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1 Toray Industries, Inc. PW-series Positive Tone Photosensitive Polyimide Coatings “Photoneece TM

Positive Tone Photosensitive Polyimide Coatings · 1 Toray Industries, Inc. PW-series Positive Tone Photosensitive Polyimide Coatings “Photoneece ”TM

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  • 1

    Toray Industries, Inc.

    PW-series

    Positive Tone Photosensitive Polyimide Coatings

    Photoneece TM

  • 2

    PW-series introduction

    Semiconductor Package Structure

    Why is PI necessary forsemiconductors package?

    Why is POSI PI the most adjustableto semiconductors process?

    Why is PW-series the best solution ofyour problems?

    Semiconductor Process

    Solution examples

  • 3

    Semiconductor Package Structure1.TSOP or QFP

    2.FBGA(stacked type)

    3.Bare chip (Bump structure)

    4.Wafer Level Package(WLP)

    Polyimide

    Mold compound

    Lead flame

    Polyimide

    Mold compound

    Solder bump

    Gold bump

    Gold Bump

    Polyimide

    Redistributedline(metal)

    Polyimide

    The reason why PI is necessary is---to protect filler attack---to increase packages reliability(buffer effectiveness)

    The reason why PI is necessary is---to protect filler attack---to increase packages reliability(buffer effectiveness)

    ---to protect upper IC attack

    The reason why PI is necessary is---to protect IC substrate(PI acts

    like encapsulation)---to increase adhesion to ACF

    The reason why PI is necessary is---to protect IC substrate(PI acts

    like encapsulation---to increase adhesion to ACF---to distribute line

  • 4

    Semiconductor Process

    photoresist

    passivationAlSi

    Photoresist coating

    Photoresist developing

    Passivation dry-etching

    Photoresist stripping

    PI coating

    Photoresist coating

    Photoresist &PI developing

    Photoresist stripping

    PI curing

    PI coating

    PI developing

    PI curing

    Passivation dry-etching

    exposure

    exposure

    exposure

    Non-photosensitive PI photosensitive PI

    POSI PSPI--alkaline solvent--high resolution

    NEGA PSPI--organic solvent--low resolution

    The most adjustable!

    The number of processis fewer than non-PSPI.

    exposure 2 times exposure 1 time

  • 5

    Solution examples

    The features of PW-series

    High chemical resistanceHigh adhesion strengthGood taper shape

    Useful for Bump & WLP

    Low residual stress Useful for 12 wafer

    High resolution

    Low price

    Useful for advanced memory & logic(Advanced memory= fuse box size is about 5um,Advanced Logic= left pattern width is 7um)

    Useful for every device using NEGA

    Solution

    Is there any problems about above matters with you?We can provide solutions by recommending PW-series.

    The reason why PW-series is the most suitable for all applicationsis that PW-series has following features solving your problems.

  • 6

    1. Marketing Data

  • 7

    Cost reduction of process and materialsRequirementsAvailability for aqueous development(TMAH 2.38%)Low temperature curing process/Good photo-speed Long storage lifeHigh resistance for dry etching process(1 mask process)

    Customers Requirement Trends for PI

    6inch 8inch 12inch

    TSOP

    QFP

    PBGA STACKED BGA

    FBGA

    FCBGA

    BARE CHIPBUMP IC

    WLP

    Wafer Size

    Higher package reliabilityRequirementsHigh electric and thermal resistanceHigh adhesive strength

    Semiconductor and package downsizingRequirementsHigher resolutionHigher adhesion to passivation layer

    12inch wafer applicationRequirementsGood photo-speedLow residual stress and CTE

    CSP(WLP) and bump applicationRequirementsExcellent chemical resistanceHigh adhesion to various materialsAvailability for multi layer(High Tg)

    Package Density

    TCP

    4inch

  • 8

    PIs Technical Trend

    Non Photosensitive PI (negative tone)

    Non Photosensitive PI (positive tone)

    Photosensitive PI (negative tone)

    Photosensitive PI (positive tone)

    To stop hydrazine process

    To be fine resolutionTo reduce process

    But it has many problems such asneeds organic developmentneeds HMDS for increasing adhesionhas less film & liquid propertieshas out gas includedetc To reduce cost(process &

    materials)To be high resolutionTo prevent deposit on side-wallTo lower out gasTo increase adhesion to MC and passivation layerTo be environmental friendly

    Decreasing

    Decreasing

    Have vanished

    1980 1990 2000

    Solution of the problems Its becoming standard!

  • 9

    Features of PW-series

    High package reliabilityHigh electric and thermal resistanceHigh adhesion strength

    Cost reduction of process and materialsAvailability for aqueous developmentLow temperature curing processGood photo speedLong storage lifeHigh resistance for dry etching process

    Semiconductor and package downsizingHigh resolutionHigh adhesion strength to passivation layer

    CSP and bump applicationExcellent chemical resistanceHigh adhesion strength to various materialsAvailability for multi layer

    12 inch applicationGood photo speedLow residual stress and CTE

    Customers requirement

    Satisfying ICs requirement (Pure PI film)Excellent adhesion strength to MC and Si,SiN,TEOS etc.

    Available for TMAH 2.38%Available for curing under 280The best photo speed in positive tone PSPIStable at room temperatureExcellent resistance for 1 mask process

    The highest resolution(3um at 8um thickness)Excellent adhesive strength of even 5um line pattern to SiN

    The highest chemical resistance in all PSPIExcellent adhesion strength to many metals(Cu,Al,Ni,Cr,Ti,Au,etc)High Tg and stability during curing process

    The best photo speed in positivetone PSPIless than 40MPa and 36ppm/

    PW-series is(has)

    We can show you more detailed informationin the following Technical Data

  • 10

    The best solution exampleIf you face following problems Then we can provide you with solutions such as

    For non photosensitive customers:Poor viscous stability or solution stabilityLow resolution(around 30um)Numerous process

    For negativetone photosensitive customers:Expensive material costLow resolution(about 10um)Deposit on side-wallOut gasWeak adhesion to MC and passivation layerOrganic development

    For PBO customers:High CTE & residual stressLow chemical resistancePoor adhesion to passivaition layerLess storage stabilityNarrow cure process latitude

    Excellent viscous stabilityFar higher resolution(3um)Photoresist process reduction

    Moderate PI price and availability for aqueous developmentHigher resolution(3um)Far less out gas included and good taper shapeFar less out gas includedExcellent adhesion to that(not to need HMDS)Availability for aqueous development

    The lowest CTE & residual stress in all PSPIExcellent chemical resistance(no crack during chemical process)Excellent adhesion to passivation layer(even if 5um line is OK)Excellent storage stability(no particle after R.T.storage)Wider cure process window(available for curing in air)

    From PI customers view

  • 11

    From IC manufacturers viewThe best solution example

    For buffer coatings application

    For CSP & bump application

    (The present)A few padsFuse box 1020umTSOP

    Fuse box

    Pad

    Left pattern

    Pad

    CSP & bump is very promising package.It can realize package shrinkage,improvement of electric properties, and cost reduction. Au bump

    Redestribution routeUnder bump metal

    PI layer

    Si substrate

    PI is/will be required for following things

    Higher resolution(3-5um)

    Higher chemical resistance for CSP & bump.

    Higher adhesive strength to passivaiton layer.Higher chemical resistance for HF solution during wet etching before dry etching.

    Higher adhesion strength to various metals.Higher chemical resistance for various etchant, flux, cleaner, solvent etc.

    PW-series emphasize this field

    (The future)A few padsFuse box 520umCSP

    (The present)A lot of padsLeft pattern width 10umQFP

    (The future)A lot of padsLeft pattern width 5umCSP

  • 12

    DRAM

    Flash

    SRAM

    MRAM

    Logic(Graphic,LCDdriver,ChipSet,MPU,etc)

    System LSI

    TSOP

    Bump ,WLP

    Conventional propertiesElectric propertyThermal propertyAdhesion to MC & SIN

    etc

    Conventional propertiesProtective property forfiiler in MC

    Low temperature curig

    Higher Adhesion to SiNHigh chemical resistance(HF)

    Conventional properties+Low temperature curingHigher Adhesion to SiNHigh chemical resistance

    High chemical resistance(flux + cleaner,etchant,solvent)

    Devicetrend

    Packagetrend

    From IC manufacturers viewThe best solution exampleHigher resolution

    In the future, youll need requirement.PW-series is only PI which can satisfy these demands.

  • 13

    PW-series basic properties

    film property

    PW-1000 PW-1200 PW-1500 PW-2100

    Type Standard Thick Film High Chemical High Photo-Applicable Resistance Sensitivity

    viscosity 1,500 1,500 1,500 1,500

    total solid content 38 40 40 40-16 month 9 9 9 94 month 6 6 6 6

    room temp. month 1 1 1 1th ickness 3-7 3-10 3-7 3-7

    tensile strength 130 150 150 150250 cure % - 20 20 20320 cure % 30 20 20 20350 cure % 20 20 10 20380 cure % 10 20 10 20400 cure % 10 20 10 20

    young's modulus 3.0 3.9 3.8 3.8CTE 36 36 36 36

    250 cure MPa - 26 35 30320 cure MPa 28 36 38 36

    5% weight loss temp. 480 475 435 475250 cure - 230 250 235320 cure 270 305 320 310350 cure 270 305 380 310380 cure 270 305 400 315400 cure 270 305 430 320

    die lectric constant 2.9 2.9 2.9 2.9volume resistance >10^16 >10^16 >10^16 >10^16surface resistance >10^16 >10^16 >10-16 >10-16breakdown voltage >420 >420 >420 >420water absorption 0.6 0.6 0.6 0.6

    Tg(TMA)

    f ilm property

    liquid property

    residual stress

    life time

    elogation

    kV/mm

    -

    cmcm2

    %

    Gpa(320)ppm/

    (320)

    mPa.swt%

    Mpa(320)um

  • 14

    PW-series basic propertiesPW-1000 PW-1200 PW-1500 PW-2100

    coat spin spin spin spin

    prebake 120/3 120/3 120/3 115/33um mJ/cm2 175 150 150 1005um mJ/cm2 400 300 300 1507um mJ/cm2 650 550 550 250

    PEB Not required Not required Not required Not requireddevelop 20-120 20-120 20-120 20-120

    cure 320-380 250-380 250-380 250-380NMP rt/15min no change no change no change no changeGBL rt/15min no change no change no change no changeEL rt/15min no change no change no change no change

    acetone rt/15min crack no change no change no changePGMEA rt/15min no change no change no change no change

    resist stripperDMSO/mono-ethanolamine

    90/30min50% thickness decrease 10% thickness decrease 10% thickness decrease 10% thickness decrease

    25%NaOH 40/10min no change no change no change no change10%KOH 40/10min no change no change no change no change

    H2SO4/H2O2 40/10min no change no change no change no change1%HF /5min no change no change no change no change

    f lux Deltalux533 290/30sec crack no change no change no changecleaner Pine-arfa 40/30min no change no change no change no change

    process performance

    chemical resistance

    sec/min

    exposure

    solvent

    alkakine

    etchant

    without HMDS/min

  • 15

    2. Technical Data

  • 16

    0 50 100 0 50 100 0 50 100

    10000

    Oxygen

    1

    100

    250

    PCT treatment time

    Final Curing Temperature

    Cure Koyo-Thermo Systems CLH-21CDPCT :121 C, 2 atm

    Adhesion to Substrate (Si and SiN)

  • 17

    0hr 100hr 0hr 100hr 0hr 100hr

    no treatment 0/100 0/100 0/100 90/100 0/100 0/100

    0/100 0/100 0/100 30/100 0/100 0/100

    CF4(RIE) 0/100 0/100 0/100 0/100 0/100 0/100AR(Spatter) 0/100 0/100 0/100 0/100 0/100 0/100

    treatment Ti

    O2 (Plasma)

    Adhesion

    Adhesion to Metals(Cu,Ti,Cr)

    Metals is made by spattering process after each treatment.Test method:Peeling test after 0hr,100hr at 150 (peeling pcs/total pcs)

  • 18

    0

    5

    10

    15

    20

    25

    30

    35

    40

    0 50 100 150 200 250 300 350

    Temperature

    Resi

    dual

    Str

    ess

    M

    Pa

    Heating

    Cooling

    Non photosensitive P I (35MPa)

    PW-1000

    Residual Stress

  • 19

    MassChemical Group

    m/z a RT16030min 16035060min 350500

    18 H2O (Imidization 4.32 1.49 1.01

    44 CO2(Sensitizer 6.49 1.91 0.93

    99 NMPSolvent 5.57 0.09 0.00

    4.18 2.00 0.88

    28 Organic gas (Sensitizer) 3.05 0.64 1.27

    132(

  • 20

    Patterning Process of PW-1000

    Spincoat 700rpm for 10sec and 3000rpm for 30secPrebaking 120oC3min (Hot plate) (Thickness:5.1 m)Exposure 175 mJ/cm2 (g-line, i-line stepper)Development 45 sec. 2 Paddle development (Thickness:4.2 m)

    (2.38% TMAH solution)Curing 170oC for 30min+320oC for 60min (N2)

    (Thickness:3.1 m)

    3

    Spincoat 700rpm for 10sec and 2100rpm for 30secPrebaking 115oC3min (Hot plate) (Thickness:8.1 m)Exposure 325 mJ/cm2 (g-line, i-line stepper)Development 45 sec. 2 Paddle development (Thickness:6.9 m)

    (2.38% TMAH solution)Curing 170oC for 30min+320oC for 60min (N2)

    (Thickness:5.0 m)

    5

  • 21

    Spincoat 700rpm for 10sec and 1600rpm for 30secPrebaking 115oC3min (Hot plate) (Thickness:11.6 m)Exposure 450 mJ/cm2 (g-line, i-line stepper)Development 60 sec.2 Paddle development (Thickness:10.0 m)

    (2.38% TMAH solution)Curing 170oC for 30min+320oC for 60min (N2)

    (Thickness:7.0 m)

    7

  • 22

    for 5 m Thickness after Curing(Manual Coating)Coating Recipe(manual coating)

    STEP Time Rotate Accell. Dispense(sec) (rpm) (rpm/sec)

    1 10.0 200 1000 PI Dispense2 5.0 0 1000 03 10.0 700 2000 04 30.0 2100 1000 05 2.0 0 1000 0

    Development Recipe

    STEP Time Rotate Accell. Dispense(sec) (rpm) (rpm/sec)

    1 1.0 1000 10000 02 3.0 1000 10000 1 73 1.0 500 10000 1 74 1.0 100 10000 1 75 4.0 30 10000 1 76 36.0 0 10000 57 3.0 1000 10000 1 78 1.0 500 10000 1 79 1.0 100 10000 1 7

    10 4.0 30 10000 1 711 31.0 0 10000 512 5.0 0 10000 513 5.0 500 10000 3 4 914 5.0 2000 10000 3 4 915 10.0 3000 10000 0

    DeveloperTMAH 2.38%Flow rate0.6 L/minRinserwaterFlow rate1.2 L/minBack rinsewaterFlow rate150 mL/minExhaust60 PaNozzleStream Nozzle

    Polyimide coating (Mark 7)

    C/SCOL 23 X 60 sCOATPre-Bake (HP) 115 X 180 sCOL 23 X 60 sC/S

    ExposureI-line Stepper GCA 8000 DSW WAFER STEPPER

    Exposure Dose 325 mJ/cm2)focus 0m

    Development (Mark 7)C/SDEVC/S

    CuringAppratusINH-21CD (Koyo Thermosystem)Heatingr.t. 17030 min 32060 min r.t. (slope 3.5/min)Oxygen concentration

  • 23

    Coater recipe(Auto)STEP Time Rotation Accel Dispence Arm1 Arm2

    1 1.0 0 100 0 1 center W home2 2.0 0 100 0 1 center NW home Dispence No.3 9.0 50 100 1 1 center NW home 1PI dispence4 6.0 50 100 1 1 center NW home 5back rinceOK735 5.0 0 10000 0 1 center NW home 6edge rinceOK736 10.0 1100 10000 0 1 home NW home7 30.0 1530 10000 0 1 home NW home8 5.0 1530 10000 0 1 home NW in19 1.0 1000 10000 6 1 home NW in1 Film thickness is controled in step 7,8.10 30.0 1000 10000 5 6 1 home NW in211 1.0 1000 10000 5 6 1 home NW in112 25.0 1000 10000 5 6 1 home NW in2 Edge rince flow rate10ml/min13 5.0 1000 10000 6 1 home NW in2 Back rince flow rate70ml/min14 1.0 1000 10000 0 1 home NW home15 2.0 500 10000 0 1 home NW home

    for 5 m Thickness after Curing(Auto Dispense)

    Development Recipe

    STEP Time Rotate Accell. Dispense(sec) (rpm) (rpm/sec)

    1 1.0 1000 10000 02 3.0 1000 10000 1 73 1.0 500 10000 1 74 1.0 100 10000 1 75 4.0 30 10000 1 76 36.0 0 10000 57 3.0 1000 10000 1 78 1.0 500 10000 1 79 1.0 100 10000 1 7

    10 4.0 30 10000 1 711 31.0 0 10000 512 5.0 0 10000 513 5.0 500 10000 3 4 914 5.0 2000 10000 3 4 915 10.0 3000 10000 0

    DeveloperTMAH 2.38%Flow rate0.6 L/minRinserwaterFlow rate1.2 L/minBack rinsewaterFlow rate150 mL/minExhaust60 PaNozzleStream Nozzle

    Polyimide coating (Mark 7)

    C/SCOL 23 X 60 sCOATPre-Bake (HP) 115 X 180 sCOL 23 X 60 sC/S

    ExposureI-line Stepper GCA 8000 DSW WAFER STEPPER

    Exposure Dose 325 mJ/cm2)focus 0m

    Development (Mark 7)C/SDEVC/S

    CuringAppratusINH-21CD (Koyo Thermosystem)Heatingr.t. 17030 min 32060 min r.t. (slope 3.5/min)Oxygen concentration

  • 24

    Keeping days 0 3 7

    after coating

    Thickness

    Thickness afterdeveloping

    Sensitivity

    0 3 7after exposure

    11.52 11.52 11.52

    11.52 11.52 11.52

    10.06 10.05 10.02

    10.06 10.04 9.96

    425mJ/cm2

    425mJ/cm2

    425mJ/cm2

    425mJ/cm2 425mJ/cm2

    425mJ/cm2

    Prebaking Condition 4min (TEL Mark-7)Development Condition solution 120sec(total time)bSensitivity 5m resolution @7m thickness

    Keeping days

    Thickness

    Thickness afterdevelopingSensitivity

    Coated Film Stability

  • 25

    Thickness Range SigmaWafer No.

    1 7.8043 2642 7.8000 2333 7.7900 2924 7.8031 3165 7.7936 2596 7.7702 2247 7.8055 2018 7.8558 2549 7.8385 314

    10 7.7771 22011 7.7686 22612 7.7380 40813 7.9036 31114 7.8005 37315 7.7960 32916 7.8075 35417 7.8102 49118 7.8467 44519 7.8712 54620 7.8622 38821 7.7697 23422 7.8696 29023 7.8050 20024 7.8281 32925 7.8784

    1040713828848772546573711863513606

    1121936

    1153835

    10811264124315531142657676539980168 64

    Mean 7.8162

    Wafer ThicknessNo1

    1 7.82082 7.77083 7.79914 7.78575 7.78836 7.83197 7.85978 7.81499 7.7892

    10 7.805211 7.806612 7.755713 7.8280

    Mean 7.8043

    Range 1040

    264

    17

    13

    Coater : Tokyo Electron Mark-7

    Film Thickness Uniformity

  • 26

    Critical Dimension after Development

    Process ConditionPre-baking 1203min (proximity)

    (Thickness 7.90m)Exposure tool i-line stepperDevelopment 120sec. Paddle (2.38%TMAH solution)

    (Thickness 6.67m)

    Mask Size 10

    4

    6

    8

    10

    12

    14

    16

    150 200 250 300 350

    Exposure Dose (mJ/cm2)

    Ape

    rture

    Size

    (m

    )

    Top

    Bottom

    Mask Size 5

    0

    2

    4

    6

    8

    10

    12

    150 200 250 300 350

    Exposure Dose (mJ/cm2)

    Ape

    rture

    Size

    (m

    )

    Top

    Bottom

    Mask Size 20

    14

    16

    18

    20

    22

    24

    26

    150 200 250 300 350

    Exposure Dose (mJ/cm2)A

    pertu

    re S

    ize (

    m)

    Top

    Bottom

  • 27

    Mask Linearity after Development

    Bottom Size

    0

    5

    10

    15

    20

    25

    30

    150 200 250 300 350

    Exposure Dose (mJ/cm2)

    Ape

    rture

    Size

    (m

    )

    5m Mask

    10m Mask

    20m Mask

    Top Size

    0

    5

    10

    15

    20

    25

    30

    150 200 250 300 350

    Exposure Dose (mJ/cm2)

    Ape

    rture

    Size

    (m

    )

    5m Mask

    10m Mask

    20m Mask

  • 28

    Critical Dimension after Curing

    Curing ConditionApparatus INH-21CD (Koyo Thermosystem)Heating 14060min+32060min

    (slope: 3.4/min)Oxygen under 300ppm (Nitrogen gas purge)

    (Thickness 5.12m)

    Mask Size 5

    0

    2

    4

    6

    8

    10

    12

    150 200 250 300 350 400

    Exposure Dose (mJ/cm2)

    Ape

    rture

    Size

    (m

    )

    Mask Size 10

    4

    6

    8

    10

    12

    14

    16

    150 200 250 300 350 400

    Exposure Dose (mJ/cm2)

    Ape

    rture

    Size

    (m

    )

    Mask Size 20

    14

    16

    18

    20

    22

    24

    26

    150 200 250 300 350 400

    Exposure Dose (mJ/cm2)A

    pertu

    re S

    ize (

    m)

  • 29

    Mask Linearity after Curing

    BottomSize

    0

    5

    10

    15

    20

    25

    30

    150 200 250 300 350 400

    Exposure Dose (mJ/cm2)

    Ape

    rture

    Size

    (m

    )

    5m Mask10m Mask

    20m Mask

    Top Size

    0

    5

    10

    15

    20

    25

    30

    150 200 250 300 350 400

    Exposure Dose (mJ/cm2)

    Ape

    rture

    Size

    (m

    )

    5m Mask

    10m Mask

    20m Mask

  • 30

    DOF of PW-1000

    0123456

    -5 0 5

    Focus

    Actu

    al S

    ize

    DOF of PW-1000

    8

    9

    10

    11

    -5 0 5Focus

    Actu

    al S

    ize

    DOF of PW-1000

    18

    19

    20

    21

    -5 0 5

    Focus

    Actu

    al S

    ize

    Mask Linearity of PW-1000

    0

    20

    40

    60

    0 20 40 60

    Mask Size (A

    ctu

    al S

    ize(

    DOF and Mask linearity

  • 31

    Storage Stability

    1500cp

    3000cp

    Viscosity

    500

    1000

    1500

    2000

    0 5 10 15 20 25 30Storage days (at 23)

    mP

    a

    Viscosity

    1000

    2000

    3000

    4000

    0 5 10 15 20 25 30Storage days (at 23)

    mPa

    Exposure Dose

    0

    200

    400

    600

    800

    1000

    1200

    1400

    0 5 10 15Storage days (at 23)

    mse

    c

    Exposure Dose

    0

    200

    400

    600

    800

    1000

    1200

    1400

    0 5 10 15Storage days (at 23)

    mse

    c

  • 32

    0

    20

    40

    60

    80

    100

    0 200 400 600

    cure temperature

    reac

    tion r

    ate(%

    )

    Relationship between Reaction rate and Curing Temperature

  • 33

    Supplement

  • 34

    exposure

    Indene carbonic acid

    Photo Reaction

    Insoluble in Alkaline Soluble in Alkaline

    Sensitizer

    Alkaline Developer

    Polymer

    OH

    X

    OH

    XR R

    ON2

    SO2OR

    COOH

    SO2OR

    Naphtoquinone diazido

    Soluble in Alkaline

    Basic Principle of Photosensitivity

    Easily SolubleHardly SolublePositive tone pattern

  • 35

    Toray Positive tone Photosensitive Polyimide

    Negative tone Photosensitive Polyimide/Ester type

    Comparison of Negative-tone and Positive-tone Polyimide Structure

    COOR*

    O

    NH

    OHN

    *ROOC

    NN

    O

    O

    O

    O

    Polyamic acid ester

    Heat

    nn

    Polyimide

    R*NR2+H2O

    CH2CH2OO

    O

    R*:

    Polyamic acid ester

    R*: CH3

    COOR*

    O

    NH

    OHN

    HN

    *ROOCn

    H2COSi

    CH3

    CH3

    COOR*

    O

    NH

    O

    *ROOC xy

    m

    Heat

    R*

    O

    N

    O

    HN

    H2COSi

    CH3

    CH3

    x yN

    OO

    Si-unit

  • 36

    Assumed Model Adhesion between PI and EMC

    Negative tone Photosensitive Polyimide/Ester type

    Toray Positive tone Photosensitive PolyimidePolymerSi-unit

    Curing

    Epoxy MoldingCompound Direct bonding

    Epoxy Molding Compound

    Curing

    Polymer

    Indirect bonding

    Si unit additives

  • 37

    Suflic acid+

    Hydrogen Peroxide

    FumedNitric acid

    40C for 1hr. No change

    RT 1hr. No change50C 10min Completely Resolved

    NMP, DMF, IPA, MEK etc. Inert

    Cured Film

    Uncured Film(As developed)

    NMP GBL Cyclo-Pentanone Ethyl-lactate Acetone IPA

    Easily soluble Easily soluble SolubleEasily soluble InsolubleInsoluble

    Positive resist stripper, such as TOK-106, can be removed PW-1000 before curing easily.

    Stability for Chemicals

  • 38

    etchin

    0.00

    0.50

    1.00

    1.50

    2.00

    2.50

    3.00

    3.50

    0 1 2 3 4 5 6

    Treatment

    Etc

    hin

    g th

    ickn

    ess

    OFPR-800

    PW-1000

    BG-2480

    etching

    0.00

    1.00

    2.00

    3.00

    4.00

    5.00

    0 1 2 3 4 5 6

    Treatment time (min.)

    Etc

    hin

    g th

    ickn

    ess

    OFPR-800

    PW-1000

    BG-2480

    etching

    0.00

    0.20

    0.40

    0.60

    0.80

    1.00

    0 2 4 6

    Treatment time (min.)

    Etc

    hin

    g th

    ickn

    ess

    OFPR-800

    PW-

    BG-2480

    RIE conditionApparatus Reactive Ion Etching Model RIE-IONsamcoGas O2: 50.2 SCCM

    CF4/O2: 25.1/25.3 SCCMCF4: 50.0 SCCM

    RF-Power RF-cont: 500FWD: 278W REF: 1WTime 1min, 3min, 5minPressure 0.60 Torr

    Plasma Etch Resistance of PW-1000

  • 39

    Characteristic Curve of "PW-1000(5 m Thickness after Curing)

    Exposure: i-line Stepper (GCA DSW-8000:NA=0.42)Thickness:7.8m after Prebaking on Si

    0%

    20%

    40%

    60%

    80%

    100%

    1 10 100 1000 10000

    115120125

    Nor

    mal

    ized

    Rem

    aini

    ngFi

    lm T

    hick

    ness

    Exposure Dose(mJ/cm2)

    Prebaking Temperature

    Lithographic Performance on I-Line Exposure System

  • 40

    Koyo-Thermo Systems CLH-21CD170 C30min X 60min

    540 10 %OK400 C

    522 20 %OK350 C

    480 30 %OK320 C

    5%Weight Loss Temp.Elongation

    AdhesionSi, Al, SiNafter PCT 400 Hr

    Curing Temp.

    Effect of Curing Condition (PW-1000)