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    Advancements in Textiles Series 2012EDPIU, MINTEX --- SFDAC

    AdvancedDyeing & PrintingTechniques

    Muhammad Hanif MemonSynthetic Fiber Development and Application CenterMinistry of Textile Industry, Government of Pakistan

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    The Textile Industry, including the dyeing sector,

    has undergone major changes,

    Which are centered on

    The introduction of new fibers

    (and dyes for their coloration)

    New machinery for more efficient processing

    More severe demands from the consumer

    Legislation controlling environmental issues

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    Two primary forces have driven recent

    technologies in Coloration

    The Environment

    andThe Economy

    i.e.,

    ENVIRO-ECONOMICS

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    The textile companies will be competing

    more and more on a global basis

    The successful must deliver quality products,

    on time, and maintain the highest standards

    Developments in machinery

    have a critical part to play,

    butwithout state-of-art-chemical technology

    even the most sophisticated machinery

    will not provide optimum performance

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    Companies wishing to improve their

    environmental performance through technology

    may

    Control established production processes by

    treating waste emissions,

    in order to limit the impact on the environment

    OR

    Adopt clean technologies that incorporate

    environmental considerations into their design,

    to avoid or reduce adverse impact on the

    environment

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    There is now a global perspective for

    the textile and apparel industries,

    which has been brought about by

    economic growth,

    development of communication

    technologiesand

    the unprecedented ability to transport

    people and goods throughout the world

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    Automatic Control is used on both batch and continuous processes,

    giving marked improvements in productivity and savings in resources.

    Automatic Control results into

    Increased production and improved quality, because machine will be

    running at the set optimum conditions.

    Savings in plant costs, because the dyeing process, equipment and

    ancillary processes will have been designed to operate under automatic

    control

    Savings in raw materials arising from processes being carried out underoptimum conditions

    Improved working conditions

    Improved plant management

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    An automatically controlled plant

    provides more information of higherquality on process conditions, leading

    to potential improvements in process

    operation

    The danger here is thatThe information is not understood or it

    cannot be acted upon

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    S o f t f l o

    W i n c h

    K n i t t e d

    J i g g e r

    W o v e n

    P a c k a g e C a b i n

    F i b r e / Y

    E x h a u s

    C o l d P a d ( C P B )

    P a d - J i g P a d - D r y -

    W o v e n /

    S e m i - C o n

    P a d - D r y - P

    ( P D P S )

    W o v e n

    C o n t i n u

    D y e i n g

    D i r e c t

    D i s c h a r

    R e s i s t

    F l a t b e d / R o l

    P r i n t i n

    A p p l i c a t

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    Stringent Quality requirements led by export market

    Higher pressure on Price Trend towards high economy

    Conservation of Energy / Utility Cost

    Shift of manufacturing from Europe to Asia

    Growing commoditization of Products

    Modernization, Automation & Re-structuring activities

    Growing importance of Brands and Retailers

    Fast changing consumer tastes

    Newer fibres and blends

    Better RFT and Reproducibility

    Shade accuracy and quick delivery

    Increase in the technical su ort re uirements b the user

    Changing Scenario

    Textile Industry

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    Reduced Costs

    Less Dyestuff Less Chemical

    Less Water Less Energy Reduced Stock Costs

    Higher Productivity

    Shorter cycles RFT Performance Robustness

    Product Integrity

    Shade Reproducibility Color Fastness Eco-compliance

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    Exhaust

    Hot13.0%

    Exhaust

    Warm

    40.0%

    Pad -

    Batch

    15.0%Continuous

    11.0%

    Printing

    21.0%

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    Blended

    42.0%

    Cotton

    43.5%

    Synthetic

    12.5%

    Silk

    1.5%

    Wool

    0.5%

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    Disperse

    32.7%

    Reactive

    29.4%

    Acid

    12.4%

    Direct

    4.6%

    Others*

    14.9%

    Vat

    6.0%

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    E-Control System

    Digital Ink Jet Printing

    RFT Approach

    Dyeing in Ultra Low Liquor ratio

    Dyeing of Newer fibers & Blends (Lycra, Lyocell, bamboo etc.)

    Rapid dyeing Disperse dye

    One Bath Continuous dyeing of Polyester / Cellulose blends

    (without R.C.)

    Pad OX Process

    Reactive dyeing Perceptible shift from Hot dyeing to Warm dyeing

    process

    Replacement of Vat dyes with Reactive dyes - achievement of Light

    and Wash fastness properties.

    Recent Applications / Concepts

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    E-ControlProcess One Step, Simple & Economical Continuous process

    No unproductive batching sequence

    Ideal for short lot dyeing

    Effective Wash-off

    A wide variety of fabric can be dyed

    Rapid shade matching in laboratory

    Energy efficient

    Performance

    High Productivity due to short process Environment friendly as no salt, urea & silicate are used

    Soft handle of fabric due to mild fixation conditions

    Migration is minimised by rapid fixation & humidity control

    No crushing of pile fabrics.

    Improved penetration of different fabrics - Presence of Humidity at

    high temp. Very good Lab- to -Bulk & Bulk- to-Bulk reproducibility.

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    RFT ApproachImportant FactorsImportant Factors

    Raw material: Substrate

    Dyestuffs

    Chemicals

    Water

    Preparation of Substrate Process Conditions: Machine parameters

    Liquor ratio Time / Temperature

    profile

    Dye bath pH

    Concentrations of

    Chemicals

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    THE BENEFITS OF

    FINANCIAL

    Lower Costs per Batch

    Increased Output

    Improved Profit margin

    NON FINANCIAL

    Better Customer Service

    Improved Quality

    Reduced Effluent load

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    19

    RFT Approach

    NON RFTNON RFT Impact on Process Costs Impact on Process Costs

    RFT 1 Add 2 Adds BlackOverdye

    Unlevel Off Shade& Unlevel

    0

    150

    100

    50

    200

    Re

    lativeBatc

    hCost

    100

    118

    134141

    180200

    Dye Energy Water Chemicals Labour Fixed Drying

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    RFT Approach

    NON RFTNON RFT Impact on Productivity Impact on Productivity

    100% RFT90% RFT80% RFT70% RFT60% RFT0

    75

    50

    25

    100

    %M

    achine

    Time

    % PRODUCTIVE TIME % REPROCESSING TIME

    20

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    Dye HouseManagementKey FactorsKey Factors Cost Reduction

    RFT Approach

    Technology Up-gradation

    Improved quality

    Reduced cycle times

    Reduced lead time for delivery

    Perfect Repeatability

    Reliable results satisfying critical

    fastness requirements

    Maximum machine flexibility

    International competitiveness

    Much reduced environmental im act

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    From a practical point of view

    Textile printing is the process which

    incorporates artistic design,engineering and chemical technology

    to produce unique patterns which can

    then be accurately repeated on largevolumes of fabric

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    Most common Printing techniques

    Screen Printing, both rotary and

    flat bed

    Transfer Printing

    The newer technique

    Digital Printing

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    Rotary

    Screen

    58.0%

    Flat Bed

    28.0%

    Transfer

    5.0%

    Intaglio

    3.0%

    Hand

    Screen

    6.0%

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    The trends in textile printing include:

    Continued improvement of

    microprocessor control systems forprinting machines of all types

    including flat-bed screen, rotary

    screen, transfer printing calendersand digital ink-jet printers

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    Refinements in Screen Printing

    Increased printing output

    Minimization of set-up timesHigher print pattern control

    Minimization of downtime for pattern

    changeover and machinery cleaning

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    Improvement in mechanical design

    Hydraulic drives replaced with electronicdrive systems

    results into increased printing speeds with

    subsequent reduced maintenance costs

    Both rotary and flat-bed printing machines

    with highly compact print tables in order to

    conserve expensive processing floor

    spaces

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    Refinements in

    Color mixing and dispensing systems

    Print paste recovery and reuse

    Improved systems for filmless screen engraving

    Which produce excellent image resolution with

    increased accuracy

    Also engrave screens at a higher productivityrate, thus reducing the overall cost of the

    engraving process.

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    Heat Or Sublimation Transfer Printing:-

    Clean & environmentally safe.

    The only by product is paper.

    Perfect medium for today's

    market demand (apparel).

    Fes samples can be

    produced at small scale with

    good results at lesser cost.

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    Mechanism:-

    Sublimation paper & special dyesublimation inks are used.

    Temperature & heat is provided.

    Transfer inks are passed over to

    the printable material.

    The inks (sublimation) permeate

    the coating of the material.

    Excellent fastness.

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    Why Ink-jet? Simple technology and high quality

    Existing colorants can be used [Reactive / Disperse / Acid / Pigment]

    Constantly improving technology [Robustness, Speed (>100 m

    2

    /hr.),Quality (1440 dpi)]

    Printing of innovative & unique designs

    No screens / Unlimited colours in a design

    Outstanding colour gamut

    Different types of SubstratesTrend is towards digital photography (Home / Photolabs]

    Lower start-up costs & shorter production times

    Shorter time from design to print

    Supply chain advantages

    More design options

    Reactive dyes in ink-jet printingPurified MCTs

    Inks specially designed for existing ink jet head technology

    Covalent bond gives excellent wash fastness

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    DR AM b R i i

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    DReAM by Reggiani

    Two unique innovationsFirst, it combines the high technology of Reggiani swell proven textile substrate conveying systems,

    holding the fabric in position very accurately, with

    Aprion s Magic six color inkjet heads.

    Second, it use completely new printing inks developed

    by Ciba Specialty Chemicals. These inks include

    reactive dyes, acid dyes, disperse dyes and pigments.

    This machine reportedly achieves printing speed of up

    to 150 square meters per hour, with designs suitable

    for both apparel and home furnishing.

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    DuPonts Artistri machine is built by Toshin-Kogyo of Japan, and the two companiescelebrated the shipment of their50th machine as a milestone. The marriage of

    Toshin-Kogyos experience and expertise in the

    design of textileprinting equipment with DuPonts leadershipposition in chemistry and inkjet technology hasallowed the companies to co-operatively

    develop a uniquely capable and robust system,said Shiro Ichinose, president of Toshin-Kogyo.

    The system includes DuPonts Artistri inks for

    silk, polyester, wool, cotton and nylon/Lycra;

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    The DuPont Artisri

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    The Isis competes head-to-head with rotary screen

    printing, printing 20 linear meters a minute (1.6m wide)

    at 1440dpi, using either reactive or pigment inks.

    Crucially, the machine will use standard screen

    printing inks, vastly reducing the cost per meter,

    with pigments this will be around 1 per linear meter;a little more for reactive. The figure includes capital

    costs, and no pretreatment is required.

    Based on three color ways per design, the print costfor runs of less than 1,000 meters will be equal

    to or less than rotary screen printing. However, for

    longer runs (e.g., 1,500m) will be slightly higher.

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    There is a strong correlation, among these

    machines, between production capacity and

    price, making it hard to pick a winner.

    Artistri, for example, with a typical printing speed of

    30m2/hour, comes at a capital cost of around 150,000;

    The DReAM does 150m2/hour but costs 750,000.

    The expensive special inks often required also have to

    be accounted into the calculation.

    The most original machine of them all is the Isis (price

    tag 3 million), from Dutch firm The Isis Osiris.

    The Mona Lisa machine starting at 250 000 uses

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    The Mona Lisa machine, starting at 250,000, uses

    Epson printhead technology, but its unique configuration

    of 24 print heads produces greater speed than the

    familiar sampling printers. The 12 Mona Lisa so fardelivered have gone mainly to the Como district of Italy

    and are being used on silk, cellulose and

    polyamide/elastomer, in conjunction with the Genesta

    family of inks from For.Tex.

    According to Robustelli, print speeds in the first year

    since launch have increased from 78m2/hour to

    120m2/hour, without loss of quality. Intermediate printing

    resolutions of 450dpi and 630dpi have been added to

    the standard 360-540-720dpi.

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    The Mona Lisa by Robustelli

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    Another change is the ability to adjust the gap between

    the heads and the fabric during printing, without stopping

    the printing itself. It is very likely that during mass

    production the fabric to be printed is uneven (seams,

    frays or thickness unevenness), says Robustelli. It is

    therefore essential to have the possibility to change thegap between the heads and the fabric without stopping

    printing, then go back to the original gap. Other recent

    improvements include the drying and printed-fabric

    collection systems. Infrared radiators are now combinedwith a special ventilation system, and continuous

    collection of the fabric, with start-stop photocells, has

    been added as standard.

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    Recently added features include an

    advanced feeding system that allows for

    the use of wider varieties of fabrics, and anew selvage protection mechanism that

    improves printing reliability.

    DuPont Ink Jet has opened its DuPont

    Artistri Technology Center (ATC) in

    Cavenago, (Milan) Italy, providing

    demonstrations, technology training and

    customer service.

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    Another wide-format printer with interesting characteristics is the

    VirtuMT, built by the Swiss Spuhl AG, a subsidiary of AmericasLeggett & Platt. This super wide machine offers a single 2.5m

    printing width, or even a 3.5m version that will print 2x1.5m widths.

    Speed is claimed to be up to 125m2/hour, or 35m2/hour

    (2-pass/600 dpi, 6 colours).

    The machine is already established in the graphics market, while

    dye-sublimation printing on textiles was introduced early in 2003

    and direct printing with UV-curing pigment inks was launched at

    ITMA. However, the problem was close to a solution and new inks

    were expected to be available late this year or early next. The Virtu

    range starts at around 320,000.

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    The Virtu

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    Nano Art Nanotechnology Coatings Textile

    Paper, claiming this to be the first and only

    product of its type in the world specificallyintended for computer-generated, fine-art

    inkjet printing, and made from nano-coated

    polyester, cotton and blends

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    The further one looks into the future, the more exciting the

    possibilities become. Researchers at the University of Arizona

    talk about light-emitting textile curtains and window blinds based

    on ultra-thin organic films that either emit light,

    or alternatively, act as solar cells, collecting light to generate

    electricity.

    Ghassan E. Jabbour, associate research professor of optical

    sciences and his group, along with European partners, are

    developing nanometre-thick organic films for printing on paper,

    plastic and textiles. His laboratory claims to be the first to printorganic light-emitting devices on large areas of plastic and

    textile by screen printing and has also developed a unique

    technique for inkjet printing these layers on to textiles.

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    In terms of more conventional textile printing and

    coloration, nano-powders are likely to have animportant impact on future ink technology and all major

    producers are believed to have active research

    programs in this area.

    For example, in Israel, which is a leading developer

    and producer of inkjet technology, a consortium of 14

    companies and 12 academic research groups, Nano

    Functional Materials (NFM), has been formed to seek

    new ways of fabricating and using nano-particles in

    industrial processes and products.

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    SciTex Vision, developer of the unique Aprion piezo drop-on-

    demand technology used by the Reggiani DReAM printer, isanother member of the consortium and is seeking to develop a

    new generation of inks based on nanotechnology of pigments

    and polymers to achieve high performance inks and films

    through ultra-high jetting performance (drop velocity,

    directionality, jetting stability), conductivity, stabilization and

    better color gamut.

    Nanotechnology also offers new routes to achieving effects such

    as metallic or opalescent prints that are difficult or expensiveusing existing inkjet techniques, while printed nano-films can

    produce iridescent effects on textiles.

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    Advancements in Textiles Series 2012EDPIU, MINTEX --- SFDAC AdvancedDyeing &

    Printing