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SolsticeTM LGWP Impact, High Efficiency Blowing Agents
Commercialization Update
BKK, Jun 2013
Agenda
• Honeywell Low-GWP Product Portfolio
• SolsticeTM LBA Commercialization Updates
- Safety, Environmental Property & Energy Efficiency
- Commercial Trials: Appliance, Spray & Panel
- Commercialization Progress
- Global Registration Status
2
- Global Registration Status
- Supply Availability
• SolsticeTM GBA Commercialization Updates
- Safety, Environmental Property & Insulation Performance
- Commercialization Progress
- Global Registration Status
- Supply Availability
Low Global Warming Options from Honeywell
HONEYWELL OPTIONS
ApplicationsLow Global Warming
ProductsGWP100
Foams
SolsticeTM LBA <5
SolsticeTM GBA <6
SolsticeTM L-41 <500
3
Refrigerants
SolsticeTM L-41 <500
SolsticeTM L-40 200-300
Solvents SolsticeTM Performance Fluid <5
Aerosols SolsticeTM Propellant <6
Low GWP Solutions for Foam, Refrigerant, Solvent, Aerosols
Sustainable Solutions for Foam Applications
Solstice™LBA
GWP <5Non-ODP
VOC-Exempt*Non-Flammable
Solstice™GBA
GWP <6Non-ODP
VOC-Exempt*Non-Flammable
Refrigerator / Freezer
Insulated Metal Panels
Extruded Polystyrene
4
Solstice™ LBA and GBA: Sustainable Solutions for Foam Applications
Non-Flammable Non-Flammable
Replaces:245fa, 365mfc,
141b, HC
Replaces:22, 142b, HC,141b, 134a
Spray Foam
One Component Foam
* US EPA VOC Exemption
SolsticeTM Liquid Blowing Agent
Global Commercialization Updates for PU Foam
< 5
1,430
1,030
725
<25
Safe for Users and the Environment
SolsticeTM
LBA134a245fa141bCP
Lifetime (yrs)
VeryShort-lived
Low GlobalWarming
0.1
13.0
7.69.3
Global Warming
Potential (GWP)
SolsticeTM
LBA134a245fa141bCP
6
LBA
• Cyclopentane
• 365mfc
FLAMMABLE NOT FLAMMABLE
• 141b
• 245fa
• 134a
• SolsticeTM LBA
• Cyclopentane
VOC NOT VOC
• 141b
• 245fa
• 134a
• 365mfc
• SolsticeTM LBA*
LBA
Higher Cost/RiskPermitting Issue
Higher Cost
Superior Safety and Environmental Performance
*VOC Exemption pending EPA approval
SolsticeTM LBA – More Energy Efficient
• In refrigerator trials, SolsticeTM
LBA saves costs:
– 10-12% more efficient than
cyclopentane
– 2% more efficient than 245fa
• Results proven with major
OEMs in US, China, Japan,
% Energy Efficiency Change of
Refrigerator1
Baseline(245fa)
2%
Solstice™Liquid Blowing Agent
7
OEMs in US, China, Japan, Korea, Europe, M. East , Japan
• Similar performance for spray and other PU foams – trials
conducted in global
1) Commercial refrigerator trials; unoptimized formulation of
Solstice LBA; Cyclopentane vs. 245fa from AHAM trials
8-10%
Hydrocarbon(Cyclopentane)
Lowest Cost Option for Meeting Stringent Efficiency Standards
SolsticeTM LBA Versus 141b in Spray Foam
Initial Thermal Conductivity (Lambda)
19.0
19.2
19.4
19.6
19.8
20.0
La
mb
da
, m
W/m
K
• SolsticeTM LBA saves
costs:
– 2-4% more energy
efficient than 245fa
– Improved blowing
efficiency
– Wider application
window
Lower is
Better
8
SolsticeTM LBA Shows Superior Performance to 141b and 245fa
18.0
18.2
18.4
18.6
18.8
19.0
141b 245fa Solstice LBA
La
mb
da
, m
W/m
K
window
– Initial results show
better yields and
improved
compressive
strengths
18
19
20
21
22
23
5 10 15 20 25 30
K-f
acto
r, m
W/m
. K
Mean Temp. °C
141B
LBA
Cyclopentane
Thermal conductivity
SolsticeTM LBA Trials for Refrigerated Container
9
0
50
100
150
200
250
300
141B LBA Cyclopentane
Co
mp
ressio
n,
KP
a
// ┴ ┴
Compressive Strength
No Sacrifice of Performance When Phase-out 141b
Global Evaluation of SolsticeTM LBA Underway
JapanIndia
UK
EUUSA
Canada
TurkeyS. Korea
10
Home Appliance
Globally Programs and Successful Trials for Multiple Applications
Japan
China
Philippines
India
DubaiSouth
America
Spray Foam Insulated Panel
N. Zealand
Commercialization Progress
• Appliance:- Whirlpool North America adoption starting in 2013
- Numerous successful trials with OEMs globally
• Spray Foam:- Commercial systems available in Japan; successful trials in
Philippines
- US System Houses commercializing foam systems
11
- US System Houses commercializing foam systems
- Foam meets current code requirements
- Engaging more system house and industry association globally
• Panel:- Successful trials in Europe and the US
- Successful trials in refrigerated containers in China
Multiple Applications Being Developed Globally
Global Registration Status
• US EPA approval for commercial sales (PMN and SNAP)- On SNAP list as suitable alternative to ozone depleting substances
• Japan: On inventory, no restriction on commercial sales
• S. Korea: On inventory, can be sold commercially
• Australia / New Zealand: Registration process underway
• China: - Commercial sales permitted to 10MT
12
- Commercial sales permitted to 10MT
- Level 4 notification filed in May 2013
• EU:- Commercial sales permitted to 10MT
- REACH >1,000 MT application will be filed 2013
Broad Regulatory Approvals being Secured
Supply Availability
• 2013 Availability: Semi-Commercial supply- Global trials
- Initial commercialization in Spray and Appliance
• 2014 Availability: Commercial quantities available beginning in Q2
13
• 2015 and Beyond- Built additional capacity globally as demand grows
- Locations to be determined by regional demands
Commercialization on Track
SolsticeTM Gas Blowing Agent
Global Commercialization Updates for XPS
Safe for Users and the Environment
GWP (100 year horizon)
<615140
1,430
1
134a 152a SoslticeTMCO2
Low Global
Warming
Iso-butane
15
Offers Best Balance of Environmental Performance & Safety
GBA
• Iso-butane
• 152a
Flammability POCP
FLAMMABLE NOT FLAMMABLE
• CO2
• 134a
• SolsticeTM GBA
• Iso-butane
High POCP Low POCP
• CO2
• 134a
• 152a
• SolsticeTM GBA
butane
Thermal Insulation Foam Performance
XPS Long Term Insulation Lambda Performance
mW
m-1
K-1
~29~31
34-38
~27 - 29
20
30
40
• Production scale extrusion , Solstice GBA demonstrates:
– ‘Good’ foamed XPS planks: thermally and mechanically
– Lambda (Insulation): 20-25% improvement to CO2 and similar to HCFC-142b & HFC-134a
Comments
LOWER IS MORE ENERGY EFFICIENT
16
λ∗
,m
W
0
10
20
HFC 134a HFC 152a CO2 HFO 1234ze
– Capability to extrude thick foam, unlike CO2
– Capability to extrude low density foam
– Compressive strength similar to HFC-134a
– Dimensional stability similar to HFC-134a
* As per EN 13164 Annex C
20-25% Better Insulation Performance Than CO2 Blown XPS
SolsticeTM
GBA
Jackon Adopting Solstice GBA since 2011
Jackodur Pλus XPS boards
•Lambda of 27* mW/m-K for building
construction applications
•Lambda of 25* mw/m-K for industrial
fabrication applications (e.g. truck
17
Jackodur Pλus Boards Commercially Available Since 2011
bodies, mobile-home elements)
•GWP < 6
Solstice GBA Registration Status
European Union• REACH –Solstice GBA: Registered under REACH (article 24) to
1000+ tones
Japan• Registration complete
18
United States• Pre-Manufacture Notification (PMN): Complete
- TSCA Inventory Listing
• SNAP (Significant New Alternatives Policy) Application: Complete
- On SNAP list as suitable alternative to ozone depleting substances
Solstice GBA is Notified for Importation into EU & Japan / Commercial in US
Supply Availability
• 2013 Availability: Supply from Semi-Commercial pilot plant- Tripled production capacity
- Commercial volumes already being supplied to customers in EU, US, Japan for XPS, aerosol applications
• 2014 and Beyond-
19
- New plant being built in Louisiana USA, to be commissioned in 2014
- Plant will supply commercial volumes of 1234ze globally
Commercialization on Track
Summary
• Honeywell has high performance, sustainable solutions for multiple foam applications
- SolsticeTM Liquid Blowing Agent
- SolsticeTM Gas Blowing Agent
• Both have strong environmental properties
- Ultra-low GWP, non-ODP, VOC-exempt, non-flammable
• Both are commercially available today
20
- Today: Large “semi-commercial” plants
- Early 2014: World class, large scale plants
• Both are registered globally
- Solstice LBA, current registrations: US, Japan, Canada, Mexico, Brazil, S. Korea, others
- Solstice LBA, registrations in Process: EU, China, Australia, Philippines, New Zealand
- Solstice GBA: Registered in US, EU, Canada, Japan, China, Australia and S. Korea
Solutions Exist Today to Meet Higher Energy Standards While Improving Environmental Sustainability
www.honeywell.com
21
www.honeywell.com
DISCLAIMER
Although all statements and information contained herein are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind,
expressed or implied. Information provided herein does not relieve the user from the responsibility of carrying out its own tests and experiments, and the user
assumes all risks and liability for use of the information and results obtained. Statements or suggestions concerning the use of materials and processes are made
without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe on any patents. The user should not
assume that all toxicity data and safety measures are indicated herein or that other measures may not be required.