Upload
others
View
3
Download
0
Embed Size (px)
Citation preview
1
Unit 2: Atoms, Bonds,
Ions, and Their Properties
Name:____________________________________ Date:________ Period:_______
SECTION 1: ENGAGE
Investigation 1.1: What is an Atom?
SECTION 1: EXPLORE
Investigation 2.1: Introduction to the Periodic Table
SECTION 3: EXPLAIN
Investigation 3.1: Atomic Puzzle
Investigation 3.2: Understanding an Electron’s Behavior—Photons
Investigation 3.3: Electron Configuration
Investigation 3.4: Describing Valence Electrons using Lewis Dot Structures
Investigation 3.5: Understanding the formation of bonds and ions
SECTION 4: ELABORATE
Investigation 4.1: Replacement Reaction
Investigation 5.1: Ionic Bonds
Investigation 6.1: Covalent Bonds
Investigation 7.1:
SECTION 5: EVALUATE
Investigation 6.1: Test
2
Investigation 1.1 What is an Atom?
Atoms are the building blocks of matter. To begin our investigation, you will be
defining and identifying all the parts of an atom.
1. Hypothesize what you think the following terms mean:
Nucleus:
Protons:
Electrons:
Neutrons:
2. In the space below, draw what you think an atom looks like. Please include
labels for each of the above terms.
3
Background Information:
All matter is made up of atoms. The center of the atom is the nucleus which is a
cluster of protons and neutrons. The protons have a positive electric charge
while the neutrons are electrically neutral. The nucleus makes up almost all of an
atom's mass. Whirling at fantastic speeds around the nucleus are smaller and
lighter particles called electrons which have a negative charge.
3. Using the background information redefine your terms (incorporate charge
when appropriate).
Nucleus:
Protons:
Electrons:
Neutrons:
Figure 1
4. Compare and contrast
your drawing of an atom
to the one on the right
4
Figure 2
5. Using the information below (Table 1) complete table 2.
Table 1
13
Al Aluminum
27
79
Au Gold
197
29
Cu Copper
64
47
Ag Silver
108
92
U Uranium
238
Table 2
Element Atomic # Atomic
Weight
# of Protons # of
Electrons
# of
Neutrons
Al
Au
Cu
Ag
U
6
C CARBON
12
Atomic Number = represents the number of
Protons as well as the number of Electrons
Chemical Symbol
Chemical Name
Atomic Weight = represents the number of
Protons and the number of Neutrons added
together
5
6. Complete the chart using the information provided in Table 3.
Table 3
Element Atomic # Atomic
Weight
# of Protons # of
Electrons
# of
Neutrons
Na 11 23
Cl 17 18
Fr 87 136
Pt 195 78
H 1 1
6
2.1 Introduction to the Periodic Table
Background:
The periodic table is arranged in horizontal rows called periods and vertical
columns called groups/ families. The periods have their atomic numbers
increase from left to right, while the groups contain elements having similar
chemical properties. Each group is represented by a Roman numeral and letter.
Letter A represents representative metals, while letter B represents transition
metals. In addition, the figure below highlights several other important factors,
such as ionization energy, metallic properties, and atomic radius.
Organizing the Periodic Table:
The periodic table is arranged into several sections, those being Alkali metals,
Alkali Earth metals, Transition metals, Metals, Metalloids, Non-metals, Halogens,
and Nobel gases.
Directions: Using a copy of the period table and eight different colored pencils
identify each of the sections listed above. Then answer the questions that follow.
7
8
9
Characteristics of Periodic Groups
Alkali Metals
Alkali Earth Metals
Transition Metals
Metals
Metalloids
Non Metals
Halogens
Noble Gases
10
1. Which pair of elements is in the same period?
2. Which pair of elements is in the same group/family?
3. Which element has the smallest atomic number?
4. If the atomic number of element D is 20, then what is the atomic number of
element R?
(Use your periodic table to answer the remaining questions: 5- 10)
5. This element has the lowest atomic number of any Group 16 element.
6. This element has the most protons of any element in Group 15.
7. This element is in the same family as lead, and it has fewer protons than
sodium.
8. This element has an atomic number that is one greater than platinum.
9. This element has an atomic number that is double that atomic number of
silicon.
10. This element is in Group 1 and has a higher atomic number than chlorine,
but a lower atomic number than bromine.
11
Investigating 3.1 ATOMIC PUZZLE Directions: Use the periodic table to determine the element that each lettered question refers
to. Put the element's symbol on the line after each of the clues. When these symbols are
arranged one after the other, they will form a word or phrase. When you discover this word or
phrase, transfer each symbol into the appropriate lettered box. For each problem, a hint is
provided for you.
1. HINT: Produced by the Pancreas?
a. Has 49 positive particles _________
b. Has 6 electrons in its third, and outermost shell ___S______
c. A greenish, radioactive mineral used in the production of
electricity ___U__
d. This element's nucleus contains only 4 neutrons _________
e. The atom with 7 electrons _________
a b c d e
2. HINT: What your teacher will "keep" during a test.
a. Lightest element in the universe _________
b. It has 7 electrons on its 5th, and outermost shell ___i___
c. Has 16 protons _________
d. Has a mass of 127 _________
e. An element used to form water _________
f. Element with 7 neutrons _________
g. Atomic number 39 _________
h. The gas that our blood absorbs during respiration_____
I. Symbol for uranium _________
a b c d e f g h i
3. HINT: They lived in a submarine in 1966
a. Has four protons _________
b. Element with 125 neutrons, in the same family as fluorine _________
c. Roman numeral for "50" ___L______
d. The “Actinoid” element named after "Albert" _________
a b c d
12
4. HINT: A typical Irish breakfast
a. Has 104 neutrons _________
b. Symbol for carbon _________
c. Has 7 less electrons than Iron_________
d. Has 39 protons _________
e. Has only a filled inner shell, and half-filled second shell ____
f. An element found in water, and hydrochloric acid _________
g. Has 8 electrons in it's outermost, third shell _________
h. Abbreviation for "Miss" _________
a b c d e f g h
5. HINT: He had an element named after him
a. Symbol of the element used in foil _________
b. The element with 6 neutrons and 5 protons ___B______
c. Contains 67 more positive particles than Hydrogen _________
d. 20th letter of the alphabet _________
e. Letter used to symbolize a negative subatomic particle _E________
f. Has a mass that is 31 greater than krypton _________
g. It has 6 electrons on its 3rd and outermost shell_________
h. Atom whose atomic number is 52 _________
I. Its electron configuration is 2, 8, 18, 18, 3 _________
a b c d e f g h i
6. HINT: Projected onto a screen by a cathode ray tube = TV TUBE
a. Symbol for boron _________
b. The element with two electrons in its 7th shell ___Ra____
c. 10th element of the "lanthanoid" series _DY________
d. It's second, outermost shell has 3 electrons ________
e. Contains a total of 92 protons _________
f. One of the laughing gas elements _________
g. Atomic mass is 12 _________
h. Having no neutrons it is an explosive gas once used in blimps _________
a b c d e f g h
13
Investigation 3.2 Laboratory Investigation: Understanding an
Electron’s Behavior
In 1913, the Danish physicist Niels Bohr proposed yet another
modification to the theory of atomic structure based on a curious
phenomenon called line spectra.
Under Bohr's theory, an electron's energy levels (also called
electron shells) can be imagined as concentric circles around the
nucleus. Normally, electrons exist in the ground state, meaning
they occupy the lowest energy level possible (the electron shell closest to the
nucleus). When an electron is excited by adding energy to an
atom (for example, when it is heated), the electron will absorb
energy, "jump" to a higher energy level, and spin in the higher
energy level. After a short time, this electron will spontaneously
"fall" back to a lower energy level, giving off a quantum of light
energy. Key to Bohr's theory was the fact that the electron
could only "jump" and "fall" to precise energy levels, thus emitting a limited
spectrum of light. The animation linked below simulates this process in a
hydrogen atom.
Problem:
How does the emission of spectra of various types of light appear through a
spectroscope?
Materials:
incandescent light
fluorescent light
hydrogen light
helium light
krypton light
spectroscope
high voltage source
Procedure: Part 1
1. Obtain a spectroscope.
2. Look through the spectroscope toward the fluorescent lights in the room.
Observe the color produced.
3. Record the color(s) of the spectra in data table 1 (see example in book).
4. Draw the color(s) of the spectra in the box labeled fluorescent light. Record your
observations by using colored pencils.
5. Repeat steps 2-4 using an incandescent light bulb. Record all observations.
14
Part 2
6. Obtain a spectroscope as you instructor inserts a vacuum tube of an element in
the high voltage source.
7. Record the color(s) of the spectra in data table.
8. Draw the color(s) of the spectra in the box labeled fluorescent light. This is the
bright line spectrum. Record your observations by using colored pencils.
9. Repeat steps using the other two vacuum tubes of various elements identified in
the materials.
Observations/Data Table:
Type of Light
Source
Color of gas as
visible without a
spectroscope
Drawing of the continuous and/or bright-
line spectrum
(please used colored pencils for your
drawings)
Fluorescent Light
bulb
Incandescent
light bulb
Helium
Hydrogen
Krypton
Neon
Mercury
15
Analysis Questions:
1. White light is made up of all seven parts of visible light. Identify the seven
components.
2. Describe the difference you see between the light bulbs (fluorescent/
incandescent) and the other elements that give off light (vacuum tubes).
3. Of the five different types of light spectra you examined, which ones do you
think are the MOST similar? Explain.
4. Create a prediction regarding how using an emission spectra would be
helpful to scientists?
5. What is the purpose of the high voltage source?
6. Explain the process of how the bright line spectrums are produced in the
samples of light that were examined.
7. How might spectral analysis be useful in astronomy? Think about this question
carefully before you answer. Please provide a detail explanation of this
question.
16
Investigation 3.3 Electron Configuration
How does electron configuration relate to the periodic table? The periodic table is organized into Periods (rows), Groups 1-18 (columns) and Blocks (s, p, d and f).
The periodic table below shows the s, p, d and f view:
The arrangement of electrons within the orbitals of an atom is known as the electron configuration. The most stable arrangement is called the ground-state electron configuration. This is the configuration where all of the electrons in an atom reside in the lowest energy orbitals possible. Keeping in mind that each orbital can accommodate a maximum of two electrons, we are able to predict the electron configurations of elements using the periodic table.
Basically, the distributions of orbitals can be laid out in the following fashion (read from the bottom up):
_ 4s _ _ _ 3p _ 3s _ _ _ 2p _ 2s _ 1s
The bottom energy level is level 1 - it has the lowest energy. Each "_" represents an orbital. You can see
that there is 1 orbital for an s subshell. There are 3 orbitals for a p subshell. Each orbital can hold 2
electrons. Therefore, the s subshell can hold 2 electrons and the p can hold 6. As a result, the first
energy level can hold 2 electrons (1s = 2), and the second energy level can hold 8 electrons (2s2p = 2 +
6), etc.
17
Parts of an electron configuration:
Energy level - a number (1, 2, 3 and so on)
Sublevel (orbital) - a letter, either s, or p
Number of electrons - a superscript number
Analogy: The energy level is like a driveway with cars in it, the sublevels are the type of cars in parking
lot, and the orbitals are how many seats are in the car.
How to write an electron configuration:
In a neutral atom, the number of electrons equals the number of protons of the atom. When the electrons
fill the orbitals, they occupy the lowest energy orbitals that are available.
For example, hydrogen is atomic number 1 (has 1 proton). The one electron that it has occupies the
lowest orbital, which is 1s. To write its electron configuration, it would be 1s1. In an orbital diagram, it
would simply be a line with one up arrow in it, which represents the 1s orbital:
H: 1s1
Practice: Write the electron configuration for the following elements-
1s2 2s2 2p6 3s2 3p6 4s2
He Li
Cl P Ca C O F B Ne
18
Investigation 3.4 Describing Valence Electrons using Lewis Dot
Structures
Background:
American chemist Gilbert Lewis developed another method for depicting an
atom’s electron configuration. Lewis focused on the valence electrons in his
representations of elements. Valence electrons are all of the electrons in the
outer orbital/shell of an element.
1. Based upon the above information how many valence electrons do the
following elements have:
a. B
b. Mg
In a Lewis dot structure the valence electrons are represented as dots placed
around the element symbol.
2. Draw what you think the Lewis dot structure looks like for:
a. B
b. Mg
Check your predictions by sharing with the class.
19
Draw the Lewis-Dot Structure for the following atoms. Review the following
bullets before you begin.
Around the element’s symbol use dots to represent each valance
electron
The dots should be spread over the four sides. Dots are not paired until all
sides have at least one dot.
Place the initial dot above each symbol and then proceed to arrange the
rest in a clockwise direction.
The number of valance electrons is equal to the group number (Roman
numeral).
1. B
2. Ne
3. Li
4. He
5. C
6. P
7. S
8. Mg
9. H
10. F
20
Investigation 3.5: Understanding the formation of bonds and ions. The octet rule says that atoms tend to gain, lose or share electrons so as to have eight
electrons in their outer electron shell.
When atoms form ions they seek to obtain a stable electron
configuration (8 valance electrons—Lewis-dot structures). As a result,
they will either attempt to gain electrons and or lose electrons to
become stable. In either situation they will do whatever is the easiest. The
protons (+) in the nucleus of an atom remain unchanged by ordinary chemical
reactions, but atoms readily gain or lose electrons (-). When electrons are removed
from or added to a neutral (non-charged) atom, a charged particle called an ion is
formed. If the atom gains electron(s), its net charge becomes negative. A negative
ion is called an anion. If the atom loses electron(s), its net charge becomes positive. A
positive ion is called a cation. Gaining or losing electrons allows every energy level in an
ion to hold only a "stable" number of electrons, namely, 2, 8, 18 or 32.
How many electrons are in the following ion
a. Al 3+ _________
b. Te 2- _________
c. Si 4+ _________
d. Sb 3- __________
e. Cs 1+ _________
f. He _________
g. C4- _________
h. Sr 2+ _________
i. F 1- _________
j. Bi 3- ________
II. According to the Octet Rule, what do these ions need to do in order to become
stable? Indicate how many electrons they would gain or lose.
a. Calcium: Ca ____
b. Boron: B _________
c. Chlorine: Cl _________
d. Indium: In __________
e. Sulfur: S _________
f. Phosphorus: P _________
g. Sodium: Na _________
h. Tin: Sn _________
i. Argon: Ar _________
j. Hydrogen: H _________
III. Are the following atoms anions (a negative ion), cations, both, or neither.
a. Magnesium:___________ d. Neon: ______________
b. Gallium: _____________ e. Carbon:_____________
c. Rubidium:____________ f. Iodine: ______________
21
Investigation 4.1: Replacement Reaction
Procedure:
Safety- During this lab you will be wearing googles, gloves and should make
sure that you do not spill any solutions on yourself as there is a strong
possibility of staining clothes.
1. Obtain a piece of metal from your teacher and mass it. Record this
mass in your notes.
2. Obtain a beaker for the mystery solution.
3. Obtain 0.9 grams of the mystery powder and 50 milliliters of water from
the tap and dissolve the mystery powder in the water using a stirring
rod. To avoid stains, be sure to rinse the stirring rod with distilled water
before setting it down.
4. Place the piece of metal in the mystery solution, making sure not to
splash any of the solution.
5. Make note of any reaction that takes place in the beaker.
6. After 10 minutes, gently shake the metal to remove the accumulated
solid. Then place the metal on a paper towel on your lab bench to
allow it to dry.
7. Once dry, mass the metal again and record this value in your notes.
Filtering Procedure:
1. Obtain a piece of filter paper and initial the paper with a pencil. Then,
mass the filter paper, recording this in your data table.
2. Fold the filter paper using the following visuals as a guide:
3. Place the filter paper in a funnel and place another beaker below the
funnel.
4. Pour the solution from your beaker through the filter paper, allowing all
of the solution to transfer to the bottom beaker.
5. Take your filter paper and let it dry. Once dry, mass the filter paper
and precipitate. Subtract the mass of the filter paper to get a final
value for amount of precipitate. Record all data in your data table.
22
Analysis Questions:
1) Describe what happened in the beaker when you placed the metal in
the mystery solution?
2) Provide quantitative evidence to support what you described in the
answer above.
3) Hypothesize what you think occurred when the metal and mystery
solution were combined.
23
Investigation 5.1 Ionic Bonds
In ionic bonding, electrons are completely transferred from one atom to
another. In the process of either losing or gaining negatively charged
electrons, the reacting atoms form ions. The oppositely charged ions are
attracted to each other by electrostatic forces, which are the basis of the
ionic bond.
The following bullets characterize ionic bonding:
Transfer of electrons
Form between metals and nonmetals
Are crystalline solids
Dissolve easily in water
Conduct electricity in solution
Complete the chart for each element.
Element # of Protons # of Electrons # of Valance Electrons
Sodium
Chlorine
Beryllium
Fluorine
Lithium
Oxygen
Potassium
Directions:
Write the symbol for each element
Using a different colored pen/pencil create a Lewis dot structure for each
element
Draw an arrow(s) indicating the transfer of the electron(s)
Determine the charge of each ion and write the formula
Make sure the sum of the bond is zero
1. Potassium + Fluorine
2. Magnesium + Iodine
24
3. Sodium + Oxygen
4. Sodium + Chlorine
5. Calcium + Chlorine
6. Aluminum + Chlorine
25
Investigation 6.1Covalent Bonds
Covalent Bonding
Covalent bonding occurs when atoms share electrons. As opposed to ionic
bonding in which a complete transfer of electrons occurs, covalent
bonding occurs when two (or more) elements share electrons. Covalent
bonding occurs because the atoms in the compound have a similar
tendency for electrons (generally to gain electrons).
The following bullets characterize covalent bonding:
Share electrons
Generally occur between two nonmetals
Complete the chart for each element.
Element # of Protons # of Electrons # of Valance
Electrons
# of Electrons to
Fill Outer Shell
Hydrogen
Oxygen
Chlorine
Carbon
Fluorine
Helium
Lithium
Directions:
Write the symbol for each element
Using a different colored pen/pencil create a Lewis dot structure for each
element
Rearrange the electrons to pair up electrons from each atom.
Draw circles to show the sharing of electrons
Write the chemical formula for each molecule
1. Hydrogen + Hydrogen (Diatomic Element)
2. Hydrogen + Oxygen
26
3. Chlorine + Chlorine (Diatomic Element)
4. Oxygen + Oxygen (Diatomic Element)
5. Carbon + Oxygen
6. Carbon + Hydrogen
27
Investigation 7.1: Lab: Ionic vs. Covalent Bonds
Hypothesis: (Based on the properties of ionic and covalent compounds make a
hypothesis as to which type of bond each compound will have)
Compound Hypothesis Compound Hypothesis
Gelatin Magnesium Oxide
Sugar Detergent
Salt Cornstarch
Baking Soda Copper Chloride
Procedure:
1. You will need safety glasses, lab apron, and gloves.
2. Label 8 pieces of paper towel (good size) with the names of the compounds.
3. Place 5 grams of the compounds on each piece of paper (do ONE at a time).
4. Observe and WRITE the description of the compounds on the data chart.
5. Place 200 ml. of water in a beaker.
6. Add about ½ of the compound to the water and stir with a stirring rod for 10
seconds and observe. If the compound dissolves write SOLUBLE in the data chart
under “Solubility”. If it does not dissolve, write INSOLUBLE.
7. Place the leaders of the conductivity tester (as shown below) into the mixture.
Observe whether or not the bulb lights. If it does, write YES under
“Conductivity” in the data chart. If it does not light up write NO.
8. Rinse and dry the beaker.
9. Repeat the steps for each of the compounds.
10. Be sure to follow the teacher’s directions for how to dispose of the mixtures. DO
NOT just dump them into the sink.
28
Data:
Compound Description Solubility Conductivity Bond
Gelatin
Sugar
Salt
Baking Soda
Magnesium Oxide
Detergent
Cornstarch
Copper Chloride
Analysis Questions:
1. Some characteristics of many ionic compounds include solubility in water and
the ability to conduct electricity. On the basis of these two properties, which
compounds appear to have ionic bonds (please indicate in last column “Type
of Bond” in data chart)?
2. Water solutions of covalent compounds do not conduct electricity. Based on
this property, which compounds that you tested would you classify as
covalent compounds (please indicate in last column “Type of Bond” in data
chart)?
3. Explain how ionic and covalent compounds are different. USE
EVIDENCE FROM YOUR LAB.
4. Did all of the compounds that conducted electricity show the same amount of
conductivity? How can you tell (from the lab…)?
5. Solid table salt does not conduct electricity. Why do you think dissolving
table salt in water allows the salt to conduct electricity?
29
Unit 2 Study Guide-Atoms, Bonds, ions, and their
properties
Key Terms:
You must be able to define and explain each of the following terms below
Atom
Molecule
Element
Proton
Neutron
Electron
Nucleus
Ionic bonding
Covalent bonding
Isotope
Ion
Cation
Anion
Lewis Dot
Atomic number Atomic weight group/family
Period Octet Rule Valence Electron
Application:
You must be able to evaluate and utilize the periodic table in order to:
Decipher the number of proton, electrons, neutrons, atomic
number, and atomic weight.
Evaluate whether the element is a Alkali Metal, Alkali Earth Metal,
Transition Metal, Metal, Metalloide, Non-Metal, Halogen, or a Noble
gas
In terms of characteristics, be able to identify and explain the
similarities and difference between and among the eight different
groups
Situate the electrons into their respective orbital using the electron
configuration model and the Lewis-Dot model.
Interpret and explain ions according to the Octet Rule, example
Ca 20, protons 20 electrons, and 20 neutrons. According to the
Octet Rule it is simpler for Ca to give away 2 electrons than gain
eight. Therefore, Ca becomes Ca2+ with electron configuration of
2-8-8.
Determine whether an ion is a cation, anion, or neither.
Draw and depict a covalent and ionic bond
Graphing/ Short Response:
Be able to organize and synthesize data
30
Unit Three Key Terms
Directions: Define the following terms using either your book or
the internet. Please attempt to make the definition clear,
concise, and simple.
1. Atom
2. Molecule
3. Element
4. Proton
5. Neutron
6. Electron
7. Nucleus
8. Ionic bonding
31
9. Covalent bonding
10. Ion
11. Cation
12. Anion
32
33