Report On XRF Analysis of Samples Grimsthorpe and Tudor ...€¦ · Report On XRF Analysis of Samples Grimsthorpe and Tudor Townships, Ontario For Lydia Diamond Exploration of Canada

Report On

XRF Analysis of Samples

Grimsthorpe and Tudor Townships, Ontario

For

Lydia Diamond Exploration of Canada Ltd.

October 23, 2003

31C14SW2019 2.26551 GRIMSTHORPE 010

Index

Introduction

Property

Location and Access

General Geology

Sample Collection

Analysis

Page

l

1

2

2

3

Location Plan

Twp. of Tudor

Twp. of Grimsthorpe

facing 2

facing 2

facing 2

Appendix I XRF Analysis

Sample WD-AR-TI

October 26, 2001

Appendix II XRF Analysis

Samples TDMM - 10 fc 33

November 1,2001

Appendix III XRF Analysis

Samples MM80 *fe 103

Decembers, 2001

Appendix IV XRF Analysis

Sample TD MM 177

January 17,2002

Appendix V

Index cont'd

XRF Analysis

Sample TD MM 188

February- 8, 2002

Appendix VI XRF Analysis

Samples TD MM 192 (fc 193

February 19,2002

Appendix VII XRF Analysis

Samples MM 198,217, 202, 13, 31, 196,

195, 188, 201, 203, 208, 215, 216, 212,

211,210,209A, 189,200,63, 199, 103,42

and 204

March 4, 2002

Appendix VIII XRF Analysis

Samples MJ- 17B&8A

Drill Holes 99 @ 420 ft.

100 @ 392 ft.

101 @ 200 ft.

May 6, 2002

Appendix IX XRF Analysis

Samples MJ - 19A (2 samples)

May 8, 2002

Appendix X XRF Analysis

Samples MJ - 9, 12, 13, 14, 15 A 16

May 9, 2002

Index cont'd

Appendix XI XRF Analysis

Samples MM 239, MJ21, 28 k 29

May 29, 2002

Appendix XII XRF Analysis

Sample 269F

May 31, 2002

Appendix XIII XRF Analysis

Samples


105 @ 112 ft.

June 6, 2002

Appendix XIV XRF Analysis

Samples MJ 24 k 24 PDR

June 27, 2002

Appendix XV XRF Analysis

Samples MJ 39, 41,38

Drill Hole 113@ 16ft.

Appendix XVI XRF Analysis

Samples

Drill Holes 115 @ 26.5 ft.

115@ 29ft.

115@ 36ft.

Index cont'd

Appendix XVII XRF Analysis

Samples TD MM 107, 61, 162, 184, 171,

170&99

December 18,2002

Appendix XVIII XRF Analysis

Samples BE-2N


75 @ 18 ft.

75@21 ft.

75 @ 25 ft.

75 @ 25 ft.

75 @ 26 ft.

75 @ 30 ft.

76 @ 34 ft.

Appendix XFX Sample Locations

Introduction

Analysis by XRF both of hand samples collected in the field and samples of drill

core was carried out on samples from Grimsthorpe and Tudor Townships, Ontario for

Lydia Diamond Exploration of Canada Ltd. The XRF analysis was performed at the

XRF laboratory, Department of Geology, University of Toronto in Toronto, Ontario.

Reports on the results of the XRF analysis are given in the appendices.

Property

The property consists of 125 claims containing 1,025 claim units. The claims are

numbered SO 1077074, SO 107791 to 1077095 incl.; SO 1167015 to 1167026 incl.;

SO 1167045 to 1167048; SO 1167139, SO 1167255 to 1167256, SO 1167279,

SO 1167289, SO 1184029 to 1184030; SO 1192192, SO 1192200, SO 1195071 to

1195072; SO 1195077, SO 1195165, SO 1195167, SO 1195169, SO 1195177 to 1195181

incl.; SO 1195183, SO 1199128 to 1199167 incl.; SO 1199170 to 1199172 incl.;

SO 1199888 to 1199890 incl.; SO 1199501 to 1199518 incl.; SO 1199520 to 1199530,

SO 1199550, SO 1242376 to 1242379 incl. and SO 1242095 to 1242906 incl. in the

townships of Tudor, Grimsthorpe, Cashel and Effingham, Southern Ontario Mining

Division. They are held in the name of Lydia Diamond Exploration of Canada Ltd.

In addition there are 9 claims containing 134 units numbered SO 1235047 to

1235052 incl., and SO 1235054 to 1235056 incl. in Grimsthorpe Township held in the

name of Prinz Jergen von Anhalt and Princess Emilia von Anhalt.

O 10 20 1 Inch.11 miles or 1 centimetre-7 kilometres

30 Milles

Hi TOWNSHIP OF

TUDOR

(e)' VII

la H

Vi

VI

V

IV

II

1.120)

Location and Access

The property is located about 20 km north of Madoc, Ontario. Madoc lies at the

junction of Highways 7 and 62. Highway 7 runs east from Toronto through Peterborough

to Ottawa; Highway 62 runs north from Belleville to Bancroft. Madoc is about 41 km

north of Belleville. Access to the property is by secondary township roads which run east

from Highway 62. Sample sites on claims SO 1195181 and SO 1195077 are accessed by

the Wolf Lake Road, logging roads and trails from this road.

Sample sites on claim SO 1235050 was accessed from a forest access road which

passes through the north part of Grimsthorpe Township. The forest access road connects

with the Weslemkoon Road between the villages of Gilmour and Gunter. The

Weslemkoon Road runs east from Highway 62 about halfway between Madoc and

Bancroft. Property location is shown on the enclosed map.

General Geology

The property is underlain by a volcanic to sedimentary sequence intruded by

mafic to granite rocks. Metamorphic grade is generally high. The area is part of the

Proterozoic Grenville province of the Precambrian shield. In general, the east part of the

property is underlain by mafic intrusive rocks of the Lingham Lake complex with mafic

volcanics to the west and south, with a narrow band of felsic volcanics followed by

carbonate metasediments further west.

There has been previous exploration in the area for gold and lead-zinc.

Sample Collection

Samples were collected by Lydia geologists from pits, trenched and outcrops on

the property. Sample of several pounds were placed in plastic bags, identified as to

location and later cleaned and examined before sending to the XRF lab at University of

Toronto. Approximately 1A day was spent on collection of each sample.

Drill hole cores were examined using existing logs as a guide and samples

selected for analysis. Samples were placed in plastic bags, identified as to drill hole

number and footage in the hole before sending to the XRF lab at U. of T.

Approximately l hour was spent on collection of each sample.

Analysis

The XRF analysis was carried out at the laboratory, Department of Geology,

University of Toronto, using a Philips PW2404 sequential x-ray fluorescence

spectrometer. A short flyer from the Department of geology is attached.

Appendix I

XRF Analysis

Sample WD-AR-TI

October 26, 2001

UNIVERSITY OF TORONTO

DEPARTMENT OF GEOLOGY22 Russell Street, Earth Sciences Centre

Toronto, Ontario M5S3B1

Fax: (416)978-3938 Tel: (416)978-302?.

Date: 26 October 2001

Fax Number: 416 504 7760 No. Pages: 2

Please call (416)978-3022 tf you do not receive all the pages

TO: JeremyBrett

FROM: Mike Gorton

WD-AR-Tl Tholeiitic basaltic/gabbroic compositionHigh Cr, Ni and Co suggest somewhat cumulate nature

10/26/2001 11:08University of Toronto

Quantified peaks in d:\superq\data\w1-ar-t1.pks

Summary of results

Page 1

Sample;Measured:

Quantified:Sum:RMS:

Used lines:

Qual. program:

WL-AR-T110/26/2001 10:3710/26G001 11:08 J100 'A0.00123Rhsemiq

ConcentrationsAnalyt*

NaMgAJSiPSCIK

CaTiVCrMnFeCoM,ZnRbSr

r YZrNb3a

Type

SampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSamplesampleSampleSampleSample

CaUbnfian status

CalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibrated

Compound

Na20MgO

A12O3SiO2

P205S03

CIK20CaOTi02

VCr

MnOFe2O3

Concentration ! Calculation CM l method

1.35211.30412.48749.1550.4120.0310.03

1.7276.2011.1210.01

00850.141

15.822Co 0.009Mi

ZnRbSrY

ZrNb

Calibrated 1 Ba

0.0320.0210.0110.0080.0040.0170.0020.019

CalculateCalculate

u^-

XCalculate -CalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculate

^

-* V^f

**x**5c^•2.z\\\o^^^lof q 3

KJ

Sample preparationSample typis: pressed powder l

Area ratio: l.if |Additive/sample: ~07

Film: NoneNormalise: to 100 O1*,X-ray path: Vacuum

Quantify parameters^cV5uperq\datateemiql.rcp

.Spectrometer resp. fihs g \supefq\da1a\se miq stiUse compound list c;\5uperq\exainpte\geoiog.cpl'

Apply drftt con.'. No DiMll. etern. set: NoneDraall. h'nes set NoneErrofWBiohtJmi: Root'

Appendix II

XRF Analysis

Samples TD MM - 10 A 33

November l, 2001



Toronto, Ontario M5S 3B1

Fax: (416)978-3938 Tel: (416)978-3022

Date: l November 2001


Please call (416)978-3022 if you do not receive all the pages

TO, Jeremy Brett

FROM: Mike Gorton

TD-MM-10 Very high MgO, Cr, Ni and Co. Obviously a very olivine rich cumulate

Fe a bit high - opaques7

TD-MM-33 Only totals 90Vo Surface irregularities could explain totals as low as about 97Vo, so the rest must be alteration (mostly H2O)Results recalculated to 970/*, which requires 6'7o H2O - this is not areliable calculation.Again very high MgO, and Ni with Cr and Co higher still. Even morecumulate than TD-MM-107High Fe = opaques0 Some cpx as well.

'1/1/2001 12:04University of Toronto

Quantified peaks in d:\superq\ctata\td-ntm-1a.pks

Summary of resultsSample:

Measured:Quantified:

i Sum:I RMS:

Used Imw;s Traces:

TD-MM-1011/1/2001 11 4111/1/2001 12:0398.6 %0001 j20Rh i

i QuaJ. program: semiq i

Page 1

ConcentrationsAnalyte

NaMgAlSipSC!K

GaTiVCfMnFeCoNiC(JZnSr

Type

SampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSample

ZLr i Sample

Calibration status

CalibratedCalibratedCatoatedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibrateaCalibratedCalibrated

Compound

Na20Mgd

AI203SI02

P205SO3

CIK20CaOTIO2

vCr

MnOFc2O3

CoNi

CuZnSrZr

ConcentrationW

0.16526.675

5.46743.463

Od490.736008

0077

5.53103210.01602170.135

15.5170.0190.0920.01800120.0070.002

Calculation method ;

Calculate jCalculate iCalculate 'Calculate jCalculateCalculate :Calculate 'Calculate :Calculate ;Calculate jCalculate ,Calculate 'Cslcu'ate jCalculateCalculateCalculateCalculate iCalculateCalculateCalculate j

L.

Sample preparation Sample type; pressed powder

____Area ratio: 1.01^-—,—.—, Additiygteampte: O_______

Fito NNoneNormalise: noX*raypath: Vacuum

Quantify parameterei Recipe:' Spectrometer rasp, flte:

Use compound list:Appty drift corr.:

! Otsall. dam. set:Di&ail. lines sat:Error weighting:

Max. Sealed detector intensity:Max. Flow detector intensity: Max. Scmt detector intensity:

c:\3uperq\date\semiq1 .repc:\suoerq\dataVsemiq.stic:VsuperqVexamo!e\geolO3 cNoNoneNoneRoot2500 kc^s2500 kcpsISOOkcps

i i

ci l

-\-J___ 1

i

12.23University of Toronto

Quantified peaks in d:\3uperq\dataVW-mnv33.pks

Summary of resultsSample: TD-MM-33

Measured: 11/1/2001 11: iQuantified:

Sum:11/1/2001 12:23 i 90.8 V, H

RMS; Q.001Used lines: 20

Traces; Rh

Pagel


NaMgAlSiPSCiK.

CaTiVGrMnre

CoNsZnAsSrZr

Type Calibration ttatus

Bincer ; Not matchedSample : CalibratedSamp.e i CalibratedSamplesample

CalibratedCalibrated

Sample i CalioratedSample CalibratedSampie i CalibratedSample calibrateaSample CalibratedSample j CalibratedSample CalibratedSampleSample


Sample CalibratedSample CalibratedSample j CalibratedSample CalibratedSample Calibrated

: Samole ; CalibratedSamcie Calibrated

Compound

H20Na20

ConoBfitnttMM) VM

6.1110.051

MgO 24858

Calculation i inuttiod

FixedCalculateCalculate

AI2O3 1 4.206 j CalculateSi02P205503

389920.0510.037

CI 0.024K2O 0.012

CalculateCalculateCalculateCalculateCalculate

CsO 6.29 i CalculateTiO2

VGr

0.4010.019

CalculateCalculate

0.3 CalculateMnO ' 0.157 ; Calculate

Fe2O3 15,254 ' CalculateCo 0.03 CalculateNl 0.091InAs

0,010005

CalculateCalculateCalculate

Sr 0.008 CalculateZr 0002 Calculate

Sample preparationle type: Powder (binder: H2O) i

Initial weight: 100 g —-™—.Final weight 1.06 g-—-^—-———-

Area ratio: 1.07 --—,Additive/sample: O 07 _______ ___Film: None .^ -

Normalise: no -^-—^^-^X-raypath: Vacuum

Quantify parameters_____________ Recipe: c:\superq\riata\semiq1.rep ~"[

Spectrometer reap, fite: s. \superqV3ataV8emiq.sti \ Use compound list; c:\superq\exarnple\aeolog.cpi ,

___ Apply drift corn NoDrsall. clem, set: None Disall. lines set: NoneError weighting: Root

Appendix III

XRF Analysis

Samples MM 80 A 103

December 3,2001

12/3/2001 1642 University of Torontoiâka in d:\superxjVatota\W-mm-8Q.pks

Page

Concentrations

Sample Ma Sample Mg Sampte A) Sample Si Sample

i p Sampte ' s Sampte l ci sample l K Sample

Ca Sample Ti Sample V Sample Cr Sample Mn Sampte Pe Sample Co Sampte Ni Sample j Cu \ Sample Zn Sample

j Rb SampleSr Sample i

Sample

Not matched Calibrated Calibrated Calibrated Calibrated , Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated CalibratedT i •famprv. i ——.,— -,,

Zr j Sampte j Calibrated

Na2O Mgo

502 P20S503

CI

CaOT102

V205cr

MnO Fe203 j

c** iNij

Cu iZn!RbSrVZf

10.298

7.8410802

0-1220-123

Dance Calculate Calculate Calculate Calculate i Calculate i Calculate Calculate | Calculate j Calculate Calculate Calculate Calculate Calculate

L041 j Calculate | 0004) Calculate t

Calculate Calculate Calculate0.008

0.0030.0220.002

Calculate Catenate Calculate

nnosl Calculate.

Use*

amatere-—^——data\semiql r fc

TaSIcAsuEergWataMniB^! - Ms--^gSgMJ*nEW!BSSl84SEU

EiTocwejgceiaL

page i

iza'2001 16.1' University of Toronto

(P'

——— jsampte"

Na MgA! Si lp is iCI K

Ga T; VGr Mn FeCo

Sample Sample Sample Sample SampleSampteSample SampleSample SampleSanpte

****"* —— i-Not matched

Calibrated Calibrated Calibrated j Calibrated ;

, CalibratedCalibratedCalibrated Calibrated Calibrated

j calibrated j Calibrated

.Sample i Calibrated Samptej Calibrated Sample! Calibrated

l Sample 1 CalibratedNi i Sample i Calibrates Cu 'SampleS CalibratedZnRbSrYZr Nb...

—— fnoT ——— 7.752 Balance ^0 1RB3I CalculateNaû i MgO|

AJ2O3 SiO2

P2O5CQ3O^Jw

Q K20CaO Tt02

V205Prl Ol

MnO Fe203

Co NiCuT-Sample) Calibrated j "*

Samplej Calibrated IJsample Calibrated ^Sampte Calibrated YSample Calibrated *

' — —-i /~9liKrntaH l1*'.i Samp

9.081 . 11326 37.077

0.065 0.0590.0280.919

1Z053 3.702 Q.174

0.010.147

15.885 0.006

Calculate Calculate Calculate Calculate CalculateCalculateCalculate ; Calculate Calculate Calculate t Calculate \Calculate j calculate j Calculate

0.006 i Calculate0.006

0.010.0030.0160,003o.otfo.oo:

Calculate CalculateCalculateCalculateCalculate

t Calculates Calculate

re j âuiyi'cii.^* t — ——— -- .- — —————

•Vi"

Appendix IV

XRF Analysis

Sample TD MM 177

January 17,2002



Toronto, Ontario MSS 3B1

Fax: (416)978-3938 Tel: (416)978-3022

Date: 17 January 2002



TO: Jeremy Brett

FROM: Mike Gorton

TD-MM-l 77 Very low total which I have made up with H2O.Cumulate mafic rock with rather high Ca - probably amphibole

1/17/02 14:52University ot Toronto

Quantified peaks In c:\superq\data\ttimm-177.pks

Page 1

Summary of nw***Sample: TDMf

Measured: ~ 1/17/Quantified! 1M7_____

Sum: 100. Vo |_____RMS; 0.001____j

Utcd lines: 17_____ j____Traces! CuZnRhCs~lQua!, program: serniq_ ^j

ConcentrationsAnalyte Type l Calibration Compound l Concentration

status : WSampls Notmatcneu H2O 18,613

Na Sample Calibrated Ma2OMg Sample Calibrated MgOAl j SampleSi j SampleP ; SampleS SampleCi SampleKCaTi

. VCr

Sample

Calibrated AI203Calibrated SiO2Calibrated P2O5Calibrated SO3Calibrated i CI

059717.6939363

368060.0110.054OOB7

Calibrated K2O ' 0 102Sample CalibratedSample CalibratedSampleSample

Mn SampleFe SampleCo SampleMi SampleSr Sample

CalibratedCalibratedCalibratedCalibrated

CaO S.883Ti02

V0.128

0.01Cr2O3 ! 0.165

MnO i 0 097Fe203

Calibrated j CoCalibrated NiCalibrated Sr

70340.00800390005

Calculation ' methodBalanceCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculate

Sample preparationSample type: pressed powder

Area ratio: 1AddHive/sampte: 0

Fitnu NoneNormalise: to 1 00 0^ with as balance H20X-ray path: vacuum

Quantify parameters—-—————Recipe: c:Vsupefq\data\serniq1 rep

c: \superq\data\8emiq. stiUse compound list: c:\9UpeKi\6xample\96olofl.cpl'

APPIV drift cofT.: NoDisatl None^ ., DisaJl. lines set: None

Root________Enof weighting: Max. Sealed detector intensity: 1300kcps

Max Flow detector jntanaity 25CO kcpe Mac. Scmt detector intensity: 10OP ks&s

Max. Duplex detector intensity: 3000 kcps '

Appendix V

XRF Analysis

Sample TD MM 188

February 8, 2002

3. 2ii2 4:43P'*1


DEPARTMENT OF GEOLOGY22 Russell Street. Earth Sciences Centre


Fax; (416)978-3938 Tel: (416)978-3022

Date: 8 February 2002


Please cal) (416)978-3022 if you do not receive aJl the pages

TO: JeremyBrett

FROM: Mike Gorton

TD-MM-188 Looks like a normal, slightly fractionated, tholeiitic basalt

Recalculated to l OO'/o because it only totaled 90"A (altered?)

2/8/C2 University of Toronto Quantified peaks In c:\superq\ctatettdmm-1884*8

Measured: 2/8/0215.09

_____Traces: Cr CoGaJ^l! jjMigjgggram: semlq —

Page

Anaiyte

Ma iMg tAl i

i Si j: Pi S1 CIi Krv: Ca

Tj

' VMnFtMi

i "li 1 -.-u1 Zn

Kb; si Y1 Zr

Type j Calibration (1 ' '

Sample :Sample iSample iSample iSample .Sample jSampleSample jSample jSample iSample iSample

: Samplej Samplej Sample' Samplej Sample1 Samplej Sample

Samp'e

SORU* iCalibrated fCalibrated iCalibratedCalibratedCalibrated jCalibrated iCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibrated

! Calibratedi Calibratedj Calibrated

Calibrated

Concentrations--———rrz—————. . ^ j l i central**' i'

CA) !LJMlMiai**H ' 1

method" 2.828 j Calculale |

6.69114629

CalculateCalculate ;

52.846! Calculate0.22S0046

CalculateCalculate

0.078 Calculate0 986 l Calculate !774212130.032

Q. 1712.438

0.0170.007O.OG8O.OM0.02600020.013

Calculate iCalculaleCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculate.

Appendix VI

XRF Analysis

Samples TD MM 192 A 193 February 19, 2002

Ft




Fax: (416)978-3938 Tel: (416)978-3022

Date: 19 February 2002

Fax Number: 4165047760 No. Pages: 2


TO: JeremyBrett

FROM: Mike Gorton

TD-MM-192 Very coarse grained. High MgO, CaO, Fe2O3 and very low A12O3, P205, Sr, Zr etc. Cumulate pyroxenite.

TD-MM-193 Low total (altered ?), basaltic composition, very primjtivf Zr/Y

OF

2/19/0217:14University of Toronto

Quantified peaks in c:\Buperq\dataVtdmnv192-pks

Summary of resultsSampte: TOM M-192

Measured: 2/19/021449Quantified: 2/19/02 17 12

Sum: 99.8 "/oRMS: 0.001

Used lines: 22Traces: Rh

Qual. program: semiq

Pagel

ConcentrationsArtalyto

NaMgAlSIPSCIK

Ca

Type Calibration Compound l status ;

Sample Calibrated Na20Sample i CalibratedSampleSampleSampteSampleSampleSample


MgOAI203Si02

Calibrated P205Calibrated SO3Calibrated CICalibrated K2O

Sample Calibrated CaOri Sample Calibrated

j V Sample CalibratedCr Sample CalibratedMn ! Samcle CalibratedFe SampleCo SampleNi SampleCu SampleZn Sample

TJ02V

CrMnO

Calibrated Fe2O3Calibrated CoCalibrated NiCalibratedCalibrated

RC Sample i Calibrated. Sr , Sample

Y SampleCalibratedCalibrated

CuZnRtSrY

Zr ; Sample Calibrated Zr

Concentration(y.)

0.375U.8834.236

47.8760.029055900530.245

1333820040.0540.0410.241

15.739002

0.039OC220.0110.0010.00200020.003

Calculation method

CalculateCalculateCalculate .Calculate .CalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculate 'CalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculate

Sampte preparationSample type: pressed powder

Area ratio; 1.Addttive/sampte: 0.

Film: NoneNormalise: noX-ray pattr Vacuum

Quantify parametersRecipe: c:\superg\data\semiqlTOp

Spectrometer res p. file: c:\superq\data\3emiql .sti _Useopfnppund J

Appry drift corr.: Nocpl !

Dtsall. olem. set: Di&alL lines set: NoneE/TOT weighting: Root

Max- Sealed detector intensity: 2000 Kcps

2/19/021708 University of Toronto Quantified peaks in c:\8uperq\datt\Mmm-193.pKs

Summary of resultsSample: TDMM-193

Measured; 2/19/02 14 31Quantified: 2/19/02 17:08

Sum: 94.6'/oRMS: O.OOilines: 20

Traces: Cu Rh CsQiiaL program:

Pagel

-y-Concentrations

Hnaiyw

NaMgAiSiPSCIKCaTiVGrMnFeNiZnRt

. SrYcr

type i v/auorauon ' vompourra (*oncvmnmon âtcuiaiion : status. (y.) method '

Sample Calibrated Na20 1.652SampleSampleSampleSampleSample


M9O 918AI2O3

SiO2P2O5

Calibrated SO3Sample i Calibrated j CI

10.76346.642

0,2630.074

Calculate :CalculateCalculateCalculateCalculateCalculate

0.091 CalculateSample' Calibrated i K2O 1.639 i CalculateSample Calibrated CaO 9.736Sample ; CalibratedSample CalibratedSample CalibratedSampleSampleSample

T!02 1.001V

CrCalibrated i MnO

00250.03S0.147

Calibrated Fe2O3 13.23Calibrated : Ni

Sample CalibratedSample CalibratedSample CalibratedSample

CalculateCalculateCalculateCalculateCalculateCalculate

0013 CalculateZn 0.012 CalculateRb 0.005Sri 0.013

Calibrated YSample Calibrated Zi

0.0030.01

CalculateCalculateCalculateCalculate

Sample preparation [^ Sgryte type: pressed powder i Ara*ratio: IDS______ i Additive/sample: Q ——————. P ~" Fibre Nonel— Normalise: no

X-ray path: Vacuum

Quantify parametersRecipe: c:\supe(q\data\3emlq'! .rep

. file: c:\superq\data\semiql.stiUse compound list c:\superq\exampletaeology.cpl

1 Apply drm corr.i NoDtsatl. elem. set 1Disall. lines sirt:

____ Error weiflhttna: Root _ Max. Sealed detector intensity: 2000 Kcps

Max. Flow detector intenttty 10OOjtcps Max, Scint detector Intensity., j'ooo K

Appendix VII

XRF Analysis

Samples MM 198, 217, 202,13, 31,196,195,188, 201, 203, 208,

215, 216, 212, 21, 210, 209A, 189, 200 ,

63,199,103,42 and 204

March 4, 2002

20)2



Toronto. Ontario M5S3B1

Fax: (416)978-3938 Tel: (416)978-3022

Date. 4 March 2002


Pleas* call (416)978-3022 if you do not receive all the pages

TO: Jeremy B re It1

FROM Mike Gorton

Here are the results, without comment (it's too late tonight).

All of the results have been recalculated to 1000A anhydrous, because

many chips were too small to total correctly.

42 had no letter prefix. I've assumed it was MM-42 ../"

MM-21 7 is a pressed powder pellet, as requested.

i/4/02 12:26 University of TorontoQuantified paaks in c:\8UpcrH\data\nmt198_.phs

Na 1Mg lA!SiPSC!KCa7iVCrMnPeCoMlCuZnGaRbSry7;

Nh

i

Sample ;Sample iSample jSampleSampleSample

i SampleSampleSample

i Sample( Sample' Samplei Samplei Sample

1 Sample

Calibrated jCalibratedCalibrated 'Calibrated jCalibrated jCalibratedCalibrated |calibrated jCalibrated j

j Calibrated '; Calibratedi Calibratedl calibrated


1 sample Calibratedl Sample ! Calibratedl Sample | Calibratedi Sample ; CalibratedSample j Calibrated

1 Sample l CalibratedSample 1 CalibratedSample ; Calibrated

, Sample , Calibrated

Na20Mgd

AI2O3

P2O5I S03!

CIK20CaO'TiO2

V205Cr2O3

MnOFc203

CoNi

Cu

2.264 9.178 !

10.897 56.567

0.189 0.098 0.107 1.023 9.045 O 745 i D.054 i 0.058 ! 0.1291

9.56 l 0.008 0.028 0009

0.01 0.0020.003;0.019 ! 0.002 l 0.005 l 0001

"Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate j Calculate | Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate

"X-rav path:, Vacuum

4/4/021806 'Jniversrty ot Toronto

Quantified peaks In c:\superqldata\mm217_

Summary of results^ Sample:i Measured:i Quantified:i Sum:i RMS:^ Used Unas:; Traces:

Quat, program:

MM2174/4/02 17:36 '4/4/0218:05100 "X,000018 iY Rh j

sem q i

Page


NaMgAlSiP5C!K

GaTiV

i Crl Mn

FeNiZn

l SrZr

Type i Calibration L status

SampleSampleSample

CalibratedCalibratedCalibrated

Sample CalibratedSample \ CalibratedSample ' CalibratedSample CalibratedSample CalibratedSample CalibratedSample CalibratedSample 1 CalibratedSample CalibratedSample CalibratedSample j CalibratedSample ; CalibratedSample ; CalibratedSample CalibratedSample Calibrated

CompoundJ .-ji Na20

MgC' A12C31 StO2

P20SSOS

; ci1 K20i CaOi T.O2: V205

Cr203MnO

Fe203i Ni

i z*STZf

CortcentrationW

0.66823176

4.53250.49005

0.0140.04

0.28611636

0.3350.0370.4240.115

8.": 3

0.0560.00500030003

i Calculation ' method1 Calculate! Calculatel Calculatei Calculate; Calculate

Calculate1 Calculatei Calculate, Calculate

Calculate1 Calculate

Calculate: Calculatei CalculateI Calculate\ Calculatei Calculate' Calculate

Sample preparation Sample typo: pressed powder

Area ratio: 1.05 ___Additive/sample: Q.^——.

^______Ftlm; MoneNotmat'tfe: to 10D.0%X-ray path: Vacuum

Quantity parametersRecipe: c:\superqVJatateemiq1rcp

Spectrometer resp. fite; c:\supefg\data\6emiql .

Use compouod Itef. c:\supefq\gxampteSgeologv.cp1

____Apply drift cotT.; No______________. eletn.set; 1

. lines set: NoneError weight ing: Jjoot

Max. Sealed detector intensity. 2000 Kcps

Max. Flow detector intensity-. "^goo kcps

Max.jcirrt detector intensity: lOQOkcps^

jttf Dêxjjgtector intensity; 3000 kcps

Page4/4/32 15 CI University of Toronto

Quantified peaks In c:\superq\data\mni202_—.pks

Summary of results: Sampte: MM202j ——— Measured: 4/4/0212:!'" auanttfted: 4/4/021!?.

47|:U1

i Sum: 100 %! RMS: 0.001T Used lines: 22j"' Traces: R h

l ———— -H

lj Qua), program: semiq __ !

Concentrations -AnaJyle '

r— Na 'M*?S,

i P i S1 a i K1 C3

Se rl V Gr

i Mn i Fe j Co

N. i Cu

Zn Sr Y

'- Zi

Type CalibratJon | Compound , ; status 1 i

Sample Sample Sample - Sample j Sample Sample Sample Sample

' Sample i Sampte ! Sample

Sample Sample

l Samole Sample

i Sample Samcie Sample

' Sample i Sample

Sample ! Sample

Calibrated i Calibrated Calibrated l Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated

Derived Calibrated Calibrated Calibrated

i Calibrated Calibrated



1 Calibrated Calibrated Calibrated

Na2Oi Mgo

A12O3 SIO2 P205

SO3 CI

K20 CaO

Se TiO2

V2O5 Cr203

MnO 1 Fe203

Co Ni

CU

i l\ v

z

Concentration gaicuuraon (%) method i0.442, " ' --

14. 169 | 3.693 ;

48.163 i 0.035 0-177 0113 0271 1482

i 0.011 ' 0.93 ' 0.142

0.043 0.205

l 16.674 i 0,009

O.Cf29 l 0.051 j 0.012 l 0.003 \ 0.003

r ! 0.005

oatcuiaie Calculate j Calculate Calculate j Calculate ! Calculate \ Calculate j Calculate i Calculate Calculate , Calculate |

i Calculate j j Calculate i

Calculate j Calculate

1 Calculate j Calculate Calculate ; Calculate i Calculate '

, Calculate , 1 Caicuiate |

- Sample type:Area ratio:

"Addttive/sampte:Film:

Normalise:X-ray path:

Dressed powder'1.040.None Jto IOQ.0% jVacuum j

jauantay paramgtetsRecipe: c:\superq\data\semiql .rep

~" c:\3Uperq\data\semiqi sti

Max. Saalad detector irrtaniity

SEGtC'G 1'

4/4/02 10:38 University of Toronto

Quantified peaks in c:\supenfldataunm13_

_ Summary of resultsSanyte: MM13

..pks

Measured: 4/4/02,08:36Quantified; 4/4/02 10 36

Sum: 100 %RMS: 0000

Usedlirws: 23Traces: Rh

l Qual. program: scmig

Pagel

ConcentrationsAnatyte Type Calibration ; Compound

! statueNa Samplevig SampleA!

Calibrated Na2OCalibrated

Sampte Calibrated31 Sample i CalibratedP SampleS Sample


Ci Sample CalibratedK Sample

MgOAI2O3

SiO2P205

SO3Ci

Calibrated K20

Ca Sample Calibrated CaO

Se Sample i Derived Se

li : Sample Calibrated TiO2

v ' SampleGrMnFeCoMiCL

SampleCalibrated V2C5Calibrated ' Cr2O3

Sample CalibratedSample CalibratedSample Calibrated

MrtOFe203

Co

Sample ' Calibrated l N:Sample Calibrated

Zn SampleRtST

, V

SampleSampleSample

CuCalibrated ZnCalifcratect ; RbCalibrated SrCalibrated Y

1 Zr Sample l Calibrated Zr

Concentration W

0.0610.0416031

4862600420.0910.0580266

19S44O.C060.9470.1190.2630.16B

136710007005

0.0070.006

) 0.0030007

l 0.0020,005

Calculation iwthod

CalculateCalculateCalculate 'CalculateCalculateCalculateCalculateCalculateCalculate 'CalculateCalculateCalculateCalculate iCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculate


1.07Area ratio:Additive/samp!*: 0. ——

Film: Noneto IQP'0%

^X-ray partti; Vacuum

Quantify parametersRecipe: c.\superq\data\8erniqi.rcp

Spectrometer reap, fite: c:V3Liperq'j3ata\semiq1 ,ati _

Use compound fist; cAsuperq\cxampleêo!ogy cpi

____Appty drift corr.: No ___________

____DisaH. etom. set. 1________________

____Disalt. tines set: None^-—-————J^—-—-, Roct

\ r r.u ' n.. i. 20C2 f; f fi n U L^ .Uv \0. -/:

4W/02 1036'age

University of Toronto

Quantified peaks In c:\5uperqvdata\mrn31,

Summary of results

..pks

, Sample: MM31i NteMured: 4/4/020856^l Quantified: 4/4/02

Sum: 100 "/o10:36

j RMS: O.OODUsed lines: 19 __ ,

Traces; Rh, Qual. program: semkL

ConcentrationsAnatytn

i: Na

Mg; AI! Si' pl s' CI; Ki Cai Ti

Mni **i Coi Ml| Cu1 Zn

Sri Yi Z'

Type

SampleSampleSampleSampleSampleSampleSampleSampleSam pieSamoleSample

i SampleSampleSampleSampleSampleSample

l Sample' Sample

Calibrationstatus

CalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibrated

Con •pound C

Na2OMgO

AI2D3SiO2

P2O5SO3

ci iK20CaOTiO2MnO

Fe2O3CoNi

CuZnSr,Y iZrl

XNICDfUftftltNI

W0.208

19.6385.234

51 .3240.0260.0450.0520.0636.6330.0660.206

16.4110,01005

O.0040.0170.0020.0030.002

Catctilationnwthod

CalculateCalculateCalculateCalculateCalculateCalculate iCalculate jCalculateCalculate ICalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculate

1 Calculate

Sample preparationSamototype: pressed powder

, Area ratio: l. 071 Addttwtfsompte: 0.

FHm: None .. iNormalise: to 100. OK —— iX-ray path: Vacuum ____ ,

Quantify parametersc:\3Uperq\dataVsemiq1.fcp

Spectrometer nap, file; c:\superq\data\semiqrstiUse compound list:

i Apply drift conv.Dtsdl. elem. setCHftall. Unas set:

c:\superq\exampleVêology.cpl lNo1None

-l

Error we* RootMax. Seated detector intensity: 2000 tops.

Max. Flow detector intensity: ijiOO kcps Man. Scint detector intensity.' 1GOO kcps

Max-Duplaidetectorintenstty: 3000 Kcps,

4/4/C2 1' University of Torontc Quantified peaks In c:\superqWata\mm196_ ..pks

Summary of results _——^Sartpte: MMI^L-^

—— 4/4/02 TTT7J

-—-Used IHVBS: 2C

Traces: CuRn,Qua), program:

Page

[Analytejir Na

MgA)Si

i PS

i CIl Kl Ca

Tii Gri Mn1 Fe

Coi Ni1 Zn' Rb

3rYZr

TypejSample '

Sample jSampleSampleSampleSampleSampleSampleSampleSample

' Samplel Sample' Sample

SampleSampte

j Samplei Sample| Sample1 Sample

Sarule

Calibration i Cotstatus

Calibrated ,Calibrated !CalibratedCalibrated jCalibrateaCalibrated iCalibratedCalibrated :Calibrated ,Calibrated

i CalibratedCalibratedCalibrated :

i Calibrated !! Calibrated ;i Calibrated 'i Calibrated ,! Calibrated '

Calibrated ii Calibrated

Na2OMgO!

AI203 lSiO? i

P2OS 1SC3

CiK20caoTiO2

Cr2O3MnO

Fe2O3CoMl

ZnRbSryZr

- — \-^j ——— i, 3.273 15.198 j

Calculate lCalculate

'S. 143 i Calculate |50.731

0.41Calculate iCalculate

0,265 | Calculate0.016 Calculate077: Calculate886

1.635CalculateCalculate

0.013 ; Calculate0.13 "

12.414j 0.006


i 0 006 Calculatej 0014 l Calculate

0 002 i Calculate; 0.05 j Calculate! 0 004 Calculatei Q 01 1 i Calcjlarte

____Normalise; to JCj^y path: Vacuum

4'4.'02 11:-i O University ot Toronto

Quantified peaks in c:\superq\data\mnrl95_.pks

Summary of resultsSampte: MM195

Measured: 4/4/02 10 59

j Analyte

NaMgAlSiPSCiCaSeT:vGrMnFeCo

' Ni. Zn

Y

Typ*

Sample1SampleSampleSamoleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSamcleSampleSample

! l! Sample

1 Quantified: 4/4/02Sum: 100 K

l RMS: 0.001: Used lines: 19

Traces: RhQua), program: semiq

ConcentrationsCalibration {Compound C

status lCalibrated , Na2OCalibrated , MgO |Calibrated j AI203 -Calibrated l SiO2Califtraled ! P2O5Calibrated j S03Calibrated ; ciCalibrated ' CaO

Derived j SeCalibrated TiO2Calibrated i V2O5Calibrated l Cr2O3Calibrated ( MnOCalibrated ; Fe2O3Caiibratec | CoCalibrated j NiCalibrated ! Zn iCalibrated : YCalibrated Z r

11:40

J___ j

Soncentration(Vo)

0 14115.8873778

46.0910.02

00470.021

10.6370.01157780.1870.0590.199

170760.0150.032O.C1600020.004

Calculation jTTWtJiod

Calculate 1CalculateCalculateCalculate lCalculate jCalculate !Calculate jCalculate iCalculate 'CalculateCalculate \CalculateCalculate iCalculateCalculateCalculateCalculateCalculate 'Calculate

Sample preparationSample type: pressed powder 1

Area ratio: 102Addrtive/sampte: 0.

Film: None—————

j

Normalise: tolOO.0% iX-ray path: Vacuum '

Quantify parametersRecipe; c:\superq\data\semiq1 ree

i Spectrometer rasp, file; c:\6uperqVJata\semiqi.sti ,

i Use compound list:Apply drift corr.:Dicail. dem set:DlMll. lines s*t

i Error weighting:Max. Settled detector intensity:

Max. Flow detector intensity:Max. Scmt detector intensity.

Max. Duplex detector intensity:

c:\supergVexample\qeologv.cpl iNo |1None iRoot ,2000 kcps1000 kcpsTooo kcps3000 kcps

4/4/02 11-09 University of Toronto

Quantified peaks in c:\superq\data\nrrm188^^.pks

Summary of resultsSamptc-.

Measured: 4/4/02 10 24 lQuantified: 4/4/02 11.09 j

Sum: 100. 'fr ;RMS: 0.001 .

Used lines-. 2CTraces: Rh

QuaL program: semig

Page

Concentrationsi Analyte

! NaMgA!

l 3"i P

S! C!i K

Cal T;i V! Cri Mn

FeCoNiCu

! Znl S ': Zr

Type.

SampleSample

Calibration status


Sample CalibratedSample CalibratedSample CalibratedSampleSampleSample


Sample CalibratedSample CalibratedSample CalibratedSample CalibratedSample ; CalibratedSarrple . CalibratedSample CalibratedSample CailbraredSample CalibratedSampie CalibratedSample j Calibrated

t Sample i Calibrated

Compound

Na2OMgO

AI203Si02

P2O5SO3

CIK20CaOTiO2

V205Cr:o3

MnCFe203

CoNi

CuZnSrZr

Concentrationl (*)j 4.276l 6.253l 13,345

51.573i 0.166

01110.306

; 0562; 6.017l 0.39i 0025! C.056i C. 094

6.749: 0.005

0 0170.0040 007

j O.G250907

Calculation method

CalculateCalculate !Calculate ,CalculateCalculateCalculateCalculate iCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculate

Sample preparation Sampte type: pressed powder

i ratio: 1.06 __ i

Film: NoneNormalise: ta IOQ.0% X-ray path; Vacuum

Quantify parameters

Spectrometer rasp, file: c:\Bupercydate\senriiqi.sti

DM compound llsf. c:\9uperqVexample\aeologv cpl

Apply drift corr.: No CSsaJI. elem. set: 1Disall. Rnm set NoneError weighting; Root

Max. Seated detector inrtentity: 2000 topsFtow detectoîntenatty; 1 000 Kcps

Max. 3cint detector mtettity 1000 kcp^

•S/d/02 14.59 University of Toronto

Quanttfled peaks in c:\superq\data\mm201—-.pks

Summary of resultsi Sample:


Sum:L RMS:i Used lines:l Traces:l Qua), program;

MM2014/4/02 12:294/4/0214:59100. "h0.00123RhAusemiq

-'age

/,

ConcentrationsAnatyte

; N3

l Mgl A!: Si, p1 5

CIK

i Ca1 Se; Ti

V] Gr1 Mn

Fei Coi Ni! Cui Zn

1 ^bi Sri Y1 Zr

Type

SampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSarnnieSamoleSampleSampleSampleSampleSample

'Calibration 1 statusj Calibrated

Compound

NalO 1Calibrated MgO

Concentration W

Calculation method

0.2S5 Calculate13.907 Calculate

Calibrated i AI203 4.96 Calculate1 Calibrated SiO2 47.68 Calculate

, CalibratedJ Calibrated

P205SO3

1 Calibrated ciCalibrated K20

j Calibrated CaOi Derived Se1 Calibrated Ti02j Calibrated V205j Calibrated Cr203i Calibrated

Calibrated

0,015 Calculate0.093 Calculate0.043 Calculate0.323 Calculate

15.068 Calculate0.013 Calculate0 741 Calculate0127 Calculate0042; Calculate

MnO 1 0.193 CalculateFe2Q3 , 16.483 i Calculate

! Calibrated Co i 0.007 - Calculate

i Calibrated Ni 0.016 ! Calculate

Calibrated Cu 0.011 Calculate

i Calibrated ' Zn 0.008 Calculate

i Calibrated Rb j 0.0011 Calibrated Sr ! 0.005

CalculateCalculate

j Calibrated Y 0.004 1 Calculate

Calibrated Zr ! 0 004 Calculate

Sample preparationSamptetype: pressed powder

Arm ratio: 1.04Additive/sample; O

Film: NoneNormalise: to IOQ.0% X-ray path: Vacuum

Quantify parametersRacipe: c:\superq\data\sgrmqi.rcp

_ Spectrometer resp. file: c:\8uperq\data\semiq1 .silUte compound list:

Apply drift carr.:c:XsupePqVexample\geology cpl No

Disall. dem. set: 1Ditall. lines set None Error weighting: Root

AFS. O: v i" v GEOLOGY i f,

4/4/02 15.38 University of Toronto Quantified peaks in c:\superq\data\mm203—-.pks

Page

Summary of results[ Sarnpte: MM20i Measured: 4/4/02

Quantified: 4/4/02i . .. Sum: 100 V

RMS: 0.000

314:531536

i ii

j Used lines: 21Traces: Cu Rh

' Qtial, program: semlq


1 Na i Mgi At 1 Si1 P1 s1 CI I Ki eal Ti

V 1 Cr

Mn 1 Fe l Co ; Ni i Zn j Rb

Sr

i Y

tyjw

^Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample

Calbration status

Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated

Compound

N320MgO'

AI203 SiO2

P2O5 S03

CI K2O CaO TJ02

V205 Cr203

M no Fe203

Co Ni Zn Rb Sr Y Zri

Concentration

0.441 9.111 8,255

56.652 0.09?

004 0074 1.332

11.531 0416 0.047 0084 0.143

11.688 0,009 0.034 0015 0003 0.009 0.003 0.011

Calculation

Calculate , Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate


Area ratio: 1.07 ÂcMrtive/sampte: 0

Film: NoneNormalise: to 100 WkX-ray path: Vacuum

-^*'

Quantify parametersRecipe: c.\superg\data\5emiq1 .rep

Spectiutneter mtp. ftte: c:\supergVdBta\serpiq1 .sti Use compound list c:\5ugerq\examgla\geology epl

Apply drrft con-.: No Diaatl. eteru set:_1

—i

Disatl. lines set: NoneError weighting: Root

Max. Saatrt detector intensity: 2000 kcps Max. Ftew detector intensity: 1000 Kcps

University of TorontoQuantified peaks in c:\superq\data\mm208^^.pks

Summary of resultsSampte: MM208

MBWUwAfWra.

RMS: 0.001Used lines: 20,

Traces: Gr Rh.Quaj. program: semiq

Page

AnatytK

Na , Mg

Al i Si

P S CI K

i Ga Ti Mn

". FeCo Cu

l Zn 1 Rt-

1 Type j

; Sample 1 Sample

Sample ' Sample | Sample j Sample

Sample Sample

i Sample , Sample 1 Sample

SampleSample

i Sample

Calibration (Compound j COW*™-" l*sta&i* i

Calibrated Calibrated Calibrated Calibrated j Calibrated , Calibrated '

: Calibrated i Calibrated i Calibrated

Calibrated Calibrated Calibrated

1 Ca!tbrated i Calibrated

Sample , Calibfatea1 Sample i Calibrated

—— "Na2C[

Mgct AI203 t

S1O2 1 P205!

SO3 i CI

K20 CaO TiO2 MnO

Fe2O3X***N.Co

1 Cu i Zn\ Rb! o.

: 5f l Sample ! CaliWaiea l ~YIsNb

1 Sample i Caltbraneo: Samp;e ! Calibrated

Sample : Calibrated

——— 3.35ST 4595

17.642 i 48.122 !

0.68 ' 0.223 l 0.107 j 0.731 '

7.744 1.393 0166'

15.152 l 0.01i 0.004 j 0.01

0.003 0.043OOQ3

j Zr , 0.01, Mb ; 0.002

method ^Calculate 1 Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate CalculateCalculateCalculateCalculate Calculate

i Calculate•; Calculatej Calculate

Max. Scint detector 'mtensi

18:00 University ci TorontoQuantified peaks in c:\siiperq\cteta\mrn215_

Summary of results

UsacMines;Traces: Rh

[Quill. jirogram: semiq.

Page 1

•3f-

Compound i Concentration

i NaMg

; N1 Si

P1 Si ri1 K1 Cai T *

V1 Cri Mn

FeGcNi

1 Cu : Zn: Sr

Y; z-i Nb

Sample | CalibratedSample Calibrated i Sample ! Caiibrated jSamole i CalibratedSample Calibrated |Sample j Calibrated j

! Sample i Calibrated ;! Sample Calibrated ;i Sample | Calibrated .i Sample l Calibrated i Sample ; Calibrated i Sample Calibrated; Sample 1 Calibrated

Sample i CalibratedSample i Calibrated

i sample l CalibratedSample ; Calibrated

i Sample ' Calibratedi Sample ' Calibrated

Sample | Calibrated1 Sample j Calibrated

i Sample ! Calibrated

Na20 1Mgo j

AI203 ;SiO2

P205 ;SO3 !

i 'vsr\ K2O iCaO :TJ02!

V2C5 :CC203'

MnO i Fe2O3

f r 'vû1 M lNi 1 ni1 \Û

ZnSrYZr

i Nb

^^2.126 3.524 !

17.338 i 46.2-d l

0.44 i 0.06 :

0.037 i 0.313 4 476 1 385 0.039 0.015

0.19

0.0070.0070.0040.0210.03600020.0130.002

Calculationmethod

Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate

i Calculate ; Calculate

Calculate i Calculate i Calculate ; Calculate

Calculate

Sample preparationSamptetype: preyed pc

Use compound lisJL,c:\sujcj

University ot Toronto

Quantified peaks in c:\superqVdata\mm2l6

Summary of resultsl

h —

r

Semple:Measured:

Quantified:Sum:RMS:

Used lines:Traces:

MM2164/4/0217 194/4/02 18:04100. %0.00022Rh

Qua), program; semig

,pks

Anatyte

NaMgAlS)

i P: S

i ClK

i Cal Ti

VGrMn

i FeNil

: Cul Zn

RbSrYz-Nb

Typ*i

Samplel Samplel Samole' Sample! Samplei Samplej Sample

, Sample] Samplei Sample

SampleSampleSample

l Samplei Sample' Samplei Samplei Sample. Sample

Samplej Sample

Sample

ConcentrationsCalibration ' Compound

statusCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedcalibratesCalibratedCalibratedCalibratedCalibrated

i Calibrated

Na2OMgC

AS203SiC2P2O5

SO3CI

K20CaOTiO2

V7O5Cr203

MnOFe2C3

NiCuZnRbSrY2sNb

Concentration ! Calculation i ('A) i method ':

3.74810.09712.989

Calculate rCalculale |Calculate i

50 068 ; Calculate ~ L-

0.544 ; Calculate0.49

0.0620.7879.3990.8250.021

CalculateCalculateCalculate ' rCalculate !Calculate jCalculate

0094 Calculate0.129

10,608Calculate 'Calculate

0017 Calculate0.014 Calculate0.015 Calculate i0004

, 0.06500040.017

i 0.002

CalculateCalculate ^CalculateCalculate *Calculate

__ Sample preparationSample type: pressed powder

____Area ratio: 107-^^^—

Additive/saiDPle: 0. _______

______Film; None————-Jtennalitft: to IOQ.0%

^_X-ray path'. Vacuum-———-

_____Quantify parameters________ ____Raeipe: c:\supetq\data\3emig1, rep

SpsctTiometBfresp.nte: c \superq\data\semig l

Uaa compound fat; \ drift corj.:

ill, elem. sefc^ Pjsati. lings set:

_ Error weighting:

c.\superq\e)tamplB'iQeology.cpl

NO

'toot

Way.. Seated^stector intensity'- 20DO Kcpa

4/4/02 17:b l University of Toronto Quantified peaks in c:\superqVdata\mnn212.

Paa E

/' T^ y/ ' ,^,-f t-*" 1

! Aruilytei

Ma, l^td

i Mgi A!

Sil p

5c:K

i Ca

i STi1 Vi C'i f'

Fe1 [Mi

1 Cui Zni Rb

SrY! z*

' Cs . Sa

~~Typ8 [Calibration .Com1 status i

~S^rrTple~^cIiib7ated !Sample j Calibrated j

1 Sample : Calibrated 11 Sample i Calibrated

sample j Calibratedi Sample j Calibrated |1 samcle j Calibratedj Sample i Calibrated .j samote ' Calibrated ;

, Sample , Derived i Sample Calibrated iSample ' Calibrated |

i Sample i Calibrated i sample | Calibrated, Sample , Calibrated1 Sample ', Calibrated i' Sample | Calibrated 1;

1 Sample i Calibrated jj Samole j Calibrated1 Sample ! Calibrated |

1 Sample Calibrated Sample i Calibrated ,

' Sample ! Calibrated | ^Sajê-LCa|iibiate^,,.

Na20MgO

AI203

P2O51 S03,

CI i

caO : Se

TtO2 V205': Cr203

MnO i Fe?03

Nl

Y , Zr: Ca '

EaO

Calculate^* Calculate Calculate Calculate j Calculate Calculate ; Calculate i Calculate i Calculate j Calculate Calculate Calculate

j Calculate i Calculate

O 043 f Calculate 0004! Calculate 0.015 l Calculate 0.003 ; Calculate 0.045 y Calculate 0.004 Calculate

Q 02 j Calculate O 028 ' Calculate 0.122 ; Calculate

1106 11.-03'

44.875 i O 424 i Q.459 j 0.027 i 3.701 13386 0,006I.018 0.034 O 143 0178II.264

i

Page

university of Torontc Quanted peaks in c:\superq\data\mm211.

ivigaaiii**.. ^-,,^-—— Quantified; 4WQ2 17:51

•y-

COIN^^TîfÎl — -TsSrTêTCalibTated j" l Mg l Sample i Calibrated . i At l Sample i Calibrated

S, Sampte i Calibrated i p Sample , Calibrated ' s ' Sample j Calibrated

1 -| ' sample ! Calibratedi K ! Sample l Calibrated i ea Sample i Calibrated l -i i Sample i Calibrated

C r ; Sample Calibrated 1 vin ' Sample i Calibrated

1 pe ,Samplel Calibrated1 -"o ' Sample ! Calibrated

ig^H^s*' —— Na20

MgO A1203 l

Si02 l P2O5 j

| S03Ja i

, | K9O 'r^LN^

j CaO \ 1 Ti02 1 ! Cr203 j

1 MnO i , Fe203 ji f*,^ 'Co ,

K t; iNi l Sample 1 Calibrated , ^ |Cu , sample 1 Calibrated j Cu

i zn , Sample ! Calibrated -f ,Sr . Sample i Calibrated ' Sr ,y 1 Sample i Calibrated ' J!

1 zr l Sample 1 Calibrated Zr 1 re 'RgmEJej Calibrated 1 CeJ.

3 131 i Caicuiaie ; ^r1 1 .91 1 l Calculate 1 12.814 Calculate j 48835 Calculate j

0 561 i Calculate ; t 0.427 j Calculate 0.012 Calculate j0 074 ' Calculate \-7.977 l Calculate i

0.86 j Calculate \ 01581 Calculate i 0171 Calculate ;

12.849 Calculate 0 014 Calculate iQ' C 34 i Calculate i0.036 ' Calculate i0 014 l Calculate ,0084 l Calculate j0003 Calculate .0017 Calculate

^^ÔH^Caiculate^

,i.'t---,

4/4/02 17.47

"aqc 1

Jniversrty of Toronto

Quantified peaks in c:\superq\data\rrnn21 Q

Summary of results

_ .pks

r Sample:i Measured:T Quantified:i Sum:l RMS:1 Used Itrm:1 Traces:i Qua), program:

MM210 ^J4/4/02 16:064/4/02 17-.47 1100. "A \0.000

^26Rhsemiq

ConcentrationsAnalyte i Type Calibration ' Compound j Concentration i Calculation j

NaMgAJSiPSC!KCaTiVCr

! Mn

Co

! Cui in

Rbi Sr1 Y

ZrNb

. SaLa

, Ce

i Sample '! Sample 1j Sample |

Sample i'i Sample |: Sample j! Sample !1 Sample .1 Sampte 1j Sample 1i Sample i| Sample 'j Sample |i Sample j| Sample |

Samplei r i , Sample ,' Sample 1i Sample' Sample j

Sample ii Sample ji Sample !i Sample -

Sample iiSamglej

\\

r

status iCalibrated iCalibrated iCalibrated iCalibratedCalibrated iCalibrated lCalibrated iCalibratedCalibrated ;CalibratedCalibrated |Calibrated 'Calibrated jCalibrated !Calibrated 'CalibratedCalibratedCalibratedCalibrated iCalibrated jCalibrated iCalibrated 'CalibratedCalibratedCalibrated 'Calicrated '

iN320 ;MgOl

AI2O3 1Si02 :

P2O5 iS03 j

C', 1,

K20CaCiTi02 '

V2O5 iCf2O3 i

VnO 1Fe2O3 ;,

Co:NilCuZniRb'

SriYi2r j

Nb 'BaO

La iCe ;

t A) i3.553

10.008 '13.686 i52.737 !

0.983 i0 055 :

0.065 i3.586 '5.706 i1.746 l0.04!0.11 !

0.094 i10.435 :

0.010.05 \

0,004;0.012;0.002 (,0.025!0.008!3.025 !0.002 !0.0230.0150.017 i

iiKnlioo iCalculate j ^Calculate iCalculate iCalculateCalculateCalculate iCalculate -Calculate j *-Calculate iCalculate \Calculate |Calculate iCalculateCalculate iCalculateCalculateCalculateCalculateCalculate 1Calculate ' *CalculateCalculate | -/fCalculate lCalculate t ^Calculate lCalculate ',

Sampte preparation __Sample type

Area ratioAdditive/ sample

FilmNormaliseX-ray path

: pfftssed powder^: 1.15: 0.; None: tolOC.0%: Vacuum

i

i1

ter reap, fite: jc:\supgrtj\dataêmiqV3ti

University of Torooio Quantified peaks in c:\superq\data\mm2Cr9a__.pks

Summary of resutoSample:

i Measured:Quantified;

L Sum:. RMS:1 Used lines:i Trace*:, Qual. proaram:

MM209A4M/02 15:48 l4/4/021741 i100. ak0.001 l23Rh jsemiq '

O ;

Analyte

S NaMgAl

i Sii Pi S1 CI1 \

Gai T:1 y

i CrMnFeCoNi

1 Cu1 Znl Rbi Sr

YIs

\ Ba

Type

SampleSampleSampleSampleSamoleSampleSarnoleSampleSampleSampleSampleSampleSampreSampleSampleSampleSampleSampleSampleSampleSampleSampleSample^

ConcentrationsCalibration

l statusCompound

Calibrated Na2OCalibrated \ MgOCalibrated AI203Calibrated Si02Calibrated : P2O5

Concentration TO

1.9259.377

14,44946204

2.14

Calculation method


Calibrated SO3 0.49 Calculate j


CI 0.061 Calculate

K2O 5.393

Calibrated CaOCalibrated Ti02

Calculate3.2 l Calculate

1.671 Calculate

Calibrated V2OS 0.066

Calibrated Cr2O3. Calibrated

CalibratedMnO

0.047CalculateCalculate

0.049 CalculateFe203 i 14.66

Calibrated Co 0.01Calibrated Ni O.O21


Calibrated Cu 0.012 i Calculate

Calibrated ZnCalibrated ! RbCalibrated Sr

, Calibrated

0.013 Calculate0.01 ! Calculate

0.019 CalculateY 0005 Calculate

Calibrated Zr i 0.025l Calibrated BaO

Calculate0.15 Calculate

Y-

Sampte preparationSample type: pressed powder |

Area ratio: 1.06 ___ __j0.

Film: None______| NonnalUMt: to IOQ.0% X-ray parth; Vacuum ~|

Quarrtffy parametsrai-^.n^^,Recipa: c:ûperq\data\gem'al icp

Spcctremeter resp. file: c:\8uperq\data\semiq1,3ti

Use compound listAppty dntt oorr.:

c\superq\example\aeologY,cpl No

Oisall. dcm. act: 1Disail. lines sat*. None Error weighting: Root'

d/4'02 11 32 University of Toronto Quantified peaks In c:\superq\data\mni1B9_

Summary of results _Sample: MM 189 i

,.pks

Measured: 4/4/02 10.4-"Quantified: 4/4/0211:33

Sum: 100RMSi O.QOO


Qua!, program^ serniq

P.jge


i Nai Mgi Al 'l s;

PsCI

i Ki Cai Ti

MnFe

i MiCuZr

1 SaRb

i SrY

i *1 Nb

Ba•- La

Ce

Tjrpc Calibration i Compound status i

SampleSampleSampleSampleSample

Calibrated 1 Na20Calibrated MgOCalibratedCalibrated

AI203Si02

Calibrated P2C5Sample CalibratedSampleSample

SC3Calibrated CICalibrated K20

Sample ; Calibrated CaCSample \ Caltbraied Ti02Sample Calibrated MnOSemple Calibrated Pe2C3Sample Calibrated \ NiSample CalibratedSample

CuCalibrated Zn

Sample Calibrated Ga

Sample Calibrated RbSample Calibrated SrSample ! CalibratedSampleSample

y

Calibrated ZrCalibrated 1Mb


BaOLaCe

Concentration CA)

S 3061.174

'8.25158.972

Q.5320.9750,5292,2983.9230.4730.11172290.0080.014

l 0012' 0.003

0007i 0.053

0.003l 0.042

0.002: 0.043

0.0130.028

Calculation i method

CalculateCalculateCalculate lCalculateCalculate lCalculateCalculate :CalculateCalculate !CalculateCalculateCalculateCalculateCalculatecalculateCalculateCalculateCalculateCalculateCalculateCalculate

; Calculatei Calculate

Calcuiate

- Area ratio: V13___

Additive/ samptei^ Film: None—-—

Normalise: to IOO.Q.%

Quantify parameters

Spectrometer resp. flle: 1,1 Use compound list:

Recipe: g:\superq\datategmig1jcg_c teupsrq\data\serrvq1 .sti

cpl

Disall- e\em. setDJsall. linwt s*rt:

4/4/02 '2:35Page 1

Univereity Of Toronto

Quanttfied peaks in c:\superqWata\mm200^.pks

Summary of results

j Analyte

! Na

i sii Pi S1 CI

K i Ga

TiV

i Cr Mr

1 Fe ! Co

Ni

! Ga

SfV"

. Zr1 Ba

Type

SampleSample SampleSample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Samole

; Sample i Sample i Sample

Sample ' Sample

Sample

| Sample: MM200 !j Measured: 4/4/0212:12 :i Quantified: 4/4/02 12:36i sum: 100. *

RM8: 0.000Used line*: 23 i

Traces: Rh Cd lOual. program: semiq i

ConcentrationsCalibration Compound Concentration

status (V.)Calibrated Na2O 1.529 Calibrated MgO 12.009 Calibrated l AI2O3 13.075 Calibrated SiO2 56072 Calibrated P2O5 0.222 Calibrated S03 0.08 Calibrated CI 0.069 Calibrated K2O 2.487 Calibrated | CaO i 2-661 Calibrated Ti02 0.574 Calibrated V2O5 0.041 Caiibiated . Cr2O3 0.083 Calibrated MnO 0107 Calibrated ': Fe2O3 10.952 Calibrated Co 0,01 Calibrated Nt 0.042 Calibrated ' Zn 0.012 Calibrated Ga 0.002

i Calibrated Rb 0.01 ' Calibrated Sr 0.01

Calibrated Y , 0004 Calibrated ' Zr | 0^017 Calibrated BaO l 0.031


Area ratio: 1.09Additiva/sampte: 0.

Film: NoneNormalise: toiOO.0%X-ray path: Vacuum

Quantify parameters

Calculation ineiliod

Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate

, Calculate Calculate Calculate

Recipe: c:\superq\data\semiq1rcpSpectrometer raspite: c:\superqW8ta\eemiQl .sti

Use compound Hsfc c \Buperq\exampleVgeology.cpl .Andy drift corr.: NoDisall. clem, set: 1

!Disall. lines set: NoneError welqMmq: Root 1

X?

/-v

-U:

4/4/02 1V13 University of Toronto Quantified peaks In c:\superq\data\mm63_

Summary of resultsSample;

4/4/02 1JL1LSum: 100 *A

-,———^.RMS: 0.000Used lines: 24

____Traces: ScRhQuaL program: semiq

Page

Concentrations^nalyte j

Na |MS sAl !sp' 1s 1CI l K i

Ca Ti | V Gr Mn Fe Co Ni Cu

1 Zn i Rb

Sr yZr

! Mb i Ba

Type ' Calibration ^ status

Sample i Sample i Sample ' Sample : Sample j Sample j Sample Sample ! Sample j Sample Sample Sample Sample Sample Sample Sample Sample Sample

i Sample Sample Sample

i Sample ' Sample ^Sample

Calibrated . Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Caliarateo

j Calibrated i Calibrated j Calibrated ' Calibrated j Calibrated

Compound l Concermwion1 (*L^

NaZD i MgO 1

AI203 SKD2 P205'

SO3 :

K20| CaO| TiO2|

! V2O5 j Cr203 !

l MnO i Fe203 ' i Co Ni '

Cu Zn Rb

1 Sr : Y i zr

1 Mb 1 BaO

O.Jfcb j 8,4 i

11.119 41.815)

1.59| 0.593 0.08

3918 5662 2382 0034 0062 0223

23.293 0.009 0,033 0,185 0.024 0.014 0.006 0.009

, OXM9 1 0.004 1 0 13jL, ————— —^— - - ——

CaiculatJoo method j

CalculateCalculate ; Calculate | Calculate j Calculate j Calculate Calculate Calculate Calculate Calculate Calculate Calculate

j Calculate 1 Calculate

Calculate Calculate

1 Calculate Calculate

l Calculate 1 Calculate 1 Ca'culate

Calculate i Calculate i Calculate

y

Sampte preparationSample type: pressed powdejj

MdrtiWsarnpje: Q.Film: None

Nonnalisg: to 100.051X-ravpalhL Vacuum

c:\8UperqVJata\semiq1_rcgSpectrometer resp. file: c:\supero|V3at9\6emiqi .sm j

Us* compound list c:\3uperq\example\geology.cpi :l

Apply drift corr.: Jai*--———rpisati. etem.,set: Dlsall. lines

Jô1None

University ot Toronto Quantified peaks in c:\superq\data\mm199_

Summary ofrasutte^Samjgje: MM 199 i

Measured: 4/4/02 11:54 j ____4/4/02 12:33J Sum: IOQ.%—— RMS: 0.000 "

24Traces: "Rh La

program: serniq

Page 1

ConcentrationsAnalytei

i

Na iMg i Al S)

lCI K

Ca 1 T! ! V i Cr 1 Mn

Fe Co Ni Zn

! Rb 1 Sr

Y ZrMb Ea C s

Type

SampleSample Sample i Sample j Sample ' Sample i Sample Sample Sample Sample Sample

| Sample i Sample l Sample L Sample ' Sample

Sample l Sample ' Sample j Sample i Sample ' Sample ; Sample

Ssmo'e

Caibration (Compound Concentration j tsMeuiaww i status i j W) j method ^

Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated | Calibrated Calibrated ; Calibrated Calibrated Calibrated Calibrated Calibrated

l Calibrated Calibrated



' Calibrated ; Calibrated ' Calibrated

N320I MgO j

AI2O3 j Si02|

P205 SOS

CI K20CaO7iO2

V2O5 Cr203

Mno Fe2O3

Co Ni Zn Rb Sr Y Zr

Nb 8aO

i Ce

2.635 y 7.139 i 14.35

•^ 55.221 - 0.401 1

0.061 0.067

- 2 662 5.925 0.823 0.044 0,068 0.107

--10.325 0.008 0009

0,01 0.011

l 0026 0.004 0.016

i 0.002 0.043 0.019

'taicuiaie TCalculate * Calculate Calculate - ^ Calculate Calculate Calculate Calculate * Calculate \ Calculate j Calculate ' Calculate \ Calculate ] Calculate \ * Calculate Calculate ' Calculate Calculate Calculate Calculate Calculate

j Calculate i i Calculate 1 1 Calculate !

Sample preparation SJunpte tYIP6: pressed powder

i Area ratio: 1-05i Addibve'sample: 0. l

Fibn: None j, Normalise: tolOO.0% :

X-ravnatti: Vacuum :

Quantify parameten?Recipe; c:\superq\data\aemiql.rcg

-- ——-J-l—\——.nlM^ ~4|

: c:\superq\exaApply drm corr.: Otsall. eicrn. sat:

.BfMSMt: None.

i. 2002 '•O. f 4-/-

4/4/02 11 03 University of Toronto.

Quantified peaks In c:\superc^data\nrm103-—.pks

Summary of results

Pags 1

Sampte: MM103Measured: 4/4/0210:06

Quantified: 4/4/0211.03Sum: 100 %RMS: 0.001


—l

Qua), program: semiq

ConcentrationsMiwyiB

NaMgAl

•y p:

Sample

VpauDranon Stahl*

CalibratedSample ' Calibrated

vrfxnpourra

Na20MgO

Sample 1 Calibrated AI2O3

Si : SampleP ' SampteSCIK

GaTiv

MnFeCoNiIn

SampleSampleSampleSampleSampleSampleSample

CalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibrated

Sample ; CalibratedSample CalibratedSample CalibratedSample Calibrated

Ga j SampleRbSrY

SampleSample


StO2P205S03

CIK2OCaOTi02

\*onaemnmcn Pi)

MMcuiauof) method

3.199 ' Calculate5.735 Calculate

1 B. 348 i Calculate48.721

0.3330.25

0.1281.16

6.7512325

V205 0.089MnO 0.086

CalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculate

Fe203 12.772 Calculate

CoNiZnGaRb

Calibrated Sr

Sample ! Calibrated ! Y

0.009 Calculate0.0040.008000300030.0540.003


Sampte preparation Sample type; pressed powder

Area ratio: 1,06^^^^ AddHive/tampte: 0:_^_____

Film: None Itormalise: tolOOO'/cX-ray path: Vacuum

Quantify parametersRecipe: c:\B_uperqyteta\semiq1.rcp

untttur resp. file: c:\superq\datBVsemiq1 .sti

Use compound list: Apply drift COTT.;

C'VsuperqXexampte'qeology.cpl'No

DJsaH.etem.set 1Oisall. lines s**: NoneEnorweighting: Root

^^_________^____t~9 ,L •w^ntaf'*"**g* i-xiufvi

Max, Seated detector intensity: 2000 kepi

Max. Flow dotactor intensity; 1000 Kcps

Max. Scint detector intensity: 10OP kcps

GtCLOG v


Quantified peaks In c:\supwq\data\mm_42_

Summary of results ' ~ SampU: MM 42

Measured: 4/4/0209:17 Quantified: 4/4/0210:48

Sum: 100RMS: 0.001lines: 20

Traces: RhQual program; semiq

Pagel


Na Mg Al Si P S CI K

Ca Ti Mn

Ni Cu 2n

f,Y

l Nb

Type

Sampte SampleSample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample

Calibration status

Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated

Compound

Na2OMgo

A12O3 Si02 P205 S03

CI K20 CaO Ti02Mno

Fe203 Ni

Cu 2n Rb Sr

'- Y ! Zr

Nb

ConcentrationW .

3.823322

16.836 49.921

0.657 0 178 0.078 1.052 7,105 1.435 0.129

15.353 0.006 0.009 0.012 0,004 0.057 0.004 002

0.003

Calculation method

Calculate Y Calculate \s Calculate Calculate v Calculate Calculate Calculate Calculate ft. Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate , Calculate | \t Calculate Calculate Calculate


Area ratio: 105 iAdditive/sample: 0

Film: None !

Normal)**: to 100 0*^ iX-ray path: Vacuum l

Quantify parametersRecipe: c \superqVdata\serma1 rep

| Spectrometer nap. fit*: c:\5uperq\data\3emiqi.gti fl Use compound list: c:\superqVexampleifleology cp!

Apply drift COFT.: No )Diull. etom. set: 1 |Distil, lines set NoneError weighting: Root

Max. Sealed detector intensity: 2000 KcpsMax. Flow detector intenstty: 1000 kcw

i

, MOT. Sclnt drtoctof Intansitv: 1000 kcpg j

4/4/02 15.43University of Toronto

Quantified peak* In c:\superqvdata\mm204__.pks

Summary of resultsSample:


Sum:RMS:

Used lines:, . Traces:

Qua), program:

MM2044/4/0215:114/4/021543100 'K.0000 ]24Rhsemiq

Page

ConcentrationsAnalyte . Type Calibration

statusMa Sample CalibratedMg SampleAlSJPSC'.

SampleSampleSample

Compound

Na20Calibrated MgOCalibrated , A12O3Calibrated SiO2Calibrated P2O5

Sarrple Calibrated SO3Sample

K SampleGa ; SampleTi SampleVCr

Calibrated CICalibrates K2CCalibratedCalibrated

Sample , Calibrated

CaOTiO2

V2O5Sample Calibrated : Cr2O3

Mn i SampleFe SampleCo i SampleNiZn

SampleSample

Calibrated MnOCalibrated Fe2O3CalibratedCalibratedCalibrated

Ga Sample CalibratedRbSr

SampleSample


Y ; Sample Calibrated

CoNiZnGaRbSfY

2r Sample i Catibrated ? ZrMb Sample ! CalibratedBa Sample

NbCatibrated BaO

Concentration ' Calculation (•A) nwthod

2447 Calculatea 01 9 i Calculate

16.116 Calculate57.877 Calculate

0.268 i Calculate0 036 ! Calculate0.0452.37412180942


0.042 i Calculate0.052 ' Calculate0.106

10.324l 0.01

0.0240.0080.0020.009

1 0.022

CalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculate

0.003 1 Calculate0.026 , Calculate0.001 Calculate0.027 Calculate

Sample preparation Sanptetype; pressed powder

Area ratio: 1.14 ——^—0.

Film: NoneNonnaUse: to-IOQ.0% X-ray path: Vacuum

Quantify parametersRecipe: c:Vsuperq\data\semiq1.rcp

SpBcttuiiieter resp. fite: c:\superq\data\semiql .st!UM compound list;

Apply drift eon-.:c:\8uperq\exaffple\geology.cpl No

Disall. dem. act 1Disali. lines s**: None

Appendix VIII

XRF Analysis

Samples MJ - 17B A 8ADrill Holes 99 @ 420 feet

100 @ 392 feet101 @ 200 feet

May 6, 2002

6.2002 6:01 3 M OP

5/6/02-1755 University of Toronto

Quantified peaks in c:\auperq\data\mj-17b__.pks

Summary of results

Page

Anaiyte

Na Mg Al Si P S CI K Ga Ti V Cr Mn Fe Co Ni Zn Sr Y Zr

Type

Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample

Sanwle: MJ-178Measured- 5/6/0217:08Quantified! 5/6^0217:55

Sum: 100. * iRMS: 0.001

Used lines: 20 jl Traces: Rn ;

Qual, program: semiq j

ConcentrationsCalibration Compound Concentration

status CA)Calibrated Na2O 1.213 Calibrated Mgo 15.735 Calibrated ACO3 5.S71 Calibrated i SiO2 46.872 Calibrated ; P2O5 0.277 Calibrated SO3 0.042 Calibrated CI 0.126 Calibrated K2O 0.257 Calibrated CaO 11.438 Calibrated TiO2 0.6T8 Calibrated V2O5 007 Calibrated Cr 0.052 Calibrated MnO 0.267 Calibrated Fe2O3 17.221 Calibrated Co 0.009 Calibrated Ni ; 0.024 Calibrated Zn 0.012 Calibrated Sr 0.011 Calibrated Y 0.002

: Calibrated Zr 0.004

Sampte preparationSample type: Dressed powder j

Area ratio: 109 _ |Additive/sample: 0 i

Film: NoneNormalise: to noo.0%X-ray path: Vacuum :

Quantify parametera

Cateutatkxi— ti _ i i mBnoa !

Calculate Calculate Calculate Calculate Calculate | Calculate Calculate Calculate Calculate , Calculate Calculate : Calculate Calculate Calculate Calculate Calculate ! Calculate Calculate Calculate Calculate

Recipe: o'\superqVdata(semiq1 rep

Spectrometer resp. fita c .\8ucero\aata\semiqi .90Use comoound list c:\superq\exampleVjeotogy.cpl [

Apply drift oorr.: NoOisall. etem. set: 1 1

Disall. lines set: None

Mn. Sealed i Mm. Flow

Error wstqrttiiw: Rootdetector intensity: 2000 kcpsdetector mtensity; 1 000 kcoe

i Max. Sent detector intensity: 1000 Kctxs

'vV'v fc. 20:2 6' l! 'il

5/6/02 17 37 University of Toronto Quantified peaks in c:\superq\data\mj4a-—.pks

Summary of result*Samnfe:


Sum:HMS:

Used lines:Traces:

Qual. program:

MJ-fiA 15/6/02 18:075/6/02 17.37100. tt0.01122Rhsemiq

Pagel

ConcentrationsAnatytel Type

i

NaMgAlSiPSCIKCaTiVCrMnFeCoNizn

1 RbSrY

! ZrBa

SampleSampleSampleSampleSampleSampleSample

Calibrationstatus

Not matchedCalibratedCalibrated

Compound

H20Na20MgO

Calibrated | A1203CalibratedCalibratedCalibrated

Sample CalibratedSampleSample


Sample CalibratedSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSample


Si02P2O5

SOSCI

K2OCaOTi02

V2O5Cr

GwiMivikbAlonW)

8.4432.6239.86711.98

Calculation imethodBalanceCalculateCalculateCalculate

49.655 Calculate0.3S30.0270.029

1.53


4.473 Calculate0.904 Calculate0.0370.024

MrO ' 0.057Fe2O3

Calibrated CoCalibrated NiCalibrated i ZnCalibratedCalibratedCalibrated

RbSrY

Calibrated ZrSample calibrated Ba

9.9240.0070.012


0.007 Calculate0.0040.0110.001



Sample preparationSample MM: pressed powder l

Ana ratio: 1.rAddrtwe/wmpU: 0j Film: None: Normalise: to iQO.0% with as balance H20L X-rav path: Vacuum

•y-

Quanttfy parametersRecipe: c:\superq\data\semigl rep

Spectrometer r*sp. file: c:\supefq\datateemiq1.stiUaa compound Hat; e.\3Upcrq\example\aeQlogy cpl

Apply drttt carr.: NoDiMil. eton, set: 1Oicall. lines sat NoneError weighting; Root

GE; W. t /'VJ l

5/6/02 17 32 University oi TorontoQuantified peaks in c:\superq\ctetaUsnSM20.pks

jAnalyte

Ma! Mq 1 A)

! S1 s

CI K

Ca Ti

1 V i Cr l Mn i ee; Ni ' Cu

Zn Rb

i Sr i Yz-i Kb

Ja

'~

~

~"

Summary of resultsSvnpte: BH99-420 i

MMKured: 5/6/021512QuanWwd: 5/6/02 17:32

Sum: 100 V-, iRMS; C.010



ConcentratkMisType l Calibration T Compound j Concentration \ t

1 status 1 |*A) ;alculation method

Sample Net matched . H2O j '-2 883 j a*,*,,,^ Sample j Calibrated Na20 ' 3.152 Calculate Sample ; Calibrated i MgO j 6 472 j Calculate , Sampte Calibrated i AI2O3 ; 13.958 ' Calculate

! Sample Calibrated SiO2 l 43.234 i Calculate : Sample Calibrated P2O5 l 0,537 j Calculate l j Sample ! Calibrated S03 ' 0.261 i Calculate l : Sample j Calibrated , C; : 0 026 | Calculate j Sample i Calibrated , K20 1.81 Calculate ' Sampie Calibrated ' CaO : 7.481 ; Calculate | i Sample i Calibrated Ti02 '.034! Calculate 1 Sample : Calibrated i V2O5 i 0.037 i Calculate

Sample ' Calibrated i Cr [ 0.008 Calculate i Sampie ' Calibrated i Mno l 0114: Calculate

Sample i Calibrated Fe2O3 S 879 j Calculate i Sampte i Calibrated l Ni '- 0.01 j Calculate

Sample i Calibrated i Cu 0.0', Calculate i Sample i Calibrated i Zn i 0.007 Calculate ' Sample i Calibrated Rb 0,005 Calculate Sample i Calibrated i Si 0.02? l Calculate

, Sampte i Calibrated L Y 0.003 Calculate 1 Sample Calibrated i 'Is : 0.016 Calculate i Sanpie i Calibrated : Nb 0 001 . Calculate - Sarnie i Calibrates Ba 0 037 ! Calculate

S

Addh

~H73s— — — -

Sampie preparationamplatflrje: pressed powderArea ratio: 1

ive/aampic: 0.Film: None

Normalise: to 100 Wo v/itri as bakarce H2X-ray path: Vacuum

Quantify parametersRecipe: c.\auperc[\data\serniq

xtrotratnr reap, fite: cAaupefq'xJata\se-mjgUse compourxl hsfc c:\superq\sxampie^t

Apply drift COTT.. jNlo ___ ,, ——. "Diaall. fttem. set: i ^^

Disall. tines Brt: "None

i

C i

1 rep llist! lsology cpH

^ ____ i

————— j

Page 1

Page/6/02 "' University of Toronto

Quantified peaks in c:\supefq\data\bh100-39.pks

Summary of rasuttsSample:


^~~ Sum:RMS:

Used lines:Tracas:

Qual. program-,

BH 100-392 '5/5/02 15: 30l5/6/02 17:58 j100. "A j0.007 l16,

Rh _ jsemiq

Analyte

Ma Mg Al Si P S Ci K

!Cr

j Mn Fe Co

| Ni l Cu i Zn : Rb

3r Y Zr

: Nb Ba

Type |

Sample i Sample Sample Sample j Sample i Sample Sample i Sample i Sample j

i Sample j i Sample ! l Sample

Sample Sample Sample Sample Sample Sample

l Sample ! Sample

Sample , Sample

Sample Sample Samole

Calibration status i

Not matched i Calibrated i Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated

j Calibrated Calibrated

i Calibrated i Calibrated i Calibrated

Compound ' Concentration Calculation; , (V.) methodH20 i --— - - ~ -

N32O : MgO

AI2O3 S102 i

P2O5 503

CI K20 CaO Ti02

V2O5 Cr

l MnO i Fe2O3

Co

! Z' Zn | Rbi Sr

Y Zr

Mb i 83

14.091 l 3.295

12.171 10.861 41.825 j

0.78! 0.291 0029 3337 3.123 1.762 0.036 0.058 0.102 8.111 0.004 0.026 0011 0.006

l 0.01! 0.011

0003 0.023 0.003

i 0.042

Balance j Calculate ! Calculate l Calculate | Calculate ; Calculate : Calculate j Calculate Calculate ; Calculate j Calculate \ Calculate Calculate Calculate Calculate l Calculate 1 Calculate Calculate ; Calculate

l Calculate i l Calculate

Calculate Calculate

1 Calculate ^ Calcvi ! ate

Sample preparation.Sample type: pressecLBowder

Arearabo:Additive/sample: O

Trim: NoneNormalise: to 100, pjfr with as balance

Vacuum*20

Quantify parameter?Recipe:

fite:c \superq\data\3emiqi rep ~-—t:-J^^-- ~ qi sti

Iha? compound list:conr-i

Dtsafl set: 1

5/S/Q2 ' 7 SG University ol TorontoQuantified peak* in c:\superq\data\bhl01-20.pks

Summary of results! Sample: BH101-200

Measured: 5/6/02 15.48Quantified: 5/5W2 1?:50

Sum: 100. %RMS: 3.006

Used lines: 20; Traces: R h

l Anaiyte l Typei ,

i i Sample Na Sample ;

i Mg i Sample l AI j Sample ! Si ' Sample ! P Sample i S i Sample

C! i Sample 1 K 1 Sample

Ca | Sample ! Ti , Sample , V j Sample j Cr 1 Sample | Mn j Sample 1 Fe ! Sample

Co J Sample NI 1 Sample Cu Sample Zn ! Sample

, Sr Samole 1 Zr Samsie

Qual.progr

ConeCalibration

SfefejS jNot matched l

Calibrated Calibrated ': Calibrated j Calibrated j Calibrated ! Calibrated ' Calibrated Calibrated Calibrated Calibrated

i Calibrated : Calibrated i Calibrated ; Calibrated i Calibrated

Calibrated l Calibrated

Calibrated ! Caiibrsted 1 Calibrated

am: serr.iq

^sntrationsCompound Concentration l

j WHZQl " ~'

Na20 Mg C

AI2O3SiC2 :

P2O5SOS i

Ci K2O ' CaOTiOZi V205 1

CrMnG ;

Fe2C3 : Co i

i Mi : Cu

- Zn Sr 2r

10674 0,225

23 979 3818

4-4..8B4 01 3d 0.035 0.015 0.137 5924

0.27 0025 0.209 0 119 9412 001

O.Q9S 0.007 C.009 0006 0.004

Calculation j riwlliod iBalance

Calculate j Calculate i Calculate Calculate Calculate Calculate Calculate Calculate Calculate

i Calculate ! Calculate

Calculate Calculate Calculate Calculate

j Calcuiate l Calculate i Calculate 1 Calculate

Calculate

Sample preparationSample typ*: pressed oowder i

lAdd*

i

Area ratio: ' — _ jlive/sample: 0. l

Film: None iNormalise: to 1 DO.0% v/itti as balarce H2OX-my oatti: '

Quart

Vacuum

thy parameters

- ..J

i Recipe: c-\sut5erci\dataAsemiq1.rcp

UsecompounAuolvdnfi

id list: c:Vsugergê corr.: No

jcamcleV} eology.cpl '

Di&ali. etem. set: 1j Disall. lines set: Nonei Error werahtmq: Root i

Max. Sealed cfetoctor intensity: 2000 kcosM.aa. Ftew detector intensrtv: tOCO Kcps ;

Appendix IX

XRF Analysis

Samples MJ- 19A (2 samples) May 8, 2002


DEPARTMENT OF GEOLOGY22 Russell Street. Earth Sciences Centre


Fax: (416)978-3938 Tel: (416)978-3022

Date: 8 May 2002



TO: JeremyBrett

FROM: Mike Gorton

When MJ-19A is analysed as a pressed powder pellet, the total is

91 .5 0Xo. Using this result, but allowing the computer to calculate the

H20 by difference (not reliable) gives 12.3 Vo H2O (analysis #1).

Experience suggests this is an overestimate of H2O and thus all the

elements are correspondingly slightly too low An alternative calculation can be performed by manually adding

H2O to the analysis (and recalculating) until it totals 1000X0 . This

required 5 507o H2O (analysis #2). Ideally this should have given the

same result as # l .When fired in air (3), ~- 1000 C, the loss on ignition was 7.20Xo.

Note that weight gain as a result of oxidation of FeO will have

reduced the loss slightly, and thus actual H2O (+CO2) should be a

little higher (- 807o).Thus it would appear that a true analysis would be closer to the

average of #1 and #2.

5/8/C2 1836 University of Toronto

Quantified peaks in c:\superqVdata\mj19a^^.pks

Summary of resultsSampto: MJ19A j

Measured: 5/8/02i Quantified: 5/8/02

11 07 i18:35 |

i Sum: 100. "A 'I RMS: 0008

Us*d lines: 23 l; Trac*s: P S Rh Cs ![ Qual. program: aemia l

ConcentrationsjAnalyte

Nai Mg' Ali Si! P

CIi K

Cai Se

TiVCrMnFe

i Coi Nl

Cul Zn1 Rbi Sf1 Y

ZrNb

Type

SampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSamoieSampleSampleSampleSampleSampleSampleSampleSampleSample

Calibrationstatus

Not matchedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibrated

DerivedCalibratedCalibratedCalibratedCalibrated

, CalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibrated

Compound l Concentration Calculation

H2ONa2OMgO

AI2O3SiO2

P2O5CI

K2OCaO

SeTiO2

V205Cr

MnOFe203

CoMi

CuZnRbSrYZr

Nb

PA) method13.521

0.211209

BaianceCalculateCalculate


0.207 Calculate ,0.045 Calculate3.863 i Calculate0.7910.0071.551O.Q39o.ooa0.056

10.3050.005

CalculateCalculateCalculateCalculate 'CalculateCalculateCalculateCalculate

0.016 Calculate0.0060.008

0.010.002


0.003 Calculate0.014 i Calculate0.001 . Calculate


Ar*a ratio: 1AddKivefeanwfe: 0

i Film: Nonet Normalise: to 1 00. We with as balance H2O

X-ray path: Vacuum

Quantjfy parameters

r" Ui ——

Recipe:Spectroowter rasp, fite:

Us* compound Hit:Apply drift eorr.:OKall. clem. s*t:

c:\supera\data\semiql.rcp ;c:\superq\data\6emiQ 1 stt jc:\superq\example\aeology.cp! iNo1

Dlsall. lines set: None

VAY 3. 20"

5'8rt)2 1938 University of Toronto

Quantified peaks in c:\superqVdata\rnj13a_

Summary of results

.,pks

SamoH: MJ19AMeasured: 5/8/02 11 07Quantified: 5/6/0218:37

Sum: 94.5 9A lRMS: 0.000lines: 23

l Traces: F S Rh Ga Qual. program: semiq ^

Page 1

ConcentrationsAnalyte Type

BinderNaMgAlSI

Sample

Calibration status

Not matchedCalibrated


P Sample Calibrated: CI Samote Calibrated

KGa

SampleSample

Se ; SampleTiVCT

SampleSample


DerivedCalibratedCalibrated

SarnDie CalibratedMn Sample CalibratedFe Sample CalibratedCo Sample CalibratedN' i SampleCu Sample


Zn i Sample Calibratedi Rh

SrY

i Zr

Sample CalibratedSample CalibratedSample i CalibratedSample ! Calibrated

Nb i Sample : Calibrated

Compound

H20Na20

MgOAI2O3Si02P205

CIK2OCaO

SGTi02

V205Gr

MnOFe2O3

CoNi

i CuZn

i Rb5rYZr

Mb

Concentration ! Calculation {%) method

5.50.212

11.94516.40146.811

0.230.05

4.309

Fixed !Calculate 'CalculateCalculateCalculateCalculateCalculateCalculate

0,388 Calculate0.007 i Calculate i1.7450.044

CalculateCalculate

0.009 Calculate0,064 Calculate

11 711 Calculate0.006 Calculate0.018 Calculate

i 0.006 Calculatej 0.01 Calculate

0.011 ' Calculate0.002 CalculateO.C04 Calculate0,016 CalculateO.OQ2 Calculate

Sample preparationSample type; Powder (pinder: H201;Initial weight:Final might:

Area ratio:AcMftive/sampJe:

Film:' Normalise:

X-ray path:

1.00 g1.05 g1.080,06None !no iVacuum i

Quantify parametersRecipe: c:\superg\datateemiq1.rcp

Spectrometer resp. flte; e:\superq\data\8emiq1 .sti,Usa compound list o:\supgrq\exampleêology.cpi

____Apply drift cofT,; NO______________

Appendix X

XRF Analysis

Samples MJ - 9,12,13,14,15 A 16

May 9, 2002

VAX 9. ;i'U 5 ci 2 : V ^ OF T G[CLOG V \G. i-3-C




Fax: (416)978-3938 Tel: (416)978-3022

Date: 9 May 2002

Fax Number: 416 504 7760 No. Pages; 7

Please cai! (416)978-3022 if you do not receive all the pages

TO: JeremyBrett

FROM: Mike Gorton

MJ-9 Odd composition because of the low CaO - sediment? Zr/Y of 11 is high enough to be interesting.

MJ-12 Hi Fe and low Ni,Cr, Zr. Looks like a Fe-rich cumulate.

MM3 Hi Fe, low Ni, Zr. Low Si02 due to amphibole. Fe cumulate

MJ-14 Reasonably normal mafic rock. K2O due to mica, Zr/Y ^8

MJ-15 Same as MJ-14, but lacking mica and K2O.

MJ-i6 High Fe, low SiO2 mafic cumulate again (c.f. MJ-12 and 13).

r. v ?. n; !: L


Quantified peaks in c:\superq\data\mj-9_

Summary of results

Page "

Sample: MJ-9Measured: 5/9/02

Quantified: 5/9/02Sum: 97 KRMS: 0.001

Used lines; 24

15:0016:07 sr \^ P

Traces: Rh \Qual. program: aemiq x

ConcentrationsAnalyta

NaMgAJSIPSCIK

CaTiVCrMnFeCoNiZnGaRbSrYZrMbBa

Type Calibration

SampleSample

statusCalibratedCalibrated

Sample i CalibratedSample CalibratedSample ' CalibratedSample CalibratedSample CalibratedSample CalibratedSample CalibratedSampleSampleSampleSampleSampleSampleSampleSampleSample


Sample CalibratedSample j CalibratedSampleSampleSampleSample


Compound Concentration Calculation

Na20Mgd

AI203!Si02P2O5:

SCI

K20,CaOTi02

V2O5Cr

MnOFe203

CoNiZnGaRbSrYZr

NbBa

(Y.)2.6238.872

14.24553213

0.1760.0140.0321.8521.3221.2640.03

0028

nwtiiuU ^CalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculate

0.154 Calculate13.024 i Calculate0.00800130.00900020.00400230.0020.0230.001


0 023 : Calculate

Sample preparationSample type: pressed powder j

Are* ratio: 103Addttvefeampto: 0. j

Film: None ^Normalise: no .X-ray path: Vacuum i

Quantify parameters^—^,^^^ c:\superq\data\semiql .rep

OpCOU^jiTU&Bf Ute: c:\superq\data\semiq1,3tiUs* compound list: c:\superq\exampte\geotogy.cp[

Apply drift com NoDisall. etom. set: 1Dteail. I'mes set: None

MA*. 9.20J2


Quanttffed peaks in c:\superq\data\mj-12_.pks

Summary of results

Page 1

Sample: MJ-12Measured; 5/9/0215:23;Quantified: 5/9/02 17:25

Sum: 97.5^RM8: 0,000


jQual. program: semiq

ConcentrationsAnaiyte

Ma

Type Calibration statut

Sample \ CalibratedMg Sample CalibratedAl SampleSi SampleP SampleSCIK

CaTiV

SampleSamoleSampleSampleSampleSample

Cr : SampleMn SampleFeCoNiCuZn

sampleSampleSample

CalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibrated

Sample i CalibratedSample i Calibrated

Rb Sample CalibratedSr Sample CalibratedY Sample Calibrated2s | Sampte CalibratedNbBa

Sampte CalibratedSample Calibrated

' Compound

Na2OMgO

AI2O3SiO2P205

SCI

K2CCaO

' Ti02V2O5

CrMr.O

\ Pe203Co

; NICaZn

i Rb1 Sr

Y! ir' Nb1 B9.

Concentration CX.)

D.2193.1393.613

45.2591.001

Calculation method


0.232 Calculate0.076 Calculate1.972

10,741CalculateCalculate

2.062 i Calculateo.cea0.016

0.1418015

0.010.009


0.011 i CalculateG 014 CalculateO.OQ5 CalculateO.OC6 Calculate0.002 CalculateC.OQ5 Calculate0.0020024

CalculateCalculate

Sampte preparation Samp** type: pressed powder

Area ratio: 02Addrtivo/sampie: O.

Film: NoneNormalise-: noX-ray path: Vacuum ^

Quantify parameters-——-—^-—.Recipe: c:\superq\data\semiqrrcp

Spectrometerresp.file; c:\superq\dataVMmigl.stiUse compound list c:\superq\exampJc\geoloqycpl

eorr.: rDisall. etatn,Disatl. lines set:

1 'None

A 1'. 12002 r.

5/9/02 17 27University of Toronto

Quantified peaks in c:\superq\data\mj-13-—,pha

Summary of restiteSampte: MJ-13

Measured: 5/9/0? 15 40Quanttftodi 5/9/0217:26

___Sum; 96 1 %RMS: 0.000

Used lings; 22 Traces: Cr fth

semiq

. *t34 :J

Pagel


NaMgAlSiPs

Type

SampleSampleSampleSampleSampleSample

CI l SampleK

GaTiVMnFeCoNiCUZnRb

' SrY

\ Zr

SampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSample

Calibration statue


Compound

Na20MgO

Calibrated ! AI2O3Calibrated ' SiO2Calibrated P2O5Calibrated , SCalibrated CICalibrated K2Ocalibrated CaOCalibrated TiO2

ConccfltiDUufi

2.3416.992

1464942.034

0.6860.0410.10606629,6862.211

Calculation

CalculateCalculateCalculateCalculateCalculateCalculate 'CalculateCalculateCalculateCalculate

Calibrated V2O5 0.064 1 CalculateCalibrated MnO ! 0.24Calibrated Fe2O3CalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibrated

Sample CalibratedNb Sample Calibrated

CoNi

1 B.2720.0090.007

Cu 0.005ZnRbSrYZrNb

0.0120.0020.0350.0040.0070.002

CalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculate

Sample preparation Samptetype: pressedl powder!

Area ratio; 1.02Addithre/sarapte; 0.

FHm: NoneNormalise: noX-ray path: Vacuum

Quantify parametersRecipe: c:\superq\datateemlq1.rep.

_ Spectrometer reap. He; c:\3upefq\data\semtql.sti ^_____Use compound list: c:\superq\exampleV9eology cpl

Apply drift carr.: NoOltall. efcm set- 1Disall. lines set: NoneError weighting: Root

Max. Sealed detector intensity; 20QQ Kcpo

9.2002

5W02 17:28University of Toronto

Quantified peaks in c:\suparq\data\rnj-14_

Summary of results

..pks

Sample:Measured:Quantified:

Sum:RMS:

Used lines:Traces:

Qua), program:

MJ-14 j5/9/0215:58 i5/9/02 17:27 '95.4 "A0.001 :21 iRh isemiQ ;

Pagel

ConcentrationsAnaryte

NaMgA!SiPSC!K

CaTiMnFeNiCuZnGaRbsrYZrNb

Type

SampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSample

Calibration status

CalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibrated

Compound

Na20MgO

AI2O3SiO2

P2O5S

CIK2OCaOTio2MnO

Fe2O3NI

CuZnGaRbSrv

ZrNb

Concentration (W

25276.89214.04

47.6480.6240.0150.0981.8967.5071.9760.108

11.96500120.0060.0120.0030.0050.0320.0030.0240002

Calculation method

CalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculate

-v-

Sample preparation Samptotyp*: pressed

Area ratio: 1.05 Addrtjve/tampte: Q. ____ Film: None

Normalise: no"X-ray path: Vacuum

Quantify parametersRtcips: c:\3uperq\riata\3efnlq1.rcp

Spectrometer resp. file: c:\superq\dataV6emiq1 stlUse compound list:

____Apply drift corr.: NoDisall. etem. s*t 1Dtsall. lines set None

i: Root___ 2000 kcpTi Max. Sealed detector intensity

Max. Flow detector intangity 1000 kcps ZJ


Quantified peaks in c:\supercj\data\mj-15——,pks

Summary of restiteSample: MJ-15

Measured: 5/9/0216:16Quantified: 5/9/0217:30

Sum: 949**.KMS: O.ODQ

Usod Ikies: 19^————Trans: RhW

Qual. program: semtq

ConcentrationsAnalytej Typ*

————————— —————————NaMgAlSipsCIK

GaTiMnFcMlZnRbSr

SampleSampleSample

Calibration status


Sample CalibratedSample CalibratedSample j CalibratedSample CalibratedSampleSampleSampleSampleSampleSampleSample


Compound

Na2OMgO

AI203SiO2P2O5

SCI

K20CaOTi02MnO

Calibrated j Fe2O3CalibratedCalibrated

Sample i CalibratedSample j Calibrated

Y j Sample CalibratedZr SampleNJb ' Sample

Calibrated

NiZnRbSrY

ZrCalibrated Mb

Concentration Calculation W) method

2.9846.535

13.87248693

0550.02100510.911

CalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculate

6. 482 t Calculate1 .668 Calculate0.133 ' Calculate

12.696 Calculate001 Calculate

00110.0030036000300250.002


— to-

Sampte preparationOmiipte type: pressed powder

Area ratio; 1.05Additivc/sanuite: 0.

Film: NoneNormîse: noX-ray path; Vacuum

Quanttfy parameters-—————Recipe: c:\auperq\data\semiq1.rqp

____Spectrometer re*p. tlte; c.\superq\dataVsemiqt .sti______Use compound list: c;\superq\exampleVaeology,cpl_______ Apply drift corr.: No____________________'bHatl.cOm.Mtt: -\______________________DisalL Hnes set: None-——-————-——-.——

Srror wcightinq; Root ~~--—-—-.Max. Seated detector intensity: 2000 Kcps__________

Max. Flow detector intensity; 10OP kcpsMax. Scint detector intansity: 10OP Reps

IZlMax. Duptex detector intensity 3000 kcps

VAV 9. 20J


Quantified peaks In c:\supcrci\data\mH6. ,,Pte

Summary of resets' Sampte:


Sum:RW8:

Us*d lines:Traces:

l Qua), program:

MJ-165/9/02 16:395/9/02 17:2996.2 "M, l0,000 i19 1Rhsemto

Page 1


Na , SampleMg i SampteAl -: SampleSi SamplepSCIK

Ca

SampleSampleSample

Calibration Compound status i

Calibrated j Na2OCalibrated j MgOCalibrated l AI2O3Calibrated SiO2

Concdttiiition (W

1.8076.962

14.159

CalculationIIMitllOd

CalculateCalculate !Calculate

40699 Calculate

Calibrated ' P205 1 355 CalculateCalibrated ' s o 093Calibrated j ci 0.156

Sample Calibrated K2O 0406Sample t Calibrated CaO

Ti SampleMnreNiCu

SampleSampleSampleSample

Calibrated ! Ti02106322.433

Calibrated MnO ! 0.211Calibrated Fe2O3 18.191Calibrated ; N,Calibrated : Co

O.OO50005


Zn Sample Calibrated Zn 0.008 Calculate

Sr SampleY SampleZr Sample

Calibrated Sr ! 0.036 CalculateCalibrated Y 0.003 CalculateCalibrated : Zr 0.003

Mb i Sample i Calibrated 1 Mb 0.002CalculateCalculate


Arsa ratio: 104 ___iAddKtv^sample: Q. ——

FHnrc None,____ Normalise: no

X-ray___

Vacuum

Quantify parameters___________Rectps: c \supgrg\data\semiq1 .rep :

Spectrometer resp. file: c:\soperq\data\8emiql.sti j____Use compound ifet: c:'supefq\example'aeolQgy.q?l j

Apply drift corf.: NoDtsall. eJem. set 1

lines set: NoneError weighting: Root

Ma*. Seated detector intensity. 2000 KcpsMax. Flow detector intanatty: 1 0OP HopsMaa. Scint detector mtensrty. 1000 kcpa

Ouptex detector tntenaity. 3000 kcpg

Appendix XI

XRF Analysis

Samples MM 239, MJ 21, 28 St 29

May 29, 2002

-.29.2002 5;32PM OF i GEOLOGY . 3MB

5/29/02 1 '24 University Of TorontoQuantified peaks in c:\supenJ\data\iTwn-239__.pkii

Summary of resultsI+ WUWIlgfc iw. * —

b S09JD217:221Sum; 100. 'ftRM8: 0.003

Traces: Ga RF Qual. program; semlq

Aflaryte

NaUsiwgAlSi PsCtK

Ca Ti CrMn Fe Ni CuZn Rb Sr

1 YZr Ba

t*a

Sample SampleSampleSampleSample SampleSample SampleSampleSample Sample SampleSample Sample Sample SampleSample Sampte Sample SampleSample Sample

CafibraHonstatus

Not matched CalibratedCalibratedCalibratedCalibrated CalibratedCalibrated CalibratedCalibratedCalibrated Calibrated CalibratedCalibrated Calibrated Calibrated CalibratedCalibrated Calibrated Calibrated CalibratedCalibratedf***JUk*MftA4ftcajijpnNeQ

Compound

H2C Na20MgO

AQ03Si02 P20S

SO3 CI

K2OCaO TIO2

CrMnO

Fe203 Ni

CUZn RbSr Y

Zr BaO

ConcenMbotiW1 c

vS^^jitt745

V/41.S24 0.2052.001 0,016

fi.izT^^

-0.8T2-0.054

0.042 ^-.9.444 J 0.024 w 0.003

.., 0.005(jxoro; ^•''ÔB5"

0.001:o.oi63.887

Cakutetton' — * rnwiaaBalance CalculateCalcutateCalculateCalculate CalculateCalculate CalculateCalculateCalculate Calculate CalculateCalculate Calculate Calculate CalculateCalculate Calculate Calculate Calculate

) Calculate "Calculate

Sampte preparationSample type: pressed powdef

None,-———.—^——— to 100.0** vrith as balance H2O

Jjrtavna*h: Vacuum

QuanBfv parametersc:\9upem\dataVaemiql.rcp

reap, fito c:\superUse confound fate

-- No

•HialUnessgt; None: i: Root

2000 tops

2*. 20C2

5^29/02 IV 10 University of TorontoQuantified peaks in c:\superq\data\mj-29

Summary of results,—•SampieTMJ-Zi.

S/29/02 15:54Q55^rtr^952JI^9

Sum: 100,."RMS: 0-000

Used lines: 24Traces: RbRJL

aemiq

NO.

Analyte Type Calibration compouno w.i status .1 _____ L.

— Si —— sample \ Cal.brated ; Na2CMg jAl W

! si

Sample i SampleSample

p l Samplec

! cs,SampleSample

j K l SampleCa

i Se: Ti1 Vi Crj Mn

Fe ,

Sample

Calibrated | CalibratedCalibratedCalibrated

Mgu AK2O3

SiO2P205 i

_ ^ . j± l

Calibrated sw |CalibratedCalibratedCalibrated

Sample i DerivedSample | CalibratedSampleSample

i Sample! Sample

j Ni i SampleCu Sample

! Zn: Ga1 ft ci MB i Sri Y .

SampleSampleSample


01K20Caol

-, 1SeT102

VCr

Calibrated wnu 'CalibratedCalibratedCalibratedCalibratedCalibratedCalibrated

j Sample , Calibratedi Sample

i Zr : Sample, Nft 1 Sample

j CalibratedCalibraledCalibrated

Fe2O3Ni

CuZnGa

1 AS

i Sr1 YZr1 Nb

5.3985,86

•i 5. 937

Calculate lCalculateCalculate

53.51 1 Calculate j0.1730.061

CalculateCalculate j

O.OB4| Calculate0.33304290.0032.5470.053


0.016 ! Calculate0.14' Calculate

14.3690.01200080.0120.002


0.003 j Calculate0.00500070.018

l CalculateCalculateCalculate

0 002 Calculate

Recipe: c:\superq\data\aemiq1 .reg**~i'-- -s^-- -___,__

c:Vsuparq\example\aeQlopv.cpl

W 29.2002 r.

5/29/0217:06

i OF * GEC.CGY

University of TorontoQuantlfted peaks in c:\superq\data\fnj.28_

of results.SumrnaiyorresuK*mssc^CSS

't 'J, J v L \

Page

Type

I—Ra Ma

l AlMgAlSiPSCIK

CaTiVCrMnFeCo NiZnMRbSrY2fMbei

SampleSample Sample Sample Sample Sampl* Sample Sample Sample

( Sample l Sample i Sample l Sample

Sample Sample Sample Sample Sample

, Sample l Sample | Sample

Sample Sampje

jaimratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedcalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibrated 'Calibrated j

NiZnAsRbSrYZr

Nb

0.8.154 B.995

30813 0.214 0.059 0.028 1309

- 29.983 3.307 0,022 0.033 l 0.137 i

.- 11.59&! O 01 S' 1 0.023

0.61 0,018 0.004 0.009 0.012 0.023 0.006 0,017

alculate Calculate Calculate Calculate calculate Calculate ' Calculate l Calculate l Calculate ; Calculate ^ Calculate j Calculate j Calculate : Calculate Calculate l Calculate Calculate j Calculate , Calculate Calculate Calculate Calculate

i Calculate Calculate

e typ*^ pressed powder

imeters

ya.'. 29.2302 5;32 3 V

5/29/02 17:00

"f T r,f v j r ' ut

Umverelty of TorontoQuantified peaks in c:\5up8rtJWata\mj-21.

Measured: 5/29/02 15:0Quantified; 5^9/0217:00'

"Ahaiywl

Na l Mg Al

i 5i' ;CIK

i Ca Ti V Cr

i Mn i Fe l CO' Ni, Z" l Rb1 Sr

Y

1 **.IW

Type

Sample Sample Sample : Sample Sample Sample Sample ! Sample Sample Sample Sample Sample Sample

i Sample SampleSample Sample Sample Sample Sample Sample

Concentrations Calibration 1 Compound" i

statusCalibrated Calibrated CalibratedCalibrated Calibrated Calibrated Calibrated j Calibrated 1 Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated CalibratedCalibrated Calibrated Calibrated Calibrated

: Calibrated i Calibrated i Calibrated

N320 MgO

W203 SiO2

P2O5 SOS

CI K2O CaO Ti02

V Cr

MnO Fe203

Co NiZn Rb Sr Y

Zr Nt

Soncentratlon (^)

—— 2-136 9.602

11.527 50.127

0.269 i 0.054 0.056 1.1431 e.497 1.71* 0.029 0036 016

12.822 0.011 0.0180.012 0.004

l 0.019 0003 0,014 0,002

Calculation method i

Calculate Calculate | Calculate Calculate j Calculate j Calculate Calculate Calculate i Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate )Calculate j

j Calculate j Calculate ' l calculate j 1 Calculate

J^ Calculate

Page

j __ Film: None r~~; Monnali**: "Q

X-ray BamL

rameters

Max. Seated detector mtens

Appendix XII

XRF Analysis

Sample 269F May 31, 2002

,c -i i i 'V'1 "' i S: 5 l. i-l U i J

5/31/02 17.43 University of Toronto Quantified peaks in c:\s^wrqfrdbia\i

Sianmaiy of remits

hr

Sample:Measured:

Quantified:Sum;RM8:

UstdHms:T- - - --

races.

QuaLproqraoc

MM269F5/31/D2 15:525^1/02 17:43100.6 H,0.00019Rhsemiq

Page 1

ConcentrationsAnaJyte

MaMgA)

. SiPSCIKCaTi

; vi Cf

MnFeNiZnSf

Type

SampleSampteSampleSampleSampleSampteSampleSampleSampleSampleSampteSampleSampleSampleSamptaSampleSample

Y SampleZr i Sampie

CaHiration •tatut

CalibratedCalibratedCalibratedCalibratedCalibratedCaHbratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCautxatodCalibratedCalibratedCalibratedCaHbratedCalibratedCalibrated

Compound

Na2OMgo

AC03SMD2

P206S03

CIK2OCaOTV02

VCr

MnoFe2O3

MiZnSry

Zr

. W1.271

17.9495.S59

16.79200420.0450.3280.409

10.7510.55

0.0330,0180.237

16.5770.0220.011

0.010.0020.003

Calculation:MBÂMk^ \nmnooCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculate

Sampte preparationSampte type: pressed powder

AIM ratio; 0.99"AtMJtive/Mfnpte: oT

Film: NoneNommtiM: noX-ray path: Vacuum

Quantify parameters^^jpgfl^data\8emiq1.fcp

3*ctt r c:\9upejxfldatateemiq1.stiU*ecCTmpeundtiM; o:\supetgVexample'Qeotogy.cpl

jUBLnow detector Hmnrthr; 1000 kcps JNtex.Sciftt detector mtemitv. lOOOkcps

JgaxJjijENt dûtor inldroity: 3000 kcps

Appendix XIII XRF Analysis

SamplesDrill Holes 104® 177 feet

105® 112 feet June 6, 2002




Fax: (416)978-3938 Tel: (416)978-3022

Date: 6 June 2002


Please call (416)978-3022 if you do not receive ali the pages

TO: JeremyBrett

FROM Mike Gorton

BH104-177 Totals 94"7o, recalculated with H2O by difference.Porphyritic, with relatively high Ni and Co, looks like a

heaviiv chlontized mafic lava - but absence of Cr is hard to explain.

BHI05-! 12 Totals 95*o, recalculated with H2O by difference Analysis of biotite-free zone. Again looks like chlontized mafic, but with high Cr. Also very high P2O5 and high Zr

3/6/0215-05Page


Quantified peaks in c:\superq\dataAbh104_17.pks

Summary of resultsSample: 94104=177

Maasured: 6/6/0210:51Quantified: 6/6/0215.05.

Sum: 100. 0A jRMS; 0.012

UswJ lines; 20i Traces: Rfi

QualjprogFanr semiq

ConcentrationsAnalyto

1i Ma

MgA!

S Si1 P

SCI

i K| Cai Tli vi Mn

Fe1 Co

NiZrGa

: SrYZr

Type

SampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSamoieSampleSampleSampleSampleSampleSample

Calibrationstatus

Not matchedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibrated

i CalibratedCalibratedCalibrated

Comoound Concentrationi C

H20!Na20 ,MaO i

AI203 iSiO2

P2O5S03!

CMK2OCaOTI02 i

yMao i

Fe203CoNi '

Zn :GaSrY lZr

"0,3270.07323.46

15.31323.977

0.37500530.0290.0271.735Q.2b20.029O.Q68

186010,0120.0380.0170.0030.0020.0010,007

Calculationmethod iBalance ;

Calculate 'Calculate :Calculate jCalculate 'CalculateCalculateCalculateCalculateCalculate 'Calculate |Calculate 'CalculateCalculate jCalculate

, Calculate iCalculateCalculateCalculateCalculate iCalculate !

Sample jMreparation ——Samote tvne: pressed powdei

Area ratio: 1Additive/sample: G

Fikn: NoreNonrolls*: to 100 O'/e with as balance H2Q ,

X-ravpath: Vacuum j

Quantify parameters——-——-——Recipe: c \3iiperq\gata\semiql.rep

L.-

trometer re*P- file: Use compound list:

App*y drift con.: No

"OisaCtine-Tswt: None

e:\superqV33taJgernj_ql.sti ; c:\syperq\exarnp'e\flColoaY.cp! i

Max. Seated detector intensity. Max. Row detector Intsmitv:

Error weqtrting: Root20CO

erS/02 15 O" University of TorontoQuantified peaks in c:\superqVdata\bh105-11.pks

Summary of restite——— Sampfe: BH10M12

"RMS: 0.013"Used

Traces: Na Rh: Qual. program:

Page

Conci Analyse Type j Calibration (

i \ statusSample j Mot matched

Mg ! Sample i Calibrated 1, Al . Sample i Calibrated 1 Si Sample l Calibrated i : p Sample j Calibrated i

S Sample ; Calibrated1 CI Sample ' Calibrated ,

K Sample Calibrated i C a i Sample j Calibrated ! 7i ; Sample l Calibrated

V Sample Calibrated; Gr i Sample i Calibrated

Mn i Sample ! Calibrated j Fe ! Sample i Calibrated

Co Sample CalibratedN; Sample ' Calibrated

1 Zn i Sample j Calibrated ; Ga i Sample | Calibrated

3b Sample i Calibrated i Sr ! Sample | Calibrated

Y | Sample Calibrated Zr ! Sajnnpjej^ Calibrate

jntrationsimpound Concentration Calculation

j (^ HK^llOIJ

H20! MÎO 1

A1203 ! SiO2|

P2O5 S03

CIK2OCaO TiO2

vC -

)

MnO Fe203

i COi Mi ! Zn j Oa ! Rb l Sr

Y Z)

7.992 Balance j 23.614 j Calculate 16.102 ; Calculate 27.956! Calculate j

2.268 i Calculate ! 0.037 | Calculate 0059 Calculate j0.175 j Calculate i 1668 Calculate ; 0.664 Calculate 0 024 ' Calculate0.054 ; Calculate0.077 i Calculate

19.198 ! Calculate 0.011 i Calculate0.045 j Calculate

j 0.01S i Calculate i 0 004 , Calculate ! 0.002 ! Calculate j 0.003 i Calcuiate ! 0.003 ' Calculate ; 0.028 t Calculate

Sample tgKLratio*-

0.Film: None

Normalise: O'/c with as balance H2O,

Quantify paramaters ----——.^--^—^Recipe: c'.\supcfqvdata\samiq1.fcp ^

raprfife: ciNsuoerg'jatateSfTvgc:\superq\example\g9ologY cpl

Max. Seated cfetertorwtw*

Appendix XIVXRF Analysis

Samples MJ 24 A 24 PDRJune 27, 2002

JUN. 28. 20C2

6/2B/02 11:36 University of Toronto Quantified peaks in c:Asuperq\da*aUnj24.

Summary of resutt*Sarate Mj24.____

6/27/0216:35.Quantified; 6(28/0211:35

Sum: 100. Tunis; O.OQ3

Used rims: 22.Traces: Rry

semtq

Pagel

NaMgAlSiP SCI KGaTiVCrMnFeMiCuZnRbsrY ZrMb

Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample

i Sample Sample Sample1 ——i r

CalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedcalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCafibratedCalibratedCalibratedCalibrated

HNa2OMgO

A1203SiO2P205i

SCI

K20CaOTiO2

VCr

MnO Fe2O3

Mi Cu Zn Rb Sr Y Zr

Mb

10.665 0.32

a.986 10.081 57.536

0.082 0.026 0.042 2.469 0.413

0.85 0.022 0.023 0.087! 8.328 0.013 0.009 0.009 0.005 0.002 0.002 0.009 0.001

tance Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate

Qua""•J F———— ——————— .—.————————————

Recipe; c:\superci\data\semiq1, rep

jN. 28. 2002 IV.SUW Of T GEOLOGY

6/28/021140 University of Toronto Quantified peaks In c:\supen^ta\mi24pdrv.pkd

Summary of rasutte

Page 1

Sample:Measured:

i Quantified:Sum:RMS:

Used tines:Trace*:

QuaL praqranK

MJ24PDR6/27/02 16:636/28/02 11:40100. *0.01426Rhsemiq

Analyte

MaMgA)SiPSCIKCaSeTiVCrMnF*CoNtCuZnRtSrYZrMbWPb

Typ*SampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSample

statusNot matchedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibrated

DerivedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibrated

. CalibratedCalibratedC ,.l;fc , MJa ii atcicatea

CalibratedCalibratedCalibratedCalibratedCalibratedCalibrated

Compound

H20Na2OMgO

AC03SIO2P205

Sa

K20CaO

SeTiO2

VCr

MnOFe2O3

CoNi

CuZnRbSrYZrNbWPb

Concentration

10.0080.082

13.68212.87948.162

0.1460.22

0.0520.8480.5160.0050.906

0.030.0430.119

12.1970.0090.0230.0090.0170.0030.0010.0030.0110.0010.024o.oor

Calculation,— 1,^4. i, atIIWUtOQBalanceCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCsricutate !CalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculate

Smote tree:Area ratio:

MdittM/caraple:Rim:

A^tM^BÂ^*^*IWU1MM9V*

1 X-ray path:

pressed powder1.0.Noneto 100 046 with as balance H2OVacuum

Quantify parameters

Ute compound list c:\superqXexampleôeokxT^.cp)

Appendix XVXRF Analysis

Samples MJ 39,41,38Drill Hole 113 (a)16 feet

I'l-i

1701 University of Toronto Quantified peaks in c:\superq\data\rnj-39,

Summary of resultsSampte: J/IJ-39

Measured: 9/11/0215:24Quantified: 9/11/02 17 01

Sum; m'%RNIS: 0000-——-

Used lines: 21Traces: Rh Cs

Qual. pfoqram: semiq

Page l

ConcentrationsAnalytei Type

NaMgAlSi

Sample

Caibratun status

CalibratedSample | CalibratedSample CalibratedSample Calibrated

P Sample CalibratedSCIK.

GaTiCrMn

SampleSample


Sample Calibrated

Compound

Na2OMgo

AI2O3SI02

P205SO3

CIK2O

Sample Calibrated CaOSample i CalibratedSample Calibrated

Ti02Cr

Sample Calibrated MnOFe SampleCoNi

SampleSample

Calibrated Fe2O3Calibrated CoCalibrated ! Ni

' Cu l Sample ! Calibrated j CuZnSrYZr

i Pb

Sampte CalibratedSample CalibratedSample; CalibratedSample Calibrated

ZnSrYZr

Sample Calibrated Pb

Concentratkm Calculation ] (•A) method i

0 626 Calculate j25.211 Calculate

9.549 Calculate44179 Calculate


0.133 Calculate0094 Calculate6.901 Calculate

0.52 i Calculate0.177 Calculate0.14512.050.0150.0850.006o.ooa0.0070.0020.0030.005

CalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculate


Area ratio: 1.03 Additive/sample; O

Film: Nonei Nomadia*: to1QQQ gAl X-ray path; Vacuum

Quantify parameters| Recipe:; Spectrometer nep. flte:i Use compound list:i Apply drift corr:' Dtsall. elem. set:

Otsall. lines Mt:Error weighting;

; Max, Seated detector intensity:1 Max. Flow detector BTtan&ity:

c:\superq\data\semiq1 . repc:\8yperq\data\aemig1 stic:Ssugerg\exainple\geology, cplNo1 'NoneRoot2000 kcps1000 kcpa

9m/02 1702 University of Toronto

Quantified peaks in c:\superq\data\mj-41—-.pks

Summary of results T 'Sample: MJ-41 "l

Measured; 9/11/02 15:43 ;Quantified; 9/11/0217:01 j

;______Sum: 100, '/e ! RM8: 0.000

UsedUne*; 20Traces: Rh

Qua, program; semiq

Page


NaMgAlSiP

Type

SampleSampleSampleSampleSample

S SampleCI SampleK

CaTi

SampleSampleSample

Cr ' SampleMnFeCoNi

Calibration status

Calibrated

Compound Concwnimtion l*)

Na20Calibrated ; MgOCalibrated AI2O3CalibratedCalibratedCalibratedCalibratedCalibratedCalibrated

SI02P206503

CIK2OCaO

Calibrated i TiO2Calibrated Cr

Sample CalibratedSample : CalibratedSample CalibratedSample

Cu i SampleZnSrY

SampleSampleSample

Zr Sample

CalibratedCalibratedCalibratedCalibratedCalibratedCalibrated

MnO

Calculation medtud

0.238 : Calculate30.201

8.23244.520.0630.1370.104

0.045.88

04960.1970.113

Fe2O3 9.618Co , 0.008Ni

CuZnSrYZf

0.10900070.0080.0050.0010.004

CalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculate

Sampte preparationSample type: pressed powder l

Area ratio; 1.03 'AddrtiveVMmple: 0.

FMm: NoneNormalise: to IOQ.0%

Jt-ray path; Vacuum

Quanttfy parametefsRecipe: c:\supefqV3ata\semici1.rcp

Spectrometer ra*p. fit*: c:\5up6rq\datateemiq 1 stiUse oompound list: c:\8iiperq\gxampieêology, cpl

____Apply drift corr.: No__________________Oisall. eton. s*t; 1_______________

set NoneError weighting: Root

Max Seated detector intercity. 2000 kcpsMax, now detector Intensity: 1000 tops Max. Sciru dntector crtensity: 10OP kcps"

9/11/02 16 42 University of Toronto Quantified peaks in c:\*upen4\dataVmj-38,

Summary of result*Semple:

Meatund:Quanti

SM:urn:

RMS:Used Imw:

Traces:QuaJ. program:

MJ-389/11/029/1 V02106 ^0.00019Rhsemiq

i15:04 j16:42

ConcentiatkxtsAnatyta Type

NaMgA!SiPSCIK

CaTiVCrMnFeCoNiCuinSf

SampleSampleSampleSample

Calibration status


Sample CalibratedSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSample

Compound

rt&bMgo

AI203Si02

GuDumtintiun (Y.)

0.46225.906

CalculationMM*l4MAfneilNMCalculateCalculate

8.253; Calculate43.656

P205 i 0.085Calibrated i SO3Calibrated CICalibrated K2OCalibrated CaOCalibrated TI02Calibrated , VCalibrated : CrCalibratedCalibrated

MnOFe2O3

Calibrated CoCalibrated : NiCalibrated CuCaHbrated ' InCalibrated ' Sr

0.1910.1060.0776.9550.4720.01702640.18213.220.0080.0930.0040.0080.011

CalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculate


Ana ratio; 106—--———,

ifcn: NoneNomiaKaeT tolQO.0%X-rav path! Vacuum

Quantify parametersRecip*: c:\8U perq\dataXBemiq 1 rep

Spectrometer reap, fit*: c:\8uperqV3ata\semiql .stiUM compound fate c:VBUperq\example\9eology.cpi

A ?ply drift ooirj No

Ditall, fines aet 'NoneError

Max Seated detectof Intensity; 2000 hcpaMax Flow dfltectorinHiMMy: 1000 KcpsMay. Scintd*Uctoftm*nmy: 1000 kcpe

Max. Oupte detector fartarojty: 3000 Kcps

9/11/02 17-03 University of Toronto Quantified peaks in c:\5upefq\data\113-l6m_.pks

Summaiy of resort*Samete: 113-16

9/11/02 16:02 9/11/0217:02

Mte. 0.001Used lines: 22

RhQuaL program: aemiq

Page 1

Analyte

NaMgA)SiPSCIK

CaTiVCrMnFeCoMiCuZnRbSr

i YZr

Type

sampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampteSampleSample

Calibrate*) status

CalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibrated

Campo**

Na2OMgd

At2O3S*02

P2O5S03

CIK2OCaOTt02

VCr

MnOCalibrated : Fe2O3CalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibrated

CoMi

CUZnRbSrYZr

Concentrationm

0.226.048

7.37542.567

0.0830.2640.0571.3676.7160.5850.0250.2090.224

14.1250.0160.0970.0090.0120.0070.0090.0010.003

Calculation

CalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculate


Area ratio: 105r. 0.

CTtafK Noneto IOQ.0%

X-nry patte Vacuum,

Qmntify pifauftfttera ^-—-———Retjtei c:\supefq\data\9emiq1rcp

IJeTc:\superqVnxample\oeologY.cpl No_____________

atom. MttNone"

ErrerWiuliUig; Rootr. 2000KcpT

Appendix XVI

XRF Analysis

Samples

Drill Holes 115@ 26.5 feet

115® 29 feet

Il5(a) 36 feet


DEPARTMENT OF GEOLOGY

22 Russell Street, Earth Sciences Centre Toronto, Ontario M5S 3B1

Fax: (416)978-3938 Tel: (416)978-3022

Date: 17 September 2002

Fa* Number: 416 504 7760 No, Pages: 4


TO: JeremyBrett

FROM: Mike Gorton

BH115-26.5 and BH115-29 are high Mg rocks with compositions

very similar to komatiites

BH115-36 appears roughly basaltic in composition with relatively

high incompatibles such as K2O, Na20 and TiO2.

However, Cr and especially Co are too high whereas SiO2 and especially Zr

and Y aie too low. Could be a cumulate from a relatively fractionated basalt.

9/17/32 15:42 University of Toronto Quanted peaks in c:lsuperq\data\bh115-26.pks

Summary of resute" BH11 5-26.5

: 5717702 15'13 j

Sum:

traces:Qual. program: ,se

Page 1

Anatyte

Na i : Mg

Ali Si l Pi Si Cl 1 Ki Ca

TjV

1 r"*1 w*Mn

i FS i Co

Ni Ir RbSrY

i zrPb

ConTyp* | Calibration j

j status j.Sample j Sample Sample Sample Sample ! Sample Sarrple Sample Sample Sample Sample Sample

i Sample Sample

j Sample 1 Sample i Sample 1 Sarule- Sample

Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated


j Calibrated Calibrated Calibrated CalibratedCalibrated

1 Sampie ; Catibrateo ; Samaie '- Calibrated

Sarnole Calibrated

c*ntrationsCompound j C

Na20; MgO|

AC03 S102 P2O5

SOS CI

1 K20 1 CaO

T,02 : V

Cr i MnC

Fe203 j Cc ! N:

Zn! Rt;

SrY ZrPb

lonoentratioci i Calculation i i.%) mathod

0.349 i '-•'''"••0*1 ' 26.458 !

7875 44302

0.099 0.127 0.091 0.139 5.849 0.535 0.019 0.162 0.145

11.619 0.012 C. 088 0.005 0.001

i 0.007 :

Calculate i Calculate | Calculate ' Calculate Calculate Calculate Calculate Calculate Calculate Calculate

; Calculate : Calculate ; Calculate i Calculate j Calculate ' Calculate

Calculate i Calculate

O.C02 ': Calculate0.003 Calculate 0.006 ' Calculate

c Vsupwydauvsemiql sti

i~Max. Seaied detector intensity:

University of TorontoQuantified peaka in c:\super4\data\bM1S-29.pks

Summary of results.Sample: SHIIfrzT

Page 1

Concentrations, ____ —i^tei Type |dali6r^~tonipoundiC^ce.rtnnion

1 status ' L —— S-2L-— —Na jM9 i Al | Si P i

3 i C! lK

GaTi CrMn Fe Co Ni Cu Zn Br Sr Y Zr

____ o, Sample SampleSample Sample Sample 1 Sample Sample Sample Sample Sample Sample Sample

' Sample l Sample

Sample i Sample ! Sample j Sample

Sample Sample

' Sample

Calibrated , Calibrated ' CaKbrated | Calibrated ! Calibrated Calibrated Calibrated ' Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated

i Calibrated Calibrated Calibrated Calibrated

i calibrated i Calibrated 1 Calibrated , Calibrated

Na2O MgO

AI203 SiO2

P205 SO3

CI K2O CaO TiO2

Cr MnO

j Fe203 1 Co \ Mi i Cu

Zn B

1 S

i i-J ——— — — **— ——————

0.869 29.541

7084 43.673

0.0760.263 022'

0.103 4.506

j 0.39 0.22

0.133 i 12.401 | 0.011 i 0.112 i 0.018 l 0.009

r l O 002

r l 0.01 * ' 0.001LJL, 0- 0(K

Calculatkjn j method i

Calculate ! Calculate j Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate

i calculate ! Calculate 1 Calculate

Calculate j Calculate

Sample preparation ,"" Sanrpte type: pressea powoei ' Area ratio! l . . —— , — l

Ariditive/samote: 0-(.i ———— Kkn: None . ——— iNormalise: no

H- X-ra0*Jh: vae-i

uum ;

Quantify parameters—————p*rJ*'-i^L. A-V0*mamV

Max. Seated detector intensity———————•5—— -- -— - - :—'—..Ik.

9/17/021558

-, -J r

Unlveisrty of Toronto Quantified peaks in cûperq\data\bh115-36.pks

Used lines; 24 Traces:

Page 1

Concentrations "Type j Calibration Compound rwentration j Calculation

MaMg Al Si P S CI K

Ca Ti V Gr Mn Fe Co Ni Cu Zn Br Rb Sr Y Zr Pb

SampleSample ! Sample Sample Sample Sample ( Sampl* | Sample l Sample j Sample | Sample Sample Sample Sample , Sample i Sample Sample Sample Sample

l Sample Sample Sample j

! Sample j 1 Sample .

CalibratedCalibrated jCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibrated

Na2OMgO

A1203 SSiO2

P205S03 j

Ci lK20*CaO .Ti02

V!

Mr\0 Fe2O3

Co NiCulZn!BriRb 1SrY

ZrPb

.) 12.40912.95

12.526 i44.65!0.1220.3510.6771.639

10.56409230025OOBfl0.113

inuthod l Calculate ,Calculate !Calculate |Calculate lCalculateCalculateCalculateCalculate jCalculate 'Calculate |CalculateCalculateCalculate

11 374 l Calculate0.012 Calculate0.027 ' Calculate0.0110.0070.0020.007

0.02

CalculateCalculate

l Calculate! Calculatej Calculate

0.001 l Calculate0,003 ! Calculate0 005 ; Calculate

Normalise;Rim: None

Quantify parameters

Appendix XVII

XRF Analysis

Samples TD MM 107, 61,162, 184, 171,170 Si 99

December 18, 2002

JU.




Fax: (416)978-3938 Tel: (416)978-3022

Date: iSDetember 2001



TO: Jeremy Brett

FROM: Mike Gorton

BG Looks like a carbonatite with calcite, phlogopite, olivine? CaO reported as CaC03, giving a total of 99 30Xo Low K2O and AJ203 because surface analysed did not expose much

phlogopite.Thus the B a is rather high - maybe some in the calcite.

Note because all the Ca is in calcite and all the Mg and Si are m a

silicate phase, this will cause severe problems for the data reduction Thus

this analysis is definitely 'semi-quantitative'

TDMM107 Porphyritic amphiboliteTholeiitic basaltic looking chemistry High Cr with low SiO2 suggest

somewhat cumulate High FeO, TiO2 and K20 suggest fractionated

TD" ;-(061 Very coarse amphiboliteMafic cumulate with high MgO, Mi, Cr and Co Low incompatibles.

Rather high CaO - pyroxenite originally'5

rTDMA1162 Very coarse amphibolite

Mafic Cumulate. High TiO2 and V suggest opaques. Very low A12O3 Very high CaO - pyroxenite originally 1

TD W J 84 Very coarse amphibolite.Mafic cumulate, rather more Fe rich.

TDMM171 Amphibolite - porphyritic?Basaltic, but low A1203, Zr and Zr/Y still suggest cumulate origin.

TDMM170 Very coarse amphibolite with feldspathic clots.Very high FeO with high incomparibles (especially Y).But Zr/Y very low - still somewhat cumulateLooks like one of those very Fe rich, big feldspar, tholeiites.

TDMM099 Fine-grained micaceous looking rock.Rather high incompatible elements, but Zr/Y tholeiitic - not so cumulate Looks like a less fractionated variety of TDMM170

12/19*2001 University of Toronto

Quantified peaks in d:\superq\data\tdmml07 r* s

Summary off results

Page

Sampte:Measured:Quwrtffied:

Sum:RMS;

Used lines:Tracas:

Qua), program:

TOM M 10712^18/200112/18/2001100. ft0.00020RhPdsemiq

11:5512:19


NaMBAiSiP3CIKCaTiGrMnFeNiir.RbSfYZrNO

Type

SampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSample

Calibration status

CalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibrated

Compound

Na2OMgO

AI2O3SIO2

P205S03

CIK20CaOTiO2

CrMnOFeO

NiZnRbSrYZrNb

Concentration IK)

3.6547,81715.02

44.6110.5780.2130.1891.3056.752

2.20.0570213

153140,012

0.010,0040.0350.0020.0110.002

Calculation imECHJU

CalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculate

Sampte preparationSampte type:

Ate* ratio:Additive/sample;

Film:Normalise:X-ray path:

pressed powder1.080.Noneto 100.0'AVacuum

—

Quantify pararrtetereRecipe: c:\superqVJata\semiq1.rcp

Spectrometer retp. file! c:\superq\data\sermq.8tiUse compound list.

Apply drm con.: NO

Max. Se

Disall. lines sot:Error weighting^

atad detector intensity:

NoneRoot2500 kcpe

Max. Hew detector intensity: 2SOOkcp3lâx.Scirrt detector mtcfisrty iSOOkcps

12/18/200' 15:36University of Toronto

Quantified peaks in d:\superq\data\ldar061_.pk3

Summary of results! Sampler TDHM061 ^ J

Measured: 12/18/2001 12:13'Quantified: 12/18/200115.28

Sum: 100. 3A "RIDlSnyOOO""""

u&cd lines; 20____Traces: 3h Ba

Qua! program: semtq

Page 1

Annlyte! Type____Concentrations _________ i Calibration Compound l Concentration i Calculation i

1 statusNa Sample r CalibratedMg i SampleAl SampleSI i SampleP , Sampla


S i Sample ; CalibratedCIK.

Ca"ivGrMn

Sample CalibratedSample CalibratedSample i CalibratedSample CalibratedSample CalibratedSample CalibratedSample Calibrated

i F e i Sample CalibratedGo ; Sample Calibrated

i Ni ; Sample . CalibratedZn Sample \ Calibrated

i Rb Sample CalibratedSr Sample

: Y SampleCalibratedCalibrated

iNa2OMsOi

AI2O3 iSiO2

P205 1SOS \

CIK20CaOTi02

V205Cr

MnOFeO

CoN,Zn!Rb)SriY i

W) method1,114 Calculate !

19.106 Calculate8 819 i Calculate

46.217 Calculate0019 Calculate0.049 Calculate0115 Calculate0.431

13.S64CalculateCalculate

0.263 Calculate0.0330.136

0.18


9.583 Calculate0.011 Calculate0 039 CalculateO.OOB Calculate00020.0060.002


Sampte preparation—-—^| Sample type: pressed powder

Area ratio: 1.13——-——.Additive/samplg: Q.________

Film:Normatisc: to 100,0^ X-ray path: Vacuum

Quantify parametersRecip*:

Spectrometer resp. file:Us* compound list:

Apply drift con*.:i OisaU. elem. set:

Disall. lines set:! Error weighting:

Max. Sealed detector intensity:Max. Flow detector intensity:Max. Seim detector intensity:

c:\superqViata\semiq1 repc:\euperq\data\serniq.stic Asuoe rg\exampte\geolog CD No '

NoneNoneRoot2500 kcps2500 kcps1500KCD6

l

.^

1l

1

university or loront" Quantified peaks in d:\super3Watattdar1 SZ

Summary of resultsSample: TpttM162 ^^.

Measured: 12/18/2001 12:31Quantified: 12/18/2001 15:40

Sum: 98.5RMS: 0.001

Used lines: 20 -____Traces: Rh Tl'QuaL program: semiq

ConcentrationsAnaiyte i Type

Na SampleMgAlSi

i PSCI

SampleSample

Calibration Compound status

Concentration (V.)

Calibrated Na2O i 0.376Calibrated MgO 15.228Calibrated AI2O3

Sarnpie Calibrated SiO2Sample Calibrated P2O5Sample i Calibrated SOSSample ; Calibrated Ci

! K Sample CalibratedGaTi

l VcrMn

Sample ; CalibratedSample CalibratedSampleSample


Sample Calibratedi F e Sample Calibrated

CoNlZnSryZr

1.73448.133

0.0070.0260.054

K20 007CaO i 15,4

Calculation method


TI02 ; 2,615 CalculateV2O5 i 0.09 Clalculate

Cr! 0.146 CalculateMnO 0.229 CalculateFeO j 14 315 Calculate l

Sample ; Calibrated \ CoSample Calibrated NiSamp'e Calibrated i Znsampie CalibratedSample Calibrated Sample i Calibrated

SrYX

0 01 ' Calculate0,027 i Calculate0.011 Calculate0.002 Calculate0 003 j Calculate 0 006 j Caiculate


Area ratio: 1.02Additive/sample: 0

FHm: NoneNonTHlis*: noX-ray patfi: Vacuum -~.

Quantify parameters__________Recipe: c \superq\aatateemiq1 rep

Spectrometer rop. fite: c:\superq\data\3emiq.s:i___iUse compound fet c.\supefq\examp!e\geo og.cpT

Apply drift carr.: No_________ ^^^Diull. elem. set NoneDisall. lines sei: None Errofvycightins- Root

Max. Sealed detector •rtansjty; 2SOOkcpsMax. now detectof rtensity: 2500 kcps

" MOT. Seint datector *itanîty! 1500 kcps

Summary of resultsSample: TPMM171

Measured: 12/18/2001 13:06 12/18/7001 15:09

Sum: W*RMS: 0.001

Used lines: 21Traces:

Qua!, program: semiq —^

ConcentrationsAnaiyte

NaMgAlSipSCIK

CaTiCrMnFeCoNiZnRb

. SrYZr

l Qa

Type


Calibrationstatus


Compound

Na20MgC

AJ203Si02P205

SOSCI

K2OCaOTiO2

CrMnOFeC-

Cc-MiZnRbSrY

ZrBaO

Sample preparat

ConcentrationW

2.881121148

3718744B5

00450.0550,438

D. 5710

00324770.02

0.21912.376

Q 0080.0250 31700030.0560.00200

ion

004041

Calculationmethod


Sample type: pressed powderATM ratio: 105

Additive/sample: ~ 0.Film: None

Normalise: to IQO.0%X-ray path: Vacuum

Quantify parameters1 Recipe: c:\superq\data\semiq1 rep ti Spectrometer resp. fite; c:\superq\data\9emiqsti ij Use compound list: c:\superqVexample\geotoa.cpi j

Apply drift eon*.: No! Disall. etenv set. Nonei Disali. Unea tt* None |[~ Error weighting: Root

Max. Seated detector intensity: 2500l Max. F taw dotKtor intensity: 2500

RepsJKCJ56

B-ol D3LL VOS 9Tir spuoiueiQ d O I : 5 I G O 91 "4 o o

Univenuty m (m,*,;- Quantified peaks in d:\superq\data\tdar184_.pk.'1;

Summary of resultsSampk; TOW 194

Measured: 12/18/2001 12:50__Quantified: 12/18^2001 '5:44 _____Sum:100 'Mi ________RMS: 0.001

Usedltnes: 21____ ^.m—-Traces: Rh———————Qual. program; sjarmg———-—-

ConcentrationsAnalyte i Type

Na SampleMg SampleAJ SampleSiPSCIK

SampleSampleSample

Calibration status


Compound ConcentrationW

NaiOMoo

Calibrated AI203Calibrated SiO2Calibrated P2O5

1.59114.527.464

46.3650.409

Calculation method

CalculateCalculate .CalculateCalculateCalculate

Calibrated SO3 0.071 Calculate

Sample CalibratedSample Calibrated

Ca Sample j CalibratedTt SampleV ; SampleCr SampleMn Sample

CI 0.174K2O 0.655CaO

Calibrated TtO2Calibrated V2O5Calibrated : CrCalibrated

F* Sample i CalibratedMi Sample calibratedCu i Sample : Calibrated

t ZnRbSr

SampleSampleSample

10.7341 3280.0410.036

Calculate jCalculateCalculateCalculateCalculateCalculate

MnO 0.243 CalculateFeO 16.272 Calculate

Ni i 0.033 CalculateCu 0.012 Calculate

Calibrated Zn : 0.018 CalculateCalibrated R6 ; 0.004 CalculateCalibrated Sr 0.016 Calculate

Y Sample Calibrated ! Y 0.005 ; CalculateZr Sample : Calibrated zr , 0.011 1 Calculate


Area ratio: ..vii——..m.Additive/samplB: 0.————.——

Film: None-—^--—-"Norrratls*: to iOQ.0%X-ray path: Vacuum

Qtantify parametersRecipe: c:\superqVdata\semiq1.rep

etef rxp. Tlto: c:Vsuperq\aata\semiq,stiUs* compound list: c:\superq\example\geolog.cpl i

Apply drift coir.: NoDiull. etem. aet: NoneOisall. lines set: None

_______ NUu. Seated detector intensity:

Root 2500 RODS

Max. Flow datacttM- intensity: 2500 Kcps

, OF

University of l oronto

Quantified peaks in d:\superq\data\Wrrjml7Q_

Summary gf restite Sampte! TJIMM170

Measured: 12/18/2001 13:26Quantified: 12/18/2001

Sum: 100RMS: 0.000

Used lines: 20Trace*: Ga Ru Rh



l

NaMgAl

Sample

Calibration Compound status

Calibrated

CofiocjituAiofi C54)

Na2O 1.656Sample Calibrated MgO 7.923Sample Calibrated : AI203 , 12.725

Si Sample Calibrated SiO2P Sample ! Calibrated P2O5S Sample CalibratedCI

SO3Sample , Calibrated ' CI

K Sample i Calibrated K2OCa ' SampleTi , SampleVGr


Sample CalibratedSample

CaOTi02

V2O5

38.6290.5940.112

1.142.667

10.973

CalculationITMttlOd



Calibrated Or 0.021 CalculateMn Sample i CalibratedFe Sample CalibratedNi . SampleZn

1 Rb

CalibratedSample CalibratedSample

1 Sr SampleY Sample

MnOFed

0.33520906

Ni i 0,018


Zn ; 0 015 | CalculateCalibrated Rb 0,005 CalculateCalibrated SrCalibrated

Zr Sample CalibratedY

00110.013

CalculateCalculate

Zr 0.017 i Calculate

Sample preparationSample typq; pressed powder

Area ratio: 109-—-———Mdrtivc/sampte; O________

______Film: None M———Nomalise: to IOQ.0%X-ray path; Vacuum———,-

Quantify parameters ——Rid ———— .repSpectromatef resp. file: c:\superq\data\8emiq sti

Uae compound fet: c;\3Upgtq\exampie\0eQlog.cplAppty dnft oorr.: NoDiMll. etenvtat: NoneOlMll, lines *et None gmnr weighting; Root

l Max. Seated detector intensity. 2500 kcpsl Man. Flow detector intensity; 2500 kcps

Max. Scint detector intensity. 1500 kcps"

)EC.';. 2001 c: i

12T. 3/2001 16:04

M.'i'i

University of Toronto Quantified peaks in d:\superq\data\ldmrnOW_.pk5

Summary of resultsSample: TDMM099

Measured: 12/18/200113:44Quantified: 12/18/2001 16:04

Sum: 100.RMS: 0.000

21Trace*: Rh

Qual. program: semiq

Page


N3MgA!SipSCIKCa

Type

SampleSampleSampleSampleSampleSampleSampleSampleSample

Calibration ttatus


Ti : Sample j CalibratedV Sampte CalibratedGr Sample i CalibratedMn SampleFe SampleNiZnRbSrYZrNb

SampleSampleSample

CalibratedCalibratedCalibratedCalibratedCalibrated

Sample CalibratedSample CalibratedSampleSample


Compound

Na20MgO

AI2O3Si02

P205S03

CIK2OCaOTiO2

Coi tctiitajRion C/.)

072511.064

12.3747.481

0.8810.054

0.07Z683825

1948V2O5 1 0.048

CrWnOFeO

NiZnRb

00680.206

14.0460.02

0.021

CBteutetioolIHlttlod :

Calculate 1CalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculate

0.008 ! CalculateSr 0 022Y 0.004Zr 0.027

Nb i 0.003



Area ratio: 1.07

Film: NoneNormalise: tolOO.0%X-ray path: Vacuum

Quantify parametersRecipe: c:\superq\data\semiq1.fcp

Spectrometer reap, f He: c:\3uperqVdata\gemiq.ttiUte compound lUt; c:\BUperq\exampteVacolog.cpl j

Apply drift NoDisaiL etem. set: NoneOisalL tines set NoneError weighting; Root

Man. Sealed detector intensity: 2500 Reps Max Flow detector intensity 2600 kcps

Appendix XVIII XRF Analysis

Samples BE - 2N Drill Holes 75 f® 11 feet

15(a). 18 feet 75 (ffi:21 feet

75 (a). 25 feet 75 tib. 26 feet

75 @ 30 feet76 (a). 34 feet

li \ f, ^ n o - ~ ~AD^ l- f' C ~ '^ r ^]'~^v *tr~i ' L ,- ^ "*

JL V. '!) :J! r:OrM b wr : 'CLOlJo v "^. •j-'- rC ROM



Toronto, Ontario M5S 3Bl

Fax: (416)978-3938 Tel; (416)978-3022

Date: 19 Joly 2001



TO: JeretnyBrett

FROM: Mike Gorton

Here are the results from the latest set of samples - recalculated to 100*54.

BH75- 1 1 Very high K2O, high P2OS, Ba, Ti02, Zr, Mb and Y, but Zr/Y only ~ 8

BH75-1 8 Same reddish staamng and low SiO2, but lower Zr, Mb etc and Zr/Y ~ 6.

BH75-21 Half core with a sedimentary inclusion (mostly avoided) Low P2O5 but

somewhat higher TiO2, Zr, and Nb with Zr/Y -11. High CaO (carbonate assimilation7)

BH75-2S Weird stuff this. .High K2O, P2O5 and Nb but low Zr with Zr/Y ~ 3.5

(half typical tholeiitic values)The side analysed contains a mafic inclusion on the edge, but only about

have been included in the analysis.

BH75-26 Breccia fragments abou: 25^b, carbonate matrix about 750xi CO2

calculated bv differenceNo sign of interesting elements (like Nb, ZT etc) ;n the carbonate.

BH75-30 High P2O5, Ba and ST, but only moderate Zr, Mb with Zr/Y ~ 8

BH76-34 Red-brown micaceous rock with about 350/* pale coloured areas (alteration?).

High MgO, Cr, M, and Co contrast whh high Fe Presumably there was a mafic parent overprinted by Fe. Once again very low Zr/Y.

BE-2N High Ti02, K2O, P2O5, Ba, Sr, Zr and Nb with Zr/y -11.

7/19/2001Pane


Quantified peaks in d:\superq\data\bh7S-11_.pks

Summary gf resufcsP Sample: SH75-11_____|

Measured: 7/19/20011235Quantised: 7/19/2001 14 47

Sum: 100. "A_____ttMS: 0.000

Usedlinesi 23Tract*: Rh



NaMgA)SiPSCIK

GaTiCrMnFeCoNiCu2nRbSr

i Y: Zr

Mbea

Type

SampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSample

Calibration status

CalibratedCalibratedCalibratedCaltoratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedcalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibrated

Compound

Na2OMgo

AJ203S1O2

P2O5SO3

CIK20CaOTi02

Cr2O3MrtO

Fe2O3CoNi

CuZnRbSrYZrNbBa

Concentration Pt*

0.1867199

•f 1.75843822

3.7260.0890.0547.3259.8242.6020.0220.048

1Z8680.0060.0240.0080.0160.018

0.070.0060.0470.007

^ 0.274

CateMiatiofiM^Mfe^bJIIKUHM

CalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculate

Sampte preparationSamptetype; pressed powder

Area ratio: 108

Mom to IQO.0%X-ray prth; Vacuum

Quantify parametersRecipe: c:ûpergvctet3Vsemiq1 ,fcp

Spectrometef resp. flte;

FU*e compound fafc c Asuperq\Rxampte\geolog.cpt

Apply drift conr.: No _ ..^—————Dbai. eten. set: None

___ Oteafl. lints x*-. None Error e*9htOTq: Root

A. '9.2001 3:?: D M J Of T GtC.OGY

'19/7.001 145?Pace

University of Toronto Quantified peaks in d:\supeitfldata\bh75-l8_.pks

Analyte

Na Mg Al SiPsCI K

Ca TlV Gr Mn Fe Co Ml

i Cu Zn Rb Sr Y Zr

i Nb

Type

Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample

| Sample

Summary off reaidtsSample: BH75-18

Measured: 7H9C001 1Z53QuanOied: 7/19^001^4-51

Sum 92.7*FIMS: 0.001

UMd lines: 23Traces: Rh

Qual. pro-am: semiq J

ConcentrationsCafibtalion

statusCalibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated Calibrated

Compound

Na2O MgO

AJ2O3 SiOZ

P2O5 SOS

CI K20 CaO Ti02

V2O5 Cf203

MnO Fe203

Co ^&

Cu Zn Rb

Zl Nb

Concentration (Y.)

1.698.761

10.304 42.64 0.655 0.076 0.055 2.866

10.546 1.8B5 O.D51 O.D23 0.073

12.995 0.009

0.02 0.009 0.014 0.009 0.018 0004 0.025 0.005

Sample preparationSamptatyptK pressed powder

Area ratio: 1.08Addttivafedmple: 0.

Film: NoneNomxaSse: noX-rav Mth: Vacuum

Quantify parameters

—i

Cakabtion fnrami

Calculate Calculate : Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate Calculate

Reeve: c:\3Uperq\data\semiq1.rcp jSpeOimnatef rasp, fite: c:\wpwtfdata\seroiq.3ti

Use comoound list: c:V3uperq\cxample\seotog.cpl

l

l

Aopiy drift COT.: NoDtsan.efcMi.Mt: NoseDisalLhnesteU NOfl*Error WBrahtavi: Koot

ti

'('19/2001 14-57University of Toronto

Quantified peaks In d:\superq\data\bh75-21_.pks

Summary of remits

Page 1

Sampte: BH75-21Measured: 7/19/2001 13:11

QuarrtifiBd: 7/19J2O01 ifj^Sum: 100. V*

_____RMS: 0.000—-——-Used lines: 22_______

____Traces: CoRhOsQuaL program: semiq————^

ConcentrationsAnaJyte Type

Na | SampleMg SampteAlSip

SampteSampleSample

S i SampleCI SampleK

CaTiVCrMnFeNiCuZnRbSr

l YZrNb

SampleSampleSampleSampleSampte

Caibfation status

CalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibrated

Compound

Na2OMgo

AI2O3S)O2

P2O5SC3

CIK2O

Calibrated 1 CaOCalibrated

Concentration(y.)

3-8567.693

11.75140.15106690.1280.0981542

Calculation method

Calculate }Calculate 1CalculateCalculateCalculateCalculateCalculateCalculate

.17.565 CalculateTiO2 | 2411 : Calculate

Calibrated V2O5Calibrated

Sample i CalibratedSample CalibratedSampleSampleSampleSampleSampleSampleSampleSamcle


Cr203MnO

Fe2C3

0058 Calculate i0.021 Calculate0.116 Calculate13.81

Ni i 0.016Cu 0.01 7ZnRb

Calibrated SrCalibrated \ YCalibrated ZrCalibrated Nb

0.01300060.03100040.0440.009

CalcuiateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculate

Sampte preparation Sampte type; pressed pov*3ef

Ama ratio: 11Addrtivtrfsampte: 0.

Fibre Honel— Nonralise: to 100 (W

c Vacuum

Quantify parametersRacipe: c:ûpe^q^data\3erîiQ1.^cp t

i. file: c:\9upferqVdatateemia.sU l

Apply drift con-.: NoDMuai.atein.sM; NoneDisaH. Kngs act: None

c:\superq\gxampte\geotog.cpl

Root- ___ r^jt.J^fed dcteaor intentrty. 2500 kcps

GEOLOGY

7M 9/2001 Umversity of Toronto 2, S' Quantified peaks in d:\3Uperq\data\toh754fc..pKs

Summary of restitesample; BH754* Z S".

Measured: 7/19/200113:29Quantified: 7/19/2001 1S 00

Sum: 100.RMS: 0.000

UtwtBmx: 19Rh

i Quat. program: semiq


IMaMgAlSiPSCIKGa

! TiMnFe

: NiZnRbSrY

Zri Nb

Type

SampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSample

Caibnfon L statue

CalibratedCalibratedCalibratedCalibratedCalibratedcalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibrated

Compound

Na2OMao

A12035iO2

P2O5SO3

CIK20caoTi02MnO

Fe2O3MiZnRbSrYZr

Nb

Concentration (*1

Z459.281

12.82341.604

2.950.0660.0613.579

10.0542.750.05

14.1090.0120.01200110.0520.0050.0180.012

CaJdKatioo method

Calculate jCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculate

Sampte preparationSample t pressed powder

Area ratio: 1.08

Rim: Noneto IOQ.0%

X-ray path: Vacuum

Quantify parametefsRecapc: c:\supefq\Jata\sefrlql.fcp

^pectrptnetBf rcsp.tite: c:ABUpaq\data\Bemiq stiUse compound list: c.\supeTq\example\9eoioQ.cpi

Apply drift coir.; NoDisatt. etem. set: None

NoneError weighting. Root

Max. Seated detector intensity! 2SOD kcps Max. Fto* detector rrrteMHtyTlSOO heps UtouScint detector intensity: iSOOKcps

Max.0uptex detectorintcngrty: 3000 Kcps

,' ;JL 19.2031 3

7/19/2001 1506

Of T GEOLOGY

University of Toronto 2.4. Quantified peaks in d:Vsuperq\data\bh75-(NL,pks

Summary of resultsSample: BH75^Xf,

Measured:f Quantified:

Sum:RMS:

Used lines:Traces:

Qual. program:

7/19/2001 13:477/19/2001 15:06100. "ft000117Rhsemiq

IV (J.

Page 1

t,-

ConcentrationsAnaJyte

NaMgAlSiPSCIK

GaTtV

MnFeNiCuSrY

Type

SampleSampJeSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampteSample

Calibration status

Mot matchedcalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibrated

Compound

C02Na20MgC

AI2O3SiO2P2O5

SO3CI

K20CaOTKD2

V2O5MrvO

Fe203Ni

CuSrY

Concentration W

332650.1112.5581.875

..6.13&0.1060.0640.0160.444

50.644.0.4110.0160097

4.170.0070.0040,0730,003

Catortatkm•MÂhrfMim^noQBalance j

CalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculate

Sample preparatior)Sanyletype: pressed pov*def

Ara* ratio: 1

FUrre NoneMormaHse: to IOQ.0% witri as balance CO2 X-ray path; Vacuum—^——————J

Quantify parametersRecipe;

Spectrometer rcsp. file:Use compound Hst:

Apptv drift carr.:DisaiL etem. set:DisaU. fines sat:Error welyliting;

Max. SeaJdf detector intensity;v Max. Flow detector intensity:

Max. Scant detector intttlsMy:Max. Duptex detector intensity;

c:\superq\data\semiql repc:\suptrqVdata\semiq.3t)c:V9uperq\example\aeologNoNoneNoneRoot2500 kcps2500 kc^61500 Kcps3000 kcps

,,.. (—— i

icd!

ii

iii

__ j

7/19/2001 15 -CUniversity of Toronto SO

Quantified peaks in d:\superqVdata\bh75-fll_.pKs

Summary of results

-nge

Sanvte:Maasumf:Quantified:

Sum:RMS:

Used toes:Traces:

Qual. program

BH7S*7/19/20017/19T2001100. %0.00021Cr Rh Pdsemiq

3.014:0515.09

ConcentrationsAnaryte

NaMgAlSiPSCIK

GaTiMnFeNiCuZnRbSrYZrNbBa

Type

SampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampleSampteSampleSampleSampleSampleSampleSample

Cribrate* stable


Compound

Na2OMgO

ACO3SiO2

P2O5S03

CIK20CaOTiO2MnO

Fe203Ni

CuZnRbSrY

ZrNbBa

Concentrationm

5.5636703

13.57146.173

2.260.1120.0582.59

12.6351.9980.1137.7390.0140.0070.0090.0050.1030.0040.0310.0050.246

caculabon method

Calculate--CalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculateCalculate

Sampte preparationSampte type: pressed powder

AIM ratio: 1.06

Fihn: NoneNomwlise: to 100 (rtfcX-ray path: Vacuum

Quantify parametersi— Recipe: c:\superq\data\3emiqlrcp

Spectrometer resp. fie: c:\superq\data\semlq.stiUse compound Batt c.^superqVelcample^geolog.cpl_ Apply drift COTT.: No-——————.—.--——

Dimtt. etere. safe None________ __Disall lines set None ""-——^

in!* Rootl Man. Staged detector inOnajty; 2500 kcps i Nlax. Row detector Intensity: 2500 Reps

.•l!L. 19. 2051 Or : GcU.JbY


Quantified peaks in d:\superq\data\bh76-34_.pks

Summary of results

Pagei

Sample:Measured:

Quantified:Sum:RMS:

UsedKnes:Traces:

Qual. program:

8H76-347/19/20017/1972001100. %0.00021Rhsemiq

14:3515:13 &Y f t' f - t — '

ConcentrationsfWBiyie

NaMgAlSiPSCIKeaTiCrMnFeCoNiZnRbSrYZrNb

type


MMuraoon status

CalibratedCalibratedCalibratedCalibratedCalibrated

vompouna

Na2OMgd

AJ203SIO2

P2OSCalibrated SOSCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibratedCalibrated

CIK20CaOTi02

Cr2O3MnO

Fe203CoNiZnRbSiY

ZrNb

voncenvanon l*)

0.27214.43510.59737.893

1.170.0550.0492.428

11.8661.9310.0290.099

19.0660.0130.0230.0250.0110.0170006

0.010.003

vriKUiauon HVBwQli


•i r: i''4 -.

jfc "'

,/'l j /'

v /f '•'-f

Sample preparationSample type; pressed powder

Area ratio; 105_____0.

Ftfnc NoneNonnafae:K-fiy patte Vacuum

Quantify parameterei Recipe:

Spectrometer resp. file:Use compound list;

Apply drift carr.:DisaH. etem, set:OisaJL fines sot:Efror wnaylitfl tg~.

Max. Seated detector intensity:Max. Flow detector intemitv:

c:\3Uperq\data\semlqVrcpc:\superg\data\Eemiq.sH lc:\superer\exampteVieolog.cplNoNoneNoneRoot2500 kcps ""2500 kCpS

Appendix XIX Sample Locations




Fax: (416)978-3938 Tel: (416)978-3022

Date: 15 October 2003

Fax Number: 416 504 7760 No. Pages: l


TO: JeremyBrett

FROM: Mike Gorton

The lab is called 'the XRF lab, dept. of Geology, U. of T.'

The instrument is a Philips PW2404 sequential x-ray fluorescence spectrometer.

Solid core samples were analysed using a recently developed, rapid, standardless technique

Rock Samples From Tudor Township

Collected by M. McGili

an 'f suffix denotes float

Revised June 6, 2002

Sample Number TDMM-01 TDMM-02 TDMM-03

1DMM 03Af TDMM-04 TDMM-05 TDMM-06 TDMM-07 TDMM-08 TDMM-09 TDMM-10 TDMM-11 TDMM-12 TDMM-13 TDMM-14

TDMM-16TDMM-17TDMM-18TDMM-19TDMM-20TDMM-21TDMM-22I DMM-23fTDMM-24TDMM-25TDMM-26

UTM Coordinates 301005,4954002 300861,4954063 300607,4954327 300607,4954327 300623,495429 f 300636,4954265 3006224954226 300626,4954209 300619,4954178 300669,4954150 300656,4954075 300734,4954067 300767,4954077 300833,4954095 300833,4954095 300855,4954076 300877,4954062 300938,4954049 300947,4954047 300947,4954047 300951,4953251 300951,4953251 300951,4953251 300922,4953232 3007984953201 300771/4953193 300730/4953160

MS Lithology 4P? 4P?

gabbro cum fg gabbro7

4P?4P7, vcg4P?, vcg4P7, mg4P?, eg4P?, mg4P?, mg4P7, mg4P?, eg4P?,cg

4P?4P?, eg4P?, mg4P?, mg

4P?, vvcg, cum4P?, vvcg, cum

V7, fuchs?V7?

dykerocK'"'1gabbro

granodiorite?, tonalite'' fg4P? mg 3G

Remarksplotted

medium grained, plottedplottedplottedplottedplottedplottedplottedplottedplottedplottedplottedplottedplottedplottedplottedplottedplottedplottedplottedplottedplottedplottedplottedplotted

non-magnetic plotted non magnetic, plotted

TDMM-27 TDMM-28 TDMM-29 TDMM-30 TDMM 31 TDMM-32 TDMM-33 TDMM-34 TDMM-35 TDMM-36 TDMM-37f TDMM-38

TDMM-38A TDMM-39 TDMM-40 TDMM-41 TDMM-42 TDMM-43

TDMM-45 TDMML-45fTDMM-46f

TDMML-46fTDMM-47

TDMML-47fTDMM-48TDMML-48

TDMML-48AfTDMM-49

TDMML-49 TDMM-50f TDMML-50TDMM-51

TDMML-51fTDMM-52

TDMML-52fTDMM-53f

300699/4953162 300699/4953162 300699/4953162

301081/4953329 301114/4953586 300957/4953596 300919/4953580 300898/4953578 300771/4953660 300814/4953709 300787/4953709 300787/4953709 299438/4955970 299438/4955970 299585/4955880 299585/4955880 299620/4955580 299695/4955305 300055/4956505 300444,4954987 299963/4955872 300433,4954991 299963/4955872 300441,4955072 300000/4955945 300461,4955107 300461,4955107 300011/4955974 300489,4955124 300037/4955978 300489,4955124 300072/4956023 300499,4955106 300120/4956039 300518,4955167 300238/4956096

feldspathic dyke

cg4P?4P?

mg 4P?

mg4P?cg4P?mg 4P?fg4P?MlMl4P?4P?3G3G3L?3G?mg3GMl

Ml dyke

Ml Ml 3G Ml 3G Ml 3G

cg3G Ml Ml 3G Ml

plottedplottedplotted

non-magneticmagnetic, plotted

slightly magnetic, plottednon-magnetic, plotted

magnetic, plottedmagnetic, plottedmagnetic, plotted

non-magnetic, plottednon-magnetic, plottednon-magnetic, plotted

plottedplottedplottedplottedplottedplottedplottedplottedplottedplotted

non-magnetic, plottedplotted

non-magnetic, plottedplottedplotted




tr po, plottedplottedplotted

TDMML-53TDMM-54 TDMML-54l DM M-55

TDMML-55t TDMM-56f TDMML-56TOM M 57 TDMML-57 TDMM-58f TDMML-58TDMM-59

T DM M l.-59TDMM-60 TDMML-60

T DM M 61 TDMML-61TDMM-62 TDMML-62 TDMM-63f TDMML-63TDMM-64TDMML-64

TDMML-64AfTDMM-65fTDMML-65fTDMM-66

TDMML-66tTDMM-67TDMML-67

TDMML-67ATDMM-68f

TDMM 68AfTDMM-69fIDMM-70TDMM-71TDMM-72

300513,4955178300252/4956135300513,4955178300278/4956161300513,4955178300301/4956184300518,4955182300315/4956223300552,4955196300327/4956232300560,4955210300324/4956290300579,4955231300145/49563723005^9,4955231300083/4956428300579,4955231300078/4956471300579,4955231300051/4956491300583,4955273300029/4956577300500,4955267300500,4955267299877/4956682300463,4955152299816/4956645300480,4955214299747/4956713300480,4955214300480,4955214300458/4955181300458/4955181300458/4955184300470,4955190300470,4955190300519/4955210

3G?Ml 3G?Ml 3G?Ml3G

cg3GMl?Ml 4P?Ml1DMl3GMl1DMl1DMlMl?Ml3L?3GMl4P?

mg 4P7Ml4P?1D3G4P?4P^1P

granodiorite

plotted plotted plotted plotted plotted plotted plotted plotted plotted

non-magnetic, plotted


non-magnetic, plotted plotted plotted plotted plotted plotted plotted

non-magnetic plotted plotted


non-magnetic, plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted

plotted

plotted

plotted

plotted

plotted

plotted

TDMM-73f TDMM-/4

TDMM-74A TDMM -75f TDMM-76f TDMM-77! TDMM-78f TDMM-79f TDMM-80f TDMM-81t TDMM-82 TDMM 83f TDMM-84 TDMM-85 TDMM-86 TDMM-87 TDMM-88f TDMM-89f TDMM-90 TDMM-911 TDMM-92 TDMM-93f TDMM-94f TDMM-95t TDMM-96 TDMM-97 TDMM-98 TDMM-99f TDMM-100 TDMM-101 TDMM-102f TDMM-103 TDMM-104 TDMM-10E TDMM-106 TDMM-107 TDMM-108

300519,4955216 300519/4955210 300556/4955598 300533/4955598 300543/4955583 300529/4955582 300522/4955555 300522/4955555 300522/4955555 300522/4955555 300529/4955558 300529/4955558 300572/4955527 300572/4955527 300655/4955534 300653/4955549 300653/4955549 300654/4955500 300673/4955549 300673/4955552 300668/4955576 300656/4955336 300675/4955365 300642/4955274 300666/4955328 300666/4955328 300666/4955328 300747/4955617 300764/4955754 300590/4955726 300329/4955563 300285/4955591 300760/4955796 300230/4955610 300285/4955591 300244/4955632 300311/4955591

3Gmonzonite

Ml

tonalite?

3G

fg3G mg 3G

qtz4P?

eg 3G/4P?

4P?

cg3G

plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted

non-magnetic plotted

TDMM-109f TDMM-110 TDMM-111 IDMM-112 TDMM-113 TDMM-114 TDMM-115 TDMM-115A TDMM-116 TDMM-116A TDMM-11'/ TDMM-118 TDMM-119 TDMM-120 TDMM-121 TDMM-122f TDMM-123 TDMM-124 TDMM-125 TDMM-126f TDMM-127 TDMM-12B TDMM-129 TDMM-130 TDMM-131 TDMM-132 TDMM-133 TDMM-134 TDMM-135 TDMM-136 TDMM-137 TDMM-138 TDMM-139 TDMM-140 TDMM-141

TDMM-141A VDMM-142

300310/4955570300320/4955543300300/4955481300675/4955927300595/4956006300589/4956018299454/4955141299454/4955141299454/4955141299454/4955141299454/4955141299445/4955225299445/4955219299450/4955230299449/4955258299415/4955337299385/4955325299338/4955356299331/4955353299257/4955360299218/4955307299181/4955346299102/4955332299481/4955153299538/4955361299491/4955382299410/4955405299260/4955402299260/4955402299260/4955402299190/4955366299655/4955279299668/4955311299340/4955063299307/4955101299307/4955101299231/4955192

mafic 3G vcg 3G^ vcgSG 3G cum MI/SG'?1

Granodiorite

non-magnetic, plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted

TDMM-143 TOMM-144

TDMM-144A TDMM-145f TDMM-146 TDMM-147 TDMM-148 TDMM-149 TDMM-150 TDMM-151 TDMM-152 TDMM-153 TDMM-154 TDMM-155 TDMM-156 TDMM-157 TDMM-158 TDMM-159 TDMM-160f TDMM-161 TDMM-162 TDMM-163f TDMM 164 TDMM-165f TD M M-166 TDMM-167f TDMM-168 TDMM-169f TDMM-170f TDMM-171f TDMM-172f TDMM-173f TDMM-174f TDMM-174A TDMM 175f TDMM-176f TDMM-177f

299231/4955192299230/4955163299230/4955163299214/4955170299114/4955143299269/4955022299533/4955157299571/4952427299551/4952427299505/4952298299505/4952308299399/4952580298842/4952301298855/4952300298874/4952267298919/4952234298925/4952241298925/4952241298925/4952241298952/4952233298975/4952225298975/4952225298996/4952212298996/4952212299040/4952082299040/4952082299051/4952067299004/4951986298989/4952081298980/4952103299214/4951551299199/4951629299200/4951618299680/4954477299680/4954477299680/4954477299680/4954477

3G?mafic SG'?

cg4P?siltstonecg4P?fg3G?

Ml?mg4P?

3G?cg3G

carbonateV7?

eg 4P?, biotite4P?4P?

fg3G?3G or 4P?

graniticgneiss/granitic

tg

plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted

magnetic, plotted non-magnetic, plotted

magnetic, plottednon-magnetic, plotted

plottedplotted

non-magnetic, foliated, plottednon-mag, biotitic? ; plottedslightly magnetic, plotted

plottedplotted

non-magnetic, plottedmagnetic, plotted

non-magnetic, plottedweakly magnetic, slightly rusty, plotted

sugary texture, plottedslightly magnetic, plotted

plotted non-magnetic, plotted

magnetic, plotted non-magnetic, plotted

TDMM-178 TDMM-178Af TDMM-178Bf TDMM-179f TDMM-180f TDMM-181f TDMM-182f

TDMM-182Af TDMM-182Bf TDMM-183f TDMM-184f TDMM-185f TDMM-186f TDMM-187f TDMM-188 TDMM-189 TDMM-190 TDMM-191 TDMM-192 TDMM-193 TDMM-194

TDMM-194A TDMM-195 TDMM-196f TDMM-197f TDMM-198 TDMM-199 TDMM-200 TDMM-201 TDMM-202 TDMM-203 TDMM-204 TDMM-205 TDMM-206 TDMM-207 TDMM-208 TDMM-209

299562/4954528 299564/4954499 299570/4954427 299172/4951708 299155/4951753 299147/4951764 299147/4951764 299051/4951746 299199/4951534 299200/4951517 299226/4951390 299221/4951358 299265/4951291 299265/4951291

299264/4954890 299391,4954816

V7?V7, ampc

granodiorite4P?Ml

mg4P? chior 3G?

3G?vcg 3Gvcg 3G

4P?

tholleiitic dykeMl

3G?vcg pyrox vcg pyrox

3L?granodiorite typical Mi pyroxenite

MlMl, typical? Ml or 3L?

3L or fg 3G? V7 xeno? vcg pyrox vcg pyrox

mg Ml3G, or Ml?

eg pyroxeniteactinolite schist9

typical Mltypical Ml

slightly magnetic, plottedslightly magnetic, plotted

non-magnetic, plottedmagnetic, plotted

magnetic, fabric, plottedmagnetic, plottedmagnetic, plottedmagnetic, plotted

non-magnetic, plottedslightly magnetic, plotted

plottedplotted

magnetic, plotted plotted plotted

garnet?, plottedbiotitic, plotted

non-magnetic, plottednon-magnetic, plotted

plottednon-magnetic, plotted non-magnetic, plotted

plotted similar to sample 193, plotted

plottednon-magnetic, plotted

deformed, plottedplotted

non-magnetic, plotted non-magnetic, plotted

plotted plotted plotted plotted plotted plotted plotted

TDMM-209A TDMM-209B TDMM-210 TDMM-211 TDMM-212 TDMM-213 TDMM-214 TDMM-215 TDMM-216 TDMM-217f TDMM-218 TDMM-219 TDMM-220 TDMM-221 TDMM-222 TDMM-223 TDMM-224 TDMM-225 TDMM-226 TDMM 226A TDMM-227 TDMM-228 TDMM-229 TDMM-230 TDMM-231 TDMM-232 TDMM-233 TDMM-234 TDMM-235 TDMM-236 TDMM-237 TDMM-238 TDMM-239f TDMM-240f TDMM-241f TDMM-241A TDMM-242f

299902,4951836299902,4951836299943,4951853

0250.3533,3

1920

Ml?lamp''

gabbro?oxide BIF in V7

plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted

Lost in Transit, plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted plotted

TDMM-243fTDMM-244fTDMM-245fTDMM-246fTDMM-247fTDMM-248TDMM-249fTDMM-250fTDMM~251fTDMM-252fTDMM-253fTDMM-254fTDMM-255fTDMM-256fTDMM-257fTDMM-258fTDMM-259fTDMM-260fTDMM-261fTDMM-262fTDMM-263fTDMM-264fTDMM-265fTDMM-266TDMM-267fTDMM-268TDMM-269fTDMM-270

300023,4951832 300023,4951832 300047,4951836 300192/4952442 300225/4952460 300225/4952460 300422/4952498 300422/4952504 300278/4952513 300278/4952513 300139/4952516 300102/4952570 300138/4952398 300219/4952437 300214/4952463 300157/4952461 300157/4952461 300157/4952461 300147/4952461 300134/4952325 300134/4952325 300150/4952333 300150/4952333

300065,4953198

299846,4951137

11.10.2822.31.6

0.380.390.390.410.490.340.480.4015.80.853.4526.50410.221.220.4206322.30.390.550.9023.3

lamp?gabbro?gabbro?

3Gcg4P?

V7, w/ biotitemg 4P"'

V7?Ml

V7, biotitic3G3G

biotite schist3L?3G?3G?4P?

carbonated V7?

mg4P"?V74P?

cg4P?ampc

plottedplottedplottedplottedplottedplottedplottedplottedplottedplottedplottedplottedplottedplottedplottedplottedplotted

non-magnetic, plottedpoor utm fix, plotted

plottednot submitted, plotted

plottedplotted

not submittedplotted

Lees' rock, exact location unknownplotted

UiJ

vim 81

z

i-i.

o

00rt' o

0o

nA,

l/rv- v./

xV

DX

)

O

C eh,l

Ot

oo

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oxJ

M hv V

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p

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co

(N0

E-os: o

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V-'oi

sto

owA* r-

11e

N

K

N{f K

4?

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5^ ^

JV

X

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C

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v^1

^ ^ d x:

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f r*? l TXf ;

^ y? T^ X o 7

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g. JO .

O

T2655lMAP REFERENCE TABLE

(The order of sample number is preserved to be consistent with the Appendices in the work report)

WORK REPORT APPENDIX

I

II

III

III

IV

VVIVIIVIIVII

VII

VIIvnvn

vn

VII

VII

SAMPLES

WD-AR-T1

TDMM-10, 33

TDMM-80

TDMM-103

TDMM-177

TDMM-188TDMM-192, 193TDMM-198, 202TDMM-217(f)TDMM-13, 31

TDMM-196

TDMM-195,TDMM-188, 189TDMM-201, 203, 200, 199, 204TDMM-208, 215, 216, 212, 211, 210, 209ATDMM-42

TDMM-63

MAP LABEL

Wolf Lake Property: Wild Dog AreaMapping Sketch: For Con 3,4 - Lot 5: Tudor Twp. (3 sheets)Location Map: Hand Specimen TDMM- 80... MJ-8A...DDH-100Location Map: Hand Specimen TDMM- 80...MJ-8A... DDH-100Tudor Property: GeoL And Sample Locations: TDMM149-185 (3 sheets)Trench 022 (3 sheets)128 Trench (1 sheet)Trench 128ATrench 102Mapping Sketch: For Con 3,4 - Lot 5: Tudor Twp. (3 sheets)Location Map: Hand Specimen TDMM-196021A (1 sheet)Trench 022 (3 sheets)Trench 128A (3 sheets)

Trench 102 (2 sheets)

Location Map: Hand Specimen TDMM-42...Tudor Twp., Lot 4 Con 6

CLAIM

1235050

1077320

1184030

1184029

1195077

11951651195165119516511840291077320

1195165

119516511951651195165

1184029

1195165

1195072

VIII

vin

VIII

IX

x

x

XI

XI

XII

XIII

xrv

XV

XV

XVI

XVII

MJ-17B

MJ-8A DDH-100 DDH-101DDH-99

MJ-19A

MJ-9

MJ-12, 13, 14, 15,16

TDMM-239

MJ-21, 28, 29

TDMM-269f

DDH-104 DDH-105

MJ-24 (MJ-24PDR)

MJ-39, 41, 38

DDH-113

DDH-115

TDMM-107

Location Map: Hand Specimen BE-2N... MJ- 39, 41, 38, Diamond D rill Hole...Location Map: Hand Specimen TDMM- 80... MJ-8A... DDH-100Location Map: Hand Specimen TDMM-42, Diamond Drill Hole DDH-99Location Map: Hand Specimen BE-2N... MJ- 39, 41, 38, Diamond Drill Hole...Location Map: Hand Specimen TDMM- 80...MJ-8A... DDH-100Location Map: Hand Specimen TDMM- 80...MJ-8A... DDH-100Trench 176-177 (1 sheet)Location Map: Hand Specimen BE-2N... MJ- 39, 41, 38, Diamond Drill Hole...Location Map: Hand Specimen TDMM-269fLocation Map: Hand Specimen BE-2N...MJ- 38, Diamond Drill Hole DDH-104, DDH-105Location Map: Hand Specimen BE-2N... MJ- 39, 41, 38, Diamond Drill Hole...Location Map: Hand Specimen BE-2N... MJ- 39, 41, 38, Diamond Drill Hole...Wolf Lake Property: Wild Dog AreaWolf Lake Property: Wild Dog AreaLocation Map: Hand

1195181

1184030

1195178

1195181

1184030

1184029

1195181

1195181

1195077

1195181

1195181

1195181

1235050

1235050

1184029

XVII

XVII

XVII

XVIII

XVIII

TDMM-162, 184, 171, 170

TDMM-99

TDMM-61

BE-2N

DDH-75

Specimen TDMM- 80...MJ-8A... DDH-100Tudor Property: GeoL And Sample Locations: TDMM149-185 (3 sheets)Location Map: Hand Specimen TDMM- 80...MJ-8A...DDH-100Location Map: Hand Specimen TDMM-61Location Map: Hand Specimen BE-2N, MJ- 17B...Location Map: DDH-75

1195077

1184030

1184029

1195183

1195181

ADDENDA

SAMPLE COLLECTION DESRIPTION AND COSTS

The following changes are added to the text filed with work report W0390.01708. Changes are noted in BOLD:

(Page 3)

Sample Collection

Samples were collected by Lydia geologists from pits, trenches and outcrop on the Property. Samples of several pounds were placed in plastic bags, identified as to location and later cleaned and examined before sending to the XRF lab at the University of Toronto. Approximately 1A day was spent on collection of each sample. (This time is calculated based on the field geologist examining GSC base maps of the local geology, locating examples of this geology in the field, identifying rock types anomalous to the mapped geology, identifying structures in the field that could affect the emplacement of intrusives, collection and labelling of field samples, rough- identification of the samples in base camp and the shipping of the sample to the Lydia head office with collection notes.)

Drill hole cores were examined using existing logs as a guide and samples selected for analysis. Samples were placed in plastic bags, identified as to drill hole number and footage in the hole before sending to the XRF lab at U of T. Approximately l hour was spent on collection of each sample. (This collection procedure included the identification of rock-types listed in the core logs, associational and structural context of the sample noted for sample selection, collection, bagging and labelling, sealing of core boxes for transport to Lydia core storage facility in Bannockburn and the shipping of samples to the Lydia head office with collection notes.)

Analysis

The XRF analysis was carried out at the XRF laboratory, Department of Geology, University of Toronto, using a Philips PW2404 sequential x-ray fluorescence spectrometer. A short flyer from the Department of Geology is attached. (Sample handling and preparation included washing, structural examination of the sample for optimal cutting angle, cutting using a diamond saw and the delivery and discussion of analysis with the XRF lab. Time: -1/3 hr @S75 ~ S25 by J.S. Brett)

LOCATION MAPS

LOCATION MAP

HAND SPECIMEN TD-MM-269T

WOLF LAKE PROPERTY

LYDIA DIAMOND EXPLORATION OF CANADA LTD. O (1:5000) 2.5km

1018

904955000mN

30000

385.S f V i , ,y ..'l V,

i

N, !(J? wp/ ^^ .-'

I . ff^ .,...)i

TDMM-196^ \

} u V

LOCATION MAP

HAND SPECIMEN TD-MM-1%

WOLF LAKE PROPERTY

LYDIA DIAMOND EXPLORATION OF CANADA LTD.

O (1:5000) 2.5km

4954000mN

.Mf. .Mf.

4956000mNLOCATION MAP

HAND SPECIMEN TD-MM-42DIAMOND DRILL HOLE DDH-99

WOLF LAKE PROPERTY


O (1:5000) 2.5km

Drill Hole 99 Azimuth: OSO0

C/ Dip:-450

TDMM-42

r 4955000mN

SOOOOOmE

b

-- -4957000mN

TDMM-61

LOCATION MAP

HAND SPECIMEN TD-MM-61

WOLF LAKE PROPERTY


O (1:5000) 2.5km

4956000mN

,-A, 4953000mN

30

' H

LOCATION MAP

DIAMOND DRILL HOLE DDH-7S

WOLF LAKE PROPERTY: WOLF LAKE AREA


O (1:5000) 2.5km

. NV ; v ~*-?\ Drill Hole

î \ Azimuth: j \^ , ^ Dip: -700

X ' ;.-û , ^--^7 ) \ ' '

i l ,'Q i . .. , . '* \ ^" f- -- s ,--,i

Wolf V xy—————— : ————— , ——— l.,-/ — ^-^.-.^•"•••••^••^ ——————— ' —

75 1700 ^

•. V"'^'. --- . S

4952000mN' f 20

4969000mN

Drill Hole 115 Azimuth: 1600 Dip:-450Drill Hole 113

Azimuth: ISO0 Dip: -450

WD-AR-T1

LOCATION MAP4968000mN HAND SPECIMEN WD-AR-T1

DIAMOND DRILL HOLES DDH-113, DDH-115

WOLF LAKE PROPERTY: WILD DOG AREA

LYDIA DIAMOND EXPLORATION OF CANADA LTD

(1:5000)

n

30Drill Hole 104 Azimuth: 0200 Dip:-450

Drill Hole 105 l— Azimuth: 020" C/ Dip:-600

MJ-41 fMJ-38

MJ-17B

M J-28 4MJ-24

MJ-29 MJ-19A

iBE'2N

20

LOCATION MAP

HAND SPECIMENS BE-2N, MJ-17B, 19A, 21, 28, 29, 24, 39, 41, 38DIAMOND DRILL HOLE DDH-104, DDH-105

WOLF LAKE PROPERTY

LYDIA DIAMOND EXPLORATION OF CANADA LTD. 0 (1:5000) 2.5km

4952000mN

LOCATION MAP HAND SPECIMENS TD-M M-80,103,107,99

MJ- 8A, 9,12,13,14,15,16DIAMOND DRILL HOLE DDH-100, DDH-101

WOLF LAKE PROPERTY


O (1:5000) 2.5km"

^

—— m r- ^

J? l .ak.r \ * —

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MJ-16-.|MJ-12-i|

f .MM* iHf — J^

TDMM-107*'Ik, j 7

Hole 100 Azimuth: 2700

-450

SOOOOOmE

Mapping Sketch: For Con 3,4 - Lot 5: Tudor Twp. (3 sheets)

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Tudor Property: Geol. And Sample Locations: TDMM149-185(3 sheets)

Mini,

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..•7!}\.'.tti -1;' j3Cm \Pnif

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Lydia Diamond Exploration of Canada Lpd.

Tud o T Pro pe rt yGeology and Sample Locations

Lrp-Mrt - l VI ttr*uekScale 1:2500

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Trench 021A (l sheet)

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a- —— i —— * f "V ————————— - - T --' —— _________________ 1 _____________________ i-—

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ONTARIO MINISTRY OF NORTHERN DEVELOPMENT AND MINES

Work Report Summary

Transaction No: W0390. 01708 Status: APPROVED

Recording Date: 2003-OCT-27 Work Done from: 2001-JUL-19

Approval Date: 2004-FEB-21 to: 2002-DEC-18

Client(s):300883 VONANHALT, PRINZ JURGEN

300933 VON ANHALT, EMILIA PRINCESS

392675 LYDIA DIAMOND EXPLORATION OF CANADA LTD.

Survey Type(s):ASSAY GCHEM

Work Report Details:

Claim*

SO

SO

SO

SO

SO

SO

SO

SO

1167279

1184029

1184030

1195077

1195165

1195178

1195181

1235050

Perform

S492

S164

S2.951

31,640

32,950

S328

31,148

31,312

31 0,985

External Credits:

Perform Approve

3492

3164

32,951

31,640

32,950

3328

31,148

31,312

310,985

SO

Applied

30

3030

30

30

3030

30

SO

Applied Approve

SO

soSO

sosososososo

Assign

SO

sososososo30

30

30

Assign Approve

0

0

0

0

0

0

0

0

so

Reserve

3492

S164

52,951

31,640

32,950

S328

31,148

31,312

310,985

Reserve Approve

3492

3164

S2.951

51,640

52,950

3328

31,148

51,312

310,985

Due Date

2004-JUN-27

2005-JUL-17

2005-JUL-17

2009-DEC-29

2006-MAR-27

2006-MAR-27

2006-MAR-07

2003-DEC-01 E

Reserve:310 ,985 Reserve of Work Report#: W0390.01708

(31 0,985) Applied by W0390.01 826 2003-NOV-20

30 Total Remaining

Status of claim is based on information currently on record.

31C14SW2019 2.26551 GRIMSTHORPE 900

2004-Mar-12 14:38 armstrong-d Page 1 of 1

Ministry ofNorthern Developmentand Mines

Date:2004-MAR-10

Ministere duDeveloppement du Nord et des Mines Ontario

GEOSCIENCE ASSESSMENT OFFICE 933 RAMSEY LAKE ROAD, 6th FLOOR SUDBURY, ONTARIO P3E 6B5

LYDIA DIAMOND EXPLORATION OF CANADA LTD. 8 KING STREET EAST, SUITE 1704 TORONTO, ONTARIO M5C1B5 CANADA

Tel: (888) 415-9845 Fax:(877)670-1555

Dear Sir or Madam

Submission Number: 2.26551 Transaction Number(s): W0390.01708

Subject: Approval of Assessment Work

We have approved your Assessment Work Submission with the above noted Transaction Number(s). The attached Work Report Summary indicates the results of the approval.

At the discretion of the Ministry, the assessment work performed on the mining lands noted in this work report may be subject to inspection and/or investigation at any time.

The revisions outlined in the Notice dated January 7 2004 have for the most part been corrected.Accordingly, assessment work credit has been approved as outlined on the Declaration of Assessment Work Formthat accompanied this submission.

If you have any question regarding this correspondence, please contact BRUCE GATES by email at [email protected] or by phone at (705) 670-5856.

Yours Sincerely,

for Ron C. GashinskiSenior Manager, Mining Lands Section

Cc: Resident Geologist

Robert Allan Macgregor (Agent)

Assessment File Library

Prinz Jurgen Vonanhalt (Claim Holder)

Emilia Princess Von Anhalt (Claim Holder)

Lydia Diamond Exploration Of Canada Ltd. (Claim Holder)

Lydia Diamond Exploration Of Canada Ltd. (Assessment Office)

Visit our website at http://www.gov.on.ca/MNDM/LANDS/mlsmnpge.htm Page: 1 Correspondence 10:19213

ONXASUOCANADA RECORDER1* OFFICE

Mining Land Tenure Map

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UTM Zone 18 5000m grid

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General Information and Limitations

Date t Time of Issue: Wed Mar 10 10:07:35 ESt 2004

TOWNSHIP l AREA PLAN TUDOR M-0156

ADMINISTRATIVE DISTRICTS 7 DIVISIONSMining Division Southern OntarioLand Titles/Registry Division HASTINGSMinistry of Natural Resources District BANCROFT

TOPOGRAPHIC Land Tenure

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LAND TENURE WITHDRAWALS

IMPORTANT NOTICES

LAND TENURE WITHDRAWAL DESCRIPTIONS

FT BURFUCI; *BOWS TEGIflVITt

RES. M.NR. fll-E:

JaHJB, (WU tSCWWSW Eft H

IMPORTANT NOTICES

ME CONTACT THE APPRCPfBtTI UM3 IWOI

2.26551 ASSAY GCHEM

Documents

Report On XRF Analysis of Samples Grimsthorpe and Tudor ...€¦ · Report On XRF Analysis of Samples Grimsthorpe and Tudor Townships, Ontario For Lydia Diamond Exploration of Canada