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2002 Bridged compounds
Bridged compoundsQ 0060 Synthesis of 7-anti-Bromo-3,3-dimethyl-2-oxonorbornane-1-carboxylic Acid:
A New Chiral Source from the Chiral Pool. — A new chiral fenchone-type norbor-nane carboxylic acid is prepared from commercially available camphor derivative (I) using a Wagner—Meerwein rearrangement as the key step. — (GARCIA MARTINEZ*, A.; TESO VILAR, E.; GARCIA FRAILE, A.; DE LA MOYA CERERO, S.; LORA MAROTO, B.; Tetrahedron: Asymmetry 13 (2002) 17, 1837-1840; Dep. Quim. Org., Fac. Cienc. Quim., Univ. Complutense, E-28040 Madrid, Spain; Eng.) — Nuesgen
04- 082