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Peanut; Arachis hypogaea Protein DB : only 677 (too small). 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. 28. 29. 30. 31. 32. 33. 34. 35. 36. 37. 38. 39. 40. 41. 42. 43. 44. 45. 46. 47. - PowerPoint PPT Presentation
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Peanut;
Arachis hypogaea
Protein DB : only 677 (too small)
1
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_1 6 (0.203) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:8) TOF LD+ 498842.27
1489.76
1188.59
1096.54
843.27
1041.49
844.27
1028.39
1189.59
1482.81
1388.77
1277.68
1490.77
1719.83
1658.83
1491.78
1638.85
1720.83
2024.011829.90
2023.011830.89
1994.98
2025.022297.14
2212.102211.10
2025.98
2298.14 2457.34
2985.572984.53
2781.362459.35
2
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_2 5 (0.170) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:7) TOF LD+ 2.56e3842.31
843.32
868.42
870.42
2212.111508.78
1487.751155.66871.42
1075.67944.56
1296.66
1681.88
1524.802211.10
1888.941788.00 1890.96
2214.08
2216.07
2749.272227.11 2692.28
2808.27
3
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_3 8 (0.281) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:12) TOF LD+ 1.00e31277.74
842.32
1041.64
843.32
1011.64
854.89872.16
1082.60
1083.61
1179.62
1278.74
1924.98
1923.99
1638.901527.91
1279.73
1396.86
1639.91
1840.95
1640.90
1926.00
1927.03
2003.99
2212.132384.99
2383.98 2873.382781.48
2516.222875.33
4
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_4 8 (0.288) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:11) TOF LD+ 7881639.89
1475.78842.31
854.87
1278.72860.91 1183.65
1144.62
880.94
1066.08
1383.71
1476.79
1708.81
2212.11
2211.10
1709.80
1870.001871.021909.89
1996.01
2084.05
2213.11
2706.152226.12
2705.152285.16
2402.252502.22
2658.25
2749.30
2751.30
2810.282874.352917.49
5
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_5 6 (0.231) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:11) TOF LD+ 2.05e3842.31
843.31
1566.82870.41
1475.78
1318.75994.14
935.53
1302.721082.59
1277.72
1179.60
1319.75
1320.72
1638.892212.11
2211.10
1707.81
1843.04
1853.972084.01
2213.10
2226.12
2706.132227.12 2402.24
2502.24
2808.28
2810.292915.46
6
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_6 3 (0.097) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:4) TOF LD+ 1.47e3870.42
1566.80
1019.59
935.55
1020.59
1448.841055.59
1056.59
1567.81
1678.811679.81
2084.102083.10
1680.812052.06
2051.051826.01
2438.15
2437.162085.11
2384.10
2086.11
2257.03
2439.16
2612.20
2440.162610.19
2613.192824.31
2614.20 2826.31
7
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_7 7 (0.234) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:7) TOF LD+ 4.32e3842.31
870.42
935.54
1566.82
1318.75936.55
1179.61
1461.80 1568.82
2212.111582.89 1843.06
1639.90 1844.051999.03
2213.122384.952383.96
2749.292706.14 2808.29
8
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_8 9 (0.302) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:9) TOF LD+ 954842.32
868.43
2212.11
1707.81870.42
1567.831475.79
1462.811302.73
871.42
1277.72
1179.62935.52
1106.57
1461.81
2211.101708.81
1709.81
1838.971851.96
1967.06
2213.11
2384.962214.11
2225.11
2706.162502.23
2705.16
2664.32
2662.26
2749.29
2751.29
2809.27
2810.282916.45
9
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_9 10 (0.333) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:10) TOF LD+ 1.89e31284.73
842.311280.78
860.91
1229.70882.21
1082.58
1638.89
1285.74
1475.78
1286.74
1302.72
1307.69
1476.78
1477.78
1640.89
1700.93
1707.80
1851.95
2706.142212.10
1994.99
1996.01
2705.142213.112502.24
2227.11 2503.22
2707.14
2708.17
2873.35
10
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_10 10 (0.342) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:10) TOF LD+ 853860.90
1475.781284.74876.94
877.95
892.98
1280.77
1229.71901.00
902.98
1285.74
1307.71
1386.78
1639.891476.79
1477.78
1640.89
2212.10
1700.92 1851.96
1853.971994.99
1996.00
2084.00
2213.11
2706.152226.13
2227.12 2705.13
2503.24
2506.25
2808.292809.282810.29
2874.392915.45
11
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_11 13 (0.470) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:27) TOF LD+ 9.47e3842.30
843.31
868.42
870.41
1280.77871.41 1045.55 2212.101475.78
1307.69 1639.88 2094.241700.92 2226.11 2749.302402.262915.47
12
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_12 3 (0.097) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:9) TOF LD+ 1.74e41116.56
1005.59
985.56
1117.56
1245.62
1246.63
1411.801261.70 2995.37
1465.762994.381517.78 2170.971846.00
2281.162411.14 2978.36
13
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_13 1 (0.030) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:6) TOF LD+ 3.65e31022.55
842.31
1023.54
1340.66
1024.55
1228.61
1124.59
1884.00
1341.67
1712.791342.67
1709.811390.691714.79
1730.80
1885.01
2064.08
1886.01
1886.98
2065.09 2212.102713.242361.20
2363.18 2715.242811.32
14
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_14 7 (0.243) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:13) TOF LD+ 6461707.81
1639.90
1022.55
809.05
810.06823.04
868.41
951.29
1302.74
1023.54
1277.73
1179.60
1303.731475.79
1476.80
1708.82
1884.001882.99
1709.81
1710.81
1885.002502.24
2212.11
2211.10
2063.08
1885.99
1910.87
2065.07
2501.262213.09
2384.96
2286.11
2503.25
2504.252713.26
2712.262905.35
2907.33
2935.41
15
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_15 9 (0.313) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:13) TOF LD+ 8192212.11
1494.76
842.31
999.61
843.32
940.46
1000.60
1478.771068.55
1434.661198.73 1283.64
2211.101495.77
1765.061496.77
1497.76
1638.90
1767.05
1919.02
1920.01
2213.11
2226.13
2227.13
2402.282749.30
2403.272721.28
2404.28
2493.27
2781.98
2810.29
2917.49
2934.37
16
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_16 1 (0.030) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:12) TOF LD+ 7951639.91
1260.69
868.42
869.43
870.38 1022.55
999.611216.65
1110.60
1638.90
1475.79
1261.69
1277.70
1303.72
1308.71
1476.80
2212.11
1640.91
2211.10
1641.91
1851.961642.90
1709.841853.97
1884.00
1885.002187.06
2213.12
2226.132706.17
2695.242227.13
2694.242402.27
2502.272503.26
2520.28
2707.18
2750.31
2810.29
2811.30
2915.472918.43
17
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_17 3 (0.097) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:9) TOF LD+ 1.82e31474.74
868.40 1357.75876.93
882.97 1302.71
1475.74
2031.87
2030.88
1476.75
1477.751816.97
1638.87
2032.88
2131.15
2132.16
2205.032212.08
2213.08 2409.20
2408.19 2749.262706.13 2808.26
18
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_18 5 (0.164) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:7) TOF LD+ 1.38e31458.77
994.14868.42
869.43
1357.77995.15
1307.71996.15
1205.12
1459.77
1460.77
1475.78
1639.93
1638.90
1477.80
2131.171640.93 1794.95
1642.91
1952.05
1796.96 2031.89
2212.112222.07
2409.222706.15
2411.222808.29
19
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_19 9 (0.301) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:15) TOF LD+ 786842.32
868.42
2212.11
2211.10
1161.65869.43
870.42
871.41
952.28
1162.65
1511.86
1475.79
1292.70
1512.87
1639.90 1991.001941.95
1851.961995.05
2213.11
2370.32
2750.312371.31
2748.292402.25
2664.32
2809.312810.29
2915.452922.41
20
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_20 1 (0.030) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:5) TOF LD+ 6701707.82
1638.91
1475.79
1302.74
1068.57
868.411064.62
995.54
1069.57
1158.58
1303.73
1476.80
1477.79
1478.80
1708.82
1709.83
2502.25
1909.86 1995.01 2501.25
2212.111996.00
2150.10 2286.13
2503.252873.38
2872.362504.27
2586.20
2875.35
2876.362891.30
21
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_21 4 (0.131) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:6) TOF LD+ 9381638.92
1475.81
842.32
1004.57
869.43
870.42
1453.851302.74
1277.74
1082.62
1303.74
1307.72
1476.81
1477.81
1635.98
1478.80
1639.92
1640.92
1707.83
1708.832212.10
1851.98 2211.10
1853.981995.02
1996.03
2130.05
2403.182402.19
2227.13
2706.162404.17
2705.19
2502.272504.25
2707.17
2873.38
2875.33
2916.47
22
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_22 9 (0.311) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:13) TOF LD+ 2.94e31036.53
842.31
843.31
857.29
1037.54
1083.60
1438.75
1203.65
1204.65
1439.75
1455.741475.80
1791.941707.831886.91
2048.102212.13 2603.272360.14 2808.31
23
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_23 1 (0.030) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:17) TOF LD+ 1.42e31465.80
1021.54
842.32
860.92
868.42
877.98
1022.54
1023.551459.87
1051.68 1407.72
1466.80
2212.11
2211.10
1467.81
1475.80 1639.93
1487.81 1708.882084.021941.95
2012.97
2213.11
2749.312226.12
2411.182692.28
2664.332413.23
2751.30
2808.312810.30
2918.48
24
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_24 5 (0.164) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:5) TOF LD+ 1.03e3842.33 1475.83
1082.62
843.34
1064.64
1036.56
1302.76
1083.62
1179.64
1307.73
1308.73
1326.80
1330.77
1476.83
1638.94
1477.84
1478.81
1640.93
1853.00
1641.93 1995.052706.211996.05
2705.202502.292212.16
2385.01 2503.292692.34
2707.212708.19
2904.44
2914.49
25
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_25 2 (0.064) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:6) TOF LD+ 1.70e32224.16
2223.16914.40 1803.89
933.51
1069.57
934.52
935.51
1552.761070.56
1071.57
1197.671198.67
1415.69
1553.77
1554.76
1568.75
2096.07
2095.07
1804.89
1810.82
2076.99
2075.98
1966.98
1827.82
2225.17
2352.25
2353.25
2741.28
2354.25
2613.19
2612.19
2355.262356.27
2742.27
2743.27
2744.26
2745.27
2873.34
26
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_26 8 (0.276) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:12) TOF LD+ 1.35e31465.79
868.42
869.431404.71
1326.77985.58 1302.73
1254.711083.59
1466.80
2212.101475.79
2211.10
1476.79
1638.89
1477.78
1567.83
1694.93
1708.841851.96
1709.871853.97
2083.03
2213.10
2808.282226.112749.30
2227.13 2706.162402.26
2665.27
2810.28
2811.29
2917.40
27
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_27 3 (0.097) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:7) TOF LD+ 7361342.75
1312.79
842.311302.73
868.421156.68
1139.65
869.43
870.40
1045.57
1295.76
1639.90
1343.75
1475.80
1476.79
1477.79
1478.78
1707.82
2212.10
2211.10
1852.96
1853.96
2084.001868.95
1941.96
2213.11
2706.152227.13
2705.162502.23
2286.16 2503.25
2647.28
2707.17
2809.30
2810.242874.32
2917.54
28
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_28 2 (0.064) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:9) TOF LD+ 6911082.60
1036.53
868.41
869.41
1329.741312.79
1083.60
1295.751330.74
1790.93
1408.74
1542.821543.84
1707.84
2212.101791.93
2211.10
1887.91
1914.95
1954.052050.08
2213.11
2226.132603.25
2285.132420.17 2749.29
2808.30
2810.332811.34
29
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_29 4 (0.135) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:15) TOF LD+ 5982212.11
2211.10
868.42
1475.79
869.42
1315.74
1302.72876.95
1277.72878.97
1082.58951.32
1316.73
1708.81
1476.79
1477.80
1980.07
1709.80
1851.96
2087.01
2213.11
2280.18
2749.30
2706.162284.18
2286.152705.17
2692.292402.28
2403.242663.31
2662.34
2750.30
2751.32
2808.29
2810.25
2917.442934.47
30
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_30 9 (0.301) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:15) TOF LD+ 1.32e3854.87
878.93
880.93
1475.80
1064.62
951.301302.73
1082.60 1321.63
1707.82
1838.95 2212.092211.101840.962112.10
1869.00
2781.372213.092502.23
2225.11 2780.42 2832.15
2875.35
31
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_31 8 (0.274) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:13) TOF LD+ 4491453.81
868.43
869.44
1141.63
870.36
1051.70968.57
1142.631302.75
1143.65
1303.75
1454.82
2212.091475.81
1639.921476.81
1477.82
1555.87
2211.10
1640.91
2084.011707.842082.99
1708.83
1852.97 1941.95
2012.99
2749.29
2213.11
2226.12
2748.27
2402.24 2664.30
2418.242419.24
2504.24
2750.28
2808.28
2809.28
2810.28
2915.452916.43
2917.41
2918.46
32
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_32 5 (0.167) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:17) TOF LD+ 1.04e32132.13
2131.13
1638.90
1302.72
868.40
1141.611028.53
958.49
1427.76
1453.781562.86
2057.09
2056.101640.89
1851.96
1710.901873.95
2706.202133.13
2705.20
2691.25
2134.13 2690.24
2212.112689.22
2472.212213.10
2285.14 2502.26
2854.39
2853.39
2709.23
2855.39
2856.38
2884.40
2885.382968.41
33
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_33 12 (0.450) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:13) TOF LD+ 1.35e31870.06
1869.06
1592.88
1004.55
842.31
843.31
854.88
874.35
1005.55
1387.761147.61
1006.541148.61
1149.60
1388.76
1393.84
1521.95
1593.88
1594.88
1773.931595.871622.85
1871.06
1872.05
2212.101873.06
1974.072403.16
2214.102457.20
2749.322459.19 2809.26
34
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_34 8 (0.279) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:12) TOF LD+ 1.10e31837.98
1836.99
1624.84
1533.88
1166.64
842.30
854.86
868.41
1167.64
1475.781168.64
1302.71
1625.84
1626.85
1646.87
1819.95
1838.99
1840.00
2212.102211.10
1994.06
1996.052043.02
2213.09
2781.382226.11
2706.142493.32
2492.33 2705.13 2782.392810.22
35
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_35 4 (0.136) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:9) TOF LD+ 7141770.011501.78
1352.82
1276.67
905.48
1121.52
906.49
1093.50
1122.53
1137.51
1353.82
1354.82
1769.03
1502.79
1503.79
1707.81
1517.77
1518.77
1771.00
2212.10
2211.101772.00
2111.061772.972024.03
2213.11
2401.232226.12
2399.192402.26
2750.302403.24
2721.272404.22 2808.292810.30
2917.44
36
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_36 7 (0.235) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:11) TOF LD+ 1.64e3948.55
949.55
2212.10
1702.91
964.54
965.54
1277.721066.54
1067.531179.61
1475.78
2211.10
1703.91
1789.93
1791.91
1838.992084.01
2213.10
2214.11
2226.122750.302286.14
2720.27 2808.292917.31
37
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_37 21 (0.751) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:26) TOF LD+ 8461804.98
892.98
899.01
915.00
1634.82
1573.80
1113.58917.00 1556.811229.67
1303.72
1636.84
1805.98
2212.101806.98
2211.10
1807.98
2102.99
2041.06
1943.04
2213.11
2226.10
2451.162227.09 2565.22
2749.282808.292810.32
38
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_38 5 (0.168) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:10) TOF LD+ 1.31e3948.55
1343.76949.55
1066.53
1067.53
1293.72
1068.561277.74
1344.75
2389.24
2212.112211.10
1638.901475.78
1476.781764.85
1765.86
2131.161853.97
2388.24
2226.12
2390.23
2391.23
2392.23
2706.152502.23 2750.302810.29
39
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_39 8 (0.289) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:11) TOF LD+ 3611174.61
868.41
869.42
1082.59954.52
1995.01
1994.02
1641.88
1175.61
1539.83
1254.65
1475.79
1278.72
1388.76
1642.88
1708.81
1854.97
2212.11
2211.10
1996.01
1997.03
2070.07
2071.06
2213.12
2226.13
2749.302706.162384.97
2705.192385.98
2665.31
2502.21
2750.28
2809.29
2810.26
2915.47
2917.44
40
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_40 9 (0.314) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:17) TOF LD+ 1.21e31855.981174.60
1130.56
868.40928.50
1175.60
1515.791254.64
1255.63
1256.64
1277.691475.79
1796.881517.79
1791.91
1639.89
1856.98
2553.13
2552.121857.98
2537.131995.03
2536.132263.02
2262.03
1997.03
2264.012279.03
2286.17
2554.13
2555.13
2556.13 2749.27
2811.28
41
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_41 4 (0.130) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:4) TOF LD+ 2.36e31174.61
928.49 998.00
1175.61
1855.98
1254.64
1255.64
1276.66
1277.661278.66
1797.87
1357.701514.76
1856.981995.03
1996.04
1997.03
2097.08 2347.182750.29
2450.24 2834.32
42
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_42 5 (0.167) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:8) TOF LD+ 4.12e31174.60
842.30
869.41
1175.60
1254.63
1255.63
1855.98
1256.63
1276.651797.88
1278.64 1513.77
1995.03
1996.03
2212.101997.05
1998.032213.11
2809.302285.13 2750.30 2914.51
43
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_43 9 (0.303) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:9) TOF LD+ 1.94e31174.60
842.30
843.30
868.41
870.41
871.411010.52
1175.60
1254.63
1255.63
1855.98
1475.77
1256.63
1276.65
1513.76
1514.771515.771796.89
1995.03
2212.111996.03
2211.10
2131.17
2213.10
2226.11
2227.12 2384.98 2749.31 2809.29
44
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_44 3 (0.101) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:5) TOF LD+ 3.34e32131.18
2130.18
1474.74
940.57868.41
1458.741066.07
1475.75
1476.752031.89
1952.031794.941477.75
1577.78
1796.95
2132.18
2133.19
2205.06
2409.232408.22
2207.07
2308.17
2410.23
2411.242721.352413.28 2781.50 2957.50
45
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_45 4 (0.139) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:7) TOF LD+ 4.57e31458.76
1357.77940.58 1205.12976.52
1459.76
1460.77
2131.182130.18
1474.761952.04
1794.961476.75
1562.80
1796.96 1953.05
2132.192309.20
2221.062310.20
2409.22
2411.232414.17 2721.32
2809.31
46
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_46 5 (0.175) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:19) TOF LD+ 1.12e3876.96
883.00
892.99
899.02
2212.111475.78
901.01 1474.761158.58
915.02
916.99
1458.76
1159.57
2211.10
1476.80
2031.921477.81
1795.881708.832032.92
2213.11
2214.13
2750.322286.17
2692.282385.012809.332810.28
47
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_47 5 (0.170) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:15) TOF LD+ 3.14e31068.56
904.51
905.52
906.50
1069.56
1159.57
1458.761160.56
1446.84
1170.61
1459.77 2387.252212.11
1475.782131.182031.91
1834.922213.122308.19
2388.262409.23
2781.442664.31 2915.44
48
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_48 1 (0.030) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:5) TOF LD+ 1.67e31458.75
1298.78
1170.67
868.40 1154.58940.58
1299.78
1300.79
1459.76
1460.76
2309.192131.18
1815.991461.76
1475.76
1476.75
1951.04
1953.03
2310.19
2409.20
2411.222749.282649.36 2809.33
49
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_49 13 (0.448) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:19) TOF LD+ 676840.86
876.93
892.96
893.97
916.98
2212.081082.02 1305.65 1813.84
1406.771674.98 2080.94 2214.11 2578.84
2673.902941.43
50
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_50 18 (0.642) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:20) TOF LD+ 8832621.26
2346.161035.49
939.54
1819.89
1819.40
1036.491200.71
1037.49
1049.50
1818.90
1201.70
1737.88
1542.861202.691517.25
1413.70
1894.991896.96
2345.161897.95
1914.97
1915.98
2079.92
1995.022080.91
2168.16
2620.26
2347.16
2348.16
2349.17
2368.15
2520.25
2622.26
2623.26
2624.26
2781.482780.49 2782.47
2950.20
51
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_51 12 (0.431) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:19) TOF LD+ 837854.89
878.96
2212.11880.96
2211.10
2079.94882.972078.93
1066.11
899.00 1082.081894.00
1737.901516.731108.06 1277.751639.95 1896.00
1994.02
2213.11
2346.13
2348.13
2621.252386.00
2425.122721.30 2897.54
52
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_52 4 (0.137) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:8) TOF LD+ 6232618.28
2617.27
1638.92
1035.49
868.41
939.56
1277.75
1036.51
1263.74
1278.76
1464.811279.74
1391.831476.82
1493.82
1839.98
1640.92
1723.89
1995.04
1840.98 2151.12
1996.05
1997.04
2079.95
2152.11
2153.12
2154.132400.06
2619.28
2620.28
2621.28
2905.422622.292907.43
53
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_53 4 (0.137) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:14) TOF LD+ 1.07e32115.00
2114.01
1638.90
998.53
804.07
842.30
869.42
871.39
999.53
1035.491308.60
1136.51
1387.67
1738.95 2070.10
1956.97
1740.96
1905.95
2273.07
2116.01
2272.072274.07
2595.24
2275.082594.23
2454.192303.16
2596.23
2597.25
2598.25
2722.25 2838.28
54
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_54 5 (0.172) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:32) TOF LD+ 770854.87
860.91
876.95
878.94
1684.92880.94
1683.931066.08
882.961053.56 1067.07
1185.67 1396.80
2974.312212.11
2211.101685.92
1686.93
2022.071787.901852.04
2973.282213.09
2410.19
2214.102311.25
2411.172566.272568.26
2916.35
55
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_55 5 (0.169) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:8) TOF LD+ 5861412.79
1411.81
1396.81
1395.80
868.40891.49 1393.81
1106.541375.63
2212.10
2211.10
1413.80
1744.96
1743.96
1414.80
1592.87
1745.95
1746.95
1852.002020.97
2213.11
2284.19
2595.352286.18
2402.272403.28
2404.29
2808.32
2597.342974.30
2810.30
56
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_56 14 (0.503) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:21) TOF LD+ 928860.91
876.96
1539.83
877.97
892.99
901.00
905.00
1088.071476.78
1110.08 1302.73
1540.832212.10
2211.10
2113.06
1541.85
1808.99
1602.90
1708.801809.98
1994.97
2213.11
2214.10
2234.10
2235.09 2383.972707.152385.99 2756.13 2949.86
57
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_57 10 (0.355) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:12) TOF LD+ 5031771.96
1325.77
860.91876.95
901.47
1135.64
902.47
1129.53
994.15
1136.64
1168.65
1326.77
1567.831327.78
1347.76
1362.74
1376.77
1569.83
1619.89
1772.96
2212.121773.96
2211.10
2041.94
1774.96
1861.07
2114.07
2213.12
2214.11
2234.12
2235.142731.29
2302.12 2706.27 2732.33 2899.50
58
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_58 13 (0.486) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:23) TOF LD+ 920854.89
1684.92
1683.94
878.96
880.96
882.97
1060.08894.98
896.99898.99 1396.801082.07
1106.54
1645.90
1685.91
2974.302212.10
2211.10
1686.92
2042.022041.02
2025.021687.92
1851.98
2043.02
2044.03
2973.30
2213.10
2214.12
2779.272226.10
2778.262311.252384.972502.30
2781.29
59
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_59 7 (0.265) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:35) TOF LD+ 1.76e3892.99
894.00
909.00
910.001328.78
917.01
931.00 1104.05
1310.78
1329.78
2212.101330.78
1435.831475.81 1627.99 1892.11 1938.302213.122233.12 2384.96 2583.61
2965.45
60
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_60 12 (0.415) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:13) TOF LD+ 1.61e31855.99
1621.86
1174.60
928.48928.99
1173.61
1175.60
1176.61
1255.641577.91
1256.65
1622.86
1623.87
1797.88
1624.85
1638.90
1856.99
1857.99
1995.03
1996.04
2212.121997.04
2023.03
2347.202781.44
2402.272920.37
2922.39
61
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_61 8 (0.280) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:12) TOF LD+ 1.34e31174.60
804.06
805.07
806.07
842.30
868.41
929.44
1175.601855.99
1854.98
1254.63
1255.64
1796.88
1256.64
1677.821276.651641.87
1279.68
1856.99
1995.042212.11
2211.10
1997.05
2083.01
2213.11
2808.302226.12
2749.322285.14 2692.29
2810.332811.27
62
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_62 3 (0.097) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:14) TOF LD+ 1.59e3985.58
842.31
910.44
1465.79
986.58 1116.59
1117.59
1170.651447.79
1245.65
1407.69
1466.80
1467.80
1502.88
2171.001567.83
1569.841708.91 2065.09
2212.112213.10 2411.19
2284.18 2413.21 2996.412865.44
2749.29
63
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_63 8 (0.290) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:21) TOF LD+ 1.28e3842.31
985.58
910.43
1465.79
1116.58
986.58
1117.58
1170.65
1411.83
1189.66
1466.79
1467.79
2212.111502.88
2171.012170.00
1708.892065.101800.07
2213.10 2411.192410.20
2865.432413.17
2807.34
64
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_64 14 (0.479) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:24) TOF LD+ 1.80e3842.31
854.87
860.91
878.94
880.95 1066.08
882.961060.06 1067.08
2212.111090.04
1277.132214.12
2466.21 2664.14 2876.24
65
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_65 25 (0.889) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:34) TOF LD+ 3.33e3842.31
843.31
868.41
870.42
2212.12871.422211.10
1051.70 1582.901350.711106.49
1707.812096.99
1851.97
2213.11
2226.082385.02 2565.22 2729.29 2914.40
66
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_66 21 (0.786) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:22) TOF LD+ 2.04e3842.31
868.41
869.42
870.41
878.94
2212.101340.67880.94 1022.53
1067.07 1713.801342.66
1648.712152.121794.92
2214.102396.28
2638.48
67
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_67 10 (0.348) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:19) TOF LD+ 2.16e3842.31
1004.56
843.32
868.42
874.35
882.95
1005.56
2212.102211.10
1906.011387.761006.56
1114.541143.61
1145.591622.81
1389.75
1794.85
1908.00
1909.002196.12
2213.11
2214.10
2403.142405.16 2615.86
2745.352916.51
68
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_68 27 (0.946) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:34) TOF LD+ 1.84e3842.31
843.31
1610.91856.87
1472.70888.29 1343.69952.35 1612.91
2212.10
1977.091661.84 2284.152566.21 2723.32 2881.45 2934.01
69
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_69 6 (0.209) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:10) TOF LD+ 1.34e3842.31
843.32
868.41
1022.55870.42
871.41
1610.911340.671023.54
1228.62
2212.122211.101612.91
1884.011627.922175.10
2063.09
2213.11
2284.162749.332301.18 2456.23 2809.26
70
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_70 15 (0.517) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:22) TOF LD+ 2.11e3854.86
855.87
870.891060.04
878.92
897.37
1044.07
1307.701061.04
1179.601638.891475.78
1309.68 1477.79
2384.931852.951640.88
1641.891853.94
1994.98
2287.12
2706.122385.952502.21
2504.23
2707.122708.132709.11
2933.45
71
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_71 15 (0.560) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:43) TOF LD+ 2.11e3842.30
843.31
983.49
1252.69984.49
1072.56
1074.55
1253.691421.67
1254.69 1631.861423.68 2212.11
1648.861796.89 2084.06
2808.342749.322226.152402.25 2915.49
72
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_72 30 (1.083) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:40) TOF LD+ 4.27e3854.88
876.96
878.95
893.001066.09
894.98
901.01
903.01
1082.06
1083.06
1090.06 1501.891108.021277.13
1295.111503.90
2212.141794.86
1869.052808.322402.27
73
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_73 1 (0.030) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:4) TOF LD+ 3.51e3842.30
1241.70
1203.65843.31
870.41
944.551185.63
1047.56
1242.71
1243.71
1816.981401.70 1549.73
1551.75
2374.121817.98 2362.112212.10
1845.01 2376.142808.362664.34
2915.45
74
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_74 2 (0.064) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:18) TOF LD+ 8.88e3842.31
843.31
844.31 985.58
1465.791021.531045.56 1407.68
1467.792212.09
1708.871794.83 1941.93
2808.302285.13
2402.29 2749.252945.35
75
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_75 7 (0.236) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:10) TOF LD+ 4.39e3842.31
843.31
870.411474.86
1302.771146.65871.42
1045.55 1332.75
1777.901716.04
2212.111779.91
1907.99 2226.122808.332750.33
2402.352965.33
76
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_76 22 (0.797) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:32) TOF LD+ 1.41e4842.31
843.32
844.32
871.431320.621161.66 2212.12
1707.831493.781794.86 1941.96 2227.12 2808.29
2400.052749.32 2874.39
77
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_77 12 (0.463) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:23) TOF LD+ 1.08e4842.31
843.31
844.31
2212.10871.42 1045.56
1651.961475.78 1980.97 2226.11 2749.282402.30
2808.29
78
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_78 11 (0.399) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:27) TOF LD+ 2.36e3842.31
843.32
2212.10868.42
1294.67870.42 1260.68
1219.70871.42
1045.55
1295.681521.821296.68
1630.83 1778.94 1944.902040.10
2213.12
2214.12
2695.222287.15 2452.28 2750.31 2915.41
79
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800m/z0
100
%
07MD_79 21 (0.771) Cn (Cen,4, 80.00, Ht); Sm (SG, 2x5.00); Sb (10,20.00 ); Cm (1:37) TOF LD+ 1.03e3842.33
843.33
854.891004.58
1005.59
2781.021387.811060.11
1271.292780.06
1389.79 1944.111855.10
2371.472212.07
2781.98
2783.462954.41
