Group 2 wells shall be purged of at least one well volume of groundwater before monitoring for field conductivity.

4.2.3 Assessment Monitoring Assessment monitoring may be required by WDNR at the site if exceedances of WDNR PALs, ESs, or ACLs are confirmed in Subtitle D wells and cannot be attributed to natural conditions per NR508.05. The County’s EC will notify the laboratory when assessment monitoring is required. For the first sampling round of assessment monitoring, all of the Subtitle D groundwater monitoring wells (Table 9), the leachate lift stations for the East Landfill (EPS-1 and EPS-2), and the leachate lift stations for the Northeast Landfill (PB-1, PB-2, and PB-3) shall be sampled for the parameters listed in Appendix II of NR 507. The parameter list for subsequent rounds of assessment monitoring will be supplied by the County’s EC, if needed. At present, no assessment monitoring has been required of the Outagamie County Landfill.

Assessment monitoring samples being analyzed for metals must be obtained using a low-flow sampling technique (FOP 6, Monitoring Well Sampling Procedure).

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SECTION 5

5 Sedimentation Basin Sampling and Analysis

A monthly sample must be collected from each of the two onsite sedimentation basins (SBs) for the Outagamie County Landfill. The sampling locations include SB-1 (651), which is located south of the West Landfill, and SB-2 (652), which is located south of the East Landfill.

Sampling should be performed when there is active discharge, whenever possible. This is generally during the spring, summer, or fall. For SB-1 (251), the sample shall be collected at the end of the discharge basin. The sample for SB-2 (652) shall be collected near the discharge end of the basin at a distance of 10 feet from shore. When sampling cannot be performed during active discharge (typically winter months), then the sample should be collected at one-third the depth of the water column. For example, if the water is 9 feet deep, then the sample should be taken from 3 feet below the surface.

Discharge structures will be inspected each month, and field sheets should indicate whether or not there is active discharge, the amount of precipitation in the previous 24 hours, and the status of the basin water (that is, frozen or debris). A boat or raft will be used to access the sampling location (to minimize mixing of the bottom sediments and the water column). It is the responsibility of the SA Firm to provide the floatation device for sample collection. The sedimentation basin will be sampled and analyzed for the parameters in Table 12. A field duplicate must be collected and analyzed from one of the two locations twice per year (does not need to coincide with May and November annual and semi-sampling events). The results for all parameters must be submitted monthly to the County and County’s EC in hard copy, and quarterly to the County and County’s EC electronically. The results for TSS must be reported quarterly to the WDNR.

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SECTION 6

6 Gas Sampling and Analysis

Gas monitoring will require instruments able to provide the information requested. Unless otherwise specified, a LANDTEC GEM 500 or GEM 2000 portable gas meter will be used. These are industry standard instruments adequate to accomplish the required gas monitoring.

6.1 Gas Probe Monitoring The gas probe locations are listed in Table 13 and shown in Figure 3. Gas probes shall be sampled quarterly for the parameters in Table 14, and according to FOP 7, Gas Probe Monitoring Procedure. A LANDTEC GEM 500 or GEM 2000 shall be used to determine the percent methane, percent oxygen, and probe (soil) gas pressure. Meteorological data shall either be gathered onsite (if available), or may be gathered from data observations taken at the Outagamie County Regional Airport (KATW) during the same time period as the monitoring event. Collecting this data will, at a minimum, meet the requirements of NR 507.22(1)(a).

At each gas probe, monitoring shall be performed at the sample port top. The monitoring instrument shall be connected to the sample port, and the port shall be opened. Prior to purging the gas probe, the initial probe gas pressure shall be recorded. The probe shall then begin to be purged and an initial methane reading shall be taken. The probe shall continue to be purged until a stabilized methane reading is detected, or until the methane concentration drops to zero, at which time the value shall be recorded. The probe oxygen concentration shall also be recorded when the methane reading stabilizes or reaches zero. The gas probe sampling valve shall then be closed prior to disconnecting the instrumentation.

As discussed above, the initial and stabilized methane levels shall be measured and recorded. Initial readings are not required to be submitted to the WDNR unless the stabilized reading for a particular monitoring point drops to zero. Gas probe sample results from the sample port top shall be reported quarterly to the WDNR.

6.2 Gas Monitoring in Buildings The buildings requiring gas monitoring are shown in Figure 2. The results shall be submitted to WDNR annually by the County’s EC.

6.2.1 Onsite Buildings with Continuous Monitors The following four buildings (followed by their WDNR number) have continuous methane monitors (Figure 2):

B-1 (790) Service Building (on West Landfill Site, north of Cell 10)

B-3 (792) Landfill Gas Compressor Building (on West Landfill Site, southwest of Cell 10)


6-2 ES081011134121MKE

B-10 (795) Landfill Gas Cogeneration Facility (south of East Landfill Site)

B-11 (796) Service Building (on Northeast Landfill Site)

The monitors in these buildings are alarm only. The alarm history for the respective quarter shall be obtained from the County’s records by the SA Firm. Methane data, date, and time shall be summarized for each quarter and submitted to WDNR annually (by the County’s EC).

6.3 Gas Extraction System Monitoring The gas extraction system monitoring is discussed in the following subsections.

6.3.1 Gas Collection Station Daily monitoring (flow rate, vacuum, methane, and oxygen) is collected at the landfill gas collection station WDNR No. 775 (formerly known as the Gas Compressor System). The data is currently gathered at the main gas header line leading to the Outagamie Clean Energy Project, LLC, facility, which purchases the landfill gas for combustion in three engine/generator systems used to produce electricity.

The collection station landfill gas data is collected on a continuous basis (that is, 3-minute intervals) by the County. The data is collected using inline thermal mass flowmeters and an onsite gas chromatograph. The data shall be obtained by the SA Firm and tabulated for two dates each month (approximately the 1st and 15th of the month) for the parameters indicated in Table 14. The results from the landfill gas collection station shall be submitted to WDNR each quarter.

The landfill gas entering the compressor system (by the inlet pipe to the gas blower) shall be sampled and analyzed annually for the compounds listed in Tables 7 and 15. Sampling and analysis shall be performed in accordance with USEPA Method 3C and USEPA method 18 (40 CFR 60).

While the gas collection station is running, an evacuated sampling canister shall be connected to the sampling port with Teflon tubing. The sampling port shall be opened, and the canister valve slowly opened. The canister shall be filled over an approximately 30- to 60-second time period. After sampling is complete, the canister valve shall be closed. A sample shall be collected for mercury analysis through the use of a single gilded silica sorbent tube in accordance with laboratory sampling procedures. As indicated in Table 14, barometric pressure, ambient temperature, source temperature, sample flow rate, and time shall also recorded at the time of sampling.

Quality assurance/QC samples for gas collection station monitoring shall include a trip blank and a site blank. A duplicate gas sample will also be collected during the annual sampling event at the inlet to the gas blower.

All parameters listed in Table 14 should be reported quarterly to the County, the County’s EC, and the WDNR. The sample parameters listed on Table 17 should be reported annually to the County and the County’s EC. Only VOCs listed in Table 7 shall be reported to WDNR annually by the County’s EC. WDNR parameter identifications for gas shall be used for reporting as indicated in Table 15.

ES081011134121MKE 7-1

SECTION 7

7 Leachate Systems Sampling and Analysis

This section presents the leachate sampling and analysis requirements resulting from WDNR’s requirements and the requirements established by the City of Appleton and the Heart of the Valley Wastewater Treatment Facilities. The leachate monitoring system locations are shown in Figure 2. Table 16 shows the leachate pump station sampling schedule and analytical parameters to be collected. The table incorporates requirements from the WDNR, Appleton WWTP, Heart of the Valley Metropolitan Sewerage District, the County, and the County’s EC. Redundant, unnecessary sampling and analysis will not be compensated by the County.

Six leachate pump stations are present at the Outagamie County Landfill, as shown in Figure 2. Leachate pump stations and composite samples are also presented below.

Common Name WDNR No. or Equivalent Description

WPS-1 218 West Landfill Pump Station

EPS-1 124 East Landfill Pump Station-South

EPS-2 125 East Landfill Pump Station-North

EPS-1 & EPS-2 C50 East Landfill Composite

PB-1 400 Northeast Landfill Phase 1 Pump Station



PB-1 & PB-2 C51 Northeast Landfill Composite

PB-1 & PB-2 & PB-3 C52 Northeast Landfill Composite a The anticipated leachate collection for PB-1 is 1 year from date of the NE Landfill opening, PB-2 is 4 years, PB-3 is 7 years.

b Once leachate collection begins from PB-1 and PB-2, and later, PB-1, PB-2, and PB-3, a composite sample (equal amounts from each PB-1, PB-2, and PB-3) shall be collected and analyzed for the parameters indicated in Table 16.

7.1 WDNR Leachate Sampling Requirements The WDNR leachate sampling requirements are discussed in the following subsections.

7.1.1 Leachate Pump Station Sampling Leachate pump stations in the Outagamie County Landfill are to be sampled and analyzed in accordance with WDNR requirements provided in Tables 16, 17, and 7. Samples are to be collected in accordance with FOP 8, Leachate Pump Station Sampling. Sampling must be performed when surface water is not being collected by the leachate system. The pump stations include sampling spigots. Leachate samples shall be taken from the spigots. The spigot line shall be purged for several minutes and the sample collection jars rinsed with leachate before sampling. If the pump station spigots are not operable, then the leachate


7-2 ES081011134121MKE

pump station valve vaults will be opened, and the leachate will be collected manually using a bailer (as described in FOP 6) or a bucket.

Leachate volume (WDNR No. 00056) collected from West, East, and Northeast Landfills will be recorded by a digital flow meter, tabulated on a monthly basis, and will be reported to WDNR on a semiannual basis. The semiannual parameters are to be sampled and analyzed in May and November, while the annual parameters are to be sampled for and analyzed in May.

Laboratory QA/QC performance shall be in compliance with the requirements listed in Table 3, and field QA/QC samples shall be collected in accordance with the QA/QC section of this SAP.

7.1.2 Leachate Level Measurements In addition to the leachate pump station sampling, leachate head elevation (WDNR No. 00023) and depth to leachate (WDNR No. 00031) shall be measured monthly in accordance with FOP 5, Water Level and Leachate Level Measurements, from the locations from the East Landfill and Northeast Landfill noted in Table 18 and reported annually to WDNR by the County’s EC. No monthly leachate level measurements are required for the West Landfill, as all manholes have been capped and sealed.

7.2 Appleton WWTP Requirements The West Landfill leachate discharges to the Appleton WWTP. Leachate samples shall be obtained from the West Landfill Lift Station (WDNR No. 218) and analyzed for the parameters listed in Table 16 at the frequency indicated. Laboratory QA/QC shall comply with the requirements listed in Table 3. No field QA/QC samples will be collected as part of the Appleton WWTP sampling. The semiannual parameters are to be sampled and analyzed in May and November. The annual parameters are to be sampled and analyzed in May.

Monthly reports with BOD, TSS, and pH results shall be submitted directly to each party (Appleton WWTP, the County, and the County’s EC) by the 10th day of the month after the sampling period. Semiannual and annual results should be submitted in compliance reports directly to each party by June 15 and December 15 for all parameters listed in Table 16 for the West Landfill Lift Station.

Copies of periodic compliance report forms can be obtained from the Pretreatment Coordinator at the address below.

City of Appleton Pretreatment Coordinator 2006 East Newberry Street Appleton, WI 54915-2785 Phone: (414) 832-5945

The SA Firm will send the reports directly to each party. Hard copy reports are required for Appleton WWTP, the County, and the County’s EC. Electronic reports are required for the County and the County’s EC semiannually.

Each report shall contain the following:

SECTION 7—LEACHATE SYSTEMS SAMPLING AND ANALYSIS

ES081011134121MKE 7-3

The date, exact place, time, and methods of sampling or measurements, and sample preservation techniques or procedures

The name of the person performing the sampling or measurements

The date(s) analyses were performed

The name of the person performing the analyses

The results of the analyses

Reports shall include the following certification statement and be signed:

“I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquire of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations.”

The SA Firm will be assessed a penalty of $100 per business day by Outagamie County for late submittals to the City of Appleton.

7.3 Heart of the Valley Metropolitan Sewerage District Requirements

The East Landfill and Northeast Landfill leachate discharges to the Heart of the Valley Metropolitan Sewerage District. Composite samples from the East Landfill (EPS-1 and EPS-2) shall be sampled and analyzed for the parameters listed in Table 16 at the frequency indicated. Once leachate begins to collect from PB-2 and PB-3, a Northeast Landfill composite sample (equal amounts from each PB-1, PB-2, and PB-3) shall be collected and analyzed at the frequency indicated in Table 16.

For both the East and Northeast leachate composite samples, a priority pollutant scan (parameters indicated on Table 16) shall be completed once per permit period (every 3 years). For all semiannual sampling, a 24-hour composite shall be grabbed for metals and cyanide (Table 16); base and neutral and acid extractable compounds (Table 17); and BOD, TSS, phosphorus, pesticides/ herbicides/ polychlorinated biphenyls (Table 19). As approved by the Heart of the Valley Metropolitan Sewerage District, the 24-hour composite can be collected by pumping the levels down in each lift station and turning off the pumps. Leachate shall be allowed to collect in each lift station 24 hours before sampling. The sampling shall be done during a period of no rainfall. The County shall be contacted to coordinate the shutdown of the lift stations. A grab sample shall be collected for pH and VOCs.

The semiannual parameters are to be sampled and analyzed in February and August by the SA Firm. Heart of the Valley Metropolitan Sewerage District will perform sampling in


7-4 ES081011134121MKE

May and November. A priority pollutant scan is required once during the length of the permit. A priority pollutant scan shall be coordinated with other sampling events to minimize duplication of analysis.

The leachate sample results shall be reported to the Heart of the Valley Metropolitan Sewerage District. Laboratory QA/QC shall comply with the requirements listed in Table 3. Field QA/QC samples will be collected as part of the Heart of the Valley Metropolitan Sewerage District sampling.

Semiannual periodic compliance reports shall be submitted directly to each party (Heart of the Valley Metropolitan Sewerage District, the County, and the County’s EC) within the calendar quarter.

Copies of periodic compliance report forms can be obtained from the Director of Public Works at the address below:

Director of Public Works Village of Little Chute 109 West Main Street Little Chute, WI 54140 Phone: (920) 788-7395

The SA Firm will submit the hard copy reports required for Heart of the Valley Metropolitan Sewerage District, Village of Little Chute, the County, and the County’s EC. Electronic reports are required for the County and the County’s EC semiannually.

The SA Firm will be assessed a penalty of $100 per business day by Outagamie County for late submittals to Heart of the Valley Metropolitan Sewerage District.

ES081011134121MKE 8-1

SECTION 8

8 Other Sampling

The County’s EC requires that BOD, TSS, and pH analyses be performed on each lift station (EPS-1, EPS-2, PB-1, PB-2, and PB-3) of the East and Northeast Landfills at the same frequency (quarterly) that the parameters are collected for East and Northeast composite samples for Heart of the Valley Metropolitan Sewerage District requirements. Semiannual phosphorus shall be analyzed for each lift station, and TSS shall be analyzed for both the East and Northeast composite samples. The County also requires monthly copper analysis for the West Landfill composite sample (WPS-1). Requirements of the County are summarized in Table 16. The results shall be submitted semiannually in electronic and hard copy format to the County and to the County’s EC.

Attachment A

Tables

TABLE 1Frequency of Monitoringa and Reportingb

Outagamie County Landfill - 2013 SAP

Private Wells

Groundwater Wells

SedimentationBasins

Gas Probes

Building Airc

Gas Collection Stationc

Annual Landfill

Gas Sample

LeachateLevel

Measurements

Leachate Pump

Stations (WDNR)

Leachate Pump

Station (Appleton

WWTP)

Leachate Pump

Stations (Heart of the Valley MSD)

Other Leachate Sampling

Month/ Location M

onito

ring

Rep

ortin

g

Mon

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g

Rep

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ortin

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Mon

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Rep

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Mon

itorin

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Rep

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g

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Rep

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January H,E X H,E H,E X H X H,E X H,E Xd X H,E Xe XFebruary X H X X X X H Xd X H X XMarch X H X X X H Xd X H Xe XApril X H,E H,E X H,E X H,E X H Xd H,E X H Xe H,E X H,EMay X X X H X X X X X H X X H Xe XJune X H X X X H Xd X H Xe XJuly H,E H,E X H,E H,E X H X H,E H,E X H Xd X H,E Xe XAugust X H X X X X H Xd X H X XSeptember X H X X X H Xd X H Xe XOctober X H,E H,E X H X H,E X H Xd H,E X H Xe H,E X H,ENovember X X H X X X X H X X H Xe XDecember X H X X X H Xd X H Xe XH - Hard copy reportE -Electronic reportWDNR - Wisconsin Department of Natural Resources WWTP - Wastewater Treatment Planta See individual sections and associated tables for each location type parameter list. b Specific details on reporting requirements can be found in Table 4.c Continuous monitoring is performed.d Tabulated leachate volume (DNR Parameter No. 00032) measurements only.e Continuous flow measurements only.

TABLE 2Method, LOD, Bottle, and Preservation Requirements for Water MatricesOutagamie County Landfill - 2013 SAP

Analyte USEPA Method Number LOD (mg/L) Bottle Requirementa PreservativeConventional ParametersDepth to Leachate FOP 5 -- None None—Field measurementField Color FOP 1 -- None None—Field measurementField Conductivity (at 25°C) FOP 1 -- None None—Field measurementField Odor FOP 1 -- None None—Field measurementField pH FOP 1 -- None None—Field measurementField Redox Potential FOP 1 -- None None—Field measurementField Turbidity FOP 1 -- None None—Field measurementField Groundwater Temperature FOP 1 -- None None—Field measurementGroundwater/Leachate Head Elevation FOP 5 -- None None—Field measurementTotal Alkalinity, Unfiltered and Filtered 310.1 or 310.2 10 250-mL plastic or glass 4°CAmmonia-Nitrogen, Total and Dissolved 350.1, 350.2 or 350.3 0.2 500-mL plastic or glass H2SO4 to pH < 2, 4°CBOD, 5-day 5210B 2.0 1-L plastic or glass 4°CChloride 300.0 2.0 100-mL plastic or glass 4°CCOD, Unfiltered and Filtered 410.1, 410.2 or 410.3, 410.4 11.3 250-mL plastic or glass H2SO4 to pH < 2, 4°CCyanide 335.4 0.00612 500-mL plastic or glass NaOH to pH > 12, 4°CTotal Hardness, Unfiltered and Filtered 6010 0.15 250-mL plastic or glass HNO3 to pH < 2, 4°CNitrate + Nitrite as N, Total and Dissolved 353.2 or 353.3, 354.4 0.125 100-mL plastic or glass H2SO4 to pH < 2, 4°CPhosphorus, Total 365.1, 365.2, 365.3 or 365.4 0.2 100-mL plastic or glass H2SO4 to pH < 2, 4°CSolids, Total Suspended 2540D 1.54 1-L plastic or glass 4°CSulfate, Total and Dissolved 300.0 2.0 / 2.5 100-mL plastic or glass 4°CTotal and Dissolved MetalsAluminum 6010 0.0066 500-mL plastic or glass HNO3 to pH < 2, 4°CAntimony 6010, 7041 0.0013 500-mL plastic or glass HNO3 to pH < 2, 4°CArsenic 6010, 7060, 7061 0.0019 500-mL plastic or glass HNO3 to pH < 2, 4°CBarium 6010 0.0001 500-mL plastic or glass HNO3 to pH < 2, 4°CBeryllium 6010, 7090, 7091 0.0001 500-mL plastic or glass HNO3 to pH < 2, 4°CBoron 6010 0.0013 500-mL plastic or glass HNO3 to pH < 2, 4°CCadmium 6010, 7031 0.0005 500-mL plastic or glass HNO3 to pH < 2, 4°CChromium 6010, 7091 0.0004 500-mL plastic or glass HNO3 to pH < 2, 4°CCobalt 6010, 7201 0.0004 500-mL plastic or glass HNO3 to pH < 2, 4°CCopper 6010, 7201 0.0003 500-mL plastic or glass HNO3 to pH < 2, 4°CFluoride 300.0, 340.1, 340.2 0.2 / 0.25 500-mL plastic or glass HNO3 to pH < 2, 4°C

Page 1 of 2

TABLE 2Method, LOD, Bottle, and Preservation Requirements for Water MatricesOutagamie County Landfill - 2013 SAP

Analyte USEPA Method Number LOD (mg/L) Bottle Requirementa PreservativeTotal and Dissolved Metals (Continued)Iron 6010, 7380, 7381 0.0038 500-mL plastic or glass HNO3 to pH < 2, 4°CLead 6010, 7421 0.0014 500-mL plastic or glass HNO3 to pH < 2, 4°CManganese 6010, 7460, 7461 0.0002 500-mL plastic or glass HNO3 to pH < 2, 4°CMercury 7470 0.0001 250-mL plastic or glass HNO3 to pH < 2, 4°CNickel 6010, 7521 0.0006 500-mL plastic or glass HNO3 to pH < 2, 4°CSelenium 6010, 7740, 7741 0.0034 500-mL plastic or glass HNO3 to pH < 2, 4°CSilver 6010, 7761 0.0005 500-mL plastic or glass HNO3 to pH < 2, 4°CSodium 6010 0.5 / 0.0466 500-mL plastic or glass HNO3 to pH < 2, 4°CThallium 6010, 7840, 7481 0.0015 500-mL plastic or glass HNO3 to pH < 2, 4°CVanadium 6010, 7910, 7911 0.0005 500-mL plastic or glass HNO3 to pH < 2, 4°CZinc 6010, 7950, 7951 0.0036 500-mL plastic or glass HNO3 to pH < 2, 4°CVolatile OrganicsWells 5030B / 8260B See Table 7 3 x 40-mL glass volatile vials 4°C, no headspace, HCl to pH < 2VOC Analytes in Private Wells 524/504c See Table 7 3 x 40-mL glass volatile vials 4°C, no headspace, HCl to pH < 2

Base/Neutral Extractable and Acid Extractable Compounds

3510C or 3520C / 8270C See Table 23 2 x 1-L amber glass bottles 4°C

Pesticides/PCBs/HerbicidesPesticides/PCBs/Herbicides 3510C or 3520C / 8081A See Table 27 2 x 1-L amber glass bottles 4°CBOD - biochemical oxygen demandCOD - chemical oxygen demandLOD - limit of detectionL - litermL - millilitersVOC - Volatilize Organic Compounda All bottle lids shall be Teflon lined. Sample bottles with similar container type and preservation may be combined.b Copies of internal SOPs shall be provided on request by the County or County's consultant.c Method 504 should be used to analyze groundwater samples collected from private wells for 1,2-dibromomethane and 1,2-dibromo-3-chloropropane.

Base/Neutral Extractable and Acid Extractable Compounds

Page 2 of 2

TABLE 3Laboratory QC RequirementsOutagamie County Landfill - 2013 SAP

Lab Blank Lab Duplicate Lab Spike Known Standard MS/MSDa

Analyte Freq. Limit Freq. Limit Freq. Limit Freq. Limit Freq. LimitField pH N/A N/A N/A N/A N/A N/A Daily ± .05 unit N/A N/AField Conductivity (corrected to 25ºC) N/A N/A N/A N/A N/A N/A Daily 90–110% N/A N/ABOD Daily < LOD 1/10 * N/A N/A 1/20 * N/A N/ASolids, Total Suspended Daily < LOD 1/10 * N/A N/A N/A N/A N/A N/ATotal Alkalinity, Unfiltered or Filtered Daily < LOD 1/10 * N/A N/A N/A N/A N/A N/AMetals, Total or Dissolved 1/10 < LOD 1/10 80–120% 1/20 75–125% 1/20 80–120% 1/20 75–125%COD, Unfiltered or Filtered Daily < LOD 1/10 80–120% N/A N/A 1/20 80–120% N/A N/AChloride Daily < LOD 1/10 80–120% 1/20 75–125% 1/20 80–120% 1/20 75–125%Total Hardness, Unfiltered or Filtered Daily < LOD 1/10 80–120% 1/20 75-125% 1/20 80–120% 1/20 75-125%Sulfate Daily < LOD 1/10 80–120% 1/20 75–125% 1/20 80–120% 1/20 75–125%Ammonia-Nitrogen, Total or Dissolved Daily < LOD 1/10 80–120% 1/20 75–125% 1/20 80–120% 1/20 75–125%Total Kjeldahl Nitrogen Daily <LOD 1/10 80–120% 1/20 75–125% 1/20 80–120% 1/20 75–125%Nitrate + Nitrite as N, Dissolved Daily < LOD 1/10 80–120% 1/20 75–125% 1/20 80–120% 1/20 75–125%Volatile Organics > 1/12 hr < LOD 1/10 * 1/20 * 1/20 * 1/20 *Base/Neutral Extractable and Acid Extractable Compounds

> 1/12 hr < LOD 1/10 * 1/20 * 1/20 * 1/20 *

Pesticides, PCBs, and Herbicides > 1/12 hr < LOD 1/10 * 1/20 * 1/20 * 1/20 *

BOD - biochemical oxygen demandLOD - limit of detectionN/A - not applicableFreq. - frequencyMS/MSD - matrix spike/matrix spike duplicatea Not required for sedimentation or leachate samples.* The laboratory should use authoritative sources cited in NR 149.03(5) for limits.

TABLE 4Reporting RequirementsOutagamie County Landfill - 2013 SAP

Agency Address Type of Report Receiveda List of Reports Received Due Dates Report(s) Created and Sent By

WDNR Mr. Mike Solomon WDNR-required parameters only Annual reports for private well, gas monitoring in buildings, gas blower, Due to DNR 60 business days after sampling periodBureau of Waste Management – Electronic data deliverable and leachate level measurements (Due to County's consultant 40 business days afterEnvironmental Monitoring Data, WA/3 – Data certification page Semiannual reports for groundwater monitoring well and leachate pump sampling period)Wisconsin Department of Natural Resources – Any exceedance notice station samplingP.O. Box 7921 Quarterly reports for sedimentation basins, gas compressor system, andMadison, WI 53707 gas probes

WDNR Regional Office Mr. Greg Tilkens WDNR-required parameters only Same as those listed for WDNR Same as those listed for WDNRWisconsin Department of Natural Resources – Data certification pageNortheast Region Headquarters – Any exceedance notice1125 North Military AvenueP.O. Box 10448Green Bay, WI 54307-0448

Appleton WWTP City of Appleton Appleton WWTP-Required Quarterly reports for flow, BOD, TSS, and PH Monthly reports due to Appleton by the 10th day of the Pretreatment Coordinator parameters for W. Landfill Semiannual Periodic Compliance Reports month after the sample event2006 E. Newberry St. -Hard copy report Periodic Compliance Reports due to Appleton by June 15Appleton, WI 54915-2758 and December 15

Heart of the Valley MSD Director of Public Works Heart of the Valley-required Monthly reports for leachate flow (County to submit) Semiannual results due within the calendar quarterVillage of Little Chute parameters for E. Landfill Semiannual Periodic Compliance Reports Priority Pollutant Scan due with closest periodic compliance108 W. Main St. – Hard copy report Priority Pollutant Scan Report (once per length of permit) reportLittle Chute, WI 54140

Outagamie County Director of Solid Waste All data All reports submitted to agencies2 See appropriate agenciesb for due dates County's consultantOutagamie County Landfill – Electronic data deliverable Monthly hard copy reports for sedimentation basin, leachate level, Heart Reports shall be submitted 40 business days after the sampling1419 Holland Rd. – Data certification page of the Valley MSD, Appleton WWTP, and other leachate sampling period, except those submitted directly to the agenciesAppleton, WI 54911-8985 – Any exceedance notice Quarterly hard copy reports for gas monitoring in buildings, gas wells,

– Hard copy report and center leachate system risers

County's consultant Mr. Jon Tortomasi All data Analytical Data and Exceedance Reports See appropriate agencies2 for due dates Analytical Lab and Sampling contractorCH2M HILL – Electronic data deliverable Monthly reports for leachate flow Reports not required by the agencies shall be submitted Outagamie County135 South 84th St., Suite 325 – Data certification page Semiannual Periodic Compliance Reports 40 business days after the sampling period Outagamie CountyMilwaukee, WI 53214-1456 – Any exceedance notice

– Hard copy reportaUnless indicated, one copy of a report is needed.bAgencies include DNR, and Heart of the Valley MSD.BOD - biochemical oxygen demandMSD - Metropolitan Sewerage DistrictTSS - total suspended solidsWDNR - Wisconsin Department of Natural Resources WWTP - Wastewater Treatment Plant

TABLE 5Private Well LocationsOutagamie County Landfill - 2013 SAP

Well No. DNR I.D. Well OwnerOwner Address/Phone Number Well Address

Tenant Name/Phone Number

PW-001 500 Selle, Richard 3904 N. French Rd. Same SameAppleton, WI 54911Phone: 920-739-9037

PW-003 81 Shedler, Mark 94 Oak Park Drive St. Nicholas Greek OrthodoxMenasha, WI 54952 ChurchPhone: 920-969-9075 3333 N. French Rd.

Appleton, WI 54911PW-005 49 Hoh, Robert 3117 N. French Rd. Same Same

Appleton, WI 54911Phone: 920-739-0271

PW-006 56 Dorn, Gerald 3111 N. French Rd. Same SameAppleton, WI 54911Phone: 920-739-4056

PW-007 48 Ebben, R. 3217 E. First Ave. Same SameAppleton, WI 54911Phone: 920-954-0740

PW-008 52 DeKeyser, Clint 2909 N. French Rd. Same SameAppleton, WI 54911Phone: 920-739-7858

PW-009 53 Custom Meat Industries 3220 E. Northland Ave. Same SameCedar Creek, WI Appleton, WI 54911Bill Stoesser Phone: 920-734-3504

PW-010 55 Romenesko, Clem 3236 E. Northland Ave. Same SameAppleton, WI 54911Phone: 920-734-9792

PW-027a 507 b Shade Today Landscaping 1401 W. Evergreen Dr. Same Sameand Nursery Appleton, WI 54913

Phone: 920-687-3100

PW-029a 508 b Mr. Gary L. Glaser 2910 Pogrant Road Same SameLittle Chute, WI 54140Phone: 920-788-2634

PW-030 509 b Appleton Zion United 2914 Pogrant Road Same SameMethodist Church Little Chute, WI 54140

Phone: 920-687-9191aThe requirement to sample these wells will be reevaluated at a later date.b Proposed WDNR well number

MKE\100320001

TABLE 6Private Well Analytical ListOutagamie County Landfill - 2013 SAP

Analyte WDNR No.

Conventional ParametersTemperature, water 00010Field conductivity (at 25°C) 00094Field pH 00400Total Alkalinity, Unfiltered 00410Chloride 00940COD, Unfiltered 00340Total Hardness, Unfiltered 00900Sulfate, Total 00945Volatile Organics

VOC (using Method 524/504a) See Table 7 for compounds

COD - chemical oxygen demandVOC - volatile organic compoundsa Method 504 should be used to analyze groundwater samples collected from private wells for 1,2-dibromomethane and 1,2-dibromo-3-chloropropane.

MKE\100320001

TABLE 7Landfill Volatile Organic Compound Lista,b


Name of CompoundParameter Number

Limit of Detection

(µg/L) Name of CompoundParameter Number

Limit of Detection

(µg/L)Acetone 81552 2.5 1,1-Dichloroethane 34496 1Benzene 34030 0.5 1,2-Dichloroethane 32103 0.5Bromodichloromethane 32101 0.6 1,1-Dichloroethylene 34501 0.6Bromoform (Tribromomethane) 32104 0.94c Dichloromethane (Methylene chloride) 34423 0.5Bromomethane (Methyl bromide) 34413 1 1,2-Dichloropropane 34541 0.5Carbon disulfide 77041 0.7 Ethylbenzene 78113 0.6Carbon tetrachloride 32102 0.5 Methyl ethyl ketone (2-Butanone) 81595 4.5Chlorobenzene 34301 0.5 Methyl-tert-Butyl Ether (MTBE) 78032 0.7Chloroethane 34311 1 Naphthalene 34696 1Chloroform (Trichloromethane) 32106 0.4 Styrene 77128 1Chloromethane (Methyl chloride) 34418 0.3 Tetrachloroethylene 34475 0.5cis-1,2-Dichloroethene 77093 1 Tetrahydrofuran 81607 2cis-1,3-Dichloropropene 34704 0.2 Toluene 34010 0.71,2-Dibromo-3-chloropropane (DBCP) 38437 1.7c trans-1,2-Dichloroethene 34546 1Dibromochloromethane 32105 1 trans-1,3-Dichloropropene 34699 0.21,2-Dibromoethane (EDB) 77651 0.56c 1,1,1-Trichloroethane 34506 1Dibromomethane (Methylene bromide) 77596 0.6 1,1,2-Trichloroethane 34511 0.51,2-Dichlorobenzene (o-) 34536 1 Trichloroethylene 39180 0.51,3-Dichlorobenzene (m-) 34566 1 Fluorotrichloromethane (Freon) 34488 0.81,4-Dichlorobenzene (p-) 34571 1 Vinyl chloride 39175 0.18c

Dichlorodifluoromethane 34668 1 Xylenes 81551 3

LOD - limit of detectionµg/L - micrograms per litera All VOC analyses shall be extracted using USEPA solid waste Method 5030, purge and trap, and quantified using Method 8260B. These methods are described in USEPA document SW-846, "Test Methods for Evaluating Solid Waste,'' Third Edition, November 1986, including updates from December 1987, November 1990, June 1997, and April 1998. However, private well analysis shall be performed using Method 524 and 504.b Results for all components detected during the VOC analysis, including those compounds not included in this table, are to be reported.c Current Limit of Detection at certified WDNR lab is known to be above the PAL.

MKE\100320001

Common Well Name Well No.

Well Casing

Diameter

Top of PVC Well Casing

Elevation

Ground Surface

Elevation Well

Deptha (ft)

Screen Length

(ft)Exisiting Monitoring WellsP-7A 002 2 739.36 737.64 34.0 5P-9C 022 2 741.59 740.21 35.5 5P-7B 024 2 740.23 738.51 41.1 5OW-14A 026 2 740.10 737.80 22.3 10P-14B 027 2 740.34 737.58 42.6 5P-22B 031 2 738.82 735.72 43.9 10P-106A 035 2 734.59 732.08 75.1 10P-15A 042 2 737.53 736.20 41.3 5OW-15B 043 2 740.05 736.49 23.0 10P-112B 058 2 739.27 736.82 83.9 10P-10D 059 2 734.77 732.40 31.0 5P-111B 061 2 742.42 740.83 61.3 2P-111C 062 2 742.64 741.30 51.1 2P-115D 083 2 745.05 742.68 103.9 13.8P-115E 084 2 744.19 742.62 48.2 5OW-301B 086 2 735.09 731.79 23.0 10P-301C 087 2 734.59 731.66 53.0 5P-305A 097 2 737.23 734.26 91.4 15OW-305B 098 2 737.41 734.92 22.9 10OW-306B 101 2 739.01 737.89 23.5 10OW-307B 104 2 740.39 738.50 23.0 10P-308A 106 2 739.74 737.66 80.7 15OW-308B 107 2 739.84 737.67 22.9 9.2P-308C 108 2 739.87 737.50 45.7 5OW-309B 110 2 737.96 736.03 22.9 10OW-316B 113 2 733.09 729.99 22.5 10OW-111D 118 2 743.00 741.59 23.5 10OW-117C 120 2 735.37 731.95 22.5 10P-112D 126 2 739.43 736.83 43.1 5.4OW-112E 127 2 738.84 737.12 20.7 10.4OW-115F 128 2 745.22 742.54 22.5 10.4P-307D 129 2 740.94 738.86 42.0 5.4P-307E 130 2 740.60 738.04 71.3 15.4P-310A 131 2 738.22 735.74 58.7 5.4OW-310B 132 2 738.07 736.18 20.5 10.4P-311A 133 2 740.15 737.07 50.4 5.4P-311B 134 2 739.87 737.20 89.0 15.4P-315A 135 2 737.03 734.25 84.4 15.4P-316D 136 2 731.67 728.69 58.9 15.4OW-317A 137 2 736.02 733.56 20.9 10.4OW-318A 138 2 737.25 735.03 20.6 10.4OW-319A 139 2 741.52 739.65 21.0 10.4P-320A 140 2 740.76 738.76 75.7 15.1P-320B 141 2 740.46 739.03 45.2 5P-321A 142 2 743.32 741.41 75.2 15.4P-321B 143 2 743.58 740.83 45.1 5.4P-322A 144 2 744.18 741.99 78.0 15.4OW-323A 145 2 739.16 737.00 20.6 10.4P-324A 146 2 735.18 732.42 45.2 5.4P-325A 147 2 738.68 736.68 45.3 5.4

TABLE 8Groundwater Monitoring Well InformationOutagamie County Landfill - 2013 SAP

Page 1 of 3


Well Casing

Diameter


Elevation

Ground Surface

Elevation Well

Deptha (ft)

Screen Length

(ft)


P-325B 148 2 737.92 736.46 81.1 15.4P-326A 149 2 741.67 739.32 44.6 5.4P-326B 150 2 741.90 739.40 72.9 15.4OW-413A 152 2 734.33 732.68 20.3 10.4P-413B 153 2 735.14 732.66 46.8 5.4OW-416A 157 2 737.57 735.25 20.2 10.4OW-513A 159 2 744.20 742.34 21.4 10.2P-513B 160 2 744.46 741.99 51.9 5.1P-513C 161 2 744.69 742.35 84.4 15.3P-4D 162 2 742.16 741.09 45.2 5.1P-13D 163 2 735.84 733.47 44.3 5OW-13E 164 2 736.31 733.62 22.8 10.1P-14D 165 2 739.51 737.34 70.0 15.3P-111E 166 2 741.15 740.44 70.3 15.1P-305D 168 2 735.29 734.35 45.3 5.1P-306D 169 2 738.68 737.82 72.3 15P-306E 170 2 739.44 738.18 46.9 5.1P-6D 171 2 744.45 741.71 47.8 5.2P-316CR 175 2 731.95 729.95 37.9 5OW-503A 206 2 734.12 731.61 22.6 10P-503B 207 2 734.44 732.23 47.1 5P-503C 208 2 734.44 731.68 86.9 15OW-504A 209 2 734.42 731.94 22.1 10P-504B 210 2 734.66 731.92 47.3 5P-504C 211 2 734.64 731.95 78.3 15P-13C 219 2 736.43 734.14 79.3 15P-15C 220 2 739.46 737.05 99.4 15P-23B 221 2 741.35 737.19 45.0 10OW-302BR 226 2 739.91 737.60 21.9 10P-302CR 227 2 739.99 737.60 48.0 5P-302AR 228 2 740.28 737.90 78.0 15OW-601A 230 2 733.78 730.60 17.5 10OW-602A 231 2 732.94 730.40 17.1 10OW-701A 232 2 735.52 733.40 18.0 10P-701C 234 2 735.38 733.40 64.2 15OW-702A 235 2 732.78 730.75 22.0 10P-702B 236 2 733.02 730.97 37.6 5P-702C 237 2 733.06 730.93 69.1 15OW-703A 238 2 734.84 732.92 22.1 10P-703B 239 2 734.59 732.81 46.8 5P-703C 240 2 734.94 732.80 67.2 15P-704B 241 2 736.54 734.64 31.8 5P-705B 242 2 741.77 739.88 36.8 5OW-313BR 243 2 744.20 741.69 21.5 10P-701BR 244 2 735.42 733.37 35.2 5P-801B 245 2 731.23 728.04 39.0 5P-802BR 247 2 735.94 732.31 44.0 5P-302D 248 2 738.48 740.42 83.0 5P-503D 249 2 731.17 733.55 97.0 5P-701D 250 2 733.02 735.01 116.0 5OW-801A 251 2 728.30 730.96 16.0 10P-802C 252 2 732.80 735.84 61.0 5

Page 2 of 3


Well Casing

Diameter


Elevation

Ground Surface

Elevation Well

Deptha (ft)

Screen Length

(ft)


P-802D 253 2.5 732.90 735.84 112.5 5OW-1010A 254 2 745.60 749.05 31.5 10P-1010B 255 2 745.30 748.80 56.0 5P-1010C 256 2 745.50 748.61 79.0 5OW-1011A 257 2 746.10 749.68 23.0 10P-1011B 258 2 746.20 749.20 54.0 5P-1011C 259 2 746.30 749.26 72.0 5P-1012B 260 2 736.10 740.74 44.0 5P-1012C 261 2 736.20 740.44 80.0 5P-1012D 262 2.5 736.00 740.24 127.3 5P-1013B 263 2 732.60 737.44 53.0 5P-1013C 264 2 732.80 737.72 75.0 5P-1013D 265 2.5 732.70 737.37 122.5 5P-1014B 266 2 734.30 738.42 55.0 5P-1014C 267 2 734.00 738.21 81.0 5P-1014D 268 2.5 734.00 737.82 130.0 5P-1015B 269 2 733.50 738.13 53.0 5P-1015C 270 2 733.80 738.81 72.5 5P-1015D 271 2.5 733.70 738.30 125.3 5P-801C 272 2 728.10 730.62 57.5 5P-801D 273 2.5 728.00 730.48 108.2 5OW-802A 274 2 732.50 735.77 17.0 10OW-1012A 275 2 736.10 741.01 18.0 10OW-1013A 276 2 732.70 737.55 16.0 10OW-1014A 277 2 734.20 738.92 19.5 10OW-1015A 278 2 733.30 738.37 20.0 10

a From top of PVC casingNote: All monitoring wells have PVC casing

Page 3 of 3

TABLE 9Groundwater Monitoring Wells Sampling FrequencyOutagamie County Landfill - SAP 2013

Well NameWDNR

Well No.

Semiannual Sampling for

Detection Monitoring

Parameters in Table 11

Annual Sampling for Detection Monitoring of

VOCs in Table 7

Semi-Annual Sampling for

Detection Monitoring of

VOCs in Table 7

Semiannual Groundwater Elevation &

Annual Conductivity

Baseline Monitoring for Parameters in

Table 10Sitewide Subtitle D Wells

P-305D 168 X XP-503B 207 X XP-703B 239 X XP-701BR 244 X XP-801B 245 X XP-802BR 247 X X

West Landfill Groundwater Monitoring WellsP-7A 002 X XP-9C 022 X XP-7B 024 X XOW-14A 026 X XP-14B 027 X XP-22B 031 XP-106A 035 X XP-15A 042 X XOW-15B 043 X XP-112B 058 X XP-10D 059 X XP-111B 061 X XP-111C 062 X XP-115D 083 X XP-115E 084 X XOW-301B 086 XP-301C 087 XOW-307B 104 X XP-308A 106 X XOW-308B 107 X XP-308C 108 X XOW-316B 113 X XOW-111D 118 X XOW-117C 120 XP-112D 126 X XOW-112E 127 X XOW-115F 128 X XP-307D 129 X XP-307E 130 X XP-310A 131 XOW-310B 132 XP-311A 133 X XP-311B 134 X XP-315A 135 X XP-316D 136 X XOW-317A 137 X XOW-318A 138 X XOW-319A 139 X XP-322A 144 X XOW-323A 145 X XP-324A 146 X XOW-413A 152 XP-413B 153 XOW-416A 157 XOW-513A 159 X XP-513B 160 X XP-513C 161 X X

1 of 3


Well NameWDNR

Well No.





VOCs in Table 7



VOCs in Table 7


Annual Conductivity


Table 10P-4D 162 X XP-13D 163 X XOW-13E 164 X XP-14D 165 X XP-111E 166 X XP-6D 171 X XP-316CR 175 X XP-13C 219 XP-15C 220 X XP-23B 221 XP-704B 241 X XP-705B 242 X X

West and East Landfill Groundwater Monitoring WellsP-325A 147 X XP-325B 148 X XP-326A 149 X XP-326B 150 X X

East Landfill Groundwater Monitoring WellsP-305A 097 X XOW-305B 098 X XOW-306B 101 X XOW-309B 110 X XP-320A 140 X XP-320B 141 X XP-321A 142 X XP-321B 143 X XP-306D 169 X XP-306E 170 X XOW-702A 235 X XP-702B 236 X XP-702C 237 X XOW-703A 238 X XP-703C 240 X XOW-313BR 243 X X

East and Northeast Landfill Groundwater Monitoring WellsOW-504A 209 X XP-504B 210 X XP-504C 211 X XOW-302BR 226 X XP-302CR 227 X XP-302AR 228 X XOW-701A 232 X XP-701C 234 X XP-302D 248 X XP-503D 249 X XP-701D 250 X XOW-1010A 254 X XP-1010B 255 X XP-1010C 256 X XOW-1011A 257 X XP-1011B 258 X X XP-1011C 259 X X X

Northeast Landfill Groundwater Monitoring WellsOW-503A 206 X XP-503C 208 X X

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Well NameWDNR

Well No.





VOCs in Table 7



VOCs in Table 7


Annual Conductivity


Table 10OW-601A 230 X XOW-602A 231 X XOW-801A 251 X XP-802C 252 X X XP-802D 253 X XP-1012B 260 X XP-1012C 261 X XP-1012D 262 X XP-1013B 263 X XP-1013C 264 X XP-1013D 265 X XP-1014B 266 X XP-1014C 267 X XP-1014D 268 X XP-1015B 269 X XP-1015C 270 X XP-1015D 271 X X XP-801C 272 X X XP-801D 273 X XOW-802A 274 X XOW-1012A 275 X XOW-1013A 276 X XOW-1014A 277 X XOW-1015A 278 X X

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TABLE 10Baseline Monitoring Requirements for Groundwater Monitoring WellsOutagamie County Landfill - 2013 SAP

Analyte WDNR No.

Number of Baseline

Sampling Rounds for East and West

Number of Baseline Sampling

Rounds for Northeast Landfill

Conventional ParametersField Color 00002 8 8Field Conductivity (at 25°C) 00094 8 8Field Groundwater Temperature 00010 8 8Field Odor 00001 8 8Field pH 00400 8 8Field Turbidity 00003 8 8Groundwater Elevation 04189 8 8Alkalinity, Filtered 39036 8 8Chloride 00940 8 8COD, Filtered 00341 8 8Hardness, Filtered 22413 8 8Ammonia-Nitrogen, Dissolved 00608 8 8Nitrate + Nitrite as N, Dissolved 00631 8 8Solids, Total Suspended 00150 1 1Sulfate, Dissolved 00946 8 8

Dissolved MetalsArsenic 01000 4a 4a

Barium 01005 4a 4a

Boron 01020 8 8Cadmium 01025 4a 4a

Chromium 01030 4a 4a

Copper 01040 4a 4a

Fluoride 00950 4a 8Lead 01049 4a 4a

Manganese 01056 4a 4a

Mercury 71890 4a 4a

Selenium 01145 4a 4a

Silver 01075 4a 4a

Sodium, Dissolvedb 00930 - 8Zinc 01090 4a 4a

EPA Dissolved Metalsc

Antimony 1095 4a 4a

Beryllium 1010 4a 4a

Cobalt 1035 4a 4a

Nickel 1065 4a 4a

Thallium 1057 4a 4a

Vanadium 1085 4a 4a

Volatile OrganicsVOC Analytesd See Table 7 2d 2d

b This parameter shall be analyzed only for Northeast Landfill monitoring wells.cRequired for Subtitle D wells only (see Table 9).

aIf any of these parameters exceed the NR 140 ES once or the NR 140 PAL twice during the four baseline sampling rounds at a well, four additional sampling rounds for those parameters will be required at that well. In addition, if the average concentration of the first four baseline sampling rounds exceeds the NR 140 PAL, four additional sampling rounds will be required at th t ll

d If VOCs are detected in the first two sampling rounds at a well, then two additional rounds of VOC sampling shall be performed at that well.

MKE\100320001

TABLE 11Detection Groundwater Monitoring Well Analytical ListOutagamie County Landfill - 2013 SAP

Analyte WDNR No.Conventional Parameters

Field Color 00002Field Conductivity (at 25°C) 00094Field Groundwater Temperature 00010Field Odor 00001Field pH 00400Field Redox Potential 00090Field Turbidity 00003Groundwater Elevation 04189Alkalinity, Filtered 39036Boron, Dissolved 01020Chloride 00940COD, Filtered 00341Hardness, Filtered 22413Ammonia-Nitrogen, Dissolved 00608Nitrate + Nitrite as N, Dissolved 00631Fluoride, Dissolveda 00950Sodium, Dissolveda 00930Sulfate, Dissolved 00946

Volatile OrganicsVOC Analytesb See Table 7

aThis parameter shall be analyzed only for Northeast Landfill monitoring wells.bThis parameter shall be analyzed only in May for monitoring wells, but shall be sampled in May and November for Subtitle D wells.

MKE\100320001

TABLE 12Sedimentation Basin SamplingOutagamie County Landfill - 2013 SAP

Analyte WDNR No.Sample turbidity 00003Temperature, water 00010Field Conductivity (at 25ºC) 00094Field pH 00400Chloride 00940COD, Unfiltered 00340Total Hardness, Unfiltered (as CaCO3) 00900Solids, Total Suspended 00150Notes:The amount of precipitation in the 24 hours prior to sampling and the condition of the basin water (i.e., frozen, debris) shall be recorded and submitted along with the results.The discharge structures shall be inspected each month and notations shall be made regarding whether or not there is active discharge.Actual sampling shall be performed whenever there is an active discharge, which will be generally during the spring, summer, and fall season, but could also occasionally occur (after precipitation events or snowmelts) during the winter.

MKE\100320001 1

TABLE 13Gas Probe LocationsOutagamie County Landfill - 2013 SAP

Gas Probes WDNR No. Description/LocationWest Landfill Gas Probes

GP-1 780 West of landfill exit road, on south side of the service drive to compressor building, in front of small garage

GP-2 781 Adjacent to well nest 14, west of cells 7–8 of the West LandfillGP-3 782 Adjacent to well nest 513, west of cells 1–6 of the West LandfillGP-4 783 Adjacent to well nest 117, north of cells 1–6 of the West Landfill

East Landfill Gas ProbesGP-5 784 Adjacent to well nest 302, east of East Landfill North Pump StationGP-6 785 East toe of landfill screening berm along Holland RoadGP-7 786 East toe of landfill screening berm along Holland RoadGP-8 787 South side of landfill entrance road, west of road from scaleGP-9 788 South side of landfill entrance road, south of entrance to landfill

GP-10 789 South of southeast corner of whitegoods/brush disposal area at east end of berm

Northeast Landfill Gas ProbesGP-A 797a Northeast corner of NELF, north of P-801BGP-B 798 a East of southeast corner of NELFGP-C 799 a North side of NELF, east of OW-602AGP-D 800 a North of northwest corner of NELFGP-E 801 a West of southwest corner of NELF

aProposed WDNR well number

MKE\100320001

TABLE 14Gas Probea and Gas Collection Station Monitoring RequirementsOutagamie County Landfill - 2013 SAP

Anaylte WDNR CodeQuarterly Monitoring

Gas ProbebDailyc Monitoring Gas

Collection StationAnnual Monitoring

Gas Collection StationVacuum (inches of water) 46390 XFlow Rate (cubic feet per minute) 99098 XPercent Methane 85547 X XPercent Oxygen 85550 X XSource Temperature None XAir Temperature (oF) 00021 X XBarometric Pressure (mm Hg) 00025 X XTrend in Barometric Pressure 46381 XSoil Gas Pressure (inches of water) 46389 XGround Condition None XSample Flow Rate (approximate) 46386 XStart time None XStop time None XAnnual Landfill Gas Monitoring Table 17 None Xa Oxygen measurements should be taken at the sample port only.b The monitoring shall be performed on a Monday, Tuesday, or Wednesday.c Data from the County's records shall be obtained by the monitoring firm and tabulated approximately the 1st and the 15th of each month.Note: If any of the gas monitoring shows one or more methane concentration readings in excess of 1.0 percent (by volume), they shall be reported to the County's Landfill Manager verbally within 2 hours, as well as in writing via fax or courier the same day that the readings were observed.

MKE\100320001

TABLE 15Annual Landfill Gas Sample ParametersOutagamie County Landfill - 2013 SAP

Parameter Units Parameter NumberNatural Gas AnalysisOxygen (O) volume % 85550Nitrogen (N) µL/L 99181Carbon dioxide volume % 85544Carbon monoxide µL/L 46113Methane volume % 85547Ethane ppm volume C0006a

Propane ppm volume C0007a

Isobutane ppm volume C0008a

n-Butane ppm volume C0009a

Isopentane ppm volume C0010a

n-Pentane ppm volume C0011a

Hexane plus ppm volume C0012a

Non Methane Organic Compounds (NMOC) ppm volume C0052a

Natural Gas Analysis-ConditionsMolar Mass Ratio C0013a

Relative Density C0014a

Compressibility Factor C0015a

Heating Valdry (ideal) BTU/cubic foot C0016a

Heating Valdry (real) BTU/cubic foot C0017a

Pressure Base psi absolute C0018a

Other AnalysisMercury nL/L 98438Halide, total organic (as Cl) ppm volume C0020a

Ethanol nL/L 99288Sulfur Components of Natural GasHydrogen sulfide ppm volume C0022a

Carbonyl sulfide ppm volume C0023a

Sulfur dioxide ppm volume C0024a

Carbon disulfide nL/L 99374Methyl mercaptan ppm volume C0026a

Ethyl mercaptan ppm volume C0027a

Isopropyl mercaptan ppm volume C0028a

n-propyl Mercaptan ppm volume C0029a

tert-butyl Mercaptan ppm volume C0030a

sec-butyl Mercaptan ppm volume C0031a

Isobutyl mercaptan ppm volume C0032a

n-butyl Mercaptan ppm volume C0033a

Methyl sulfide ppm volume C0034a

Ethyl methyl sulfide ppm volume C0035a

Ethyl sulfide ppm volume C0036a

Methyl disulfide ppm volume C0037a

Ethyl methyl disulfide ppm volume C0038a

Ethyl disulfide ppm volume C0039a

Thiophene ppm volume C0040a

Tetra-hydro thiophene ppm volume C0041a

2-Methyl thiophene ppm volume C0042a

3-Methyl thiophene ppm volume C0043a

2-Ethyl thiophene ppm volume C0044a

3-Ethyl thiophene ppm volume C0045a

2,5-Dimethyl thiophene ppm volume C0046a

Benzothiophene ppm volume C0047a

Unidentified sulfur compounds ppm volume C0048a

1 of 2

TABLE 15Annual Landfill Gas Sample ParametersOutagamie County Landfill - 2013 SAP

Parameter Units Parameter NumberVolatile OrganicsAcetone nL/L 99375Acrylonitrile nL/L 99771Benzene nL/L 99001Bromodichloromethane nL/L 99340Bromoform (Tribromomethane) nL/L 99365Bromomethane nL/L 99342Methyl ethyl ketone (2-butanone) nL/L 99380Carbon disulfide nL/L 99374Carbon tetrachloride nL/L 99343Chlorobenzene nL/L 99344Chlorodifluoromethane ppm volume C0049a

Chloroethane nL/L 993452-Chloroethylvinyl ether nL/L 99776Chloroform nL/L 99346Chloromethane nL/L 99347Dibromochloromethane nL/L 99349Dibromomethane (methylene bromide) nL/L 991571,2-Dibromoethane nL/L 993841,2-Dibromo-3-chloropropane nL/L 99156o-Dichlorobenzene nL/L 99357m-Dichlorobenzene nL/L 99361p-Dichlorobenzene nL/L 99364Dichlorodifluoromethane nL/L 993691,1-Dichloroethane nL/L 993771,2-Dichloroethane nL/L 993581,1-Dichloroethylene nL/L 99373cis-1,2-Dichloroethene nL/L 99379trans-1,2-Dichloroethene nL/L 99376Dichlorofluoromethane µg/L 771191,2-Dichloropropane nL/L 99360cis-1,3-Dichloropropene nL/L 99362trans-1,3-Dichloropropene nL/L 99363Ethylbenzene nL/L 99008Fluorotrichloromethane nL/L 993722-Hexanone nL/L 99383Methylene chloride (Dichloromethane) nL/L 993504-Methyl-2-pentanone (MIBK) nL/L 99382Methyl tert butyl ether nL/L 99289Naphthalene nL/L 991802-Propanol (isopropyl alcohol) nL/L 99480Styrene nL/L 990261,1,2,2-Tetrachloroethane nL/L 99356Tetrachloroethylene nL/L 99351Tetrahydrofuran nL/L 99501Toluene nL/L 990281,1,1-Trichloroethane nL/L 993541,1,2-Trichloroethane nL/L 99355Trichloroethylene nL/L 99381Vinyl acetate nL/L 99378Vinyl chloride nL/L 99353Xylenes, Total nL/L 99371volume % - volume percentµL/L - microliters per liternL/L - nanoliters per literppm - parts per millionBTU - British Thermal Unitpsi absolute- pounds per square inch absoluteaNot a DNR parameter code.

2 of 2

TABLE 16Leachate Pump Station Analytical ListOutagamie County Landfill - 2013 SAP

Analyte WDNR No. WDNR Appleton WWTPHeart of the Valley MSD

Outagamie County

Monthly ParametersFlow (Continuous, submitted monthly) 00056 Xa Xb,c

BOD (5-day) 00310 Xa

Copper, Total 01042Field pH 00400 Xa

Solids, Total Suspended 00150 Xa

Parameters to be Analyzed Semiannually (May & November) (May & November) (February & August)Leachate, Volume Pumped 00032 XField Conductivity (at 25°C) 00094 XField pH 00400 X Xb,c Xe (Feb & Aug)Alkalinity, Unfiltered 00410 XBOD (5-day) 00310 X Xb,c Xe (Feb & Aug)Chloride 00940 XCOD, Unfiltered 00340 XHardness, Unfiltered 00900 XNitrogen, Total Kjeldahl 00625 XAmmonia Nitrogen, Total 00610 XSolids, Total Suspended 00150 X Xb,c Xe (Feb & Aug)Sulfate, Total 00945 XBoron, Total 01022 XCadmium, Total 01027 X Xa Xb,c

Chromium, Total 01034 Xa Xb,c

Copper, Total 01042 Xa Xb,c Xa

Cyanide, Total 00720 Xa Xb,c

Fluoride, Total 00951 Xd

Iron, Total 74010 XLead, Total 01051 X Xa Xb,c

Manganese, Total 01055 XMercury, Total 71900 X Xa Xb,c

Nickel, Total 01067 Xa Xb,c

Phosphorus, Total 00665 Xb,c Xe (May & Nov)Selenium, Total 01147 XSilver, Total 01077 Xb,c

Sodium, Total 00929 XZinc, Total 01092 Xa Xb,c

VOCs See Table 7 XParameters to be Analyzed Annually (May) (May)

Aluminum, Total 01105 Xa

Arsenic, Total 01002 Xa

Base/Neutral Extractable and Acid Extractable Compounds See Table 19 XPriority Pollutant Scan (Once per length of permit)Semiannual parameters listed above, and:Antimony, Total 01097 Xb,c

Arsenic, Total 01002 Xb,c

Beryllium, Total 01012 Xb,c

Cyanide, Amenable to Chlorination C0051f Xb,c

Selenium, Total 01147 Xb,c

Thallium, Total 01059 Xb,c

Base/Neutral Extractable and Acid Extractable Compounds See Table 19 Xb,c

Pesticide/PCBs/Herbicides See Table 21 Xb,c

VOCs See Table 7 Xb,c

Includes leachate locations WLS, E-1, E-2, PB-1, PB-2, PB-3 unless otherwise noted.a West Site Composite onlyb East Site Composite onlyc Northeast Site Composite onlyd PB-1, PB-2, PB-3 onlye E-1, E-2, PB-1, PB-2, PB-3 onlyf Not a DNR parameter code

TABLE 17Base/Neutral and Acid Extractable CompoundsOutagamie County Landfill - 2013 SAP

Compound NameParameter

Number LOD (µg/L) Compound NameParameter

Number LOD (µg/L)Acenapthene 34205 1 2,4-Dinitrophenol 34616 2.5Acenaphthylene 34200 1 2,4-Dinitrotoluene 34611 0.9a

Acetophenone 81553 2 2,6-Dinitrotoluene 34626 1.1a

Anthracene 34220 1 Di-n-octyl phthalate 34596 2Benzo[a]anthracene (Benzanthracene) 34526 1 Diphenylamine 77579 1.5Benzo[b]fluoranthene 34230 1.5a Fluoranthene 34376 1Benzo[k]fluoranthene 34242 1.5 Fluorene 34381 1.5Benzo[g,h,i]perylene 34521 1 Hexachlorobenzene 39700 1.2a

Benzo[a]pyrene 34247 1a Hexachlorobutadiene 34391 0.7Benzo alcohol 77147 1.5 Hexachlorocyclopentadiene 34386 1.5Bis(2-chloroethoxy)methane 34278 1.5 Hexachloroethane 34396 1Bis(2-chloroethyl)ether 34273 1 Indeno(1,2,3-cd)pyrene 34403 1Bis(2-chloroisopropyl)ether 73522 1 Isophorone 34408 1.5Bis(2-ethylhexyl)phthalate 39100 2.6a 1-Methylnaphthalene 81696 1.54-Bromophenyl phenyl ether 34636 1.5 2-Methylnaphthalene 77416 1.5Butyl benzyl phthalate (Benzyl butyl phthalate) 34292 1.5 Naphthalene 34696 1p-Chloro-m-cresol 34452 1.5 2-Nitroaniline 78142 12-Chloronaphthalene 34581 1 3-Nitroaniline 78300 12-Chlorophenol 34586 1 4-Nitroaniline 73605 1.54-Chlorophenylphenyl ether 34641 1.5 Nitrobenzene 34447 1.5Chrysene 34320 1a 2-Nitrophenol 34591 1.5m-cresol (3-Methylphenol) 77151 1 4-Nitrophenol 34646 1o-cresol (2-Methylphenol) 77152 1 N-nitrosodimethylamine 34438 0.6p-cresol 77146 1 N-nitrosodi-n-propylamine 34428 1.5Dibenzo[a,h]anthracene 34556 1.5 Pentachlorophenol 39032 1.1a

Dibenzofuran 81302 1.5 Phenanthrene 34461 1Di-n-butyl phthalate 39110 1 Phenol 34694 1.53,3'-Dichlorobenzidine 34631 1.5 Pyrene 34469 22,4-Dichlorophenol 34601 1.5 Pyridine 77045 1.5Diethyl phthalate 34336 1.5 2,3,4,6-Tetrachlorophenol 77770 2.52,4-Dimethylphenol 34606 1.5 1,2,4-Trichlorobenzene 34551 1Dimethyl phthalate 34341 1.5 2,4,5-Trichlorophenol 77687 14,6-Dinitro-o-cresol 79533 1 2,4,6-Trichlorophenol 34621 1.5

LOD - limit of detectiona Current Limit of Detection at certified WDNR lab is known to be above the PAL.

TABLE 18Locations for Monthly Leachate Level Measurementsa


Name WDNR No. Name WDNR No.WEST LANDFILL SITEc,e

ManholesMH-1 841 MH-6 846MH-2 842 MH-7 847MH-3 843 MH-8 848MH-4 844 MH-9 849MH-5 845

EAST LANDFILL SITEb,c

Leachate Head WellsLGM-1 821 LGM-7 827LGM-2 822 LGM-8 828LGM-3 823 LGM-9 829LGM-4 824 LGM-10 830LGM-5 825 LGM-11 831LGM-6 826 LGM-12 832

ManholesMH-10 850 MH-21 861MH-11 851 MH-22 862MH-12 852 MH-23 863MH-13 853 MH-24 864MH-14 854 MH-25 865MH-15 855 MH-26 866MH-16 856 MH-27 867MH-17 857 MH-28 868MH-18 858 MH-29 869MH-19 859 MH-30 870MH-20 860 MH-31 871

NORTHEAST LANDFILL SITEb,c

Leachate Head WellsLHW-1A 833d

LHW-1B 834d

LHW-2A 835d

LHW-2B 836d

LHW-3A 837d

LHW-3B 838d

Leak Detection ManholesLD-1 872d

LD-2 873d

LD-3 874d

LD-4 875d

eRegarding all West landfill leachate monitoring points, if they are in a closed and sealed condition, ask the County whether monitoring should be performed.

d Proposed WDNR well number.

a Only those leachate head wells and manholes that are existing and accessible shall be monitored.b Where possible, the relative flow rate at the bottom of each manhole shall also be noted.cThe measuring point elevation will be provided prior to sampling.

MKE\100320001

TABLE 19Pesticide, Herbicide, and PCB Parameter ListOutagamie County Landfill - 2013 SAP

Pesticides/PCBsParameter

NumberEstimated Detection

Limits (µg/L)Aldrin 39330 0.05alpha-BHC 39337 0.05PCB, Arochlor-1016 34671 0.5PCB, Arochlor-1221 39488 0.5PCB, Arochlor-1232 39492 0.5PCB, Arochlor-1242 39496 0.5PCB, Arochlor-1248 39500 0.5PCB, Arochlor-1254 39504 0.5PCB, Arochlor-1260 39508 0.5beta-BHC 39338 0.05Chlordanea 39350 0.24,4’-DDD 39310 0.14,4’-DDE 39320 0.14,4’-DDT 39300 0.1delta-BHC 34259 0.05Dieldrin 39380 0.1Endosulfan I (alpha-) 34361 0.05Endosulfan II (beta-) 34356 0.1Endosulfan Sulfate 34351 0.1Endrin 39390 0.1Endrin aldehyde 34366 0.1gamma-BHC (Lindane) 39340 0.05Heptachlor 39410 0.05Heptachlor epoxide 39420 0.05Toxapheneb 39400 0.5a This entry includes alpha-Chlordane, beta-Chlordane, gamma-Chlordane and constituents of Chlordane.b This entry includes congener chemicals contained in technical toxaphene; i.e., chlorinated

MKE\100320001

Attachment B

Figures

\\HERCULES\Proj\Outagamie\SAP\2013 SAP Revision and Submittal\Attachment B - Figures_Figure_1_GroundwaterMonitoringNetwork_v1 7-23-13

FIGURE 1 Groundwater Monitoring NetworkOutagamie County LandfillAdapted from Foth

\\HERCULES\Proj\Outagamie\SAP\2013 SAP Revision and Submittal\Attachment B - Figures_Figure_1_GasMonitoringNetwork_v1 7-23-13

FIGURE 2 Gas Monitoring NetworkOutagamie County LandfillAdapted from Foth

\\HERCULES\Proj\Outagamie\SAP\2013 SAP Revision and Submittal\Attachment B - Figures_Figure_1_LeachateMonitoringNetwork_v1 7-23-13

FIGURE 3 Leachate Monitoring NetworkOutagamie County LandfillAdapted from Foth

Attachment C

Field Operating Procedures

MKE/100320001 C-1

Field Operating Procedures

1 Equipment Calibration

2 Equipment Decontamination

3 Sample Custody

4 Private Well Sampling

5 Water Level and Leachate Level Measurements

6 Monitoring Well Sampling Procedure

7 Gas Probe Monitoring Procedure

8 Leachate Sampling Procedure

MKE/100320001 C-3

FIELD OPERATING PROCEDURE 1

Equipment Calibration

Field Air Monitoring (Photoionization Detector [PID]) Purpose The purpose of this operating procedure is to provide a general guideline for the field measurement of air quality with a photoionization detector (PID).

Scope This is a general description of PID calibration procedures.

Equipment/Materials Photoionization Detector (Mini-Rae 2000, OVM, or equivalent)

Procedures and Guidelines Because instruments used during the field investigation may be in fact several models produced by different manufacturers, it is not feasible to present instrument-specific details in this section. Instead, instrument-specific calibration will be performed in accordance with each manufacturer’s instructions in regard to both frequency and method.

Key Checks and Items Make sure the manufacturer’s calibration/user manual is included with equipment.

Check to see that batteries are adequately charged.

Make sure all materials necessary for calibration are present (e.g., calibration gas/calibration standards, correct regulator and tubing, spare batteries, and charging equipment).

Field Measurements of pH Purpose The purpose of this operating procedure is to provide a general guideline for the field measurement of pH in water samples.

Scope Standard field pH determination techniques and instrument calibration are to be used on groundwater samples.


C-4 MKE/100320001

Equipment/Materials pH buffer solution for pHs 4, 7, and 10 Deionized water in squirt bottle pH meter Combination electrodes Beakers Solution of HCl Glassware that has been washed with soap and water, rinsed twice with hot water, and

rinsed twice with deionized water

Procedures/Guidelines Procedures 1. Before going into the field:

Check batteries. Do a quick calibration at pHs 7 and 4 to check electrode. Obtain fresh standard solutions.

2. Calibrate meter using calibration procedure. 3. Pour sample into a clean beaker. 4. Rinse electrode with deionized water between samples. 5. Immerse electrode in sample solution. Record pH reading. 6. Recheck calibration with pH 7 buffer solution daily. 7. Decontaminate pH meter before use at each sample location. 8. Rinse probe with deionized water before storage each day. 9. Check meter for battery charge and physical damage each day. 10. Store meter and pH buffer solution in a cool, dry environment.

General 1. When calibrating meter, use pH buffers 4 and 7 for samples with a pH < 8, and buffers 7

and 10 for samples with a pH > 8. If meter will not read pH 4 or 10, something may be wrong with the electrode.

2. Measurement of pH is temperature dependent. Therefore, temperatures of buffers and samples should be within about 2°C. For refrigerated or cool samples, use refrigerated buffers to calibrate the pH meter.

3. Weak organic and inorganic salts, oil, and grease interfere with pH measurements. If oil or grease is visible, note it on the data sheet. Clean the electrode with soap and water, rinse it with a 10 percent solution of HCl, and recalibrate the meter.

4. Following field measurements:

Report any problems. Compare with previous data. Clean all dirt off of the meter and from inside the case. Store the electrode in a pH 4 buffer solution.

FOP 1–EQUIPMENT CALIBRATION

MKE/100320001 C-5

5. Accuracy and precision are dependent on the instrument used. Refer to manufacturer’s manual. Expected accuracy and precision are ± 0.1 pH unit.

Key Checks/Items Check batteries Calibrate

Field Measurements of Conductivity and Temperature Purpose The purpose of this operating procedure is to provide a general guideline for the field measurement of conductivity and temperature.

Scope Field instruments must be calibrated daily before beginning sampling activities. The methods and frequencies of calibration for the instruments used for each field activity are described below.

Equipment/Materials Reagents: deionized water in squirt bottle and standard potassium chloride solution Reagent preparation:

Stock potassium chloride (KCl) solution (1.00 N): Dissolve 74.555 g KCl in deionized water and dilute to 1,000 mL in a volumetric flask.

Standard potassium chloride solution (0.01 N): Dilute 10.0 mL of stock 1.00 N KCl solution to 1,000 mL with deionized water using a volumetric pipet and flask.

Conductivity meter and electrodes Beakers or jars, plastic or glass Spare batteries

Procedures/Guidelines Groundwater Detection limit = 1 μmho/cm at 25°C; range = 0.1 to 100,000 μmho/cm 10 μmhos/cm = 1 mS/m

Calibration Check Check instrument calibration before initial daily use and at least once at the end of the field day. Check instrument with standard solution. Deviations should be noted in the field log book.

1. Turn on the instrument.

2. Set meter to indicate temperature corrected results (conductivity units should be µmhos).

3. Read the standard and note the results.


C-6 MKE/100320001

4. Rinse the probe with deionized water.

5. Run the sample and record the results

6. Rinse with deionized water when finished.

7. Decontaminate the conductivity meter before use at each sample location.

8. Rinse the probe with deionized water before storage each day.

9. Check the meter for battery charge and physical damage each day.

10. Store the meter and conductivity standard in a cool, dry environment.

Operating Procedures 1. Perform calibration at beginning and end of each day.

2. Switch mode to Temperature. Allow time for the probe temperature to come to equilibrium with the water before reading. Read the temperature on the bottom scale of the meter in degrees Celsius.

3. Switch mode to correct range. If the reading is below 50 on the 0 to 500 range (5.0 on the 0 to 50 mS/m range), switch to the next range. If the reading is still below 50 (5.0 mS/m), switch to the X1 scale. Read the meter scale and multiply the reading by the mode factor. The answer is expressed in ìmhos/cm. Measurements are not temperature compensated.

4. The meter reading should fall less than 2 percent; if greater, the probe is fouled and the measurement is in error. Clean the probe and remeasure.

Operating Suggestions Obstructions near the probe can disturb readings.

When the calibration test indicates low readings, the probable cause is dirty electrodes. Hard water deposits, oil, and organic matter are the most likely contaminants.

Caution: Do not touch the electrodes inside the probe. The plating material is soft and it can be scraped off easily.

If cleaning does not restore probe performance, replatinizing may be required. Always rinse the probe thoroughly in tap water, then in deionized water after cleaning and before storage. Note that it is best to store conductivity cells in deionized water.

Most problems in obtaining good records with monitoring equipment are related to electrode fouling and inadequate sample circulation.

Decontaminate the conductivity meter before use at each sample location. Rinse probe with deionized water before storage each day. Check meter for battery charge and physical damage each day. Store the meter and conductivity standard in a cool, dry environment.

Water temperature readings can be taken using the conductivity meter. Switch from conductivity mode to temperature mode and record the reading in the field notebook.


MKE/100320001 C-7

Key Checks/Items Document any deviations from the above procedure Check battery Check calibration Clean probe with deionized water when finished When reading results, note sensitivity settings

Preventive Maintenance Refer to operation manuals for recommended maintenance. Check batteries. Have a replacement set on hand.

Field Measurements of Dissolved Oxygen Purpose The purpose of this operating procedure is to provide a general guideline for the field measurement of dissolved oxygen in water samples.

Scope This procedure provides information regarding the equipment, materials, and procedures used for standard field dissolved oxygen determination in water samples.

Equipment/Materials Dissolved oxygen meter Dissolved oxygen probe Potassium chloride (KCl) probe refill solution Spare probe membranes Spray bottle with deionized water


Check batteries Perform calibration Check probe membrane

2. Record instrument make, model, and serial number in the log book or data form.

3. Calibrate the meter using the manufacturer’s recommended calibration procedure and take a duplicate reading every 10 samples.

4. Pour the collected water sample into a clean beaker.

5. Rinse probe with deionized water.


C-8 MKE/100320001

6. Immerse the probe in the sample. Record the dissolved oxygen reading in the log book or data form, and record the results once the readings have stabilized.

7. Decontaminate the probe and the beaker and cover them to guard against contamination.

General Measurement of dissolved oxygen is temperature dependent. Therefore, temperature

correction must be accurate when calibrating.

Following field measurements:

Record any problems Compare with previous data and note any large variances Clean all dirt off of the meter and from inside the case Store probe in calibration container with wet towel/sponge

Accuracy and precision are dependent on the instrument used. Refer to manufacturer’s manual. Expected accuracy and precision are ± 0.1 mg/L.

Key Checks/Items Check batteries Check the membrane Calibrate Decontaminate and cover the probe

Field Measurements of Oxidation-Reduction Potential Purpose The purpose of this operating procedure is to provide a general guideline for the field measurement of oxidative-reductive potential (ORP) in water samples.

Scope Standard field ORP determination techniques for use on groundwater samples.

Equipment/Materials 0.1 M potassium ferrocyanide 0.05 M potassium ferricyanide Hach cat. no. 50280-05 filling solution Distilled water in a squirt bottle ORP meter 2 x 100 millileter (mL) volumetric flasks Beakers Glassware that has been washed with soap and water, rinsed twice with hot water, and

rinsed twice with de-ionized water


MKE/100320001 C-9


Check batteries. Obtain fresh standard solutions.

2. Calibrate the meter using the following calibration procedure:

Transfer 100 mL of 0.1 M potassium ferrocyanide to a 150 mL beaker. Place the electrode in the solution and wait until the reading stabilizes. The potential should be about 234 millivolts (mV).

Rinse the electrode with deionized water and repeat with 0.05 M potassium ferricyanide. The potential should read about 300 mV.

3. Pour the sample into a clean beaker.

4. Rinse electrode with distilled water between samples.

5. Immerse the electrode in the sample solution. Record the ORP reading.

6. Recheck the calibration with the iron solutions after every 10 samples.

Decontaminate the ORP meter before use at each sample location. When not in use, the electrode may be stored dry, in air. Remove salt crystals on the outside of the electrode sleeve by rinsing it with distilled water and draining the filling solution from the chamber. Flush the chamber with distilled water and store it dry. Check the meter for a battery charge and physical damage each day. Store the meter and ORP calibration solution in a cool, dry environment.

General 1. The filling solution is Hach cat. No 50280-05

2. Following field measurements:

Report any problems Compare with previous data Clean all dirt off of the meter and from inside the case Store the electrode in a pH 4 buffer solution

3. Accuracy and precision are dependent on the instrument used. Refer to manufacturer’s manual. Expected accuracy and precision are ± 10 mV.

Key Checks/Items Check batteries Calibrate

Preventive Maintenance Refer to operation manuals for recommended maintenance. Check batteries. Have a replacement set on hand.


C-10 MKE/100320001

Gas Probe and Gas Well Monitoring (GEM 500 and GEM 2000) Purpose The purpose of this operating procedure is to provide a general guideline to perform instrument calibration prior to conducting field measurements using the GEM 500 and GEM 2000.

Scope This is a general description of the GEM 500 & GEM 2000 calibration procedures.

Equipment/Materials LANDTEC GEM 500 or GEM 2000 portable gas meter. Calibration gases, including span gas and zero gas (or ambient air).

Procedures and Guidelines Calibration will be performed in accordance with the manufacturer’s instructions in regard to both frequency and method. A field calibration shall be performed on-site immediately prior to conducting monitoring.

Key Checks and Items Make sure the manufacturer’s calibration/user manual is included with equipment.

Check to see that batteries are adequately charged.

Make sure all materials necessary for calibration are present (e.g. calibration gas/calibration standards, correct regulator and tubing, charging equipment).

MKE/100320001 C-11


Equipment Decontamination

Purpose The purpose of this procedure is to provide a general guideline for decontaminating sampling and monitoring equipment. Equipment decontamination procedures minimize the potential for cross contamination between wells and maintain data quality.

Scope All equipment contacting well water or any unclean surface should be properly decontaminated prior to and after sample collection.

Equipment/Materials Deionized (DI) water Approximately 2.5 percent by weight nonphosphate detergent and water solution (e.g.,

Liqui-Nox) Large plastic pails or tubs/bottles for detergent and water Scrub brushes Plastic bags Paper towel

Sampling Equipment Decontamination The following procedures will be used for decontamination of nondedicated sampling equipment between sampling locations:

1. Wash sample contact equipment with a non-phosphate detergent solution (e.g., Alquinox®, Liquinox®).

2. Rinse with DI water and air-dry.

Nondedicated pumps, such as a Grundfos will be decontaminated using the following procedure:

1. Wash equipment with a non-phosphate detergent solution and scrub with an inert brush. For internal mechanisms and tubing, circulate the detergent solution through the equipment.

2. Thoroughly rinse the equipment with DI water.

3. For organic sampling, rinse equipment with an organic desorbing agent (e.g., pesticide grade isopropanol, acetone, methanol or hexane). For inorganic sampling, rinse with


C-12 MKE/100320001

inorganic desorbing agent (e.g., dilute [0.1 Normal] reagent grade hydrochloric acid or nitric acid solution). For stainless and low-carbon steel, a more dilute hydrochloric acid solution (1 percent) is recommended.

4. Rinse with potable water (only if inorganic desorbing agent is used).

5. Rinse with deionized water. Allow the equipment to air dry before next use.

6. Place equipment in an inert container or wrap in clean plastic or aluminum foil for storage and transport.

In addition, disassemble the equipment as much as possible and wash/scrub it with a nonphosphate detergent during decontamination. Because disassembling equipment can take time and be hard on the equipment, use professional judgment to determine when this is necessary.

Decontamination Documentation At a minimum, decontamination documentation should include the following:

1. The location where decontamination occurred.

2. The individuals performing the decontamination.

3. The decontamination procedures, including the wash solution and rinse water used (e.g., potable water and DI water).

4. Equipment storage and transport procedures.

5. The handling and disposal of decontamination wastewater.

MKE/100320001 C-13


Sample Custody

Purpose The purpose of this procedure is to delineate protocols for shipping of samples, provide a definition of “custody,” and to describe protocols for documenting the transfer of custody from one party to the next (e.g., from the site to the laboratory). A documented custody trail is established through the use of a chain-of-custody form that uniquely identifies each sample container and the identity of the individual who has possession of the sample from its origin to its final destination. The chain-of-custody form also describes the sampling point, date, time, and analysis parameters.

Scope This FOP is applicable for all samples collected and prepared for analysis at an offsite laboratory. Sample personnel should be aware that a sample is considered to be in a person’s custody if the sample meets the following conditions:

It is in a person’s actual possession It is in view after being in a person’s possession It is locked up so that no one can tamper with it after having been in a person’s physical

custody

When samples leave the custody of the sampler, the cooler must be custody-sealed and its possession must be documented.

Chain of Custody The chain of custody form must contain the following information:

Client name

Site name and state

Project manager

Sampling company

Sample ID: This is the unique number that will be used for sample tracking.

Matrix: Describes the sample media (e.g., Groundwater, Soil, etc.).

Sampler name: The name of the sampler or sample team leader.

Sample type: “Grab” or “Composite.”


C-14 MKE/100320001

Analysis: This indicates the analyses required for each sample.

Preservative: Document what preservative has been added to the sample (e.g., “HCl”, “Ice Only,” “None”).

Sample Collect Date and Time: Use military time.

QC Type: This is for field QC only, and includes field duplicates, field blanks, equipment blanks, and trip blanks.

Airbill Number: Airbill number used for shipping (if samples are hand-delivered to their destination, “Hand Delivered” should appear in this field).

Shipping Label: This is the laboratory name and full address, including the laboratory contact. If the contact is not known, use “Sample Custodian.”

Chain-of-Custody Record Fields: The sampler’s signature must appear in the “Relinquished By” field. The date and time (military time) must also be included. Although the samples are “relinquished” to the shipping carrier, the shipping carrier does not have access to the samples as long as the shipping cooler is custody sealed. Consequently, the shipping carrier does not sign the chain-of-custody form.

Sample(s) to be used for Laboratory QC: This identifies which samples are to be used for matrix spike/matrix spike duplicate analyses.

Sample Identification Label samples to avoid misidentification. Use waterproof ink and securely attach labels to bottles, as ice used to cool samples can smear ink and cause labels to detach. Storing samples in plastic bags will help prevent these problems. Labels should include (1) a unique sample number and Wisconsin Unique Well Number (WUWN) if available; (2) site or facility name; (3) date and time sample was collected; (4) sample collector's initials; (5) preservative added to the sample; and (6) the analysis required.

Custody Seals If custody seals are used, affix the seal to the sample container so that it has to be broken to open the container. The seal should include the initials of the person sealing the container and the date and time the sample is sealed.

If security tape is used, make sure that the tape must be cut or ripped to open the shipper. Use nylon-reinforced or equivalent tape that cannot be tampered with unnoticed. The tape should include the initials of the person sealing the container and the date and time of sealing.

MKE/100320001 C-15


Private Well Sampling

Purpose The following describes the procedures for the collection of groundwater samples from private wells.

Scope This procedure is applicable for private wells that are functioning within their designed specifications. The well owner should be consulted for any specific well operating procedures.

Procedures/Guidelines Pre-sampling Activities (Purging) The following activities shall be completed before the start of sampling:

1. If possible, locate a tap/faucet/spigot as close to the well's pump as possible; preferably before the water passes through any softener, heater, storage or pressure system, or tank. A sample tap is usually located just before the pressure tank. Remove any aerators, filters or other devices from the tap before collecting samples. If you must collect the sample from an outside tap, remove any hoses.

2. Confirm that the tap/faucet/spigot selected is deemed acceptable for sampling with the well owner.

3. If present, remove aerator on tap/faucet/spigot.

4. Connect garden hose to tap/faucet/spigot, if necessary. If the sample tap is located before the pressure tank and treatment systems, make sure the pump is running and flowing from the sample tap for at least 2 minutes before collecting any samples. If the sampling tap is located after the pressure tank, allow the water to run for at least 5 minutes and to become cold before collecting any samples. This should allow the stagnant water to be flushed out of the pressure tank and be replaced by freshly pumped water. For large pressure tanks, a longer waiting period may be necessary. Either calculate the necessary flushing time based on the pressure tank volume and purging flow rate, or allow the pump to cycle at least two or three times and wait until the water is cold before collecting your samples.

5. Make sure any water being purged is properly collected/diverted out of or away from the Owner’s buildings using the garden hose.


C-16 MKE/100320001

Sampling Activities Procedures for sampling are as follows:

1. Fill the 5-gallon bucket from the selected collection point and immerse the multi-meter probe in the water. Record field parameter values once they have stabilized.

2. Fill all sample containers directly at selected tap/faucet/spigot after purging the line and/or any holding tanks. Any sample containers containing chemical preservative should not be overfilled.

3. Record the purging time, tap location, and time of collection.

4. Draw a diagram of where samples were collected.

5. Place all samples in designated sample cooler(s).

6. Make sure sampling point is shut off before leaving private property.

MKE/100320001 C-17


Water Level and Leachate Level Measurements

Purpose A general guideline for measurement of water levels in monitoring wells and leachate levels at leachate pump station clean outs.

Scope Standard method of water level and leachate level measurement..

Equipment / Materials Water-level indicator Photoionization meter Deionized water Liqui-Nox® Methanol Spray bottles Paper towels

Procedures / Guidelines Uncap the well/clean out and immediately place the photoionization meter at the

wellhead for readings.

Decontaminate water level indicator with Liqui-Nox®, methanol, and deionized water.

Test battery on water level indicator.

Measure depth to water:

Adjust gain/sensitivity (while probe is dry) to the maximum sensitivity that does not activate the audible sensor.

Lower probe into the well slowly until the audible sensor activates.

Raise and lower the probe slowly to precisely measure the top of the water.

Hold the tape (indicating depth) against the north top edge of the well casing (the designated measuring point) and read depth to water to the nearest 0.01 foot.

Record depth to water.

Measure total well depth (monitoring wells only):


C-18 MKE/100320001

Turn gain/sensitivity off.

Lower probe into the well until the probe contacts the bottom.

Raise and lower the probe slowly so the probe is vertical and not leaning across the diameter of the well.

Hold the tape (indicating depth) against the north top edge of the well casing and read depth to the nearest 0.01 foot.

Decontaminate the water level indicator using Liqui-nox®, methanol, and deionized water.

MKE/100320001 C-19


Monitoring Well Sampling Procedure

Purpose The purpose of this procedure is to provide a general guideline for groundwater sampling from monitoring wells.

Scope Standard method for groundwater sampling using purge and low-flow techniques

Equipment/Materials Water level indicator Peristaltic pump and batteries Disposable Teflon bailer and rope Photo-ionization detector Teflon tubing Masterflex tubing A calibrated multi-meter and flow-through cell Field notebook, sample data sheets, chain-of-custody forms, and custody seals Purge water collection buckets with lids/tank Socket wrench and socket set Well keys Deionized water, methanol, and Liqui-Nox® in spray bottles Paper towels Ice for sample coolers Tubing weight Tubing cutters

Procedures/Guidelines Groundwater samples will be collected no earlier than one week after completion of well construction and development. Wells will be sampled by the purge method using a bailer and rope or by the low-flow method using a peristaltic pump and tubing.

The following sampling procedures will be used to collect groundwater samples from the monitoring wells:

1. Remove the well cap and screen airspace within the protective casing for volatile organic compounds using a photoionization detector (PID). Record PID reading in the logbook. Note: PID screening can be skipped at wells with no known VOC impacts, however the


C-20 MKE/100320001

PID should be with the field team at all times to monitor the breathing zone while sampling.

2. Screen well casing and workers’ breathing zone with the PID and record readings in the logbook. Evaluate breathing zone PID reading with respect to the Health and Safety Plan; if above Action Level, upgrade to appropriate personal protective equipment (PPE).

3. Determine the depth to water and total well depth using the following procedures:

Decontaminate water level indicator Test battery on water level indicator Measure depth to water using the following procedure in FOP No. 1 Record depth to water on appropriate Field Form from Appendix B

4. Measure total well depth by using the following procedure:

Turn gain/sensitivity off

Lower probe into the well until the probe contacts the bottom

Raise and lower the probe slowly so that the probe is vertical and not leaning across the diameter of the well

Hold the tape (indicating depth) against the north top edge of the well casing at the permanent measuring point (typically a chisel mark on the top of the well riser) and read depth to bottom to nearest 0.01 foot

Record total well depth on appropriate Field Form from Appendix B

5. When using the purge method to sample, calculate the volume of water in the well (well volume) using the following equation:

Total Well Depth - Depth to Water Gallons Per Foot of Depth (0.041 for 1-inch well or 0.163 for 2-inch well) = Volume of Water in the Well

Purge the well, prior to sampling, by using a disposable Teflon bailer

Calculate the purge volume for the well by multiplying the well volume calculated in Step 4 by three

Tie new string onto a new disposable bailer and lower the bailer to the bottom of the well

Remove the bailer and pour purge water into a 5-gallon bucket

Repeat this process until the volume calculated above has been purged; sampling can then begin

Following the removal of the purge volume, sampling can begin. All samples are collected in laboratory supplied bottles. Sample bottles will be filled by slowly tipping the bailer to allow water to flow from the top of the bailer into the sample container.

FOP 6 – MONITORING WELL SAMPLING PROCEDURE

MKE/100320001 C-21

6. When using the low-flow method to purge/sample, use the total depth measured of the well and the screen length to determine the location of the center of the screened interval.

Lower Teflon tubing into the well so that the opening is located in the center of the screened interval.

Connect Teflon tubing to master flex tubing and feed it through the peristaltic pump. Connect tubing to flow-through cell and install calibrated multi-meter.

Pump groundwater at a maximum rate of 1 liter per minute during low-flow purging, and less than 300 mL per minute during low-flow sampling and monitoring stability parameters.

Monitor and record field parameters using the multi-meter until three consecutive readings spaced about 2 minutes or about 0.5 well volumes or more apart are within the following ranges:

Parameter Range (unit)

Dissolved Oxygen +/- 0.2 mg/L

Specific Conductivity +/- 5.0 mhos/cm for concentrations < 1,000 mhos/cm

+/- 10.0 mhos/cm for concentrations > 1,000 mhos/cm

pH +/- 0.1 pH unit

Temperature +/- 0.1 oC

Turbidity < 5 NTUs if metal sample will not be filtered

Disconnect the flow-through cell from the pump and sampling can begin. All samples are collected in laboratory-supplied bottles. The sample vial will be placed at the tip of the discharge line of the pump.

Use a 0.45 micron filter for all filtered samples.

7. Replace well cap.

8. Preserve samples, as appropriate, if not collected in laboratory pre-preserved bottles.

9. If tubing is not dedicated, remove from well and dispose of properly. Decontaminate all non-dedicated equipment including water level measurement equipment, purging devices, sampling devices and filtration devices between each well.

10. Place all sample bottles in an iced cooler and deliver under proper chain of custody to the Laboratory.

11. Collect QC samples as described in Section 2 of the Sampling and Analysis Plan.


C-22 MKE/100320001

Key Checks/Items When using the low-flow method, be sure that tubing is within screened interval Verify sample parameters and volumes prior to sample collection Verify that all equipment works prior to sampling Make sure that well cap and protective cover are on before leaving the site

MKE/100320001 C-23


Gas Probe Monitoring Procedure

Purpose The purpose of this procedure is to provide a general guideline for gas monitoring from the perimeter soil gas probes.

Scope Standard method for gas probe monitoring using a portable gas meter.

Equipment/Materials LANDTEC GEM 500 or GEM 2000

Calibration gas and equipment (see FOP for Equipment Calibration)

Extra sample tubing

Keys for pro-casing

Field notebook or data sheets

Procedures/Guidelines Gas probes shall be monitored on Mondays, Tuesdays, or Wednesdays. This will allow Thursday and Friday to be used to address any potential issues that might arise early in the week. At the start of the sampling event, record the onsite meteorological data (if available). As an alternative, the meteorological data may be gathered at a later time from observations taken at the Outagamie County Regional Airport (KATW), using observations from the time closest to the start of the monitoring event.

Record the following meteorological data:

Air temperature (°F) Barometric pressure (mm Hg) Trend in barometric pressure Precipitation within the last 24 hours

The following monitoring procedures shall be used to collect gas data from the gas probes:

1. With the GEM turned on, but the pump turned off, connect the sampling tube from theinstrument to the probe sample port, ensuring that the sampling port valve remainsshut.


C-24 MKE/100320001

2. Open the sampling port and immediately record the static pressure (inches of water), which represents the probe (soil) gas pressure.

3. Start the GEM sampling pump, and record the initial methane concentration.

4. Continue to purge the gas probe until the methane reading stabilizes or reaches zero, and record the methane and oxygen concentrations.

5. Turn off the pump (instrument may be left on if additional monitoring is required), close the sample port valve, and disconnect the tubing from the port.

6. Ensure that the sampling port valve has been closed, then close the protective casing and lock the case.

7. Record the ground condition around the gas probe.

Key Checks/Items Calibrate the instrument in the field prior to performing the monitoring event.

Verify that all equipment works prior to monitoring.

Ensure that the sampling port is closed at the end of the monitoring event to prevent potential gas from escaping from the atmosphere.

Make sure that the probe cap and/or protective cover are on before leaving the site.

Document any damage to the monitoring probes or necessary repairs

MKE/100320001 C-27


Leachate Sampling Procedure

Purpose The purpose of this procedure is to provide a general guideline for leachate sampling from leachate pump stations.

Scope Standard method for leachate sampling from pump stations within the NELF

Equipment/Materials Field notebook, sample data sheets, chain-of-custody forms, and custody seals 5-gallon buckets with lid Paper towels Ice for sample coolers Laboratory supplied sample bottles

Procedures/Guidelines Leachate samples will be collected according to the schedule outlined in the Sampling and Analysis Plan.

The following sampling procedures will be used to collect leachate samples from the leachate pump stations:

1. Open spigot and allow enough leachate to flow to clear the line. Collect leachate in a 5-gallon bucket.

2. Collect sample in laboratory supplied sample bottles from the spigot. Any sample containers containing chemical preservative should not be overfilled.

3. Place all samples in designated sample cooler(s). Make sure sampling point is shut off before leaving pump station.

Key Checks/Items Verify sample parameters and volumes prior to sample collection. Make sure sampling point is shut off before leaving pump station.

Attachment D

Forms

Form 1

Well ID Date / Time

Depth to Water

(ft btoc)

Measured Well

Depth (ft btoc)

Groundwater

Elevation (msl)

Observations/Notes on Well Condition

(broken, frozen, dry, abandoned, etc.)

Signature of Field Personel:


Groundwater Elevation Collection Form

Form 2

Well Number: Designation: Subtitle D , Group 1 , Group 2 , Baseline

Field Crew: Field Conditions:

Well Pad Acceptable Not Acceptable Explain:

Protective Casing Acceptable Not Acceptable Explain:

Well Casing Acceptable Not Acceptable Explain:

Locking Cap Acceptable Not Acceptable Explain:

Well Label Acceptable Not Acceptable Explain:

Purge Date: Time: Method/Device:

Total Well Depth (ft btoc) =

Depth to Water (ft btoc): =

Water Column (ft): =

Well Diameter (inches) =

Total Purge Volume (gal) =

Odor: None , Low , Mod. , High , H2S , Fuel Like , Other:

Color:

Turbidity: Clear , Slightly Cloudy , Cloudy , Very Turbid , Other:

TimeTemperature(oC)

pH(s.u.)

Eh (ORP)(mV)

Turbidity(NTU)

Purge Volume (gal) / Flow Rate (mL/min)

Depth to Water(ft)

Date: Time:

Sample ID: Method of Sample Collection/Device:

Analytical Parameters:

Q.C. Sample Type: MS/MSD Duplicate Duplicate Sample ID:

Q.C. Parameters:

SIGNED/SAMPLER:

- PVC Bailer- Teflon Bailer- Guzzler Pump- Centrifugal Pump- Bladder Pump- Peristaltic Pump- SS Bailer

FIELD PARAMETERS

SAMPLING

PURGE METHOD

Monitoring Well Field Data Sheet - Outagamie County Landfill

WELL CONDITION

OBSERVATIONS

Conductivity(S/cm)

Specific Conductivity(correct to 25oC)

Form 3

Field Gas Probe Monitoring Report FormClient: _____________________________________________Site: ___________________________Weather Conditions: _____________________________________________________________________Barometer:Date: ______________________________________________Sampled By: ____________________

Percent Percent Air Barometric Precipitation

Time Time Methane Methane Percent Temperature Pressure Barometric within 24 hrs. Ground Remarks/

Location Date Start End (initial) (stabilized) Oxygen (ºC) (mm of Hg) Trend (inches) Conditions ObservationsSoil Gas Pressure

Percent Methane

Downwind

MKE/ATT D FORMS 4-6

Form 4 Example Outline for Analytical Reports

1. PAL/ES Exceedance Letter (see Form 5)

2. Private Well Analytical Results (see Form 6)

3. Subtitle D Well Analytical Results (see Form 6)

4. Monitoring Well Analytical Results (see Form 6)

5. Sedimentation Basin Analytical Results (see Form 6)

6. Gas Analytical Results (see Form 6)

7. Leachate Pump Station Analytical Results (see Form 6)

8. Field Analytical Results (see Form 6)

a. Private Wells b. Groundwater Wells c. Sedimentation Basin d. Gas Locations e. Leachate Pump Stations

9. QA/QC Results (see Form 6)

Private Wells—Blank results, duplicate results, spike results, known standard results, MS or MS/MSDs

Groundwater Wells—Blank results, duplicate results, spike results, known standard results, MS or MS/MSDs

Sedimentation Basin—Duplicate results

Leachate Pump Stations—Duplicate results

Inlet Pipe to the Gas Blower — Blank results, duplicate results

9. Field Groundwater, Sedimentation Basin, and Leachate Monitoring Report Forms (see Form 2)

10. Field Gas Probe Monitoring Report Forms (see Form 3)

11. Groundwater Monitoring Data Certification Form (see Attachment F)

MKE/ATT D FORMS 4-6

Form 5

December 31, 2010

Mr. Mike Soloman Bureau of Waste and Materials Management Environmental Monitoring Data, SW/3 Wisconsin Department of Natural Resources PO Box 7921 Madison, WI 53707

Subject: Outagamie County Landfill, License #02484, FID #445012370— Fourth Quarter 2010 Monitoring Event

Mr. Solomon:

In accordance with NR140, this letter hereby notifies the DNR that Groundwater Monitoring Data for the Fourth Quarter 2010 monitoring event for the above facility had the exceedances listed in Table A.

Samples were collected on the dates of November 5 through November 9, 2009.

The following wells were not sampled because of Dry or Low Volume conditions: #149 (P-326A) #233 (P-701B)

The following well was broken, and we were unable to obtain a sample:

#215 (OW-508A)

Also included on the diskette is all required Field and Laboratory QC data.

Cause and significance of the NR140 exceedance will be addressed in the Site Engineers' upcoming Annual Groundwater Report.

Please call if there are any questions.

Sincerely, [Signature] [Name] Project Manager Attachments 2011 SAP--Attach C_Forms.doc

c: Mr.Greg Tilkens/WDNR-Green Bay Mr. Philip P. Stecker/Outagamie County

MKE/ATT D FORMS 4-6

Form 5 Outagamie County Landfill Exceedance Report Sampling Date: 8/6/2010 Report Date: 12/20/2010 4:19:58 PM Series: 1 Well No. Well Name Param. No. Parameter Description Qualifier Value Exceedance Type 218 WLS 01042 Copper, Total = 150 PAL

MKE/ATT D FORMS 4-6

Page 1 of 1 Form 6

Outagamie County Landfill 2009 Summary Groundwater Report

Prepared by CH2M Hill November 7, 2010

Well No. 002 Well Name: P-7A

Date Param No. Parameter Description Value 5/17/2009 39036 Total Alkalinity, Filtered 290 11/20/2009 39036 Total Alkalinity, Filtered 270 5/17/2009 81552 Acetone 2.4 280.00 Avg. Value 2.40 Hist. Avg. 306.76 Hist. Avg. 5/17/2009 01020 Boron, Dissolved 0.38 5/17/2009 22413 Total Hardness, Filtered 170 11/20/2009 01020 Boron, Dissolved 0.34 11/20/2009 22413 Total Hardness, Filtered 170 0.36 Avg. Value 170.00 Avg. Value 0.37 Hist. Avg. 209.04 Hist. Avg. 5/17/2009 00940 Chloride 4.7 5/17/2009 00625 Total Kjeldhal Nitrogen 2.2 11/20/2009 00940 Chloride 4.3 11/20/2009 00625 Total Kjeldhal Nitrogen 2.6 4.50 Avg. Value 2.40 Avg. Value 2.87 Hist. Avg. 2.48 Hist. Avg. 5/17/2009 00341 COD, Filtered 37 5/17/2009 39175 Vinyl chloride 0.52 23.06 Hist. Avg. 1.82 Hist. Avg. 5/3/2009 04189 Ground water elevation 724.5 11/8/2009 04189 Ground water elevation 722.98 723.74 Avg. Value 722.99 Hist. Avg.

5/17/2009 00608 NH3-N, Dissolved 1.8 11/20/2009 00608 NH3-N, Dissolved 1.9 1.85 Avg. Value 2.12 Hist. Avg.

5/17/2009 00090 Oxidation Reduction Potential -5 11/20/2009 00090 Oxidation Reduction Potential -32 -18.50 Avg. Value 11.85 Hist. Avg.

5/17/2009 00400 pH - Field 7.82 11/20/2009 00400 pH - Field 7.69 7.76 Avg. Value 7.51 Hist. Avg.

5/17/2009 00094 Specific Conductance-Field (at 25C) 452 11/20/2009 00094 Specific Conductance-Field (at 25C) 426 439.00 Avg. Value 504.85 Hist. Avg.

5/17/2009 81607 Tetrahydrofuran 50 33.20 Hist. Avg. Note: VOC results and calculations represent detect or estimated detect * One-half of detection

Page 1 of 113

Attachment E WDNR-Approved

Well-Specific PALs and ACLs

ATTACHMENT EDNR-Approved Well-Specific PALs and ACLsOutagamie County Landfill

MKE\100320001 Page 1 of 2

Well Name WDNR No. Parameter No. Parameter Name Value UnitsType of

StandardP-305D 168 00094 Specific Conductance-Field (at 25C) 680 umhos/cm PALP-305D 168 00341 COD, Filtered 37 mg/L PALP-305D 168 00608 NH3-N, Dissolved 2.4 mg/L PALP-305D 168 00915 Calcium, Dissolved 57 mg/L PALP-305D 168 00925 Magnesium, Dissolved 54 mg/L PALP-305D 168 00930 Sodium, Dissolved 80 mg/L PALP-305D 168 01056 Manganese, Dissolved 1400 ug/L ACLP-305D 168 22413 Total Hardness, Filtered 290 mg/L PALP-305D 168 39036 Total Alkalinity, Filtered 400 mg/L PALP-305D 168 70295 Total Dissolved Solids 530 mg/L PALOW-503A 206 00094 Specific Conductance-Field (at 25C) 1600 umhos/cm PALOW-503A 206 00341 COD, Filtered 37 mg/L PALOW-503A 206 00608 NH3-N, Dissolved 2.2 mg/L PALOW-503A 206 00915 Calcium, Dissolved 330 mg/L PALOW-503A 206 00925 Magnesium, Dissolved 150 mg/L PALOW-503A 206 00930 Sodium, Dissolved 69 mg/L PALOW-503A 206 00946 Sulfate, Dissolved 230 mg/L ACLOW-503A 206 01056 Manganese, Dissolved 220 ug/L ACLOW-503A 206 22413 Total Hardness, Filtered 1100 mg/L PALOW-503A 206 39036 Total Alkalinity, Filtered 740 mg/L PALOW-503A 206 70295 Total Dissolved Solids 1100 mg/L PALP-503B 207 00094 Specific Conductance-Field (at 25C) 440 umhos/cm PALP-503B 207 00341 COD, Filtered 55 mg/L PALP-503B 207 00608 NH3-N, Dissolved 2.2 mg/L PALP-503B 207 00915 Calcium, Dissolved 40 mg/L PALP-503B 207 00925 Magnesium, Dissolved 28 mg/L PALP-503B 207 00930 Sodium, Dissolved 64 mg/L PALP-503B 207 01056 Manganese, Dissolved 260 ug/L ACLP-503B 207 22413 Total Hardness, Filtered 150 mg/L PALP-503B 207 39036 Total Alkalinity, Filtered 210 mg/L PALP-503B 207 70295 Total Dissolved Solids 390 mg/L PALP-503C 208 00094 Specific Conductance-Field (at 25C) 450 umhos/cm PALP-503C 208 00341 COD, Filtered 35 mg/L PALP-503C 208 00608 NH3-N, Dissolved 2.2 mg/L PALP-503C 208 00915 Calcium, Dissolved 49 mg/L PALP-503C 208 00925 Magnesium, Dissolved 32 mg/L PALP-503C 208 00930 Sodium, Dissolved 53 mg/L PALP-503C 208 22413 Total Hardness, Filtered 180 mg/L PALP-503C 208 39036 Total Alkalinity, Filtered 250 mg/L PALP-503C 208 70295 Total Dissolved Solids 370 mg/L PALOW-504A 209 00094 Specific Conductance-Field (at 25C) 930 umhos/cm PALOW-504A 209 00341 COD, Filtered 37 mg/L PALOW-504A 209 00608 NH3-N, Dissolved 2.2 mg/L PALOW-504A 209 00915 Calcium, Dissolved 390 mg/L PALOW-504A 209 00925 Magnesium, Dissolved 74 mg/L PALOW-504A 209 00930 Sodium, Dissolved 120 mg/L PALOW-504A 209 00946 Sulfate, Dissolved 250 mg/L ACLOW-504A 209 01056 Manganese, Dissolved 700 ug/L ACLOW-504A 209 22413 Total Hardness, Filtered 610 mg/L PALOW-504A 209 39036 Total Alkalinity, Filtered 460 mg/L PALOW-504A 209 70295 Total Dissolved Solids 720 mg/L PALP-504B 210 00094 Specific Conductance-Field (at 25C) 640 umhos/cm PAL

ATTACHMENT EDNR-Approved Well-Specific PALs and ACLsOutagamie County Landfill

MKE\100320001 Page 2 of 2

Well Name WDNR No. Parameter No. Parameter Name Value UnitsType of

StandardP-504B 210 00341 COD, Filtered 87 mg/L PALP-504B 210 00608 NH3-N, Dissolved 2.2 mg/L PALP-504B 210 00915 Calcium, Dissolved 76 mg/L PALP-504B 210 00925 Magnesium, Dissolved 28 mg/L PALP-504B 210 00930 Sodium, Dissolved 130 mg/L PALP-504B 210 01056 Manganese, Dissolved 380 ug/L ACLP-504B 210 22413 Total Hardness, Filtered 230 mg/L PALP-504B 210 39036 Total Alkalinity, Filtered 220 mg/L PALP-504B 210 70295 Total Dissolved Solids 620 mg/L PALP-504C 211 00094 Specific Conductance-Field (at 25C) 420 umhos/cm PALP-504C 211 00341 COD, Filtered 35 mg/L PALP-504C 211 00608 NH3-N, Dissolved 2.2 mg/L PALP-504C 211 00915 Calcium, Dissolved 37 mg/L PALP-504C 211 00925 Magnesium, Dissolved 29 mg/L PALP-504C 211 00930 Sodium, Dissolved 53 mg/L PALP-504C 211 00950 Fluoride, Dissolved 1.2 mg/L ACLP-504C 211 01046 Iron, Dissolved 0.35 mg/L ACLP-504C 211 01056 Manganese, Dissolved 62 ug/L ACLP-504C 211 22413 Total Hardness, Filtered 150 mg/L PALP-504C 211 39036 Total Alkalinity, Filtered 230 mg/L PALP-504C 211 70295 Total Dissolved Solids 350 mg/L PALOW-302BR 226 00094 Specific Conductance-Field (at 25C) 980 umhos/cm PALOW-302BR 226 00341 COD, Filtered 41 mg/L PALOW-302BR 226 00608 NH3-N, Dissolved 2.1 mg/L PALOW-302BR 226 00631 NO2 & NO3,N-Dissolved 7.6 mg/L ACLOW-302BR 226 00915 Calcium, Dissolved 210 mg/L PALOW-302BR 226 00925 Magnesium, Dissolved 72 mg/L PALOW-302BR 226 00930 Sodium, Dissolved 20 mg/L PALOW-302BR 226 00946 Sulfate, Dissolved 160 mg/L ACLOW-302BR 226 22413 Total Hardness, Filtered 640 mg/L PALOW-302BR 226 39036 Total Alkalinity, Filtered 470 mg/L PALOW-302BR 226 70295 Total Dissolved Solids 810 mg/L PALP-302CR 227 00094 Specific Conductance-Field (at 25C) 620 umhos/cm PALP-302CR 227 00341 COD, Filtered 60 mg/L PALP-302CR 227 00608 NH3-N, Dissolved 2.2 mg/L PALP-302CR 227 00915 Calcium, Dissolved 180 mg/L PALP-302CR 227 00925 Magnesium, Dissolved 38 mg/L PALP-302CR 227 00930 Sodium, Dissolved 78 mg/L PALP-302CR 227 01025 Cadmium, Dissolved 0.97 ug/L ACLP-302CR 227 01056 Manganese, Dissolved 500 ug/L ACLP-302CR 227 22413 Total Hardness, Filtered 230 mg/L PALP-302CR 227 39036 Total Alkalinity, Filtered 330 mg/L PALP-302CR 227 70295 Total Dissolved Solids 500 mg/L PALP-302AR 228 00094 Specific Conductance-Field (at 25C) 490 umhos/cm PALP-302AR 228 00341 COD, Filtered 53 mg/L PALP-302AR 228 00608 NH3-N, Dissolved 2.2 mg/L PALP-302AR 228 00915 Calcium, Dissolved 47 mg/L PALP-302AR 228 00925 Magnesium, Dissolved 34 mg/L PALP-302AR 228 00930 Sodium, Dissolved 49 mg/L PALP-302AR 228 01056 Manganese, Dissolved 58 ug/L ACLP-302AR 228 22413 Total Hardness, Filtered 190 mg/L PALP-302AR 228 39036 Total Alkalinity, Filtered 240 mg/L PALP-302AR 228 70295 Total Dissolved Solids 390 mg/L PAL

Attachment F WDNR Reporting Environmental

Monitoring Results Instructions

ENVIRONMENTAL MONITORING DATA CERTIFICATION

Note: This certification page, and any exceedance notification and explanation, must be preparedfor each license number included in the submittal (diskette or e-mail) and mailed to WDNRCentral Office with the submittal data. A copy of this form and any exceedance notification andexplanation must be mailed to the WDNR Regional Office in which the facility is located. DoNOT send the data submittal to the WDNR Regional Office.

[ ] Check here to indicate that a copy of this page (and a copy of the exceedance notificationletter, if any) was mailed to the WDNR Regional Office.

The accompanying submittal (diskette or e-mail) contains data for the following facility orfacilities:

License No Facility ID No (FID) Facility NameResults are for SamplingRequired in the Month(s) of:

Type of data submitted (check as applicable):

[ ] Groundwater monitoring data[ ] Non-groundwater monitoring data (gas, leachate, air)

Check one of the following:

[ ] An exceedance notification and explanation is attached.[ ] An exceedance notification is not attached because there are no exceedances to report.

( ) - Name of disk preparer Company name Phone Number(for disk formatting questions)

To the best of my knowledge, the information reported and the statements made on this datasubmittal and enclosures are true and correct. Furthermore, per ss. NR 140.24(1)(a), NR140.26(1)(a), NR 635.18(20) and NR 507.30, Wis. Adm. Codes, I have attached notification ofenforcement standard, preventative action limit, or alternative concentration limit exceedances,if any, which includes a list of the wells at which the exceedances occurred and a preliminaryanalysis of the cause and significance of the concentration.

Facility Representative's Name (please print) Date

( ) - Signature Phone Number

Title

Sample Record Layout

----+----1----+----2----+----3----+----4----+----5----+----6----+----7----+----8----+----9----+----100--+----1----+----2----+----3----+----4----+----

6 008931080094000092801 1 110 MMM .65 2.15 00090100100340751 EPA 9251 157066030

6 008931080104600092801 1 1.64 MMM .012 .041 00090100092940751 EPA 6010B 157066030

6 008931082241300092801 1 613 MMM .057 .190 00090100092940751 SM 2340B 157066030

Documents

Outagamie County Landfill