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Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering University of Michigan [email protected] References: http://www.lakescientist.com/learn-about-lakes/water-quality/pollution.html, http://www.calgreeks.com/ifc/sustainability/ Utility University Partnerships Water Resources Recovery Leadership Forum Hosted by: Michigan Department of Environmental Quality Michigan Water Environment Association

Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

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Page 1: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

Sustainability and Innovation

Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering University of Michigan [email protected]

References: http://www.lakescientist.com/learn-about-lakes/water-quality/pollution.html, http://www.calgreeks.com/ifc/sustainability/

Utility University Partnerships

Water Resources Recovery Leadership Forum Hosted by:

Michigan Department of Environmental Quality Michigan Water Environment Association

Page 2: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

Design Life:

Bridge: 50 yrs

Design Life:

Basins: 25 yrs Deep pipes: 50 yrs

Federal Highway System signed into law in 1956

Clean Water Act signed into law in 1972 Safe Drinking Water Act signed into law in 1974

End of infrastructure design life offers opportunities for innovation.

Page 3: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

Design Life:

Bridge: 50 yrs

Design Life:

Basins: 30 yrs Deep pipes: 50 yrs

Federal Highway System signed into law in 1956

Clean Water Act signed into law in 1972 Safe Drinking Water Act signed into law in 1974

End of infrastructure design life offers opportunities for innovation.

Page 4: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

US Population Served by Centralized Wastewater Treatment

Primary Goals: Protect public health by removing pathogens Protect environment by removing oxidizable organic carbon

Year

USEPA, Clean Watersheds Needs Survey, 2012 Report to Congress

Page 5: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

The evolution of conventional, centralized wastewater treatment

Influent

Effluent

Solids Handling

Biosolids

Grit Removal

Screens

Primary Settling

Activated Sludge Chlorine Contact

Anaerobic Digestion

Preliminary Treatment

Primary Treatment

Disinfection

Circa 1960’s

Page 6: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

Oxidation State High energy content Low energy content

-4 -3 -2 -1 0 +1 +2 +3 +4 +5

Carbon CH4

Most wastewater constituents

CO2

Nitrogen NH3 N2 NO2- NO3

-

Phosphorus PO4-3

Key metabolic processes in biological secondary treatment based on oxidation state

aerobic

anaerobic

aerobic

mainstream

anaerobic

sludge processing

Page 7: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

The evolution of conventional, centralized wastewater treatment

Influent

Effluent

Solids Handling

Biosolids

Grit Removal

Screens

Primary Settling

Activated Sludge Chlorine Contact

Anaerobic Digestion

Preliminary Treatment

Primary Treatment

Disinfection

Circa 1960’s

Page 8: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

The evolution of conventional, centralized wastewater treatment

Influent

Effluent

Solids Handling

Biosolids

Dewater

Grit Removal

Screens

Primary Settling

Activated Sludge Secondary Settling Chlorine

Contact

Anaerobic Digestion

Preliminary Treatment

Primary Treatment

Secondary Treatment Disinfection

Circa 1980’s

Page 9: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

US Population Served by Centralized Wastewater Treatment

Year

USEPA, Clean Watersheds Needs Survey, 2012 Report to Congress

Primary Goals: Protect public health by removing pathogens Protect environment by removing oxidizable organic carbon, nitrogen and phosphorus

Page 10: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

US Population Served by Centralized Wastewater Treatment

Year

USEPA, Clean Watersheds Needs Survey, 2012 Report to Congress

Primary Goals: Protect public health by removing pathogens Protect environment by removing oxidizable organic carbon, nitrogen and phosphorus

Page 11: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

CDC, Morbidity Mortalilty Weekly Report, Achievements in Public Health: 1900-1999, Control of Infectious Diseases, July 30, 1999, 49(29):621-629.

Pneumonia

Stroke

Tuberculosis

Diarrhea & Enteritis

Heart Disease

Liver Disease

Injuries

Cancer

Senility

Diphtheria

The 10 leading causes of death as a percentage of all deaths – United States, 1900 and 2015.

2015

1900

0 10 20 30 40

Heart disease

Cancer

Chronic lower respiratory disease

Accidents

Stroke

Alzheimer's disease

Diabetes

Influenze and pneumonia

Kidney disease

Suicide

http://www.medicalnewstoday.com/articles/282929.php

Page 12: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

US Population Served by Centralized Wastewater Treatment

Year

USEPA, Clean Watersheds Needs Survey, 2012 Report to Congress

Primary Goals: Protect public health by removing pathogens Protect environment by removing oxidizable organic carbon, nitrogen and phosphorus

Page 13: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

http://www.zaragoza.es/ciudad/medioambiente/onu/en/detallePer_Onu?id=71

Page 14: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

Oxidation State High energy content Low energy content

-4 -3 -2 -1 0 +1 +2 +3 +4 +5

Carbon CH4

Most wastewater constituents

CO2

Nitrogen NH3 N2 NO2- NO3

-

Phosphorus PO4-3

Key metabolic processes in biological secondary treatment based on oxidation state

anaerobic

aerobic

mainstream

anaerobic

sludge processing

aerobic

Focus is on Nitrogen Removal

Page 15: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

Cordell et al., Global Environmental Change (2009)

Phosphorus removal and recovery: Convert from soluble to insoluble form that can be reused for beneficial purpose.

NASA/Earth Observatory (2011)

Page 16: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

Oxidation State High energy content Low energy content

-4 -3 -2 -1 0 +1 +2 +3 +4 +5

Carbon CH4

Most wastewater constituents

CO2

Nitrogen NH3 N2 NO2- NO3

-

Phosphorus PO4-3

Key metabolic processes in biological secondary treatment based on oxidation state

aerobic

anaerobic

aerobic

mainstream

anaerobic

sludge processing

Page 17: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

Phosphorus Recovery

Chemically precipitated

Biologically sequestered as polyphosphate

Chemically sequestered as struvite

www.kemira.com Kortsee et al. 2000. Biokhimiya. Guest et al. 2009. ES&T.

Page 18: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

The evolution of conventional, centralized wastewater treatment

Influent

Effluent

Solids Handling

Biosolids

Dewater

Grit Removal

Screens

Primary Settling

Activated Sludge Secondary Settling Chlorine

Contact

Anaerobic Digestion

Preliminary Treatment

Primary Treatment

Secondary Treatment Disinfection

Circa 1980’s

Page 19: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

The evolution of conventional, centralized wastewater treatment

Influent

Effl

uen

t

Solids Handling

Biosolids

Dewater

Grit Removal

Screens

Primary Settling

Anaerobic Digestion

Preliminary Treatment

Primary Treatment

Secondary + Advanced Treatment

Dis

infe

ctio

n

Alum Electron

donor

Circa 2005 Schematic for Broad Run Water Reclamation Facility

Page 20: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

The evolution of conventional, centralized wastewater treatment

Influent

Effl

uen

t

Solids Handling

Biosolids

Dewater

Grit Removal

Screens

Primary Settling

Anaerobic Digestion

Preliminary Treatment

Primary Treatment

Secondary + Advanced Treatment

Dis

infe

ctio

n

Alum Electron

donor

Circa 2010

Benefits • Fits within conventional infrastructure layout • Achieves high quality effluent • Enhanced microbial diversity • Possibly enhanced trace organic contaminant removal

Limitations • Energy Intensive • Not optimized for any one biological metabolism • Not optimized for energy or resource capture • Large footprint

Page 21: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

http://www.zaragoza.es/ciudad/medioambiente/onu/en/detallePer_Onu?id=71

Rosso et al. (2008) http://www.hazenandsawyer.com

Tchobanoglous et al., 2013

Energy required for centralized, conventional secondary wastewater

treatment

Energy available in average wastewater for treatment

1,200 to 2,400 MJ/1000 m3

6,000 MJ/1000 m3

Page 22: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

t=0 t=1 year t=6 years

Floating sludge Before DO reduction

Good settling After DO reduction

Page 23: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

N conversion (NH4+ NO3

-)

N removal (NH4+ N2) P recovery (PO4

3- cell-incorporated

polyP granules)

P removal (PO43- precipitated)

C, N, P

CO2

sludge Nutrients in dewatering fluids

C removal via oxidation

Conventional single-sludge approach

Page 24: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

C removal via oxidation

Low energy N removal via NO2-

P, N recovery as algae

P removal (PO43- precipitated)

C, N, P

CO2

Sludge (C capture)

Short SRT, Granular, Bioelectrolysis C recovery as methane

P, N recovery as struvite or algae

N removal by N2 via anammox

C capture via reduction

N recovery (NH4+ algae)

Low energy N removal via NO2-

P recovery (PO43- algae) C, N, P

CH4

sludge Thermal treatment to fertilizer or adsorbant

Separate sludge (A B) approach

Page 25: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

C removal via oxidation

Low energy N removal via NO2-

P, N recovery as algae

P removal (PO43- precipitated)

C, N, P

CO2

Sludge (C capture)

Short SRT, Granular, Bioelectrolysis C recovery as methane

P, N recovery as struvite or algae

N removal by N2 via anammox

C capture via reduction

N recovery (NH4+ algae)

Low energy N removal via NO2-

P recovery (PO43- algae) C, N, P

CH4

sludge Thermal treatment to fertilizer or adsorbant

Separate sludge (A B) approach

Page 26: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

C removal via oxidation

Low energy N removal via NO2-

P, N recovery as algae

P removal (PO43- precipitated)

C, N, P

CO2

Sludge (C capture)

Short SRT, Granular, Bioelectrolysis C recovery as methane

P, N recovery as struvite or algae

N removal by N2 via anammox

C capture via reduction

N recovery (NH4+ algae)

Low energy N removal via NO2-

P recovery (PO43- algae) C, N, P

CH4

sludge Thermal treatment to fertilizer or adsorbent

Separate sludge (A B) approach

Page 27: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

We are using models and experiments to develop MABR and GSR technologies that use less aeration.

Membrane Aerated Biofilm Reactor Granular Sludge Sequencing Batch Reactor

Counter-Current Co-Current

Jeseth Delgado Vela Ph.D. Candidate

Zerihun Alemayehu Ph.D. Student

Dr. Charles Bott HRSD

Dr. Kelly Martin Black & Veatch

Page 28: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

References: http://www.lakescientist.com/learn-about-lakes/water-quality/pollution.html, http://www.calgreeks.com/ifc/sustainability/

(Waste)water Management, Reuse and Recovery

Page 29: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

What is the impact of microaerobic treatment environments on trace organic chemical transformations?

Dr. Lauren Stadler Rice University

Page 30: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

Low DO treatment directly and indirectly impacts pharmaceutical transformations.

Dissolved oxygen (DO)

Microbial community

Pharmaceutical biotransformations

(1) it is a limiting substrate and slows the activity of aerobic microorganisms

(2) it shapes the microbial community. Growth in low DO conditions results in:

• increased biomass concentration • enrichment of ammonia oxidizing bacteria (AOB) • increased microbial diversity

Stadler and Love, In review. Impact of microbial physiology and microbial community structure on pharmaceutical fate driven by dissolved oxygen concentration in nitrifying bioreactors

Page 31: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

Low DO treatment directly and indirectly impacts pharmaceutical transformations.

Dissolved oxygen (DO)

Microbial community

Pharmaceutical biotransformations

(1) it is a limiting substrate and slows the activity of aerobic microorganisms

(2) it shapes the microbial community. Growth in low DO conditions results in:

• increased biomass concentration • enrichment of ammonia oxidizing bacteria (AOB) • increased microbial diversity

Stadler and Love, In review. Impact of microbial physiology and microbial community structure on pharmaceutical fate driven by dissolved oxygen concentration in nitrifying bioreactors

Pharmaceutical transformation is comparable to faster under low DO environments

Page 32: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

Sustainability and Innovation

Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering University of Michigan [email protected]

References: http://www.lakescientist.com/learn-about-lakes/water-quality/pollution.html, http://www.calgreeks.com/ifc/sustainability/

Utility University Partnerships

Water Resources Recovery Leadership Forum Hosted by:

Michigan Department of Environmental Quality Michigan Water Environment Association

Page 33: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

Utility University Partnerships

Facilitate Innovation

Requires mutually understanding the needs and offerings of the other

Rules are different at every utility and university

Not constrained to partnerships only with those in your back yard

Engage the next generation of water professionals

Page 34: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

Utility University Partnerships

Facilitate Innovation

Requires mutually understanding the needs and offerings of the other

Rules are different at every utility and university

Not constrained to partnerships only with those in your back yard

Engage the next generation of water professionals

Page 35: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

Utility University Partnerships

Facilitate Innovation

Requires mutually understanding the needs and offerings of the other

Rules are different at every utility and university

Not constrained to partnerships only with those in your back yard

Engage the next generation of water professionals

Page 36: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

Utility University Partnerships

Facilitate Innovation

Requires mutually understanding the needs and offerings of the other

Rules are different at every utility and university

Not constrained to partnerships only with those in your back yard

Engage the next generation of water professionals

Page 37: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

Utility University Partnerships

Facilitate Innovation

Requires mutually understanding the needs and offerings of the other

Rules are different at every utility and university

Not constrained to partnerships only with those in your back yard

Engage the next generation of water professionals

Page 38: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

Utility University Partnerships

Facilitate Innovation

Requires mutually understanding the needs and offerings of the other

Rules are different at every utility and university

Not constrained to partnerships only with those in your back yard

Engage the next generation of water professionals

Page 39: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

Utility University Partnerships

Facilitate Innovation

Requires mutually understanding the needs and offerings of the other

Rules are different at every utility and university

Not constrained to partnerships only with those in your back yard

Engage the next generation of water professionals

Page 40: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

Leaders Innovation Forum for Technology http://www.werf.org/lift

Page 41: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

Leaders Innovation Forum for Technology http://www.werf.org/lift

Page 42: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

https://deepblue.lib.umich.edu/handle/2027.42/39366

Access to University resources is getting easier

Page 43: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

Sustainability and Innovation

Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering University of Michigan [email protected]

References: http://www.lakescientist.com/learn-about-lakes/water-quality/pollution.html, http://www.calgreeks.com/ifc/sustainability/

Utility University Partnerships

Water Resources Recovery Leadership Forum Hosted by:

Michigan Department of Environmental Quality Michigan Water Environment Association

Page 44: Sustainability and Innovation - mi-wea.org and Utility-University... · Sustainability and Innovation Nancy G. Love, Ph.D., P.E., BCEE Department of Civil and Environmental Engineering

At the Confluence: Nutrients, Trace Chemicals and Sustainability in the Urban Water Sector

The Interplay Between Chemicals and the Microbiome: An Environmental Biotechnology Perspective

http://aeesp.org/distinguished-lecturer