Sample Copy. Not for Distribution. · decided to share our notes which we had made from different sources,modules of different institution and from different books in a SINGLE BOOK

Sample Copy. Not for Distribution.

i

RS ORGANIC CHEMISTRY

@ YOUR FINGERTIPS


ii

Publishing-in-support-of,

EDUCREATION PUBLISHING

RZ 94, Sector - 6, Dwarka, New Delhi - 110075

Shubham Vihar, Mangla, Bilaspur, Chhattisgarh - 495001

Website: www.educreation.in

________________________________________________________________

© Copyright, Authors

All rights reserved. No part of this book may be reproduced, stored in a retrieval system, or transmitted, in any form by any means, electronic, mechanical, magnetic, optical, chemical, manual, photocopying, recording or otherwise, without the prior written consent of its writer.

ISBN: 978-1-5457-0848-4

Price: Rs.486.00

The opinions/ contents expressed in this book are solely of the authors and do not represent the opinions/ standings/ thoughts of Educreation or the Editors .The book is released by using the services of self-publishing house.

Printed in India


iii

RS ORGANIC CHEMISTRY

@YOUR FINGERTIPS A Complete Quide And Solution For

MEDICAL AND ENGINEERING ENTRANCE EXAM

Written By-

Rumana Fatima

Written AND Edited By-

Kamran Ahmad

AND

A TEAM OF IDEOVATE ONLINE STUDY GROUP (IOSG)

EDUCREATION PUBLISHING (Since 2011)

www.educreation.in


http://www.educreation.in/

iv

IOSG GROUP-

1. KAMRAN AHMAD (Co-Founder) 2. ASHISH ARMAN 3. TARUNAY SINHA 4. Dr. SHOAIB 5. UZMA ISLAM 6. Dr. SIMRAN KHAN 7. Er. ANJALI CHATURVEDI 8. RUMANA FATIMA (Co-Founder)

SPECIAL THANKS TO- 1. DR. Zeenat Kaifi (Scholar Of JNU Delhi) 2. Er. Fatima Ahmad (Graduated From IIT Delhi) 3. Sadaf Ahmad (MBBS)

ADVANCE THANKS TO-

1. ROMAN SAINI (IAS, AIIMS Graduated)

2. Dr. Anand Rai (Whistleblower-Vyapam Scam ; Opthalmologist)


v

YOU CAN FOLLOW US FOR GIVING

FEEDBACK AND SUGGESTION

Twitter- Rumana Fatima @su8260 AND

Kamran Ahmad @i_kamranahmad

Instagram –i.m.ru AND i.m.kamran_ahmad

FB PAGE– IDEOVATE OLINE STUDY GROUP

GMAIL – [email protected]

For BULK order i.e more than 50 book

And Distributor‘s enquiry. Mail on above given gmail.


vi

Dedicated To

Our Parents

And Also

To Our Grandparents

For Thier Love Respect And Prayer

A Special Thanx To Our Brother.


vii

Acknowledgment

―Learning gives creativity,creativity leads to thinking,thinking

provide knowledge,knowledge makes you great‖.This is a famous

quote by our beloved and most respected President,The 11th

president of our country-DR APJ ABDUL KALAM who have

inspired millions of youth and students.So,We would like to thanks

him from internal core of heart. We also like to thanks Zeenat

(aapi)- A PhD Scholar from JNU and ESPECIAL thanks to Farhan

Ahmad.

We would also like to thanks Aman Verma , Anam Fatima

and Ashish Arman for their help AND special thanks to

EDUCREATION.

At last we would like to thanks our PUBLISHER Ms Shradha

and her team mate for immense effort for giving final shape of our

book.We also like to thank typewriter who typed for us AND

ESPECIAL to thanks to all my friends and juniors (Afreen

Pervin,Abhilasha,Uzma Islam,Ashish Arman,Tarunay Lavange

and Saransh Kumar) who made easy path for us to publish edit and

distribute the book.


viii

Preface

The idea of writing book came when we were individually

preparing for the entrance exam and not satisfied with the way

Teacher or INSTITUTION used to teach.

After some time when we meet different juniors,friends and

classmate they all had similar story regarding this issue.So,we than

decided to share our notes which we had made from different

sources,modules of different institution and from different books in

a SINGLE BOOK in form of e book and paperback.This is how we

came up with the book-―RS ORGANIC CHEMISTRY @ YOUR

FINGERTIPS‖- a complete guide of organic chemistry for

various entrance exam.

If you RELY on this book,we can assure you Organic Chem

will as easy as possible along with ‗CLEAR CRYSTAL

COCNCEPT‘.At last i would like quote few words of Bahadur

Shah Zaffar so that all aspirant may get motivated when they open

this book.

― In hasratoun ko keh do khi aur ja bashai,

Itni jageh nhi Dil-e-dag dar m,

Mang k layai thai char din ,

Do arzu m kat gye do intezar m”


ix

Sailent Features

Concept Covered with for every single topic.

Cocise Theory

Collection of concept based solved question asked in

different entrance.

Cocncept is dealt in every Ques which seems to be

necessary.

Key Point,Note and Fact is mentioned under seprate box.

Clear Crysral Concept is dealt with ques which is termed as

„CCC‟. And Concept Building Question (CBQ) is dealt

Tricks for solving question.

Tips and Review for imp topic.

80%-90% ques has came from the CONCEPT of this book

in various exam such as NEET, JEE MAINS, AIIMS,

JIPMER .AND55%-60% ques has came in IIT (JEE

ADVANCE).

From RESONANCE TOPIC to REST TOPIC of this book

which is V.Imp is dealt with CONCEPT IN EVERY

SINGLE OPTION and TRICK for solving ques i.e which

concept is to be used in every option and what is trick

which can save time in exam.

We have only written this book with a view that average and

student who can‘t afford institute can get maximum benefit.As

coaching institute not just EFFECTIVE for entrance now a days .

AND also to prevent students from getting misguided from

large number of refrence available in market.


x

How To Start Preperation

Before Starting preparation you (students) just need to

about the pattern of exam ,syllabus and everything useful

thing which will help you in preparation of smooth flow for

exam.

As Syllabus is too big so it needs SMART

PREPERATION.SMART PREPERATION means By

studying least possible book you can afford maximum

marks possible in entrance.

BOOKS TO BE AVOIDED

MEDICAL ASPIRANT

PHYSICS – HC Verma, DC Pandey, Walker, SL Arora,

ERODOF and all this kind of book.

CHEMISTRY –Modern ABC ,Pradeep, Dinesh ,Organic

Chemistry by Robert Thornton,Solomons and Fryhle AND by

Peter Skyes.

Instead of reading all these book of organic chemistry ,RELY

on my organic chemistry book – Organic Chemistry with

Concept and Trick.this will help you for better score.

BIOLOGY- All book EXCEPT NCERT.Presonally, We have

went through all these book during preparation and found

worthless and just waste of time for ENTRANCE exam as you

have to give ENTRANCE EXAM –NEET and you need not have

write PhD thesis.

BOOKS AND REFERENCE TO BE USED

PHYSICS – NCERT must + Class notes + package is sufficient

If you (students) want us to share our notes of PHYSICS than

give us feedback on gmail or website.

CHEMISTRY – NCERT must+ Class notes + package AND for

ORGANIC CHEM – our book ―RS ORGANIC CHEMISTRY @

YOUR FINGERTIPS‖ is best as it is collection of different book.


xi

BIOLOGY – NCERT must (only) + if you want reference than

you can prefer RAHUL CHAWLA‘s book.

Imp Fact of exam –

NEET-

BIO- 90% ques comes from NCERT.

CHEM- 80% ques from NCERT + 80%-90% ORGANIC CHEM

Ques will come from CONCEPT of this book.

PHY- no fix % from any book BUT more or less ques is Easy and

concept based i.e 80% ques there is no mixing Of 2 concept in

single ques.

AIIMS-

BIO- 70% ques comes from NCERT

CHEM- 60%-65% ques comes from NCERT and 70-75% ques of

ORGANIC CHEM will come from the CONCEPT of this book.

PHY- little Tougher compared to NEET as there is mixing of

concept in one single ques which is asked.

For Assertion and Reason you must have to read NCERT book

as it is directly or indirectly from NCERT only-there is no

substitute for this.

Solve all 3 sub NCERT book‘ss ques.(imp for clear crystal

concept)

Practise as much as possible.

Concept should be CLEAR CRYSTAL – basic need for

qualifying exam.


xii

Contents

S. No. Title Page

1. Important Table 1

2. Important Reagent and Name Reaction 13

3. Nomenclature 28

4. Isomerism 44

5. Tautomerism 54

6. Geometrical Isomerism 60

7. Optical Isomerism 69

8. Resonance 105

9. Effect of Chemistry (I/ M effect etc) 136

10. Reaction Mechanism 183

11. Naming Reaction 285

12. Review for student 306

NOTE-


1 | R S O R G A N I C C H E M I S T R Y @ Y O U R F I N G E R T I P S

Important Tables

1

PRIORITY OF SOME FUNCTIONAL GROUP

Functional

Grp Trick Prefix Name

Suffix

Name

-COOH Car Carboxy oic Acid

-SO3H Sulpho Sulph Sulphonic

Acid

-CO O CO Water loss Acid Anhydride oic

anyhdrdide

-COOR east Alkoxy carbonyl Oate

-COX oil Helo carbonyl oyl halide

-CONH2 Mobil oil Carbamoyl Amide

-CN Cy Cyano Nitrile

-NC I Isocyano Isonitrile

-CHO Al Formyl Al

-C O Ke Keto /oxo One

-OH ol hydroxy Ol

-SH Thio mercapto Thiol

-NH2 aim Amino Amine

-OR ? Alkoxy Alkoxy

Er Epoxy Epoxy

C C C=C ene Ene

C C CC yne Yne

N2 Azi Azo Azo

NO2 night Nitro Nitro

NO so Nitroso Nitroso

X helo Helo Chloro


R u m a n a F a t i m a , K a m r a n A h m a d | 2

Trick For Remembering Table-

One man is driving Car and found no Sulphur in car due to this

Water loss began .He travelled to Eastand tookOil and Mobil oil.

Some body asked him in other language What is your aim

(CyAlKeOl, thio (tmhara) aim? ). He replied Engineer. Work of

engineer is to build home. Therefore He will build first two storey

building (C=C) than three storey (C C).After returning home he

wanted to have chat with wife but she refused and told Azi Night

,So (sleep). He told Helo listen.

Water loss- Acid anhydride


Important Tables

3 | R S O R G A N I C C H E M I S T R Y @ Y O U R F I N G E R T I P S

FEW IMPORTANT TABLE IN SUMMARY FORM

STRUCTURAL FORMULA IUPAC NAME

CH3- Methyl

CH3-CH2- or C2H5- Ethyl

CH3-CH2-CH2- or C3H7- Propyl

CH3-CH2-CH2-CH2- or C4H9- Butyl

CH3-CH-CH3

Isopropyl

CH3

CH3-CH-CH2-

Isobutyl group

Sec. butyl group

Tertiary butyl group

Isopentyl group

Neopentyl group

Tetiary pentyl group

Isohexyl group


Get Complete Book At Educreation Store

www.educreation.in



Documents

Sample Copy. Not for Distribution. · decided to share our notes which we had made from different sources,modules of different institution and from different books in a SINGLE BOOK