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Porto Alegre, setembro de 2009. Relatório de viagem técnica. Motivação: Participação na primeira conferência sobre Oxi-combustão. Destino: Cottbus – República Federal de Alemanha. Data de saída: 05/09/2009 Data de retorno: 13/09/2009 Participantes: Prof. Dr. Nilson Romeu Marcílio. Prof. Dr. Paulo Smith Schneider. Eng. Mec. Diego Rubén Schmeda López. O congresso foi organizado pela Agencia Internacional de Energia, no seu programa de pesquisa e desenvolvimento sobre gases de efeito estufa (IEA – Greenhouse Gas R&D Programme). O processo de oxi-combustão consiste na queima do combustível em uma atmosfera rica em oxigênio, até um máximo de cerca de 30%, completado por gás carbônico aquecido, desviado dos gases de exaustão do sistema de queima. Com isto a temperatura da queima é mais elevada permitindo seu acoplamento a geradores de vapor supercríticos. Dada a ausência de nitrogênio na mistura comburente, não há formação de NOx e a os níveis de SOx são reduzidos. Como produto de combustão se obtém basicamente CO2 e vapor de água, existindo outros compostos ácidos em quantidades mínimas. Impressões gerais do congresso. A tecnologia de oxi-combustão é ainda uma técnica em desenvolvimento, tendo ainda muitos problemas para serem resolvidos, como por exemplo: a obtenção mais barata de oxigênio e a solução de problemas relativos à região de queima com grande infuência de radiação térmica.. Materiais para altas temperaturas também devem ser desenvolvidos. Os organizadores apresentam esta tecnologia como uma possibilidade viável de sequestro de CO2 em curto tempo, a pessar da planta piloto ainda não mostrar resultados satisfatórios. Processos de combustão com oxigênio puro não foram abordados no congresso devido às dificuldades técnicas e tecnológicas de seu desenvolvimento. Ficam ainda pendentes questões técnicas e econômicas ligadas ao transporte e armazenamento do CO2, bem como a adaptabilidade do processo a diferentes tipos de carvão. Empresas de grande porte como a Vattenfall, Air Liquide, Air products, Alstom e Linde, apostam fortemente nesta tecnologia. Outras empresas como Schlumberger, Metso, etc. também estiveram presentes.

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Porto Alegre, setembro de 2009.

Relatório de viagem técnica.

Motivação: Participação na primeira conferência sobre Oxi-combustão.

Destino: Cottbus – República Federal de Alemanha.

Data de saída: 05/09/2009

Data de retorno: 13/09/2009

Participantes:

Prof. Dr. Nilson Romeu Marcílio.

Prof. Dr. Paulo Smith Schneider.

Eng. Mec. Diego Rubén Schmeda López.

O congresso foi organizado pela Agencia Internacional de Energia, no seu programa de

pesquisa e desenvolvimento sobre gases de efeito estufa (IEA – Greenhouse Gas R&D

Programme).

O processo de oxi-combustão consiste na queima do combustível em uma atmosfera rica em

oxigênio, até um máximo de cerca de 30%, completado por gás carbônico aquecido, desviado

dos gases de exaustão do sistema de queima. Com isto a temperatura da queima é mais

elevada permitindo seu acoplamento a geradores de vapor supercríticos. Dada a ausência de

nitrogênio na mistura comburente, não há formação de NOx e a os níveis de SOx são

reduzidos. Como produto de combustão se obtém basicamente CO2 e vapor de água, existindo

outros compostos ácidos em quantidades mínimas.

Impressões gerais do congresso.

A tecnologia de oxi-combustão é ainda uma técnica em desenvolvimento, tendo ainda muitos

problemas para serem resolvidos, como por exemplo: a obtenção mais barata de oxigênio e a

solução de problemas relativos à região de queima com grande infuência de radiação

térmica.. Materiais para altas temperaturas também devem ser desenvolvidos. Os

organizadores apresentam esta tecnologia como uma possibilidade viável de sequestro de CO2

em curto tempo, a pessar da planta piloto ainda não mostrar resultados satisfatórios.

Processos de combustão com oxigênio puro não foram abordados no congresso devido às

dificuldades técnicas e tecnológicas de seu desenvolvimento.

Ficam ainda pendentes questões técnicas e econômicas ligadas ao transporte e

armazenamento do CO2, bem como a adaptabilidade do processo a diferentes tipos de carvão.

Empresas de grande porte como a Vattenfall, Air Liquide, Air products, Alstom e Linde,

apostam fortemente nesta tecnologia. Outras empresas como Schlumberger, Metso, etc.

também estiveram presentes.

Aparentemente a tecnologia sería aplicável à realidade brasileira porém uma avaliação

técnico-econômica deve ser feita. Tanto na Europa como aqui, resta saber o que fazer com

com o CO2 sequestrado, locais e tecnologias para armazenagem.

Visitas Técnicas Realizadas.

• Laboratório da Cadeira de Tecnologias de Plantas de Potência da Universidade Técnica

de Brandenburgo.

• Planta termelétrica a carvão de Schawrtze Pumpe de 2 geradores de 800MW,

pertencente a Vattenfall.

• Planta Piloto de Oxi-combustão de Schwartze pumpe pertencente à mesma

companhia.

O programa da conferência pode ser visto a seguir:

Tuesday 8th

Keynote 1 - Vattenfall Oxyfuel Activity- Prof Lars Stromberg, Vattenfall

Keynote 2 - Oxyfuel Flue Gas, Steel and Rock; Implications for CO2 Geological Storage: Matteo Loizzo; Schlumberger Water and Carbon Services

Keynote 3 - Experiences from Commissioning and Test Operation of Vattenfall's Pilot Plant: Hubertus Altmann*, Thomas Porsche, Uwe Burchhardt; Vattenfall Europe Generation AG & Co. KG

Plenary Session 1 - Vattenfall Schwarze Pumpe Experience

1. Vattenfall Oxyfuel Power Plant Development -Engineering of a Coal Fired Power Plant with Oxyfuel Technology: Daniel Hultqvist*, Markus Glausch, Heike Meyer, Detlef Radunsky and Thomas Witter;Vattenfall Europe PowerConsult GmbH

2. The Proven Cryogenic Air Separation Process Adapted to the needs of Oxyfuel Combustion and First Results from Schwarze Pumpe Pilot Plant: Gerhard Beysel*; Linde AG

3. Oxyfuel Pulverized Coal Steam Generator Development 30 MWth Pilot Steam Generator Commissioning and Testing: Frank Kluger*,Patrick Monckert, Bernd Krohmer, Georg-Nikolaus Stamatelopoulos;Alstom Power, Jurgen Jacoby, Uwe Burchardt; Vattenfall

4. Flue-gas Cleaning Processes for CO2 Capture from Oxyfuel Combustion - Experience of FGD and FGC at 30MWth Oxyfuel Combustion Pilot Plant: J. Yan*, Vattenfall Research and Development AB, Richard Faber; Vattenfall Europe Generation AG & Co. KG, Thomas Schmidt, gerhard Ross; Babcock Noell GmbH, Jürgen Jacoby, Marie Anheden, Rainer Geiting; Vattenfall Research and Development AB, Daniel Kosel; Vattenfall Europe Generation AG & Co. KG

5. First experience in the commissioning of the CO2-plant in Schwarze Pumpe: Roland Ritter*; Bernd Holling; Linde-KCA, Thomas Porsche, Mario Biele; Vattenfall Europe Generation

6. Behaviors of NOx and SOx in CO2 Compression/Purification Processes - Experience at 30 MWth Oxy-Coal Combustion CO2 Capture Pilot Plant: Cyril Thébault*, Jinying Yan; Vattenfall Research and Development AB, Mario Biele; Vattenfall Europe Generation AG & Co. KG, Roland Ritter; Linde-KCA, Jurgen Jacoby, Marie Anheden; Vattenfall Research and Development AB, Daniel Kuehnemuth; Chlamers University of Technology

7. Experiences from the Operation and Test Measurements of the 30MWth Oxyfuel Pilot Plant: Jurgen Jacoby*; Vattenfall Research and Development, Uwe Burchhardt; Vattenfall Europe Generation, Rainer Gieruing, Marie Anheden; Vattenfall Research and Development

Session 1a Heat Transfer Experiments and Modelling (Part 1)

1. Radiation and Convection Heat Transfer in Oxyfuel Combustion: John Smart*, Phil O'nions, Gerry Riley, Ed Jamieson; RWEnpower

2. Modification of the Weighted-Sum-of-Grey-Gases Model to Account for Both Air-and Oxy-Fired Conditions: Robert Johansson*, Chalmers University of Technology

3. Spectral Radiation Measurements on Oxyfuel Natural Gas Flames and Flue Gases: Comparison of Air and Oxyfuel Radiation: Valentin Becher*, Hartnut Spliethoff;Technische Universität München

Session 1b Flue Gas Clean Up/ Impact Purification/ VLE Experiments

1. Impacts of Non-condensable Components on CO2 Compression/Purification, Pipeline Transport and Geological Storage: Jinying Yan*, Marie Anheden, Christian Bernstone; Vattenfall Research and Development AB, Stefan Liljemark, Helena Pettersson; Vattenfall Power Consultant AB, Hailong Li, Jinyue Yan; Royal Institute of Technology

2. Flue Gas Cleaning in Oxyfuel Combustion: Wuyin Wang*, Jörgen Grubbström; Alstom Power Sweden AB

3. Vapor Liquid Equilibria (VLE) Experimental Validation of Aspen Plus® Model Parameters for Mixtures of CO2 and Argon: Alexander Fassbender*, Li Tao, Robert Henry, Linxaio Chen;ThermoEnergy Corporation

Session 1c Ash Slagging, Fouling and Deposition

1. Characterisation of Rig Deposits from Oxy-Coal Combustion: Fraser Wigley*; Imperial College London, Ben Goh; E.ON UK

2. Impacts of Oxy-combustion Flue Gas Recycle on Coal Ash Slagging and Fouling: Bradley Adams*, Andrew Fry; Reaction Engineering International

3. Ash Partitioning Mechanisms under Oxy-Coal Combustion Conditions: Jost Wendt*, Will Morris; University of Utah, Dunxi Yu; University of Utah & On leave from State Key Laboratory of Coal, Yunlu Jia, JoAnn Lightly; University of Utah

Session 2a Oxy-Coal Burner Development - Experimental Work

1. Highly Flexible Burner Concept for Oxyfuel Combustion: s. Grathwohl, O. Lemp, U. Schnell, J.Maier, G. Scheffknecht B. Khromer; IVD Universitat of Stuttgart, F. Kluger, B.Krohmer, P.Moenckert G-N. Stamatelopoulos; Alstom Power Systems GmbH

2. Oxycoal Swirl Flame Stability as a Function of Flue Gas Recycling Ratio: Dobrin Toporov*, Malte Förster, Reinhold Kneer; Institute of Heat and Mass Transfer, RWTH Aachen

3. An Investigation on the Characteristics of Oxyfuel Combustion of Premixed Swirl Flame: Ju Hyeong Cho, Han Seok Kim, Sang Min Lee, Won Seok Choi, Kook Young Ahn; Korea Institute of Machinery and Materials, Ta Kwan Woo; Sung Il Co., Ltd.(SIM), Ryu Seung Kwan; Hyundai Engineering Co., Ltd.

4. Development of 0.1MW-class Oxy-PC swirl Burner with Primary O2 Direct-Injection: Dae Keun Lee, Dong-Soon Noh, Kyong-Bin Choi, Dong Myung Seo, Chang-Bog Ko, Eun Kyung Lee; Korea Institute of Energy Research

Session 2b CO2 Processing Unit - Experimental and Fundamental Study

1. Removal of SOx and NOx from Oxyfuel-Derived CO2: Laura Torrente Murciano*; Imperial College London, Vince White; Air Products, David Chadwick; Imperial College London

2. Liquefaction of Oxyfuel flue Gas - Experimental Results and Comparison with Phase Equilibrium Calculations: Daniel Koepke*; Hamburg University of Technology/ Institute of Thermal and Separation, Karl Mieske, Alfons Kather; Hamburg University of Technology/ Institute of Energy, Rudolf Eggers; Hamburg University of Technology/ Institute of Thermal and Separation

3. Performance Evaluation of an Advanced Pilot-Scale CO2 Capture and Compression Unit (CO2CCU): Kourosh Zanganeh*, Ahmed Shafeen, Carlos Salvador; CANMET

4. Detailed Chemical Kinetic Modeling of Pollutant Conversion in Flue Gases from Oxycoal Plant: R.P Lindstedt*, R.K Robinson; Imperial College

Session 2c Material Related Issues Under Oxyfuel Combustion

1. Results from Initial Material Exposure Tests in Oxyfuel Environment: Anders Hjörnhede*; Vattenfall Power Consultant AB, Melanie Montgomery; Vattenfall A/S, Alexander Gerhardt; Vattenfall Research and Development AB,

2. Corrosion of Superheater Materials under Oxyfuel Conditions: Rene Kull*, Malgorzata Stein-Brzozowska, Jörg Maier, Günter Scheffknecht; Institute of Process Engineering and Power Plant Technology (IVD), University of Stuttgart, A.Schopf, Thomas Theye, H.J Massonne; IVD, Univ. Stuttgart

3. Ageing and Corrosion of Steels in CO2 Rich Flue Gases: Axel Kranzmann*; Daniela Hünert, Wencke Schultz, Werner Österle, Romeo Saliwan-Neumann, Gabriele Oder, Ingrid Urban; Federal Institute for Materials Research and Testing , BAM

4. Material Qualification for Oxyfuel Applications Focusing on Interactions Between High Temperature Corrosion and Mechanical Creep/Fatigue Loads: Juergen Olbricht*, Hellmuth Klingelhöffer, Birgit Skrotzki; BAM Federal Institute for Materials Research and Testing

5. The Impact of High Chlorine Coal to Steel Alloys Typically Used in USC Boilers: Ben Goh; E.On Engineering UK

Wednesday 9th

Keynote 4 Alstom's Oxy-Firing Technology and Demonstration: Near, Medium and Long Term CO2 Solutions: John Marion; Alstom

Keynote 5 Research Perspective - Review of the Currents Understanding, Identifying Research Gaps: Gunter Scheffknecht

Plenary Session 2 Update and Discussion of other Large Demo/Pilot Plant Projects

1. Oxy-combustion for Carbon Capture and Storage (CCS): Status, Prospects and Roadmap to Commercialisation: Terry Wall*, Jianglong Yu; The University of Newcastle, Stanley Santos; IEA Greenhouse Gas R&D PRogramme

2. Presents Status of Callide: An Oxyfuel Project: Chris Spero; CS Energy

3. The CO2 Pilot at Lacq CO2 Capture, Transportation, Injection and Storage Ready for Sart Up: Nicolas Aimard*, Claude Prebende; Total, Dennis Cieutat, Ivan Sanchez-Molinero, Remi Tsiava; Air Liquide

4. CIUDEN CCS Experimental Platform for Oxycombustion Technologies Development in Coal Power Generation: Monica Lupion*, Benito Navarrete, Pedro Otero, Vicente Cortes; Ciuden

5. Jamestown Oxy-Coal Technology Overview; Rick Victor*, Minish Shah, Sho kobayashi; Praxair

6. Korean Oxy-Fuel Demonstration Project: Sungchul Kim*, Hyun Dong Lee; Korea Electric Power Research Institute

7. The Case of Retrofitting Meri-Pori Power Plant

8. Oxygen Based Combustion for CO2 Capture and NZEP Performance; Kevin McCauley; B&W

9. ENEL Ox-Combustion Project: Status Update: Marco Gazzino*, Nicola Rossi, Giancarlo Benelli; Enel Engineering and Innovation Division

Session 3a Heat transfer Experiments and Modelling (Part 2)

1. Spectral Modelling of Radiative Heat Transfer in Oxy-Coal Combustion: Jochen Ströhle, Bernd Epple, Matthias Orth*; Technische Universität Darmstadt

2. Measurement of Radiative Heat Flux of Methane Jet Oxy-Flames in CO2 Diluted Atmospheres: Mario Ditaranto*, Thomas Opplet, Bård Lode; SINTEF Energy Research

3. A Quantitative Study of the Performance of Commercial Radiation Models for Predicting Behaviour of Oxy-Coal Combustion: P. Edge*, P.O'Nions, M. Pourkashanian; University of Leeds (UK), P. Stephenson, J. Smart; RWE Npower (UK), A. Williams; University of Leeds (UK)

Session 3b CO2 Processing Unit - Industrial Gas Company Perspective

1. Purification of Oxyfuel-Derived CO2: Current Developments and Future Plans: Vince White*, Kevin Fogash; Air Products PLC

2. Flue Gas compression and Purification Units for Oxy-Coal Combustion Systems: Philippe Court, Arthur Darde, Jean-Pierre Tranier*, Nicolas Perrin; Air Liquide

3. Energetic Evaluation of a CO2 Purification and Compression Plant for the Oxyfuel Process: Roland Ritter*, Annett Kutzschbach, Torsten Stoffregen; LINDE-KCA DRESDEN GMBH

Session 3c Coal Ignition and Char Combustion Related Issues (Part 1)

1. Oxy-coal combustion: Effects of PO2 on Coal Jet Stability in O2/CO2 Environments: Jingwei Zhang, Kerry Kelly*, Eric Eddings, Jost Wendt; University of Utah

2. Detailed Investigation of the Effects of Oxy-Fuel Combustion Conditions on Pulverized Coal Ignition and Char Burning Rate: Christopher Shaddix*, Ethan Hecht; Sandia National Laboratories, Santiago Jimenez; LITEC, Sang Min Lee; Korea Institute of Machinery and Materials, Alejandro Molina; National University of Colombia, Medellin

3. Ignition Characteristics of Single Coal Particles in Air (O2/N2) and Oxy-fuel (O2/CO2) Environments: Zeenathul Farida Gani*, Behdad Moghtadderi, Terry Wall; The University of Newcastle

Session 4a Oxy - CFB Combustion Experiments and Fundamentals

1. Oxyfuel-CFB Boiler Scale-up Based on Integrated Experimental and Modeling Work: Reijo Kuivalainen*; Foster Wheeler Energia Oy, Toni Pikkarainen, Timo Leino, Antti Tourunen; VTT Technical Research Center of Finland, Kari Myöhänen, Sirpa Takkinen, Timo Hyppänen; Lappeenranta University of Technology

2. Circulating Fluidized Bed Boiler Technology – A Competitive Option for CO2 Capture through Oxyfuel Combustion?: Niklas Simonsson*; Vattenfall Research & Development AB, Timo Eriksson; Foster Wheeler Energia Oy, Minish Shah; Praxair Inc.

3. Pilot-scale Evaluation of Oxycoal Firing in Circulating-Fluidized-Bed and Pulverized-Coal-Fired Test Facilities: Eric Eddings*, Ryan Okerlund; University of Utah, Lawrence Bool; Praxair, Inc., Andrew Fry, Bradley Adams; Reaction Engineering International

4. First Results of an Oxyfuel Combustion Fluidized Bed: Luis M. Romeo*, Isabel Guedea, Irene Bolea, Ana Gonzalez, Carlos Lupiañez, Javier Pallares, Luis I. Diez; CIRCE

Session 4b Oxygen Production and Alternative Technology

1. Air Separation Unit for Oxy-Coal Combustion Systems: Jean-Pierre Tranier*, Richard Dubettier, Nicolas Perrin; Air Liquide

2. Oxy-Combustion on Oxygen Transport Membranes: Minish Shah*, Max Christie, Nick Degenstein, Jamie Wilson; Praxair, Inc.

3. Oxygen Supply for Oxycoal CO2 Capture: Vince White*; Air Products PLC, Kevin Fogash; Air Products and Chemicals Inc

4. OXYCOAL-AC: Integration of High Temperature Membranes for Air Separation in Oxyfuel Power Plants: Stefan Engels*, Michael Modigell, Franz Beggel; Aachener Verfahrenstechnik

Session 4c Coal Ignition and Char Combustion Related Issues (Part 2)

1. Reactivity of Pulverised coals in simulated Air (O2/N2) and oxy-fuel (O2/CO2) Conditions: Renu Kumar Rathnam*, Liza Elliot, Yinghui Liu, Behdad Moghtaderi, Terry Wall; The University of Newcastle

2. Transported Probability Density Function Modelling of Combustion of Complex Fuels with Recirculation of Flue Gases: R.P Lindstedt*, K. Gkagkas; Imperial College

3. On the Prediction of Char Burnout from Oxy-coal Combustion: Sarma Pisupati*, Prabhat Naredi; The Pennsylvania State University

4. Theoretical and Experimental Approach to the Kinetics of the Combustion in O2/CO2-Atmospheres: Stephanie Tappe*, Hans joachim Krautz; BTU Cottbus, Chair of Power plant

Thursday 10th

Plenary Session 3 - Burner and Boiler Manufacturer Corner

1. Evaluation of Oxy-Coal Combustion at a 30MWth Pilot: Hamid Farzan*, Denny McDonald; Babcock & Wilcox Power Generation Group, Raj Varagani, Nicolas Docquier, Nicolas Perrin; Air Liquide

2. Demonstration of the Doosan Babcock Energy 40MWt OxyCoalTM Combustion System: E. Cameron*, D. Sturgeon, C McGhie, F. Fitzgerald; Doosan Babcock Energy Limited

3. Study results on Oxy-fuel Combustion System for CO2 Capture: Toshihiko Yamada*, Makoto Takafuji; IHI Corporation

4. Hitachi Babcock 30MWth Burner Testing Plans at Vattenfall Schwarze Pumpe Pilot Plant: C. Bergins; Hitachi Babcock

5. Development and Demonstration of Oxy-CFB for Power Plants with CO2 Capture: Horst Hack*; Foster Wheeler

Session 5a Emission Related Issues

1. The Sulphur Mass Balance in Oxy-Fuel Combustion of Lignite: Daniel Fleig*, Daniel Kühnemuth, Fredrik Normann, Klass Andersson, Filip Johnsson, Bo Leckner; Chalmers University of Technology

2. Experimental and kinetic modeling study of the effect of SO2 on fuel oxidationin an O2/CO2 atmosphere: Jorge Giménez*, Angela Millera, Rafael Bibao, Maria Uxue Alzueta; University of Zaragoza

3. Sulfur and Coal-Fired Oxyfuel Combustion with CCS: Impacts and Control Options: Terry Wall*, Rohan Stanger; The University of Newcastle, Joerg Maier; University of Stuttgart

4. Assessment of Mercury Fate in Oxy-Coal Combustion: Maryam Gharebaghi*; University of Leeds, Ben Goh; E.ON Engineering UK Plc, Mohamed Poukashanian, Alan Williams; University of Leeds

5. Control of Oxy-Fuel Combustion NOx Emission: Fredrik Normann*, Klas Andersson, Filip Johnsson, Bo Leckner; Chalmers University of Technology

6. The Characteristic of NO Production Linetics and Fuel-N Conversion in Oxy-Firing Coal Combustion: Choi Gyung-Min*; Pusan Clean Coal Center, Pusan National University, Go Sun-Mi, Lee Kang-Yoel, Kim Duck-Jool; Pusan National University.

Session 5b Large Scale Oxyfuel Burener Development Programme Activities

1. Oxy-fuel Process Developments Leading to Demonstration Plant Design: Dennis McDonald*, Douglas DeVault; The Babcock & Wilcox Company, Jean-Pierre Tranier, Nicolas Perrin; Air Liquide

2. Oxyfuel Fundamentals and Underpinning Technologies: David Fitzgerald*, Angus Duncan, Barry McGhee, Clive McGhie, David Sturgeon; Doosan Babcock Energy Limited

3. Alstom 15MWth Oxyfuel Test Programme for Tangential Firing: JohnMarion*, Frank Kluger, Armand Levasseur, Nsakala Ya Nsakala, Jorgen Grubbstrom, Jean-Francios Leandri; Alstom Power

4. Oxyfuel Retrofit to Condensing Coal Power Plant - Combustion Properties: Toshihiko Mine*, Babcock-Hitachi K.K.Kure Research Laboratory, Kenichi Ochi; Babcock-Hitachi K.K. Kure,

Hirofumi Okazaki; Hitachi Ltd. Energy & Environmental Systems Laboratory, Pauli Dernjatin; Fortum Service

5. Oxy-Coal Combustion Experiences on a 3 MW Test Rig Facility: Danila Cumbo*, Nicola Rossi, Giancarlo Benelli, Marco Gazzino; ENEL, Engineering and Innovation Division, Technical Area Research

6. Update Jupiter Oxygen Corporation Large Scale Boiler Test Facility Results from first year of Operation with Carbon Capture: Brian Patrick*, Diretrich Gross, Mark Schoenfield, Thomas Weber; Jupiter Oxygen Corporation, Tom Ochs, Danylo Oryshchyn, Cathy Summers; USDOE - NETL

Session 5c CFD Modelling & Experimental Validation

1. Numerical Simulation of a 3 MWth Oxycoal Burner: Lorenz Griendl*; Institute of Thermal Engineering, Graz University of Technology, Ulrich Hohenwarter, AE&E Austria GmbH & Co KG, Jürgen Karl; Institute of Thermal Engineering, Graz University of Technology

2. Development of Recirculation system & Key components in Oxyfuel Combustion: Terufumi Kawasaki*, Yuji Fukuda; Babcock-Hitachi K.K. Kure Research Lab., Osama Ito; Hitachi Ltd., Energy & Environmental Systems Lab., Christian Bergins; Hitachi Power Europe GmbH, Song Wu; Hitachi Power Systems America

3. Numerical Simulation of Oxyfuel Combustion: Andreas M. Kempf, Oliver T. Stein*; Imperial College London

4. Experimental Data and CFD Calculations of Oxyfuel Firing and Adapted Pilot Scale Burner Design: Sebastian Rehfeldt*; Hitachi Power Europe GmbH, Dept. Research & Development & Institute of Process Engineering and Power Plant Technology, Dept. Power Plant Technology, University of Stuttgart, Christian Bergins; Hitachi Power Europe GmbH, Dept. Research & Development; Christian Kuhr, Martin Ehmann; Hitachi Power Europe GmbH, Dept. Technology Center, Klaus-Dieter Tigges, Jürgen Niesbach, Dieter Lasthaus; Hitachi Power Europe GmbH, Dept. Steam Generation

5. Simulation of Air and 'oxy Combustion of Pulverized Coal with CO2 Recirculation: Seunghwan Lee, Karam Han, Kang Y. Huh*; Department of Mechanical Engineering, POSTECH

6. Numerical simulation of Lignite combustion in O2/CO2 environment by Eddy-Dissipation Model: Tanin Kangwanponpan*,Hans Joachim Krautz; Chair of Power Plant Technology, Brandenburg University of Technology, Cottbus,Germany

Session 6a Power Plant Reftrofit and Process Optimisation

1. Development of Oxy-Burner Retrofit Principles for Existing Coal-Fired Utility Boilers: Andrew Fry*, Bradley Adams, Marc Cremer; Reaction Engineering International, Jiefeng Shan; Siemens Environmental Systems & Services

2. Oxyfuel Retro-Fit to Condensing Coal Power Plant – FS of 500MW Class Plant: Pauli Derjantin; Fortum Power and Heat, Yuji Fukada; Babcock-Hitachi K.K.,Kure Research Laboratory

3. Flue Gas Recirculation for Oxyfuel-Boilers: Energetic and Operational Design Issues: Christian Hermsdorf*, Alfons Kather; Hamburg Unviversity of Technology, Institute of Energy Systems

Session 6b Chemical Looping Combustion Concept

1. Simulation of a Chemical Looping Combustion Process for Coal: Jochen Stroehle*, Alexia Lombarte, Matthias Orth, Bernd Epple; Technische Universität Darmstadt

2. Alstom Chemical Looping Technology Advancement: Corrine Beal*, Herbert Andrus, Michel Vandycke; Alstom Power

3. Kinetics Study for O2 Absorption/ Desorption Using a Co-based Oxygen Carrier: Teng Zhang*, Zhen-shan Li, Ning-sheng Cai; Key laboratory for Thermal Science and Power Engineering of Ministry of Education

Session 6c Oxyfuel Combustion Technology Experimental Programme

1. Oxy-combustion Technology Research through the DOE-NETL Existing Plants Capture Program: Timothy Fout*, Zhen-shan Li, Jared Ciferno, Lynn Brickett, Michael Matuszewski; U.S. Department of Energy / NETL

2. Novel Oxy-steam Burner for Zero-emission Power Plants: Chris Salvador, Milenka Mitrovic, Kourosh Zanganeh*; Clean Electric Power Generation, Canada

3.Development of Oxyfurl Combustion within the E.On Group: Ben Goh*; E.ON Engineering Ltd

Poster Presentations

1. Oxy-Coal Combustion Modeling: Eddy Chui*, Adrian Majeski; CanmetENERGY, Natural Resources Canada

2. Comparison of Experimental and Model-Based Overall Heat Transfer Coefficient for Mixtures of CO2 and Argon at Elevated Pressure: Alexander Fassbender*, Li Tao, Robert Henry, Linxaio Chen; ThermoEnergy Corporation

3. Operating Experience with a 0.1MWth OxyFuel-CFB Test Rig: Tomasz Czakiert*, Slawomir Karski; Czestochowa University of Technology, Karol Sztekler, Daniel Markiewicz;; Czestochowa University of Technology & Foster Wheeler Energia Polska Sp. z o. o. , Pawel Mirek; Czestochowa University of Technology, Marek Andrzejczyk; Foster Wheeler Energia Polska Sp. z o. o.,Wojciech Nowak; Czestochowa University of Technology

4. Char Combustion Modeling under Oxyfuel Conditions; Adrian Goanta*; Jan-Peter Bohn, Valentin Becher, Harmut Spliethoff; Technische Universität München

5. An Overview on the Development Status of 100kW class Power Plant using Oxyfuel Combustion at KIMM: Kook Young Ahna, Ju Hyeong Cho, Young Duk Lee*, Sangseok Yu; Korea Institute of Machinery and Materials, Hyun-il Jeongb; Korea Southern Power Co, Ta Kwan Woo; Sung Il Co., Ltd.(SIM); Hyoung June Parkd; Hyundai Engineering Co., Ltd

6. EPA's developing oxy-fuel combustion research program: Willian Linak*, Chun Wai Lee; US Envrionmental Protection Agency, Myrrha Andersen; North Carolina State University

7. Coal Devolatilization and Char Conversion in Oxy-Fuel Combustion: Jacob Brix*, Peter Arendt Jensen, Anker Degn Jensen, DTU Department of Chemical and Biochemical Engineering

8. Simultaneous Devolatilisation and Char Combustion in Oxyfuel Coal Combustion. Flame Stand-off Distance: Aleksandra Milewska*, Bartosz Swaithowski, Rastko Jovanovic; Institute of Power Engineering, Department of Thermal Processes

9. Reliability of Steels during Injecting of CO2 into Saline Aquifer: Anja Pfennig*; HTW Berlin, Applied University, Ralph Bäßler, Dirk Bettge, Axel Kranzmann; BAM Federal Institute for Materials Research and Testing

10.Experimental Assessment of the Pollutant Formation during Oxyfuel Combustion: Karl Mieske*, Alfons Kather;Technical University of Hamburg

11. Calcination of Limestone and In-Furnace Desulfurization Characteristics in Oxy-Fuel Combustion: Hyung-Keun Lee*, Young-Mo An, Hang-Dae Jo, Won-Kil Choi; Greenhouse Gas Research Center, Korea Institude of Energy Research, Sang-In Keel; Environment System Research Center, Korea Institude of Machinery & Materials

12.Flue Gas Condensers for Oxyfuel: Stefan Åhman*, Wuyin Wang, Jörgen Grubbström; Alstom Power Sweden AB

13.Electrochemical Assessment of Metallic Materials for Process Applications: Ralph Bäßler*, Andreas Burkert; BAM Federal Institute for Materials Research and Testing

14.Radiative Heat Transfer in Oxyfuel Combustion: Rachel Porter, Mohamed Pourkashanian, Alan Williams; University of Leeds, Gerry Hesselmann, Brian Smith, David Smith, Nicolas Taylor; Doosan Babcock Energy Limited

15.Modeling Oxy-combustion in the E.ON UK Combustion Test Facility: Sandro Dal Secco* EDF

16.A Preliminary Feasibility Study of Partnerships in Oxy fuel Combustion Research on High Ash Coal: Malti Goel*; Indian National Science Academy, V.S Verma; Central Electricity Regulatory Commission

17.A Numerical Method for Optimizing Oxyfuel Power Plants: Xinxin Li*, Klaus Lackner, Department of Earth and Environmental Engineering

18. Oxy-fuel Combustion Based Hydrogen Production Systems: Murlidhar Gupta*; CanmetENERGY, Natural Resources Canada

19.Efficiency Increase of Oxyfuel Processes|by Integration and Optimization: Mathias Klostermann, Alfons Kather; Hamburg University of Technology

20. A Case of Performance Evaluation Studies of Oxy-coal Power Generation Systems: Sangmin Choi*; Department of Mechanical Engineering, Korea Advanced Institute of Science and Technology, Taehyung Kim, Sangil Seo; Korea Electric Power Research Institute

21.CO2 Standard and Its Implications on Oxy-fuel Combustion: Ligang Zheng*, Quan Zhuang, Yewen Tan, Bruce Clements, Richard Pomalis; CANMET Energy Technology Centre

22. Comparison of Ash Release and Deposition under Air vs. Oxyfuel Combustion of solid fuels: L. Fryda*; ECN, C. Sobrino; Delft University of Technology, M. Losurdo; Technische Universität München, M.Cieplik, C. Bertrand; ECN, W. de Jong; Delft University of Technology, W. L. van de Kamp; ECN