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THE APPLICATION OF WASTE GLASS AS PARTIAL R EPLAC EMENT FOR CEMENT IN CONCR ETE YVONNE WILLIAM TONDUBA A proj ect report submitted in partial fulfillment of the requirements for the award of the degree of Master of Engineering (Civil ) Faculty of Civil Engineering Universiti Teknologi Malaysia JANUARY, 2016

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THE APPLICATION OF WASTE GLASS AS PARTIAL REPLACEMENT FOR

CEMENT IN CONCR ETE

YVONN E WILLIAM TONDUBA

A proj ect report submitted in partial fulfillment of the

requirements for the award of the degree of

Master of Engineering (Civil )

Faculty of Civil Engineering

Universiti Teknologi Malaysia

JANUARY, 2016

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ACKNOWLEDGEMENTS

My deepest and most heartfelt gratitude goes to my supervisor, Dr. Yong Ee

Ling for the continuous guidance and support have enabled me to approach work

positively. Special thanks to all my lab mates for their helped and support. I would also

like to thank everyone who has contributed whether directly or indirectly to this

project. Finally, I thank God for the continuous blessing, much more than I deserve.

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ABSTRACT

Construction and demolition activity has led to increased piling up of waste in the

landfills of Malaysia, a developing country. Glass waste is among the generated waste

as well. Other than that, the demand of cement, an important construction material has

been increasing every year which led to increase in production of cement. Cement

production is a significant source of global carbon dioxide (CO2) emissions. This paper

looks at the possibility of glass waste usage as cement replacement in concrete mixture.

The mechanical strength of the glass waste concrete was analyzed. The percentages

used as a partial replacement, were 5%, 10%, 15%, 20% and 25%. The results of this

study have proven that glass waste construction possesses a pozzolanic strength of

82.3% making it suitable pozzolanic material. The compressive strength, tensile

strength, flexural strength and elastic modulus strength had shown 10% of glass waste

replacement to be the optimum percentage that gives higher strength than the normal

concrete strength.

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ABSTRAK

Pembinaan dan aktiviti perobohan telah membawa peningkatan penimbunan sisa di

tapak pelupusan di Malaysia yang merupakan sebuah negara membangun. Sisa kaca

adalah antara bahan buangan yang dihasilkan daripada aktiviti tersebut. Selain daripada

itu, permintaan simen, bahan binaan yang penting untuk pembangunan telah meningkat

setiap tahun yang membawa kepada peningkatan dalam pengeluaran simen.

Pengeluaran simen adalah sumber besar karbon dioksida global (CO2). Artikel ini

mengkaji dalam penggunaan sisa kaca sebagai pengganti simen dalam campuran

konkrit. Kekuatan mekanikal konkrit sisa kaca telah dianalisis. Peratusan digunakan

sebagai pengganti separa ini, adalah 5%, 10%, 15%, 20% dan 25%. Keputusan kajian

ini telah membuktikan bahawa pembinaan sisa kaca mempunyai kekuatan pozzolanic

sebanyak 82.3% justeru boleh menjadikannya bahan pozzolanic sesuai. Kekuatan

mampatan, kekuatan tegangan, kekuatan lenturan dan kekuatan modulus elastik telah

menunjukkan 10% daripada penggantian sisa kaca sebagai peratusan optimum yang

memberikan kekuatan yang lebih tinggi daripada kekuatan konkrit biasa.

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TABLE OF CONTENTS

CHAPTER TITLE PAGES

TITLE PAGE

ABSTRACT iv

ABSTRAK v

TABLE OF CONTENTS vi

LIST OF TABLES ix

LIST OF FIGURES x

LIST OF NOTATIONS

LIST OF APPENDICES

xii

xiii

1 INTRODUCTION

1.1 Background of Study 1

1.2 Problem Statement 5

1.3 Objectives of Study 6

1.4 Significant of Study 6

2 LITERATURE REVIEW

2.1 Concrete Information 7

2.2 Concrete Material 9

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2.2.1 Cement

2.2.2 Aggregates

2.2.3 Water

2.3 Recycle Materials in Concrete

2.3.1 Fly Ash in Concrete

2.3.2 Sawdust Ash in Concrete

9

11

12

14

15

16

2.4 Glass in Concrete 17

2.5 Advantages of Glass in Concrete

20

3 RESEARCH METHODOLOGY

3.1 Introduction

3.2 Materials

3.3 Concrete Mix Design

3.4 Mixture Proportions

3.5 Preparation of specimen

3.6 Testing and Analysis of Specimen

3.6.1 X-ray fluorescence (XRF) and X-ray

diffraction (XRD) analysis

3.6.2 Slump Test

3.6.3 Pozzolanic Activity Strength

3.6.4 Scanning Electron Microscopic

Observation (SEM)

3.6.5 Mechanical Strength of Concrete

22

24

26

26

27

30

30

30

31

32

32

4 RESULT AND DISCUSSION

4.1 Introduction

33

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4.2 X-ray fluorescence (XRF)

4.3 X-ray diffraction (XRD)

4.4 Slump Test

4.5 Pozzolanic Activity Strength

4.6 Scanning Electron Microscopic Observation

(SEM)

4.6.1 Microstructure of Cement versus Waste

Glass Powder

4.6.2 Particle Size Distribution of Waste Glass

Powder

4.6.3 Microstructure of Hardened Concrete

4.7 Mechanical Strength of Concrete

4.7.1 Compressive Strength Test

4.7.2 Tensile Strength Test

4.7.3 Flexural Strength Test

4.7.4 Young’s Modulus (Elastic Modulus)

Strength test

34

35

37

39

42

42

43

45

52

52

54

57

59

5 CONCLUSION AND RECOMMENDATION

5.1 Conclusion

5.2 Recommendation

62

63

REFERENCES 64

Appendices A – G 71-82

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LIST OF TABLES

TABLE NO TITLE PAGE

2.1

3.1

4.1

Composition of ordinary Portland Cement (Smith,

1971)

Quantities of four major components in concrete

Chemical composition of cement and glass

10

27

35

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LIST OF FIGURES

FIGURE NO TITLE PAGE

3.1

3.2

3.3

3.4

3.5

3.6

3.7

4.1

4.2

4.3

4.4

4.5

4.6

4.7(a)

4.7(b)

4.8

Procedure of the Study

Los Angeles Crusher Machine

Waste glass powder

Steel Moulds for the concrete specimens

Mixing of material using concrete mixer

Compaction using vibrating table

Slump Test

X-ray spectrum of cement

X-ray spectrum of waste glass

Result of slump

Measurement of slump with 15% of waste glass

replacement

Results of pozzolanic strength

Compression test on mortar block

The microstructure of cement

The microstructure of glass

Particles size of crushed waste glass powder

23

25

25

28

28

29

31

36

37

38

39

40

41

42

43

44

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4.9(a)

4.9(b)

4.9(c)

4.9(d)

4.9(e)

4.9(f)

4.10(a)

4.10(b)

4.10(c)

4.10(d)

4.10(e)

4.10(f)

4.11

4.12

4.13

4.14

4.15

4.16

4.17

4.18

4.19

4.20

SEM image of 0% waste glass powder at 7 days

SEM image of 5% waste glass powder at 7 days

SEM image of 10% waste glass powder at 7 days

SEM image of 15% waste glass powder at 7 days

SEM image of 20% waste glass powder at 7 days

SEM image of 25% waste glass powder at 7 days

SEM image of 0% waste glass powder at 28 days

SEM image of 5% waste glass powder at 28 days

SEM image of 10% waste glass powder at 28 days

SEM image of 15% waste glass powder at 28 days

SEM image of 20% waste glass powder at 28 days

SEM image of 25% waste glass powder at 28 days

Result of compressive strength

Compressive strength test

Result of tensile strength

Tensile strength test

Split concrete cube

Result of flexural strength

Flexural strength test

Crack at the middle of the span

Result of Young’s modulus strength

Young’s (Elastic) modulus strength test

46

46

47

47

48

48

49

49

50

50

51

51

53

54

55

56

56

58

58

59

60

61

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LIST OF NOTATION

MSW - Malaysia’s Municipal Solid Waste

BS - British Standard

ASTM - American Society for Testing and Materials

CO2 - Carbon Dioxide

CCBs - Coal Combustion By-Products

OPC - Ordinary Portland Cement

SEM - Scanning Electron Microscope

ASR - Alkali-Silica Reaction

SCM - Supplementary Cementitious Material

SDA - Saw-Dust Ash

XRF - X-ray fluorescence

XRD - X-ray diffraction

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LIST OF APPENDICES

APPENDIX TITLE PAGE

A The concrete mix design method 71

B Result of Sieve Analysis of Sand 79

C Result of Mechanical Strength of Concrete 80

D Elastic Modulus Strength (Young’s Modulus) 81

E

F

G

Slump Test Result

Pozzolanic Strength Results

Concrete Mixture Proportion

81

82

82

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CHAPTER 1

INTRODUCTION

1.1 Background of Study

Malaysian construction industry approached a critical limit, especially in terms

of composition and amount of waste materials generated by it. Problems in the

removal of such waste are mounting. For quite a few years, large construction building

and infrastructure development projects have led to increased production of

construction waste material. The construction waste has impacted the environment due

to the sheer quantity of waste production (Begum RA et al., 2007). Most of the waste

materials disposed into landfill compromise construction and workers’ productivity as

well as causing wider environmental implication. Moreover, Malaysia has little reliable

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statistic for construction and demolition that shows the rate of waste generation, type of

waste, method of handling wastage, and the quantity of material wastage minimized at

source, reused or recycled on-site or off-site in a specific type of construction such as

residential construction (Haliza, 2010). A study conducted on 30 construction sites

identified six types of waste materials which included concrete (12.32%), metals

(9.62%), bricks (6.54%), plastics (0.43%), wood (69.10%) and waste that included

glass (2%). Wasted wood generation was more than others among the construction

waste (Faridah et. al., 2004).

An article from The Star (April, 2015) reported that on Aug 9 last year,

Lafarge’s cement production capacity was about 12.95 million tonnes, followed by

YTL Cement at 5.95 million tonnes, CIMA at 3.4 million tonnes, Tasek Corp at 2.3

million tonnes and both Hume Cement and Holcim Malaysia at 2 million tonnes each.

Carbon dioxide is emmitted during the production of clinker (a component of cement)

in which calcium carbonate (CaCO3) is heated under high temperature (1450o to

1600o) in a rotary kiln to induce a series of complex chemical reactions. CO2 is

emmitted as a by-product during calcination, which occurs in the upper, cooler end of

the kiln, or a precalciner, at temperatures of 600-900°C, and results in the conversion of

carbonates to oxides (Michael J. et al, 2012).

There are many examples of successful recycling of waste glass as cullet, as

raw material for the production of abrasives, in sand-blasting, as an aggregate substitute

in concrete, in road beds, pavement and parking lots, as raw materials to produce glass

pellets or beads used in reflective paint for highways, to produce fiberglass, and as

fractionators for lighting matches and firing ammunition (Chen et al., 2002).

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Substitutions of waste glass in concrete production have been investigated by

many researchers. Waste glass was used either as an aggregate replacement in concrete

mixture or as a cement replacement. The possibility of reusing waste glass from

crushed containers and building demolition as aggregates for preparing mortars and

concrete was studied. It involved varying the particles size of the finely ground waste

glass. No reaction was observed with particles size up to 100µm. A strong

improvement of the mortar mechanical performance was also noted (Corinaldesi et al,

2004).

Yet another research was conducted to analyze the possibilities of recycling

waste glass as fine aggregate for concrete. They concluded that the compressive, tensile

and flexural strengths of concrete decreased when the content of waste glass was

increased. The concrete containing waste glass of 30% mixing ratio gave the highest

strength properties (Park et al, 2004). The results obtained in another study proved that

28 days achieved 80% of the pozzolanic strength from an optimum percentage of glass

(20%) resulting in maximum value of compressive and flexural strength (Zainab and

Enas, 2008).

Another studies investigated on the possibilities of using finely ground waste

glass as partial cement replacement in concrete three sets of tests the lime-glass tests to

assess the pozzolanic activity of ground glass, the compressive strength tests of

concrete having 30% cement replaced by ground glass to monitor the strength

development, and the mortar bar tests to study the potential expansion. The results

showed that ground glass having a particle size finer than 38µm did exhibit a

pozzolanic behavior. The mortar bar tests demonstrated that the finely ground glass

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helped reduce the expansion by up to 50%. Shao did crystalinity test of the glass using

X-ray diffraction technique and the result shows that soda lime glass is a typical

amorphous material (Shao et al. 1999).

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1.2 Problem Statement

Numerous waste materials are generated from manufacturing processes, service

industries and municipal solid wastes. The increasing awareness about the environment

has tremendously contributed to the concerns related with disposal of the generated

wastes. Solid waste management is one of the major environmental concerns in the

world. With the scarcity of space for landfilling and due to its ever increasing cost,

waste utilization has become an attractive alternative to disposal. Research is being

carried out on the utilization of waste products in concrete. Such waste products

include discarded tires, plastic, glass, steel, burnt foundry sand, and coal combustion

by-products (CCBs). Each of these waste products has provided a specific effect on the

properties of fresh and hardened concrete. The use of waste products in concrete not

only makes it economical, but also helps in reducing disposal problems. Reuse of bulky

wastes is considered the best environmental alternative for solving the problem of

disposal. This study overcomes the problem of the glass waste that is generated from

construction and demolition activity. In order to reduce the product of glass waste, it

has been suggested to reuse glass waste materials to substitute a percentage of the

cement used in the ordinary portland cement (OPC). Waste glass will be used as partial

replacement for cement in concrete. The purpose is to analyze the possibilities of using

recycled waste glasses in production of concrete.

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1.3 Objectives of Study

1. To investigate the applicability of recycled glass in concrete mixture.

2. To investigate the Scanning Electron Microscope (SEM) of concrete with waste glass

replacement.

3. To examine the mechanical properties of the concrete with recycled glass as

replacement of cement in concrete.

1.4 Significant of Study

1. Development of concrete with recycled glass as cement to protect the environment.

2. To study the physical and mechanical properties of concrete in which contained waste

glass.

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