SPE93374_Performance Analysis of Compositional and Modified Black Oil Models for Rich Gas Condensate Reservoir

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  • 8/11/2019 SPE93374_Performance Analysis of Compositional and Modified Black Oil Models for Rich Gas Condensate Reservoir

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    SPE 93374

    Performance Analysis of Compositional and Modified Black-Oil Models for a Rich GasCondensate ReservoirB. Izgec and M.A. Barrufet, Texas A&M U.

    Copyright 2005, Society of Petroleum Engineers Inc.

    This paper was prepared for presentation at the 2005 SPE Western Regional Meeting held inIrvine, CA, U.S.A., 30 March 1 April 2005.

    This paper was selected for presentation by an SPE Program Committee following review ofinformation contained in a proposal submitted by the author(s). Contents of the paper, aspresented, have not been reviewed by the Society of Petroleum Engineers and are subject tocorrection by the author(s). The material, as presented, does not necessarily reflect anyposition of the Society of Petroleum Engineers, its officers, or members. Papers presented atSPE meetings are subject to publication review by Editorial Committees of the Society ofPetroleum Engineers. Electronic reproduction, distribution, or storage of any part of this paperfor commercial purposes without the written consent of the Society of Petroleum Engineers isprohibited. Permission to reproduce in print is restricted to a proposal of not more than 300words; illustrations may not be copied. The proposal must contain conspicuousacknowledgment of where and by whom the paper was presented. Write Librarian, SPE, P.O.Box 833836, Richardson, TX 75083-3836, U.S.A., fax 01-972-952-9435.

    Abst ractThe modified black-oil model (MBO) was tested against the

    fully compositional model and performances of both models

    were compared using various production and injectionscenarios for a rich gas condensate reservoir.

    We evaluated the performance of MBO model by

    investigating: the effects of black-oil PVT table generation

    methods from a tuned equation-of-state, oil-gas ratio (OGR)

    and saturation pressure versus depth as initialization methods,

    uniform composition versus compositional gradient withdepth, location of the completions, production and injection

    rates, kv/khratios, and vertical wells versus horizontal wells.Contrary to the common belief that OGR versus depth

    initialization gives better representation of original fluids in

    place, initializations with saturation pressure versus depth

    gave closer original fluids in place considering the true initialfluids in place are given by the fully compositional model

    initialized with compositional gradient.

    Unrealistic vaporization in the MBO model was

    encountered in both, production by natural depletion and gas

    cycling. The changes in oil-gas ratio of the recyled gas showedthat, it is not possible to accurately represent the changing

    PVT properties of the recycled gas with a single PVT table.Unrealistic vaporization also led to different arrival times forthe displacement fronts and different saturation profiles for the

    near wellbore area and for the entire reservoir for the two

    models even though the production performance of the models

    was in good agreement.The MBO model representation of compositional

    phenomena for a gas condensate reservoir proved to be

    adequate for full pressure maintenance, reduced vertical

    communication, vertical well with upper completions, and forhorizontal well producers.

    IntroductionBlack-oil simulators represent a high percentage of al

    simulation applications and they can model immiscible flowunder conditions such that fluid properties can be treated as

    functions of pressure only.

    However, gas condensate reservoirs exhibit a complexthermodynamic behavior that cannot be described by simple

    pressure dependent functional relations. Compositions changecontinuously during production by natural depletion, or by

    cycling above and below dew point pressures.

    In another black-oil modeling approach reservoir fluidconsists of a gas component and vaporized oil which allows

    the use of a simple and less expensive model.

    According to this modified black-oil approach liquid

    condenses from a condensate gas by retrograde condensationwhen the pressure is reduced isothermally from the dew point

    and retrograde liquid is vaporized by dry gas.Coats1 presented radial well simulations of a gas

    condensate that showed a modified black-oil PVT formulation

    giving the same results as a fully compositional EOS PVT

    formulation for natural depletion above and below dew point

    Under certain conditions, he found that the modified black-oimodel could reproduce the results of compositional simulation

    for cycling above the dew point. For cycling below the dew

    point, the two-component simulation gave results that were

    quite inaccurate.According to Fevang and Whitson2, results from Coats

    example should be used with caution as EOS characterization

    uses seven components with one C7+ fraction. With a moredetailed C7+ split, oil viscosity differences between black-oi

    and compositional formulations often yield noticeable

    differences in well deliverability.

    Fevang et al.3 obtained results which mostly support the

    conclusions by Coats.1However, they found differences in oi

    recoveries predicted by compositional and MBO models whenthe reservoir is a very rich gas condensate and has increasing

    permeability downwards. According to their final conclusionsa black oil simulator may be adequate where the effect of

    gravity is negligible, and for gas injection studies black oil

    model can only be used for lean to medium-rich gascondensate reservoirs undergoing cycling above dew point.

    El-Banbi and McCain4, 5suggested that the MBO approach

    could be used regardless of the complexity of the fluid. Their

    paper presented the results of a full field simulation study for a

    rich gas condensate reservoir. The MBO models performance

    was compared with the performance of a compositional mode

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    in the presence of water influx and also a field wide history

    match study was conducted for above and below the dew

    point. Their paper presents an accurate match of averagereservoir pressure and water production rates. However gas-oil

    ratio and condensate saturation plots were not provided and

    initial condensate production rates do not represent a clear

    match for 500 days.

    For the present study a representative gas condensate fluidwas selected and a fluid model was built by calibrating the

    EOS to the available experimental data, which consisted ofconstant composition expansion (CCE) with relative volume,

    liquid saturations and gas density values.

    By using the calibrated EOS black-oil PVT tables were

    generated for MBO model using Whitson and Torp6 and

    Coats1methods.

    The compositional model was run either with

    compositional gradient or with uniform composition. The

    compositional gradient in MBO model was given by depth

    variation of OGR (Rv) and GOR (Rs) or saturation pressureversus depth tables.

    Initially there was a discrepancy in saturation pressureswith depth in the MBO model which resulted in earlier

    condensation and lower oil production rates whether it was

    initialized with GOR / OGR or saturation pressure versus

    depth tables.

    For natural depletion cases as the reservoir gas becomes

    leaner during production, the initial differences between themodels, due to saturation pressure changes with depth

    disappear and a better match was obtained, especially for the

    poor vertical communication.For the gas cycling cases the models were in good

    agreement as long as the reservoir was produced with rates

    high enough to minimize condensation. If the MBO model isinitialized with compositional gradient, lower production and

    injection rates and bottom completions created differencesbetween the performances of the models.

    Almost all the cases showed differences in condensate

    saturation distribution around the wellbore area and the entirereservoir. The minimum difference between the models is 5 %

    in terms of average field oil saturation and this was obtained

    for a high rate gas injection case combined with reducedvertical communication.

    However, the saturation differences between models

    depend on the case and the time interval studied. As an

    example, for gas injection with bottom completions, at 1000days, the condensate saturation difference between the two

    models was as high as 60 % although they converged to a

    close value at the end of the simulation.In MBO model, the runs with horizontal wells exhibited

    closer performances with compositional model compared tothe runs with vertical wells.

    The changes in oil-gas ratio of the cycling gas showed that,

    it is not possible to accurately represent the changing PVTproperties of recycled gas with a single PVT table in the MBO

    model since every time the produced gas passes through the

    separators and is injected back into the reservoir its oil-gasratio and accordingly vaporization characteristics changes.

    Fluid CharacterizationThe fluid selected for the study is a rich gas condensate taken

    from Cusiana Field in Colombia.A compositional analysis with hydrocarbon components

    that includes a heavy fraction of C30+, a set of experimenta

    data obtained from a constant composition expansion and a

    separator test were used to characterize the fluid. Table 1

    presents the extended compositional description of the fluid.Following the procedure proposed by Whitson6, where the

    groups are separated by molecular weight we used sixpseudocomponents and one non-hydrocarbon, CO2. The

    pseudocomponents were defined as two pseudo-gases, GRP1

    and GRP2, one gasoline group, GRP3 and three heavy

    pseudocomponents, GRP4, GRP5 and GRP6. For the purpose

    of CO2injection, this component was kept as a separate groupThe corresponding components for each pseudo componen

    and the final molar compositions are given in Table 2.

    Once the pseudocomponents were defined we proceeded

    with the EOS tuning process. The variables used as regressionparameters were binary interaction coefficients, and shif

    factors for selected groups. The final values for these variablesare presented in Table 3-4. Binary interaction coefficients

    values after tuning are presented in Table 5.

    Four parameter Peng-Robinson EOS was selected and

    tuned to the data obtained from the constant composition

    expansion at 254F, which includes the liquid saturation, gas

    density and the relative volume. Figs. 1 through3illustrate the

    match between the experimental and the simulated data.

    Black-Oil PVT Table GenerationBlack-oil PVT properties in this study have been generatedwith an EOS model using the Whitson and Torp7procedure

    Coats1 developed another black-oil PVT table generation

    method. Instead of flashing the equilibrium liquid and vapor

    compositions separately to obtain Bo, Rs, Bg, Rv directly asindicated by Whitson and Torp, Coats determines only one ofthese properties Rv, from flash separation and determines the

    remaining three using equations that force the PVT properties

    to satisfy mass conservation equations and yield correct

    reservoir liquid density. In determining Rv from the surfaceseparation at each CVD pressure step Coats uses the surface

    oil and gas molecular weights and densities obtained from the

    separation of the original fluid mixture.McVay8 found better agreement between compositiona

    and MBO simulations models if the surface oil, gas molecular

    weights and densities are obtained from the separation of the

    mixture at each CVD pressure step to calculate Rv at each

    pressure. Also by using Coats method it is not possible toobtain the PVT properties of the liquid phase at the saturation

    pressure. Coats defined the first CVD pressure step to be 0.1

    or 1 psi below the saturation pressure and used the values

    calculated at this pressure as the PVT properties at thesaturation pressure. Standard extrapolation of sub-dew poin

    properties to dew point can lead to situations where the oil hasnon-physical negative compressibility.

    Figs. 4 through 9 give the saturated oil, and gas PVT

    properties obtained by Whitson and Torp and Coats methods

    Notice that gas formation volume factors at lower pressure

    values are quite different for the two methods.

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    Coats method was not preferred for this study since it

    created convergence problems in MBO model and the run was

    automatically terminated due to number of errors encountered.

    Initialization MethodsTo obtain the correct and consistent initial fluids in place for

    black-oil and compositional models it is important to initialize

    the models properly. The initial reservoir fluid composition iseither constant with depth or shows a vertical compositional

    gradient where the effect of gravity is not negligible.Depending on the type of the reservoir fluid, the model should

    be initialized either with solution GOR/ OGR versus depth or

    saturation pressure versus depth to minimize the errors for

    initial fluids in place.

    Although initialization with saturation pressure versusdepth gives more accurate representation of fluids in place, at

    the bottom of the reservoir where the amount of heavy fraction

    increases, this initialization method provided higher

    condensate saturations, especially for the gas cycling cases,compared to the MBO model initialized with GOR/OGR

    versus depth and the compositional model.

    Constant Composition with Depth. For the constant

    composition case modified black-oil model was initialized

    with either solution oil-gas ratio versus depth or saturation

    pressure versus depth tables, which correspond to the

    composition at a reference depth of 12,800 ft.The constant composition case was only run for the natural

    depletion to show that initialization methods do not affect the

    performance of the MBO model if compositional gradient isnot used and identical pressure, oil-gas ratio, recovery factor

    and saturation plots can be obtained.

    Also if the effect of gravity is negligible, both initializationmethods give the same initial fluids in place. The error in

    initial fluids in place is calculated as 4 % for both initializationmethods. Table 6 shows the oil in places values for

    compositional and MBO models initialized with two different

    methods for the unifom composition case.

    Compositional Gradient. Variation of the composition of C1-

    N2 and C7+ with depth is presented in Figs. 10 and 11.

    Corespondingly MBO model was initialized with solution gas-

    oil and oil-gas ratio versus depth tables and saturation pressure

    versus depth tables to investigate the effects of different

    initialization methods. Table 7shows that when the black-oilmodel was initialized with saturation pressure versus depth, a

    better representation of initial fluids in place could be

    obtained. The error in initial fluids in place can be as low as 2% with saturation pressure initialization. With the use of

    compositional gradient, different initialization methodsexhibited different initial fluids in place values.

    Numerical SimulationA quarter of a 5-spot model with the description of a real gas

    condensate fluid system was scaled to represent the entire

    field. The top of the model is at 12,540 ft with an initialpressure of 5,868 psia at a reference depth of 12,800 ft. The

    gas water contact is at 12,950 ft. The 359 ft total thickness is

    represented by 18 layers having different porosity and

    permeability values. Table 8 gives the thickness, porosity and

    permeability values for each layer.

    The injector and producer wells are located on the oppositecorners of the model. The producer operates under the

    constraint of a fixed gas production rate of 3,000 Mscf/D unti

    the minimum bottomhole pressure is reached. For the gas

    cycling cases the optimum injection rate was chosen to be

    2,500 Mscf/D and a three separators having 500, 30, 15 psiapressure and correspondingly 180, 150, 80 oF temperature

    increments, were used on the surface.

    Natural DepletionInitially a discrepancy in saturation pressures versus depth was

    observed in MBO model for both uniform composition and

    compositional grading with depth cases. The differences insaturation pressures versus depth for uniform and

    compositional gradient initialization methods are given in Fig

    12 and Fig. 13. The second figure shows that error in

    saturation pressures increases with depth when thecompositional gradient is used.

    The differences in saturation pressures resulted in earliercondensation and lower oil production rates in MBO mode

    initialized with oil-gas ratio versus depth. On the other hand

    saturation pressure versus depth table initialization made the

    model more sensitive to pressure drop in the reservoir and the

    model exhibited more condensate drop-out and higher oil

    production rates at early times. However, it was observed thatthe error in saturation pressure versus depth had a little impac

    on the production performance and recoveries and it

    diminished as the reservoir was depleted.Oil production rate and the average field pressure for both

    models are given by Fig. 14 andFig. 15.MBO model exhibits

    slightly higher-pressures initially since early condensate dropout and accumulation around the wellbore reduces relative

    permeability to gas and slows down the gas production and aswell as the pressure drop in the reservoir.

    According to Fig. 16 andFig. 17 the effect of initialization

    method on the performance of the MBO model is lesspronounced if the composition is not changing with depth.

    Fig. 18 shows the comparison of two different

    initialization methods for average saturation in each model. Byobserving the oil saturation values below critical saturation

    that is 0.24, it can be concluded that a reduction in oi

    saturation above this value is due to mobilization of liquid

    phase and a reduction in oil saturation below this value is dueto revaporization. The liquid holding tendency of the gas in

    modified black-oil model is dependent on the pressure. The

    oil-gas ratio plot generated by the EOS determines therevaporization process in MBO model and this allows gas to

    pick-up oil until it reaches to the value determined by the PVTtable. The tabulated values of oil-gas ratios at lower pressures

    are very small. Accordingly the presence of more gas would

    have caused excess amount of revaporization in MBO modeas will be seen gas cycling case.

    The oil saturation distribution at the end of the simulation

    time is given by Fig. 19 andFig. 20. In compositional modean additional condensate bank away from the producer is

    observed. The same bank cannot be observed in the MBO

    model. The wells are completed in the first nine layers and the

    drainage of the fluids is faster from these layers in relation to

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    completions and their higher permeability values. At the top of

    the reservoir even though the gas is not as rich as in the

    bottom layers because of compositional grading, condensationis still more effective due to faster drainage. At some distance

    away from the producer, closer to the top of the reservoir

    where no flow boundary conditions dominate, quick drainage,

    pressure drop and lack of pressure support from the

    neighboring layers in the region may form this kind ofbanking. If the injector well is completed inside this

    additional bank or outside the bank but in the lower layers, itwill only be effective around the near wellbore region and

    production from top layers will be negatively affected. The

    size of the bank in the case of uniform composition is much

    larger as can be seen in Fig. 21 since the percentage of heavy

    components in the upper layers increases when the uniformcomposition is assumed.

    For the natural depletion case two types of runs were

    conducted to investigate the effect of completions. The first

    one with the well completed in the first two layers and thesecond with the well completed in the last two layers. For the

    two runs conducted average field pressure, oil production rate,saturation and gas-oil ratio comparison plots exhibited exactly

    the same patterns as the previous examples. The differences in

    recovery factors between compositional and MBO models for

    upper and lower completions are given as 4 % and 7 % at the

    end of the simulation time. The effect of the location of the

    completions on the production performance is morepronounced for gas cycling cases and will be further

    investigated in this section.

    Gas CyclingTo investigate the effect of different parameters on

    revaporization process, the producer is completed in the topnine layers and the injector is completed in the bottom nine

    layers for all the cases except, the cases including theinvestigation of the effects of completion locations. By doing

    so the bottom layers with high permeability and higher heavy

    fractions are open to flow and also consequent channelingwith revaporization is expected to be maximized. Production

    and injection rates are 3,000 and 2,500 Mscf/day.

    Compositional model has the produced gas as injection gas,which gets leaner with time by passing through the three-stage

    separator system and MBO model has the regular gas phase

    option as an injection gas. The injected gas behavior in MBO

    follows the gas PVT table characteristics obtained by Whitsonand Torp6method.

    In compositional model the revaporization process begins

    with the lighter ends of the oil and proceeds slowly with timesince the stripping of the liquid components is in inverse

    proportion to their molecular weight. In MBO model the oiluptake of the injected gas is only a function of pressure which,

    results in excess amount of revaporization. According to Fig.

    22 andFig. 23 higher pressure dependent vaporization leavesless oil in the reservoir giving slightly higher oil production

    rates for MBO model towards the end of the simulation.

    The extent of vaporization occurring in both models can bequantified from Fig. 24through Fig. 28. According to the first

    three plots, the third gridblock from the producer for layer

    nine (23, 23, 9), gives zero condensate saturation at 5000 days,

    which is not the case with compositional model and MBO

    model initialized with saturation pressure versus depth table

    The last two plots are the examples of unrealistic vaporization

    in oil-gas ratio versus depth initialized MBO model forgridblocks at the producer in layer four and five. Higher oil

    saturation is obtained from MBO model but as soon as the

    displacement front arrives all the oil is vaporized. This type o

    formulation allows dry gas to pick up oil until the gas becomes

    saturated. Since miscibility cannot be represented in MBO, thearrival time of displacement front differs for both

    compositional and MBO models and as well as for differentinitialization methods among the MBO models.

    The liquid content of the initial gas composition and

    different gas compositions obtained by flashing the origina

    gas to different pressures is given in Fig. 29. The figure was

    generated by flashing the original gas to 5,000, 4,000 and3,000 psia and generating black oil tables for each pressure

    In fact, this process represents the changes in oil-gas ratio of

    the injected gas during the cycling. According to the figure

    especially at high pressures, it is not possible to accuratelyrepresent the continuously changing PVT properties of the

    recycled gas with single PVT table in MBO model since everytime the produced gas passes through the separators and is

    injected back into the reservoir its oil-gas ratio and

    accordingly vaporization characteristics changes.

    In the swept zone, the reservoir pressure is either above or

    below its original dew point when the injection gas fron

    arrives. If it is above the dew point a gas-gas miscibledisplacement will yield 100 % recovery of the curren

    condensate in place, which is the case with higher production

    and injection rates. If reservoir pressure is below the dew poinwhen the displacement front arrives, ultimate recovery of

    condensate depends on both gas-gas miscible displacement o

    the reservoir gas, and partial vaporization of the retrogradecondensate. The latter case is encountered with lower

    production and injection rates and the amount of condensatedrop-out before gas-gas miscible displacement takes place is

    determined by the fluid type. Fig. 30 shows the average oi

    saturation obtained from both models for low production andinjection rates. The condensation times indicate the increasing

    differences between the models with lower production and

    injection rates.The richest part of the gas is located at the bottom of the

    reservoir due to gravitational forces and the compositiona

    effects, such as development of miscibility changes with

    depth. Since miscibility cannot be represented with black-oimodels, more discrepancies are expected in the regions where

    highly miscible processes take place i.e. around the bottom

    completions. When the producer and injector were completedat the bottom part of the reservoir (layer 10 to 18), it has been

    observed that saturation pressure versus depth initializationmethod resulted in extreme amounts of condensate

    accumulation initially in MBO model. An unrealistic

    vaporization of all the condensed oil follows in the swept zoneuntil the saturation becomes to the level given by the

    compositional model. Fig. 31 andFig. 32 show the average oi

    saturation and gas-oil ratio plots for the bottom completionscenario.

    When kv/kh ratio is reduced to an extreme value of 10-4

    which almost restricts the mass transfer between layers, it is

    clearly observed that compositional and MBO models showed

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    closer performances both for natural depletion and gas cycling

    cases.

    The reduced communication between layers prevented themixing of the leaner reservoir gas (relative to initial

    conditions) with the oil formed after condensation. In the case

    of good vertical communication; the leaner gas after the first

    drop-out, tends to go up and at the same time vaporizes the oil

    on its path during the continuing depletion process. Also theaccumulated condensate tends to go down under gravity

    forces. Both scenarios are not possible with the restrictedvertical communication. Every layer is left with its own ability

    to vaporize the condensate accumulated. In the case of

    reduced vertical communication, condensate accumulation and

    vaporization process for each layer is proportional to the

    layers content of heavy and light component fractions.Compositional effects gain importance at the bottom part of

    the model because of the isolated richer gas phase. Fig. 33 and

    Fig. 34 show the oil production rate and gas-oil ratio plots for

    reduced vertical communication.The lower drawdown pressure for horizontal well,

    compared to the vertical well, for the same flow rate,considerably reduces retrograde condensation.9 Therefore

    there is less condensate deposited near the horizontal wellbore.

    This means lesser liquid drop-out and smaller amounts of

    vaporization for MBO model, which in turn makes the models

    give similar performances. Dehane and Tiab9 compared the

    productivity of the horizontal and vertical wells for a gascondensate reservoir. According to their results the

    productivity of the horizontal well outperforms the

    productivity of the vertical well and drain hole length is themost important criteria for the productivity of a horizontal

    well. Longer drain hole causes a lower drawdown and less

    condensation around the wellbore, which is an importantfactor in duplicating the fully compositional model

    performance with MBO model. In comparison with the runsthat had horizontal well completed in upper and bottom layers,

    it can be concluded that MBO model performance with

    horizontal well approaches to the compositional modelperformance if the well is placed closer to the area where fluid

    sample is coming from, even if the sample is coming from the

    bottom part of the reservoir. If the well is placed in the upperlayers also a good match can be obtained since the gas

    becomes heavier with increasing depth. Also with the

    horizontal well, error in dew point pressure versus depth is

    almost eliminated for the gas cycling case and a betteragreement between the models has been obtained compared to

    the vertical wells. Fig. 35 through Fig. 37 gives the oil

    production rate, gas-oil ratio and recovery factors for gascycling with horizontal well set as a producer.

    Conclusions1. The performance of the MBO model is not affected

    by the initialization method if composition is constantwith depth. Also OOIP is the same for all

    initialization methods if no compositional gradient is

    used.2. Unrealistic vaporization in MBO model is not just

    limited to gas cycling, it can also be encountered in

    natural depletion to some degree depending on the

    depletion scenario.

    3. In natural depletion the gas present in MBO has alower capacity to hold liquid and more oil is left in

    the reservoir.4. In gas cycling case, the injected gas in MBO can pick

    up oil as a function of pressure and the oil left in the

    reservoir is always lower than in the compositional

    model.

    5. Lower kv/khratios provide a better match between themodels.

    6. The arrival time of displacement front differs for bothcompositional and MBO models and as well as for

    different initialization methods among the MBO

    models.

    7. Due to reduced retrograde condensation and partialelimination of the error in dew point pressure versusdepth, MBO model with the horizontal wells exhibits

    better agreement with compositional model.

    8. Oil saturation distributions around the well andthroughout the reservoir may be quite different in twomodels regardless of a match with the production

    performance.

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    11. Whitson, C.H., and Thomas, L.K.: CompositionalGradients in Petroleum Reservoirs, paper SPE 28000

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    16. Behrens, R.A., and Sandler, S.I.: The Use of

    Semicontinuous Description to Model the C7+ Fraction inEquation of State Calculations, paper SPE 14925

    presented at the 1986 SPE/DOE Symposium on EnhancedOil Recovery, Tulsa, Oklahoma, 23-23 April.

    17. Kuenen, J.P.: On Retrograde Condensation and theCritical Phenomena of Two Substances, Commun. Phys.

    Lab U. Leiden(1892) 4, 7.18. Whitson, C.H., and Thomas, L.K.: Simplified

    Compositional Formulation for Modified Black-OilSimulators, paper SPE 18315 presented at the 1988 SPE

    Annual Technical Conference and Exhibition, Houston,Texas, 2-5 October.

    19.Nolen, J.S.: Numerical Simulation of CompositionalPhenomena in Petroleum Reservoirs, paper SPE 4274

    presented at the 1973 SPE Symposium on Numerical

    Simulation of Reservoir Performance, Houston, Texas, 11-12 January.

    20. Spivak, A., Dixon, T.N.: Simulation of Gas-CondensateReservoirs, paper SPE 4271 presented at the 1973 SPESymposium on Numerical Simulation of ReservoirPerformance, Houston, Texas, 11-12 January.

    21. Cook, A.B., Walker, C.J.: Realistic K Values of C7+Hydrocarbons for Calculating Oil Vaporization During GasCycling at High Pressures,JPT(July 1969), 2, 901.

    22. Geoquest, PVTi Reference Manual 2001a, Geoquest,Houston (2001).

    23. Schulte, A.M.: Compositional Variations within aHydrocarbon Column due to Gravity, paper SPE 9235

    presented at the 1980 SPE Fall Technical Conference and

    Exhibition, Dallas, Texas, 21-24 September.24. Hirschberg, A.: Role of Asphaltenes in CompositionalGrading of a Reservoirs Fluid Column, JPT (January1988), 5, 89.

    25. Kenyon, D. E. and Behie, G.A.: Third SPE ComparativeSolution Project: Gas Cycling of Retrograde CondensateReservoirs, paper SPE 12278 presented at the 1983Reservoir Simulation Symposium, San Francisco, 15-18

    November.26. Izgec, B.: Performance Analysis of Compositional and

    Modified Black-Oil Models for Rich Gas CondensateReservoirs with Vertical and Horizontal Wells, MS

    Thesis, Texas A&M University, College Station, Texas(2003).

    Table 1 Extended mix ture composition

    Com ponent Sym bol Mol %

    Carbon Dioxide CO2

    4.57

    Nitrogen N2 0.52

    Methane C1

    68.97

    Ethane C2

    8.89

    Propane C3

    4.18

    Isobutane iC4

    0.99

    N- Butane nC4 1.4

    Isopentane iC5

    0.71

    N-Pentane nC5 0.6

    Hexanes C6

    0.99

    Heptanes C7

    1.02

    Octanes C8

    1.28

    Nonanes C9

    0.97

    Decanes C10 0.73

    Undecanes C11

    0.53

    Dodecanes C12 0.44

    Tridecanes C13 0.48

    Tetradecanes C14

    0.41

    Pentadecanes C15

    0.36

    Hexadecanes C16

    0.28

    Heptadecane C17

    0.26

    Octadecanes C18

    0.24

    Nonadecanes C19

    0.19

    Eicosanes C20

    0.16

    C21 's C21

    0.13

    C22 's C22 0.11

    C23 's C23 0.1

    C24 's C24

    0.08

    C25 's C25

    0.07

    C26 's C26

    0.06

    C27 's C27

    0.06

    C28 's C28 0.05

    C29 's C29

    0.04

    C30+ C30+ 0.13

    Table 2 Pseudocomponent grouping andcomposition

    Ps eudocom ponent Com ponents Mol %

    CO2

    4.57

    GRP1 N2-C

    1 69.49

    GRP2 C2-C

    3 13.07

    GRP3 C4-C

    6 4.69

    GRP4 C7-C

    10 4

    GRP5 C11

    -C16

    2.5

    GRP6 C17-C34 1.68

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    Table 3 Pseudocomponent properties

    Com ponent Molecular Weight Pc (ps ig) Tc (0F)

    CO2 44.01 1056.6 88.79

    GRP1 16.132 651.77 -117.46

    GRP2 34.556 664.04 127.15

    GRP3 67.964 490.47 350.279

    GRP4 112.52 384.19 591.912

    GRP5 178.79 269.52 781.912

    GRP6 303.64 180.2 1001.13

    Table 4 Pseudocomponent properties

    Component ZC VC(ft3/lb-mo l) s-Shifts

    CO2

    0.27407 1.50573 -0.045792

    GRP1 0.28471 1.56885 -0.144168

    GRP2 0.28422 2.63712 -0.095027

    GRP3 0.27197 4.67964 -0.041006

    GRP4 0.25668 7.26188 0.003672

    GRP5 0.23667 11.09534 0.00893404

    GRP6 0.21972 17.67366 0.0115616

    Table 5 Variation in parameters selected forregression

    Parameter Ini tial Value Final Value % Change

    BICGRP6-GRP1 0.0544 0.1231 -126.28BIC

    GRP6-GRP2 0.01 0.0226 -126

    BICGRP5-GRP1

    0.0464 0.1052 -126.72

    BICGRP5-GRP2

    0.01 0.0226 -126

    BICGRP4-GRP1

    0.0377 0.0248 34.21

    BICGRP4-GRP2

    0.01 0.0066 34

    BICCO2-GRP1 0.1 0.0657 34.3

    BICCO2-GRP2 0.1 0.0657 34.3

    BICCO2-GRP3

    0.1 0.0657 34.3

    BICCO2-GRP4

    0.1 0.0657 34.3

    BICCO2-GRP5

    0.1 0.0657 34.3

    BICCO2-GRP6

    0.1 0.0657 34.3

    SFCO2 0.0066 -0.0458 793.93SF

    GRP4 0.0525 0.0037 92.95

    SFGRP5

    0.0714 0.0089 87.53

    SFGRP6 0.095 0.0116 87.78

    Table 6 Fluid in place and CPU time for uniformcomposition with depth

    OOIP, s tb CPU, s ec. Er ror in OOIP, %

    Compositional 999916.20 785.91 -

    Rv vs Dept h 958733.40 64.47 4.11

    Pd vs Depth 958733.40 65.00 4.11

    Table 7 Fluid in place and CPU time withcompositional gradient

    OOIP, s tb CPU, s ec. Er ror in OOIP, %

    Compositional 941669.40 745.56 -

    Rv vs Dept h 888033.20 72.22 5.69

    Pd vs Depth 922730.10 64.28 2.01

    Table 8 Reservoi r Propert ies

    Layer Thickness Poros ity Perm eability (m d)

    1 20 0.087 0.1

    2 15 0.097 0.2

    3 26 0.111 0.3

    4 15 0.16 0.2

    5 16 0.13 7

    6 14 0.17 0.1

    7 8 0.17 14

    8 8 0.08 2

    9 18 0.14 12

    10 12 0.13 3

    11 19 0.12 10

    12 18 0.105 9

    13 20 0.12 0.1

    14 50 0.116 0.3

    15 20 0.157 0.2

    16 20 0.157 0.2

    17 30 0.157 0.2

    18 30 0.157 0.2

    Table 9 CPU time in seconds for vertical wells

    Com pos itional MBO MBO

    Rvvs Depth Pdvs DepthNatural Depletio n

    Constant Composition 785.91 64.47 65

    Compositional Gradient 745.56 72.22 64.28

    Bottom Completion 539.12 82.58 81.32

    Top Completion 820.37 80.35 79.01

    Reduced kv

    985.45 106.35 103.2

    Gas Cycling

    Compositional Gradient 3021.78 597.77 582.49

    Bottom Completion 3068.71 458.86 479.42

    Top Completion 3296.56 531 603.04

    Reduced kv

    4743.82 363 453.81

    Low Rates 1957.74 401.39 626.68

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    8 SPE 93374

    0

    0.5

    1

    1.5

    2

    2.5

    3

    3.5

    4

    4.5

    0 1000 2000 3000 4000 5000 6000 7000Pressure (psia)

    RelativeVolu

    me

    Simulated

    Experimental

    Fig. 1 Simulated and experimental relative volume data from CCEat 254 F

    0

    0.05

    0.1

    0.15

    0.2

    0.25

    0 1000 2000 3000 4000 5000 6000 7000

    Pressure (psia)

    LiquidSaturation

    Simulated

    Experimental

    Fig. 2 Simulated and experimental liqu id saturation data from CCEat 254 F

    0

    5

    10

    15

    20

    25

    30

    0 1000 2000 3000 4000 5000 6000 7000

    Pressure (psia)

    GasDensity

    (lb/ft3)

    Simulated

    Experim ental

    Fig. 3 Simulated and experimental gas density data from CCE at254 F

    0

    0.5

    1

    1.5

    2

    2.5

    3

    0 1000 2000 3000 4000 5000 6000

    Pressure, psia

    GOR,M

    scf/stb

    Whitson and Torp Coats

    Fig. 4 Gas-oil ratio comparison from Coats versus Whitson andTorp methods

    0

    0.5

    1

    1.5

    2

    2.5

    3

    0 1000 2000 3000 4000 5000 6000

    Pressure, psia

    Bo,rb/stb

    Whitson and Torp Coats

    Fig. 5 Oil formation volume factor comparison from Coats versusWhitson and Torp methods

    0

    0.1

    0.2

    0.3

    0.4

    0.5

    0.6

    0 1000 2000 3000 4000 5000 6000

    Pressure, psia

    Viscosity,cp

    Whitson and Torp Coats

    Fig. 6 Oil viscosity comparison from Coats versus Whitson andTorp methods

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    SPE 93374 9

    Fig. 7 Oil-gas ratio comparison from Coats versus Whitson andTorp methods

    Fig. 8 Gas formation volume factor comparison from Coatsversus Whitson and Torp methods

    Fig. 9 Gas viscosity comparison generated from Coats versusWhitson and Torp methods

    12500

    12550

    12600

    12650

    12700

    12750

    12800

    12850

    12900

    12950

    13000

    0.6 0.62 0.64 0.66 0.68 0.7 0.72 0.74

    Molar composit ion fraction

    Depth(ft)

    GWC

    0

    0.02

    0.040.06

    0.08

    0.1

    0.12

    0.14

    0.16

    0.18

    0 1000 2000 3000 4000 5000 6000

    Pressure, psia

    OG

    R,stb/Mscf

    Whitson and Torp Coats

    Fig. 10 C1-N2compositional gradient

    12500

    12550

    12600

    12650

    12700

    12750

    12800

    12850

    12900

    12950

    13000

    0.04 0.06 0.08 0.1 0.12 0.14 0.16

    Molar composit ion fraction

    Depth(ft)

    GWC

    0

    1

    2

    3

    4

    5

    6

    7

    8

    0 1000 2000 3000 4000 5000 6000

    Pressure, psia

    Bg,rb/Mscf

    Whitson and Torp Coats

    Fig. 11 C7+compositional gradient

    0

    0.01

    0.02

    0.03

    0.04

    0.05

    0.06

    0.07

    0 1000 2000 3000 4000 5000 6000

    Pressure, psia

    Fig. 12 Change in dew-point pressure with depth, uniformcomposition case

    Viscosity,cp

    Whitson and Torp Coats

    4000

    4500

    5000

    5500

    6000

    12500 12550 12600 12650 12700 12750 12800 12850 12900

    Depth, ft

    Press

    ure,psi

    Compositional Model MBO Model

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    10 SPE 93374

    Fig. 13 Change in dew-point pressure with depth, compositionalgradient case

    Fig. 14 Oil production rate for the model initialized withcompositional gradient

    Fig. 15 Average field pressure with composi tional gradient

    0

    100

    200

    300

    400

    500

    600

    0 500 1000 1500 2000

    Time, days

    ProductionRate,stb/day

    MBO initialized w ith fixed RvCompositionalMBO initialized w ith fixed Pd

    4000

    4500

    5000

    5500

    6000

    12500 12550 12600 12650 12700 12750 12800 12850 12900

    Depth, ft

    Pressure,

    psi

    Compositional Model MBO Model

    1044 psia900 psia

    4000

    4500

    5000

    5500

    6000

    12500 12550 12600 12650 12700 12750 12800 12850 12900

    Depth, ft

    Pressure,

    psi

    Compositional Model MBO Model

    1044 psia900 psia

    Fig. 16 Oil production rate for the natural depletion case, constancomposition

    0

    20

    40

    60

    80

    100

    120

    0 500 1000 1500 2000

    Time, days

    GOR,Mscf/stb

    MBO initialized w ith fixed RvCompositionalMBO initialized w ith fixed Pd

    0

    100

    200

    300

    400

    500

    0 500 1000 1500 2000

    Time, days

    ProdcutionRate,stb/day

    MBO with Rv vs DepthCompositionalMBO with Pd vs Depth

    Fig. 17 Gas oil ratio for the natural depletion case, constantcomposition

    0

    1000

    2000

    3000

    4000

    5000

    6000

    7000

    0 500 1000 1500 2000

    Time, days

    Pres

    sure,psia

    MBO w ith Rv vs DepthCompositionalMBO w ith Pd vs Depth

    0

    0.05

    0.1

    0.15

    0.2

    0.25

    0 500 1000 1500 2000

    Time, days

    Saturation

    MBO w ith Rv vs DepthCompositionalMBO w ith Pd vs Depth

    Fig. 18 Oil saturation distribution for the model initialized withcompositional gradient

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    SPE 93374 11

    Fig. 19 Oil saturation distribution from compositional model withcompositional gradient

    Fig. 20 Oil saturation distribution from MBO model withcompositional gradient

    Fig. 21 Oil saturation distribution from compositional model foruniform composition

    0

    0.02

    0.04

    0.06

    0.08

    0.1

    0.12

    0 1000 2000 3000 4000 5000 6000

    Time, days

    Saturation

    MBO w ith Rv vs DepthCompositionalMBO with Pd vs Depth

    Fig. 22 Average oil saturation for gas cycling case

    0

    20

    40

    60

    80

    100

    120

    0 1000 2000 3000 4000 5000 6000

    Time, days

    GOR,Mscf/stb

    MBO with Rv vs DepthCompositionalMBO with Pd vs Depth

    Fig. 23 Gas-oil ratio for gas cyclin g case

    0.05

    0.1

    0.15

    0.2

    0.25

    0.3

    1 2

    Gridblock Number

    Satura

    tion

    3

    500 day s 1000 day s 1500 day s 2000 day s

    2500 days 3000 days 4000 days 5000 days

    Fig. 24 Saturation distributi on for compositional model for layer 9

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    12 SPE 93374

    Fig. 25 Saturation distr ibution for MBO model for layer 9

    Fig. 26 Saturation distribution for MBO model (Pd versus depthiniti alization) for layer 9

    Fig. 27 Saturation di stribu tion for MBO model gri dblock (25, 25, 4)

    0

    0.05

    0.1

    0.15

    0.2

    0.25

    0.3

    1 2 3

    Gridblock Number

    Satura

    tion

    500 day s 1000 day s 1500 day s 2000 day s

    2500 days 3000 days 4000 days 5000 days

    0

    0.05

    0.1

    0.15

    0.2

    0 1000 2000 3000 4000 5000 6000

    Time, days

    Saturation

    CompositionalMBO with Rv vs Depth

    Fig. 28 Saturation di stribut ion f or MBO model gri dblock (25, 25, 5)

    Fig. 29 Oil-gas ratio versus pressure generated from differencompositions

    Fig. 30 Average oil saturation for low production and injectionrates

    0.1

    0.15

    0.2

    0.25

    0.3

    1 2

    Gridblock Number

    Saturation

    3

    0

    0.02

    0.04

    0.06

    0.08

    0.1

    0.12

    0.14

    0.16

    0.18

    0 1000 2000 3000 4000 5000 6000

    Pressure, psia

    LiquidContentofGas,stb/Mscf Without flashing original gas

    Flash to 5000 psiaFlash to 4000 psiaFlash to 3000 psia

    500 day s 1000 day s 1500 day s 2000 day s

    2500 days 3000 days 4000 days 5000 days

    0

    0.02

    0.04

    0.06

    0.08

    0.1

    0.12

    0.14

    0 1000 2000 3000 4000 5000 6000

    Time, days

    Saturation

    MBO w ith Rv vs DepthCompositionalMBO Pd vs Depth

    0

    0.05

    0.1

    0.15

    0.2

    0 1000 2000 3000 4000 5000 6000

    Time, days

    Saturation

    Compositional

    MBO with Rv vs Depth

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    SPE 93374 13

    Fig. 31 Average oil saturation with wells completed at the bottomof the model

    Fig. 32 Gas-oil ratio with wells completed at the bottom of themodel

    Fig. 33 Oil productio n rate for kv/khratio of 0.0001

    0

    20

    40

    60

    80

    100

    120

    140

    160

    180

    0 1000 2000 3000 4000 5000 6000

    Time, days

    GOR,Mscf/stb

    MBO with Rv vs DepthCompositionalMBO with Pd vs Depth0

    0.02

    0.04

    0.06

    0.08

    0.1

    0 1000 2000 3000 4000 5000 6000

    Time, days

    Saturation

    MBO w ith Rv vs DepthCompositionalMBO w ith Pd vs Depth

    Fig. 34 Gas-oil ratio f or k v/khratio of 0.0001

    0

    50

    100

    150

    200

    0 1000 2000 3000 4000 5000 6000

    Time, days

    GOR,Mscf/stb

    MBO w ith Rv vs DepthCompositionalMBO with Pd vs Depth

    0

    100

    200

    300

    400

    500

    0 1000 2000 3000 4000 5000 6000

    Time, days

    Rate,stb/day

    MBO Compositional

    Fig. 35 Oil production rate for gas cycling with horizontal well

    0

    50

    100

    150

    200

    0 1000 2000 3000 4000 5000 6000

    Time, days

    GOR,M

    scf/stb

    MBO Compositional

    0

    50

    100

    150

    200250

    300

    350

    400

    450

    0 1000 2000 3000 4000 5000 6000

    Time, days

    ProductionRate,stb/day

    MBO with Rv vs DepthCompositionalMBO with Pd vs Depth

    Fig. 36 Gas-oil ratio for gas cycling with horizontal well

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    14 SPE 93374

    0

    0.1

    0.2

    0.3

    0.4

    0.5

    0 1000 2000 3000 4000 5000 6000

    Time, days

    Recovery

    Factor

    MBO Compositional

    Fig. 37 Recovery factor for gas cycling w ith hori zontal well