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Quantum Physics II PHYS 402, Fall 2015 Instructor: Victor Galitski Lecture 2: A physical interpretation of QM Part I: Meaning of the wave function; the Born rule

Quantum Physics II PHYS 402, Fall 2015 Instructor: Victor Galitski Lecture 2: A physical interpretation of QM Part I: Meaning of the wave function; the

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Page 1: Quantum Physics II PHYS 402, Fall 2015 Instructor: Victor Galitski Lecture 2: A physical interpretation of QM Part I: Meaning of the wave function; the

Quantum Physics IIPHYS 402, Fall 2015 Instructor: Victor Galitski

Lecture 2: A physical interpretation of QMPart I: Meaning of the wave function; the Born rule

Page 2: Quantum Physics II PHYS 402, Fall 2015 Instructor: Victor Galitski Lecture 2: A physical interpretation of QM Part I: Meaning of the wave function; the

Schrödinger equation

The Nobel Prize in Physics 1933 was awarded jointly to Erwin Schrödinger and Paul Adrien Maurice Dirac "for the discovery of new productive forms of atomic theory."

Page 3: Quantum Physics II PHYS 402, Fall 2015 Instructor: Victor Galitski Lecture 2: A physical interpretation of QM Part I: Meaning of the wave function; the

Born interpretation

The Nobel Prize in Physics 1954 was divided equally between Max Born "for his fundamental research in quantum mechanics, especially for his statistical interpretation of the wavefunction"

Page 4: Quantum Physics II PHYS 402, Fall 2015 Instructor: Victor Galitski Lecture 2: A physical interpretation of QM Part I: Meaning of the wave function; the

So, what is the wave-function?

• It may be a wrong question to ask, as the wave-function is a mathematical construct(one among several others) that allows us to calculate what we are interested in (observables, i.e., something we can actually measure).

Quantum observable, X, at t=0

Know:

Quantum observable, X, at a later time t=T

Want to know:

No closed equation for X…

Find the wave-functionwhich satisfies a closed

Eq and determines X

• We certainly have seen such auxiliary concepts elsewhere in physics. For example:

Neither scalar nor vector potential is directly observable, which does not surpriseus, neither should we be surprised by the wave-function…

Page 5: Quantum Physics II PHYS 402, Fall 2015 Instructor: Victor Galitski Lecture 2: A physical interpretation of QM Part I: Meaning of the wave function; the

Quantum Physics IIPHYS 402, Fall 2015 Instructor: Victor Galitski

Lecture 2: A physical interpretation of QMPart II: Operators

Page 6: Quantum Physics II PHYS 402, Fall 2015 Instructor: Victor Galitski Lecture 2: A physical interpretation of QM Part I: Meaning of the wave function; the

Appearance of operators in Schrödinger’s “derivation”

Experimental fact: quantum electronsmay exhibit wave-like properties

Assume that they may be describedby a plane-wave function:

We have to reconcile it with

Hence the free Schrodinger equationWe can write it as

if we identify,

Generalize it to

with

Page 7: Quantum Physics II PHYS 402, Fall 2015 Instructor: Victor Galitski Lecture 2: A physical interpretation of QM Part I: Meaning of the wave function; the

Expectation values

Page 8: Quantum Physics II PHYS 402, Fall 2015 Instructor: Victor Galitski Lecture 2: A physical interpretation of QM Part I: Meaning of the wave function; the

Quantum Physics IIPHYS 402, Fall 2015 Instructor: Victor Galitski

A physical interpretation of quantum theoryPart III: Time-independent Schrödinger Eq. Eigenvalue problems

Page 9: Quantum Physics II PHYS 402, Fall 2015 Instructor: Victor Galitski Lecture 2: A physical interpretation of QM Part I: Meaning of the wave function; the

Getting rid of the time derivative, when it’s not needed

Page 10: Quantum Physics II PHYS 402, Fall 2015 Instructor: Victor Galitski Lecture 2: A physical interpretation of QM Part I: Meaning of the wave function; the

A simple (mathematical) example of an eigenvalue problem

Page 11: Quantum Physics II PHYS 402, Fall 2015 Instructor: Victor Galitski Lecture 2: A physical interpretation of QM Part I: Meaning of the wave function; the

Operators, eigenvalues, and eigenvectors in QM: summary

Page 12: Quantum Physics II PHYS 402, Fall 2015 Instructor: Victor Galitski Lecture 2: A physical interpretation of QM Part I: Meaning of the wave function; the

Quantum Physics IIPHYS 402, Fall 2015 Instructor: Victor Galitski

Lecture 2: A physical interpretation of QMPart IV: Superposition principle; Dirac notations; representations

Page 13: Quantum Physics II PHYS 402, Fall 2015 Instructor: Victor Galitski Lecture 2: A physical interpretation of QM Part I: Meaning of the wave function; the

Superposition principle in quantum mechanics

Page 14: Quantum Physics II PHYS 402, Fall 2015 Instructor: Victor Galitski Lecture 2: A physical interpretation of QM Part I: Meaning of the wave function; the

Simple reminder from linear algebra

x

y

x’

y’

Page 15: Quantum Physics II PHYS 402, Fall 2015 Instructor: Victor Galitski Lecture 2: A physical interpretation of QM Part I: Meaning of the wave function; the

How to choose a basis/representation