SDMS US EPA REGION V -1
SOME IMAGES WITHIN THISDOCUMENT MAY BE ILLEGIBLE
DUE TO BAD SOURCEDOCUMENTS.
GULF COAST LABORATORIES, INC.
2417 Bend St. Unhrtrtity Park, Illinois 60466
Phoow (312) 534-5200 (219)885-7077 (815) !
'
June 29. 1987
Mr. John MatlockMAECORP. IncorporatedPlain & Route 2Westville. IN 46391
Dear Mr. Matlock:
Please find enclosed the analytical reports for yourProject *IN505. P.O.* 21848IN505. They were submitted toftulf Coast Laboratories, Inc. on June 10. 1987. They wereidentified as follows:
GCL*
107402107403107404107405107406107407
IDENTIFICATION
MC-001MC-002MC-003MC-004MC-006MC-007
EffluentEffluentEffluentEffluentEffluentEffluent
SAMPLE DATE
06/04/8706/05/8706/06/8706/07/8706/09/8706/10/87
If you have any questions, please contact ourlaboratories.
Sincerely,
QULF COAST LABORATORIES. INC.
John BoudreauAnalytical Director
JB/kl
Enclosures
V " ' • » ' '•'•-. , ••/ • .. . .' 'i * i frafeli l^yififff T • ' • • ' ' ' ' ' V. ,'rirt^i<^.-'f--^.»>r?'.v.^~-~ / ^•'J:';l^rs*Wn*^*?l!^P5PfR^r^5nPf'?v^"i' *' ' ' ' . . ' ' * "
• ' ' « . ' " • • . - > • ,
/terlfc^Fffc^iL^liii^HHP^P^^
I TO: MAECORP Incorporated DATE1 Plain & Rt. 21 Hestville IN 46391 RE
1 ATTN: Mr. John Matlock
1 • '!*:' ''' MWBMIP^P '1 ^ GCL 9 PARAMETERS ' """HW PlliVPP'l
1 107402 Chromium, Total
1 107402 Lead, Total
1 107402 Oil and Grease (Freon Extraction)
107402 PCBs, Total
107402 Aroclor 1016
107402 Aroclor 1221
107402 Aroclor 1242
_ 107402 Aroclor 1248
1 107402 Aroclor 1254
107402 Aroclor 1260
107402 pH
107402 Phenols
107402 Solids, Total Suspended107402 Zinc, Total
^^ ')^Sl ^apiftfe::.- ;'» . * * . ' . * .
GULP COAST LABORATORIES, INC
2417 Bond St., University P«rk, I l l inoi* 60466PtwfMt (312) 534-5200 (219)8857077 (815)
A N A L Y T I C A L R E P O R T
: 06/25/87
: Proj* IH505 - P0# 21848IHJMC-001 EffluentSample Date: 06/04/87Date Received: 06/10/87GCL Number: 107402
liprfp^^ **ANALYST RESULTS
jh < 0.020 mg,
nt 0 . 062 mg,
rsk < 5 mg,
Ism < 0.001 ag,
Ism < 0.001 mg
Ism < 0.001 mg
lSB < 0.001 Bg
Ism < 0.001 agIsa < 0.001 ag
Isa < 0.001 agks 7.8efl 0.013 ag
bt 28 Bg
jh < 0.010 ag
GULF COAST LABORATORIES. INC
2417 Bond St., University Park, Illinois 60466
Phorwi (312) 534-5200 (219)8857077 (8151
ANALYTICAL REPORT
TO: MAECORP. IncorporatedPlain it Route 2Westville, IN 46391
ATTN: Mr. John Matlock
DATE: June 12, 1987
RE: Project «IN505 P.0.421848IFMC-001 EffluentSample Date: 06/04/87Date Received: 06/10/87GCL* 107402
VOLATILE COMPOUNDS '""*^~-u-!> 1-XfW
Chloromethane
Bromomethane
Vinyl Chloride
Thloroethane
Methylene Chloride
Acetone
Carbon Bisulfide
1 , 1 -Dichloroethene
1 , 1-Dichloroethane
Trans-1 , 2 -Dichloroethene
Chloroform1 , 2-Dichloroethane
2-Butanone
1,1,1 -Tr ichloroethane
Carbon T«traohlorid«Vinyl AcetateBronodichXoroMetnaiie
'" "iRfffillLT r™' '" ™~* DETECTION LIMIT
BDL
BDL
BDL
BDL
BDL
BDL
BDLBDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
10
10
10
10
5
10
5
5
5
5
5
5
10
5
5
10
5
0
0
U
u0
0
auD
uuuuu00
0
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1ug/1ug/1
GULF COAST LABORATORIES. INC.
2417 Bond St.. Unhrtrsity Park. Illinois 60466
Phorw* (312) 534-5200 (219) 885-7077 <815) Tt
ANALYTICAL REPORT
TO: MAECORP, IncorporatedPlain & Route 2Westville, IN 46391
ATTN: Mr. John Matlock
DATE: June 12, 1987
RE: Project «IN505 P.0.421848IN!MC-001 EffluentSample Date: 06/04/87Date Received: 06/10/87GCLtt 107402
[ VOLATILE COMPOUNDS ""'"'
1 , 2-Dichloropropane
Trans-1 , 3-Dichloropropene
Trichloroethene
Dibromochloromethane
1,1, 2-Trichloroethane
Benzene
cis-1 , 3-Dichloropropene
2 -Chloroethy Iviny lether
Bronoform
4-Methyl-2-Pentanone
2-Hexanone
Tetrachloroethene
1,1,2, 2-Tetrachloro«thane
Toluene
ChlorobenceneEthjrlbenBene
1 Stjrrene1 Total Xylenes
^RESULT ^
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
DETECTION LIMIT
5
5
5
5
5
5
5
10
5
10
10
5
5
5
55
515
U
U
0
0
U
U
0
0
0
0
0
U
0
0
0U
a0
ug/l
ug/l
ug/iu«/l
ug/lug/l
ug/lug/l
u«/lug/l
ug/lug/lug/l
ug/l
ug/lug/lug/lug/l
TO: MAECORP, IncorporatedPlain & Route 2Westville, IN 46391
ATTN: Mr. John Matlock
GULF COAST LABORATORIES. INC2417 Bond St.. University Park. Illinois 60466
Phoim 1312) 534-5200 (219) 885-7077 1815) 7!
A N A L Y T I C A L REPORT
DATE: June 12, 1987
RE: Project «IN505 P.O.»21848INMC-001 EffluentSample Date: 06/04/87Date Received: 06/10/87GCL* 107402
TENfAT
One (1) Volatile Compound greater than IPX of the nearest____
internal standard was tentatively identified by mass spectral
library search. This is exclusive of any priority pollutants.
surrogates or internal standards. __
COMPOUND ESTIMATED CONCENTRATION
Unknown 29 ug/1
GULF COAST LABORATORIES, INC
2417 Bond St., University Park, Illinois 60466
Phon« (312) 534-5200 1219)8857077 (815)
A N A L Y T I C A L R E P O R T
TO: MAECORP IncorporatedPlain 4 Rt. 2Westville IN 46391
ATTN: Mr. John Hatlock
DATB: 06/25/87
RB: ProJ* IN505 - PO* 21848IN5MC-002 EffluentSaaple Date: 06/05/87Date Received: 06/10/87GCL Number: 107403
GCL £ PARAMETERS (j bg^A^§^§wMMj§jpjpjH|§MSi|Kfln107403 Chroniun, Total" ; i^llf •»»£* "**
107403 Lead, Total
— 107403 Oil and Grease (Freon Extraction)
107403 PCBs, Total
107403 Aroclor 1016
107403 Aroclor 1221
107403 Aroclor 1242
107403 Aroclor 1248
- 107403 Aroclor 1254
107403 Aroclor 1260
107403 pH
107403 Phenols
107403 Solids, Total Suspended107403 Zinc, Total
t^^aAtaSm
nt
rsk
IsmIsn
IsnIsnleu
Isn
Isn
ks
efl
bt
Jh
^^^^M^^^M^^^^^juL^BU^jA.Oai^HUn^n^n^n^n^BlB^n^B^B^nflBBMniBMlN^B
0 . 062 ng/
< 5 ng/
< 0.001 ng/
< 0.001 ng/
< 0.001 ng/
< 0.001 ng,< 0.001 ma,< 0.001 ng,< 0.001 ng,
7.0
0.015 ng,
32 ng,0.015 me,
TO: MAECORP. IncorporatedPlain & Route 2Westville, IN 46391
ATTN: Mr. John Matlock
GULF COAST LABORATORIES. INC
2417 Bond St.. Univirtity Park. Illmou 60466
Phonw (312) 534-5200 (21918857077 (815t
ANALYTICAL REPORT
DATE: June 12, 1987
RE: Project 0IN505 P.O.*21848I1MC-002 EffluentSample Date: 06/05/87Date Received: 06/10/87GCLft 107403
VOLATILE COMPOUNDS - -*~~*fmmmm i UN ii.ui .J* • " SW*?**-1- ' >• ' • •-'
Chlorbnethane
Br omome thane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon Disulfide
1 , 1-Dichloroethene
"~ 1 , 1-Dichloroethane
Trans-1 , 2-Dichloroethene
Chloroform
1 , 2-Dichloroethane
2-Butanone
1,1, 1-Trichloroethane
Carbon TetrachlorideVinyl Acetate
BroaodichloroMthane
BDL
BDL
BDL
BDL
BDL
20
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
10
10
10
10
5
10
5
5
5
5
5
5
10
5
5
10
5
JIK
U
U
U
uuB
U
U
0
0
D
U
U
0
0
U
0
>n Iffi3 !(.'«:--'*i
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1ug/1
u«/J
ug/1
ug/1
ug/1
ug/1
ug/1ug/1ug/1Off/1
GUI-F COAST LA8OPATORIE > <iM :
2417 Bond St., University Park. l^n-o <
Phones (312) 534-5200 (219) C'3!S 7'"7 '8 IS) 723
ANALYTICAL Hf PO R '
.>RP, incorporatedPlai-, & Route 2West vi He. IN 46391
ATTN: Mr John latiock
DATE: June 12, J987
RE: Project »IN505 P.O. «:21848IN5C1-MC-002 EffluentSample Date: 06/05/87Date Received: 06/10/87GCL# 107403
1 , 2-D:i.ch.loropropane
Trans- 1 , J -Dichloropropene
Trichi oroethene
Da bron ochioromethane
1,1,2- Trichloroethane
Benzene
cis - L , 3 -Dichloropropene
2 -Cn icroathylvinylether
Bromof orm
4 -Meth/l-2-Pentanone
2-Hexaxione
Tetrachl oroethene
1, .1,2, :i-T«-tr«chloroethane
Toluene
Chiorobenzene
Sthylbeineene
3tyren«
Total Xylenes
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
5
5
5
5
5
5
5
10
5
10
10
5
5
5
6
5
5
15
U
U
uuuu0
nuuuuuu0
u0
u
ug/1
Ug/J
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
u«/lug/1
TO" MAKCorcP, IncorporatedPlain 4 Route 2Westvi He. IN 46391
ATiN Mr. John Matlock
A N A L Y T I C A L R ~ P0 R T
DATE: June 12, 1987
RE: Project «IN505 P.0.021848IN505MC-002 EffluentSample Date: 06/05/87Date R«ceived: 06/10/87GCL* 107403
TENTATJ
Two (2) Volatile Compounds greater than IPX of the nearest
internal standard were tentatively identified by mass spectral
library search. This is exclusive of any priority pollutants,
surrogates or internal standards.
COMPOUND ESTIMATED CONCENTRATION
Unknown CzHe 0 140 ug/1
Unknown 37 ug/1
GULF COAST LABORATORIES, INC
2417 Bond St.. University Pirk. Illinois 60466
Phones (312) 534-5200 (219) 885-7077 (815) 72
ANALYTICAL REPORT
TO: MAECORP IncorporatedPlain 4 Rt. 2Westville IN 46391
ATTN: Mr. Greg
DATE: 06/25/87
RE: ProJ* 1N505 - PO* 21848IN50MC-003 EffluentSample Date: 06/06/87Date Received: 06/10/87GCL Nunber: 107404
GCL « PARAMETERS
107404 ChroBiUB, Total107404 Lead, Total
107404 Oil and Grease (Freon Extraction)
~~1 07404 PCBe, Total
107404 Aroclor 1016
107404 Aroclor 1221
107404 Aroclor 1242
107404 Aroclor 1248
107404 Aroclor 1254
- 107404 Aroclor 1260
107404 pH
107404 Phenols
107404 Sol Us, Total Suspended107404 Zinc, "otal
ANALYST
nt
rsk <
ISB <
Ism <
ISB <
ISB <
ISB <ISB <ISB <
kseflbtJh
RESULTS
, 0.020 ,
0.062
5
0.001
0.001
0.001
0.001
0.001
0.001
0.001
7.0
0.010
16
0.023
Bg/1
Bg/1
Bg/1
Bg/]
Bg/]
Bg/]
Bg/]
Bg/]
Bg/]•ur/:
Bg/:Bg/:Bg/:
/ COAST mmit ^wS|»*%JVwSSKHMMMfl
^^^^^^^^^^^^^^^^^^^^^^^^^^^j^^^^t^^^^^BBB^^^BBii ^^^BB^^WH^^^WBi ^^^^^^^^BP^^^Hi
TO: MAECORP, IncorporatedPlain &. Route 2West'-ille, IN 46391
ATTN Mr John Mat lock
•r" " 'VOLATILE
Chloromethane
Brornomethane
— Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon Diaulfide
1 , 1 -Dichloroethene
1 , 1-Dlehloroethane
Trans-1 , 2 -Dichloroethene
Chloroform
1 , 2-Dichloro«thane
2-Butanone
1,1, 1-Trichloroethane
Carbon Tetrachloride
Vinyl Acetate
Broaodichloronethane
/•» 1 ,' DOrM! •ji , u n i V B i ' i u y r 4 u « , nt ini i <»"ta-°
Phorm (312! 534-5200 (219> 885-707 ' 1815)723753:
^ ^ A N A L Y T I C A L R E P O R T
|M1 '
DATE: June 12, 1987
RE: Project «IN505 P . O . «»21848IN505MC-003 EffluentSample Date: 06/06/87Date Received: 06/10/87GCL» 107404
s- ;-" -•""•"-••'' 'BDL:' "" "•" "' ! •" > ; "io'I-!ov"ug/i""
BDL
BDL
BDL
BDL
65
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
10 U ug/l
10 U ug/l
10 U ug/l
5 U ug/l
10 B ug/l
5 U ug/l
5 U ug/l
S U ug/l
5 U ug/l
5 U ug/l
5 U ug/l
10 U ug/l
5 U ug/l
5 0 ug/l
10 U ug/l
5 U ug/l
GULF COAST LABORATORIES. INC.
2417 Bond St.. University Purk, Illinois 60466
Phon« (312) 534-5200 (219)8857077 (815)
ANALYTICAL REPORT
TO: MAECORP, IncorporatedPlain & Route 2Westville, IN 46391
ATTN: Mr. John Matlock
DATE: June 12, 1987
RE: Project 3IN505 P.O.*21848IMC-003 EffluentSample Date: OS/06/87Date Received: 06/10/87GCL* 107404
VOLATILE CUHFUUNUttfftiiilHI HH'\JJ'lil|plul^
1 , 2-Dichloropropane
Trans-1 , 3-Dichloropropene
Trichloroethene
Dibromochloromethane
1,1, 2-Trichloroethane
Benzene
cia-1 , 3-Dichloroprop«ne
2 -Chloroe thy Iviny lether
Bromoform
4 -Methyl - 2 -Pentanone
2-Hexanone
Tetrachloroethene
1,1,2, 2-Tetrachloroethan«
Toluene
Chlorobenzen*
Bthylbenzene
StrrmMTotal Xylenes
E9 ^ EKC22S8EII IIEi
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
5
5
5
5
5
5
5
10
5
10
10
5
5
5
5
5
5
15
U
U
uuuu0
0
0
u0
u0
u0
uuu
'•••• H" wipm **ug/iug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
•H/lug/l
ug/lug/l
TO: MAECORP, IncorporatedPlain & Route 2Westville, IN 46391
ATTN: Mr. John Matlock
GULF COAST LABORATORIES, INC.
2417 Bond St.. University Park. Illinois 60466
Phonti (312) 534-S200 (219) 885-7077 (815) 7
A N A L Y T I C A L R E P O R T
DATE: June 12, 1987
RE: Project «IN505 P.O. J»21848IbMC-003 EffluentSample Date: 06/06/87Date Received: 06/10/87GCL* 107404
TENTATIVELY IDENTIFIED COMPOUNDS
Three (3) Volatile Compounds greater than 10» of the nearest
internal standard were tentatively identified by mass spectral
library search. This is exclusive of any priority pollutants,
surrogates or internal standards. _____________
COMPOUND ESTIMATED CONCENTRATION
Unknown 70 ug/1
Unknown CaH«0 170 ug/1
Unknown 5 ug/1
OAST*0' IIMUIWSIIC
GULF COAST LABORATORIES. INC.2417 Bond St.. Uimtnity Perk, Illinoil 60466
(312) W4-S200 {219)885-7077 (815)72
A N A L Y T I C A L R E P O R T
TO: MAKCORP IncorporatedPlain 4 St. 2VHetville IN 46391
ATTN: Mr. John Matlock
DATE: 06/25/87
RE: Proj* IN505 - P0» 21848IN50HC-004 EffluentSaaple Date: 06/07/87Date Received: 06/10/87GCL NuBber: 107405
CCL * PARAMETERS ANALYST RESULTS
1 -107405 ChroBiu., Total *i ^
107405 Lead, Total
107405 Oil and Grease (Freon Extraction)107405 PCBs, Total
107405 Aroclor 1016
107405 Aroclor 1221
107405 Aroclor 1242
107405 Aroclor 1248
107405 Aroclor 1254
107405 Aroclor 1260
107405 pH
107405 Phenols107405 Solids, JFotal Suspended107405 Zinc, Total
nt
r*k
IsmISB
ISBISBISBISBISB
kseflbtel
< 0.05 BC/]
< 5 Bg/]
< o.ooi BC/:< o.ooi BC/:< o.ooi Bg/:< o.ooi BC/:< 0.001 BC/
< 0.001 BC/
< 0.001 BC/
6.2
0.023 BC/
12 BC/
0.251 BC/
GULF COAST LABOKATORIES. INC.
2417 Bond St.. University Park. Illinois 60466
PhonM (312) 534-5200 (219) 885-7077 (815) 723-7
ANALYTICAL REPORT
TO: MAECORI, IncorporatedPlain & Route 2Westville, IN 46391
ATTN: Mr. John Matlock
DATE: June 12, 1967
RE: Project «IN505 P.O.*21848IN50MC-004 EffluentSample Date: 06/07/87Date Received: 06/10/87GCL* 107405
VOLATILE COMPOUNDS
i -• Chloromethane. •'•* ":;';': ?; • ""•••ffliPI
1 Bromome thane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
_ Carbon Disulflde
1 , 1-Dichloroethene
1 , 1-Dichloroethane
Trans-1 , 2-Dichloroethene
Chloroform
1 , 2-Dichloroethane
2-Butanone
1,1, 1-Trichloroethane
Carbon Tetrachloride1 Vinyl Acetate
I' Broaodiohlorooethan*
RESULT
PWWPpjf|JfJ ?™w™PW?
BDL
BDL
BDL
BDL
110
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
DETEC
10
10
10
5
50
5
5
5
5
5
5
10
5
5
10
5
3Ti<• P**ff
U
U
U
U
B
U
U
U
U
0
U
U
U
0
u0
)N LIMIT^ ••VSMHHMHIHH HMMMI
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
uc/1
,
TO: MAECORP, IncorporatedPlain 4 Route 2Westville, IN 46391
ATTN: Mr. John Mat lock
GULF COAST LABORATORIES, INC.
2417 Bond St., Univ«nity Park, Illlnoit 60466Phonw (312) S34-S200 (219)885-7077 (815)72:
ANALYTICAL REPORT
DATE: June 12, 1987
RE: Project «IN505 P.O.«21848INEMC-004 EffluentSample Date' OC/07/87Date Received: 06/10/87GCL* 107405
VOLATILE COMPOUNDS
1 , 2-Dichloropropane
Trans-1 , 3-Dichloropropene
Trichloroethene
Dibromochloromethane
1,1, 2-Trichloroethane
Benzene
— cis-1 , 3-Dichloropropene
2-Chloroethylvinylether
Bromof orm
^_ 4-Methyl-2-Pentanone
2-Hexanone
Tetrachloroethene
1,1,2, 2-Tetrachloroethane
Toluene
Chlorobensene
Ethjrlbeneene8tjrr«a«Total Xylenes
RESULT
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
DETECTION LIMIT
5
5
5
5
5
5
5
10
5
10
10
5
5
5
5
5
5
15
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
D
U
0
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1ug/1ug/1
.
/GULF/COASTftu«uims.iK
GULF COAST LABORATORIES. INC
2417 Bond St., Umvertiry Park, Illinoit 60466
Phonet (312) 534-5200 (219)8857077 (815)7
ANALYTICAL REPORT
TO: MAECORP, IncorporatedPlain & Route 2Westville, IN 46391
ATTN: Mr. John Matlock
DATE: June 12, 1987
RE: Project «IN505 P.O. #21848I1>MC-004 EffluentSample Date: 06/07/87Date Received: 06/10/87GCL* 107405
TENTATIVELY IDENTIFIED COMPOUNDS
Four (4) Volatile Compounds greater than IPX of the nearest
internal standard were tentatively identified by mass spectral
library search. This is exclusive of any priority pollutants,
surrogates or internal standards,
COMPOUND ESTIMATED CONCENTRATION
— Unknown 22 ug/1
Acetaldehyde 35 ug/1
Unknown CzHeO 160 ug/1
2-Propanol 150 ug/1
QULF COAST LABORATORIES. INC.
2417 Bond St.. Univtrtity Park, Illinois 60466
Phoim (312) 534-5200 (219)885-7077 (815)7
ANALYTICAL R E P O R T
TO: MAECORP IncorporatedPlain a Rt. 2Westville IN 46391
ATTN: Mr. John Matlock
DATE: 06/25/87
RB: Projft IN505 - PO* 21848IN5'MC-006 EffluentSample Date: 06/09/87Date Received: 06/10/87GCL Nuaber: 107406
GCL « PARABBtnt9ip|MHiJ^BHMOTi107406 ChroBluB, Total
107406 Lead, Total
107406 Oil and Grease (Freon Extraction)107406 PCBe, Total
107406 Aroclor 1016
—107406 Aroclor 1221107406 Aroclor 1242
107406 Aroclor 1248
^ 107406 Aroclor 1254
107406 Aroclor 1260
107406 pH
107406 Phenols
107406 Solids, Total Suspended107406 Zino, Total
JKL
el
ntrskIsm
IBB
lSB
ISB
IBBlSB
IBBkseflbtel
•PPIj-SP;?": v-.;-r^.- ".T - : •• ' • '!«JBJ< o . 020
0.05
< 5
< 0.001
< 0.001
< 0.001
< 0.001
< 0.001
< 0.001
< 0.001
6.7
0.016
25
0.098
•f ' ' '' ••g/
Bg/
Bg/
Bg/
Bg/
BftV
•g/
Bg/
Bg/
Bg/
Bg/
Bg/
Bg/
COAST'IUM1WK.K
GULF COAST LABORATORIES. INC.
2417 Bond St.. University P«rk, Illinois 60466Phoiwt (312) b34-8200 (219) 885-7077 (815) 72
ANALYTICAL REPORT
TO: MAECORP, IncorporatedPlain & Route 2Westville, IN 46391
ATTN: Mr. John Matlock
DATE: June 12, 1987
RE: Project *IN505 P.O.*21848IN!MC-006 EffluentSample Date: 06/09/87Date Received: 06/10/87GCL* 107406
VOLATILE COMPOUNDS
Chloromethane
Bromorae thane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon Disulfide
1 , 1-Dichloroethene
1 , 1-Dichloroethane
Trans-1 , 2-Dichloroethene
Chloroform
1 , 2-Dichloroethane
2-Butanone
1,1, 1-Trichloroethane
Carbon Tetrachloride
Vinyl Acetate
BroaodiohloroMthane
RESULT
BDL
BDL
BDL
BDL
BDL
1500
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
DETECTION LIMIT
10
10
10
10
5
200
5
5
5
5
5
5
10
5
5
10
5
0
U
uU
uB
U
U
U
o0
D
D
U
0
0
0
ug/iug/l
ug/iug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/lug/l
ug/l
ug/log/1
GULF COAST LABORATORIES. INC
2417 Bond St.. Unlvirnty Park. Illinois 60466
(312) 534-6200 (219) 885 7(T7 (815) 7
ANALYTICAL REPORT
TO: MAECORP, IncorporatedPlain & Route 2Westville, IN 46391
ATTN: Mr. John Matlock
DATE: June 12, 1987
RE: Project *IN505 P.O.1*218481*MC-006 EffluentSample Date: 06/09/87Date Received: 06/10/87GCLft 107406
VOLATILE COMPOUNDS
1,2-Dichloropropane
Trans-1 , 3-Dichloropropene
Trichloroethene
Dibromochloromethane
1,1, 2-Trichloroethane
Benzene
cis-1 , 3-Dichloropropene
2-Chloroethylvinylether
Bromoform
4-Methyl-2-Pentanone
2~Hexanone
Tetrachloroethene
1.1,2. 2-Tetraohloroethane
TolueneChlorobenzeneIthylbenceneStjrreneTotal Xjrlenes
RESULT
BDL'BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
DETECTION LIMIT
5
5
5
5
5
5
5
10
5
10
10
5
5
5
65
6
15
•3ff
U
uuu0
uD
U
U
0
0
uuu000
u
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1ug/1ug/1ug/1
ug/1ug/1ug/1ug/1
TO: MAECORP, IncorporatedPlain & Route 2Westville, IN 46391
ATTN: Mr. John Matlock
GULF COAST LABORATORIES. INC
2417 Bond St., Unlvtnity Park, Illinois 60466Phoow 1312) 534-5200 (219)885-7077 (815)7;
ANALYTICAL REPORT
DATE: June 12, 1987RE: Project UIN505 P.O.tt21848IN
MC-006 EffluentSample Date: 06/09/87Date Received: 06/10/87QCL* 107406
TENTATIVELY IDENTIFIED COMPOUNDS
Five (5) Volatile Compounds greater than 10% of the nearest
internal standard were tentatively identified by mass spectral
library search. This is exclusive of any priority pollutants,
surrogates or internal standards,
— COMPOUND
Unknown
Unknown CaH«0
2-Propanol
1 -Propanol
Unknown
ESTIMATED CONCENTRATION
34
130
190
8
5
ug/1
Uf/1
ug/1
u«/lug/1
GULF COAST LABORATORIES. INC.
2417 Bond St., Unlvtriity P«rk, Illinoil 60466Phonw (312) 834-5200 (219)885/077 (815)
A N A L Y T I C A L R E P O R T
TO: MAECORP IncorporatedPlain & Rt. 2Westville IN 46391
ATTN: Mr. John Matlock
DATB: 06/25/87
RB: ProJ* IN505 - PO* 21848IN!MC-007 EffluentSanple Date: 06/10/87Date Received: 06/10/87GCL NuBber: 107407
GCL « PARAMETERS
-' 107407 Chrcaiua, Total
107407 Lead, Total
107407 Oil and Grease (Freon Extraction)107407 PCBs, Total
107407 Aroclor 1016
107407 Aroclor 1221
107407 Aroclor 1242
107407 Aroclor 1248
107407 Aroclor 1254
107407 Aroclor 1260
107407 pB
107407 Phenols
107407 Solids. Total Suspended107407 Zinc. Total
ANALYST
el
nt
rskIBBlaslea
Is*
ISBISB
lam
ks
efl
btel
RESULTS
< 0.020
0.075
< 5
< 0.001
< 0.001
< 0.001
< 0.001
< 0.001
< 0.001
< 0.001
8.7
0.022
24
0.031
•cBCBB sT
£m »
M
BC
•C
Bg-•fl
•I
•i•1•1
OULF COAST LABORATORIES. INC
2417 Bond St., Univtrtity Park, Illinoit 60466(312) B34-B200 (219)6857077 (8151
ANALYTICAL REPORT
TO: MAECORP, IncorporatedPlain & Route 2Westville, IN 48391
ATTN: Mr. John Matlock
DATE: June 12, 1987
RE: Project *IN505 P.O.*21848IMC-007 EffluentSample Date: 06/10/87Date Received: 08/10/87GCL« 107407
VOLATILE COMPOUNDS
-" Chloromethane
Bromomethane
Vinyl Chloride
— Chloroethane
Methylene Chloride
Acetone
Carbon Disulfide
1 , 1-Dichloroethene
1 , 1-Di chloroethane
Trans-1 , 2-Dichloroethene
Chloroform
1 , 2-Dichloroethane
2-Butanone
1.1,1 -Trichloroethane
Carbon Tetrachloride
Vinyl AcetateBromodiohloromethane
RESULT
BDL
BDL
BDL
BDL
BDL
2400
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
, , i/J»lJbl
10
10
10
10
5
500
5
5
5
5
5
5
10
5
510
5
U
U
0
U
0
B
U
U
U
U
U
U
0
U
0
U
U
Ml LJJJUT
ug/1
ug/1
ug/1
ug/1
Ug/1
ug/1
ug/1
ug/1ug/1
ug/1
ug,"ug/1
ug/1
ug/1
ug/1ug/1ug/1
GULF COAST LABORATORIES. INC
2417 Bond St., Umvtrtity Park, Illinois 60466
Phontt (3121 534-6200 (219)8857077 (815)7
ANALYTICAL REPORT
TO: MAECORP, IncorporatedPlain & Route 2Westville, TN 46391
ATTN: Mr. John Mat lock
DATE: June 12, 1987
RE: Project HIN505 P.O. *21848IhMC-007 EffluentSample Date: 06/10/87Date Received: 06/10/87GCL* 107407
—•
VOLATILE COMPOUNDS
1 , 2-Dichloropropane
Trans-1 , 3-Dichloropropene
Trichloroethene
Dibromochloromethane
1,1, 2-Trichloroethane
Benzene
cia-1 , 3-Dichloropropene
2-Chloroethylvinylether
Bronoform
4-Metnyl-2-Pentanone
2-HexanoneTetrachloroethene
1,1,2, 2-Tetrachlorowthane
TolueneChlorobensene
Ethylbentene
StrreneTotal Xylenea
RESULT
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
DETECTION LIMIT
5
5
5
5
5
5
5
10
510
10
5
5
5
5
5
515
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0
0
UU
uc/1
uc/1
uc/iuc/1
uc/1
uc/1
UC/1
uc/1
uc/1
uc/1
uc/1
uc/1
uc/1
UC/1
uc/1
UC/1
uc/1uc/1
/GULF'COASTIIMU1MIK'
OULF COAST LABORATORIES. INC
2417 Bond St., Unlvtriity Pirk. Illinois 60466
Phoiw* (312) 534-6200 121918857077 1815)
A N A L Y T I C A L R E P O R T
TO: MAECORP, IncorporatedPlain & Route 2Westville, IN 46391
ATTN: Mr. John Matlock
DATE: June 12, 1987
RE: Project 0IN505 P.O.H21848IMC-007 EffluentSample Date: 06/10/87Date Received: 06/10/87GCL« 107407
Six (6) Volatile Compounds greater than 10% of the nearest
internal standard were tentatively identified by mase spectral
library search. This is exclusive of any priority pollutants.
surrogates or internal standards.
COMPOUND ESTIMATED CONCENTRATION
Unknown 45 ug/1
Ethanol 78 ug/1
2-Propanol 170
1-Propanol 9
Unknown 12 ug/1
Unknown 14 ug/1
MVIR-" -HOT Oof Enfofctmtnt
CY
( I - (CHAIN OF CUSTODY RECORD
RMtived for Laboratory by Oat. /Tim. R«narki
VI HI IOTI )NA
CHAIN OF CUSTODY RECORDPROJ.NO. PROJECT NAME
STATION LOCATION
NO
OF
CONTAINERS
REMARKS
ll
(I
II I/M
inquisncd by: (S*n»tur»l
Ranivcd for Laboratory by
of £nfo<c*<rtntCHAIN OF CUSTODY MtCOHD
PROJ. NO. PROJECT NAME
SAMPLERS: I.
STA.NO OATf TIMI
NO
OF
CONTAINERS
STATION LOCATION
REMARKS
flt-ttf
y.y-aqr-
Data/Tim* Rtcahwd by D«U/Tlm« R*ctiv«d by:
Date/Tint* Ractivtd by: (S&tturtl -Rtlinquilh«d by 0«U / Tim«
0m/Tinw Rwvivcd for Labor*tory by: Oat*/Tima iRtmarks
of EnfiforcemmtCHAIN OF CUSTODY RECORD Chtcogo.
PROJ. NO. PROJECT NAME
SAMPLERS:
STA.NO DATE TIM* STATION LOCATION
NO
OF
CON-TAINERS
REMARKS \
I- /JCl-IJl
Received for Laboratory byRelinojuwhedoy
/GULF'COAST
JflCTCT
GULF COAST LABORATORIES. INC
2417 Bond St., Univenity Park, Illmon 60466
Phon«» (3121 5345200 (219)8857077 (81
The following is a list of flags that Gulf Coast Laboratoriesfrequently uses on our anljrtical reports. All flags may notbe applicable for the enclosed reports.
B - Indicates the compound was found in the blank as well asthe sample, it indicates possible/probable blank contamin-ation and warns the data user to take appropriate action.
E - Severe matrix interference
D - Result is on a dry weight basis
J - Indicates an estimated value which is below detection limit
F, PCBs appear to be present; but are below detection limit
ND - Not detected above detection limit
P PoaKn present but do not appear to be PCBs
U Indicates compound was analyed for but not detected
R - Spike recovery not within control limit
W - Result is on an "as is basis" (wet weight)
* - Duplicate not within control limits
+ - Correlation coefficient for MSA < 0.995
BDL - Below Detection Limit
WATER SURROGATE PERCENT RECOVERY SUMMARY( r-a-c
ntnif)
nSRc
RlANUc
07*105 msOUCQIkOfm^o.loiMoHfolds'\j 1 i^/^t^I N™^ 4f^\ f
\mio5fOT^Ofeoi«toi
"""7Q^l
^JO(OfiqqJOO(01<*<*
mafOfttooqq
IM-tltt
qqrtOqq
0^IOG100nn[100q$t101ipiqq
ir*-it«t
< (j
C gc ^< 7
^H969!c c< 7<: fjq?
•
IM'**«I
UitTtt» Kit
CM-VOCATN.E _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
~*lit- •*«
— - - -
!>• n»
[«ST:CtC€
.»,..**'C« 0*1 •»••!
11* '< • '
• VALUES ARE OUTSIDE OF CONTRACT REQUIRED OC LIMITS Volatitoi O — out of 36 t outsirf* of OC l^ts**AOV80RY LIMITS ONLY Swui-VotttHtw ———— out of ———— ; outsit of OC l™ts
Ptstkidtst ____ out of ___ _ ; outside of OC limits
WATER MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY
PRACnOM
VGASMO
SAMPLE NO./07V6&
•mSMO
IAMPLCNO.
ACIOSMO
SAMPLE NO.
PESTSMO
SAMPLE NO.
COMPOUND
i.t ni[tii»imii«iTtlrfiteiujitujuO*iOfOb*»«it>nTo4tM*«
tfnnn*l.7.« Tnch>otoB«ni«««Acentafcthtnt2.4 Ointt'oiolwwio•k___^__
1 AOicMorobwtnnoP«nUchlorop*MnotPi nol
~?l ?-Ss»=rl*£T™* ——HtotichlorAktrinOwldfinEnorin4.4'4)OT
CONC VIKEAOOEO f«*/LI
5Og-/1^7SOS<2
SAMPLERESULT
—
-
OONCMS
HiV5"•Vt*J(^^
RfCf^ii<!/
P«l§•*s
v5
°ssV3Vo
Ui?5O
RCC
ft&10yc1
i]
}J2^^
RPO
V5"t
f-t
c.^
^-
AST! RISKED VALUES ARE OUTStOf OC UNITS.
RPO: VOA*_Q_*wtof_j^L cutt-to OC Nmin RECOVERY: VOA»___L•/N ____ owl of ___ owtiitft OC NMitt 1/N ———ACIO ———— »ui of ——— ounMo OC Kmiit ACIO ——PEST _____ owl of - ownidi OC limit* ' PCST —— •
1 ft
1414lj13tl213131313121W.424042N»*2022It2127
fc | iMtT^'PlECOvEHV
ai-i4ft71-1207S.130
74.17739994C-1 tl24 1429-12741.114
_JH*'*'t-10312-M27-12323t7
M-12340-13140-12057 17844 12131-127
owtof_Z-^: o«m<d» OC litnin
9^f of —— r owMnJt OC Ihwindft Of ___• OUllid* QC liWill
. rw\ e =
At
It;,
V.
-JASJL
B y . D»t*
VCLATJUCORPOUMSConcent'ition: (Tow) Nediui (Circle Oil)
Bite E«tricted/Prepired!
Dite Analyzed!
Cone/Dilution Futon pH
Ptrcent Noiiturti (Not Decintrd)
ttfrcli OnH
74-87-3
74-83-9
73-01-*
75-00-3
73-00-2
67-64-1
73-13-0
73-33-4
73-34-3
136-60-5
&7-U-3
107-06-2
78-93-3
71-53-4
34-23-3
108-03-4
73-27-4
1
CMorotethint
BroioMthtni
Vinyl Chloridl
Chloro»thini
Htthvlene Chlorldt
Acetone
Cirbon OiwHidi
1.1-DichlorotthMf
1.1-Dichlorofthini
Trini-1 .2-OicMorotthtne
Chlorofori
!.:-DirMorotthiM
2-lutmone
1.1.1-Trlchlor ottline
Cirlon Tetrichlorlde
Vinvl (kttiti
IrowUlehlareMtliiM1 .-.r4g! TiWiK
< 10
< 10
( 10
< 10
<s<IO
< 3
i^tlllAS
< 3
( 5
< 5
' 5
< 10
< 5
< 3
< 10
< 9!!
CAS I (Circtt Of
78-87-5
10061-02-6
77-01-6
124-48-1
79-00-3
71-43-2
10041-01-5
110-73-8
73-25-2
391-78-4
108-10-1
127-18-4
79-34-3
108-88-3
108-90-7
100-41-4
100-42-5
1.2-DicMofODrooine
Trim 1.3-Dichloroproptni
Trichlorotthtni
DibroiochloroKthini
1.1.2-Trichloroethinc
Btrutni
cli-1.3-OichloroorMini
2-CMoroithvlvinvlcthir
IroNfori
4-d«th¥l-2-Pfntinon»
2-timnont
Titrichlorocthtne
1 . 1 .2.2.-Tttrtchlof otthtni
Tolitni
CklorobMtMi
EthvlbMtmt
ItvrtMI1 Tttll ItlMH
< 5
< 3
c^sVS
< 3
< 3
cxun< {< 10
( 3
< 10
< 10
< 3
< 3
txs«te,<xs-W4
< s< s< IS
QUANT REPORT
Operator ID: USER2Output File: ~MCP02::D3Data File: >MCP02::L2Name: MAECORP 107402MSMisc: 5mL SAMPLE » 5uL ISS1122
Quant Rev: 6 Quant Time:In jected at:
Dilution Factor:
670610 16:870610 15
1.001
lOuL MS*086
ID File: IO_UDS::U1Title: ID FILE FOR DAILY UOLATILE STANDARDLast Calibration: 870610 14:58
Compound R.T. Scant Area Cone Uni
1)9)
14)15)23)25)30)35)36)39)40)
• BROMOCHLOROMETHANE1,1-OICHLOROETHENETRAMS • t-r2-OlCHLOROETH£NE1 , 2 - D I CHLOROETHANE- 04• 1 , 4-0 I FLUOROBENZENETRICHLOROETHENEBENZENE
« CHLOROBENZENE- 05TOLUENECHLOROBENZENEBROMOFLUOROBENZENETOLUENE- 08
9.959.54
______ 9 .54 —SSS 12.72
20.2717.1917.6925.1224.0925.23
SSS 29.55SSS 23.94
220209
293492411424620593623737589
1811115024
416347778627002641627084275437561485804293382
50.00 PPB40.62 PPB
— 35.31 PPO,48.02 PPB*?50.00 PPB45.03 PPB47/74 PPB50.00 PPB45.94 PPB45.62 PPB.49.69 PPB"50.27 PPBK
* Compound is ISTO
W'••ii
r
TOTflL ION CHROnBTOQRPnF i l m >rCPOZ 40.0-360.0 *»u. HHtCDRP
TIC0*L SflnPLt + 5uL IS!
600 800
8
' A ' « 16 f^t4 ^?i ^TT T 6^
Data File: >MCP02::L2Name: MAECORP 107402MSMisc: 5mL SAMPLE * 5uL 155*122
Quant Output Filet AMCP02::D3
' lOuL MS*086
Id F i l e s ID_UOSs:U1Title: ID FILE FOR DAILY UOLATILE STANDARDLaat Calibration: 870610 14:58
Operator ID: USER2Quant Time: 870610 16:30Injected at: 870610 19:91
j i i:'. t_»,_»
6ut".c'i:»S By. Rccti«t:.
COS I
Htditm (Circli Ont)
Dltt Eitrictid/Prtpiritf!
Citt Anilyzed!
Cone/Dilution Fictori oH
Itoiiturii (Not Otcintid).
(Ctrclt Ont)
74-87-3
74-83-9
73-01-4
73-00-3
75-09-2
67-64-1
73-13-0
73-33-4
73-34-3
136-60-3
47-44-3
107-06-2
78-93-3
71-33-4
1 34-23-3JI 1M-M-41! 79-27-4t1
CMoroftthiM
BrOMMthiM
Vinvl CMorldt
CMOTNthAM
Ntthylnt CDlBridf
Acitont
Cirkan Mnlfite
Ul-DUklorottlnnt
1.1-OichlarMtliMt
Trini-1 .2-BldlarNthtnf
Cklorofiri
!.2-tlcllvartluM
2-Butinont
1.1.1-TrlclilarHthifii
CvkM Titradlaritft
«Ml fcftltl
•"- IrllBTBMBIt
I'-iSiSi
< 10
< 10
< 10
( 10
<s<IO
( 3
<^43fl6
< s< 3
< 3
< 3
< 10
< 9
< 3!! < 1011 < S11
CftS I (Cirel
78-B7-3
10061-02-6
7?-Ol-6
124-4B-1
79-00-3
71-43-2
10M1-01-3
11 0-73 -fl
73-23-2
391-78-6
108-10-1
127-IB-4
79-34-3
1M-BI-3
10MO-7
10»-41-4
100-42-3
1,2-BicMoroorooini
Trim 1.3-DicMoroDrootM
TficMorotthini
DibroMChloroMthini
1.1.2-Trichlorottliini
Bmiini
el i-l .3-Di chl or ooroiMt
2-Chl or Mthy 1 vi n ylithfr
Irotofori
4-fltthvl-2-Pint«nont
2-MllMMI
Tftrj'hioroithtni
1 • 1 .2.2.-Tttrichlorotth«ni
TalMM
CklorobmiffM
EthvHtRimt
Ittrnt
Tttll IflMM
< 3
< 5
M'
' 3< 3
i^
< 9/
< 10
( 3
< 10
< 10
< 3< s
! 4-3tJ t*^!> < S11 < 911 < 19
QUANT REPORT
Operator ID:Output File:Data File:
USER2~MCP03:iD3>MCP03::L2
Quant Rev/: 6 Quant Time:Injected at:
Dilution Factor:
870610 17::870610 16:'
1.0001Name: MAECORP 107402MSDnisc: 5mL SAMPLE * 5uL ISS1122 * lOuL MS*086
ID File: ID_UDS::U1Title: ID FILE FOR DAILY VOLATILE STANDARDLast Calibration: 870610 14:58
Compound R.T. Scant Area Cone Unit
1)9)
14)15)23)25)70)35)36)39)40)
• BROMOCHLOROMETHANE1,1-DICHLOROETHENETRAMS 1,2 D1CHLOPOETHEHE1 , 2 - D I CHLOROETHANE- D4
• 1 , 4-D I FLUOROBENZENETRICHLOROETHENEBENZENE•CHLOROBENZENE-D5TOLUENECHLOROBENZENEBROMOFLUOROBENZENETOLUENE-08
9.919.49
SSS 12.6720.2217.1817.6825.0724.0825.18
SSS 29.54SSS 23.89
219208206 —292491411424619593622737588
1771915711
412707751827761671606984680015587685729790926
50.00 PPB43.42 PPB
— ??i74 PPB —48.65 PPB l50.00 PPB46.45 PPB50.14 PPB50.00 PPB49.42 PPB48.43 PPB49.75 PPB™49.65 PPB
* Compound is ISTD
^
TOTRL ION CHROtlflTOeHPMFll« >HCP03 40.0-860.0 wiu. flflECORP 10740EF18D O«L BHP1PLE * ButT
goo 400 too
Quant Output File: ""Data F i l e : >MCP03::L2Name: MAECORP 107402MSDMisc: 5mL SAMPLE * 5uL ISS*122 * lOuL MS*086
Id File: IDJJDS::U1T i t l e : ID FILE FOR DAILY VOLATILE STANDARDLast Calibration: 870610 14:98
Operator ID: USER2Quant Times 870610 17:19Injected at: 870610 16:40
METHOD BLANK SUMMARY
.ftogton. Contractor ^ jf Cccc:(
flff . J L - I .
loc £H /oI.I.J TricH/oro 1, i,i -Jr. (lucre PC
7/05
D*t* Dtti
VOIAJ1LLCOWCMSConctntritiont CLo (Circl/ Out)
CAS 1
•rt.i.ip*, f,-/n-<nCone/Dilution Futart , oH
tarrnt Naitturtt (Not tecitttd) . . ...
itirclt On»l CAS 1(]j9/j)of q^"TOrcli 0
7«-87-3
74-83-9
75-01-4
73-00-3
75-09-2
67-64-1
73-13-0
73-33-4
73-34-3
136-60-3
67-U-3
JC7-06-2I! 78-93-3!1 71-33-6I1 36-23-91! 108-03-41! 73-27-41I
CMoroMtdini
BrotONthtni
Vinvl Chloridt
CMorotthtni
Ntthvleni Chloridt
Acitont
Cirlon Diulflto
Ll-DicMorottktM
1.1-Dichlorotthint
Trini-1 •2-Dlcfelorotthmi
CMorotori
1.2-DleklaraitliMt
2-luttnont
1.1.1-TriehlarattlHi
Cirkoo TitracMorll*
VlMvl Acttiti1
! ~Jt?
( 10
< 10
( 10
< 10
<s,33
( 3
< 3
< 3
< 3
1 < 3»1 < 3I: < 10!: < s!! < 3! 1I ( 10 11 1! < 3 !11
178-87-3 1
10061-02-6
79-01-4
124-48-1
79-00-3
71-43-2
10M1-01-3
110-73-1
73-23-2
391-78-6
108-10-1
12MB-4
79-34-3
1M-M-3
10i-9«-7
100-41-4
100-42-3
1.2-Dichloroorofint
Trim 1.3-Dichloroprooint
TrlehlorottliMf
DibroMChloroMthint
1.1.2-Triehloro»thMt
Bmztnc
cli-1.3-Dlchloro>roMM
2-ChlariwthylvlivUthtr
BroMfori
4-Mthvl-2-fMtuion*
2-Mntnoni
Tttriehlo"»t»>*«»tI 1.1.2.2.-TttncMoritthiM11 Toltnt\1 CHorobmttM1! EtflVlhMIMt1! ItvriM11 Titil IvlMM
< 3
< 3
( 3
< 3
< 3
< 3
< 3<
< 10
( 3
< 10
< 10
< 3
< S
< 3
< S
( S11 < S1! t «
C«f
Ccxibt
Orgonkt Analysis Doto Shoot
Tonlotfvoly MoiitHiod Compound*
10..
IS..
20.
1/C4Win.13.31?
QUANT REPORT
Quant Rav: 6Iperator ID: USER2Output Fi le: AMA610::D3">ata File: >MA610: : L2
METHOD BLANK5mL OFU) + 5uL ISS#122
ID File: ID_UDS::U1Title: ID FILE FOR DAILY VOLATILE STANDARDLast Calibration: 870610 14:58
Quant Time:In jected at:
Dilution Factor:
870610 14:870610 14:
1.000
Compound R.T. Scant Area Cone Unit
1)8)14)15)30)39)40)
• BROHOCHLOROMETHANEACETONE1 , 2 - D I CHLOROETHANE- D4
• 1 , 4- D I FLUOROBENZENE•CHLOROBENZENE-D5BROnoFLUOROBENZENETOLUENE-08
SSC
SSSSSS
971220252923
.88
.38
.65
.19
.04
.48
.87
219153292491619736588
1795697624128278840722425899794149
50.22.48.50.50,49.49,
,0063,02,00.00,53.70
PPBPPBPPB 'PPBPPBPPB iPPB<?
6
cc
Compound is ISTD
TOTAL ION CHROnATOCRAHfilm >nR610 40.0-CtO.O ABU.
«P? .... 4?? ....
0*L OFH * OUL I»»l
. • 9 0 .......
' '3*
Data File: >MA610::L2Name: METHOD BLANKnisc: ?mL OFU * 5uL ISS*122
Quant Output File: AMA610:tD3
Id File: IO_UDS::U1T i t l e : ID FILE FOR DAILY VOLATILE STANDARDLast Calibration: 870610 14:58
Operator ID: USER2Quant Time: 870610 14:58Injected at: 870610 14:18
RCrCRtNCC STANDARD 8PECTRUMFil* >YB923Bpk Ab 8732
800W£ACETONE 0*0923 12101 Scvi
8UB 10.2*43*
08
, , , , , , , , , , , , , ..,...,. 1....J.')44 4* 40 00 02 04 0* w-
210• In.
•100
SAHPLE SPECTRUM (BRCKOROUND fUBTRACTED)Fii« >nnBpk Ab 4
400-
0-4
61099
4
'e '
nCTHOO BLANK 0«L OTM * But 188*122 8c«f» 103SUB 7.30 Bin.
13[-100
•^4' ' '4V ' •*' ' 'rfo' ' 'rft' ' •0'4' ' '01*' ' '^0
SAHPLC 3PECTRUH <UNALTCRED)Fil* >Mfl610 nCTHOO BLANK 0»L OfM * 0uL 188*122 8c«n 103Bpk Ab 499 7.30 ain.
4» -4
400-
o- r4Z ' ^4 ' 46 ' 48 ' 0*0 ' 0"2 ' 0*4 ' 8*6 ' 8*8
Data File: >MA610::L2Name: METHOD BLANKMisc: 5mL OFU * 9uL ISS1122Quant Time: 870610 14:58Injected at: 870610 14:18
Compound No: 8Compound Name: ACETONEScan Number: 197Retention Time: 7.38 min.Quant Ion: 42.8Area: 9762Concentration: 22.67 PPBq-value: 92
Quant Output File: *MA610::D3
Quant ID File: ID.UDSttUlLast Calibrationt 870610 14:58
•>-.'clr>r *rzm : JMA610
PLANK Operator: UC3ER2 MS '?/iv-87 14.•I *• 5«..iL 155*122*1S model: 96 SW/HW rev.: IA ALS # : '.)JOHN Tuning file?: TUNE3 No. of extra reccrds: 2! 5O Analyrer temp.: 1.8O Transfer linn *-emp. : 280
.-, t-. o
'T-'-iphic temperature's : 45.•ir'u.ihic ^rimer., min. : 3.0qraphir rate, deg/min: 8.0
BLANK 5ml_ OFWT T f-Area Reject: 3.00 7.Re-^jlts File VDIR86
220.20. 00. 0
0.0.00. 0
5uL ISS#122
. n .
Max Peaks: 3Sorted by Time/Area INT
Bunching: 1
r-t.<:, ? r '
2 1 4."•COnr?o
max•SC :'f1
21?
2f35292
1 astscan
»-^ ~*
208299
peakhei ght
115624656
10375
rawarea
12627649977
105820
corr .area
JJ IEJl49649
1 05570
corr.'/. max .
IS 100.0040.5886.29
7.t
413
Gum o-f correrrte'd arsar,: 277564.
1:44 PM THU., 11 JUNE, 1987
14 HQc.10 40.0-260.0 »mu. METHOD BLfiNKROC TIC
180 200 220 240 260i 11 i, i 11 11 11 i • i T • i • . i • i • . i ij 111 i • .. 111 11 11 11 i ii i
11000-
IC'C'OO-
9000-:
3000-
700^
6000^
5000-
4000:
•3000-
£000-
100'>
5mL OFW + 5u.L ISSflc'c
280 300 320
8.0 ?.0 10.0 11.0 12.0 13.0 14.0
'•wi-. iv METHOD BLBNK 5mL-r :jC7:: 'iOB POD 0
1-i 05i 47 66 •--. 37
,-J .' i . .1 r~~
OFt-J •»• 5uL I1S'E-#122 S^an £35VC 12. -3 3 r,-,ir. .01
105 116 ;. '"7. .,. ..••• -,..-,-.. . , ,.,-.• -0
60 80 100 120 140
-i >BI'3DB Ethane, 1 ,1 ,2-trichloro-l ,2
1
85: 4? 59 *6 73 > _57
0- |l('|-| > r l'|-l 1 I'l'l > I'M'I'I'I'I1! | 1 1 l'l'| F T I . | l l • • | i l l • | l . . l | . i • r-T-i-r- '
,2-trif luoro- <8CI9CI> Scar, 94030.00 min.
01f 151,
JX>5 116 121 132 - :i . , 1 1 . 1 r " ... . i L i -n
60 80 100 120 140=• PR I POL Me than*, trichlckib 9999
1": 47 66 ?Q 8£
>rofluoro- Scan 1250.00 min.
01
105 117 121 123 E
60 ' 30 ' 100 ' 120 ' 140
•i_.BIGDe Methane, tr ichl orof1
1
: 47 5,:. 66 7C) s£ 8?
Luoro- v8CI9CI> Scan 93060.00 min.
01
105 H7 121 136 :
60 ' 80 ' 100 ' 120 ' 140
Ethane, 1 , 1 ,2-trichloro-l ,2,2-tri f luoro- (8CI9CI)Methane, trichloro-fluoro-Methane, trichloro-f luoro- (8CI9CI)Methane, trichloro-fluoro-Methane, trichloro-fluoro-
186 C2C13F3136 CC13F136 CC13F136 CC13F136 CC13F
Sample f i l e i >MA61O SpectrumSearch speed: 1 Tilting option: N
285No. of ion range* searched t
Prob. CAS # CON # ROOT K DK #FLG TILT '/. CON C_It.2.3 .4.5.
7825252525
76131125
75694128127
94031619306164163
"BIGDBPR I POL"BIGDBPR I POLPR I POL
74505O5052
6443464649
32222
00000
98999696100
350505050
557777
GDIS TUNING MO HASS CM.IBMTION
4-BroMfluorobtnztm (BFB)
t—
Cast No. 1 Contractor Gulf Coast Labs Contract No. 1
InttrtiMnt 10 GOJ Data / TIM 6/18/87 13:08
Lab ID >KA610::L2 Data RalaaM Authorizad Byt _____________
t/z
50759596
173174175176177
ION M1IOMCE CRITERIA
15.0 - 40.0* of tha baM paak30.8 - 60.8* of tha bm paakBaM paak, 100* ralativa abundanca5.0 - 9.0* of tha baM paaklate than 1.0* of baM paakgreater than 50.0* of tha baM paak5.0 • 9.0* of MM 174batuaan 95.0 and 101.8* of MM 1745.0 - 9.0* of MM 176
WELATIUE
24.29 OK52.09 OK
100.08 OK6.66 OK0.00 OK
76.64 OK5.90 OK
75.31 OK4.90 OK
MUOMCE
(7.698) tl(98.24) 11(6.510) *2
THIS PERFOffMNCE TUC APPLIES TO THEPOLLQyiNG SMPLES, &MKS MO STMOMOS
11 - Uilui in parMthtiii it ti MM 174.12 - Ualui in p«r«ntht»it it \ MM 176.
i_am£ 10.IBFBTUC
107 WOS t>. u4iM>DmiaikJQQ
lQ7«f J7 Dih/W>
_>KA410.IJATIJFJIMILYS1S.IJ
6/10/87__I_^13:08.
>McPa><
>MCPII
^
-/0-K7
>• 87
A-/O-87
fS.SI
: OS
PQMV 7/W
rti* >KRtioBpk Rb 7119
790O
700O
690O600O
990O900O4900400039003000£900ZOOO
1900
100O
900o
BFB TUNC euc of 4-arB TUNINB SOLUTION sc«n 19160
10.30 Bin.•^0 ( 100 120 f 140 i 1*0 t 180 t £00
F"°'
79/
90
4ih
68- a!60
/
"<
i
C07L x.>. Ill ^
-100
-90
-BO
•70
«o•60
•40
•30
•80'•10
BO ibc i ' ifeb ' 140 " i i o " lab ' abb
>KA610 BFB TUNE191 NRM
File: >KA610 Scan *:
m/z
43.2044.1049.2047.1048.1049.1090.1091.1099.10
Int.
1211
9246
.334
.936
.784
.292
.829
.898
.287
.630
.787
m/z
96.1097.1060.1061.1062.1063.1068.1069.1070.10
191
Int.
23199311101
.079
.982
.166
.380
.169
.791
.989
.788
.011
2uL
Retn.
m/z
72.1073.2074.2079.1076.1977.0978.0979.0980.09
of 4-9FB TUNING SOLUTION
time: 10.30
Int.
.7309.19716.92792.0864.284.744.4393.849.913
m/z
81.0982.0987.0988.0992.1993.1994.1999.19
Int.
4.•
4.4.2.3.10.100.
200716397397444791690000
m/z
96.19141.10143.10174.10179.09176.09177.09207.19
QUANT REPORT
Quant Rev: 6 Quant Time:In jected at
Dilut ion Factor:
•srator ID: USER2tput File: ALB610::D3•ta File: >LB610::L2•me: 50ppb STANDARD•*c: 5mL OFU * 5uL ISStl22 * 2.5uL ea. *115 & f!20
> File: ID_UDS::U1tie: ID FILE FOR DAILY VOLATILE STANDARD^st Calibration: 870608 20:35
870610 14:0:870610 13:21
1.00001
Compound R.T. Scant Area Cone Units
1 )2)3)4)<5)4 )7)1)9)
: 0)1 1)12)13)14)5)'6)T7)-9)9)20)21)22)23)24)25)26)27)28)29)30)31)32)33)34)35)36)37)38)39)40)41)
•BROMOCHLOROMETHANECHLOROMETHANEBROMOME THANEUINYL CHLORIDECHLOROETHANECARBON DISULFIDEMETHYLENE CHLORIDEACETONE1 , 1-D I CHLOROETHENE1,1-0 I CHLOROETHANETRANS- 1 , 2 -D I CHLOROETHENECHLOROFORM1, 2 -D I CHLOROETHANE1 , 2 - D I CHLOROETHANE- D4 SSS• 1 , 4-D I FLUOROBENZENE2-BUTANONE1,1, 1-TR I CHLOROETHANECARBON TETRACHLORIDEUINYL ACETATEBROnOD I CHLOROMETHANE1,2-01 CHLOROPROPANETRANS- 1,3-01 CHLOROPROPENETR I CHLOROETHENE0 I BROMOCHLOROMETHANEBENZENE1 , 1 , 2- TR I CHLOROETHANEC I S- 1 , 3-D I CHLOROPROPENE2-CHLOROETHYLVINYLETHERBROMOFORM•CHLOROBENZENE-D52-HEXANONE4-METHYL-2-PENTANONETETRACHLOROETHENE1,1,2 ,2-TETRACHLOROETHANETOLUENECHLOROBENZENEETHYLBENZENESTYRENEBROHOFLUOROBENZENE SSSTOLUENE-08 SSSTOTAL XYLENES
9.882.073.023.774.658.296.697.389.4610.7111.4312.0012.7212.6520.1912.6814.0514.4314.9814.9616.3216.5917.1617.7617.6517.8817.8818.9420.4625.0422.4620.9922.7722.7324.0629.1627.0930.8829.4823.8732.10
21913385881177135153208241260275294292491293329339343353389396411427424430430458498619591911999998993622673773736988809
1834293959090116626052675582280013002187274061021544474523950543905817761623437176365165660342927249845936731923338077069329797297262080627923739933099939605277994171189292639873036067034606409643390147
90.00 PPB51.92 PPB55.92 PPB52.62 PPB50.12 PPB44.29 PPB47.72 PPB47.72 PPB49.82 PPB47.46 PPB49.02 PPB49.16 PPB49.62 PPB50.69 PPB50.00 PPB36.49 PPB48.50 PPB49.78 PPB47.75 PPB47.68 PPB44.09 PPB45.91 PPB47.82 PPB49.62 PP846.91 PPB47.11 PPB46.71 PPB44.81 PPB47.57 PPB90.00 PPB36.28 PPB37.42 PPB48.60 PPB46.00 PPB47.46 PPB48.21 PPB47.87 PPB48.21 PPB48.81 PPB47.86 PPB47.69 PPB
* Compound is ISTD*
TOTPL ION CHROf1PT08ROf1ril« >LB610 40.0-860.0 MU. SOppb STRNDflHD
200 ,
B«L OFU * QuL ISSwle
'- ' 16 ' "20 ' 24 ' 2'8 ' 32 ' 3'6 '
Data File: >LB610::L2 Quant Output File: *LB61Q::07Nome: SOppb STANDARDMisc: 5mL OFU * 5uL ISSfl22 * 2.5uL ea. #115 & f!20
Id File: ID_UDS::U1Title: ID FILE FOR DAILY VOLATILE STANDARDLast Calibration: 870608 20<79
Operator ID: USER2Quant Time: 870610 14:07Injected at: 870610 13:28
I N I T I A L C A L I B R A T I O NVolatile HSL Compounds
D A T A
Case No.: . . . . . . . . . . . . . . . RegionContractor : Golf Coast Labs
nt ractor No.: ...............
IEPA Instrument ID : 1Calibration Oete : 870515 13:05
RF for SPCC is 0.300( 0.25 for Browfor* )
riaxi«n WSO for CCC is 30k
Laboratory 10 :
CompoundChlorowthaneBrokee* thaneUinyl ChlorideChloroethanerfethylene ChlorideAcetoneDtrbon Oisulfide1,1-Oichloroethene1.1-Dichloroethen«Trans-1 ,2-PichloroetheneOlorofora1.2-OicMoroethane2-Butanone1,1,1-TrichloroethaneCarbon TetrarhlorideUinyl AcetateBroMdichloro*e thane1,7 OichloropropaneTrans-1 ,3-OichloropropeneTriehloroetheneOlbroaoehloroiwthane1,1,2-TnchloroethaneBenzenecis-1, 3-Oichloropropene2-ChloroethylvinylatherBromfora4-Hethyl-2-Pentanone
>Lft515::B5 >LB515::C5 >LC515::D5 >LD515::E5 >LE515::
Tetrachloroethene1,1,2,2-TetraehloroethaneTolueneChlorobtnienaCthylbtnteneStyreneTotal Xylene*
Response FKtor (subscript is the Mount of ug/U
Average Response Factor
Percent Relative Standard Deviation
RF201.0173.7477.8163.3798
1.4474.5577
3.95281.33662 62331.43842.90452.4768
.1959
.5781
.5549.7010.6000.3656.7997.4884.4785.3720
1.0646.4355.2855.3870.5080.3973.5035.5535
1.43411.0582.5058.9813
1.3218
RF501.4883.9890
1.1301.4958
1.2988.7431
5.67481.18312.34481.27762.59702.1480
.2437
.5055.4944.9914.5364.3333.7217.4228.4299.3206.9545.3702.2476.3570.6970.5104.4348.5068
1.2611.9356.4547
1.34551.7913
RF100.9380.5414.7074.3118
1.1692.3750
3.56501.07552.12721.15122.30591.9260
.1479
.4499.4467.6454.4879.3062.6674.3806.3780.2803.8722.3406.2333.3397.4286.3162.3851.4448
1.1450.8413.4103.8521
1.1201
RF150.9854.4116.7003.3023
1.1732.3867
3.59111.08992.15521.16072.2994..9010
.1464
.4438.4348.6377.4837.3029.6560.3659.3622.2643.8618.3302.2353.3406.4592.3417.3745.4534
1.1505.8501.4070.8511
1.1195
RF2001.1477.3553.5272.2840
1.1112.3753
3.6376.9895
1.97121.07592.13361.7389
.1433
.4204.4133.6519.4592.2848.6079.3535.3352.2367.8191.3035.2165.3201.4500.3289.3541.3890
1.1929.8085.3194.8741
1.1528
RF1.11W
.6090.776).3547
1.2400.4879
4.08831.13492.24431.2?072.44812.0381
.1754
.4795.4688.7255.5134.3186.6905.4022.3948.2948.9144.3540.2437.3487.5184.3789.4104.4695
1.2167.8981.4534.9812
1.3889
CCC •WSO SPCC •
19.95 • •42.7828.75 •24.4710.8633.3429.0111.63 •11.14 • •11.5912.45 •13.9925.0213.2012.0720.7710.899.89 •
10.6013.6214.4317.9010.6314.1711.627.20 • •
21.4921.0414.6013.38 • •11.18 •11.21 • •18.N •21.4622.84
CCC • Calibration Check Coepounds ( • )
SPCC - Syete* Performance Check Ceepeunda ( • •
C 0 NT I N U I N 5 C A L I B R A T I O N C H E C KVolatile HSL Coipeunds
"m MO.: !Contractor : 9ulf Coast Libs
Csntrietor No.: 1Instrument 13 : SCI!
Region : IEPA Cilibntion Date : 970608 29:35Tin : 870610 13:28
Laboratory ID : >LB6!0::L2Initial Calib Date : 870515
RF for SPCC is 0.300( 0.23 for Broiofort >
Ffaxiiui ID for CCC is 251
CoipoundChloroiethineBroioiethaneVinyl ChlondiChloroethaneletnylene ChlorideAcetoneCarbon OisulftdeI.i-Dichisroethene1.1-DuhloroithiniTrans-1,2-DichloroetheneChlorofon1.2-Dichlorofthint2-Butanone1,1.1-TruMorotthaneCarson TftrachlflrideVinyl AcetateBrotodicliloroMthine1,2-DichloropropaneTrans-l,3-Dichlor9propeniTrichloroetheneDibroioch lor Methane1,1,2-TrichloroethaneBenzeneci5-1,3-Oichloropropene2-ChloroethylvinyIetherBroMfori4-Hethyl-2-Pentino»e2-HtxanoneTetrachloroethene1,1,2,2-TetrachlorBethaneTolueneChlorobenzeneEthylbenzeneStyrennTotal lylenei
RF30 - Response Factor fro* daily ftandard file_ it 50 «g/LRF - Average Response Factor trot initial Calibration Fort VI
Fere VII
RF1. 1153.6090,7743.35471.2400.48734.09331.13492.24431.22072.44812.0381.1754.4795.4686.7255.5134.3186.6*03.4022.3968.2948.9144.3560.2437.3487.5086.3789.4104.46951.2167
BUBfl• DTOO
.4334
.91121.3009
RF50.5122.4956.4358.32991.2430.7C39
3.LB32.. '02 /'MO1.17*4
2.58..2.1S3B.1985,454fr,446S.6922.5249.3055.6771.3855.4134.3153.8640.3635.2344.3415.5385.4154.3778.56711.1591.8686.4128.91141.2256
1C54.0713.6219.106.9P.24
45.419.9110.041.313.785.68!.68
13.183.194.734.592.254.111.954.164.196.975.512.114.402.085.879.647.9420.794.733.364.767.123.79
CCC SPCCt t
I f
10 - Percent DifferenceCCC - Calibration Check Co*omdi I » >
SPCC • SyitM PrftrMflct Chtci CMp««id( ( • • )
7/83
•a:It »mt
i*':.\
Cat* B.
Lo't''*:'. N;. ___
Ditt Siipl* kccivc
Concwitritioni
D*t( Eitrictid/Prtpiridi
Diti toilyttdi____
N»d»u§ (Circlf DM)
Cone/Dilution Ficteri.
COS
PircMt Noiiturti (Not Dtcinttd).
tig/kgfrclt Ont) __ CAS I cll
74-87-3
74-83-9
73-01-4
73-00-3
75-09-2
47-M-l
73-13-0
75-33-4
73-34-3
134-40-3
47-4A-3
107-04-2
78-93-3
71-SS-4
34-23-3
10I-M-4
75-J7-4
I1
CMorotfthiM ! < 10:
IrcMMthint ! < 1011
Vinvl CDloridt ! < 10!
Chlorotthani ! < 10ii
hitfwlini Chloridf 1 < S
Acitooi i <.(011
Cirfeon Dlulfite ! ( 31
l.l-DichlorotthMt ! < 3!
l.t-DieMorotthMt 1 < 311
Trm-1.2-DlcklvattlMM i < 3!
! Cfclarofori t < 3! !1 1.2-OicklarotthiM ! < 7! !! 2-tutinont ! < 10! !
1 1! Ctrlm Tttracftlorllt ! ( 31 !! Vinvl fcttrti i < 10! !t IrMorflcH— — ffc-ry i ( S1 ~. fe 11 v^ttft |
IJIJ1
178-87-3
10061-02-6
79-01-4
124-48-1
79-00-3
71-43-2
10041-01-3
110-73-fl
73-23-2
591-79-4
108-10-1
r:-:«-479-34-3
1 KM-M-3tI lM-fO-7«I 100-41-4!1 100-43-3J1
1.2-DichloroDronnf
Trim 1,3-DichlofonrMtM
Trlehlorotthini
DibroMcMoroMthini
1.1.2-Trichlorofthani
Bmtint
cli-1.3-DiehloroBroitfli
2-ChlarMthvlvinvlithtr
IroMfori
4-Mtthvl-2-ftntiflont
2-NtlMMI
Titrichloroftktnt
1 .1 .2.2.-TitriehlorofthiM
TBlmt
CklorobMiMi
EthvllMimtJ1 ItWfM11 Tttll IvlMM
< 3
<, 3
< 9
< 3
< 3
< 3
< /
< 10
< 9
^ 19( 10
< 3
f 9Jt < s«i < atM 3i1 < Si1 < IS
r
f*»» Nn
Organict Anilysis Data Sheet(Page 4)
Tentatively Identified Compound*
CASNumbM
i
.,A
R
a
,a
ft
10
11
1114
18
1ft
17
11
JO
99
M
9A
9ft9C
97
>c
2*
M
Compewnd NWIM
UrtlCnoix) r».
.
frcctioA
to A
S*mptf Number
INwmbw
mi/)5".4(
E*tim*l«C0iK«nirai
([( /P«nig/
P9
•
form t.
QUANT REPORT
Quant Ravs 6-rator ID: USER2tput File: ~MCP01::D3ta File: >MCP01::L2•ne: MAECORP 107402^c: 5mL SAMPLE * 5uL ISSfl22
File: ID_VDS::Ultie: ID FILE FOR DAILY VOLATILE STANDARD•st Calibration: 870610 14:59
Quant Time:Injected at:
Dilution Factor:
870610 15:43870610 15:04
1.00000
Compound R.T. Scan! Area Cone Units
) »8ROMOCHLOROMETHANE) 1,2-DICHLOROETHANE-D4) • 1,4- 01 FLUOROBENZENE) »CHLOROBENZENE-05) BROMOFLUOROBENZENE) TOLUENE-08
SSS
ssssss
91220252923
.88
.65
.23
.08
.48
.87
219292492620736588
181814152977900715865831193107
50.47.50.50.49.49.
00710000,40,60
PPB<*rFPBT5PPBPPBPPB?*?PPB ff
Compound is ISTD
ca<Dot-aqXuT0
a0
D
*
J 01. O-
Xg»j
o
o0.
ur.
oH
ft.e3 0J o-JO «•x~el-
s'•
O^ 0*£ Al
1
>*
<H
LJ 1
•«
Z
\j
JTI v»Mir»r)3 ——— — — ~^^^^^~^ i
!i
3IWWMOMC .UvOOMMnS —
"MyunmMfntfyiMUB — — — ^_jw uj MJBU irvwfwm
_^j*iI
_. — — — ~-^~^
o o o o o o o oo o o o o o o oO Al Al Al v* T*
-s.Al
"Al
Al
•
OAl
*
Al'H
•O
"^
a.<••O
^-*•^4
b.««3a3O*>c3a
CM•V)U)•-1.
CM 3-1 CM UN•• O
^ i\ *0 0 Ua. .-• _iu a.E QL r^ QC <E
O 0)•• Ue UJ _J— <I E••< f if\U.
• • *•C t) O-^ E «
Q 2 £
Oa[
oz<rHU)
U
—<E UNJ ••
§ 2> 0
*T
C OOf\
r-l O>
• • ^J ••
- U. cin oOUJ -D-J *-
M 0ou. «-"Q "2.. •— «0 0— .. u-- oU. — *-
*- 0T> — 0"- ^~ «J
CS ^9^ o
UN UN••4 ^4
0 O
a MJNOUl o o(/) f\ l\D CD 09
.. MQ .. *•— 00
t — TJ0 »- 0
0 ** O«. c a0 0 — •>
^(iJS
data file header from : >MCP01
6/10/87 1«^imple: MAECORP 107402 Operator i USER2 MSnc : 5mL SAMPLE * 9uL 195*122js. *: 3 MS model: 96 SW/HUI rev.: IA ALS * I 0Hothod file: JOHN Tuning file: TUNE3 No. of extra records: 2Source temp.: 190 Analyzer tamp.: 180 Transfer line temp. : 280
Chromatographic temperature* : 49. 220. 0. 0. 0.Chromatographic times, min. : 7.0 20.0 0.0 0.0 0.0Chromatographic rate, deg/min: 8.0 0.0 0.0 0.0 0.0
MCP01 MAECORP 107402 9mL SAMPLE * 9uL ISStl2240.01 260.0 ADC TIC
Jpslope: .20 Area Reject! 3.00 * Max Peaks: 7 Bunching: 1Dnslope: 0.00 Results Fila UOIR9? Sorted by Time/Area INT
eak*
123
R *r. • •in in .
5.419.649.92
firstscan
94106214
maxscan
101107220
lastscan
106124230
peakheight
33881889
11918
rawarea
9062932661124389
corr. eorr.area K max.
466997 38.09242693 19 . 78(122714) <& 100.00
Sum of corrected areas: 193678.
10>99 PM UED., 10 JUNE, 1987
O'TT
2MS8Uno311 D(W
TOd3M<
Film >ncpoiBpk Pb 1*81
naccoftp i074ot
i 42
4«.0
n«L SAHPLC * 6uL IfSMtt Scan 101M)0 OVC 8.41 ain.
46
43 44
43.0 44.0 JLJ.48.0 4«.0
Sample file: >MCP01 Spectrum f: 101
No dete base entries were retrieved,
. • >ncpoi<k Ob 894
il« >BI80Bok Ob 9999
J
tlflCCORP 107401 6*sue not4
43
,,,,,,,,,,,1,1,,,,,,,,,.,,.,..,4Z.8 43.0 43.6 44
443
43.8 43.6 43.6 44
L tPtlPLC * 6uL IStMtt tc*n) DVC 6.M
464 x*
.6 ' 44*. 8 4\i.O 48*. 8 4«!.6
rl- <0CI*CI> te«n0.00
4 48
I *.0 44.6 46.0 46.6 4«.0
107• In.
L330
• in.
1. Si lane, methyl- (8CI9CI) 46 CH6Si
Sample file: >MCP01 Spectrum #: 107Search speed: 1 T i l t i n g option: N No. of ion ranges searched:
Prob. CAS * CON t ROOT K DK *FLC TILT * CON C_
1- 28» 992949 330 "BIGDB 21 64 1 0 60 39 II
" i l« >tlCP01Rpk Rb Z669
4
Lrum >BI808Bpk Rb 9999
L
NRCCORP 107402
L9
f , ,50 60 70
n«th*n«,
(9/
51.- - 64 65
80 6*0 7*0
5»L ffltlPLt 4 8uL 1 88*122 88U8 ROO OVC 9.
? w 9/3Vi ^'i'80 90 100 110 120
brooch lore- (8CI9CI) 8c«i0.
**• 9^ ^3 100 116120
80 90 100 lib 120
cvt 2209t min.ISO,(,i
130n 13907)0 Bin.130
lit130
1. Methane, bromoehIOPO- (BC19CI) 128 CH2BrCl
Sample fil e : >MCP01 Spectrum *:Search speed: 1 T i l t i n g option: N
220
1.
No. of ion ranges searched
Prob. CAS * CON * ROOT K DK fFLG TILT * CON C
95« 74975 13907 "B1COB 100 12 1 0 86 6
.<»:. r N*.iD*r
QHMMIC8 ANALYSIS DATA SHEET
Laboratory Mm Bi» Coait LaooratoriH. flic. CM* No.__
Likoritorr 10 NG.
S«tflf Hatrii
K Rtiort No..
Contract No. .
Data Rtltaw Autkorizri k>_ Datt Saaplt Uteri no*.
US I
vaATJJJECWWUNWCoflcentntion: CtoO NHiut (Circlt Ont)
Datf Eitracttd/Prttarrt»
Datf -? 7
Factori tH
Ptrctnt (toistwii (Rot DtcantH).
or 09/Mirclt ttnt)
11
74-B7-3 !tf
74-83-9 !11
73-01-4 !It
73-00-3 !!
73-09-2 !t1
67-64- 1 !
73-15-0
73-3S-*
73-34-3
13A-M-3
47-U-3
107-M-2
7W3-3
71-55-4
54-2M
!M-«S-4
73-27-4
!CMoroMrthaof
vTMOOftnaMf
Vinvl Oilorifc
DilorottkaM
NfthvlfM Oiloridf
Acttont
Carbw DiMlfiff
I.l-Dieklarotti«M
1.1-Hrtlorottfcm
TraM-1.2Hlcklorottk«w
Oilarofort
1-MirMarfltttaBf
2-lntaMM
1.1.1-TricfelfrofthMt
CarbM Tttrackloriff
Viivl Aeftatf
lrM ieklVaHtkaM
(10
(10
<10
(10
< 3
40 206!
< 3
< 3
< S
< 3
< 3
< 3
(10
< 3
< 3
(10
< 3
CAS tof/kg
rdt Ont)
7B-B7-3
! IOM1-02-6
79-01-6
124-«-l
79-00-3
71-43-2
10041-01-3
1 10-75-*
73-23-2
591-71-4
lOt-lO-l
127-11-4
79-34-3
lOt-U-I
10MO-7
100-41H
100-42-5
!! 1.2-9icb]oroorMa*fii! Traat 1.3-Dichlorooroifw!! TrichlorottkntI! libroMchloroMthiMIi
! l.U2-TricMorortkaM11
! IntoM1l
! cii-1.3-tickloroornMflf!! 2-CfelorattbvlvinlfUitr!! IroMfori!! 4-*MM-2-footaMM1! 2-MniMMt1 TttrifkliroftlMtf!I l.l J.-TttradlorottlMM!1 TalMMII CkltrfAMtoM11 CtkvlkMZMM1! ItfTOM11 Tltll Iff 1 MM
< 3
( 3
< 3
( 3
< 3
< 3
< 3
<IO
< 3
(10
(10
1 < 3J1 < 3J> ( 3}> < 3J1 < S1! < 311 US
JS1111111111
Case No
Organic* Analysis Data Sheet(Page 4)
Tentatively Identified Compounds
Sampl* Number
107403
CASNumtet Compound Nam* •tl
V/OA HO1 1 •37
10.1112.13
1S.
It.
27.2t.
Form 1.
QUANT REPORT
aerator ID: USER2Jtput File: ^MCP04::D3*ta File: >MCP04: :L2
MAECORP 1074035mL SAMPLE * 5uL ISS1122
Quant Rev: 6 Quant Time: 870610 18:0Injected at: 870610 17:2
Dilution Factor: 1.0000
isc
D File: ID_UDS::U1'itle: ID FILE FOR DAILY_ast Calibration: 870610
Compound
UOLATILE14:58
STANDARD
R.T. Scant Area Cone Unite
181415303940
)))))))
« BROMOCHLOROMETHANEACETONE1 , 2 -D I CHLOROETHANE- D4• 1 , 4- D I FLUOROBENZENE•CHLOROBENZENE-D5BROMOFLUOROBENZENETOLUENE- D8
SSS
SSSSSS
9.7.12.20.25.29.23.
87376422034785
219153292492619736588
1730149214031775175675215576688366
50.20.48.50.50.50.49.
00066800000991
PPBPPBPPB'PPBPPBPPBPPB
<U
(OCtoe
* Compound is ISTD
TOTPL IONril« >nCP04 40.0-860.0 MIU. HHCCOKP 107403
33000-
28000-
84000-
20000-
16000-
4000-
B»U SRHPLt •»• QuL IS!
. . . . . W . . . . . . .
' 4 ^ k iT^ !'• T 2
Data File: >MCP04::L2Name: MAECORP 107403M i s c s 5mL SAMPLE » 5uL ISS*122
Quant Output File: AHCP04::D3
Id File: IO_UOS::U1T i t l e : ID FILE FOR DAILY UOLATILE STANDARDLast Calibration: 870610 14:58
Operator ID: USER2Quant Time: 870610 18:07Injected at: 870610 17>29
ta f i l e header from : ,--MCP04
-•: MA!-:CORP 107403 Operator i USER2 MS 6/l'Vc37 17:2: 5rv_ SAMPLE + 5uL 135*122
rt: Z MS model: 96 SW/HW rev.: IA ALS # : 0.hod *ilt?: JOHN Tuning file: TUNE3 No. of extra records: 2<-.p *-. "flip.: 15O Analyser te«mp.: 180 Transfer line temp. : 28O
Chr om ni-.oqraphic temperatures : 45. 220. 0. 0. O.Chromatoqraphic times, min. : 3.0 20.0 O.O 0.0 0.0Chrornatographic rate, deg/min: 8.0 O.O 0.0 0.0 O.O
5mL SAMPLE + 5uL ISS*»122•4 MAECORP 1074O3.01 260.0 ADC TICope: .20 Area Reject: 3.00 '/.-pe: 0.00 Results File VDIR86
Max Peaks: 2 Bunching: 1Sorted bv Time/Area INT
min. *~> c: ,•?. n
'v.-r; 92
max•snan
102219
lastscan
1.24
peakheight
21332I 1097
raw.area
3415861 19726
corr .are-?
329431118271 '
corr ."/. max .
100.00SS 35-. 90
•/. otot
73.26.
'ium of corrected -arfvi.s: 4477075.
10:51 PM WED., 10 JUNE, 1987
:?.ta f i l e header -from : 'MCP04
!•?: MAFCOFP 1O7403 Operator: U<3ER2 MS 6/1O/87 17:: : r.m'., SAMPLE + 5uL 155*122. *»: 3 MS model: 96 SW/HW rev.: IA ALS # : O'•:?thod -file: JOHN Tuning -file: TUNE3 No. of extra records: 2•jrce temp.: 15O Analyzer temp.: 18O Transfer line temp. : 28O
Chromatographic temperatures : 45. 220. 0.Chromatoqraphic times, min. : 3.0 2O.O 0.0Chromatoqraphic rate, deg/min: 8.0 O.O O.O
0 .0 . 0O.O
O .0 . O0.0
r04 MAECORP 107403^O.01 260.0 ADC TIClope: .20 Area Reject: 3.OO '/.slope: O.OO Results File VDIR86
5mL SAMPLE 5uL ISS*122
Max Peaks: 2 Bunching: 1Sorted by Time/Area INT
R.T.mi n .
2.21?. 74
•first
1427
max
1731
lastscan
2735
peakheight
7072359
rawarea
939428251
corr .area
878553939
corr.'/. max .
100.004.48
7.t<
9!t
Sum 91794.
1:56 PM THU. , 11 JUNE, 1987
c
<J\o
Cf^• -
o
^1• ™
o
CO• ™
o
• '• —
o
»-*o.•
o
H» ;M_•
O
H* h» M M »-> To roT'.< u 'j. 00 o n.« •& <r- o> o r>jo o o o o o o o o o oo o o o o o o o o o o
f1. i .9. , .9. . .9. i .9. , .9. • .9. . .9. . .9. , .9. . .9. , .9.i1i'
t
\
: _.. ________ ————————— ——— *• K
^_,--~~
>-•"
/
f
(_ >
i'
!
,>
--—___' "' '_.. -=> w
_ _ _ — —— • —— ———
d _*
- to
* *-£o
Aoo
f '-o ro-0 £
•
oV »TO 30 C
•
" I>3. orH» OP!-*. Oo -*o• — •*
- OTJ
l-»H O-^ No *.
OU!
H»-o>O
Ol3
w n-o o,.0 U
3-0r-
ro n
-roCD *
enCr~
ro-A "7,-, >.' <
u-i%MIV
y*^"^
3IP
Q.
5
OJ
oo'
.o
a"CIOfroc o'
CD
l
£ -'i•*
oo4oo oo10
c«C'
c»oOJ
<XJ
, o"" •
Cvl
o.<">cu
o
cu
o
(U
oP)•
cu
ocu•
CO
o•H•
CO
.4 >MCP04 MOECORP 107403 5mL SflttPLE + 5uLAb 11294 SUB ODD DVC
45
] 41 42 43 44
J^ 1 f 142.6 ' 43.6 ' 4'4.0 ' 45".6
.1* >BI6DB Eihanol <fiCNX9CI>. - - v «b 4887
45
j 42 43 44
tH- r| i-TT- -r-n-ri-TTT-i | i i i i | i • i i f i . . . | . . i i i i i i42.0 43.0 44.0 45.0
' F i i « >B16DB M«thana, oxybis- <9CI>c-nk fib 999945
! 42 43 44i _ ^^_ / f
42.0 43.0 44.0 45.0r:l« :'BIi:-De Formic »cid <OOT XOCI9CI >
' J - . i - Pb «i095
jj f4 I
42.0 ' 43.0 ' 44.0 ' 45.0
ISS*122 Scan5.43 n
46' 47
46.0 47.0
0.00 i
y • /"I46.0 47.0Scan0.00 i
46' 47
46.0 47.0Scan0.00
46
47
46.0 ' 47*.Q
102n i n .
0
121oin.
'-0
376• in.
-0
374Min.
9
'-Q
1. Ethanol (ACNM9CI)2. Methane, oxybis- (9CI)3. Formic acid (DOT)(8CI9CI)
46 C2H6O46 C2H6O46 CH202
Sample fllei >MCP04 Spectrum fttSearch speeds 1 Tilting optioni N
102No. of ion rang** »»arCh»d:
Prob. CAS tt CON 41 ROOT K
1. 70* 64173 121 "BIQDB 282. 32* 11S1O6 376 "BIGDB 243. IS* 64186 374 "BIQDB 20
DK #FLG TILT X CON C_l
3962SO
0o0
000
2049159
71857
4:2C
> (1CP04 MSCCORP 107403 5mL SAMPLE * 5uL I6S#122ftb 3937 SUB ADD DVC
44
Scan 172 .21 min .
41 42 43
41.2 41.6 42.0 42.4 42,43.2 43.6 44.0 44.4 44.8f-Q
Sample file: >MCP04 Spectrum #: 17
No data base entries were retrieved.
ji«p,f
Lakoritory HIM
lAoritory II Ml
Suplf Hitrii_
lltl ItlNM
OMMICI MMLrill MTA MIT
Cm fe.__
CASf
74-17-3
74-63-?
73H)M
75- 2
73-15-0
73-35-4
47-U-3
107-04-2
7MM
71-g-A
34-23-3
COKNtritiMI
lltt
Ntl
tac/lilitiit Fictirs.
Nrcmt (Mitarts Utot
rclt ftit)
ChlomtthMi.{! (10
JrojMttkKtf
Viivl DilorKt
Urthvlm Dilnrilt
Octtat
1.1.1-Trichl
TttridilnrKt
Vlivl Aettati
(10
< 3
( 3
< 8
< 3
(10
< 3
Ktaportfc.
CMtrictfc.
lltt iMpIt fcctivrt.
ICirelt OM!
7J-B7-S ! 1.2-HeM
10041-02-4 I Trm 1.3-Mcfcl
79-01-t
124-4J-1
_7tOO"3_
71-41-2 I IMUM
10041-41-
10t-10-l
127-1M
10I-M-3
JOMO-7
100-42-3
1.1.2-Tri
2-Hm
Till
Tttal 1*1i
(Clrtlt htli«! < 3II
<_S__
< 5
< 3
< 8
< S
< 8
< S
< 3
( 3
Cut No
Organics Analysis Data Sheet(Page 4)
Tentatively Identified Compounds
Sample NuT>t>«r
CASCompound Nwnc
Sc.nNumber
I/OA 1Ono
\JOfi
10.11.
IB.16.
1920.
22.23.
2S.
1ft
QUANT REPORT
Operator ID: USER2Dutput File: AMCP05::D3•Data File: >MCP05: :L2'Jame: MAECORP 107404
5mL SAMPLE * 5uL ISS#122
Quant Rev/: 6 Quant Time:In jected at:
Dilut ion Factor:
870610 19:870610 18:
1.000
ID File: IDJJDS::U1Title: ID FILE FOR DAILY VOLATILE STANDARDLast Calibration: 970610 14:58
Compound R.T. Scan* Area Cone Unit
1)8)14)15)30)39)40)
• BROMOCHLOROMETHANEACETONE1 ,2-DICHLOROETHANE-D4
• 1 , 4- D I FLUOROBENZENE•CHLOROBENZENE-D5BROMOFLUOROBENZENETOLUENE- D8
SSS
ssssss
9.7.12.20.25.29.23.
88346422045186
219152292492619737588
16925156173913072178644995324985272
50.65.48.50.50.50.50.
00082900000742
PPBPPBPPB tPPBPPBPPB 10PPBiC
* Compound is ISTD
TOTAL ION CHROflflTOeRflMMl. >HCP05 40.0-360.0 *»u. "BECORP * But 185
zeooo-
34000-
2000
I6or,
1200
8000-
4000-
zyo
1£
600
84 38 3*4
Data File: >MCP05::L2Name; MAECORP 107404Miac: 5mL SAMPLE * 5uL ISSfl22
Quant Output Filet *MCP05i:D3
Id File: ID_UDS:»U1Title: ID FILE FOR DAILf UOLATILE STANDARDLast Calibration! 870610 14:96
Operator ID: USER2Quant Time: 870610 19s00Injected at: 870610 18:22
REFERENCE 5TPNOQRD SPECTRUH
Bpk Rb 73
aooo4
42
QCETONE 860923 12iBl ScanSUB 10.26
98
44 ' 46 ' 48 ' 8*0 ' 8*2 ' 8*4 ' 86 ' 88
216• in.
•100
SRHPLE SPECTRUM <BRCK8ROUNO SUBTRRCTED)FiU >nCP09 tIPECORP 107404 9«L SRtlPLE * 9uL ISSM22 Scan 192
t
1000-
A^
42
/iu
-100
. 4V ' ' 4*' ' 'A' ' '4V ' 'rfo' ' 'rft' ' '44' ' '&' ' '4*~
SflttPLE SPECTRUM <UNRLTERtO>Til* >nCP09 flRECORP 107404 8»L SRHPLE * But 138*122Bpk Rb 11*8
43
1000^
IV
42 44
1ft i» ft ft «f*f ft ' R"» ' ft
Scan 1927.34 min.
r1 ftData File: >MCP09::L2Name: MAECQRP 107404Misc: 5mL SAMPLE * 9uL ISS*122Quant Time: 870610 19:00Injected at: 870610 18:22
Compound No: 8Compound Name: ACETONEScan Number: 192Retention Time: 7.34 min.Quant Ion: 42.8Area: 19617Concentration: 69.08 PP8q-value: 96
Quant Output File: AMCP09t:D3
Quant ID File: IO_UDS::U1Last Calibration: 870610 14:98
at-\ file header from » >MCP05
Die: MAECORP 1O7404 Operator: USER2 MS- : 5mL SAMPLE + 5ul. 133*122. tt: 3 MS model: 96 SW/HW rev.: IA ALS # : 01cthod file: JOHN Tuning file: TUNE3 No. of extra records:'.tree temp.: 150 Analyzer temp.: 180 Transfer line temp. :
6/10/87 18
280
Chromatoqraphic temperatures : 45. 220. 0. 0.Chromatographic times, min. : 3.0 20.0 0.0 0.0Chromatographic rate, deg/min: 8.0 0.0 0.0 O.O
5mL SAMPLE + 5uL ISSM122
0.0.0O.O
MAECORP 107404•10.OI 260.0 ADC TIC-lope: .20 Area Reject: 2.00 7.slope: 0.00 Results File VDIR86
Max Peaks: 5 Bunching:Sorted by Time/Area INT
R.T.min .
2.225.447.34
r-1. 7O9.88
firstscan
1393145184213
maxscan
17102152188219
lastscan
28134162197228
peakheight
13739282731709983
10775
rawarea
2449764173252698614270
1 1 6220
corr. corr.area '/. max .
161199 40.12401752 100.0021359HSL s.3211905 2.96
|Ji482l|fS 28.58
t
25
1
Sum of corrected areas: 711036.
11:11 PM WED., 10 JUNE, 1987
i_» i_ * i - t t - t t - t r u r o i u t o r ua - . o o o ' v > * < 7 » c o o i v - * | J * c oo o o o o o o o o o o oc - o o o o o o o o o o o
_?_., 9 9 . 9. 9 . 9 . 9 . 9 . ? . ? . ?
01
If
Oen
' oifVi
o•o
Leo £o c
OX)- ono
-ro.0
OTJ
ru•oo
CM3
D3-or*m+01
ro "-•-*.o *H
ro
il* >MCPQ5Dk Pb 7686
41
MfiECORP 107404 5mL SOMPLE * 5uL ISS#122SUB POO DVC
44
42 43
?can 17a.£5 min.
45r J T T T T | I I I I j r l » T | n I F |TF I r J ¥ rT^rj^T-IT • I I I I I J I I I I J I I I F J I I T I I I I I I | I F T I f FTrr I • . 1T[ I I I
41.5 42.0 42.5 43.0 43.5 44.0 44.5 45.0
Sample filmt >MCP05 Spectrum #: 17
No data b«»* vntriv* H«r« r»tri»v»d.
nc-* t> 1
0-
: : .-- BI•; '_ • Mt' <•
r i l* >B1Pp i Hb «
P05 MftECORP 107404 5mL SPtlPLE + 5u5201 SUB ODD OVC
4
* **M 43
41 4* / 44
r r .M .Mu f . , , , . . . . , ! . . . , . . . . , " . , . , , . . . , .42.0 43.0 44.0 45.0
QDB Ethanol (OCNX9CI)887
45X
42 J3 44
M ' ' 1 ' M^l i . . .| . . , . |i . i , | . ii , f. , M |i . . . -IT42.0 43.0 44.0 45.0
6DB M«than«, oxybis- <9CI>
45V.
42 43 44^ /
• • . . M " . | . . . . M • ' ' 1 • • ' ' 1 ' " ' 1 ' ' ' • 1 ' ' ' • -»"*•42.0 43.0 44.0 4! .0
iL ISS#1£2 Scan5.44 r
546
,„„„„!,„„„"46.0 47.0
Scan0.00 i
46<^ 47
46.0 47.0
Scan0.00
46' 47
102ttiri .
121nin .
-0
376min.
4*i.O 47.0
1. Ethanol (ACN)(9CI)2. Methane, oxybi»- (9CI)
Sample file: >MCP05 Spectrum *>Search *peedt 1 Tilting option: N
Prob. CAS * CON ft ROOT
64173113106
1O2
46 C2H6046 C2H60
K
No. of ion range* searchedt
DK #FL6 TILT '/. CON C_I R.
"BI6DB 28 39"BIGDB 24 62
0 2OO0
7 4218 20
ZSI £OdOW<
Bfi 9S" .1 •.i•. i . i • , 3S Ofi 8t»i....11... i....n. • 11 • • 111
St-
3STOAQ QOB 8HS 89TT
Fil« >MCP05Bpk fib 753
>U-r^43.2
flflECORP 107404 5mL SfiMPLESUB ADD DVC
44/•4-r
3uL ISS#122 Scan 1888 .70 min.
45
43.6 44.0 44.4 44.8 45.2
Sample fil«i >MCPO5 Spectrum *»: 188
No data b««» »ntri«» w«r» r«tri«v«d.
~ >MCP05 flflECORP 107404 5mLOb 2410 SUB ADD
49
jtH-rif
^51 79 ,
\ 1 150 60 70 80
SfiMPLE * 5uL ISS#122 Scan £19OVC 9.38 min.
3
?1 /3
L30/ -
90 100 110 120 130i* PRIPOL Bromochloromttthan* Sc: Ob 9999
49
an 4430 .00 min .
/ 13'?•
fr '1
91 61.- 64 */•,1 ^-. I.I50 60 70 80
91 93
*^"vl,l
/ :
L._J ^O
90 100 110 120 130" i l e >BIGDB n«th»n«, bromochloro- <8CI9CI) Scan:ci fib 9999
49
0" • ' '
/51
_-- 64 65 81
50 60 70 80
139070.00 min.
91 ^ 100 116 120'1 ViU'i i j ! ! , . , , >• \ i jT, 1 i •
130
190 100 110 120 130
1. Bromochlorofflvthan*
!. Methanv, bromochloro- (8CI9CI)
128 C.H2.BR/CL
90128 CH2BrCl
Sampl* -files >MCP05 Spectrum 4»iSearch »p»»di l Tilting optioni N
219No. of ion rang** a*arch*dt
Prob.
96*95»
CAS I
44874973
CON * ROOT DK *FLG TILT % CON C_I R
20613907
PRIPOL"BIODB
108100
S12
O0
9393
66
6868
OHMICS MMLTSIS MM SOT
JMB fclf Li t L/ ratoritt. he. CM* Ml. ___
UNr«ttry II
fctrli
M
tOaK-f
VOUTILEtacMtratittt LM
litt
latt
tec/Mlititt Facttrt.
Nrcttt Itiitvtt Mtt
PHIr
iTirclt fct)
It.
CMtract H.
htt
(Circlt ON)
CM! ICiitlt
7l-<7-3 ! 1.2-ticHlorMf
10041-02-4 I Trm 1.3-ticblvow
rC*»« No
(Sul-T
Organics Analysis Data Shtet(Page 4)
S*mpl« Number
Tentatively Identified Compounds
CASMumbw
1..2..3
10.11.
IS.
Cempew«d Nwnc
"ft1/flA
Hf «» Sc«n
no/he)
35"
ISO
1. 7 I
QUANT REPORT
Quant Rav« 6oerator 10: USER2File: *MCP06::D3
File: >MCP06::L2MAECORP 107405
Use: 5mL SAMPLE » 5uL 155*122
ID File: ID_VDS::U1Title: ID FILE FOR DAILY VOLATILE STANDARDLast Calibration: 870610 14:56
Quant Timat 870610 19:4:Injactad att 670610 19:0'
Dilution Factor: 1.00001
Compound R.T. Scant Araa Cone Unit*
1)9)14)5)30)39)40)
•BROnOCHLOROMETHANEACETONE1 ,2-DlCHLOROETHANE-D4•1,4-01 FLUOROBENZENE•CHLOROBENZENE-05BROMOFLUOROBENZENETOLUENE-08
SSS
SSSSSS
9,7,12,20.252923
,88,34.64.22.08.51.86
219152292492620737588
168131058213871270424645485272182769
504434850504948
.00
.95
.10
.00
.00
.53
.91
PPBPPBPPBTWPPBPPB ,PPB 97PPB<?*
* Compound is ISTO
r;r"'.:
TOTPL ION CHROHPTOSRPnfilm >MCP06 40.0-260.0 MU. HRECORP 107405 BaL SRHPLE * QuL
32000-
88000-
84000-
80000-
16000-
18000-
8000-
400O-
4 ' k ' S ^ 16 ' 80 ' 8'4 '^8 ' 38 ' 36 '
Data File: X1CP06::L2Name: MAECORP 107405Misc: 5mL SAMPLE * 5uL ISS*122
Quant Output File: AMCP06::D3
Id Tile: ID_UOS::U1T i t l e : ID FILE FOR DAILY VOLATILE STANDARDLast Calibration: 070610 14:58
Operator ID: USER2Quant Time: 870610 19:43Injected at: 870610 19:04
REFERENCE STRNOPRO SPECTRUMfl 1Bpk
• >YBRb 2
~
2000-
>
933 (732
43•v.
42\
42
KETONE 860983 12i91SUB
87\
44 46 48 60 82 84 96
Scan10.26
89
4-
816• in.
•1001
0
SPtlPLE SPECTRUM <BPCK6ROUNO SUBTRPCTEO)FU« >MCP06 MRECORP 107409Bpk Pb 6592
43
8PMPLE SPECTRUM CUNPLTCRCD)fil« >MCP06 MRECORP 107409Bpk Pb 8592
43
5000-
0- . , . , . , . . . , . ,
42\
'"'
44/\
48 ' 44 ' 46 '
9«L SRMPLE * 9uL ISS#122
87\
48 ' ^0 ' B'2 ' ^4 ' ^6 '
Scan IBS7.34 Bin.
88j1 .
•100
,
-O88 '
Data F i l e : >MCP06::L2Name: MAECORP 107405Mtsc: 5mL SAMPLE * 5uL ISS#122Quant Time: 870610 19:43I n j e c t e d at: 870610 19:04
Compound No: 8Compound Name: ACETONEScan Number: 152Retention Time: 7.34 min.Quant Ion: 42.8Area: 105821Concentration: 443.95 PPBq-value: 96
Quant Output F i l e :
Quant ID File: ID_UDS::U1Last C a l i b r a t i o n : 870610 14:58
,. 1 «.? hr-*rj»?r f r om
,.,,_>(. ,:L|F,P tM/405 Operator: USER2 MS"•-i. ::A:-1f-'LF-: » 5ul_ ISSK122
'•1? nu'dpl : ^6 5W/HW rev.: IA ALS # : 01 • : ! < > : JOHN Tuning -file: TUNE3 No. o-f e::tr<a records:tf'rr>f.: lr".O Analvrer temp.: 1^0 Transfer line3 t"?mp. :
ir'-Mr 31-""jr phi c temperatures : 45. 220. 0. O. •'.hr .>ma*: ogr<?phi c times, mm. : 3.O 20.0 0.0 0.0 O.hroin^toqr.sphi c r^te, deq/min: 8.O 0.0 O.O 0.0 0.
MAECORP 107405 5mL SAMPLE + 5uL ISS*»122• 260.0 ADC TIC^: . 21' Area Re.iect: 2.00 "/. Max Pe^ks: 7 Bunching:
Results File VDIR86 Sorted by Time/Area INT
6/IO/87 lc':'"-4
R . 7 .mi n .
2.67^.44T. 34i:3 . 66
9. RO
•f i r ? t
14
lrJ2
214
•/. o-f
1729102J52187
219230
38130166205
226236
4227258951104432334
1O665732
156549377597148939343580
80506367170
338192
21.93100.0038.7272.12
115838 P. 13914\ (S 31.038199 797200% 2.17
12.930.7
10.3
Sum of corrected arras: 1101088.
9:52 AM THU., 11 JUNE, 1987
MCP'^. 40 0-2^0 j amu nP-CCdftP 10740? 5»»L SPMPLE + 5uL 1^5*12,flDC TIC
,•-!<>-
JOO-
000-
0 0 0~
0 0 0-
J 0 0-
• j o •>
40 30 120 160 200 240, ! , , , 1 , , 1 1 1 , 1 1 , 1 . , . 1 1 1 1 1 1 1 1 I .._L. 1 1 1 ..!_.!_ _1 _L_ 1 1 1 1 1 —— 1 —— L__l ——— 1 —— L__
513
1f,i'i 2I I
^ \ A•-:-o^ .V , )
i1t
1 •... | \.
-J "^- .. . .. . ... ....... .Trr*.-"— -x^__J ..
1
i111
1
6
'l
'\ J; i 7c . v ?.0 4.0 5.0 6.0 7.0 8.0 ?.0 10.0 11.0
I
J 4.
5rnL E-PflPLESUB HDD DVC
44
4.3
4 3 . £ 43.6 4 4 . 0 4 4 . 4 4 4 . 3
?«?sP««mf3pB|(pSp»* "**.
Sample -filei >MCP06 Spectrum *: 17
No data base entries were retrieved.
vj(D*
vjuOxlO
MNlNl
=t-tOoOf
~J)1oa•
n(0
*
noz*
aa-i
T 3n "o3" «-*aMTJ -».a £a «M M
*• V3n•oo
HM->-•ft1 U)H-T33 «o n
rt-0 1D Cn- 9**•0 *3 ~••
•
nIDrt-0*1-"aIDT>^
aID* »ooH« >
*-fc
0)n1-4
*Qnt-t^^
z >oo
•n0 5o-f.M-
O
o r
M xN
noo z
nu I
1n
a
nro
CPF 4 ;•ue
5uL
45
4 344
,J4=' .0
<L t h armi • CHIN,- i;?
C 4H 'Jc'5.44 m i ' - , .
47-L-fi
4,1 .0 4 ? . 0 44.0 45.0 46.0 47.0
3 c a n lil0 . 0 0 w l n .
4c'————— , ——— ————— rT_r_j
43 44
————— 1 ——— , | . i . , | , . . ,
46^ 4?
i l i i M i i i j ' i44.0
c' I L-< D E^
-I
4I
•4,1. :>
9C1 '
44.0 45 .0 46.0
scan 3760.00 min.
47.0
fithamol (ACN) < 9 C t )Mfthane, oxybis- <9CI>
46 C2H6046 C2H60
file: >MCPO6 Spectrum *:vpeedt 1 Tilting optiont N
1O2No. o-f ion range* searchedi
1.
Prob.
70#52*
CAB * COM
6417S115106
121376
ROOT
"BIGDB"BIGDB
K
2824
DK »»FLQ TILT V. CON C_I R
3962
00
0 1920 85
816
4220
"•MCP06Mb £££72
J",42
- .-eiGoe•_ _ 3b 9999
: 42o- Vi
42
rlftECOPP 107405SUB
45X
42 I3 44 46' \ S" f
44 46 48
5mL SfiMPLE + 5uLftDO DVC
53/
50 52 54
2-Propanol <flCNX9CI>
45
4^ 44 46
• 1 ' 1 • ' M 1 ' 1 ' 144 46 48 50 ' 52 ' 54
ISS#122 Scan 1873 .66 rn in .
57 58 59 i
56 58 60
Scan 3260.00 win.
55 56 57 58 5960 '.( { ( i 1 V I '?
56 58 60
. 2-Propanol <ACN)(9CI) 60 C3H80
Sample file: >MCPO6 Spectrum #: 187Search speed: 1 Tilting option: N No. o-f ion range* searched:
Prob.
1. 88*CAS * CON ft ROOT K DK #FL8 TILT X CON «..,! F
67630 326 "B1QDB 41 26 0 0 76 3 .»S
C*»» Mo. __
QC R»0ort *o
Contract Ho.
Ditt 5*«clt
VOLATILE CtWOUWSICirclf On»)
Ditp
Coic/Ci lut ion Factor:_
?: (Not
M)/l or if/ifWS I ICirele On*)
> ii i
74-87-J ! Chloroittlianf
7 4 - « 3 - - > ' ProWl^t
7 * -0 ! -< ' V inv ! CM 0' lie
" ^-; ; rvnrwthw
r--"--? »!hr!«-i» OloriO
^ • i i f f f t f ^ f
r ' ' •' ••• - -.-,!',;).
' r ' ! - r -i» fc h n g,
1 ' >. , < -,^,n, ,.,p
,..,....,.; -.i:,,ofo.»fcw
• r ' '!rro(nr«
• • * - ? 1,2-Oithlnr^M.
7B-93-3 2-Bul.W»
71-33-4 l.l.l-Tnehl»-o»th«n»
34-23-3 Carbon T^trtchlofilf
108-^3-4 Vinyl A«Ut»
75-27-4 trotodichlorowthant
JiPJi
4 I< 1
t ,
/O ~ 8 7
C-5 Ji.
COS iuf/1 oriCirclt On»)
11
78-87-3
10041-02-6
79-01-6
12MB-1
77-OC-5
71-43-?
10WI-0]-r,
nci-n-p
73-K-2
391-73-4
1WMO-!
127-n-i
79-J«-3
|ft|!-^-3
|f.fi_!"i-7
•,oo-«i-«
KXK42-3
1
I1
1.2-Dtchloroprown* !
Trint 1.3-Dichloroprog'nt
Trichlorofthw*
Dibro«Khlx(M(th4flf
l,l,2-Tnchloro«t|jM
Bf^lM't
'•;^-|,7-nic*loro«r8Hnf
7 r>!i~r*thYlvinyl|th»f
?ro»;«!5f»
<-^»lKyl-2-Pint»noiit
2-Hfi»noo»
T»tr*chloro*thm
!.l,2,2,-Trtr«hlorofth«nt
TolOfM
Chloro^mtfnt
F.tHrl|t«iw»
StrrtM
! Total Irlmn !
IQUANT PEPQPT
Quan t P«?v: 6
L ISS*122
Quan t TimnInjected at
Di 1ut ion Fac tor
OFU (1:5 DILUTION)
" : : 'J 1fro DAILY 'JOLATILE STANDARD
nn - P 7 0 6 1 0 14:50
R . T . Scan* Area
' • 1Q• . --I'"}
- /- /-
. '" n 'i o o
Uni ts
f'M'
•CHLOPOBENZENE-D5
f f
t; THftNE
FTHONE-D4 SSSprhlTFNFE-D5ENZF.NE SSS
?ss
971220252923
.88
.34
.64
.22
.04
.51
.96
219152292492619737580
160432516837430683406223852025816^7
50.110.49.50.50.50.50.
00657300007003
PPBPPBPPB'PPBPPBPPBPPB
S7
ID/|00
TOTOL ION CHPOnaTOQRPtt40,0-360.0
200TIC400
1»L SPHPUt * BuL ISJ
600 800 ,
Data F i l e t >MCP09s:Ue Quant Output F i l a t ~MCP09::D3Nanr.e: MAECORP 107405Misc: ImL SAMPLE * 5uL ISStl22 * 4ml OFU (1:5 DILUTION)
Id Fila: ID_UDS::U1T i t l ^ i ID FILE FOR DAILY UOLATILE STANDARDLast Calibration: 670610 14:58
Operator ID: USER2Quant Time: 870610 22:00Injected at: 870610 21:22
-.4-
REFERENCE STPNOPRO SPECTRUMFi;« >YB923 PCETOME 860983 18i51 Scan 816Bf>k Rb 2738 SUi 10.86 mln.
43~
2000-
frt
48
C8
'
98• 9 w
/ I' 44 ' ' ' 46 ' ' ' 48 ' ' J 50 ' ' ' 6"a ' ' ' 8*4 ' ' ' 5*6 ' 88
t-100
'
•0
SPflPLE $?CCTRUri <BPCKBftOUNO SUBTRACTED?>ncP09 rmccoRp 107409
Bpk at> 194843
800CH
let SMtPLC * 0uL ISSMJKsue Scan 1587.34 »tn.
^
SflHPLC SPCCTMJH <UMfltTt»CO>m« >ncf>09 nflccoRp 107406 i8pk Pr 1948
438000-
- 48
0-^-r-, . , . , .
r
44
f48 44 44 48
•L <ANPLC * 9uL 158*188 Sc«n 1987.34 *iA.
r9*0 ' 88 ' 9I4 ' S'6 ' 8*8
Data F i l e : >MCP09»:L2 Quant Output File: ys«CP09::D3Name' MAECORP 107405Miac: ImL SAMPLE * 5uL ISSfl?2 * 4ml OFW (1:5 DILUTION)Quant Time: £70610 22:00 Quant 10 File: ID_UDSi:UlInjected at: 870610 21:22 Last Calibration: 070610 14:58
Compound No: 8Compound Name: ACETONEScan Number: 152Retention Time: 7.34 min.Quant Ion: 42.8Area: 25168Concentration: 110.65 PPBq-value: 97
OPS/MI ICS AKW.Y5!!; ?•'"• " "l '
,j^JtyiM, Inc. Cn- *".___
QC »»0ort lo..
Contract do,
Oitt
VOLflTIJLL COHPOWIOS(Lw 0 fluliut ICircl*
~% 7-
C o n c / D i l u t i o n F«tor! JH.
Noiiturf: (Hot D«int*<)
ICirclt
,,.,,.. : rjnoro^thw,
7J,nv, ; 8ro.wfhMf
7 ' i -01 -< ,' " 'dyl Chlorjlf
" n"1-'. 1 CMoroftlUnf
'* f!?-? : "»fhykn» CMorid*
"• ' • ' • * • - ' ! V f t no •
; ' " i 1 r..«rt)(xi SifuHidf
!V« 1 I, j-DicnlorotthMf
"-M-3 1 l,l-Dichlorottli«Mi
!54-M>-5 ; Tr«fti-},2-DicMorottNMf
6/~W*3 I QtlOf 9^0Tlii
107-04-2 ! 1.2-DichloriMthwitl
71-73-3 i 2-tatmmtl
71-39-6 ' 1.1.1-TricMorMtHwr1
M-23-3 ! C^rbow TrtncMoritft*
IW-05-4 ! Vinyl fcititti
79-27-4 ! IriMOdiclilgrowtlKiiff1
(10
(10
(10
(10
< 5
jtwD.(.
< 5
< 3
( 5
( 3
< 3
< 3
(10
< 3
< 3
(10ll
< 3
CflS 1i
78-87-5
IOMJ-02-4
77-01-4
!24-«8-l
77-00-5
7MJ-2
-0,-b
no-Tt-e
75-23-2
371-78-4
108-20-1
127-18-4
77-34-3
lOfr-W-3
10»-tO-7
100-4H
100-42-31t
1,2-Dichlorooropint
Tranj 1,3-OichlorogroiMf
TncMoroftliW
DibrowtMorunthwf
1,1,2-lnchlorotthMl
taZfflf
cii-I.MicMar«roMM
2-CMorotthrlri«vlfthfr
Irotofari
*™flJW Vl 'Z'rWI'fnlOM
2-*f»«mw
Tttr«cHloroetlMii
1 . 1 .2.2.- Tf trial or otthMt
TollfM
DdarofefniMff
Ethyl IMZIM
StrriMl
rclt On»)
( 5
( 5
( 3
< 5
( 3
< 3
< 3
< 3
(10
(10
< 3
< 3
( 3
< 3
< 3
< 3
Trt-1
Organics Analysii Data Shurt(Page 4)
Tentatively identified Compounds
. ,
CV.Compound N»m« Fraction
VOA
• n t '
3V30
(90
Voft
7•9
1C11
1?
IT
14
! 7 '
37
n
7 8S
QUANT REPORT
Quant 9ev: 6ID: USEP21 " : ^hCPO?: :D3
>MCP07::L2107406
» 5uL ISStl22
Pile: ID_UDS::U1ie: ID FILE FOR DAILY UOLATILE STANDARD
-. t C a l i b r a t i o n : 870610 14:58
Quant Time: 8706Injected at: (3706
D i l u t ion Factor:
Compound R.T. Scant Area
10 20:210 19:41. OHOO
•am* _• ACETONE. • *.•.-..;.•-1,2-oicHLOiwef..•1,4-orPLOOROBEN^•CHLOROBENZENE-09BROMOFLUOROBENZENE
' TOLUENE-08
Compound is ISTD
Cone Units
SSSSSS
29.5023.85
737588
5192882591
1.0050.0850.09
PPBppgtOO
'CTRL ION
Data File: >MCP07::L2Name: HAECORP 107406
SAMPLE * 5uL ISStl22
Quant Output File: *MCP07::D3
Id File: ID_UDS::U1T!tM: ID FILE FOR DAILY VOLATILE STANDARDLast 'alibration; 970610 14:58
Operator ID: USER2Quant Tjme: 870610 20:26Injected at: 870610 19:47
!• .>yr,ir;> M..I Scan 315( Kf. V Mr ,J ' c1
j IP1 -) ''.
I 42
>UU iV .Cr> Bin.
[-100
37 39 1
N ' L44 46 40 BO 32 54 56 58
SPECTRUM 'BPCfeROUND SUBTRPCTEO)f i i * >1CPC7 HPECORP 107406 3»L SflHPLE » 3uL ISS0122 Se*n 153Opt Pb 31634 SIB 7.33 min.
43-
30000--41 *?
' j
'
44 57 8f/ 93 58 v ^' I f \ \ .
-100
-043 44 46 48 CO 52 54 56 68
SPHPLE SPECTRUM (UNflLTERED)Ti !• >MCP07 MOECORP 107406 5«L SfiflPLE * 5uL ISS0122 Sc«n 152Ppk Ob 31634 7.33 «ln.
43-
30000--41 4?
/ /
'
44 57 Sfl/ 13 <SG ^ ^' / / N 1
-100
LO' ) " ! ' ) * i " i " i " i ' T " i " i " r " i " j " i " r ' i " i ' i42 44 46 40 90 52 54 56 50
Data File: >MCP07::L2N-5me: MAECORP 107406Mi5C: 5mL SAMPLE * 5uL ISS*122Quant Time: 870610 20:26Injected at: 870610 19:47
Compound No: 8Compound Name: ACETONEncfln Number: 152detention Time: 7.3? min.Quant Ion: 42.8Area: 382934Concentration: 1637.09 PPBq-va1ue: 96
Quant Output File: /NMCP07::D3
Quant ID File: IO_UDS::U1Last Calibration: 870610 14:58
-. t Ml" h«">.io'f-r from : MCP'.'7
M<»! LUr-'r I'.>74'.>6 Operator: L'SER2 MS':-n>. ''.riMM. £ <• i:..il_ 155*122
M'~> model: 96 SW/HW rev.: IA ALS * : 0H Mlr: JOHN Tuning file: TLJNE3 No. of e:-tra records:f^np.: !'JO Analyser temp.: 180 Transfer line? temp. :
c temperatures : 45.1 .hr-.-m.*t oqraphi c times, min. : 3.0Chr m^hographic ratf*, deg/min: 8.0
22O.20. 00.0
<:». o0. 0
O. 00. 0
mL SAMPLE 5uL ISSW122"T'O;* MAECORP 1O7406•K'.'~'' 2(SO.O ADC FIG3lon»: .^O Area Reject: 2.00 7. Max Peaks: 8 Bunching: 1'•slope: O.-I'O Results File VDIR86 Sorted by Time/Area I NT
• \- R'. T. f irstmin. scan
2 . :: i 145.43 917. ;v: i<i4H. .->3 i«;'-'. •?•:• ;:i4
0.:?? 226::.o; :96J . «:>'T 325
ma:r
17102152td7220
2 ""9292329
lastscan
28117172201226
235300335
peakhei ght
70792227144«-»654 I96010944
jci!95171034
rawarea
133537311789540104447761 t f306 1
219259998612739
corr. <area 7.
76660300138527368HSL435192IT137071<S
132619880B5S11830
zorr .ma;: .
14.5456.91100.0082.5221.56
3.4618.742.24
Sum o-f corrected 1581958.
10:20 AM THU., 11 JUNE, 1987
0.0-£60.0 »mu.fiDC TIC
??.-4
440 0 0-
40000-
36C-OC-
35000-
•2SOOO-
£4000;
20000;
1*000-
12000-
3000-
.000-
a
•
1 Ia. i
}< I
t
V. _ I
4
uVj ^i /> ! I 3
S I A I I
Qb
40041
SmL SfltlPLE + 5uL ISS#i22SUB ODD OVC
44
43
:l r, in
41.2 41.« 42.0 4 .4 42.8 43.2 43.6 44.0 44.4 44.3
Sample filei >MCP07 Spectrum 17
No data base entries were retrieved.
ML• D 1
-
,-J
•<::• •
'>
•eiQb •:
-1
(V
F 0 ,' f1 * e 3
41, 4 .-' ,"'
42
y&r
42
• l" •42
GOB) 0 w Ci
42
42
wF<; jRF
41:
. "' 44f
44
4
4J 44
u —— f-^-44
^
43 44
44
107406 5n,L 'SAMPLE * 5'j.L IS'I-.#122 :••: in 1 02SUB ADD DVC 5.4.: r» i r> .
;b
47 5:? t---L, ,
46 4;3 50 52 54 '^ 58
0 . 0 0 'ii i fi .5
f'' 47 48 t'i f* , L-OF • i • i • i • i • i ' i ' i • i • i • i • I • r J
46 4e 50 52 54 56 58
H*tharifc, oxybi*- '. 9C I ) Scan 3760.00 in in.
5
46 T47 4S :
46 43 50 52 54 56 58
Ethanol (ACN)(9CI)tlBth«n», oxybi»- (9CI)
46 C2H6046 C2H60
Sample file: >MCP07 Spectrum 1»:Search speed: 1 Tilting option: N
1O2No. of ion range* searched:
Prob. CAS ft CON ft ROOT K DK #FLQ TILT X CON C_I R
1. 70#52*
64173115106
121376
"BIGDB"BI6DB
2424
4362
00
0 1810 BO
917
4220
* MCP07 tlflECOPP 107. tfb £5053
45x'
41 42 i5 44 46-%. ."'' : * I f" /
42 44 46
SUB fiOC DVC " 8 ".65*
57 56 5«
137it i n .
43 50 52 54 56 5% 60
1* ,-BIGDB 2-Prop»nol <flCNX9CI> Sc *n<• Pb 9999 0.00
45
] •»£ 4^ 44 46 55 56 57 53 5%0•J "* 1 " " • » • " " / / / / / x-s
42 44 46
326mm .
•
-ft49 50 52 54 56 58 60
1. 2-Propanol <ACN>(9CI> 6O C3H80
Sample -filBi >MCPO7 Spvctrum #i5<?arch *p««d> i Tilting options N
187No. of ion r«ng«m ••archvdt
Prob.
1. 88*CAS ft CON # ROOT K DK *FLG TILT X CON C_I
67630 326 "BIQDB 41 26 0 0 81 3 65
.!=/
-i fKPC-r HfiECORP 107406 5mL3b 433 SUB fiDD
4ci_
0-
41 "43 45^ 44 /1 ?' 1
42 44 46 48 50
SfiMPLE + 5uL ISS#122 Scan ££?DVC 10.55 min.
59-
57 59i i
.;to
52 54 56 58 60:* :BI6DB 1-Propanol <ftCNX9CI) Scan 127
fib 10594£
"1 43 ,_j ^ 44 ^ 46
42 44 46 48 50
0.00 min.59' 60 ,
55 56 '7 58
1 i | i l ' \ i \ i ( i 1 ' 1 i • . -
^Fit52 54 56 58 60
le >BIGDB l-Prop«ne, 2-fluoro- <9CI) Scan 18451 fib 9999
-
<y4£ 45 44 45 46
^ -•• ( **
42 44 46 43 50
:* -'BIGOB l-Prop«n«, 3-fflb 9999
0-4£ 43 44 45 46 47 48 49 50
•-- "-.. ^ s^ S S S S f—i — l — ' — i — i — i — i — — i — i — i — i — i — r— • — 1 — r — i —i i i | | i • i • i • i42 44 46 48 50
0.00 min.59
• . .--- -• vt**i™- / . _' 6055 56 5/ 381 ' ' '
N -•
-052 54 56 58 60
luoro- <9CI> Scan 1*430.00 min.59
51 52 55 56 '/ 58' 1 ' ' ' f
•
--052 54 56 58 60
1. 1-Propanol (ACN)(9CI)2. 1-Propene, 2-fluoro- (9CI>'*. 1-Propene, 3—fluoro- <9CI)
60 C3H8060 C3H5F6O C3H5F
Sample filei >MCP07 Spectrum #: 229Search speeds 1 Tilting optioni N No. of ion range* searchedi
1.2.
Prob.70»20*20*
CAS * CON *
712381184607818928
12718431843
ROOT
"BIQDB"BIQDB"BIQDB
322323
DK *FLG TILT X CON C_I
41 167 269 2
00O
7808274
75253
4233
*«vq
88 fS
j|j''~~J SS
•UIMJ frO't-T
06 9<i "Zf. 89 t»9 09 9S 36 8t» t't'1 ' 'X Si
8fi
DAQ coo ans
t*^, r
Ct-tTE qn ^
JJJM8aaaa»MlMilllill'«
OPttMllCS AMUSIS MT« SHEET
e,)M Cn^it UhorjtoriM. Inc. CJM Ho. ___
j » r ; r
K Rtaort Ko..
Contract No.
Dttt Sa*li ftictivri.
VOLATJLLCMPOWBSConcmtntson: C"' LoO
Date
Cone/Dilation Factorr_
Prrctnt Koiiturn (Not
ig/tfOnt)
1
74-87-3
74-83-9
73-01-4
^
73-07-2
7-4M
1-13-0
3-35-<
1-34-3
•4-40-5
S7-44-3
'07-04-2
78-73-3
71-53-4
34-23-S
I09-4S-4
73-27-4
Chlorowthinr
Brototrthanf
Vinyl Chlondi
Qi'orofftluiiff
frthylmt Ch'orifc
/n;/V>/*c»ton» / Jx uC
U-licMorottMM
1 l.l-Oichlorofthaafti
! Trani-1.2-D1cklaroftkifti! Oil or of or •
i 1.2-DichlarottkaM11 2-lutammi
! 1.1.1-TrickloroothantI! Carton Tttrartlorife•i! Vidvl Acttatt1i ar(K-4fcklqrojittkaM!
COS t
(Circlt Ont)
ui/1 or ug/i;tCirclf Ont)
7B-87-3
10061-02-6
77-01-6
124-4I-!
77-00-5
71-43-*
10041-01-3
110-73-9
73-23-2
371-78-4
10t-10-!
127-18-4
77-34-5
10I-K-3
10i-70-7
100-41-4
1 100-42-9!!
I1.2-JkhloroproMfli !
Trim 1.3-0ich3orooroflt»«
TrichlorocthMf
OlbroMckloroMthint
1.1.2-TrichlorNtfeiM
ImztN
cii-1.3-B:cklorotr«imt
2-ttIorMthvlviiivlftlMr
IroMfora
4-Mkvl-2-PMtanoM
2-f(fianont
Tttradilorotthttt
1 . 1 .2.2.-TfftrKklorMtkMff
Tel MM
CklorofemziM
EthflbMZMf
StVTH*
Total 1*1 MM!J
QUANT REPORT
Quant Rev: 6-;- ID: UBL92ri ]*• ~r-!CP10: :D3
i !-: >MCP10: : L2noECORP 10740625Qul o* SAMPLE * 5u I ISS *122 * 4.75ml OFW
Quant TimeIn jected at
D i l u t ion Factor
870610 22:41970^10 22:0'
1.OOOOt
: ID FILE FOP DAILY UOLATILE STANDARDCalibration: 870610 14:58
Compound R.T. Scant Area Lone Units
BROMOCHLOROME7HANEACETONE1 , 2- D I CHLOROETHANE-041 ,4-DIFLUOROBENZENECHLOPOBENZENE-D58ROMOFLUOROBENZENETOLUFMF-OR
SSS
ssssss
9712202l>2923
.90
.36
.67
.21
. 06
.55
.88
220153292492620738589
16139172327714168658635945295003095
50754650505049
.00
.31
.07
.00
.00
.50
.83
PPBPPBPPBPPBPPBPPBPPB
<%
(01100
ompound i^ ISTD
iON C!» >"CP19 40.0-360.0 AMU. F1PECORP 107406
TIC
aeooo-
34000-
20000-
16000-
13000-
6000-
4000-
230ul of SRnPLt *300 300 400 800 fepO 7pO 800
J
8.1.
Data File: >MCP10::L2Name: MAECORP 107406Misc: 250ul of SAMPLE * 5ul ISS #122
Quant Output File: *MCP10::D3
4.75ml OFU
Id File: ID_UDS: :U1T i t l e : ID FILE FOR DAILY VOLATILE STANDARDLast Calibration: 870610 14:58
Operator ID: USER2Quant Time: 870610 22:40Injected at: 870610 22:0?
pp r-ww
GPECTRUH' . \ " • • , " • » * ' ( OCr.TO«r. 860933 18l81 Sc*n 213-- i: (•:•< .-.*.•>? SUB 10.26 »ln .
~
r. oo OH
0-4
4?
\
88
/'I12 ' 44 ' 46 ' 4'e ' 80 ' 82 ' 8*4 ' 86 ' 68
hlOO
-0
(OPCKCROUMO SUBTRRCTED)F i l eBpk
1
>HCP10 nPECORP 107406Ob 1369
43
?00-
o-, . , , , . , . . , ,43
(44
43 44 46
aSOul of SPhPUE + 8ul ISS Scan 133SUB 7.36 nin.
-100
48 ' 8"0 ' rfa ' «J4 ' B1* ' 8*9SflMPLE SPECTRUM <UNRLTERED>n iBpb
•• >nCP10 MRECORP 107406 aSOul o>- SPMPUE + 5ul 1SS Se»n 1B3Rb 1369 7.36 mln .
43•i
100CH
CH
'
42
,x44
I[-100
-0*? 44 46 48 5"0 82 ^4 56 8fl
^i F i l e : >MCP10:=L2 Quant Output File:-.; M^ECORP 107406
MI-.C: 2^0ul of SAMPLE * 5u 1 ISS t!22 * 4.75rrl C1FUQuint Tim's: 970610 22:40 Quant ID File: ID_UDS::U1I n j e c t e d at: 8706JLO 22:05 Last. Calibration: 970610 14:58
Compound No: 8Compound Name: ACETONEScan Number: 153Retention Time: 7.36 min.Quent Ion: 42.9Area: 17232Concentration: 75.31 PPBq-va!ue: 92
W6AKICS ANALYSIS DATA SKIT
Hut fril> Coait Laborttorm. Inc. Caw Bo.__
Likoralory !' No. >/v\CR(2>^________ OC Itoort lo..
CUofer Contract to.
D*ti Author urt §y. Dati SMplt Rtcmtfl'.
CA5 t
Concentration:
Date EitractfflVPreparHi
Date Analyzed:_____
ICirclt Ont)
Cone/Oil«tion Factor: Ji.
Percent Noiiturti (Not Decanted)
ICi clf One) _
74-87-3
74-83-9
75-01-4
75-00-3
75-09 2
47-44-1
73-15-0
73-35-4
75-34-3
154-60-5
47-6*-3
! 107-04-2!! 7I-W-3!.' 71-35-41
> 54-23-3
! 108-03-4
! 75-27-4iiii
DuoroMthani
Irooonthanf
Vinyl Chlorirf*
Chloroctkant
Nfthylwe Chloride
Acctont
Carbon Oiwlfidt
1,1-OicMorottkMt
lil-DichlorottkaN
Trani-1.2-OicHlorwtnffnt
Chlorfforo
1.2-NcklaroftlMM
2-luttMMt
1.1.1-TricblorottNant
Carbon Tttractiloritft
Vinvl Acttati
Irooodickloroottkant
(10
<10
<10
<10
< 5
jMO-0.1
< 5
< 3
< 3
< 5
< 3
< 3
<10
< 3
< 3
<10
< 3
!
CA5Li]/])or uf/k(Circle Ont
78-97-5
10061-M>2-4
79-01-4
124-48-1
7?-00-5
7I-4J-2
10061-01-5
1KH7M
75-25-2
591-7B-4
108-10-1
127-11-4
7t-J4-3
10MI-3
10MO-7
IOM1-4
100-42-3
1.2-DichloroprONnf
Trans 1.3-Dichlorooroiwt
Trjchloro»thf«»
DibroMchloroMthant
1.1.2-Trichloroftliani
Itnitnt
cii-1 .3-BichloroDroMHf
2-OilorotthflnMltth*r
•Votofori
4-NttbvI-2-fMtaiMM
2-Hnanont
TttrackloroftlMN
I . l •2*2rTttricM orettlwui
TolMM
OllVitMZMt
EthvIbMZHM
StvrtM
1 Total IvlMH
< 5
< 5
< 3
< S
< 5
< 5
< 5
<10
< 5
<10
(10
{ s
< g
< 5
< 3
< S
< 5
L<13
C»»» NoN«/mb«f
Organic* Analysis Data Shaat
Tentatively ld*ntHi«d Compounds
CMCompewntfMwM
Eftimti*
\JOt\UOA
L VGA 64VOAVCAVGA H.OV
10.11.
18.1*.17.
99
Ii
I
QUANT REPORT
•rat or ID: USER2put File: ~MCP08::D3« File: >MCP08::L2-.s: MrtECORP 107407c: 5mL SAMPLE * 5uL 155*122
Quant Rev: 6 Quant Time:In jected at:
Dilut ion Factor:
870610 21:0)870610 20:2
1.0000
File: ID_UDS::U1le: ID FILE FOR DAILYt Calibration: 870610
Compound
VOLATILE14:58
STANDARD
R.T. Scan* Area Cone Units
•
**
BROMOCHLOROMETHANEACETONE1 ,2-DICHLOROETHANE-D41 , 4 - D I FLUOROBENZENECHLOROBENZENE-D5BROMOFLUOROBENZENETOLUENE-08
SSS
SSSSSS
9.7.12.20.25.29.23.
88346422085186
219152292492620737588
162665886483846468703601654872180298
50.2552.49.50.50.49.50.
00593900001190
PPBPPB™PPBPPBPPBPPB • »PPB (Do)
Compound is ISTD
L
«o o3 C TJ<-. a a9 3 1o •» a«-» iO H OQ. - T
a a —
( D O C\l MO)OOP]<K» JJ»-» h* NJ
10 roO f
is) o
r H «n ~ a(* rt--^ ~ -n
a —n •• —a a^— i-^ ••- Ocr ^T -n oa «|~ r c- moO (/)3 -n ••
CO l->\JO
o -c
Ml00
2 Z O- Ql ttO 3 ~n a a
vn 3 -3 3> -r m ao ••en oi> TO *3 TJ3-o n
M COO\j 10
enui
IO
rmU)
ZO
o
OC<-r-oC
•n>-•
o
n
*
»-
ro"
S-
s-
2-
r\>_<D
uro"
M rx> u> * 01 o>> -jo o o o o o oo o o o o o oo o o o o o o
?. . . . ? t . . .9. . . .? . . . ,? . . . .9. . . .9. . . . • ? . . .
^—-fr~
*
^ SURROa»TE
. — 1.4-aFUJO)tOBNZE>C
: »• ——— SURROGATE=*—— ——— CKOROBDCDC-Ofl
^==— SUWOQME
i^••^r-oo00
co1
-o S0
c
± 01*-o r0 c
e•vC
•OO
ar0)X
• 3
* sai
-ioD
jOzr>X
oD
Oa>s3
oCO
r
.TPNDPRO SPECTRUMr i 1« >ve^£3Bpk Ob £73?.
43'1 x
200C--t ',
^ J ' - ™
^
PCETONE 860923 12t81 ScanSUB 10.26
87 88\
44 ' 46 ' 48 ' 80 ' 82 ' 84 ' 36 SB ' &
213• in.
kioo
KJJ
PHPLE (BPCKBROUND SUBTRRCTEO)F i l « >nCP'.a HRECORP 107407Bpk Pb 49'j»,6
43-
4000O-"^
^l
42\
44\
42 44 46 48
SaL SPnPLC *SUB
82 83\ \
"sV ' 'rfe' '
SuL I3Stl22
88
84 ' 86
7
87 5(/ r' 88
Scan IB.?.34 »in.
9 g^
jL1-100
•O60
SfttlPLE SPf. CTRUtl <UNPLTEREO)r i l « >MCP08 MPECORP 107407Qp* Pb 49036
43, "v
40000-' 42- \
0- -,. -jL,-, . , . , . , , , .
44
\
42 44 46 48
3«L SPMPLE + SuL
82 83
\\.I ' I ' F ' T ' T T '80 82 84
ISS#122 Scan 182
88/
36
7.34 Mln.
hi 00
87 58 89/I / .88 ' 6*0
Da^fl File: >MCP08::L2Nflrr,-: MAECORP 107407M.-.c: 5mL SAMPLE * 5uL ISS#122Qu"r>» Time: 870610 21:08In.—.fed at: 870610 20:29
Compound No: 8Compound Name: ACETONEScan Number: 152Retention Time: 7.34 min.Quant Ion: 42.8Area! 588648Concentration: 2552.59 PPBq-value: 95
Quant Output File: AMCP08::D3
Quant ID File: ID_UDS::U1Last Calibration: 870610 14:58
f i l e? header -from t >MCP03
6/'<:•/87 20-1«: MAECOPP 1074O7 Operator: USER2 MS: 5mL SAMPLE •«• 5uL ISS#122
. f»: 3 MS model: 96 SW/HW rev.: !A ALS # : O'?thod file: JOHN Tuning file: TUNE3 No. of extra records: 2•jrce temp.: 150 Analyzer temp.: ISO Transfer line temp. : 280
Chrcmatographic temperatures : 45. 220. 0.Chromatographic times, min. : 3.0 20. O 0.0Chromatographic rate, deg/min: 8.0 0.0 0.0
O.0.00.0
0.0.00.0
r:08 MAECORP 1074070.0! 260.0 ADC TICi
5mL SAMPLE •»• 5uL ISS*122
DP:pe:
R.mi
2.5.7.?9.9.
1O.t I.12.14.
•
0.
T.n.
o->4. 4L.
40346688
22?A6408
20 Area Reject: 2.00 Results
first maxscan scan
1392145182214
225249286125
171O1152187219
228253292330
00 V. Max Peaks:File VDIR86 Sorted by
lastscan
26119179205225
235263302338
peakheight
86411229268043364 1 010516
1891284895952516
rawarea
1617871851738339973972701 16025
246*7297679917530918
9 Bunching:Time/Area
corr.area
9955517221481 6520 «'3783851 1030"5\ |
205272734797974 S30031
I NT
corr7. max
12.21.
y. too.46.
5 13.
2.~r•-••
S 12.3.
1
•
•
1909003451
5133OO68
y.t
42
Sum of corrected areas:
11:O3-AM THU. , 11
1752858.
JUNE, 1987
1* -MCP0840.0-260.0 amu. MflECQRP 107407ODC TIC
40
5mL SPMPLE
"0000
•L5000-
60000-4
55000-
50000-
45000-
40000-
35000-
iOOOO-
£5000-
1 0 '.' 0 0
5000- '
80 120 160 200 240
3
,J...U
280
5uL ISS#1£
320
.A A3.0 4.0 5.0 60 ?.0 10.0 11.0 1S.O 13.0 14.0 15.0
• f t C P v S PPECOPP 107407 5rv.L SAMPLE + 5uL ISS*122Mb 4i>d SUB ODD DVC
44
': c an 1 73 . i ii rri i n .
4142 43
C41.2 41.6 42.0 42.4 42.8 43.2 43.6 44.0 ' 44 .4 44.8
Sample filet >MCP08 Spectrum *s 17
No data base entries were retrieved.
I
!« 'HCP08 MftECORP'- fib 6492
41 42n. r"' i
42.0
i« :BIGOBt Pb 4887
"•
: 42/
42.0
107407 5mL SPMPLE + 5uL ISSOSUB POD OVC
4^ 441 xj
43.0 ' 44.0 ' 45.
Ethanol <flCNX9CI)
4!
43 44( /
.. I . . . » 1 i i i . l i i i i 1 ..' n i i i i -43.0 44.0 45.
U22 Scar, 1015.40 nun ,
45^ ,
lun0 46.0
Scan 1210.00 mm.
5
46 "/ ;1 •
0 46.0
1. Ethanol (ACN)(9CI) 46 C2H60
Sample filet >MCP08 Spectrum tttSearch «p»«di 1 Tilting optioni N
101No. o-f ion r*ng«« •••rchvdt
Prob.
1. 70#
CAS 4» CON # ROOT K DK #FLQ TILT Y. CON C_I
64175 121 "BIGDB 23 44 1 0 2O4 7 42
:» :MCP08 HPECORP 107407 5mL SAMPLE + 5uLPb £4970 SUB POO DVC
45. xx
j 41 42 -• 44 46 53
42 44 46 48 50 52 541* ,BIGD8 2-Propanol <PCNX9CI)t fib 9999
45
; 42 4^ 44-> "'} ^i
46
42 44 46 48 50 52 54
ISS#122 Scan 1878.66 «< i n .
57 58 59 :
1 ' 1 i "T • T ' 7"' ' 1"°56 53 60
Scar, 3260 .00 min .
55 56 57 58 59&C '.1 f f I / % •
56 58 60
1. 2-Propanol <ACN)(9CI) 60 C3H80
>*mpl» file» >MCP08 Spectrum #:speed: 1 Tilting option: N
187No. of ion ranges searchedi
Prob.
1. 88*
CAS # CON # ROOT K DK #FLQ TILT 7. CON C_I
67630 326 "BIBDB 41 26 0 0 77 3 63
* -MCPOe flOECORP 107407 5ml SflhPLE * 5uL ISS*122 Swb 493 SUB POO OVC 10.
42 '9500-i 41
r -3 ;5 *r*j i ^ i42 ' 44 ' 46 ' 48 ' 50 ' s'a 5*4 ' «fe 53
. 1* >BI60B l-Prop*nol <PCNX9CI> S^ flb 1059 0
42 «
I 43j -v 44 y> 46 55 56 3? g8J ^ -^ t t .{ /
42 44 46 48 50 52 54 56 58
can ii282i2 win .
-r-r O60)c»n 12700 rain.960 ,
J.60r i l « >BIGDB l-Propan«, 2-fluoro- (9CI> Scan 1845tok fib 9999 , ••«»• 0 .OO tiin.
59: - f6^t: 42 43 44 « 46 55 56 57 53 N F« : > > > < x / < { ( \ En
42 44 46 43 50 52 54 56 58• • l i e >BieOB l-Propene, 3-flucro- <9CI> S
3b ?9-?? 0«•«
: 42 43 44 45 46 47 43 49 50 51 52 55 56 57 58• -^ -^ --^ . x ' ^ ' x ' x - x ' / ' / / / / f /
1 • 1 • 1 • 1 • 1 • 1 • 1 • 1 • 1 • 1 ' 1 ' 1 ' 1 ' 1 ' 1 ' 1 '42 44 46 48 50 52 54 56 58
60can 1343.00 mm.5?'60
Xo60
1. 1-Propanol (ACN)(9CI)2. 1-Propene, 2-fluoro- (9CI)3. l-Prop»n«, 3—fluoro- (9CI)
60 C3HSO60 C3H5F60 C3H5F
Sampla -files >MCP08 Spactrum 4»i 22BSearch •pavdi 1 Tilting option: N NO. of ion rang** Marched!
1.
Prob.
70»20»20#
CAS * CON ft ROOT
712381184607818928
12718451843
"BIGDB"BIQDB"BIGDB
322525
DK *FLB TILT CON C_I F
41 167 269 2
0 8480 1000 89
95354
4255
SS3 BOdOW<
fig
•utw fS'TTT»fi
OAQ oob ans80d3U<
1L 8* OOI O T
I~3 NOD X nil
CB 12 80018,, 9C2I SSZ^Ol
tt NOO ft SW3
uoj
«CZ
N tuof^do T lp««d«80d3W< «»TT*
- I
09H23 8C (106) - •;
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6
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9C3T
£
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18 fr8 08 94 ZL 89 fr9 09"'"" " l t l / " " """">"
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18 fr8 08 9«i 3«i 89 fr9 09
1,80't»T OAQ oob ansu*=-S 33T#SSI l ifi + 3HdUbS T"S
94 34 6f frfr. i . i i i . i . i . i . i .
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Cone/tuition Factori.
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•l/MrcltJlBfl
: i! 74-17-3 I
74-13-9
73-01-4
73-00-3
73-Of-2
47-44-1
73-15-0 . Carfcaa
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78-35-4 I 1.1-lidilardrtfcMt
79-34-3 I 1.1-ti
J47-44-3 I
I107-04-2 I 1.2-fictlyntfiajH
I7W3-3 I
J> 1.1.1-TiI
34*23-3 I CarkM Tttriefclvife
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Iran 1.3-DicliloroDrMMt
QUANT REPORT
Quant Rev: 6 Quant Time:Injected at:
D i l u t i o n Factor:
•rator 10: USER2'put File: "t1CPll::D3'a File: >MCP11::L2•ne: MAECORP 107407^c: lOOul of SAMPLE * 9ul ISS #122 * 4.9ml OFU (1:90 DILUTION)
j File: IO_VDS::U1tie: 10 FILE FOR DAILY VOLATILE STANDARDst Calibration: 870610 14:98
870610 23:2<870610 22:4!
1.0000(
Compound R.T. Scant Area Cone Units
30:39;40
•BROMOCHLOROMETHANE.ACETONE1,2-DICHLOROETHANE-D4
•1,4-01FLUOROBENZENE•CHLOROBENZENE-D9BROMOFLUOROBENZENETOLUENE-D8
9.89 219 15999 90.00 PPB••««••
SSS
ssssss
12.6920.2329.0929.9223.87
292492619737988
3794470226692739312284832
7.39*. 152*- -10863" -48. 0149.1490.00 PPB90.00 PPB .49.36 PPB1T49..96 PPB^
" Compound it ISTD
TOTAL ION CHROMRTOORPflFilm >ncpn 40.o-2«o.o **u. HRCCORP 107407
T 1ClOOul Of SRflFLE * Si
20000-26000-24000-28000-20000-10000-16000-14000-12000-10000-6000-
«P? W
1Iij
u £8I isJ! !
|i
|
i 11
to a a« a*
Data File! >MCP1H:L2 Quant Output File: AMCP11::D3Namei MAECORP 107407Misd lOOul of SAMPLE * 5ul ISS #122 * 4.9ml OFU (1:90 OILUTIOl
Id F i l e t ID_UOS::U1Tit lei ID FILE FOR DAILY VOLATILE STANDARDLeet Ca l ibra t ion! 870610 14t98
Operator ID: USER2Quant Time: 870610 23:24In jec ted at: 870610 22:49
REFERENCE STRNOARO SPECTRUMFil« >YB923 RCETONE 8*0923 12l91 Sc*n 219Bpk Rb 2732 SUB 10.26 min.
43•
2000-
0^ ,
42/42
s98
/ 1
klOO•
(
•0•44' ' '4'*' ' '48' ' 'oV ' '&' ' '**' ' '&V ' '&
SPtlPLE SPECTRUM <BACK8ROUND SUBTRPCTED)Til* >MCP11 flPECORP 107407 lOOul of SAMPLE * 9ul 1?Bpk Rb 901 BUB
431000;
900-
Q!42
r
42 ' 4*4 ' 46 ' 4'8 ' 9*0 ' 9> ' ^4 '
S 8c«n 1527.39 »in.r& ' g'8
SRMPLE SPECTRUM (UNPLTEREO)Fll« >MCP11 MPECORP 107407Bpk Pb 901
431000:500: 42
(
I4141
4'8 ' 44 ' '4'*" '
lOOul of SPMPLE * 9ul ISS Se*n 1927.39 aln.
j-100
48 ' rfo ' 9'2 ' 9V ' 9-4 ' 'rfB
Data File: >MCPlls:L2 Quant Output File: *MCPll:tD3Name: MAECORP 107407M J S C : lOOul of SAMPLE * 5ul ISS #122 * 4.9ml OFU (1:50 DILUTIOQuant Time! 870610 23:24 Quant 10 File: ID_UDSt:UlIn jected at: 870610 22»45 Last Calibrationi 87*0610 14t9
Compound Not 8Compound Name: ACETONEScan Number! 152Retention Time: 7.35 min.Quant Ion: 42.8Area: 10863Concentration: 48.01 PPBq-value: 91