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STYRENE BUTADIENE RUBBER FOR ADHESIVES AND SEALANTS Group Dynasol

STYRENE BUTADIENE RUBBER FOR ADHESIVES AND ......The hygiene industry is an special segment that demand high quality in their adhesives uses for diaper assembly, elastic attachment

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Page 1: STYRENE BUTADIENE RUBBER FOR ADHESIVES AND ......The hygiene industry is an special segment that demand high quality in their adhesives uses for diaper assembly, elastic attachment

STYRENE BUTADIENE RUBBERFOR ADHESIVES AND SEALANTS

GroupDynasol

Page 2: STYRENE BUTADIENE RUBBER FOR ADHESIVES AND ......The hygiene industry is an special segment that demand high quality in their adhesives uses for diaper assembly, elastic attachment
Page 3: STYRENE BUTADIENE RUBBER FOR ADHESIVES AND ......The hygiene industry is an special segment that demand high quality in their adhesives uses for diaper assembly, elastic attachment

Dynasol Group has over 35 years of experience as a supplier of polymers to the Adhesive & Sealant industry.

We are a Global supplier with a wide portfolio of SBS, SEBS, SSBR and Hot SBR products that are used in applications such as hot melts and solvent borne formulas for building and construction, PSA, non-PSA packaging, specialty labels, automotive sealants andFDA grade food packaging sealants.

Our polymer know-how has positioned Dynasol Group as one of the primary global suppliers of high purity FDA compliant grades of SBS, SEBS and HotSBR products.

These products are produced to meet stringent requirements for purity and sensory factors, including odor and taste performance and are 100% compliant with all REACH requirements with zero levels Nonylphenol-type residuals. The emphasis on purity and quality assures a high standard of performance with clear benefits for all applications with exposureto consumer level users.

Dynasol Group’s global footprint includes manufacturing plants and Technical centers located strategically in China, Europe and North America to supply and support our clients worldwide.

It is our commitment to continue to develop new and improved innovative products designed to enhancethe value and performance of our customer’s products.

For more information about our portfolio please visitdynasolgroup.com

Dynasol Products For Adhesives and Sealants

Page 4: STYRENE BUTADIENE RUBBER FOR ADHESIVES AND ......The hygiene industry is an special segment that demand high quality in their adhesives uses for diaper assembly, elastic attachment

Hygiene Industry

The hygiene industry is an special segment that demand high quality in their adhesives uses for diaper assembly, elastic attachment and position feminine care to underwear.

Dynasol Group has an excellent portfolio of styrene-butadiene copolymers to meet customer needsand market trends.

Adhesives Requirements

Dynasol recommended grades for the Hygiene Industry

Elastic recovery (A)

High adhesive-cohesive strength (B)

Excellent adhesion to low surface energy (C)

Wide temperature resistance (D)

Regulations compliance for

skin contact (G)

Clear colorLow odor (H)

Capable of be applied at low

temperature (F)

Low melt viscosity (E)

Brand Grade Structure Styrene Content, % TSV, cP MFI,

g/10min A B C D E F G H

Calprene 743X Linear SBS 43 360 ¹ 23 4

Calprene 540 Linear SBS 40 600 ¹ 5.5 5

Calprene 741X Linear SBS 40 500 ¹ 9.5 5

Solprene 4428X Radial SBS 40 430 ¹ 10 5

Page 5: STYRENE BUTADIENE RUBBER FOR ADHESIVES AND ......The hygiene industry is an special segment that demand high quality in their adhesives uses for diaper assembly, elastic attachment

Excellent Good Regular

1- 25% @ 25°C // 2- 30% @ 25°C // 3- 20% @ 25°C // 4- 200°C/5Kg // 5- 190°C/5Kg // 6- 230°C/2.16Kg

Requirement performance

Condition test

Brand Grade Structure Styrene Content, % TSV, cP MFI,

g/10min A B C D E F G H

Solprene1205 / 1217 Linear SBR 25 40002 --- ---

Calprene H6110 Linear SEBS 32 4703 < 16

CalpreneH6215 Linear SBR 13 15003 ---

Page 6: STYRENE BUTADIENE RUBBER FOR ADHESIVES AND ......The hygiene industry is an special segment that demand high quality in their adhesives uses for diaper assembly, elastic attachment

Tapes

Tapes is an extensive market segment due to the versatile applications that offer from medical, office to industrial applications. Because of this the adhesives need to meet a series of requirements ofperformance and regulations to ensure good performance.

Dynasol Group provides a product portfolio offering flexibility for adhesives formulations, with a versatile range of adhesives performance because of their unique combination of adhesive and cohesive strength over a broad temperature range. In addition to comply with FDA and European regulations for contact with skin and food.

Adhesives Requirements

Dynasol recommended grades for Tapes

Initial tack Permanent (A)

No residue on substrate (C)

Holding power (B)

Regulations compliance for skin contact (D)

Repositionable (E)

Wide service temperature

range (I)

Reduce volatile organic compound (VOC) emission (H)

Mandrel hold (G)Clear or translucent color (F)

BrandGrade Structure Styrene

Content, % TSV, cP MFI, g/10min A B C D E F G H I

Solprene 4301 Linear SBS/SB 33 30001 ---

Solprene 4302 Linear SBS/SB 31 8901 ---

Solprene 411 Radial SBS 30 200001 ---

Solprene 416 Radial SBS 30 22001 ---

Page 7: STYRENE BUTADIENE RUBBER FOR ADHESIVES AND ......The hygiene industry is an special segment that demand high quality in their adhesives uses for diaper assembly, elastic attachment

1- 25% @ 25°C // 2- 30% @ 25°C // 3- 5.23% @ 25°C // 4- 15% @ 25°C 5- 5% @ 25°C // 6- 10% @ 25°C // 7- 190°C/5Kg // 8- 230°C/2.16Kg 9- 200°C/25°C

Excellent Good RegularRequirement performance

Condition test

Brand Grade Structure Styrene Content, % TSV, cP MFI,

g/10min A B C D E F G H I

Solprene 4428X Radial SBS 40 4301 107

CalpreneH6180X

Linear SEBS 15 --- 108

Solprene1205 / 1217 Linear SBR 25 40002 --- --

Solprene 5170X Hybrid SBC 25 9.23 8.99

Emulprene 1011 HSBR 23.5 3000-40004 --- --

Emulprene 1012 HSBR 23.5 150-3005 --- --

Emulprene1013 HSBR 43.5 550-7506 ---- --

Page 8: STYRENE BUTADIENE RUBBER FOR ADHESIVES AND ......The hygiene industry is an special segment that demand high quality in their adhesives uses for diaper assembly, elastic attachment

Labels

The label industry requires a great deal of versatility in pressure sensitive adhesives (PSAs) in order to satisfy the broad range of properties required for various products.

Dynasol Group has a product portfolio offering flexibility for adhesives formulations, providing a versatile range of adhesives performance because of their unique combination of adhesive and cohesive strength over a broad temperature range.

Adhesives Requirements

Dynasol recommended grades for Labels

Initial tack (A)

UV, temperature and environmental resistance (C)

Removable or repositionable (D)

Ultimate adhesion (E)

Clear or translucent color (B)

Wide service temperature

range (I)

Clod flow tack at cold or freezing

temperature (H)

Mandrel hold (G)

Meet FDA regulations (F)

BrandGrade Structure Styrene

Content, % TSV, cP MFI, g/10min A B C D E F G H I

Calprene H6110 Linear SEBS 32 4701 < 15

Calprene H6120 Linear SEBS 30 19001 15

Calprene H6180X Linear SEBS 15 --- 105

Solprene 4302 Linear SBS/SB 31 8902 ---

Page 9: STYRENE BUTADIENE RUBBER FOR ADHESIVES AND ......The hygiene industry is an special segment that demand high quality in their adhesives uses for diaper assembly, elastic attachment

Excellent Good Regular

1- 20% @ 25°C // 2- 25% @ 25°C // 3- 30% @ 25°C // 4- 5.23% @ 25°C5- 230°C/2.16Kg // 6- 190°C/5Kg // 7- 200°C/5Kg

Requirement performance

Condition test

BrandGrade Structure Styrene

Content, % TSV, cP MFI, g/10min A B C D E F G H I

Solprene 4318 Linear SBS/SB 32 7002 56

Solprene 4428X Radial SBS 40 4302 106

Solprene1205 / 1217 Linear SBR 25 40003 ---

Solprene 5170X Hybrid SBC 25 9.24 8.97

Page 10: STYRENE BUTADIENE RUBBER FOR ADHESIVES AND ......The hygiene industry is an special segment that demand high quality in their adhesives uses for diaper assembly, elastic attachment

Packaging

Packaging is an industry that is currently growing due to the high demand to buy online and thenew resalable food packaging.

Dynasol Group has the capacity to provide styrene-butadiene copolymers to formulate adhesives thatmust have special characteristics and meet specific requirements.

Adhesives Requirements

Dynasol recommended grades for Packaging

Flexible properties (A)

TemperatureViscosity relationship (B)

Wide service temperature range (C)

Meet FDA regulations (D)

Initial tackResealable (G)

Holding power (F)

Reduce volatile organic compound (VOC) emission (E)

BrandGrade Structure Styrene

Content, % TSV, cP MFI, g/10min A B C D E F G

Solprene 4301 Linear SBS/SB 33 30001 ---

Solprene 4318 Linear SBS/SB 32 7001 54

Calprene 540 Linear SBS 40 6001 5.54

Solprene 4428X Radial SBS 40 4301 104

Solprene 416 Radial SBS 30 22001 ---

Page 11: STYRENE BUTADIENE RUBBER FOR ADHESIVES AND ......The hygiene industry is an special segment that demand high quality in their adhesives uses for diaper assembly, elastic attachment

Excellent Good Regular

1- 25% @ 25°C // 2- 30% @ 25°C // 3- 5.23% @ 25°C4- 190°C/5Kg // 5- 200°C/5Kg

Requirement performance

Condition test

BrandGrade Structure Styrene

Content, % TSV, cP MFI, g/10min A B C D E F G

Solprene1205 / 1217 Linear SBR 25 40002 ---

Solprene 5170X Hybrid SBC 25 9.23 8.95

Page 12: STYRENE BUTADIENE RUBBER FOR ADHESIVES AND ......The hygiene industry is an special segment that demand high quality in their adhesives uses for diaper assembly, elastic attachment

Building & Construction

Adhesives are used in the building and construction industry for automotive, floor, subfloors, walls,ceilings and bookbinding applications.

Dynasol Group offers a wide variety of products that can meet a special customer requirements like high cohesive strength, low viscosity, aggressive adhesion to polyolefins, vinyl, and other low energy films, clarity, UV and environmental resistance, comply with regulatory trends including the capacity of adhesives formulations with low VOC.

Adhesives Requirements

Dynasol recommended grades for the Building & Construction

Holding power (A)

UV, temperature and environmental resistance (B)

Wide service temperature range (C)

Indoor / Outdoor usage (D)

Initial tackPermanent (H)

Flexible (G)

Good extrudability (F)

Low shrinkage (E)

BrandGrade Structure Styrene

Content, % TSV, cP MFI, g/10min A B C D E F G H

Calprene 500 Linear SBS 31 5000 ¹ 55

Calprene 501 Linear SBS 30 1100 ¹ ---

Calprene 540 Linear SBS 40 600 ¹ 5.55

Calprene H6110 Linear SEBS 32 4702 < 16

Page 13: STYRENE BUTADIENE RUBBER FOR ADHESIVES AND ......The hygiene industry is an special segment that demand high quality in their adhesives uses for diaper assembly, elastic attachment

Excellent Good Regular

1- 25% @ 25°C // 2- 20% @ 25°C // 3- 30% @ 25°C // 4- 5.23% @ 25°C5- 10% @ 25°C // 6- 3.68% @ 25°C // 7- 190°C/5Kg // 8- 230°C/2.16Kg 9- 200°C/5Kg

Requirement performance

Condition test

BrandGrade Structure Styrene

Content, % TSV, cP MFI, g/10min A B C D E F G H

Calprene H6120 Linear SEBS 30 19002 16

Calprene H6180X Linear SEBS 15 --- 106

Linear

Solprene 4301 Linear SBS/SB 33 30001 ---

Solprene 411 Radial SBS 30 200001 ---

Solprene 416 Radial SBS 30 22001 ---

Solprene1205 / 1217 Linear SBR 25 40003 --- ---

Solprene 5170X Hybrid SBC 25 9.24 8.99

Emulprene 1013 HSBR 43.5 500-6005 ---

Emulprene 1009LF Cross-linkedHSBR 23.5 120-4006 ---

Page 14: STYRENE BUTADIENE RUBBER FOR ADHESIVES AND ......The hygiene industry is an special segment that demand high quality in their adhesives uses for diaper assembly, elastic attachment

Products for Adhesives & Sealants

0

1

2

3

4

5

6

7

0 1 2 3 4 5 6

S-1205

S-4318S-4302

C-H6110

C-H6120

C-500 C-540

C-743X

S-4428X

S-416S-411

S-4301SSBR

Linear SBS

Linear SBS/Diblock SB

Radial SBS

Linear SEBS

ADHESION

STRENGHT

C O H E S I O N S T R E N G H T

V I S CO S I T Y

C-H6180X

C-H6215Dyne 145B

Solution Technology Products

Emulsion Technology Products

0

1

2

3

4

5

6

7

0 1 2 3 4 5 6

E-1012

Non Cross-linked HSBR

ADHESION

STRENGHT

C O H E S I O N S T R E N G H T

Cross-linked HSBR

E-1011

E-1013

E-1006

E-1009

V I S CO S I T Y

Page 15: STYRENE BUTADIENE RUBBER FOR ADHESIVES AND ......The hygiene industry is an special segment that demand high quality in their adhesives uses for diaper assembly, elastic attachment

Dynasol Technical Experience

Dynasol Group is committed to supporting its customers with the dynamism demanded by the market challenges of Adhesives & Sealants having an expert R&D department with the aim of maintaining the technological vanguard in the development of styrene-butadiene copolymers

Having two laboratories specializing in adhesives and sealants with global technical attention, one in Mexico and one in Spain, with technical staff dedicated to the development of new applications and provide assistance adhesive formulators in a quick and timely manner for the selection of raw materials and provide support for the development of applications.

Technical Capability

The global presence of Dynasol Group allows us to be aware of the importance of being in tune with the ever-changing regulations around theworld.

The products manufactured in all our sites are listed without ban in many of the chemical inventories in North and Latin America, Europe, Asia and Oceania, and comply with European and Chinese regulations for food contact, FDA standards for food contact materials, do not contain any substance included in the REACH SVHC candidate list or Annex XVII.

Regulatory Guidance

For further inquiries on regulations please contact [email protected]

Page 16: STYRENE BUTADIENE RUBBER FOR ADHESIVES AND ......The hygiene industry is an special segment that demand high quality in their adhesives uses for diaper assembly, elastic attachment

Dynasol Group. Houston

14340 Torrey Chase Blvd. Suite 365Houston, TX 77014

Phone: (281) 874 08 88Tool Free: 1 877 559 75 68

Fax: (281) 885 17 42

Dynasol Group. Madrid

C/Titán 15, 9th Floor28045. Madrid, Spain

Phone: (34) 91 753 09 38Fax: (34) 91 323 83 52

[email protected]

dynasolgroup.com