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PANDIT DEENDAYAL PETROLEUM UNIVERSITY
SCHOOL OF TECHNOLOGY
COURSE STRUCTURE FOR M. TECH. CHEMICAL ENGINEERING
From Academic year (2017-2018)
SEMESTER I M.TECH. CHEMICAL ENGINEERING
Sr.
No
Course
Code Course Name
Teaching Scheme Exam Scheme
L T P C Hrs/wk Theory Practical Total
Marks MS ES IA LW LE
1 MA 503T* Advanced Numerical Techniques and
Computer Programming 3 1 0 4 4 25 50 25 -- -- 100
2 MA 503P* Advanced Numerical Techniques and
Computer Programming Lab 0 0 2 1 2 -- -- -- 25 25 50
3 CH 501T Advanced Transport Phenomena 3 0 0 3 3 25 50 25 -- -- 100
4 CH 502T Advanced Chemical Reaction
Engineering 3 0 0 3 3 25 50 25 -- -- 100
5 CH 503T Advanced Chemical Engineering
Thermodynamics 3 0 0 3 3 25 50 25 -- -- 100
CH 504P Experimental and Software Lab 0 0 4 2 4 -- -- -- 25 25 50
6 CH 50X Elective-I 3 0 0 3 3 25 50 25 -- -- 100
Total 15 1 6 19 22 125 250 125 50 50 600
MS = Mid Semester, ES = End Semester, IA = Internal assessment (like quiz, assignments etc), LW = Laboratory work, LE = Lab Exam
CH 501T Advanced Transport Phenomena
Teaching Scheme Examination Scheme
L T P C Hrs/Week Theory Practical Total
marks MS ES IA LW LE/Viva
3 - - 3 3 25 50 25 - - 100
Course Objective:
Understand the concept of different conservation principles.
To develop understanding of different constitutive laws.
Unit I
Introduction: Examples; Types/Uses of Control Volumes; Notion of Conservation Principles and
Constitutive Laws; Illustrations of Use.
Unit -II
Conservation Principles: Mass, Momentum, Energy, Entropy; Alternative Forms; statement of
Assumptions.
Unit III
Constitutive Laws: Diffusion Flux Laws/ Coefficients, general constraints; Momentum/ Energy/
Mass Diffusion Laws; Multi-component mass diffusion; Reaction rates, mechanisms, time-scales.
Unit IV
Momentum Transport Mechanisms, Rates & Coefficients in CRFS.
Energy Transport Mechanisms, Rates & Coefficients in CRFS.
Analogies & Similitude Analyses with Application to CRFS.
Unit V
Problem-Solving Techniques, Aids, Philosophy.
Texts and references:
1. J. M. Coulson and J. F. Richardson, Chemical Engineering Vol. I Pergamon Press, 1970
2. R. B. Bird, W. E Stewart, and E. N. Lightfoot, Transport Phenomena, Edition-I John Wiley,
1960.
C. O. Bannet, and J. E. Myers, Momentum, Heat and Mass Transfer 3rd
ed. McGraw Hill, 1982.
Course Outcomes:
Able to apply the concept of transport mechanism.
Able to apply different analogies in different applications.
CH 502T Advanced Chemical Reaction Engineering
Teaching Scheme Examination Scheme
L T P C Hrs/Week Theory Practical Total
marks MS ES IA LW LE/Viva
3 - - 3 3 25 50 25 - - 100
Course Objective:
To Develop understanding of non ideal reactor design.
Understand the concept of heterogeneous reaction system for reactor design.
Syllabus:
UNIT I
Review of isothermal and Adiabatic reactor design. Steady and unsteady state operations. Heat
effects. Concept of multiple study state in CSTR.
Homogeneous reactor design and analysis for non ideal reactors. Residence time distributions
(RTD) studies. Single and multi parameter models for real reactor behavior, macro and micro
mixing, segregated flow model
Unit II
Heterogeneous reactors-gas-solid systems-Reviews of kinetics of gas-solid catalytic reactions
with and without diffusion limitations. Solid catalysts and theirs application in reactor design
for fixed and fluidized bed reactors.
Unit-III
Design for non catalytic gas-liquid reactions. Review of kinetic regimes in reactor design, case
studies. Gas-liquid systems, basic theories of mass transfer with chemical reaction. Reactor
design for mechanically agitated and bubble column reactors, selected case studies.
Unit-IV
Bio Chemical Reaction and Bio reactors: Enzyme Fermentation, microbial fermentation,
substrate-limiting and product limiting Microbial fermentation. Bio-reactor design.
Texts and references:
1. Rawlings J.B. and Ekerd, J.G., Chemical Reactor Analysis and Design Fundamentals
Nole. Hill 2002.
2. Scot Foggler, H, Elements of Chemical Reaction Engg – PHI- 4th Edition- 2005.
3. Carberry, J.J. Chemical and Catalytic reaction engineering, Doven Publishers, 2001
4. Froment G.F. and Bischoff, K.B. Chemical Reactor Design and Analysis, 2nd Ed., John
Wiley and Sons NY, 1997.
5. O. Levenspiel,” Chemical Reaction Engineering” Willey Eastern, 3rd Ed., 2000
6. Chemical Reactor Design and Operation by K. R. Westerterp, W. P. M. Van Swaaij and
A. A. C. M. Beenackers
Course Outcomes:
Able to design real reactors with single and multiple parameter models.
Able to review kinetic regimes in reactor design.
CH 503 Advanced Chemical Engineering Thermodynamics
Teaching Scheme Examination Scheme
L T P C Hrs/Week Theory Practical Total
marks MS ES IA LW LE/Viva
3 - - 3 3 25 50 25 - - 100
Course Objective:
Understand the concept of statistical thermodynamics.
To gain knowledge of excess functions.
Syllabus:
Unit I: - Basic differences between classical thermodynamics, statistical and molecular
thermodynamics. Fundamental concepts of statistical thermodynamics. Property estimation.
The Phase equilibrium problem: Phase Equilibrium in Multi-phase Closed Systems, Gibbs-
Duhem Equation, Chemical Potential, Fugacity and Activity, Raoult’s Law: It’s deduction and
Application.
Unit III: - Fugacities in liquid mixtures – excess functions: Ideal Solution, Fundamental
Relations of Excess Functions, Fugacities in high pressure Redlich-Kwong and P-R equation
of state, Activity and Activity Coefficients, Activity Coefficients from Excess Functions in
Binary Mixtures, Application of Gibbs-Duhem Equation: Application of Gibbs-Duhem
Equation: Testing Equilibrium Data for “Thermodynamic Consistency". Wohl’s Expansion for
Excess Enthalpy, Wilson, NRTL, and UNIQUAC Equations.
Unit- III: Thermodynamic criteria of miscibility. Intermolecular Forces and the theory of
corresponding states potential energy functions for different molecular systems; Polar and non-
polar molecules. Theories of solutions: van Laar, Scatchard-Hildebrand theory, Lattice theory,
two liquid theories, Flory-Huggins theory.
Unit IV: - Fluid phase equilibria in multi component system: – Calculation of vapor liquid
equilibria using equations of state and activity coefficient approach. Classical and excess free
energy based mixin g rules; Theories of solutions; Liquid models with special emphasis on
NRTL, UNIQUAC and UNIFAC theories; Solid Liquid Equilibria (SLE); Vapor Liquid Liquid
Equilibria (VLLE); Phase Equilibria of Solid- Solid Mixtures
Texts and References
1. J. M. Prausnitz, R. N. Lichtenthaler and E. G. d e Azevedo, Molecular Thermodynamics of
Fluid Phase Equilibria , Prentice Hall, 1999.
2. S. I. Sandler, Chemical, Biochemical and Engineering Thermodynamics, 4th
Ed., Wiley
India, 2006.
3. J. M. Smith, H. C. V. Ness and M.M. Abott, Introduction to Chemical Engineering
Thermodynamics , McGraw Hill, 2003.
4. Chemical Engineering Thermodynamics by Y. V. C. Rao
5. R.C. Reid, J.M. Prausnitz and B.E. Poling, Properties of Gases and Liquids, 4th ed.,
McGraw-Hill, 1987.
Course Outcomes:
Able to differentiate between classical thermodynamics, statistical and molecular
thermodynamics.
Able to do calculation of vapor liquid equilibria in multicomponent system.
CH 504P Experimental and Software lab Teaching Scheme Examination Scheme
L T P C Hrs/Week Theory Practical Total
marks MS ES IA LW LE/Viva
- - 4 2 4 - - 25 25 50
List of Experiments:
1. Vapor liquid equilibrium measurement
2. Reaction calorimeter
3. Computer controlled distillation unit
4. Membrane fabrication and characterization
5. Adsorption measurement facility
6. Biodiesel production and characterization
7. Supercritical extraction plant
8. Gas absorption-regeneration pilot plan plant
Software lab (solving open ended problem using Aspen and Matlab)
1. Solving Phase equilibrium problems
2. Solving advanced Transport phenomena problems
3. Solving Advanced Reaction Engineering Problems
4. Solving Advanced Thermodynamics problems
5. Regression analysis
CH 511T Advanced Biochemical Engineering
Teaching Scheme Examination Scheme
L T P C Hrs/Week Theory Practical Total
marks MS ES IA LW LE/Viva
3 -- -- 3 3 25 50 25 -- -- 100
Course Objective:
To gain knowledge of biochemical reactions.
To understand mass and heat transfer in bio chemical reaction systems
UNIT I
Introduction to biochemical reactions, diversity in the biological reactions, immobilized enzyme
processes, preparation methods, characterization, and mechanisms and applications of enzyme
catalysis (biocatalysis), enzyme inhibition and deactivation, enzyme kinetics, reactor engineering
aspects of enzymatic process
Unit II
Overview of cell physiology and biochemistry, applications of microbial/animal cell culture in
biotechnology, microbial growth, phases of cell growth in batch cultures; handling and
sterilization techniques, simple unstructured kinetic models for microbial growth; growth
associated product formation kinetics; batch cultivation profiles, stoichiometry of product
formation, models of microbial, continuous culture, animal cell culture, mixed cultures, bio-
product recovery, bio-separations and purification.
Unit III
Mass transfer in biochemical reaction systems, rheology of the cell culture, heat transfer
processes in biological systems, oxygen transfer fermentation processes, oxygen uptake transfer
coefficients, transport correlations, role of aeration and agitation/mixing in oxygen transfer,
power input to bioreactor.
Unit IV
Detail designing of bioreactors, materials of construction, vessel geometry, assemblies, motor
drives, aseptic seals; flow measuring devices, valves, agitator and sparger design, sensors and its
accessories, different types of bioreactors, multiphase reactors for plant and animal cell
propagation, reactors for waste-treatment processes, continuous/batch operational modes of
reactors, recycles and continuous cultivation bioreactors, scale-up and scale-down criteria.
Texts and references:
1. Bailey J.E and Ollis, D. F. Biochemical Engineering fundamentals, McGraw Hill (1986).
2. Michael L. Shuler and Fikret Kargi, Bioprocess Engineering: Basic Concepts, 2nd
Edition,
Prentice Hall (2002).
3. Harvey W. Blanch, and D. S. Clark, eds. Biochemical Engineering. New York, NY: Marcel
Dekker Incorporated, (1997).
4. Pauline M. Doran, Bioprocess Engineering Principles, 2nd
edition, Academic Press (2012).
5. Peter F. Stanbury, Allan Whitaker and Stephen J. Hall, Principles of Fermentation
technology, 2nd
edition, Butterworth Heinemann (2003).
Course Outcomes:
Able to understand cell physiology and biochemistry.
Able to design different type of bio reactors.
CH 511T Advanced Process Synthesis
Teaching Scheme Examination Scheme
L T P C Hrs/Week Theory Practical Total
marks MS ES IA LW LE/Viva
3 -- -- 3 3 25 50 25 -- -- 100
Course Objective:
To gain knowledge of different type of chemical process sysyems.
To study different separation systems.
UNIT I
Development of Chemical Process Systems; Process Synthesis, Process Integration, Philosophy
of Targeting, Thermodynamic Approach, Mathematical Programming Approach.
Unit II
Heat Exchanger Networks, Maximizing Heat Recovery; Network Evaluation, Utility and Power
Systems; Total Site Integration
Unit III
Separation Systems, Distillation Column Sequencing and Integration; Distillation of Multi-
component Mixtures, Mass Exchange Networks; Residue Curve Mapping, Reactor Networks,
Systems Synthesis
Unit IV
Reactor-Separator-Recycle Systems: Grassroots and Retrofit Designs, Multiple Base Case
Designs; Flexibility Considerations; Industrial Applications and Case Studies (Reactive
Distillation)
Texts and references:
1. Shenoy, U.V., “Heat Exchange Network Systhesis: Process Optimization by Energy and
Resource Analysis”, Gulf Publishing Company, Houston, Texas, 1995.
2. Doherty, Michael F., Malone, Michael F., “Conceptual Design of Distillation System”,
Mcgraw-Hill Chemical Engineering Series, 2001.
3. Rudd, D.F., Powers, G.J., and Siirola, J.J., “Process Synthesis”, Prentice Hall, Englewood
Cliffs, N.J., 1973.
4. Sundmacher, Kai, Kienle, Achim, “Reactive Distillation: Status and Future Directions”,
John Wiley & Sons, 2006.
Course Outcomes:
Able to design heat exchanger metworks.
Able to design reactor-separator-recycle systems.
CH 504 Advanced Separation and Purification Technology
Teaching Scheme Examination Scheme
L T P C Hrs/Week Theory Practical Total marks MS ES IA LW LE/Viva
3 -- -- 3 3 25 60 25 -- -- 100
Course Objective:
To gain knowledge of membrane separation processes.
To gain knowledge of adsorption and ion exchange processes and study adsorption
equilibrium and isotherms for different type of systems.
Unit I: - Membrane Processes: Fundamentals of separation processes, Separation factor,
various separation processes. membrane separation processes, membrane materials, module
design and module characteristics, Reverse osmosis, ultrafiltration , microfiltration,
Nanofiltration. ion exchange techniques and operation, Gas separation: mixing model for gas
separation, cross flow model, counter current flow model, single stage membrane separation,
multistage membrane separation, differential permeation with point permeate withdrawal,
bubble/dew point type curve.
Unit II: -Physical and chemical adsorption, adsorbents, adsorption equilibrium and isotherms.
Single-stage, multi-stage cross-current and multi-stage counter current operations, equilibrium
and operating lines. Liquid-solid agitated vessel adsorber, packed continuous contactor,
breakthrough curves. Rate equations for non-porous and porous adsorbents, nonisothermal
operation, pressure-swing adsorption. Principles of ion exchange, analogy between adsorption
and ion exchange.
Unit III: - Room Temperature Ionic liquids (RTIL): Physico-chemical properties of RTIL,
reactivity, solvating power, non aqueous solvents. Ionic Liquids as advanced materials in
analytical separations, absorption/adsorption, membrane separations and purification.
Applications of Ionic Liquids in biotechnology and biorefining, Chemicals and petrochemicals,
CO2- separation, environmental remediation, waste treatment.
Texts and References (1) R. Rautenbach, and R. Albercht, “Membrane Processes”, John Wiley & Sons,(1994)
(2) Simon Judd., Principles and Applications of Membrane Bioreactors for Water and
Wastewater Treatment, Elsevier, 9780080465104, 2011
(3) Scott T. Handy, Application of Ionic liquids in Science and Technology, InTech
Publication, ISBN 978-953-307-605-8, 2011
(4) Elsa Lundanes, Leon Reubsaet, Tyge Greibrokk, Chromatography: Basic Principles, Sample
Preparations and Related Methods, Wiley-VCH , 2014, ISBN: 978-3-527-33620-3
(5)Membrane Handbook Eds. By W. S. W. Ho and K. K.Sirkar
(6)Synthetic membranes : Science, Engineering and Applications, Eds. By P. B. Bunge, H. K.
Lonsdale and M. N. dePinho.
Course Outcomes:
Able to design membrane module for different type of membrane processes.
Apply the principles and knowledge of adsorption , to establish rate equations for non-
porous and porous adsorbents
PANDIT DEENDAYAL PETROLEUM UNIVERSITY
SCHOOL OF TECHNOLOGY
COURSE STRUCTURE FOR M. TECH. CHEMICAL ENGINEERING
From Academic year (2016-2017)
SEMESTER II M.TECH. CHEMICAL ENGINEERING
Sr.
No
Course
Code Course Name
Teaching Scheme Exam Scheme
L T P C Hrs/wk
Theory Practical Total
MS ES IA LW LE Marks
1 CH 508T Computer Aided Process Engineering 3 0 0 3 3 25 50 25 -- -- 100
2 CH 508P Computer Aided Process Engineering Lab 0 0 4 2 4 -- -- -- 25 25 50
3 CH 509T Advanced Process Control 3 0 0 3 3 25 50 25 -- -- 100
4 CH 510T Unit Operations and Processes in
Environmental Engineering 3 0 0 3 3 25 50 25
100
5 CH 51X Elective II 3 0 0 3 3 25 50 25 -- -- 100
6 CH 51X Elective III 3 0 0 3 3 25 50 25 -- -- 100
8 CE 527T Successful Research Program
Development 2 0 0 Au 2 25 50 25 -- -- NP/PP
Total 17 0 4 17 21 150 300 150 25 25 550
CH 508T Computer Aided Process Engineering
Teaching Scheme Examination Scheme
L T P C Hrs/Week Theory Practical Total
marks MS ES IA LW LE/Viva
3 -- 3 25 50 25 -- -- 100
Course Objective:
To give knowledge of process plant modeling and simulation.
To understand thermodynamic property estimation in simulations.
To identify the importance of process and greenhouse gas emission analysis.
To understand process economic analysis.
Unit I Introduction to Process Plant modeling and Simulation: Classification and development of
mathematical models to various chemical engineering systems; and components in a process
simulation package. Different approaches to process simulation, Steady-state sequential modular
and equation oriented simulation techniques: decomposition of networks; Tearing algorithms,
Flowsheet Calculations and Model Analysis Tools, Sensitivity analyses, Design specifications.
Unit II
Thermodynamic property estimation in process simulations: Property model specifications,
Property data requirements and input, Physical property analysis, Data regression and estimation
of interaction parameters. Recycle convergence algorithms; problem solving using selected
commercial simulators; Dynamic process plant simulation.
UNIT III
Process Energy and Greenhouse gas emission analysis: Activated Energy Analysis, Identifying
energy and greenhouse gas reduction in the design process, Optimize energy savings with
alternative design options. Setting Up an Energy Analysis Project, Generating Process Revamp
Solutions, Introducing Heat Exchanger Changes to Process Flowsheet, Analyzing and Fine-
Tuning Heat Integration Results, Heat Exchanger Network Diagram and Composite Curves,
Unit IV
Process Economic Analysis: Activated Economics Workflow and Economic Analysis, Setting up
Costing Options, Setting up Utilities, Mapping Unit Operations and Sizing and Evaluating
Equipment. CAPEX estimates and OPEX estimates for comparing and screening multiple
process schemes. ASPEN economic evaluation
Texts and references:
1. Crowe, C. M., Hamielec, A. E., Hoffman, T.W., Johnson, A. I., Woods, D.R., and
Shannon P. T., Chemical Plant Simulation, Prentice Hall, Inc., Englewood Cliff, New
Jersey, 1971.
2. Husain, A., Chemical Process Simulation, Wiley Eastern Limited, New Delhi, 1986.
3. Luyben, William, Process Modeling, Simulation, and Control for Chemical Engineers,
McGraw Hill, New York, 1990.
4. Lorenz T. Biegler, E.I. Grossmann, and A.W. Westerberg, Systematic Methods of
Chemical Process Design, Prentice Hall International Inc. Series in the Physical and
Chemical Engg. Sciences, N. J., 1997.
5. A.C. Dimian, Integrated Design and Simulation of Chemical Processes 1st Edition,
Elsevier Science, 2003.
Course Outcomes:
Able to do flow sheet calculations and model analysis.
Able to do comparative economic analysis by CAPEX and OPEX.
CH 511T Advanced Process Control
Teaching Scheme Examination Scheme
L T P C Hrs/Week Theory Practical Total
marks MS ES IA LW LE/Viva
3 -- -- 3 3 25 50 25 -- -- 100
Course Objective:
To understand control relevant linear Perturbation Models.
To identify and understand different dynamics problem.
UNIT I
Introduction and Motivation, Development of Control Relevant Linear Perturbation Models,
Linearization of Mechanistic Models, Introduction to z-transforms and Development of Grey-
box models,
Unit –II
Development of Linear Black-box Dynamic Models, Development of Control Relevant Linear
Perturbation Models (Part 2), Introduction to Stability Analysis and Development of Output
Error Models, Introduction to Stochastic Processes, Development of ARX models, Statistical
Properties of ARX models, Development of ARMAX models and Issues in Model
Development, Model Structure Selection, and State Realizations of Transfer Function Models
Unit III
Stability Analysis, Interaction Analysis and Multi-loop Control, Stability Analysis of Discrete
Time Systems, Lyapunov Functions. State Estimation and Kalman Filtering, Multivariable,
Decoupling Control, Soft Sensing and State Estimation, Development of Luenberger Observer,
Introduction to Kalman Filtering
Unit-IV
Linear Quadratic Optimal Control and Model Predictive Control, Pole Placement State Feedback
Control Design and Introduction to Linear Quadratic Gaussian (LQG) Control.
Texts and references:
1. Astrom, K. J., and B. Wittenmark, Computer Controlled Systems, Prentice Hall India (1994).
2. Franklin, G. F., Powell, J. D., and M. L. Workman, Digital Control Systems, Addison
Wesley, 1990.
3. D. E. Seborg, T. F. Edgar, D. A. Mellichamp, Process Dynamics and Control, Wiley, 2003.
4. Graham C. Goodwin, Stefan F. Graebe, Mario E. Salgado, Control System Design, Prentice
Hall, 2000.
Course Outcomes:
Able to do stability analysis.
Able to develop grey box and black box dynamic models.
CH 511T Unit Operations and Processes in Environmental Engineering
Teaching Scheme Examination Scheme
L T P C Hrs/Week Theory Practical Total
marks MS ES IA LW LE/Viva
3 -- -- 3 3 25 50 25 -- -- 100
Course Objective:
To understand water and waste water system design.
To understand and identify preliminary unit operations.
UNIT I
Introduction, Water, wastewater system design overview. Water demand, wastewater generation.
Water quality criteria. Mass balances, kinetics, reactor design.
Unit II
Chemical Engineering Approaches, Mass Transfer and Mixing, Aeration, Agitation for
environmental processes, Sag curves, Estimation of lumped oxygen transfer concentration
Unit III
Preliminary unit operations and processes, Equalization, Sedimentation, Filtration, Leaching,
Ammonia Removal, Adsorption, Ion Exchange, Membranes, Desalination, Chemical
Equilibrium, Coagulation and Flocculation, Disinfection.
Unit IV
Biological treatment of wastes: New bio-treatment, Batch Bioprocesses, Continuous Processes,
Denitrification, Mixed Cultures, Old version of Biological treatment of wastes, Activated
Sludge, Oxygen Transfer and Mixing, Trickling Filters and Rotary Biological Contactors,
Stabilization Ponds and Aerated Lagoons, Anaerobic Digestion, Aerobic Digestion, Solids
Handling, Land Treatment of Municipal Wastewater and Sludges, Sludge Incineration, Sludge
disposal.
Texts and references:
1. Tom D. Reynolds, Paul Richards, Unit Operations and Processes in Environmental
Engineering, CL Engineering, second edition, 1995.
2. R. Noyes, Unit Operations in Environmental Engineering, first edition, Noyes Publications,
1994.
Course Outcomes:
Able to do lumped oxygen transfer concentration.
Able to identify biological treatment waste from the available treatment processes.
CH 508P Computer Aided Process Engineering Lab
Teaching Scheme Examination Scheme
L T P C Hrs/Week Theory Practical Total
marks MS ES IA LW LE/Viva
-- -- 4 2 4 -- -- -- 25 25 50
Study state Process Plant simulation
Dynamic Plant simulation
Simulation of Mass transfer processes
Simulation of Heat transfer processes
Simulation of fluid flow and pressure change processes
Thermodynamic Property and property estimation
Process energy analysis
Process economic analysis
Process greenhouse gas analysis
CH 507T Modeling and Simulation
Teaching Scheme Examination Scheme
L T P C Hrs/Week Theory Practical Total
marks MS ES IA LW LE/Viva
3 -- -- 3 3 25 50 25 -- -- 100
UNIT I
Introduction to process modeling - a systematic approach to model building, classification of
models. Conservation principles, thermodynamic principles of process systems. Development of
steady state and dynamic lumped and distributed parameter models based on first principles.
Analysis of ill-conditioned systems. Models with stiff differential equations.
Unit -II
Development of grey box models. Empirical model building. Statistical model calibration and
validation. Examples. Introduction to population balance models, multi-scale modeling.
Unit III
Solution strategies for lumped parameter models and stiff differential equations. Solution
methods for initial value and boundary value problems. Euler’s method. R-K methods, shooting
method, finite difference methods – predictor corrector methods.
Unit IV
Solution strategies for distributed parameter models. Solving parabolic, elliptic and hyperbolic
partial differential equations. Introduction to finite element and finite volume methods.
Solving the problems using MATLAB/SCILAB.
Texts and references:
1. K. M. Hangos and I. T. Cameron, “Process Modeling and Model Analysis”, Academic
Press, 2001.
2. W.L. Luyben, “Process Modeling, Simulation and Control for Chemical Engineers”, 2nd
Edition, McGraw Hill Book Co., New York, 1990.
3. Singiresu S. Rao, “Applied Numerical Methods for Engineers and Scientists” Prentice
Hall, Upper Saddle River, NJ, 2001
4. Bruce A. Finlayson, Introduction to Chemical Engineering Computing, Wiley, 2010.
5. W. F. Ramirez, “Computational Methods for Process Simulation”, 2nd ed., Butterworths,
1997.
6. Amiya K. Jana, Chemical Process Modelling and Computer Simulation, Prentice Hall of
India, 2nd
Edition, 2011
7. Laurene V. Fausett, Applied Numerical Analysis using MATLAB, Second edition,
Pearson, 2009
CH 511T Nano Science and Technology
Teaching Scheme Examination Scheme
L T P C Hrs/Week Theory Practical Total
marks MS ES IA LW LE/Viva
3 -- -- 3 3 25 50 25 -- -- 100
Course Objective:
To understand the fundamentalsof Nanotechnology
Explain the nanoscale paradigm in terms of properties at the nano scale dimension.
Identify current nanotechnology solutions in design, engineering and manufacturing.
UNIT I
Introduction to nano size materials and their properties: physical, chemical and biological
properties from their constituent atoms or molecules and from the bulk materials, Quantum
Mechanics, Chemical Kinetics at nano-scale.
Unit -II
Synthesis of nano materials, bottom-up approach: self-assembly and self-organization, apor
phase deposition, plasma assisted deposition processes, colloidal, sol-gel, or simple pyrolysis,
top-down approach: miniaturization of smaller structures from larger ones like milling,
lithography, machining will be presented with suitable examples.
Unit III
Detailed characterization technique based on radiation matter interactions and their analytical
applications like imaging microscopy and spectroscopy will be used in interpreting the nano
structured objects.
Unit-IV
Applications of nano materials in chemical engineering, biological and bio medical.
Functionalized nano particles for biological applications, bio-mineralization, and biomimetic
nanotechnology will be introduced.
The safety and storage issues and the impact of nanotechnology on the environment will be
stressed at the end.
Texts and references:
1. Nanoscale science and technology, John Wiley & Sons., 2005.
2. Stuart M. Lindsay, Introduction to Nanoscience, Oxford University Press, 2009.
3. Sulabha K. Kulkarni, Nanotechnology: Principles and Practices, Capital Publishing
Company, 2007.
4. Nanomaterials: synthesis,properties and applications, Instituite of Physics, 1998.
5. Nanobiotechnology, concepts, applications and perspectives, Wiley-VCH, 2004.
Course Outcomes:
Able to interpret characterization data for nano particle.
Able to identify the application of different type of nano materials.
CH 511T Complex Fluids
Teaching Scheme Examination Scheme
L T P C Hrs/Week Theory Practical Total
marks MS ES IA LW LE/Viva
3 -- -- 3 3 25 50 25 -- -- 100
Unit I
Physics of the complex fluids; polymers, colloids, emulsions, surfactants, foams, gels, glasses,
liquid crystals, surface active polymers, biological lipids, proteins, serum lipoproteins, biological
membranes, membrane proteins, general characteristics and properties, phase behavior, chemical
bonding, particle interactions, atomic and molecular arrangements, phase transitions, and
elasticity of the complex fluids
Unit II
Introduction, fundamentals, statistical mechanics and thermodynamics review, study of
Boltzmann, Fermid-Dirac and Bose-Einstein statistics, classical statistical thermodynamics,
distribution functions; virial expansions; the Debye-Hückel theory, lattice models for liquids; the
Bragg-Williams approximation, account for the physical interpretation of partition functions and
relation to thermodynamic properties of model systems, physical characteristics of complex
fluids using the thermodynamic models, account for the fundamental ideas in the theory for
calculations of properties of complex fluids.
Unit III
Theory of rheometry, rheology of polymer solutions - techniques, pitfalls & interpretation of
rheological results, techniques for characterization of complex fluid structure, scattering
techniques, light, x-ray, and neutron scattering applied to studies of the structure and dynamics
of complex liquids.
Unit IV
Forces near interfaces, wetting and long-range forces, disjoining pressure, forces in colloidal
systems, contrasts between intermolecular, interparticle, and intersurface forces; solvation,
structural and hydration forces; steric and fluctuation forces, role of the interfacial forces in
complex fluids, Electrostatic interactions in colloidal systems, Electrical charges in dispersions,
Electrochemistry of interfaces, Electrokinetic phenomena, self-assembled structures, micelles,
structural characterization.
Texts and references:
1. Maurice Kleman, Soft Matter Physics: An Introduction, Springer Verlag, 2003
2. Samuel A. Safran, Statistical Thermodynamics of Surfaces, Interfaces and Membranes,
Westview Press Inc, 2003
3. Ronald G. Larson, The Structure and Rheology of Complex Fluids, Oxford University Press,
1999
4. Christopher W. Marcosto, Rheology: Principles Measurements and Applications, Wiley
VCH, 1994
5. Michael Rubinstein and Ralph H. Colby, Polymer Physics, Oxford University Press, 2003
6. Jacob Israelachvili, Intermolecular and Surface Forces, Academic Press, 2011
CH 511T Colloids and Interfacial Science and Engineering
Teaching Scheme Examination Scheme
L T P C Hrs/Week Theory Practical Total
marks MS ES IA LW LE/Viva
3 -- -- 3 3 25 50 25 -- -- 100
UNIT I
Colloidal materials, practical applications, surface and colloidal phenomena in industry and
nature, Brownian motion and Brownian flocculation, sedimentation, centrifugation, diffusion,
coagulation kinetics, cohesion and adhesion, physical and chemical interactions between atoms
and molecules interactions between particles, van der Waals forces, steric forces, stability of
colloidal and interfacial systems.
Unit II
Interfacial forces, surface tension, surface free energy, surface entropy, surface activity and
surfactant structures, interfacial tension and contact angle, thermodynamics of interfaces,
relations between surface and interfacial tensions, Gibbs' treatment, Antonoff 's relationship,
theory of contact angles, magnitudes of contact angles of liquids on solids, spreading
coefficients, measurements of surface and interfacial tensions, adsorption, properties of
monolayers, Langmuir isotherm.
Unit III
Overview of electro kinetic phenomena (electro-osmosis and electrophoresis), sources of
interfacial charge, electrostatic theory, Coulomb’s law, Boltzmann’s distribution and the
electrical double layer, double layer thickness, electrical aspects of surface chemistry (electrical
double layer, zeta potential, DLVO theory), distribution potentials, diffusion potentials,
interfacial and surface potentials, properties of monolayers, surface pressure, surface viscosity.
Unit IV
Capillary flow, driving forces, interfacial tension, contact angle, Laplace expression for pressure
difference across a curved interface, practical capillary systems such as wetting in woven fibers
and papers, repellency control, detergency, enhanced oil recovery, characterization of colloidal
particles, applications of colloid and surface science in petroleum recovery, coating and painting,
food, pharmaceutical and cosmetic industry, case studies.
Texts and references:
1. Hiemenz, P.C. and Rajagopalan, R., Principles of Colloid and Surface Chemistry, 3rd
Edition,
Marcel Dekker, N.Y., 1997.
2. Stokes, R. J. and Evans, D.F., Fundamentals of Interfacial Engineering, Wiley-VCH, N.Y.,
1996.
3. Edwards, D. A., Brenner H. and Wasan, D. T., Interfacial Transport Processes and Rheology,
Butterworth-Heinemann, Boston, 1991.
4. D.J. Shaw, Colloid and Surface Chemistry, 4th Edition, Butterworth-Heinemann, Oxford,
2003
5. Richard M. Pashley, Marilyn E. Karaman, Applied Colloid and Surface Chemistry, Wiley,
2004
ME 513 T: Renewable Energy & Energy Management
Teaching Scheme Examination Scheme
L T P C Hrs/Week Theory Practical Total
marks MS ES IA LW LE/Viva
3 -- -- 3 3 25 50 25 -- -- 100
Solar energy: Devices for thermal collection, solar energy applications
Wind energy: analysis of wind speeds, different types of wind turbines, Wind date, factors for
site selection, performance characteristics
Bio Energy: Biomass gasifies, types, design and construction of biogas plants, scope and future
Tidal, wave and ocean thermal energy conversion plants, geothermal plants
Energy Management: Its importance, Steam Systems: Boiler efficiency testing, excess air
control, Steam distribution, condensate recovery, flash steam utilization, Thermal Insulation
Energy conservation in Pumps, Fans, Compressed Air Systems, Refrigeration & Air conditioning
systems
Waste heat recovery: Recuperates, heat pipes, heat pumps, Cogeneration - concept, options
(steam/gas turbines/diesel engine based), selection criteria, control strategy
Heat exchanger networking: concept of pinch, target setting, problem table approach,
composite curves. Demand side management, financing energy conservation
Texts and References
1. Solar Energy by S P Sukhatme and J K Nayak
2. Solar Engineering of Thermal Processes by Duffie and Backman
3. Energy Management and Conservation Frank Kreith and D Yogi Goswami Handbook CRC
press
4. TERI hand book on Energy Conservation
5.Industrial Energy Conservation Manuals, MIT Press
6. Heat Exchanger Network Synthesis- Process Optimisation by Energy and Resource Analysis
by Uday V Shenoy, Gulf Publ. Company
ME508T COMPUTATIONAL FLUID DYNAMICS
Teaching Scheme Examination Scheme
L T P C Hrs/Week Theory Practical Total
marks MS ES IA LW LE/Viva
3 -- -- 3 3 25 50 25 -- -- 100
UNIT I
Introduction to Computational Fluid Dynamics and Principles of Conservation:
Computational Fluid Dynamics: What, When, and Why?, CFD Applications, Numerical vs
Analytical vs Experimental, Modeling vs Experimentation, Fundamental principles of
conservation Mass, momentum and energy equations; Conservative forms of the equations and
general description, physical boundary conditions.
Numerical Methods: Classification into various types of equations – parabolic, elliptic,
hyperbolic and mixed type; Boundary and initial conditions; Overview of numerical methods.
Unit II
Discretization: Finite Difference Method - explicit, implicit, stability requirement, polynomial
fitting, approximation of boundary conditions, applications to heat conduction and convection;
Finite Element Method: Variational principle and weighted residual, Rayleigh-Ritz, Galerkin and
Least square methods, 1-D and 2-D elements, applications to fluid flow and heat transfer
problems; Finite Volume Method – finite volume discretization, approximation of surface and
volume integrals, interpolation methods - central, upwind and hybrid formulations and
comparison.
Unit III
Methods of Solution: Solution of finite difference equations, iterative methods, matrix inversion
methods, ADI technique, SIMPLE algorithm, operator splitting, fast Fourier transform,
applications.
Numerical Grid Generation: Grid generation techniques, transformation and mapping,
structured and unstructured grid generation, Application of grid generation techniques.Unit IV
Reactor-Separator-Recycle Systems: Grassroots and Retrofit Designs, Multiple Base Case
Designs; Flexibility Considerations; Industrial Applications and Case Studies (Reactive
Distillation).
Unit IV
Introduction and Application of ANSYS Fluent: Geometric modeling-ANSYS
Workbench/CFX, mesh generation, boundary and initial conditions, computational approach,
analysis.
Case Study: Numerical simulation of steady and un-steady process of fluid transport with and
without heat transfer using ANSYS software – use ANSYS Workbench for geometrical
modeling and turbulence models (i.e., RNG k- model, Standard k- model) for comparative
analysis.
Texts and references:
1. Computational Fluid Mechanics and Heat Transfer, Richard Pletcher, John Tannehill and
Dale Anderson, CRC Press, 2012.
2. An introduction to computational fluid dynamics: The finite volume method, H.K. Versteeg
and W. Malalasekera, Pearson Education, 2007.
3. Numerical Computation of Internal and External Flows, Charles Hirsch, Vol.2, John Wiley &
Sons, 1990.
4. Computational Methods for Fluid Dynamics, J. H. Fergiger, M. Peric, Springer, 2002.
5. Computational Fluid Dynamics, T. J. Chung, Cambridge University Press, 2010.
6. Computational Techniques for Fluid Dynamics Vol. 1, C. A. J. Fletcher, Springer, 1991.
7. Computational Techniques for Fluid Dynamics Vol. 2, C. A. J. Fletcher, Springer, 1991.
8. Computational Fluid Dynamics, J. D. Anderson Jr., McGraw-Hill International Edition,
1995.
9. Computational Fluid Mechanics and Heat Transfer, John C. Tannehill, Dale A. Anderson and
Richard H. Pletcher, Taylor &Francis.
10. Computational Fluid Dynamics, John D. Anderson Jr., McGraw Hill Book Company.
11. Computational Fluid Dynamics: Principles and Applications, J. Blazek, Elsevier.
12. Computational Methods for Fluid Dynamics, Ferziger, J. H. and Peric, M., Third Edition,
Springer-Verlag, Berlin, 2003.
13. Introduction to Computational Fluid Dynamics: The Finite Volume Method, Versteeg, H. K.
and Malalasekara, W., Second Edition (Indian Reprint) Pearson Education, 2008.
