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What is Condensed Matter Physics? Can we manipulate materials? Can we design new materials? Christianne Beekman FSU Physics Department Quarknet July 10 th 2015

What is Condensed Matter Physics? - Florida State Universitywahl/Quarknet/summer2015/lectures... · Iron Age (c. 1200 BCE – 400 AD) From Tutankhamun’s Tomb (c. 1323 BCE) From

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Page 1: What is Condensed Matter Physics? - Florida State Universitywahl/Quarknet/summer2015/lectures... · Iron Age (c. 1200 BCE – 400 AD) From Tutankhamun’s Tomb (c. 1323 BCE) From

What is Condensed Matter Physics?

Can we manipulate materials?

Can we design new materials?

Christianne Beekman FSU Physics Department

Quarknet July 10th 2015

Page 2: What is Condensed Matter Physics? - Florida State Universitywahl/Quarknet/summer2015/lectures... · Iron Age (c. 1200 BCE – 400 AD) From Tutankhamun’s Tomb (c. 1323 BCE) From

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Translational and rotational invariance

Quarknet July 10th 2015

The Building Blocks: Atoms

Page 3: What is Condensed Matter Physics? - Florida State Universitywahl/Quarknet/summer2015/lectures... · Iron Age (c. 1200 BCE – 400 AD) From Tutankhamun’s Tomb (c. 1323 BCE) From

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Translational and rotational invariance

Interaction is a kind of action that occurs as two or more objects have an effect upon one another.

Emergent properties

Quarknet July 10th 2015

The Building Blocks: Atoms

Page 4: What is Condensed Matter Physics? - Florida State Universitywahl/Quarknet/summer2015/lectures... · Iron Age (c. 1200 BCE – 400 AD) From Tutankhamun’s Tomb (c. 1323 BCE) From

“Condensed matter physics is the field of physics that deals with the macroscopic and microscopic physical properties of matter. In particular, it is concerned with the “condensed” phases that appear whenever the number of constituents in a system is extremely large and the interactions between the constituents are strong. The most familiar examples of condensed phases are solids and liquids, which arise from the electromagnetic forces between atoms. “

Why do we study it? Interactions complexity Complexity functionality

Quarknet July 10th 2015

Condensed Matter Physics

According to Wikipedia:

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Page 5: What is Condensed Matter Physics? - Florida State Universitywahl/Quarknet/summer2015/lectures... · Iron Age (c. 1200 BCE – 400 AD) From Tutankhamun’s Tomb (c. 1323 BCE) From

Unit Cells

5 Quarknet July 10th 2015

Crystalline Materials

Page 6: What is Condensed Matter Physics? - Florida State Universitywahl/Quarknet/summer2015/lectures... · Iron Age (c. 1200 BCE – 400 AD) From Tutankhamun’s Tomb (c. 1323 BCE) From

Structure: Optical properties Magnetism Conductivity Superconductivity

6 Quarknet July 10th 2015

Structure and Properties

Page 7: What is Condensed Matter Physics? - Florida State Universitywahl/Quarknet/summer2015/lectures... · Iron Age (c. 1200 BCE – 400 AD) From Tutankhamun’s Tomb (c. 1323 BCE) From

Quarknet July 10th 2015

H

H

O

Cl

Na

Structure and Symmetry

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Page 8: What is Condensed Matter Physics? - Florida State Universitywahl/Quarknet/summer2015/lectures... · Iron Age (c. 1200 BCE – 400 AD) From Tutankhamun’s Tomb (c. 1323 BCE) From

Glass = amorphous solid Why is glass transparent? Why are metals shiny?

8 Quarknet July 10th 2015

Structure and Optical Properties

Page 9: What is Condensed Matter Physics? - Florida State Universitywahl/Quarknet/summer2015/lectures... · Iron Age (c. 1200 BCE – 400 AD) From Tutankhamun’s Tomb (c. 1323 BCE) From

9 Quarknet July 10th 2015

Condensed Matter Physics

It is ubiquitous

It is useful, we can use it to explain processes and objects that surround us

The knowledge from research and discovery are used to improve our everyday lives.

Page 10: What is Condensed Matter Physics? - Florida State Universitywahl/Quarknet/summer2015/lectures... · Iron Age (c. 1200 BCE – 400 AD) From Tutankhamun’s Tomb (c. 1323 BCE) From

Materials in the human hand

can become a technology.

Further improvement of craft

can evolve into new artforms.

Frances Martinez

10 Slide from G. Boebinger Quarknet July 10th 2015

Can we Manipulate Materials?

Page 11: What is Condensed Matter Physics? - Florida State Universitywahl/Quarknet/summer2015/lectures... · Iron Age (c. 1200 BCE – 400 AD) From Tutankhamun’s Tomb (c. 1323 BCE) From

The “Iceman” Lived at the Transition from Neolithic Age to Copper Age

3300 B.C.E.

The Iceman’s Axe At the top of the carefully smoothed yew haft is a forked shaft into which the 9.5 cm blade was fixed with birch tar and tightly bound with thin leather straps. The blade is made of almost pure copper. The narrow end was produced by cold-hammering after the blade was cast. ALL OF THESE MATERIALS ARE FOUND MATERIALS

11 Slide from G. Boebinger Quarknet July 10th 2015

The Copper Age

Page 12: What is Condensed Matter Physics? - Florida State Universitywahl/Quarknet/summer2015/lectures... · Iron Age (c. 1200 BCE – 400 AD) From Tutankhamun’s Tomb (c. 1323 BCE) From

Iron Age (c. 1200 BCE – 400 AD)

From Tutankhamun’s Tomb (c. 1323 BCE)

From Saphar-Kharaba Late Bronze Age Cemetery (c. 1300 BCE) in Southern Georgia (The country, not the state)

Bronze = Copper + 10% Tin Required long-distance trade routes

12 Slide from G. Boebinger Quarknet July 10th 2015

Human Invention of Materials begins

Page 13: What is Condensed Matter Physics? - Florida State Universitywahl/Quarknet/summer2015/lectures... · Iron Age (c. 1200 BCE – 400 AD) From Tutankhamun’s Tomb (c. 1323 BCE) From

Soot - carbon black

Calcite - CaCO3 Bone White - Ca5(CO3)2(OH)2 White Lead – 2Pb(CO3)2·Pb(OH)2

Cinnabar - HgS Hematite - Fe2O3 Red Lead – Pb3O4

Malachite – Cu2CO3(OH)2

Han Purple - BaCuSi2O6 Han Purple*** - BaCuSi2O6

Han Blue*** – BaCuSi4O10

*** human-made pigment

Han Purple: the first synthetic purple pigment. Likely made from a mix of barium and copper minerals, quartz, and a lead salt as an extra ingredient that acts as a catalyst and flux. The mixture needed to be heated to between 900 and 1000 C – any hotter and Han blue results, which is closely related to Egyptian blue (CaCuSi4O10), the oldest known synthetic pigment in the world.

Human Invention of Materials for Aesthetic Reasons (700 BCE – 200 AD)

*** human-made pigment

13 Slide from G. Boebinger Quarknet July 10th 2015

Page 14: What is Condensed Matter Physics? - Florida State Universitywahl/Quarknet/summer2015/lectures... · Iron Age (c. 1200 BCE – 400 AD) From Tutankhamun’s Tomb (c. 1323 BCE) From

…Cast Iron can build Soho

Limitation of the then State-of-the-Art

Material… CAST IRON

Cast iron building architecture

reaches six stories

14 Slide from G. Boebinger Quarknet July 10th 2015

Materials Limitations in the 20th century

Page 15: What is Condensed Matter Physics? - Florida State Universitywahl/Quarknet/summer2015/lectures... · Iron Age (c. 1200 BCE – 400 AD) From Tutankhamun’s Tomb (c. 1323 BCE) From

It takes STEEL to build Midtown

Research and development to improve steel continues at the MagLab

15 Slide from G. Boebinger Quarknet July 10th 2015

The Steel Age (20th c.)

Page 16: What is Condensed Matter Physics? - Florida State Universitywahl/Quarknet/summer2015/lectures... · Iron Age (c. 1200 BCE – 400 AD) From Tutankhamun’s Tomb (c. 1323 BCE) From

16 Quarknet July 10th 2015

Doping: semiconductors to control electrical properties

Diode, Transistors iphones etc. Whenever you put different atoms together interesting properties emerge

n-type p-type

Semiconductors: (20th and 21st c.)

Page 17: What is Condensed Matter Physics? - Florida State Universitywahl/Quarknet/summer2015/lectures... · Iron Age (c. 1200 BCE – 400 AD) From Tutankhamun’s Tomb (c. 1323 BCE) From

17 Quarknet July 10th 2015

Can we Design New Materials?

Page 18: What is Condensed Matter Physics? - Florida State Universitywahl/Quarknet/summer2015/lectures... · Iron Age (c. 1200 BCE – 400 AD) From Tutankhamun’s Tomb (c. 1323 BCE) From

Quarknet July 10th 2015

Ways to Manipulate the Lattice

Doping and impurities

External perturbations: temperature and applied fields

External pressure: hydrostatic and strain

Page 19: What is Condensed Matter Physics? - Florida State Universitywahl/Quarknet/summer2015/lectures... · Iron Age (c. 1200 BCE – 400 AD) From Tutankhamun’s Tomb (c. 1323 BCE) From

Unit Cells

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Unit Cell

Page 20: What is Condensed Matter Physics? - Florida State Universitywahl/Quarknet/summer2015/lectures... · Iron Age (c. 1200 BCE – 400 AD) From Tutankhamun’s Tomb (c. 1323 BCE) From

Thin Films Growth: Epitaxial Strain

20 Quarknet July 10th 2015

tensile compressive

σ σ

Page 21: What is Condensed Matter Physics? - Florida State Universitywahl/Quarknet/summer2015/lectures... · Iron Age (c. 1200 BCE – 400 AD) From Tutankhamun’s Tomb (c. 1323 BCE) From

Laser : 248 nm

Substrate on heater Typically ~ 600 - 800 °C

target

21 Quarknet July 10th 2015

How do we make thin films?

Page 22: What is Condensed Matter Physics? - Florida State Universitywahl/Quarknet/summer2015/lectures... · Iron Age (c. 1200 BCE – 400 AD) From Tutankhamun’s Tomb (c. 1323 BCE) From

Substrate on heater Typically ~ 600 - 800 °C

target

Laser : 248 nm

22 Quarknet July 10th 2015

How do we make Materials?

Page 23: What is Condensed Matter Physics? - Florida State Universitywahl/Quarknet/summer2015/lectures... · Iron Age (c. 1200 BCE – 400 AD) From Tutankhamun’s Tomb (c. 1323 BCE) From

Substrate on heater Typically ~ 600 - 800 °C

target

Laser : 248 nm

23 Quarknet July 10th 2015

How do we make Materials?

Page 24: What is Condensed Matter Physics? - Florida State Universitywahl/Quarknet/summer2015/lectures... · Iron Age (c. 1200 BCE – 400 AD) From Tutankhamun’s Tomb (c. 1323 BCE) From

Thin Film Growth: Pulsed Laser Deposition Setup

24 Quarknet July 10th 2015

Page 25: What is Condensed Matter Physics? - Florida State Universitywahl/Quarknet/summer2015/lectures... · Iron Age (c. 1200 BCE – 400 AD) From Tutankhamun’s Tomb (c. 1323 BCE) From

Thin Films: Applications

25 Quarknet July 10th 2015

Older Hard drive Locally change magnetization in a magnetic particles through applied magnetic field. Basically an electromagnet

GMR Hard drive Much more expensive to fabricate but much more sensitive and higher density

Page 26: What is Condensed Matter Physics? - Florida State Universitywahl/Quarknet/summer2015/lectures... · Iron Age (c. 1200 BCE – 400 AD) From Tutankhamun’s Tomb (c. 1323 BCE) From

Thin Films: Applications

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Touchscreen Indium Tin Oxide is transparent like glass but is also conductive. Oxygen stoichiometry determines the conductivity. Basically n-type semiconductor.

Page 27: What is Condensed Matter Physics? - Florida State Universitywahl/Quarknet/summer2015/lectures... · Iron Age (c. 1200 BCE – 400 AD) From Tutankhamun’s Tomb (c. 1323 BCE) From

Future

27 Quarknet July 10th 2015

Investigate the effect of doping and impurities

External perturbations: temperature and applied fields

Apply Strain to materials that have never been grown in thin film form

Expand our knowledge about the Physics of materials

Page 28: What is Condensed Matter Physics? - Florida State Universitywahl/Quarknet/summer2015/lectures... · Iron Age (c. 1200 BCE – 400 AD) From Tutankhamun’s Tomb (c. 1323 BCE) From

My Group

We are constantly making new materials and pushing the boundaries of condensed mater physics

28 Quarknet July 10th 2015