PROJECT TITLE: POLYMER COATED ORDERED MESOPOROUS CARBONS WITH MULTIFUNCTIONAL PROPERTIES CONTRACTOR: "Petru Poni" Institute of Macromolecular Chemistry, Romanian Academy GRANTED BY: Romanian National Authority for Scientific Research, CNCS - UEFISCDI PROJECT DURATION: 1 st May 2013 - 30 th April 2015 PROJECT LEADER: dr. Maria IGNAT MENTOR: dr. Valeria HARABAGIU PROJECT NUMBER: PN-II-RU-PD-2012-3-0357
PROJECT TITLE: POLYMER COATED ORDERED MESOPOROUS CARBONS WITH MULTIFUNCTIONAL PROPERTIES CONTRACTOR: "Petru Poni" Institute of Macromolecular Chemistry,
PROJECT TITLE: POLYMER COATED ORDERED MESOPOROUS CARBONS WITH
MULTIFUNCTIONAL PROPERTIES CONTRACTOR: "Petru Poni" Institute of
Macromolecular Chemistry, Romanian Academy GRANTED BY: Romanian
National Authority for Scientific Research, CNCS - UEFISCDI PROJECT
DURATION: 1 st May 2013 - 30 th April 2015 PROJECT LEADER: dr.
Maria IGNAT MENTOR: dr. Valeria HARABAGIU PROJECT NUMBER:
PN-II-RU-PD-2012-3-0357
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Project summary The proposed project entitled Polymer coated
ordered mesoporous carbons with multifunctional properties will be
developed in Institute of excellence of the Romanian Academy by a
team formed from the project leader and a tutor with
complementarily expertise required for the project development,
e.g. mesoporous carbons and polymer science, respectively. The aim
of this research project is to prepare polymer-coverd ordered
mesoporous carbon materials with high adsorption properties,
appropriate for decontamination of industrial water and
haemoperfusion. The project is organized in three research phases
dealing, respectively, with (a) the preparation of mesoporous
nanoparticles; (b) functionalisation of the particle by chemical
treatment and polymer coating; (c) characterization of structure,
physico- chemical and the sorption properties of the functional
particles. Expected results: three ISI papers; six conference
presentations.
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- To establish a reproducible method for the synthesis of
highly ordered mesoporous carbons with designed architecture and
showing high sorption properties; - To provide a treatment method
affording high functionality (surface reactivity and wettability)
of the pore surfaces; - To optimize the preparation conditions of
polymer-carbon systems in order to minimize the particle
agglomeration and to maintain appropriate porosity; - To establish
preparation-structure-properties correlations and to check the end
use properties of the optimized materials. Project objectives
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2013 A1.1. Synthesis and characterization of ordered mesoporous
carbon materials with high sorption properties. A1.2. Providing a
treatment method affording high functionality of mesoporous carbon
surface. 2014 A2.1. Synthesis and characterization of
polymer-carbon composites. A2.2. Optimizing the synthetic
conditions of the propozed composites in order to maintain
appropriate porosity. A3.3. Establishing the
preparation-structure-properties correlations of the optimized
composites. 2015 A3.1. Study of the polymer coated-ordered
mesoporous carbon for the prevention particles agglomerations.
A3.2. Verification of end-use properties of the synthesized
composites. Project activities
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Project results 2013 synthesis of ordered mesoporous carbon
Ordered mesoporous carbon materials were obtained by template
synthesis using SBA-15 silica template and glycerol as carbon
precursor.
Project results 2014 preliminary application test The obtained
results showed that the adsorption capacity obtained for
PNiPAM-functionalized mesoporous carbon (80%) is greater than the
vitamin B2 adsorption on pristine mesoporous carbon (53%). These
results show that the PNiPAM-functionalized mesoporous carbon
compare favorably with unfunctionalized mesoporous carbon
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Dissemination ARTICLES Effect of the synthesis conditions on
glycerol-derived mesoporous carbon materials, M. Ignat E. Popovici,
P. Cool, V. Harabagiu, Microporous and Mesoporous Materials,
submitted for publication. ORAL PRESENTATIONS AT INTERNATIONAL
SCIENTIFIC MEETINGS Mesoporous materials: synthesis,
characterization, applications, Maria Ignat, STREAM Summer School,
8-13 iulie, Iasi, Romania 2013. Influence of the Pyrolizing
Temperature on the Textural Properties of the Templated Mesoporous
Carbon Materials, M. Ignat, E. Popovici, P. Cool, V. Harabagiu 3rd
International Conference Nanomaterials: Applications and Properties
2013 (NAP 2013), 16-21 septembrie, 2013, Golden Kolos Resort, 9,
Chervonoarmiiys'ka Str., Alushta, Crimea, Ucraina. 2013
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Dissemination ARTICLES Surface chemistry the key-property of
templated mesoporous carbons for sorption, Maria IGNAT, Vera
MEYNEN, Pegie COOL, Valeria HARABAGIU, Revue Roumaine de Chimie,
under review; Glycerol-derived mesoporous carbon: N 2 -sorption and
SAXS data evaluation, Maria IGNAT, Liviu SACARESCU, Pegie COOL,
Valeria HARABAGIU, Applied Surface Science, under review;
"PNiPAM-functionalized mesoporous carbon for adsorption of vitamin
B2", Maria IGNAT, Maria Emiliana FORTUNA, Liviu SACARESCU, Mirela-
Fernanda ZALTARIOV, Valeria HARABAGIU, Environmental Engineering
and Management Journal, 2015, accepted for publication in 2015; The
effect of heating temperature on glycerol-derived mesoporous carbon
porosity, Maria IGNAT, Liviu SACARESCU, Valeria HARABAGIU.
2014
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Dissemination ORAL PRESENTATIONS AT NATIONAL/INTERNATIONAL
SIMPOSIA Polysilanes: organic-inorganic polymers for
optoelectronics, V. Harabagiu, M. Ignat, G. Sacarescu, M.
Simionescu, L. Sacarescu, XI me Colloque Franco-Roumain sur les
Polymres, Piteti (Cornul Vanatorului), Roumanie, Les 27-29 aot 2014
oral presentation. Riboflavin uptake by polymer functionalized
mesoporous carbon, M. Ignat, M. Fortuna, L. Sacarescu, V.
Harabagiu, XI me Colloque Franco-Roumain sur les Polymres, Piteti
(Cornul Vanatorului), Roumanie, Les 27-29 aot 2014 - poster.
Glycerol-derived mesoporous carbon: N 2 -sorption and SAXS data
evaluation, M. Ignat *, M. Fortuna, L. Sacarescu, V. Harabagiu, 10
th International Conference on Physics of Advanced Materials
ICPAM-10, Iasi, Romania, 22-28 September 2014 poster. The effect of
heating temperature on the templated carbon porosity, Maria Ignat,
Liviu Sacarescu, Valeria Harabagiu., 6 th Szeged International
Workshop on Advances in Nanoscience - SIWAN6, 1518 October 2014,
Szeged, Hungary - poster. PNiPAM-functionalized mesoporous carbon
for adsorption of vitamin B2, Maria Ignat, Maria Fortuna, Liviu
Sacarescu, Valeria Harabagiu., 2 nd International Conference on
Chemical Ingeneering ICCE 2014, Romania, Iasi, 5-8 Noiembrie, 2014
poster. Adsorption study of vitamin B2 on polimer-carbon composite:
Freundlich and Langmuir isotherms, Maria Ignat, Maria Fortuna,
Liviu Sacarescu, Valeria Harabagiu, A XXXIII-A Conferin Naional De
Chimie, Cciulata, 01-03 Octombrie 2014 - poster. 2014
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Budget Stage 2013105600 Stage 2014165600 Stage 201528800 Total
Budget300000
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Contact Dr. MARIA IGNAT "Petru Poni" Institute of
Macromolecular Chemistry Aleea Grigore Ghica Voda 41A, 700487 Iasi,
Romania Tel: +40232 260188 Fax: +40232 211299 E-mail:
[email protected]