Technical Report for Franklin Township Board Of … Technical Report for Franklin Township Board Of Education Pine Grove Manor, 130 Highland Avenue, Somerset, NJ 16-4779 SGS Accutest

05/05/16

Technical Report for

Franklin Township Board Of Education

Pine Grove Manor, 130 Highland Avenue, Somerset, NJ

16-4779

SGS Accutest Job Number: JC18894

Sampling Date: 04/22/16

Report to:

Franklin Township Board Of Education1755 Amwell RoadSomerset, NJ [email protected]

ATTN: Rick Goetz

Total number of pages in report:

Certifications: NJ(12129), NY(10983), CA, CT, DE, FL, IL, IN, KS, KY, LA, MA, MD, MI, MT, NC,

OH VAP (CL0056), AK (UST-103), AZ (AZ0786), PA, RI, SC, TN, TX, VA, WV, DoD ELAP (L-A-B L2248)

This report shall not be reproduced, except in its entirety, without the written approval of SGS Accutest.

Test results relate only to samples analyzed.

New Jersey • 2235 Route 130 • Dayton, NJ 08810 • tel: 732-329-0200 • fax: 732-329-3499 • http://www.accutest.com

Test results contained within this data package meet the requirements

of the National Environmental Laboratory Accreditation Program

and/or state specific certification programs as applicable.

Client Service contact: Kelly Patterson 732-329-0200

Nancy ColeLaboratory Director

New Jersey 05/05/16

e-Hardcopy 2.0Automated Report

43

SGS Accutest is the sole authority for authorizing edits or modifications to this document.Unauthorized modification of this report is strictly prohibited.

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JC18894

Table of Contents-1-

Sections:

Section 1: Sample Summary ................................................................................................... 3Section 2: Case Narrative/Conformance Summary .............................................................. 4Section 3: Summary of Hits .................................................................................................... 5Section 4: Sample Results ........................................................................................................ 6

4.1: JC18894-1: WATER FOUNTAIN MAIN OFFICE ...................................................... 74.2: JC18894-2: WATER FOUNTAIN BY RM 23 .............................................................. 84.3: JC18894-3: DOWNSTAIRS FACULTY RM ............................................................... 94.4: JC18894-4: KITCHEN ................................................................................................. 10

Section 5: Misc. Forms ............................................................................................................ 115.1: Chain of Custody ........................................................................................................... 125.2: Sample Tracking Chronicle ........................................................................................... 145.3: Internal Chain of Custody .............................................................................................. 15

Section 6: Metals Analysis - QC Data Summaries ................................................................ 166.1: Inst QC MA39269: Cu,Pb ............................................................................................. 176.2: Prep QC MP93341: Cu,Pb ............................................................................................. 366.3: Prep QC MP93342: Cu,Pb ............................................................................................. 40

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Sample Summary

Franklin Township Board Of EducationJob No: JC18894

Pine Grove Manor, 130 Highland Avenue, Somerset, NJProject No: 16-4779

Sample Collected Matrix Client Number Date Time By Received Code Type Sample ID

JC18894-1 04/22/16 07:10 RG 04/22/16 DW Drinking Water WATER FOUNTAIN MAIN OFFICE

JC18894-2 04/22/16 07:25 RG 04/22/16 DW Drinking Water WATER FOUNTAIN BY RM 23

JC18894-3 04/22/16 07:15 RG 04/22/16 DW Drinking Water DOWNSTAIRS FACULTY RM

JC18894-4 04/22/16 07:00 RG 04/22/16 DW Drinking Water KITCHEN

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1

On 04/22/2016, 4 Sample(s), 0 Trip Blank(s) and 0 Field Blank(s) were received at Accutest Laboratories at a maximum corrected temperature of 3.5 C. Samples were intact and chemically preserved, unless noted below. An Accutest Job Number of JC18894 was assigned to the project. Laboratory sample ID, client sample ID and dates of sample collection are detailed in the report’s Results Summary Section.

Specified quality control criteria were achieved for this job except as noted below. For more information, please refer to the analytical results and QC summary pages.

Client: Franklin Township Board Of Education

Site: Pine Grove Manor, 130 Highland Avenue, Somerset, NJ

Job No JC18894

Report Date 5/5/2016 1:37:48 PM

CASE NARRATIVE / CONFORMANCE SUMMARY

Compounds qualified as out of range in the continuing calibration summary report are acceptable as per method requirements when there is a high bias but the sample result is non-detect.

Metals By Method EPA 200.8Matrix: DW Batch ID: MP93341

All samples were digested within the recommended method holding time.

All method blanks for this batch meet method specific criteria.

Sample(s) JC18892-1MS, JC18892-1MSD were used as the QC samples for metals.

Matrix: DW Batch ID: MP93342

All samples were digested within the recommended method holding time.

All method blanks for this batch meet method specific criteria.

Sample(s) JC18894-3MS, JC18894-3MSD were used as the QC samples for metals.

Accutest certifies that data reported for samples received, listed on the associated custody chain or analytical task order, were produced to specifications meeting Accutest’s Quality System precision, accuracy and completeness objectives except as noted.

Estimated non-standard method measurement uncertainty data is available on request, based on quality control bias and implicit for standard methods. Acceptable uncertainty requires tested parameter quality control data to meet method criteria.

Accutest Laboratories is not responsible for data quality assumptions if partial reports are used and recommends that this report be used in its entirety. Data release is authorized by Accutest Laboratories indicated via signature on the report cover

Thursday, May 05, 2016 Page 1 of 1

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Summary of Hits Page 1 of 1 Job Number: JC18894Account: Franklin Township Board Of EducationProject: Pine Grove Manor, 130 Highland Avenue, Somerset, NJCollected: 04/22/16

Lab Sample ID Client Sample ID Result/Analyte Qual RL MDL Units Method

JC18894-1 WATER FOUNTAIN MAIN OFFICE

Copper 0.062 0.0040 mg/l EPA 200.8Lead 0.0070 0.00050 mg/l EPA 200.8

JC18894-2 WATER FOUNTAIN BY RM 23


JC18894-3 DOWNSTAIRS FACULTY RM


JC18894-4 KITCHEN


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SGS Accutest

Sample Results

Report of Analysis

New JerseySection 4

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SGS Accutest

Report of Analysis Page 1 of 1

Client Sample ID: WATER FOUNTAIN MAIN OFFICE Lab Sample ID: JC18894-1 Date Sampled: 04/22/16 Matrix: DW - Drinking Water Date Received: 04/22/16

Percent Solids: n/a Project: Pine Grove Manor, 130 Highland Avenue, Somerset, NJ

Total Metals Analysis

Analyte Result MCL RL Units DF Prep Analyzed By Method Prep Method

Copper 0.062 1.3 0.0040 mg/l 1 04/26/16 04/26/16 JO EPA 200.8 1 EPA 200.8 2

Lead 0.0070 0.015 0.00050mg/l 1 04/26/16 04/26/16 JO EPA 200.8 1 EPA 200.8 2

(1) Instrument QC Batch: MA39269(2) Prep QC Batch: MP93341

RL = Reporting LimitMCL = Maximum Contamination Level (NJAC 7:10 11/04)

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SGS Accutest


Client Sample ID: WATER FOUNTAIN BY RM 23 Lab Sample ID: JC18894-2 Date Sampled: 04/22/16 Matrix: DW - Drinking Water Date Received: 04/22/16








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Client Sample ID: DOWNSTAIRS FACULTY RM Lab Sample ID: JC18894-3 Date Sampled: 04/22/16 Matrix: DW - Drinking Water Date Received: 04/22/16








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Client Sample ID: KITCHEN Lab Sample ID: JC18894-4 Date Sampled: 04/22/16 Matrix: DW - Drinking Water Date Received: 04/22/16








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SGS Accutest

Misc. Forms

Custody Documents and Other Forms

Includes the following where applicable:

• Chain of Custody• Sample Tracking Chronicle• Internal Chain of Custody

New JerseySection 5

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JC18894: Chain of CustodyPage 1 of 2

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SGS Accutest Sample Receipt Summary

Job Number: JC18894 Client:

Date / Time Received: 4/22/2016 3:30:00 PM Delivery Method:

Project:

4. No. Coolers: 4

Airbill #'s:

Cooler Security

1. Custody Seals Present:

Y or N

2. Custody Seals Intact:

3. COC Present:

4. Smpl Dates/Time OK

2. Cooler temp verification:

Cooler Temperature Y or N

1. Temp criteria achieved:

3. Cooler media:

IR Gun

Ice (Bag)

Quality Control Preservation Y or N N/A

1. Trip Blank present / cooler:

2. Trip Blank listed on COC:

3. Samples preserved properly:

4. VOCs headspace free:

Sample Integrity - Documentation Y or N

1. Sample labels present on bottles:

2. Container labeling complete:

3. Sample container label / COC agree:

Sample Integrity - Condition Y or N

1. Sample recvd within HT:

3. Condition of sample:

2. All containers accounted for:

Sample Integrity - Instructions

1. Analysis requested is clear:

2. Bottles received for unspecified tests

3. Sufficient volume recvd for analysis:

4. Compositing instructions clear:

5. Filtering instructions clear:

Intact

Y or N

Comments

Y or N N/A

Cooler Temps (Raw Measured) °C:

Cooler Temps (Corrected) °C:

Cooler 1: (2.2); Cooler 2: (3.1); Cooler 3: (2.8); Cooler 4: (2.0);

Cooler 1: (2.6); Cooler 2: (3.5); Cooler 3: (3.2); Cooler 4: (2.4);

JC18894: Chain of CustodyPage 2 of 2

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SGS Accutest

Internal Sample Tracking Chronicle

Franklin Township Board Of EducationJob No: JC18894

Pine Grove Manor, 130 Highland Avenue, Somerset, NJProject No: 16-4779

SampleNumber Method Analyzed By Prepped By Test Codes

JC18894-1 Collected: 22-APR-16 07:10 By: RG Received: 22-APR-16 By: ASWATER FOUNTAIN MAIN OFFICE

JC18894-1 EPA 200.8 26-APR-16 15:32 JO 26-APR-16 JO CUMS,PBMS

JC18894-2 Collected: 22-APR-16 07:25 By: RG Received: 22-APR-16 By: ASWATER FOUNTAIN BY RM 23


JC18894-3 Collected: 22-APR-16 07:15 By: RG Received: 22-APR-16 By: ASDOWNSTAIRS FACULTY RM


JC18894-4 Collected: 22-APR-16 07:00 By: RG Received: 22-APR-16 By: ASKITCHEN


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SGS Accutest Internal Chain of Custody Page 1 of 1 Job Number: JC18894Account: FTBE Franklin Township Board Of EducationProject: Pine Grove Manor, 130 Highland Avenue, Somerset, NJReceived: 04/22/16

Sample.Bottle Transfer TransferNumber FROM TO Date/Time Reason

JC18894-1.1 Secured Storage Alfredo Crespo 04/25/16 15:04 Retrieve from StorageJC18894-1.1 Alfredo Crespo Secured Staging Area 04/25/16 15:04 Return to StorageJC18894-1.1 Secured Staging Area Lucas Schneider 04/25/16 15:23 Retrieve from StorageJC18894-1.1 Lucas Schneider Secured Storage 04/25/16 23:42 Return to StorageJC18894-1.1 Secured Storage Luis Villanueva 04/26/16 08:38 Retrieve from StorageJC18894-1.1 Luis Villanueva Secured Staging Area 04/26/16 08:38 Return to StorageJC18894-1.1 Secured Staging Area Jaclyn O'Connor 04/26/16 08:41 Retrieve from StorageJC18894-1.1 Jaclyn O'Connor Secured Storage 04/26/16 15:40 Return to Storage




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SGS Accutest

Metals Analysis

QC Data Summaries

Includes the following where applicable:

• Instrument Runlogs• Initial and Continuing Calibration Blanks• Initial and Continuing Calibration Checks• High and Low Check Standards• Interfering Element Check Standards• Method Blank Summaries• Matrix Spike and Duplicate Summaries• Blank Spike and Lab Control Sample Summaries• Serial Dilution Summaries

New JerseySection 6

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SGS Accutest Instrument Runlog Inorganics Analyses

Login Number: JC18894 Account: FTBE - Franklin Township Board Of Education

Project: Pine Grove Manor, 130 Highland Avenue, Somerset, NJ

File ID: XB042616W1.CSV Date Analyzed: 04/26/16 Methods: EPA 200.8 Analyst: JO Run ID: MA39269 Parameters: Cu,Pb

Sample Dilution PS Time Description Factor Recov Comments

10:10 MA39269-STD1 1 STDA

10:13 MA39269-STD2 1 STDA

10:16 MA39269-STD3 1 STDA

10:20 MA39269-STD4 1 STDB1

10:23 MA39269-STD5 1 STDB

10:26 MA39269-STD6 1 STDC

10:29 MA39269-STD7 1 STDD

10:33 MA39269-STD8 1 STDE

10:36 MA39269-STD9 1 STDF

10:39 MA39269-STD10 1 STDG

10:42 MA39269-STD11 1 STDH

10:45 MA39269-STD12 1 STDI

10:49 MA39269-STD13 1 STDJ

10:58 ZZZZZZ 1

11:01 MA39269-ICVA1 1

11:05 MA39269-ICV1 1

11:08 MA39269-ICB1 1

11:11 MA39269-CRIA1 1 0.3ppb Be, 1ppb As and Se

11:14 MA39269-CRI1 1

11:17 MA39269-CCVA1 1

11:21 MA39269-CCB1 1

11:30 MP93342-MB1 1

11:34 MP93342-B1 1

11:37 MP93342-S1 1

11:40 MP93342-S2 1

11:44 JC18894-3 1

11:47 JC18894-4 1

11:50 ZZZZZZ 1

11:54 ZZZZZZ 1

11:57 ZZZZZZ 1

12:00 MA39269-CCVA2 1

12:04 MA39269-CCB2 1

12:07 ZZZZZZ 1

_________________________________________________________________________________________________________

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12:11 ZZZZZZ 1

12:14 ZZZZZZ 1

12:17 ZZZZZZ 1

12:21 ZZZZZZ 1

12:24 ZZZZZZ 1

12:27 MA39269-CCVA3 1

12:31 MA39269-CCB3 1

12:34 MP93343-MB1 1

12:37 MP93343-B1 1

12:41 MP93343-S1 1

12:44 MP93343-S2 1

12:47 ZZZZZZ 1

12:51 JC18897-1 1 (sample used for QC only; not part of login JC18894)

12:54 ZZZZZZ 1

12:57 ZZZZZZ 1

13:01 ZZZZZZ 1

13:04 MA39269-CCVA4 1

13:08 MA39269-CCB4 1

13:11 MP93340-MB1 1

13:14 MP93340-B1 1

13:17 MP93340-S1 1

13:21 MP93340-S2 1

13:24 ZZZZZZ 1


13:31 ZZZZZZ 1

13:34 ZZZZZZ 1

13:38 ZZZZZZ 1

13:41 MA39269-CCVA5 1

13:45 MA39269-CCB5 1

13:48 ZZZZZZ 1

13:51 ZZZZZZ 1

13:54 ZZZZZZ 1

13:58 ZZZZZZ 1

_________________________________________________________________________________________________________

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14:01 ZZZZZZ 1

14:05 MP93340-S1 2 Cu

14:08 MP93340-S2 2 Cu

14:11 ZZZZZZ 1

14:15 MA39269-CCVA6 1

14:18 MA39269-CCB6 1


14:25 ZZZZZZ 2

14:28 ZZZZZZ 2

14:31 ZZZZZZ 2

14:35 MA39269-CCVA7 1

14:38 MA39269-CCB7 1

14:41 MP93341-MB1 1

14:45 MP93341-B1 1

14:48 MP93341-S1 1

14:51 MP93341-S2 1

14:55 ZZZZZZ 1


15:01 ZZZZZZ 1

15:05 ZZZZZZ 1

15:08 ZZZZZZ 1

15:12 MA39269-CCVA8 1

15:15 MA39269-CCB8 1

15:18 ZZZZZZ 1

15:22 ZZZZZZ 1

15:25 ZZZZZZ 1

15:28 ZZZZZZ 1

15:32 JC18894-1 1

15:35 JC18894-2 1 -----------> Last reportable sample/prep for job JC18894

15:39 ZZZZZZ 5

15:42 ZZZZZZ 1

15:45 MA39269-CCVA9 1

15:49 MA39269-CCB9 1 -----------> Last reportable CCB for job JC18894

Refer to raw data for calibration curve and standards._________________________________________________________________________________________________________

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INTERNAL STANDARD SUMMARY




Sample Time Description Istd#1 Istd#2 Istd#3 Istd#4 Istd#5 Istd#6 Istd#7 Istd#8

10:10 MA39269-STD1 100 100 100 100 100 100 100 100

10:13 MA39269-STD2 100 100 100 100 100 100 100 100

10:16 MA39269-STD3 100 100 100 100 100 100 100 100

10:20 MA39269-STD4 101.524 99.968 99.455 100.02 101.013 100.965 102.719 101.982

10:23 MA39269-STD5 101.704 100.005 98.084 100.553 101.31 101.611 103.639 102.835

10:26 MA39269-STD6 100.31 101.395 100.042 101.227 101.804 102.418 104.411 104.102

10:29 MA39269-STD7 99.731 98.324 97.526 98.927 100.596 100.784 103.931 102.8

10:33 MA39269-STD8 98.949 96.968 96.293 98.336 99.691 100.181 102.834 102.356

10:36 MA39269-STD9 99.179 97.131 97.142 99.05 99.488 100.576 104.645 104.326

10:39 MA39269-STD10 98.955 96.563 95.512 96.181 98.843 99.731 103.293 102.332

10:42 MA39269-STD11 97.509 94.967 94.809 96.326 97.569 98.65 102.56 102.695

10:45 MA39269-STD12 94.673 93.615 94.333 94.186 95.261 97.073 101.532 101.023

10:49 MA39269-STD13 93.72 93.644 95.392 94.425 94.525 95.892 101.49 100.315

10:58 ZZZZZZ 94.094 93.527 92.798 95.042 97.6 96.664 101.215 99.993

11:01 MA39269-ICVA1 93.276 96.237 95.449 96.729 96.676 98.373 102.539 102.156

11:05 MA39269-ICV1 94.281 94.317 92.755 96.052 97.998 98.306 101.233 100.154

11:08 MA39269-ICB1 92.656 92.263 92.265 93.968 96.896 96.531 99.563 99.736

11:11 MA39269-CRIA1 94.254 93.506 93.312 95.489 97.001 98.03 101.075 100.925

11:14 MA39269-CRI1 95.704 93.833 94.142 96.537 97.862 98.755 102.2 101.891

11:17 MA39269-CCVA1 93.608 94.182 94.463 95.976 96.783 97.5 101.807 101.566

11:21 MA39269-CCB1 94.333 92.687 91.89 94.208 97.01 97.61 100.695 100.15

11:30 MP93342-MB1 93.116 93.412 92.987 95.48 97.288 97.106 100.418 100.261

11:34 MP93342-B1 92.397 93.284 93.275 95.962 96.47 97.326 100.225 100.172

11:37 MP93342-S1 92.987 94.783 93.393 96.098 95.375 97.768 102.635 102.441

11:40 MP93342-S2 92.571 93.951 93.222 95.389 94.884 97.331 102.375 102.464

11:44 JC18894-3 94.475 96.151 94.97 97.908 95.992 99.288 103.911 103.857

11:47 JC18894-4 98.541 101.82 98.206 101.431 101.913 104.412 109.257 109.473

11:50 ZZZZZZ 98.373 100.226 98.066 100.47 99.214 102.402 108.106 107.655

11:54 ZZZZZZ 98.212 100.158 96.939 99.619 98.814 102.706 106.958 106.928

11:57 ZZZZZZ 96.745 97.194 95.307 97.958 95.98 98.715 102.944 103.246

12:00 MA39269-CCVA2 96.534 94.353 94.664 94.86 96.893 97.917 103.911 103.002

12:04 MA39269-CCB2 95.107 95.732 94.542 96.99 98.837 99.168 102.121 101.374

12:07 ZZZZZZ 99.213 104.261 100.276 104.695 103.61 106.171 110.557 110.641

_________________________________________________________________________________________________________

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12:11 ZZZZZZ 97.343 99.713 96.945 100.156 98.073 101.444 105.214 104.856

12:14 ZZZZZZ 99.782 101.299 98.737 101.982 100.659 103.824 108.376 107.536

12:17 ZZZZZZ 101.527 104.314 101.423 103.735 103.458 105.729 111.37 111.088

12:21 ZZZZZZ 100.187 100.817 99.044 102.749 100.178 104.395 108.211 108.474

12:24 ZZZZZZ 99.796 96.951 96.585 99.125 100.523 100.889 103.656 104.089

12:27 MA39269-CCVA3 95.172 93.411 93.52 94.831 96.232 97.953 103.572 103.698

12:31 MA39269-CCB3 95.885 96.819 95.513 97.473 100.962 100.64 103.728 103.603

12:34 MP93343-MB1 95.711 96.083 95.864 96.976 99.629 99.518 103.093 102.953

12:37 MP93343-B1 95.889 96.766 95.991 98.541 101.689 102.016 106.494 106.109

12:41 MP93343-S1 94.119 96.785 96.23 98.73 97.779 100.714 106.333 105.89

12:44 MP93343-S2 93.553 96.479 95.076 97.494 96.921 100.371 105.371 105.821

12:47 ZZZZZZ 94.966 94.379 94.032 96.455 98.513 99.103 103.27 102.861

12:51 JC18897-1 94.817 97.29 96.312 98.604 97.239 100.031 104.983 104.394

12:54 ZZZZZZ 95.264 97.449 95.533 98.368 96.962 100.265 104.121 103.972

12:57 ZZZZZZ 95.325 98.204 96.005 99.098 97.192 100.709 105.581 105.274

13:01 ZZZZZZ 95.484 97.516 95.006 98.439 97.12 99.224 103.577 103.733

13:04 MA39269-CCVA4 95.271 96.396 96.402 97.033 99.091 99.738 105.808 105.172

13:08 MA39269-CCB4 94.398 96.38 95.936 98.142 99.668 99.535 102.294 101.645

13:11 MP93340-MB1 95.881 97.52 96.436 98.81 101.43 101.846 103.452 103.064

13:14 MP93340-B1 91.571 93.394 94.264 96.08 96.574 97.134 100.735 100.684

13:17 MP93340-S1 91.754 96.238 94.708 98.434 96.237 98.035 103.672 103.307

13:21 MP93340-S2 90.758 94.965 93.974 97.689 94.76 96.856 101.494 101.452

13:24 ZZZZZZ 94.223 94.016 94.313 96.143 98.641 98.713 101.465 101.002

13:27 JC18890-1 93.32 96.537 94.291 97.24 95.5 97.816 102.534 102.553

13:31 ZZZZZZ 92.865 96.445 94.107 96.575 94.218 97.59 101.933 101.272

13:34 ZZZZZZ 91.646 95.192 93.204 96.15 93.724 96.483 101.315 100.856

13:38 ZZZZZZ 91.317 92.133 89.386 91.701 90.276 92.527 96.043 95.827

13:41 MA39269-CCVA5 89.298 88.067 88.925 89.618 88.911 89.878 94.806 93.835

13:45 MA39269-CCB5 89.144 90.834 89.387 91.538 93.171 92.311 93.817 94.096

13:48 ZZZZZZ 89.82 93.857 92.014 94.211 91.563 93.071 97.086 96.632

13:51 ZZZZZZ 86.965 89.165 88.004 90.18 87.493 89.818 92.728 92.452

13:54 ZZZZZZ 89.953 90.593 88.659 91.879 89.488 92.7 96.935 96.929

13:58 ZZZZZZ 89.345 90.816 89.545 91.375 89.636 92.696 96.763 96.435

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14:01 ZZZZZZ 89.283 89.909 88.674 90.884 89.595 92.371 96.319 96.168

14:05 MP93340-S1 89.507 89.832 88.878 90.78 90.498 91.629 95.896 94.828

14:08 MP93340-S2 88.771 90.594 89.938 91.907 91.005 92.319 95.649 95.297

14:11 ZZZZZZ 90.032 90.122 88.698 90.859 93.039 92.89 95.392 94.016

14:15 MA39269-CCVA6 88.618 88.286 88.524 90.08 90.342 91.665 95.018 95.547

14:18 MA39269-CCB6 88.444 89.631 89.148 91.483 92.875 93.19 95.602 94.702

14:21 JC18890-1 89.167 92.758 91.699 94.313 92.738 93.584 95.998 95.808

14:25 ZZZZZZ 89.346 92.485 92.38 94.101 92.569 93.592 96.351 96.613

14:28 ZZZZZZ 88.505 91.649 90.711 92.466 91.916 93.206 96.743 95.165

14:31 ZZZZZZ 87.344 87.441 86.805 88.772 88.312 90.105 93.796 93.306

14:35 MA39269-CCVA7 87.201 87.073 88.02 88.351 89.405 89.768 94.329 93.614

14:38 MA39269-CCB7 86.75 88.952 87.596 89.264 91.083 91.517 93.969 93.613

14:41 MP93341-MB1 87.527 88.508 88.077 90.171 91.548 91.875 93.515 92.831

14:45 MP93341-B1 86.716 88.932 88.62 90.323 90.374 90.999 94.338 93.713

14:48 MP93341-S1 87.123 91.953 90.261 92.56 90.905 93.16 96.757 96.319

14:51 MP93341-S2 86.042 89.739 88.957 92.258 89.574 91.935 96.132 95.669

14:55 ZZZZZZ 87.31 87.575 87.471 89.199 90.771 91.226 93.027 92.891

14:58 JC18892-1 86.619 89.656 87.684 90.93 89.336 91.597 95.862 94.471

15:01 ZZZZZZ 85.396 88.271 86.103 88.965 86.835 89.474 93.206 93.086

15:05 ZZZZZZ 86.105 89.725 88.039 90.485 88.655 91.313 95.469 95.032

15:08 ZZZZZZ 85.475 86.666 86.475 88.492 86.205 88.704 92.07 91.499

15:12 MA39269-CCVA8 88.032 87.273 87.533 89.155 89.102 90.26 95.2 93.531

15:15 MA39269-CCB8 87.049 89.58 88.503 90.954 92.25 92.027 93.8 93.494

15:18 ZZZZZZ 88.377 92.724 91.27 93.913 91.793 92.99 96.912 96.157

15:22 ZZZZZZ 86.609 88.303 87.661 90.006 87.488 89.739 94.013 93.713

15:25 ZZZZZZ 87.259 88.978 87.162 89.489 87.951 90.485 95.207 95.22

15:28 ZZZZZZ 85.954 86.523 85.565 88.133 84.894 87.48 91.834 91.638

15:32 JC18894-1 84.962 86.495 84.676 87.678 84.668 86.612 90.477 90.607

15:35 JC18894-2 85.355 87.207 85.432 88.071 84.753 87.158 90.694 90.179

15:39 ZZZZZZ 88.478 88.909 87.915 89.901 89.478 90.159 92.978 92.065

15:42 ZZZZZZ 89.672 90.44 89.256 90.583 91.999 91.244 94.046 93.08

15:45 MA39269-CCVA9 86.021 85.513 85.383 86.537 86.641 87.704 91.482 91.393

15:49 MA39269-CCB9 84.291 86.412 85.269 86.647 88.434 87.372 89.494 88.562

! = Outside limits._________________________________________________________________________________________________________

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66.1.1






LEGEND: Istd# Parameter Limits _______ ________________________ __________ Istd#1 Lithium 60-125 % Istd#2 Scandium 60-125 % Istd#3 Germanium (72-1) 60-125 % Istd#4 Germanium (74-1) 60-125 % Istd#5 Rhodium 60-125 % Istd#6 Indium 60-125 % Istd#7 Terbium 60-125 % Istd#8 Holmium 60-125 %

_________________________________________________________________________________________________________

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Sample Time Description Istd#9

10:10 MA39269-STD1 100

10:13 MA39269-STD2 100

10:16 MA39269-STD3 100

10:20 MA39269-STD4 103.384

10:23 MA39269-STD5 103.887

10:26 MA39269-STD6 105.377

10:29 MA39269-STD7 105.341

10:33 MA39269-STD8 105.203

10:36 MA39269-STD9 106.203

10:39 MA39269-STD10 103.912

10:42 MA39269-STD11 103.043

10:45 MA39269-STD12 101.016

10:49 MA39269-STD13 99.305

10:58 ZZZZZZ 100.35

11:01 MA39269-ICVA1 101.12

11:05 MA39269-ICV1 102.573

11:08 MA39269-ICB1 101.183

11:11 MA39269-CRIA1 102.684

11:14 MA39269-CRI1 102.943

11:17 MA39269-CCVA1 101.574

11:21 MA39269-CCB1 102.475

11:30 MP93342-MB1 101.495

11:34 MP93342-B1 102.204

11:37 MP93342-S1 102.672

11:40 MP93342-S2 101.651

11:44 JC18894-3 103.313

11:47 JC18894-4 107.994

11:50 ZZZZZZ 104.346

11:54 ZZZZZZ 103.148

11:57 ZZZZZZ 100.154

12:00 MA39269-CCVA2 103.956

12:04 MA39269-CCB2 103.19

12:07 ZZZZZZ 106.084

_________________________________________________________________________________________________________

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66.1.1






12:11 ZZZZZZ 103.082

12:14 ZZZZZZ 104.85

12:17 ZZZZZZ 107.922

12:21 ZZZZZZ 106.572

12:24 ZZZZZZ 106.966

12:27 MA39269-CCVA3 104.238

12:31 MA39269-CCB3 104.179

12:34 MP93343-MB1 104.791

12:37 MP93343-B1 107.42

12:41 MP93343-S1 103.86

12:44 MP93343-S2 104.057

12:47 ZZZZZZ 104.295

12:51 JC18897-1 102.251

12:54 ZZZZZZ 102.031

12:57 ZZZZZZ 102.248

13:01 ZZZZZZ 101.52

13:04 MA39269-CCVA4 105.621

13:08 MA39269-CCB4 103.295

13:11 MP93340-MB1 106.183

13:14 MP93340-B1 102.586

13:17 MP93340-S1 101.513

13:21 MP93340-S2 100.077

13:24 ZZZZZZ 104.267

13:27 JC18890-1 99.969

13:31 ZZZZZZ 98.655

13:34 ZZZZZZ 98.133

13:38 ZZZZZZ 93.521

13:41 MA39269-CCVA5 94.898

13:45 MA39269-CCB5 95.933

13:48 ZZZZZZ 92.597

13:51 ZZZZZZ 92.061

13:54 ZZZZZZ 94.476

13:58 ZZZZZZ 94.666

_________________________________________________________________________________________________________

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66.1.1






14:01 ZZZZZZ 95.069

14:05 MP93340-S1 93.278

14:08 MP93340-S2 94.516

14:11 ZZZZZZ 96.639

14:15 MA39269-CCVA6 95.458

14:18 MA39269-CCB6 95.899

14:21 JC18890-1 94.972

14:25 ZZZZZZ 95.228

14:28 ZZZZZZ 94.193

14:31 ZZZZZZ 93.512

14:35 MA39269-CCVA7 94.377

14:38 MA39269-CCB7 94.44

14:41 MP93341-MB1 94.322

14:45 MP93341-B1 94.791

14:48 MP93341-S1 95.141

14:51 MP93341-S2 94.91

14:55 ZZZZZZ 94.435

14:58 JC18892-1 94.238

15:01 ZZZZZZ 91.524

15:05 ZZZZZZ 92.935

15:08 ZZZZZZ 90.235

15:12 MA39269-CCVA8 94.141

15:15 MA39269-CCB8 94.845

15:18 ZZZZZZ 95.098

15:22 ZZZZZZ 91.981

15:25 ZZZZZZ 92.301

15:28 ZZZZZZ 88.625

15:32 JC18894-1 89.732

15:35 JC18894-2 88.978

15:39 ZZZZZZ 93.21

15:42 ZZZZZZ 94.46

15:45 MA39269-CCVA9 91.103

15:49 MA39269-CCB9 89.637

! = Outside limits._________________________________________________________________________________________________________

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66.1.1






LEGEND: Istd# Parameter Limits _______ ________________________ __________ Istd#9 Bismuth 60-125 %

_________________________________________________________________________________________________________

Page 8

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JC18894

66.1.1

BLANK RESULTS SUMMARY Part 1 - Initial and Continuing Calibration Blanks



File ID: XB042616W1.CSV Date Analyzed: 04/26/16 Methods: EPA 200.8 QC Limits: result < RL Run ID: MA39269 Units: ug/l

Time: 11:08 11:21 12:04 12:31 Sample ID: ICB1 CCB1 CCB2 CCB3

Metal RL IDL raw final raw final raw final raw final

Aluminum 50 .1

Antimony 2.0 .12

Arsenic 1.0 .38

Barium 1.0 .011

Beryllium 0.30 .004

Boron 50 3.2

Cadmium 0.50 .008

Calcium 250 2.7

Chromium 4.0 .019

Cobalt 0.50 .003

Copper 4.0 .02 -0.092 <4.0 -0.083 <4.0 0.00090 <4.0 -0.029 <4.0

Iron 50 1.1

Lead 0.50 .009 0.0040 <0.50 0.011 <0.50 0.018 <0.50 0.017 <0.50

Magnesium 250 .17

Manganese 1.0 .019

Molybdenum 1.0 .02

Nickel 4.0 .028

Potassium 250 2

Selenium 1.0 .29

Silver 2.0 .019

Sodium 250 3.9

Strontium 1.0 .009

Thallium 0.50 .016

Tin 1.0 .039

Titanium 1.0 .034

Vanadium 4.0 .11

Zinc 10 .29

(*) Outside of QC limits(anr) Analyte not requested

_________________________________________________________________________________________________________

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66.1.2





Time: 13:08 13:45 14:18 14:38 Sample ID: CCB4 CCB5 CCB6 CCB7

Metal RL IDL raw final raw final raw final raw final

Aluminum 50 .1

Antimony 2.0 .12

Arsenic 1.0 .38

Barium 1.0 .011

Beryllium 0.30 .004

Boron 50 3.2

Cadmium 0.50 .008

Calcium 250 2.7

Chromium 4.0 .019

Cobalt 0.50 .003

Copper 4.0 .02 -0.012 <4.0 0.018 <4.0 -0.0072 <4.0 -0.0073 <4.0

Iron 50 1.1

Lead 0.50 .009 0.023 <0.50 0.027 <0.50 0.029 <0.50 0.024 <0.50

Magnesium 250 .17

Manganese 1.0 .019

Molybdenum 1.0 .02

Nickel 4.0 .028

Potassium 250 2

Selenium 1.0 .29

Silver 2.0 .019

Sodium 250 3.9

Strontium 1.0 .009

Thallium 0.50 .016

Tin 1.0 .039

Titanium 1.0 .034

Vanadium 4.0 .11

Zinc 10 .29


_________________________________________________________________________________________________________

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66.1.2





Time: 15:15 15:49 Sample ID: CCB8 CCB9

Metal RL IDL raw final raw final

Aluminum 50 .1

Antimony 2.0 .12

Arsenic 1.0 .38

Barium 1.0 .011

Beryllium 0.30 .004

Boron 50 3.2

Cadmium 0.50 .008

Calcium 250 2.7

Chromium 4.0 .019

Cobalt 0.50 .003

Copper 4.0 .02 -0.024 <4.0 0.080 <4.0

Iron 50 1.1

Lead 0.50 .009 0.026 <0.50 0.021 <0.50

Magnesium 250 .17

Manganese 1.0 .019

Molybdenum 1.0 .02

Nickel 4.0 .028

Potassium 250 2

Selenium 1.0 .29

Silver 2.0 .019

Sodium 250 3.9

Strontium 1.0 .009

Thallium 0.50 .016

Tin 1.0 .039

Titanium 1.0 .034

Vanadium 4.0 .11

Zinc 10 .29


_________________________________________________________________________________________________________

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JC18894

66.1.2

CALIBRATION CHECK STANDARDS SUMMARY Initial and Continuing Calibration Checks



File ID: XB042616W1.CSV Date Analyzed: 04/26/16 Methods: EPA 200.8 QC Limits: 90 to 110 % Recovery Run ID: MA39269 Units: ug/l

Time: 11:01 11:05 11:17 Sample ID: ICVA ICVA1 ICV ICV1 CCVA CCVA1

Metal True Results % Rec True Results % Rec True Results % Rec

Aluminum

Antimony

Arsenic

Barium

Beryllium

Boron

Cadmium

Calcium

Chromium

Cobalt

Copper 60 54.7 91.2 50 48.1 96.2

Iron

Lead 60 57.0 95.0 50 49.3 98.6

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium

Silver

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium

Zinc


_________________________________________________________________________________________________________

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66.1.3





Time: 12:00 12:27 13:04 Sample ID: CCVA CCVA2 CCVA CCVA3 CCVA CCVA4


Aluminum

Antimony

Arsenic

Barium

Beryllium

Boron

Cadmium

Calcium

Chromium

Cobalt

Copper 50 47.8 95.6 50 47.3 94.6 50 46.5 93.0

Iron

Lead 50 48.6 97.2 50 48.8 97.6 50 47.9 95.8

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium

Silver

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium

Zinc


_________________________________________________________________________________________________________

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66.1.3





Time: 13:41 14:15 14:35 Sample ID: CCVA CCVA5 CCVA CCVA6 CCVA CCVA7


Aluminum

Antimony

Arsenic

Barium

Beryllium

Boron

Cadmium

Calcium

Chromium

Cobalt

Copper 50 47.0 94.0 50 47.0 94.0 50 46.8 93.6

Iron

Lead 50 48.5 97.0 50 48.4 96.8 50 48.4 96.8

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium

Silver

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium

Zinc


_________________________________________________________________________________________________________

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66.1.3





Time: 15:12 15:45 Sample ID: CCVA CCVA8 CCVA CCVA9

Metal True Results % Rec True Results % Rec

Aluminum

Antimony

Arsenic

Barium

Beryllium

Boron

Cadmium

Calcium

Chromium

Cobalt

Copper 50 46.7 93.4 50 46.9 93.8

Iron

Lead 50 48.8 97.6 50 48.6 97.2

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium

Silver

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium

Zinc


_________________________________________________________________________________________________________

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66.1.3

LOW CALIBRATION CHECK STANDARDS SUMMARY




Time: 11:11 11:14 Sample ID: CRI CRIA CRIA1 CRI1

Metal True True Results % Rec Results % Rec

Aluminum 25 25

Antimony 2.0 0.25

Arsenic 0.50 1.0

Barium 1.0 0.50

Beryllium 0.50 0.30

Boron 25 2.5

Cadmium 0.50 0.25

Calcium 250 125

Chromium 1.0 2.0

Cobalt 0.50 0.25

Copper 2.0 2.0 2.0 100.0

Iron 25 25

Lead 0.50 0.25 0.49 98.0

Magnesium 250 125

Manganese 0.50 0.25

Molybdenum 1.0 0.50

Nickel 1.0 2.0

Potassium 250 125

Selenium 0.50 1.0

Silver 0.50 1.0

Sodium 250 125

Strontium 5.0 0.50

Thallium 0.50 0.25

Tin 5.0 0.50

Titanium 1.0 0.50

Vanadium 1.0 2.0

Zinc 5.0 2.0


_________________________________________________________________________________________________________

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JC18894

66.1.4

BLANK RESULTS SUMMARY Part 2 - Method Blanks



QC Batch ID: MP93341 Methods: EPA 200.8 Matrix Type: DRINKING WATER Units: mg/l

Prep Date: 04/26/16

MB Metal RL IDL MDL raw final

Aluminum 0.050 .0001 .00074

Antimony 0.0020 .00012 .00021

Arsenic 0.0010 .00038 .00081

Barium 0.0010 .000011 .000044

Beryllium 0.00030 .000004 .000079

Boron 0.050 .0032

Cadmium 0.00050 .000008 .000041

Calcium 0.25 .0027 .0075

Chromium 0.0040 .000019 .00018

Cobalt 0.00050 .000003 .000014

Copper 0.0040 .00002 .0012 0.00037 <0.0040

Iron 0.050 .0011 .009

Lead 0.00050 .000009 .000018 0.000033 <0.00050

Magnesium 0.25 .00017 .00051

Manganese 0.0010 .000019 .00006

Molybdenum 0.0010 .00002 .000059

Nickel 0.0040 .000028 .00023

Potassium 0.25 .002 .015

Selenium 0.0010 .00029 .00051

Silver 0.0020 .000019 .000022

Sodium 0.25 .0039 .015

Strontium 0.0010 .000009 .000014

Thallium 0.00050 .000016 .0001

Tin 0.0010 .000039 .000043

Titanium 0.0010 .000034 .00038

Vanadium 0.0040 .00011 .00082

Zinc 0.010 .00029 .00061

Associated samples MP93341: JC18894-1, JC18894-2

Results < IDL are shown as zero for calculation purposes(*) Outside of QC limits(anr) Analyte not requested

_________________________________________________________________________________________________________

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66.2.1

MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY




Prep Date: 04/26/16

JC18892-1 Spikelot QC Metal Original MS MPXDW7 % Rec Limits

Aluminum

Antimony

Arsenic

Barium

Beryllium

Boron

Cadmium

Calcium

Chromium

Cobalt

Copper 0.057 0.14 0.10 83.0 70-130

Iron

Lead 0.0010 0.093 0.10 92.0 70-130

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium

Silver

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium

Zinc


Results < IDL are shown as zero for calculation purposes(*) Outside of QC limits(N) Matrix Spike Rec. outside of QC limits(anr) Analyte not requested

_________________________________________________________________________________________________________

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66.2.2





Prep Date: 04/26/16

JC18892-1 Spikelot MSD QC Metal Original MSD MPXDW7 % Rec RPD Limit

Aluminum

Antimony

Arsenic

Barium

Beryllium

Boron

Cadmium

Calcium

Chromium

Cobalt

Copper 0.057 0.14 0.10 83.0 0.0 20

Iron

Lead 0.0010 0.093 0.10 92.0 0.0 20

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium

Silver

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium

Zinc



_________________________________________________________________________________________________________

Page 2

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66.2.2

SPIKE BLANK AND LAB CONTROL SAMPLE SUMMARY




Prep Date: 04/26/16

BSP Spikelot QC Metal Result MPXDW7 % Rec Limits

Aluminum

Antimony

Arsenic

Barium

Beryllium

Boron

Cadmium

Calcium

Chromium

Cobalt

Copper 0.093 0.10 93.0 85-115

Iron

Lead 0.095 0.10 95.0 85-115

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium

Silver

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium

Zinc



_________________________________________________________________________________________________________

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JC18894

66.2.3

BLANK RESULTS SUMMARY Part 2 - Method Blanks




Prep Date: 04/26/16

MB Metal RL IDL MDL raw final

Aluminum 0.050 .0001 .00074

Antimony 0.0020 .00012 .00021

Arsenic 0.0010 .00038 .00081

Barium 0.0010 .000011 .000044

Beryllium 0.00030 .000004 .000079

Boron 0.050 .0032

Cadmium 0.00050 .000008 .000041

Calcium 0.25 .0027 .0075

Chromium 0.0040 .000019 .00018

Cobalt 0.00050 .000003 .000014

Copper 0.0040 .00002 .0012 -0.000019<0.0040

Iron 0.050 .0011 .009

Lead 0.00050 .000009 .000018 0.00000067<0.00050

Magnesium 0.25 .00017 .00051

Manganese 0.0010 .000019 .00006

Molybdenum 0.0010 .00002 .000059

Nickel 0.0040 .000028 .00023

Potassium 0.25 .002 .015

Selenium 0.0010 .00029 .00051

Silver 0.0020 .000019 .000022

Sodium 0.25 .0039 .015

Strontium 0.0010 .000009 .000014

Thallium 0.00050 .000016 .0001

Tin 0.0010 .000039 .000043

Titanium 0.0010 .000034 .00038

Vanadium 0.0040 .00011 .00082

Zinc 0.010 .00029 .00061



_________________________________________________________________________________________________________

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66.3.1





Prep Date: 04/26/16

JC18894-3 Spikelot QC Metal Original MS MPXDW7 % Rec Limits

Aluminum

Antimony

Arsenic

Barium

Beryllium

Boron

Cadmium

Calcium

Chromium

Cobalt

Copper 0.068 0.16 0.10 92.0 70-130

Iron

Lead 0.0058 0.10 0.10 94.2 70-130

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium

Silver

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium

Zinc



_________________________________________________________________________________________________________

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66.3.2





Prep Date: 04/26/16

JC18894-3 Spikelot MSD QC Metal Original MSD MPXDW7 % Rec RPD Limit

Aluminum

Antimony

Arsenic

Barium

Beryllium

Boron

Cadmium

Calcium

Chromium

Cobalt

Copper 0.068 0.16 0.10 92.0 0.0 20

Iron

Lead 0.0058 0.10 0.10 94.2 0.0 20

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium

Silver

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium

Zinc



_________________________________________________________________________________________________________

Page 2

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JC18894

66.3.2

SPIKE BLANK AND LAB CONTROL SAMPLE SUMMARY




Prep Date: 04/26/16

BSP Spikelot QC Metal Result MPXDW7 % Rec Limits

Aluminum

Antimony

Arsenic

Barium

Beryllium

Boron

Cadmium

Calcium

Chromium

Cobalt

Copper 0.093 0.10 93.0 85-115

Iron

Lead 0.095 0.10 95.0 85-115

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium

Silver

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium

Zinc



_________________________________________________________________________________________________________

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JC18894

66.3.3