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Presentation by André Steynberg Overview of Sasol CTL Technologies & Recent Activities

Overview ofSasol CTL Technologies & Recent Activities

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Page 1: Overview ofSasol CTL Technologies & Recent Activities

Presentation by André Steynberg

Overview of SasolCTL Technologies & Recent Activities

Page 2: Overview ofSasol CTL Technologies & Recent Activities

Fischer-Tropsch Technology- The Foundation For CTL:

Mainly used to provide cleaner, more useful forms of energy

Enables access to diversified energy markets

Also (potentially) produces higher value co-products

ECONOMY OF SCALE IS ESSENTIAL FOR SUCCESS

Page 3: Overview ofSasol CTL Technologies & Recent Activities

Sasol’s FT Technology can be applied to multiple feedstocks

hydrogenNaturalgas“Heavy” Oil

Coal Biomass

renewable

Biomassto

Liquids(BTL)

Coalto

Liquids(CTL)

Gasto

Liquids(GTL)

FT Diesel

Similar products

Page 4: Overview ofSasol CTL Technologies & Recent Activities

Fischer-Tropsch Enablers

+Abundant, inexpensivehydrocarbon reserves

(coal, natural gas,biomass)

Global drive for cleaner

transportation fuels

Diversity of energy supply

Reduceddependenceon crude oil

+

+

+ FT

Common Drivers

Additional CTL Drivers

Page 5: Overview ofSasol CTL Technologies & Recent Activities

World Fossil Energy Reserves

0

1,000,000

2,000,000

3,000,000

4,000,000

5,000,000

6,000,000

7,000,000

8,000,000

AmericaEastern Europe &North America Central & South Western Europe

Former U.S.S.R.

Middle East Africa Far East & Oceania

Trill

ion

BTU

Crude Oil Natural Gas Coal

Global Energy Dynamics….

Proven reserves of fossil fuels will sustain the world for just over 300 years at current production rates

• Crude Oil 42 years• Natural gas 62 years• Coal 224 years Source : Chiyoda

Oil in Middle East ≈ 4,000,000

Trillion BTU

Coal in the US ≈5,200,000 Trillion

BTU

Energy content of coal in US more than oil in Middle East.

Page 6: Overview ofSasol CTL Technologies & Recent Activities

Drivers for CTL….Countries with access to:

large reserves of low cost gasifiable coal (a minimum of approximately 2 – 4 billion tons) at proposed location

Reserves to support further expansions

Adequate water resources close to proposed site

Suitable partners – Coal supplier, product marketer, power utility & other technology providers

Low construction cost countries

with good infrastructure (roads, railway, etc.)

Countries where suitable sites are close to large attractive markets

Countries with the ability and will to provide enabling support

Page 7: Overview ofSasol CTL Technologies & Recent Activities

CTL Challenges & BenefitsChallenges:

Critical mass of key industry players Capital intensive processEnvironmental issues:“Dirty coal” - public perception Permitting –no new refineries in the US since 1984

Benefits:Relatively low operating cost

Low feedstock cost: Price of coal = USD 10/t equivalent to ~ USD 0.50/MMBtuTechnologies facing dual challenges of capture and storage of CO2 – capture not major concern for CTL due to concentration of CO2 which allows for simple CO2 sequestration.Polygeneration

Might improve plant efficiency

Page 8: Overview ofSasol CTL Technologies & Recent Activities

Combined Production of Transportation Fuels and Electricity

Transportation fuels & electricity are the main conversion products for fossil fuels

There is no good reason why they should not be produced in the same facility

In the USA this concept is known as co-production

Polygeneration = POWER, FUELS & CHEMICALS

CAN PRODUCE SYNERGIES THAT IMPROVES THE CONVERSION EFFICIENCY TO THESE PRODUCTS

Page 9: Overview ofSasol CTL Technologies & Recent Activities

Secunda

CO2 Benfield

Synthol

Fresh Feed

MethaneReforming

CryogenicSeparation

CH4 Rich

PSAH2

Propylene

Separation

C3/C4

Rectisol CO2

Raw Gas

Pure Gas

1-octene1-hexene

Pt Reformer Gasoline

CondensationDistillation

OxygenateWork-up

AlcoholKetoneAcetic Acid

Reaction Water

Diesel

Catpoly

Ethylene

Cracker

C2=/C2

Gasoline

Isomerization

C5/C6

H2 Rich

Hydrotreat Diesel

ActivatedSludge

Cooling Water

GasificationWater

Page 10: Overview ofSasol CTL Technologies & Recent Activities

Sasolburg

Rectisol

Synthesisgas

Arge Reactors

SlurryBed

Reactor

MethanolReactor

CO2

H2 to NH3Production

Dew PointCorrection

Shift

Benfield PSA

Tailgas

TowngasProduct

Separation

ProductSeparation

ProductSeparation

Coal

Air

Gasification

AirSeparation

Oxygen

Raw gas

Page 11: Overview ofSasol CTL Technologies & Recent Activities

Copyright Reserved 2004 Sasol Synfuels International

Sasol’s current global FT activities

ChinaUSA

South Africa

European Union

South America

Africa

India

Australia

CNL & NNPC34 000 bpd

Nigeria EPC In progress

Qatar Petroleum/Sasol34 000 bpd

QatarUnder Construction

Gas-to-Liquids

Coal-to-Liquids

Sasol II & Sasol III160 000 bbl/dSouth AfricaIn Operation

Sasol ChevronAustralia

Study on GTL Opportunity progressing

Sasol/Shenhua/Ningxia2 x 80 000 bpd

China Feasibility Phase

Evaluating opportunities

SasolIran

Study on GTL Opportunity progressing

Page 12: Overview ofSasol CTL Technologies & Recent Activities

Copyright Reserved 2004 Sasol Synfuels International

China CTL project status

Guahoungz

Nanjing

Tianing

Fushun

Ningxia

Shenhua

Hong Kong

Beijing

Identified 2 sites in coal rich westernpart of China:

Ningxia Autonomous region

Shaanxi province

Plant capacity ~ 85 000 barrelsper day per siteCapital cost US$ 60 000 to 80 000/daily bblDue to enter full feasibility study in 2nd quarter 2006

Page 13: Overview ofSasol CTL Technologies & Recent Activities

Copyright Reserved 2004 Sasol Synfuels International

Sasol’s future FT approach…..

Sasol wants to remain the leading producer of clean fuels from non-petroleum sources

Main focus is on natural gas feedstock (GTL)

Considering coal feedstock (CTL) where strategic drivers exist (e.g. China, USA)

Will develop biomass options (renewable) with time (BTL)

Page 14: Overview ofSasol CTL Technologies & Recent Activities

Variety of Industrial Processes

Gas/Coal processingSyngas production akin to MeOH and ammonia plants Hydrocarbon synthesis - gas, liquid and solid mixtures- recycles and solids separation- large volumes flammable materials at high pressure that auto-igniteRefinery operationsSpecialty chemical processing Integrated utility systems Power generationCatalyst manufacture has elements of mineral processing combined with the precision found in the pharmaceutical industry

Page 15: Overview ofSasol CTL Technologies & Recent Activities

Get by with a little help from our friends…

Gas processing – Chevron/ Foster Wheeler

Gas conversion – Haldor-Topsoe/ Lurgi/ Linde/…Hydrocarbon synthesis – In-house/ Stone & Webster/ IHI and others

Refinery operations – Chevron/ UOP/ IFP

Integrated utility systems – Foster Wheeler

Power generation – Foster Wheeler and others

Catalyst manufacture – Engelhard (Co)/ SudChemie (Fe)

EPC – most competitive bid

ASU – most competitive bid/ Air Liquide

Page 16: Overview ofSasol CTL Technologies & Recent Activities

The 3 different Sasol Fischer-Tropsch technologies

Cobalt low temperature Fischer -Tropsch (Co-LTFT)Iron low temperature Fischer-Tropsch (Fe-LTFT)Iron high temperature Fischer-Tropsch (Fe-HTFT)

The 3 technologies produce fundamentally different types of hydrocarbons and thus ultimately have the potential to produce different chemical products

0%

10%

20%

30%

40%

50%

60%

70%

80%

90%

100%

Co-LTFT Fe-LTFT Fe-HTFT

Olefins alkanes oxygenates aromatics

Page 17: Overview ofSasol CTL Technologies & Recent Activities

Sasol’s three different Fischer-Tropsch technologies

Gas

Coal

Fuels Chemicals

Fe-LTFTFe-LTFT

Fe-HTFTFe-HTFT

Co-LTFT

Page 18: Overview ofSasol CTL Technologies & Recent Activities

Recommendations for CTL Applications:

Power export (co-production) should be a feature from the outset

Each potential site should consider the business case for a

footprint plant and the eventual targeted product spectrum

Starting with fuel value products and gradually phasing in the high value products is a successfully proven business model

Alternative approaches only making high value products from the

outset will be complex leading to start-up delays

and difficulties in placing products in the market

Message: look for a simple starting scheme that allows the ultimate business objective to be achieved with a phased approach

Page 19: Overview ofSasol CTL Technologies & Recent Activities

Sasol’s Fe-LTFT technology – the footprint plant

Gas

Coal

Fuels Chemicals

Fe-LTFT

Coal

Tail gas (electricity)

Sasol Fe-LTFT

30 % Naphtha

68% Diesel

Syngas production

Product upgrading

Sasol’s Iron low-temperature technology is ideally suited for the production of diesel from Coal (CTL technology).

Very high quality Naphtha is produced -- ideal for steam crackers.

Best option for a simple footprint plant.

Need a use for the FT tail gas.

2 % LPG

Page 20: Overview ofSasol CTL Technologies & Recent Activities

Sasol’s Fe-HTFT technology –footprint plantsGas

Coal

26% Propylene

33 % Diesel

Fuels Chemicals

Coal

3 % LPG

SASOLFe -HTFT

33 % Naphtha

Syngas production

Product upgrading

5 % other olefins and oxygenates

HTFT products are highly olefinic and these olefins are ideal buildingblocks for producing high value products.

A simple initial product offering is possible. Various options exist and an example here illustrates a propylene, diesel and naphtha footprint plant.

Propylene volumes that accompany a reasonable scale diesel plant match well with a world scale polypropylene plant.

Major products are aimed at large markets (fuels, propylene & ethylene),to obtain economy of scale with syngas preparation and FT synthesis.

Most capital intensive product upgrading processes but some progresshas been made to decrease these costs.

Fe-HTFT

Page 21: Overview ofSasol CTL Technologies & Recent Activities

Target propylene and ethylene -- these are large chemicals markets

0.00

1.00

2.00

3.00

4.00

5.00

6.00

7.00

0 200 400 600 800Relative value

grow

th % LPG

Gasoline

DieselNaphtha

Methanol

Baseoils

Industrial ethanol

Propylene

Ethylene

LAB

DA

Butanol

1-butene

Hexene

Octene

Iso-propanol

Page 22: Overview ofSasol CTL Technologies & Recent Activities

Sasol’s Fe-HTFT technology with additional chemicalsGas

Coal

26% Propylene

33 % Diesel

Fuels Chemicals

Coal

3 % LPG

SASOLFe -HTFT

33 % Naphtha

Syngas production

Product upgrading

5 % other olefins and oxygenates

Fe-HTFT

Further processing of the streams

EthyleneButene and butylenesHexeneOcteneNoneneDetergent alcoholsEthanolN and iso-propanolN and iso-butanolAcetone MEK

Complex due to many different products with differed market drivers. Therefore a phased approach has proven to be successful