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7/23/2019 Problems of sulfur in petroleum products and derivatives.doc
http://slidepdf.com/reader/full/problems-of-sulfur-in-petroleum-products-and-derivativesdoc 1/2
7/23/2019 Problems of sulfur in petroleum products and derivatives.doc
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Process description
1n an industrial hydrodesulfuri#ation unit, such as in a refinery, the
hydrodesulfuri#ation reaction takes place in a fixedbed reactor at elevated
temperatures ranging from 3'' to *'' 4 and elevated pressures rangingfrom 3' to 53' atmospheres of absolute pressure, typically in the presenceof a catalyst consisting of an alumina base impregnated with cobalt and
molybdenum $usually called a o6o catalyst&! Occasionally, a combinationof nickel and molybdenum $called 7i6o& is used, in addition to the o6o
catalyst, for specific difficulttotreat feed stocks, such as those containing ahigh level of chemically bound nitrogen!
The image below is a schematic depiction of the equipment and the process flow streams in a
typical refinery HDS unit.