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200420
a
P
?•'/ 9 I/ i >j IUNITED STATES ENVIRONMENTAL PROTECTION AGENCY
• REGION,,,'""4 t "" CENTRAL REGIONAL LABORATORY
0 • 839 BESTGATE ROAD/ ANNAPOLIS. MARYLAND 21401
\
DATE : July 28, 1983
SUBJECT: Blosenski Results
FROM : Daniel K. Donnelly (3ES21)py:j)Chief, Annapolis Lab U~
-O : Bruce Potoka (3ES30)
Enclosed is a copy of the VGA data for the Blosenski samples.DKDrjr
Enclosurea/s
200424
3 UNITED STATES ENVIRONMENTAL PROTECTION AGENCYREGION III
'*'«« ~r *"" CENTRAL REGIONAL LABORATORY839 BESTGATE ROAD 301-224-2740
ANNAPOLIS, MARYLAND 21401 FTS-922-3752
DATE : July 26, 1983
SUBJECT: Blosenski Water Samples for VOC's by GC/MS Superfund-Removal3TFA03RD49 (7/20/83-7/25/83) 83071901-11
FROM : Rick Dresich .^Chemist ^
TO : Daniel K. DonnellyChief, Annapolis Lab
THRU : JohnTeam Leader, Organic Analysis Unit
The above samples were analyzed for volatile organic compounds. Theexhibited detection limit was 1 ppb (ug/L).
The field blank accompanying this set nullified-the reporting of severalcompounds found in several samples. The compounds in the field blankwere: chloroform, cis-1,2-dichloroethylene, trichloroethylene,tetrachloroethylene, 1,1-dichloroethane, bromodichloromethane, toluene,and chlorobenzene. The presence of these compounds affected thereporting on sample numbers 01, 06, 07, 08, 09, and 10.
• Sample Descriptions:
Lab # Description
830719-01 Blosenski Dump, Hoffman Trailer, Sta 01-02 Blosenski Dump, Hartnetz, Sta 02-03 Blosenski Dump, Bards!ey, Sta 03-04 Blosenski Dump, Umble, Sta 04 .-05 Blosenski Dump, Wagner, Sta 05-06 Blosenski Dump, Riley, Sta 06 '-07 Blosenski Dump, Southern, Sta 07-08 Blosenski Dump, Gabel Well, Sta 08-09 Blosenski Dump, Gabel Spring, Sta 09-10 Blosenski Dump, Coffeth Stream, Sta 10-11 Blosenski Dump, HPLC water blank, Sta 11
RD:jr '
cc: Patricia Krantz, QAO
200425
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200427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY 'Q,III - t«i & Walnut Sts. 4
PhilMWphia.Pa. 19106 x
SUBJECT: Potable Water Surround! ng-8tri-&ensk4-is Dump Site
PROM: William M. Blankenship, P.E.Technical AdvisorWater Supply Branch (3WM401
TO: Bruce Potoka (3ES30)
(1) Hoffman's TrailerJ*«rr(830719-01). This well water contatns150-170 ppb TCE, 18-32 ppb 1,1,1, Trichloroethane and 1-1.8 ppb PCEas reported by EPA and DER). EPA's chronic value for TCE is 75 ppb,and there is no knowledge as to how long this well has been contam-inated. This water should not continue to be consumed by humans atthis installation. Any treatment of this water siwBird reduce theTCE level below 75 ppb and preferably below 4.5 ppb.
C2) Harttfetz (830719-02), Umble (830719-04) Wagner (830719-05)Riley (830719-06) Southern (830719-07) Gabel Well (830719-08) andCoffeth Stream (830719-10). These wells and stream are essentiallyfree of the contaminants analyzed for, and assuming there are nounknown pollutants these waters are safe for human consumption.(3) Bardsley- 830719-03.This well water contains 8,3-9 ppb TCE (EPA and DER analysis). Althoughthere is no immediate concern; our life-time cancer risk (10-6) valueis 4.5 ppb, and steps should be taken to remove the source of this con-tamination.
(4) Gabel Spring (830719-09)This water is contaminated with vinyl chloride, benzene TCE, etc.This water is unfit for human consumption and possibly animals.
200429
UNITED STATES ENVIRONMENTAL PROTECTION AGENCYREGION I I I
•„ c,^ CENTRAL REGIONAL LABORATORY' Pn°1 839 BESTGATE ROAD
ANNAPOLIS, MARYLAND 21401
September 7, 1984
Chris HylemanWeston Inc.Suite 35090 Central Avenue .Pennsauken, New Jersey 08109
Dear Chris:
Enclosed are copies of the data reports for metals and organics on yourBolenski sample set. Should you have any questions, please call.
Sincerely,
Daniel K. Donnell/Chief, Annapolis Laboratory
DKD:jr
Enclosurea/s
200430
y«!>,i3 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Vttlt*/ " " " " " REGION.IIV ,tcsv CENTRAL REGIONAL LABORATORY
839 BESTGATE ROAD .301-224-2740ANNAPOLIS, MARYLAND 21401 FTS-922-3752
DATE : June 27, 1984
SUBJECT: Bolenski Landfill: Water Samples for VOC's by GC/MSSuperfund Remedial; 840605-01, -02, (6/12/84 - 6/14/84) 4TFA03RD49
FROM : Rick Dreisch Diana Pickens^PChemist r-P Chemist
TO : Daniel K. DonnellyChief, Annapolis Lab
THRU : John Austin "i^Team Leader/ Organic Analysis Section
The above samples were analyzed for volatile organic compounds by GC/MS.The nominal detection limit was 1 ppb (ug/L).
Sample Description:
Lab No. Description
840605-01 Bolenski Landfill, Off-site Sampling, Blank, Sta. 00-02 Bolenski Landfill, Off-site Sampling, Stream (off-site)
Bolenski Landfill
QA Summary
Average % Recovery
6/13
Bromochloromethane 112 _+ 81,4-Dichlorobutane 109 _+ 9para-Bromofluorobenzene 110 _+ 8
n = 5
RD/DP:ad
cc: P. J. KrantzQAO, CRL
200431
U.S. Environmental Protection Agency, Region 3, Central Regional Lab
Project Name: Bolenski Landfill - Superfund Remedial
Sample Number: ' 840605-02__________________________ug/L
VOLATILES - STANDARD EQUATABLE
CasParameter Number
1,1-Dichloroethane 75-34-3 4.7
1,1,1-Trichloroethane 71-55-6 2.2
Trichloroethylene 79-01-6 1.1
VOLATILE - NON-STANDARD EQUATABLE**
cis-l,2-Dichloroethylene 156-59-2 (5)
1,4-Dioxane? 123-91-1 (Trace)1
Tetrahydrofuran 109-99-9 (2)
1,2-Dichloro-1,1,2-Trifluoroethane (1)
Ethyl Ether (Trace)1
1,1,2-Trichloro-1,2,2-Trifluoroethane ' (Trace)1
**Estimated concentration based upon internal standard/external standardcalculation.
= <1 ppb
Page 2 of 2200432
5 UNITED STATES ENVIRONMENTAL PROTECTION AGENCYREGION III
'••>„ iff ' CENTRAL REGIONAL LABORATORY839 BESTGATE ROAD 301-224-2740
ANNAPOLIS, MARYLAND 21401 FTS-922-3752
DATE : August 31, 1984
SUBJECT: Metals Determinations of Bolenski Landfill (Superfund Remedial - 4TFA03RD49)Samples 840605-01 and -02
FROM :" B. A. Sammons K. K. F. Worthington C. K. WallingChemist Physical Scientist Physical Science Tech.
TO : Daniel K. DonnellyChief, Annapolis Laboratory
THRU : E. Ramona TrovatoTeam Leader, Inorganic Analysis Section
Samples 840605-01 and -02 were analyzed by flame-, furnace, and cold vapor atomicabsorption spectroscopy. The results are presented in the attached table.
Additional quality control data are available upon request.
Sample Description:
Lab No. Description
840605-01 Bolenski Landfill, off-site sampling, Blank, Sta. 00-02 Bolenski Landfill, off-site sampling, Stream (off -site) Bolenski
Landfill
BAS/KKFW/CKW:ad
cc: P. J. KrantzQAO, CRL
200433
tU.S. Environmental Protection Agency, Region III, Central Regional Lab '
Project Name: Bolenski Landfill (Superfund Remedial) _______________
Sample Number: 840605-01 840605-02ug/L
METALS
Parameter
Antimony <5 <5*(103%)
Arsenic <2 <2*(MSA)
Beryllium <5* <5*(100%)
Cadmium <1.0 <1.0*(MSA)
Chromium <10*(105%) <10*(109%)
Copper <25 <25*(98%)
Lead <5*(106%) <5(110%)
Mercury <0.2 <0.2*(101%)
Nickel <25 <25(98%)
Selenium <2 <2*(MSA)
Silver <10*(100%) <10
Thallium <10(109%) <10*(MSA)
Zinc <10 15 1(103%)
MSA = Method of Standard Addition*Analyzed in duplicate, both values below the specified detection limit.
Page 2 of 2
200434
5 9*pJ 3 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY\«y£/ REGION III
*/- . c^ CENTRAL REGIONAL LABORATORYPBO 839 BESTGATE ROAD 301-224-2740
ANNAPOLIS, MARYLAND 21401 . FTS-922-3752
DATE : July 18, 1984SUBJECT: GC/MS Analysis of Superfund Remedial Samples 840605-01 - 02
from Bolenski Landfill
FROM • ° n Austin^^ Joseph L. SlaytonChemist <x Chemist
TQ . Daniel K. DonnellyChief, Annapolis Lab
The samples were examined for the presence of organic compounds listed as"Base/Neutral" and "Acid" extractable priority pollutants using fusedsilica capillary column/gas chromatography/mass spectrometry.Concentrations of these compounds were determined using the relativeresponse of authentic standards to the internal standard. The detectionlimit was 1 ppb for all sample extracts.
The samples were also examined for the presence of compounds in additionthose on the priority pollutant list. Tentative identification of thesecompounds was made on the comparison of sample spectra to the EPA/NIHMass Spectral Library. Concentrations for these compounds were estimatbased on the response of the internal standard.
The sample has been corrected for any blank contamination.
Sample Description:
Lab No. Description
840605-01 Bolenski Landfill, off-site sampling, Blank, Sta. 00-02 Bolenski Landfill, off-site sampling, Stream (off-site)
Bolenski Kandfill
JA/JS:ad
cc: P. J. KrantzQAO, CRL
200435
U.S. Environmental Protection Agency, Region III, Central Regional Lab
Project Name: Bolenski Landfill - Superfund Removal________________
Sample Number: 840605-01 840605-02Field Blank
u g / I u g / LBASE/NEUTRAL EXTRACTABLE PRIORITY POLLUTANT COMPOUNDS
CasParameter Number
Bis(2-Ethylhexyl) Phthalate 117-81-7 1.4Di-n-Butylphthalate 84-74-2 1.2
ACID EXTRACTABLE PRIORITY POLLUTANT COMPOUNDS
None Detected
Page 2 of_4_
200436
U. S. Environmental Protection Agency, Region 3, Central Regional La"b-
VProject Name: Bolenski Landfill - Superfiind Remedial__________________
Sample Number: 840605-02
Base/Neutral Extract
OTHER COMPOUNDSEstimated Cone.
Scan No. Tentative Identification ____ppb____
350 Heptane 4.7
Sample Number: 840605-02
Acid Extract
OTHER COMPOUNDS * "-'Estimated Cone.
Scan No. Tentative Identification ___ppb____
None Detected
Page 3 of_4_
£00437
.Surrogate Recovery
% Recovery
2-Fluoro- D6- D5-Nitro- Decafluoro D10Sample No. phenol Phenol benzene biphenyl Pyrene
840605-01 Blank. 60.9 37.4 74.5 55.4 90.9-02 48.2 29.4 81.0 100 93.6
Quality Control
1. Before acquisition of any samples the mass spectrometer is calibratedusing FC43.
2. The calibration is verified by obtaining the spectra of a knowncompound (DFTPP). All mass assignments and relative abundances arefound to be in acceptable ranges or the instrument is adjusted untilsuitable spectra of the known are obtained.
3. Immediately before analysis each sample is spiked with an internalstandard DIO-anthracene. All quantisation or estimates ofconcentration are made in comparison to the internal standard.
4. Mixed standards of extractable priority pollutants are analyzedbefore each group of samples. The relative response of each compoundversus the internal standard is determined for use in quantisation.
5. For each group of samples extracted a method blank is prepared andexamined for laboratory introduced contamination.
6. The samples were spiked with a mixture of surrogate compounds prior toanalysis. Recovery for each was determined to check for matrix effect.
P a ge 4 o f 4
200438
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY OAREGION ,., V
CENTRAL REGIONAL LABORATORY x? <>V839 BESTGATE ROAD '• '30*1 -2740
ANNAPOLIS, MARYLAND 21401 •FTS-gft'3'752
DATE : August 2, 1984SUBJECT: PCB/Pesticides Analysis - Bolenski Landfill
Superfund Remedial, 840605-01 - 02
FROM : S. R. KayserChemist
TO : Daniel K. DonnellyChief, Annapolis Lab
THRU : John Austin 0^Team Leader/ Organic Analysis Unit
Samples were extracted with 15%- Methylene Chloride in Hexane and run inaccordance with EPA Method 608' for Pesticides and PCBs.
Sample Description:
Lab No. Description
840605-01 Bolenski Landfill, off-site, Blank, Sta. 00-02 Bolenski Landfill, off-site, Stream (off-site) Bolenski Landfill
No pesticides or PCB's detected in the samples.
Spike % Recovery
Aldrin 125%pp1 DDE 109%pp' ODD 100%
SRKrad
cc: P. J. KrantzQAO, CRL
200439
PESTICIDE/PCBS PRIORITY POLLUTANT COMPOUND DETECTION LIMITS
CasParameter Number—————— ————
Aldrin 309-00-2 0.003
Alpha BHC 319-84-6 0.002
Alpha Endosulfan 115-29-7 0.005
Beta BHC 319-85-7 0.004
Beta Endosulfan 115-29-7 0.01
Chlordane 57_74»9 0.04-
4,4'DDD 72-54-8 0.012
4,4'DDE 72-55-9 0.006
4,4'DOT • •:,- 50-29-3 . 0.016
Delta BHC 319-86-8 0.004
Dieldrin • 60-57-1 0.006
Endosulfan Sulfate 1031-07-8 0.03
Endrin 72-20-8 0.009
Endrin-Aldehyde 7421-93-4 0.023
Gamma BHC (Lindane) 58-89-9 0.002
Heptachlor 76-44-8 0.002
Heptachlor Epoxide 1024-57-3 0.004
Toxaphene 8001-35-2 0.40
PCB 1016 ' 12674-11-2 0.04
PCB 1221 11104-28-2 0.10
PCB 1232 11141-16-5 0.10
PCB 1242 53469-21-9 0.05
PCB 1248 12672-29-6 0.08
PCB 1254 11097-69-1 ' 0.08
PCB 1260 11096-82-5 0.15
Page 2 of 2
200440
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UNITED STATES ENV MJENTAL PROTECTION A6ENCYREGlONlM"
CENTRAL REGIONAL LABORATORY839 8ESTGATE ROAD 301 -224-2740
ANNAPOLIS, MARYLAND 21401 FTS-922-3752
DATE : Jul* 16» 1985SUBJECT: Blosinski Superfund Site • Well Monitoring Head-Space Analysis
James Jerpe...., ^RECEIVES
T0 . Daniel K. Donnelly SITE RESPONSE SECTION JChief, Annapolis Lab
JUL221985THRU : John Austin #A
Team Leader^ Organic Analysis Section »rr»lAtI 111
Vapor head-space over well water samples taken from the Blosinski superfundsite was subjected to gas chromtography analysis in the field.
Well water was first bailed and agitated then poured into a 40 ml cleanglass vial leaving approximately 10 ml of vapor space above the solution.Vials were sealed with teflon screw caps and analyzed within one hourwith a Photovac portable photoionization gas-chromatograph. Neithersalt electrolytes nor internal standards were added to these solutions.
Standards were prepared the day previous in the laboratory by threedistinct methods each of which was evaluated concurrently with testingprocedures.
Domestic well water from residues proximal to the site were also testedby the same procedures. Results are tabulated under the home ownersproper name.
To confirm qualitative Identification of eluting gas chromatograph peaksas a quality assurance procedure, one thousand microliter of vapor abovethe water of sample from Well #3 and Hoffman #1 were each subjected toGC/MS analysis. A1r was injected directly onto a narrow-bore fused silicacapillary column and cold-trapped with liquid nitrogen. The column wastemperature-programmed and eluting peaks were identified by computerstored library search.
Following is a list of purgeable reagents detectable by photoionizationgas-chromatography previously demonstrated detectable on this equipmentand testing conditions at a minimum limit of 2 parts per billion by volumeof benzene.
DichlorofluoromethaneBromomethaneTri chlorof1uoromethaneVinyl chlorideHethylene chloride 200442
Trans-l,2-dichloroethyleneI,l-d1chloroethaneMethyl ethyl ketoneChloroforml,2-d1chloroethane1,1,1-trlchloroethaneBenzenel,2-d1chloropropaneTrlchloroethyleneBromodlchloromethaneci s-1,3-D1chloropropenetrans-l,3-Dichloropropene1,1,2-trichloroethaneTolueneDi bromochloromethaneTetrachloroethyleneChlorobenzeneEthyl benzeneBromoformTetrachloroethane
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UNITED STATES ENVIRONMENTAL PROTECTION AGENCYREGION III
.A**" /">Ck,ITB AI B
: e*0*(v,c> CENTRAL REGIONAL LABORATORY
839 BESTQATE ROAD 301-224-2740ANNAPOLIS, MARYLAND 21401 FTS-922-3752
DATE : August 20, 1985
SUBJECT: Microbiological Report for Blosinski
FROM : Daniel K. Donnelly (3ES21) _Chief, Annapolis Laboratogir
TO : Ed Shoener (3HW21)
Enclosed is the microbiological report for the Blosinski site. These sixsamples were received at CRL on July 24.DKD:jr
Enclosurea/s
RECEIVEDSITE P"— - -Jf
AUG 2 6 1985
EPA -
200445
£UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
REGION IIICENTRAL REGIONAL LABORATORY
839 BESTGATE ROAD 301-224-2740ANNAPOLIS, MARYLAND 21401 FTS-922-3752
DATE : August 14, 1985
SUBJECT: Microbiological Determinations for Total Col i form and Fecal Col i form ofBlosinski. 850724-01 -06, Superfund Remedial
FROM : Bettlna B. FletcherjrEnvironmental Scientist
TO : Daniel K. DonnellyChief, Annapolis Lab
THRU : E. Ramona Trovato'Team Leader, Inorganic Analysis Section
Samples 850724-01 - 06 were analyzed by the Most Probable Number, MultipleTube Method for Total and Fecal Coliform. The field blank, sample 850724-05, was checked for growth with a rinsing of tryptic soy broth. Theresults are presented in the table below.
Additional quality control data are available upon request.
Sample Description;
Lab No. Description
850724-01 Blosinski Landfill, Canull House, Sta. 1-02 Blosinski Landfill, Hartmetz House, Sta. 2-03 Blosinski Landfill, Bardsley House, Sta. 3-04 Blosinski Landfill, Bardsley House Dup., Sta. 4-05 Blosinski Landfill, Air Blank-06 Blosinski Landfill, Field Blank
Results;
Total Coliform Fecal ColiformOrganisms Organisms
Lab No. per 100 mL per 100 mL
850724-01 <2* <2*-02 2 <2-03 2 <2-04 2 <2-05 — No Growth-06 <2 <2
*Analyzed in duplicate, both values below specified detection limit.
BBF:ad200446cc: P. J. Krantz
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(215) 524-0180
27 May 1986
ROY F. WESTON, INC.ATTN: Mark TuckerSuite 3, 5090 Central HighwayPennsauken, NJ 08107
Dear Mr. Tucker:
Attached please find the VOA data summary for samples receivedMay 22, 1986. Please call me if you have any questions.
Very truly yours,
ROY F. WESTON, INC.
Carter P. Nulton, Ph.D.Organic Section ManagerWESTON Analytical Laboratories
CPN:ost
Enclosure
200451
WESTON AnalyticsTAT III, VGA'sRFW #8605-0050W.O. #0010-10-09
1. The following qualifiers are used on the data summary:
U - Indicates that the compound was analyzed for but notdetected. The minimum detection limit for the sample (notthe method detection limit) is reported with the U (e.g.,10U) .
J - Indicates an estimated value. This flag is used eitherwhen estimating a concentration for tentatively identifiedcompounds where a 1:1 response is assumed or when the massspectral data indicate the presence of a compound that meetsthe identification criteria but the result is less than thespecified detection limit but greater than zero (e.g., 10J).If limit of detection 10 ug/1 and a concentration of 3 ug/1is calculated, it is reported as 3J.
MS - Indicates matrix spike in which a sample is spiked withthe CLP VOA matrix spiking solution and carried through all-the steps in the method. Spike recoveries are reported.
NA - Not applicable.
DF - Dilution factor.
NR - Not required.RP - Replicate analysis.
2. Samples were collected 5/22/86 and analyzed 5/22,23/86.
3. Methylene chloride was present in the blank at a level lessthan 2X the contract required detection limit. This is anacceptable level for blank contamination according to the CLPQC requirements. Since levels of methylene chloride found inthe samples were below that present in the blank, it isconcluded that this target compound is not present in thesamples.
Carter P. Nulton, Ph.D.Organic Section ManagerWESTON Analytical Laboratories
200452
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f UNITED STATES ENVIRONMENTAL PROTECTION AGENCYREGION III
'•% ,tcTr CENTRAL REGIONAL LABORATORY*"° 839 BESTGATE ROAD 301-224-2740
ANNAPOLIS, MARYLAND 21401 FTS-922-3752
DATE : J"ne 16» 1986
SUBJECT: Analytical Results for Blosinski Landfill
FROM : Daniel K. Donnelly (3ES21)VCChief, Annapolis Laboratory
TO : Tim Travers (3HW12)
Enclosed is the VOA report for the Blosinski Landfill samples. Sampleswere originally requested on the custody sheet to be run for VGA'sas well as for the samples to be run on the Photovac. The samples werenot run on the Photovac since the VOA's were done by GC/MS. If you haveany questions, please give me a call.DKDrjr
Enclosurea/s
200457
5 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY' REGION II,
%. .<? CENTRAL REGIONAL LABORATORY '<V~*«•«>'*• 839 BESTGATE ROAD 301-224-2M)
ANNAPOLIS, MARYLAND 21401 FTS-922-3752
DATE : June 12, 1986
SUBJECT: Blosinski Landfill: Water Samples for VOC's by 6C/MSSuperfund Remedial 6UFA03RH49, (5/30/86-6/2/86), 860530-01-05
FROM : Rick'DreischChemist
TO : Daniel K. DonnellyChief, Annapolis Lab
John Austin jTeam Leaders; Organic Analysis Section
The above samples were analyzed at 25 ml for volatile organic compoundsamenable to purge and trap and identifiable by RC/MS. Selective monitoringof the 62 ion of Vinyl chloride produced no acceptable ion current attrib-utable to Vinyl chloride in any of the samples. The standard containedVinyl chloride at 16 ug/L and values 10 times smaller would easily havebeen seen.
Sample Description;
Lab No. Description
860530-01 Blosinski Landfill, Bardsley pre-filter, 09:30-02 Blosinski Landfill, Bardsley after-filter, 09:50-03 Blosinski Landfill, Bardsley pre-filter, 15:00-04 Blosinski Landfill, Bardsley after-filter, 15:00-05 Blosinski Landfill, Blank, 16:05
QA Summary:
Average % Recovery at 4 ppbl
5/30
Bromochloromethane1,4-Dichlorobutane 106+6para-Bromofluorobenzene 95jHJ
IBFB at 2 ppbRD:er
cc: B. B. FletcherQCO 200458
E.P.A. Reoicr, III Cer,:rai Regional laDC'ster.
Volatile Organics Analysis Data Sheet v /JXSite: Blosinski Landfill Units: ua/'l *5j/Proarai: Supertund Reiedial 6UFA03RH49 NG* Preserved
Date Saspled: 29-HAY -25-NAf 29-NAi 29-HAYDate Analyzed: 30-HAY 30-HAY 3C-HAY 30-HAY
Dilution Factor = ,( 0.2 ! ( 0.2 ) ( 0.2 ) ( 0.2NBL
101010105
101555
55555
51010Cw
5
555510
105555
555c
5
555
CAS I
74-87-374-83-975-01-475-00-375-09-2
47-44-175-15-075-35-475-34-3156-60-5
65-66-3107-06-278-93-371-55-656-23-5
75-2M79-34-578-E7-510061-02-679-01-6
124-48-179-00-571-43-210061-01-5100-75-8
75-25-2591-7B-6108-10-1127-18-410S-8B-3
108-90-7100-41-4100-42-4
106-42-3
541-73-1106-46-795-50-1
ChlcroiethaneBroiotethaneVinyl ChlorideChlorcethaneflethylene Chloride
AcetoneCarbon DisuHide1,1-Dichiorcethenel,i-DichloroethanEtrans-1 , 2-Di chl oroethene
Chlorofori1,2-Dichleroethane2-Butanone1.1.1-TrichloroethaneCarbon Tetrachioride
B'oiodichloronBthare1.1,2,2-Tetrachloroethane1,2-Dichloropropanetrans-1, 3-DichloropropeneTri chl oroethene
Dibrciochlorciethane1.1,2-TrichlcrcethaneBenzenecis-1. 3-Dichloropropene2-Chloroetnylvinylether
Broiiofori2-Hexanone4-Hethyl -2-pentanoneTetrachloroetheneToluene
ChlorobenreneEthyl benzeneStyreneto & p)-Xylene isoters'.l!•-Ivlene
l,3-Dichloroben:enel,4-Dichloroben:ene1,2-Dichlorobenzene
860530-01
0.02J
0.9J
860530-02
•
0.2J
860530-03
O.OBJ
2.7J
5.4
0.1J
860530-04
0.2J
• 200459N3L * Nosinal Caantitation LilitJ = Estinated value; presence oi coepounds is indicated, but the response is less than the Quantitat:on liiitActual Buantitation Li*it = Dilution Factor x N8L(1) = Calculated iron o-Xylene
Page 2 of 3
Blosinski Landfill
Non-Standard Equatable Compounds
860530-01 860530-02 B60530-03 860530-04u g / L u g / L u g / L u g / L
cis-l,2-Dichloroethylene 0.1J 0.1J l.OJ 0.1Jl,l;2-Trichloro-1,2,2-Trifluoroethane 0.3J — 1.3J
200460Page 3 of 3_
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UNITED STATES ENVIRONMENTAL PROTECTION AGENCYREGION III
CENTRAL REGIONAL LABORATORY839 BESTGATE ROAD 301-224-2740
ANNAPOLIS. MARYLAND 21401 FTS-922-3752
DATE : September 15, 1986SUBJECT: Organic Data QA Review, Case 6348, Site: Blosenski
FROM -. Diana PickensChemi st
TO : Tim Travers (3HW12)CERCLA Enforcement Section
THRU : Patricia J. Krantz (3ES23)Chief, QA Section w
Introduction
The findings offered in this report are based upon a general review ofsample data, blank analyses results, surrogate and matrix spike results,target compound matching quality, and tentatively identified compoundresults for 38 aqueous samples analyzed by one laboratory.
The attached data summary contains only compounds which were reportedas detected in at least one sample. The complete list of target compounds,their results, and associated detection .limits are located as an Appendix.
The data summary contains the following qualifier codes:
U - The material was analyzed for, but was not detected. The associatednumerical value is the estimated sample quantitation limit.
J - The associated numerical value is an estimated quantity becausequality control criteria were not met.
N - Presumptive evidence of presence of material (tentativeidentification.)
The laboratory performed the analyses in compliance with CLP, includingthe required quality control. Holding times were met and tune andcalibration were within specifications. The package contains allinformation needed to assure compliance with the procedures. Nosignificant problems were encountered. Minor exceptions are discussedin the following section.
200482
*ir
cQualifiers
0 All reported concentrations of methylene chloride and acetone werenot above the levels detected in laboratory and/or field blanks.All positive values have been qualified as not detected (U) and thesample quantitation limit has been qualified as estimated (J).
0 No tentatively identified compounds were detected in any samples.
0 Very low concentrations of 1,1,1-trichloroethane and tetrachloroethenewere detected in the raw data for CC907. These trace levels are notrequired to be reported under the organics Statement of Work. Uponspecial request, the lab analyst verbally confirmed the presence ofthese compounds. The results were added to the data summary duringthe data review with the qualifier N to indicate the identificationis tentative and J to indicate the reported concentration is estimated.
Summary
All samples were successfully analyzed for Volatile Organics (VOAs).Very few positive results were detected by the CLP lab through theRoutine Analytical Service. The differences between the field screeningresults and this data set may be due to the difference in the methoddetection limits.Please see the accompanying support documentation appendices for specifics
Attachments
cc: Monica Connolly, FIT
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ORGANIC DATA VALIDATION SUMMARY page 1 of__(_
Date Review CompleteCase No. fc?*f « S
d HjtolSfeAS No. Contract
Site Name Bio^roU ContractSample Nos. ccQol «,
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CONCENTRATIONMATRIX low mesoil /solidaqueous 3 fcother
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Lab COMNo. (*«TOM ft*"P i* * H A.
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VOLATILES6C/MS tunlnq— BFBInitial CalibrationContinuing CalibrationSurrogate RecoveryMatrix SplicesReachole
ent Blanksing times
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ACTION COMMENTS
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SEMI-VOLATILESGC/MS tuning— DFTPPInitial CalibrationContinuing CalibrationSurrogate RecoveryMatrix SpikesReacUoU
ent BlanksIng times —— fc
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PESTICIDES JInstrument PerformanceInitial CalibrationContinuing Calibration"Surrogate Recove^fMatrix Splkftr"ReaghoU
entx*Tanks<rffg times
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OVERALL CASECompound IdentificationData Completeness
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REVIEWER'S COMMENTS:
*DOCUMENTATION ATTACHED (see following pages) 900 1R7
