SDMS US EPA REGION V -1

SOME IMAGES WITHIN THISDOCUMENT MAY BE ILLEGIBLE

DUE TO BAD SOURCEDOCUMENTS.

GULF COAST LABORATORIES, INC.

2417 Bend St. Unhrtrtity Park, Illinois 60466

Phoow (312) 534-5200 (219)885-7077 (815) !

'

June 29. 1987

Mr. John MatlockMAECORP. IncorporatedPlain & Route 2Westville. IN 46391

Dear Mr. Matlock:

Please find enclosed the analytical reports for yourProject *IN505. P.O.* 21848IN505. They were submitted toftulf Coast Laboratories, Inc. on June 10. 1987. They wereidentified as follows:

GCL*

107402107403107404107405107406107407

IDENTIFICATION

MC-001MC-002MC-003MC-004MC-006MC-007

EffluentEffluentEffluentEffluentEffluentEffluent

SAMPLE DATE

06/04/8706/05/8706/06/8706/07/8706/09/8706/10/87

If you have any questions, please contact ourlaboratories.

Sincerely,

QULF COAST LABORATORIES. INC.

John BoudreauAnalytical Director

JB/kl

Enclosures

V " ' • » ' '•'•-. , ••/ • .. . .' 'i * i frafeli l^yififff T • ' • • ' ' ' ' ' V. ,'rirt^i<^.-'f--^.»>r?'.v.^~-~ / ^•'J:';l^rs*Wn*^*?l!^P5PfR^r^5nPf'?v^"i' *' ' ' ' . . ' ' * "

• ' ' « . ' " • • . - > • ,

/terlfc^Fffc^iL^liii^HHP^P^^

I TO: MAECORP Incorporated DATE1 Plain & Rt. 21 Hestville IN 46391 RE

1 ATTN: Mr. John Matlock

1 • '!*:' ''' MWBMIP^P '1 ^ GCL 9 PARAMETERS ' """HW PlliVPP'l

1 107402 Chromium, Total

1 107402 Lead, Total

1 107402 Oil and Grease (Freon Extraction)

107402 PCBs, Total

107402 Aroclor 1016

107402 Aroclor 1221

107402 Aroclor 1242

_ 107402 Aroclor 1248

1 107402 Aroclor 1254

107402 Aroclor 1260

107402 pH

107402 Phenols

107402 Solids, Total Suspended107402 Zinc, Total

^^ ')^Sl ^apiftfe::.- ;'» . * * . ' . * .

GULP COAST LABORATORIES, INC

2417 Bond St., University P«rk, I l l inoi* 60466PtwfMt (312) 534-5200 (219)8857077 (815)

A N A L Y T I C A L R E P O R T

: 06/25/87

: Proj* IH505 - P0# 21848IHJMC-001 EffluentSample Date: 06/04/87Date Received: 06/10/87GCL Number: 107402

liprfp^^ **ANALYST RESULTS

jh < 0.020 mg,

nt 0 . 062 mg,

rsk < 5 mg,

Ism < 0.001 ag,

Ism < 0.001 mg

Ism < 0.001 mg

lSB < 0.001 Bg

Ism < 0.001 agIsa < 0.001 ag

Isa < 0.001 agks 7.8efl 0.013 ag

bt 28 Bg

jh < 0.010 ag

GULF COAST LABORATORIES. INC

2417 Bond St., University Park, Illinois 60466

Phorwi (312) 534-5200 (219)8857077 (8151

ANALYTICAL REPORT

TO: MAECORP. IncorporatedPlain it Route 2Westville, IN 46391

ATTN: Mr. John Matlock

DATE: June 12, 1987

RE: Project «IN505 P.0.421848IFMC-001 EffluentSample Date: 06/04/87Date Received: 06/10/87GCL* 107402

VOLATILE COMPOUNDS '""*^~-u-!> 1-XfW

Chloromethane

Bromomethane

Vinyl Chloride

Thloroethane

Methylene Chloride

Acetone

Carbon Bisulfide

1 , 1 -Dichloroethene

1 , 1-Dichloroethane

Trans-1 , 2 -Dichloroethene

Chloroform1 , 2-Dichloroethane

2-Butanone

1,1,1 -Tr ichloroethane

Carbon T«traohlorid«Vinyl AcetateBronodichXoroMetnaiie

'" "iRfffillLT r™' '" ™~* DETECTION LIMIT

BDL

BDL

BDL

BDL

BDL

BDL

BDLBDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

10

10

10

10

5

10

5

5

5

5

5

5

10

5

5

10

5

0

0

U

u0

0

auD

uuuuu00

0

ug/1

ug/1

ug/1

ug/1

ug/1

ug/1

ug/1ug/1

ug/1

ug/1

ug/1

ug/1

ug/1

ug/1

ug/1ug/1ug/1

GULF COAST LABORATORIES. INC.

2417 Bond St.. Unhrtrsity Park. Illinois 60466

Phorw* (312) 534-5200 (219) 885-7077 <815) Tt

ANALYTICAL REPORT

TO: MAECORP, IncorporatedPlain & Route 2Westville, IN 46391

ATTN: Mr. John Matlock

DATE: June 12, 1987

RE: Project «IN505 P.0.421848IN!MC-001 EffluentSample Date: 06/04/87Date Received: 06/10/87GCLtt 107402

[ VOLATILE COMPOUNDS ""'"'

1 , 2-Dichloropropane

Trans-1 , 3-Dichloropropene

Trichloroethene

Dibromochloromethane

1,1, 2-Trichloroethane

Benzene

cis-1 , 3-Dichloropropene

2 -Chloroethy Iviny lether

Bronoform

4-Methyl-2-Pentanone

2-Hexanone

Tetrachloroethene

1,1,2, 2-Tetrachloro«thane

Toluene

ChlorobenceneEthjrlbenBene

1 Stjrrene1 Total Xylenes

^RESULT ^

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

DETECTION LIMIT

5

5

5

5

5

5

5

10

5

10

10

5

5

5

55

515

U

U

0

0

U

U

0

0

0

0

0

U

0

0

0U

a0

ug/l

ug/l

ug/iu«/l

ug/lug/l

ug/lug/l

u«/lug/l

ug/lug/lug/l

ug/l

ug/lug/lug/lug/l

TO: MAECORP, IncorporatedPlain & Route 2Westville, IN 46391

ATTN: Mr. John Matlock

GULF COAST LABORATORIES. INC2417 Bond St.. University Park. Illinois 60466

Phoim 1312) 534-5200 (219) 885-7077 1815) 7!

A N A L Y T I C A L REPORT

DATE: June 12, 1987

RE: Project «IN505 P.O.»21848INMC-001 EffluentSample Date: 06/04/87Date Received: 06/10/87GCL* 107402

TENfAT

One (1) Volatile Compound greater than IPX of the nearest____

internal standard was tentatively identified by mass spectral

library search. This is exclusive of any priority pollutants.

surrogates or internal standards. __

COMPOUND ESTIMATED CONCENTRATION

Unknown 29 ug/1

GULF COAST LABORATORIES, INC

2417 Bond St., University Park, Illinois 60466

Phon« (312) 534-5200 1219)8857077 (815)

A N A L Y T I C A L R E P O R T

TO: MAECORP IncorporatedPlain 4 Rt. 2Westville IN 46391

ATTN: Mr. John Hatlock

DATB: 06/25/87

RB: ProJ* IN505 - PO* 21848IN5MC-002 EffluentSaaple Date: 06/05/87Date Received: 06/10/87GCL Number: 107403

GCL £ PARAMETERS (j bg^A^§^§wMMj§jpjpjH|§MSi|Kfln107403 Chroniun, Total" ; i^llf •»»£* "**

107403 Lead, Total

— 107403 Oil and Grease (Freon Extraction)

107403 PCBs, Total

107403 Aroclor 1016

107403 Aroclor 1221

107403 Aroclor 1242

107403 Aroclor 1248

- 107403 Aroclor 1254

107403 Aroclor 1260

107403 pH

107403 Phenols

107403 Solids, Total Suspended107403 Zinc, Total

t^^aAtaSm

nt

rsk

IsmIsn

IsnIsnleu

Isn

Isn

ks

efl

bt

Jh

^^^^M^^^M^^^^^juL^BU^jA.Oai^HUn^n^n^n^n^BlB^n^B^B^nflBBMniBMlN^B

0 . 062 ng/

< 5 ng/

< 0.001 ng/

< 0.001 ng/

< 0.001 ng/

< 0.001 ng,< 0.001 ma,< 0.001 ng,< 0.001 ng,

7.0

0.015 ng,

32 ng,0.015 me,

TO: MAECORP. IncorporatedPlain & Route 2Westville, IN 46391

ATTN: Mr. John Matlock

GULF COAST LABORATORIES. INC

2417 Bond St.. Univirtity Park. Illmou 60466

Phonw (312) 534-5200 (21918857077 (815t

ANALYTICAL REPORT

DATE: June 12, 1987

RE: Project 0IN505 P.O.*21848I1MC-002 EffluentSample Date: 06/05/87Date Received: 06/10/87GCLft 107403

VOLATILE COMPOUNDS - -*~~*fmmmm i UN ii.ui .J* • " SW*?**-1- ' >• ' • •-'

Chlorbnethane

Br omome thane

Vinyl Chloride

Chloroethane

Methylene Chloride

Acetone

Carbon Disulfide

1 , 1-Dichloroethene

"~ 1 , 1-Dichloroethane

Trans-1 , 2-Dichloroethene

Chloroform

1 , 2-Dichloroethane

2-Butanone

1,1, 1-Trichloroethane

Carbon TetrachlorideVinyl Acetate

BroaodichloroMthane

BDL

BDL

BDL

BDL

BDL

20

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

10

10

10

10

5

10

5

5

5

5

5

5

10

5

5

10

5

JIK

U

U

U

uuB

U

U

0

0

D

U

U

0

0

U

0

>n Iffi3 !(.'«:--'*i

ug/1

ug/1

ug/1

ug/1

ug/1

ug/1

ug/1ug/1

u«/J

ug/1

ug/1

ug/1

ug/1

ug/1ug/1ug/1Off/1

GUI-F COAST LA8OPATORIE > <iM :

2417 Bond St., University Park. l^n-o <

Phones (312) 534-5200 (219) C'3!S 7'"7 '8 IS) 723

ANALYTICAL Hf PO R '

.>RP, incorporatedPlai-, & Route 2West vi He. IN 46391

ATTN: Mr John latiock

DATE: June 12, J987

RE: Project »IN505 P.O. «:21848IN5C1-MC-002 EffluentSample Date: 06/05/87Date Received: 06/10/87GCL# 107403

1 , 2-D:i.ch.loropropane

Trans- 1 , J -Dichloropropene

Trichi oroethene

Da bron ochioromethane

1,1,2- Trichloroethane

Benzene

cis - L , 3 -Dichloropropene

2 -Cn icroathylvinylether

Bromof orm

4 -Meth/l-2-Pentanone

2-Hexaxione

Tetrachl oroethene

1, .1,2, :i-T«-tr«chloroethane

Toluene

Chiorobenzene

Sthylbeineene

3tyren«

Total Xylenes

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

5

5

5

5

5

5

5

10

5

10

10

5

5

5

6

5

5

15

U

U

uuuu0

nuuuuuu0

u0

u

ug/1

Ug/J

ug/1

ug/1

ug/1

ug/1

ug/1

ug/1

ug/1

ug/1

ug/1

ug/1

ug/1

ug/1

ug/1

ug/1

u«/lug/1

TO" MAKCorcP, IncorporatedPlain 4 Route 2Westvi He. IN 46391

ATiN Mr. John Matlock

A N A L Y T I C A L R ~ P0 R T

DATE: June 12, 1987

RE: Project «IN505 P.0.021848IN505MC-002 EffluentSample Date: 06/05/87Date R«ceived: 06/10/87GCL* 107403

TENTATJ

Two (2) Volatile Compounds greater than IPX of the nearest

internal standard were tentatively identified by mass spectral

library search. This is exclusive of any priority pollutants,

surrogates or internal standards.

COMPOUND ESTIMATED CONCENTRATION

Unknown CzHe 0 140 ug/1

Unknown 37 ug/1

GULF COAST LABORATORIES, INC

2417 Bond St.. University Pirk. Illinois 60466

Phones (312) 534-5200 (219) 885-7077 (815) 72

ANALYTICAL REPORT

TO: MAECORP IncorporatedPlain 4 Rt. 2Westville IN 46391

ATTN: Mr. Greg

DATE: 06/25/87

RE: ProJ* 1N505 - PO* 21848IN50MC-003 EffluentSample Date: 06/06/87Date Received: 06/10/87GCL Nunber: 107404

GCL « PARAMETERS

107404 ChroBiUB, Total107404 Lead, Total

107404 Oil and Grease (Freon Extraction)

~~1 07404 PCBe, Total

107404 Aroclor 1016

107404 Aroclor 1221

107404 Aroclor 1242

107404 Aroclor 1248

107404 Aroclor 1254

- 107404 Aroclor 1260

107404 pH

107404 Phenols

107404 Sol Us, Total Suspended107404 Zinc, "otal

ANALYST

nt

rsk <

ISB <

Ism <

ISB <

ISB <

ISB <ISB <ISB <

kseflbtJh

RESULTS

, 0.020 ,

0.062

5

0.001

0.001

0.001

0.001

0.001

0.001

0.001

7.0

0.010

16

0.023

Bg/1

Bg/1

Bg/1

Bg/]

Bg/]

Bg/]

Bg/]

Bg/]

Bg/]•ur/:

Bg/:Bg/:Bg/:

/ COAST mmit ^wS|»*%JVwSSKHMMMfl

^^^^^^^^^^^^^^^^^^^^^^^^^^^j^^^^t^^^^^BBB^^^BBii ^^^BB^^WH^^^WBi ^^^^^^^^BP^^^Hi

TO: MAECORP, IncorporatedPlain &. Route 2West'-ille, IN 46391

ATTN Mr John Mat lock

•r" " 'VOLATILE

Chloromethane

Brornomethane

— Vinyl Chloride

Chloroethane

Methylene Chloride

Acetone

Carbon Diaulfide

1 , 1 -Dichloroethene

1 , 1-Dlehloroethane

Trans-1 , 2 -Dichloroethene

Chloroform

1 , 2-Dichloro«thane

2-Butanone

1,1, 1-Trichloroethane

Carbon Tetrachloride

Vinyl Acetate

Broaodichloronethane

/•» 1 ,' DOrM! •ji , u n i V B i ' i u y r 4 u « , nt ini i <»"ta-°

Phorm (312! 534-5200 (219> 885-707 ' 1815)723753:

^ ^ A N A L Y T I C A L R E P O R T

|M1 '

DATE: June 12, 1987

RE: Project «IN505 P . O . «»21848IN505MC-003 EffluentSample Date: 06/06/87Date Received: 06/10/87GCL» 107404

s- ;-" -•""•"-••'' 'BDL:' "" "•" "' ! •" > ; "io'I-!ov"ug/i""

BDL

BDL

BDL

BDL

65

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

10 U ug/l

10 U ug/l

10 U ug/l

5 U ug/l

10 B ug/l

5 U ug/l

5 U ug/l

S U ug/l

5 U ug/l

5 U ug/l

5 U ug/l

10 U ug/l

5 U ug/l

5 0 ug/l

10 U ug/l

5 U ug/l

GULF COAST LABORATORIES. INC.

2417 Bond St.. University Purk, Illinois 60466

Phon« (312) 534-5200 (219)8857077 (815)

ANALYTICAL REPORT

TO: MAECORP, IncorporatedPlain & Route 2Westville, IN 46391

ATTN: Mr. John Matlock

DATE: June 12, 1987

RE: Project 3IN505 P.O.*21848IMC-003 EffluentSample Date: OS/06/87Date Received: 06/10/87GCL* 107404

VOLATILE CUHFUUNUttfftiiilHI HH'\JJ'lil|plul^

1 , 2-Dichloropropane

Trans-1 , 3-Dichloropropene

Trichloroethene

Dibromochloromethane

1,1, 2-Trichloroethane

Benzene

cia-1 , 3-Dichloroprop«ne

2 -Chloroe thy Iviny lether

Bromoform

4 -Methyl - 2 -Pentanone

2-Hexanone

Tetrachloroethene

1,1,2, 2-Tetrachloroethan«

Toluene

Chlorobenzen*

Bthylbenzene

StrrmMTotal Xylenes

E9 ^ EKC22S8EII IIEi

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

5

5

5

5

5

5

5

10

5

10

10

5

5

5

5

5

5

15

U

U

uuuu0

0

0

u0

u0

u0

uuu

'•••• H" wipm **ug/iug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

•H/lug/l

ug/lug/l

TO: MAECORP, IncorporatedPlain & Route 2Westville, IN 46391

ATTN: Mr. John Matlock

GULF COAST LABORATORIES, INC.

2417 Bond St.. University Park. Illinois 60466

Phonti (312) 534-S200 (219) 885-7077 (815) 7

A N A L Y T I C A L R E P O R T

DATE: June 12, 1987

RE: Project «IN505 P.O. J»21848IbMC-003 EffluentSample Date: 06/06/87Date Received: 06/10/87GCL* 107404

TENTATIVELY IDENTIFIED COMPOUNDS

Three (3) Volatile Compounds greater than 10» of the nearest

internal standard were tentatively identified by mass spectral

library search. This is exclusive of any priority pollutants,

surrogates or internal standards. _____________

COMPOUND ESTIMATED CONCENTRATION

Unknown 70 ug/1

Unknown CaH«0 170 ug/1

Unknown 5 ug/1

OAST*0' IIMUIWSIIC

GULF COAST LABORATORIES. INC.2417 Bond St.. Uimtnity Perk, Illinoil 60466

(312) W4-S200 {219)885-7077 (815)72

A N A L Y T I C A L R E P O R T

TO: MAKCORP IncorporatedPlain 4 St. 2VHetville IN 46391

ATTN: Mr. John Matlock

DATE: 06/25/87

RE: Proj* IN505 - P0» 21848IN50HC-004 EffluentSaaple Date: 06/07/87Date Received: 06/10/87GCL NuBber: 107405

CCL * PARAMETERS ANALYST RESULTS

1 -107405 ChroBiu., Total *i ^

107405 Lead, Total

107405 Oil and Grease (Freon Extraction)107405 PCBs, Total

107405 Aroclor 1016

107405 Aroclor 1221

107405 Aroclor 1242

107405 Aroclor 1248

107405 Aroclor 1254

107405 Aroclor 1260

107405 pH

107405 Phenols107405 Solids, JFotal Suspended107405 Zinc, Total

nt

r*k

IsmISB

ISBISBISBISBISB

kseflbtel

< 0.05 BC/]

< 5 Bg/]

< o.ooi BC/:< o.ooi BC/:< o.ooi Bg/:< o.ooi BC/:< 0.001 BC/

< 0.001 BC/

< 0.001 BC/

6.2

0.023 BC/

12 BC/

0.251 BC/

GULF COAST LABOKATORIES. INC.

2417 Bond St.. University Park. Illinois 60466

PhonM (312) 534-5200 (219) 885-7077 (815) 723-7

ANALYTICAL REPORT

TO: MAECORI, IncorporatedPlain & Route 2Westville, IN 46391

ATTN: Mr. John Matlock

DATE: June 12, 1967

RE: Project «IN505 P.O.*21848IN50MC-004 EffluentSample Date: 06/07/87Date Received: 06/10/87GCL* 107405

VOLATILE COMPOUNDS

i -• Chloromethane. •'•* ":;';': ?; • ""•••ffliPI

1 Bromome thane

Vinyl Chloride

Chloroethane

Methylene Chloride

Acetone

_ Carbon Disulflde

1 , 1-Dichloroethene

1 , 1-Dichloroethane

Trans-1 , 2-Dichloroethene

Chloroform

1 , 2-Dichloroethane

2-Butanone

1,1, 1-Trichloroethane

Carbon Tetrachloride1 Vinyl Acetate

I' Broaodiohlorooethan*

RESULT

PWWPpjf|JfJ ?™w™PW?

BDL

BDL

BDL

BDL

110

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

DETEC

10

10

10

5

50

5

5

5

5

5

5

10

5

5

10

5

3Ti<• P**ff

U

U

U

U

B

U

U

U

U

0

U

U

U

0

u0

)N LIMIT^ ••VSMHHMHIHH HMMMI

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

uc/1

,

TO: MAECORP, IncorporatedPlain 4 Route 2Westville, IN 46391

ATTN: Mr. John Mat lock

GULF COAST LABORATORIES, INC.

2417 Bond St., Univ«nity Park, Illlnoit 60466Phonw (312) S34-S200 (219)885-7077 (815)72:

ANALYTICAL REPORT

DATE: June 12, 1987

RE: Project «IN505 P.O.«21848INEMC-004 EffluentSample Date' OC/07/87Date Received: 06/10/87GCL* 107405

VOLATILE COMPOUNDS

1 , 2-Dichloropropane

Trans-1 , 3-Dichloropropene

Trichloroethene

Dibromochloromethane

1,1, 2-Trichloroethane

Benzene

— cis-1 , 3-Dichloropropene

2-Chloroethylvinylether

Bromof orm

^_ 4-Methyl-2-Pentanone

2-Hexanone

Tetrachloroethene

1,1,2, 2-Tetrachloroethane

Toluene

Chlorobensene

Ethjrlbeneene8tjrr«a«Total Xylenes

RESULT

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

DETECTION LIMIT

5

5

5

5

5

5

5

10

5

10

10

5

5

5

5

5

5

15

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

D

U

0

ug/1

ug/1

ug/1

ug/1

ug/1

ug/1

ug/1

ug/1

ug/1

ug/1

ug/1

ug/1

ug/1

ug/1

ug/1

ug/1ug/1ug/1

.

/GULF/COASTftu«uims.iK

GULF COAST LABORATORIES. INC

2417 Bond St., Umvertiry Park, Illinoit 60466

Phonet (312) 534-5200 (219)8857077 (815)7

ANALYTICAL REPORT

TO: MAECORP, IncorporatedPlain & Route 2Westville, IN 46391

ATTN: Mr. John Matlock

DATE: June 12, 1987

RE: Project «IN505 P.O. #21848I1>MC-004 EffluentSample Date: 06/07/87Date Received: 06/10/87GCL* 107405

TENTATIVELY IDENTIFIED COMPOUNDS

Four (4) Volatile Compounds greater than IPX of the nearest

internal standard were tentatively identified by mass spectral

library search. This is exclusive of any priority pollutants,

surrogates or internal standards,

COMPOUND ESTIMATED CONCENTRATION

— Unknown 22 ug/1

Acetaldehyde 35 ug/1

Unknown CzHeO 160 ug/1

2-Propanol 150 ug/1

QULF COAST LABORATORIES. INC.

2417 Bond St.. Univtrtity Park, Illinois 60466

Phoim (312) 534-5200 (219)885-7077 (815)7

ANALYTICAL R E P O R T

TO: MAECORP IncorporatedPlain a Rt. 2Westville IN 46391

ATTN: Mr. John Matlock

DATE: 06/25/87

RB: Projft IN505 - PO* 21848IN5'MC-006 EffluentSample Date: 06/09/87Date Received: 06/10/87GCL Nuaber: 107406

GCL « PARABBtnt9ip|MHiJ^BHMOTi107406 ChroBluB, Total

107406 Lead, Total

107406 Oil and Grease (Freon Extraction)107406 PCBe, Total

107406 Aroclor 1016

—107406 Aroclor 1221107406 Aroclor 1242

107406 Aroclor 1248

^ 107406 Aroclor 1254

107406 Aroclor 1260

107406 pH

107406 Phenols

107406 Solids, Total Suspended107406 Zino, Total

JKL

el

ntrskIsm

IBB

lSB

ISB

IBBlSB

IBBkseflbtel

•PPIj-SP;?": v-.;-r^.- ".T - : •• ' • '!«JBJ< o . 020

0.05

< 5

< 0.001

< 0.001

< 0.001

< 0.001

< 0.001

< 0.001

< 0.001

6.7

0.016

25

0.098

•f ' ' '' ••g/

Bg/

Bg/

Bg/

Bg/

BftV

•g/

Bg/

Bg/

Bg/

Bg/

Bg/

Bg/

COAST'IUM1WK.K

GULF COAST LABORATORIES. INC.

2417 Bond St.. University P«rk, Illinois 60466Phoiwt (312) b34-8200 (219) 885-7077 (815) 72

ANALYTICAL REPORT

TO: MAECORP, IncorporatedPlain & Route 2Westville, IN 46391

ATTN: Mr. John Matlock

DATE: June 12, 1987

RE: Project *IN505 P.O.*21848IN!MC-006 EffluentSample Date: 06/09/87Date Received: 06/10/87GCL* 107406

VOLATILE COMPOUNDS

Chloromethane

Bromorae thane

Vinyl Chloride

Chloroethane

Methylene Chloride

Acetone

Carbon Disulfide

1 , 1-Dichloroethene

1 , 1-Dichloroethane

Trans-1 , 2-Dichloroethene

Chloroform

1 , 2-Dichloroethane

2-Butanone

1,1, 1-Trichloroethane

Carbon Tetrachloride

Vinyl Acetate

BroaodiohloroMthane

RESULT

BDL

BDL

BDL

BDL

BDL

1500

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

DETECTION LIMIT

10

10

10

10

5

200

5

5

5

5

5

5

10

5

5

10

5

0

U

uU

uB

U

U

U

o0

D

D

U

0

0

0

ug/iug/l

ug/iug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/lug/l

ug/l

ug/log/1

GULF COAST LABORATORIES. INC

2417 Bond St.. Unlvirnty Park. Illinois 60466

(312) 534-6200 (219) 885 7(T7 (815) 7

ANALYTICAL REPORT

TO: MAECORP, IncorporatedPlain & Route 2Westville, IN 46391

ATTN: Mr. John Matlock

DATE: June 12, 1987

RE: Project *IN505 P.O.1*218481*MC-006 EffluentSample Date: 06/09/87Date Received: 06/10/87GCLft 107406

VOLATILE COMPOUNDS

1,2-Dichloropropane

Trans-1 , 3-Dichloropropene

Trichloroethene

Dibromochloromethane

1,1, 2-Trichloroethane

Benzene

cis-1 , 3-Dichloropropene

2-Chloroethylvinylether

Bromoform

4-Methyl-2-Pentanone

2~Hexanone

Tetrachloroethene

1.1,2. 2-Tetraohloroethane

TolueneChlorobenzeneIthylbenceneStjrreneTotal Xjrlenes

RESULT

BDL'BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

DETECTION LIMIT

5

5

5

5

5

5

5

10

5

10

10

5

5

5

65

6

15

•3ff

U

uuu0

uD

U

U

0

0

uuu000

u

ug/1

ug/1

ug/1

ug/1

ug/1

ug/1

ug/1

ug/1

ug/1

ug/1

ug/1ug/1ug/1ug/1

ug/1ug/1ug/1ug/1

TO: MAECORP, IncorporatedPlain & Route 2Westville, IN 46391

ATTN: Mr. John Matlock

GULF COAST LABORATORIES. INC

2417 Bond St., Unlvtnity Park, Illinois 60466Phoow 1312) 534-5200 (219)885-7077 (815)7;

ANALYTICAL REPORT

DATE: June 12, 1987RE: Project UIN505 P.O.tt21848IN

MC-006 EffluentSample Date: 06/09/87Date Received: 06/10/87QCL* 107406

TENTATIVELY IDENTIFIED COMPOUNDS

Five (5) Volatile Compounds greater than 10% of the nearest

internal standard were tentatively identified by mass spectral

library search. This is exclusive of any priority pollutants,

surrogates or internal standards,

— COMPOUND

Unknown

Unknown CaH«0

2-Propanol

1 -Propanol

Unknown

ESTIMATED CONCENTRATION

34

130

190

8

5

ug/1

Uf/1

ug/1

u«/lug/1

GULF COAST LABORATORIES. INC.

2417 Bond St., Unlvtriity P«rk, Illinoil 60466Phonw (312) 834-5200 (219)885/077 (815)

A N A L Y T I C A L R E P O R T

TO: MAECORP IncorporatedPlain & Rt. 2Westville IN 46391

ATTN: Mr. John Matlock

DATB: 06/25/87

RB: ProJ* IN505 - PO* 21848IN!MC-007 EffluentSanple Date: 06/10/87Date Received: 06/10/87GCL NuBber: 107407

GCL « PARAMETERS

-' 107407 Chrcaiua, Total

107407 Lead, Total

107407 Oil and Grease (Freon Extraction)107407 PCBs, Total

107407 Aroclor 1016

107407 Aroclor 1221

107407 Aroclor 1242

107407 Aroclor 1248

107407 Aroclor 1254

107407 Aroclor 1260

107407 pB

107407 Phenols

107407 Solids. Total Suspended107407 Zinc. Total

ANALYST

el

nt

rskIBBlaslea

Is*

ISBISB

lam

ks

efl

btel

RESULTS

< 0.020

0.075

< 5

< 0.001

< 0.001

< 0.001

< 0.001

< 0.001

< 0.001

< 0.001

8.7

0.022

24

0.031

•cBCBB sT

£m »

M

BC

•C

Bg-•fl

•I

•i•1•1

OULF COAST LABORATORIES. INC

2417 Bond St., Univtrtity Park, Illinoit 60466(312) B34-B200 (219)6857077 (8151

ANALYTICAL REPORT

TO: MAECORP, IncorporatedPlain & Route 2Westville, IN 48391

ATTN: Mr. John Matlock

DATE: June 12, 1987

RE: Project *IN505 P.O.*21848IMC-007 EffluentSample Date: 06/10/87Date Received: 08/10/87GCL« 107407

VOLATILE COMPOUNDS

-" Chloromethane

Bromomethane

Vinyl Chloride

— Chloroethane

Methylene Chloride

Acetone

Carbon Disulfide

1 , 1-Dichloroethene

1 , 1-Di chloroethane

Trans-1 , 2-Dichloroethene

Chloroform

1 , 2-Dichloroethane

2-Butanone

1.1,1 -Trichloroethane

Carbon Tetrachloride

Vinyl AcetateBromodiohloromethane

RESULT

BDL

BDL

BDL

BDL

BDL

2400

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

, , i/J»lJbl

10

10

10

10

5

500

5

5

5

5

5

5

10

5

510

5

U

U

0

U

0

B

U

U

U

U

U

U

0

U

0

U

U

Ml LJJJUT

ug/1

ug/1

ug/1

ug/1

Ug/1

ug/1

ug/1

ug/1ug/1

ug/1

ug,"ug/1

ug/1

ug/1

ug/1ug/1ug/1

GULF COAST LABORATORIES. INC

2417 Bond St., Umvtrtity Park, Illinois 60466

Phontt (3121 534-6200 (219)8857077 (815)7

ANALYTICAL REPORT

TO: MAECORP, IncorporatedPlain & Route 2Westville, TN 46391

ATTN: Mr. John Mat lock

DATE: June 12, 1987

RE: Project HIN505 P.O. *21848IhMC-007 EffluentSample Date: 06/10/87Date Received: 06/10/87GCL* 107407

—•

VOLATILE COMPOUNDS

1 , 2-Dichloropropane

Trans-1 , 3-Dichloropropene

Trichloroethene

Dibromochloromethane

1,1, 2-Trichloroethane

Benzene

cia-1 , 3-Dichloropropene

2-Chloroethylvinylether

Bronoform

4-Metnyl-2-Pentanone

2-HexanoneTetrachloroethene

1,1,2, 2-Tetrachlorowthane

TolueneChlorobensene

Ethylbentene

StrreneTotal Xylenea

RESULT

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

DETECTION LIMIT

5

5

5

5

5

5

5

10

510

10

5

5

5

5

5

515

U

U

U

U

U

U

U

U

U

U

U

U

U

U

0

0

UU

uc/1

uc/1

uc/iuc/1

uc/1

uc/1

UC/1

uc/1

uc/1

uc/1

uc/1

uc/1

uc/1

UC/1

uc/1

UC/1

uc/1uc/1

/GULF'COASTIIMU1MIK'

OULF COAST LABORATORIES. INC

2417 Bond St., Unlvtriity Pirk. Illinois 60466

Phoiw* (312) 534-6200 121918857077 1815)

A N A L Y T I C A L R E P O R T

TO: MAECORP, IncorporatedPlain & Route 2Westville, IN 46391

ATTN: Mr. John Matlock

DATE: June 12, 1987

RE: Project 0IN505 P.O.H21848IMC-007 EffluentSample Date: 06/10/87Date Received: 06/10/87GCL« 107407

Six (6) Volatile Compounds greater than 10% of the nearest

internal standard were tentatively identified by mase spectral

library search. This is exclusive of any priority pollutants.

surrogates or internal standards.

COMPOUND ESTIMATED CONCENTRATION

Unknown 45 ug/1

Ethanol 78 ug/1

2-Propanol 170

1-Propanol 9

Unknown 12 ug/1

Unknown 14 ug/1

MVIR-" -HOT Oof Enfofctmtnt

CY

( I - (CHAIN OF CUSTODY RECORD

RMtived for Laboratory by Oat. /Tim. R«narki

VI HI IOTI )NA

CHAIN OF CUSTODY RECORDPROJ.NO. PROJECT NAME

STATION LOCATION

NO

OF

CONTAINERS

REMARKS

ll

(I

II I/M

inquisncd by: (S*n»tur»l

Ranivcd for Laboratory by

of £nfo<c*<rtntCHAIN OF CUSTODY MtCOHD

PROJ. NO. PROJECT NAME

SAMPLERS: I.

STA.NO OATf TIMI

NO

OF

CONTAINERS

STATION LOCATION

REMARKS

flt-ttf

y.y-aqr-

Data/Tim* Rtcahwd by D«U/Tlm« R*ctiv«d by:

Date/Tint* Ractivtd by: (S&tturtl -Rtlinquilh«d by 0«U / Tim«

0m/Tinw Rwvivcd for Labor*tory by: Oat*/Tima iRtmarks

of EnfiforcemmtCHAIN OF CUSTODY RECORD Chtcogo.

PROJ. NO. PROJECT NAME

SAMPLERS:

STA.NO DATE TIM* STATION LOCATION

NO

OF

CON-TAINERS

REMARKS \

I- /JCl-IJl

Received for Laboratory byRelinojuwhedoy

/GULF'COAST

JflCTCT

GULF COAST LABORATORIES. INC

2417 Bond St., Univenity Park, Illmon 60466

Phon«» (3121 5345200 (219)8857077 (81

The following is a list of flags that Gulf Coast Laboratoriesfrequently uses on our anljrtical reports. All flags may notbe applicable for the enclosed reports.

B - Indicates the compound was found in the blank as well asthe sample, it indicates possible/probable blank contamin-ation and warns the data user to take appropriate action.

E - Severe matrix interference

D - Result is on a dry weight basis

J - Indicates an estimated value which is below detection limit

F, PCBs appear to be present; but are below detection limit

ND - Not detected above detection limit

P PoaKn present but do not appear to be PCBs

U Indicates compound was analyed for but not detected

R - Spike recovery not within control limit

W - Result is on an "as is basis" (wet weight)

* - Duplicate not within control limits

+ - Correlation coefficient for MSA < 0.995

BDL - Below Detection Limit

WATER SURROGATE PERCENT RECOVERY SUMMARY( r-a-c

ntnif)

nSRc

RlANUc

07*105 msOUCQIkOfm^o.loiMoHfolds'\j 1 i^/^t^I N™^ 4f^\ f

\mio5fOT^Ofeoi«toi

"""7Q^l

^JO(OfiqqJOO(01<*<*

mafOfttooqq

IM-tltt

qqrtOqq

0^IOG100nn[100q$t101ipiqq

ir*-it«t

< (j

C gc ^< 7

^H969!c c< 7<: fjq?

•

IM'**«I

UitTtt» Kit

CM-VOCATN.E _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _

~*lit- •*«

— - - -

!>• n»

[«ST:CtC€

.»,..**'C« 0*1 •»••!

11* '< • '

• VALUES ARE OUTSIDE OF CONTRACT REQUIRED OC LIMITS Volatitoi O — out of 36 t outsirf* of OC l^ts**AOV80RY LIMITS ONLY Swui-VotttHtw ———— out of ———— ; outsit of OC l™ts

Ptstkidtst ____ out of ___ _ ; outside of OC limits

WATER MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY

PRACnOM

VGASMO

SAMPLE NO./07V6&

•mSMO

IAMPLCNO.

ACIOSMO

SAMPLE NO.

PESTSMO

SAMPLE NO.

COMPOUND

i.t ni[tii»imii«iTtlrfiteiujitujuO*iOfOb*»«it>nTo4tM*«

tfnnn*l.7.« Tnch>otoB«ni«««Acentafcthtnt2.4 Ointt'oiolwwio•k___^__

1 AOicMorobwtnnoP«nUchlorop*MnotPi nol

~?l ?-Ss»=rl*£T™* ——HtotichlorAktrinOwldfinEnorin4.4'4)OT

CONC VIKEAOOEO f«*/LI

5Og-/1^7SOS<2

SAMPLERESULT

—

-

OONCMS

HiV5"•Vt*J(^^

RfCf^ii<!/

P«l§•*s

v5

°ssV3Vo

Ui?5O

RCC

ft&10yc1

i]

}J2^^

RPO

V5"t

f-t

c.^

^-

AST! RISKED VALUES ARE OUTStOf OC UNITS.

RPO: VOA*_Q_*wtof_j^L cutt-to OC Nmin RECOVERY: VOA»___L•/N ____ owl of ___ owtiitft OC NMitt 1/N ———ACIO ———— »ui of ——— ounMo OC Kmiit ACIO ——PEST _____ owl of - ownidi OC limit* ' PCST —— •

1 ft

1414lj13tl213131313121W.424042N»*2022It2127

fc | iMtT^'PlECOvEHV

ai-i4ft71-1207S.130

74.17739994C-1 tl24 1429-12741.114

_JH*'*'t-10312-M27-12323t7

M-12340-13140-12057 17844 12131-127

owtof_Z-^: o«m<d» OC litnin

9^f of —— r owMnJt OC Ihwindft Of ___• OUllid* QC liWill

. rw\ e =

At

It;,

V.

-JASJL

B y . D»t*

VCLATJUCORPOUMSConcent'ition: (Tow) Nediui (Circle Oil)

Bite E«tricted/Prepired!

Dite Analyzed!

Cone/Dilution Futon pH

Ptrcent Noiiturti (Not Decintrd)

ttfrcli OnH

74-87-3

74-83-9

73-01-*

75-00-3

73-00-2

67-64-1

73-13-0

73-33-4

73-34-3

136-60-5

&7-U-3

107-06-2

78-93-3

71-53-4

34-23-3

108-03-4

73-27-4

1

CMorotethint

BroioMthtni

Vinyl Chloridl

Chloro»thini

Htthvlene Chlorldt

Acetone

Cirbon OiwHidi

1.1-DichlorotthMf

1.1-Dichlorofthini

Trini-1 .2-OicMorotthtne

Chlorofori

!.:-DirMorotthiM

2-lutmone

1.1.1-Trlchlor ottline

Cirlon Tetrichlorlde

Vinvl (kttiti

IrowUlehlareMtliiM1 .-.r4g! TiWiK

< 10

< 10

( 10

< 10

<s<IO

< 3

i^tlllAS

< 3

( 5

< 5

' 5

< 10

< 5

< 3

< 10

< 9!!

CAS I (Circtt Of

78-87-5

10061-02-6

77-01-6

124-48-1

79-00-3

71-43-2

10041-01-5

110-73-8

73-25-2

391-78-4

108-10-1

127-18-4

79-34-3

108-88-3

108-90-7

100-41-4

100-42-5

1.2-DicMofODrooine

Trim 1.3-Dichloroproptni

Trichlorotthtni

DibroiochloroKthini

1.1.2-Trichloroethinc

Btrutni

cli-1.3-OichloroorMini

2-CMoroithvlvinvlcthir

IroNfori

4-d«th¥l-2-Pfntinon»

2-timnont

Titrichlorocthtne

1 . 1 .2.2.-Tttrtchlof otthtni

Tolitni

CklorobMtMi

EthvlbMtmt

ItvrtMI1 Tttll ItlMH

< 5

< 3

c^sVS

< 3

< 3

cxun< {< 10

( 3

< 10

< 10

< 3

< 3

txs«te,<xs-W4

< s< s< IS

QUANT REPORT

Operator ID: USER2Output File: ~MCP02::D3Data File: >MCP02::L2Name: MAECORP 107402MSMisc: 5mL SAMPLE » 5uL ISS1122

Quant Rev: 6 Quant Time:In jected at:

Dilution Factor:

670610 16:870610 15

1.001

lOuL MS*086

ID File: IO_UDS::U1Title: ID FILE FOR DAILY UOLATILE STANDARDLast Calibration: 870610 14:58

Compound R.T. Scant Area Cone Uni

1)9)

14)15)23)25)30)35)36)39)40)

• BROMOCHLOROMETHANE1,1-OICHLOROETHENETRAMS • t-r2-OlCHLOROETH£NE1 , 2 - D I CHLOROETHANE- 04• 1 , 4-0 I FLUOROBENZENETRICHLOROETHENEBENZENE

« CHLOROBENZENE- 05TOLUENECHLOROBENZENEBROMOFLUOROBENZENETOLUENE- 08

9.959.54

______ 9 .54 —SSS 12.72

20.2717.1917.6925.1224.0925.23

SSS 29.55SSS 23.94

220209

293492411424620593623737589

1811115024

416347778627002641627084275437561485804293382

50.00 PPB40.62 PPB

— 35.31 PPO,48.02 PPB*?50.00 PPB45.03 PPB47/74 PPB50.00 PPB45.94 PPB45.62 PPB.49.69 PPB"50.27 PPBK

* Compound is ISTO

W'••ii

r

TOTflL ION CHROnBTOQRPnF i l m >rCPOZ 40.0-360.0 *»u. HHtCDRP

TIC0*L SflnPLt + 5uL IS!

600 800

8

' A ' « 16 f^t4 ^?i ^TT T 6^

Data File: >MCP02::L2Name: MAECORP 107402MSMisc: 5mL SAMPLE * 5uL 155*122

Quant Output Filet AMCP02::D3

' lOuL MS*086

Id F i l e s ID_UOSs:U1Title: ID FILE FOR DAILY UOLATILE STANDARDLaat Calibration: 870610 14:58

Operator ID: USER2Quant Time: 870610 16:30Injected at: 870610 19:91

j i i:'. t_»,_»

6ut".c'i:»S By. Rccti«t:.

COS I

Htditm (Circli Ont)

Dltt Eitrictid/Prtpiritf!

Citt Anilyzed!

Cone/Dilution Fictori oH

Itoiiturii (Not Otcintid).

(Ctrclt Ont)

74-87-3

74-83-9

73-01-4

73-00-3

75-09-2

67-64-1

73-13-0

73-33-4

73-34-3

136-60-3

47-44-3

107-06-2

78-93-3

71-33-4

1 34-23-3JI 1M-M-41! 79-27-4t1

CMoroftthiM

BrOMMthiM

Vinvl CMorldt

CMOTNthAM

Ntthylnt CDlBridf

Acitont

Cirkan Mnlfite

Ul-DUklorottlnnt

1.1-OichlarMtliMt

Trini-1 .2-BldlarNthtnf

Cklorofiri

!.2-tlcllvartluM

2-Butinont

1.1.1-TrlclilarHthifii

CvkM Titradlaritft

«Ml fcftltl

•"- IrllBTBMBIt

I'-iSiSi

< 10

< 10

< 10

( 10

<s<IO

( 3

<^43fl6

< s< 3

< 3

< 3

< 10

< 9

< 3!! < 1011 < S11

CftS I (Cirel

78-B7-3

10061-02-6

7?-Ol-6

124-4B-1

79-00-3

71-43-2

10M1-01-3

11 0-73 -fl

73-23-2

391-78-6

108-10-1

127-IB-4

79-34-3

1M-BI-3

10MO-7

10»-41-4

100-42-3

1,2-BicMoroorooini

Trim 1.3-DicMoroDrootM

TficMorotthini

DibroMChloroMthini

1.1.2-Trichlorottliini

Bmiini

el i-l .3-Di chl or ooroiMt

2-Chl or Mthy 1 vi n ylithfr

Irotofori

4-fltthvl-2-Pint«nont

2-MllMMI

Tftrj'hioroithtni

1 • 1 .2.2.-Tttrichlorotth«ni

TalMM

CklorobmiffM

EthvHtRimt

Ittrnt

Tttll IflMM

< 3

< 5

M'

' 3< 3

i^

< 9/

< 10

( 3

< 10

< 10

< 3< s

! 4-3tJ t*^!> < S11 < 911 < 19

QUANT REPORT

Operator ID:Output File:Data File:

USER2~MCP03:iD3>MCP03::L2

Quant Rev/: 6 Quant Time:Injected at:

Dilution Factor:

870610 17::870610 16:'

1.0001Name: MAECORP 107402MSDnisc: 5mL SAMPLE * 5uL ISS1122 * lOuL MS*086

ID File: ID_UDS::U1Title: ID FILE FOR DAILY VOLATILE STANDARDLast Calibration: 870610 14:58

Compound R.T. Scant Area Cone Unit

1)9)

14)15)23)25)70)35)36)39)40)

• BROMOCHLOROMETHANE1,1-DICHLOROETHENETRAMS 1,2 D1CHLOPOETHEHE1 , 2 - D I CHLOROETHANE- D4

• 1 , 4-D I FLUOROBENZENETRICHLOROETHENEBENZENE•CHLOROBENZENE-D5TOLUENECHLOROBENZENEBROMOFLUOROBENZENETOLUENE-08

9.919.49

SSS 12.6720.2217.1817.6825.0724.0825.18

SSS 29.54SSS 23.89

219208206 —292491411424619593622737588

1771915711

412707751827761671606984680015587685729790926

50.00 PPB43.42 PPB

— ??i74 PPB —48.65 PPB l50.00 PPB46.45 PPB50.14 PPB50.00 PPB49.42 PPB48.43 PPB49.75 PPB™49.65 PPB

* Compound is ISTD

^

TOTRL ION CHROtlflTOeHPMFll« >HCP03 40.0-860.0 wiu. flflECORP 10740EF18D O«L BHP1PLE * ButT

goo 400 too

Quant Output File: ""Data F i l e : >MCP03::L2Name: MAECORP 107402MSDMisc: 5mL SAMPLE * 5uL ISS*122 * lOuL MS*086

Id File: IDJJDS::U1T i t l e : ID FILE FOR DAILY VOLATILE STANDARDLast Calibration: 870610 14:98

Operator ID: USER2Quant Times 870610 17:19Injected at: 870610 16:40

METHOD BLANK SUMMARY

.ftogton. Contractor ^ jf Cccc:(

flff . J L - I .

loc £H /oI.I.J TricH/oro 1, i,i -Jr. (lucre PC

7/05

D*t* Dtti

VOIAJ1LLCOWCMSConctntritiont CLo (Circl/ Out)

CAS 1

•rt.i.ip*, f,-/n-<nCone/Dilution Futart , oH

tarrnt Naitturtt (Not tecitttd) . . ...

itirclt On»l CAS 1(]j9/j)of q^"TOrcli 0

7«-87-3

74-83-9

75-01-4

73-00-3

75-09-2

67-64-1

73-13-0

73-33-4

73-34-3

136-60-3

67-U-3

JC7-06-2I! 78-93-3!1 71-33-6I1 36-23-91! 108-03-41! 73-27-41I

CMoroMtdini

BrotONthtni

Vinvl Chloridt

CMorotthtni

Ntthvleni Chloridt

Acitont

Cirlon Diulflto

Ll-DicMorottktM

1.1-Dichlorotthint

Trini-1 •2-Dlcfelorotthmi

CMorotori

1.2-DleklaraitliMt

2-luttnont

1.1.1-TriehlarattlHi

Cirkoo TitracMorll*

VlMvl Acttiti1

! ~Jt?

( 10

< 10

( 10

< 10

<s,33

( 3

< 3

< 3

< 3

1 < 3»1 < 3I: < 10!: < s!! < 3! 1I ( 10 11 1! < 3 !11

178-87-3 1

10061-02-6

79-01-4

124-48-1

79-00-3

71-43-2

10M1-01-3

110-73-1

73-23-2

391-78-6

108-10-1

12MB-4

79-34-3

1M-M-3

10i-9«-7

100-41-4

100-42-3

1.2-Dichloroorofint

Trim 1.3-Dichloroprooint

TrlehlorottliMf

DibroMChloroMthint

1.1.2-Triehloro»thMt

Bmztnc

cli-1.3-Dlchloro>roMM

2-ChlariwthylvlivUthtr

BroMfori

4-Mthvl-2-fMtuion*

2-Mntnoni

Tttriehlo"»t»>*«»tI 1.1.2.2.-TttncMoritthiM11 Toltnt\1 CHorobmttM1! EtflVlhMIMt1! ItvriM11 Titil IvlMM

< 3

< 3

( 3

< 3

< 3

< 3

< 3<

< 10

( 3

< 10

< 10

< 3

< S

< 3

< S

( S11 < S1! t «

C«f

Ccxibt

Orgonkt Analysis Doto Shoot

Tonlotfvoly MoiitHiod Compound*

10..

IS..

20.

1/C4Win.13.31?

QUANT REPORT

Quant Rav: 6Iperator ID: USER2Output Fi le: AMA610::D3">ata File: >MA610: : L2

METHOD BLANK5mL OFU) + 5uL ISS#122

ID File: ID_UDS::U1Title: ID FILE FOR DAILY VOLATILE STANDARDLast Calibration: 870610 14:58

Quant Time:In jected at:

Dilution Factor:

870610 14:870610 14:

1.000

Compound R.T. Scant Area Cone Unit

1)8)14)15)30)39)40)

• BROHOCHLOROMETHANEACETONE1 , 2 - D I CHLOROETHANE- D4

• 1 , 4- D I FLUOROBENZENE•CHLOROBENZENE-D5BROnoFLUOROBENZENETOLUENE-08

SSC

SSSSSS

971220252923

.88

.38

.65

.19

.04

.48

.87

219153292491619736588

1795697624128278840722425899794149

50.22.48.50.50,49.49,

,0063,02,00.00,53.70

PPBPPBPPB 'PPBPPBPPB iPPB<?

6

cc

Compound is ISTD

TOTAL ION CHROnATOCRAHfilm >nR610 40.0-CtO.O ABU.

«P? .... 4?? ....

0*L OFH * OUL I»»l

. • 9 0 .......

' '3*

Data File: >MA610::L2Name: METHOD BLANKnisc: ?mL OFU * 5uL ISS*122

Quant Output File: AMA610:tD3

Id File: IO_UDS::U1T i t l e : ID FILE FOR DAILY VOLATILE STANDARDLast Calibration: 870610 14:58

Operator ID: USER2Quant Time: 870610 14:58Injected at: 870610 14:18

RCrCRtNCC STANDARD 8PECTRUMFil* >YB923Bpk Ab 8732

800W£ACETONE 0*0923 12101 Scvi

8UB 10.2*43*

08

, , , , , , , , , , , , , ..,...,. 1....J.')44 4* 40 00 02 04 0* w-

210• In.

•100

SAHPLE SPECTRUM (BRCKOROUND fUBTRACTED)Fii« >nnBpk Ab 4

400-

0-4

61099

4

'e '

nCTHOO BLANK 0«L OTM * But 188*122 8c«f» 103SUB 7.30 Bin.

13[-100

•^4' ' '4V ' •*' ' 'rfo' ' 'rft' ' •0'4' ' '01*' ' '^0

SAHPLC 3PECTRUH <UNALTCRED)Fil* >Mfl610 nCTHOO BLANK 0»L OfM * 0uL 188*122 8c«n 103Bpk Ab 499 7.30 ain.

4» -4

400-

o- r4Z ' ^4 ' 46 ' 48 ' 0*0 ' 0"2 ' 0*4 ' 8*6 ' 8*8

Data File: >MA610::L2Name: METHOD BLANKMisc: 5mL OFU * 9uL ISS1122Quant Time: 870610 14:58Injected at: 870610 14:18

Compound No: 8Compound Name: ACETONEScan Number: 197Retention Time: 7.38 min.Quant Ion: 42.8Area: 9762Concentration: 22.67 PPBq-value: 92

Quant Output File: *MA610::D3

Quant ID File: ID.UDSttUlLast Calibrationt 870610 14:58

•>-.'clr>r *rzm : JMA610

PLANK Operator: UC3ER2 MS '?/iv-87 14.•I *• 5«..iL 155*122*1S model: 96 SW/HW rev.: IA ALS # : '.)JOHN Tuning file?: TUNE3 No. of extra reccrds: 2! 5O Analyrer temp.: 1.8O Transfer linn *-emp. : 280

.-, t-. o

'T-'-iphic temperature's : 45.•ir'u.ihic ^rimer., min. : 3.0qraphir rate, deg/min: 8.0

BLANK 5ml_ OFWT T f-Area Reject: 3.00 7.Re-^jlts File VDIR86

220.20. 00. 0

0.0.00. 0

5uL ISS#122

. n .

Max Peaks: 3Sorted by Time/Area INT

Bunching: 1

r-t.<:, ? r '

2 1 4."•COnr?o

max•SC :'f1

21?

2f35292

1 astscan

»-^ ~*

208299

peakhei ght

115624656

10375

rawarea

12627649977

105820

corr .area

JJ IEJl49649

1 05570

corr.'/. max .

IS 100.0040.5886.29

7.t

413

Gum o-f correrrte'd arsar,: 277564.

1:44 PM THU., 11 JUNE, 1987

14 HQc.10 40.0-260.0 »mu. METHOD BLfiNKROC TIC

180 200 220 240 260i 11 i, i 11 11 11 i • i T • i • . i • i • . i ij 111 i • .. 111 11 11 11 i ii i

11000-

IC'C'OO-

9000-:

3000-

700^

6000^

5000-

4000:

•3000-

£000-

100'>

5mL OFW + 5u.L ISSflc'c

280 300 320

8.0 ?.0 10.0 11.0 12.0 13.0 14.0

'•wi-. iv METHOD BLBNK 5mL-r :jC7:: 'iOB POD 0

1-i 05i 47 66 •--. 37

,-J .' i . .1 r~~

OFt-J •»• 5uL I1S'E-#122 S^an £35VC 12. -3 3 r,-,ir. .01

105 116 ;. '"7. .,. ..••• -,..-,-.. . , ,.,-.• -0

60 80 100 120 140

-i >BI'3DB Ethane, 1 ,1 ,2-trichloro-l ,2

1

85: 4? 59 *6 73 > _57

0- |l('|-| > r l'|-l 1 I'l'l > I'M'I'I'I'I1! | 1 1 l'l'| F T I . | l l • • | i l l • | l . . l | . i • r-T-i-r- '

,2-trif luoro- <8CI9CI> Scar, 94030.00 min.

01f 151,

JX>5 116 121 132 - :i . , 1 1 . 1 r " ... . i L i -n

60 80 100 120 140=• PR I POL Me than*, trichlckib 9999

1": 47 66 ?Q 8£

>rofluoro- Scan 1250.00 min.

01

105 117 121 123 E

60 ' 30 ' 100 ' 120 ' 140

•i_.BIGDe Methane, tr ichl orof1

1

: 47 5,:. 66 7C) s£ 8?

Luoro- v8CI9CI> Scan 93060.00 min.

01

105 H7 121 136 :

60 ' 80 ' 100 ' 120 ' 140

Ethane, 1 , 1 ,2-trichloro-l ,2,2-tri f luoro- (8CI9CI)Methane, trichloro-fluoro-Methane, trichloro-f luoro- (8CI9CI)Methane, trichloro-fluoro-Methane, trichloro-fluoro-

186 C2C13F3136 CC13F136 CC13F136 CC13F136 CC13F

Sample f i l e i >MA61O SpectrumSearch speed: 1 Tilting option: N

285No. of ion range* searched t

Prob. CAS # CON # ROOT K DK #FLG TILT '/. CON C_It.2.3 .4.5.

7825252525

76131125

75694128127

94031619306164163

"BIGDBPR I POL"BIGDBPR I POLPR I POL

74505O5052

6443464649

32222

00000

98999696100

350505050

557777

GDIS TUNING MO HASS CM.IBMTION

4-BroMfluorobtnztm (BFB)

t—

Cast No. 1 Contractor Gulf Coast Labs Contract No. 1

InttrtiMnt 10 GOJ Data / TIM 6/18/87 13:08

Lab ID >KA610::L2 Data RalaaM Authorizad Byt _____________

t/z

50759596

173174175176177

ION M1IOMCE CRITERIA

15.0 - 40.0* of tha baM paak30.8 - 60.8* of tha bm paakBaM paak, 100* ralativa abundanca5.0 - 9.0* of tha baM paaklate than 1.0* of baM paakgreater than 50.0* of tha baM paak5.0 • 9.0* of MM 174batuaan 95.0 and 101.8* of MM 1745.0 - 9.0* of MM 176

WELATIUE

24.29 OK52.09 OK

100.08 OK6.66 OK0.00 OK

76.64 OK5.90 OK

75.31 OK4.90 OK

MUOMCE

(7.698) tl(98.24) 11(6.510) *2

THIS PERFOffMNCE TUC APPLIES TO THEPOLLQyiNG SMPLES, &MKS MO STMOMOS

11 - Uilui in parMthtiii it ti MM 174.12 - Ualui in p«r«ntht»it it \ MM 176.

i_am£ 10.IBFBTUC

107 WOS t>. u4iM>DmiaikJQQ

lQ7«f J7 Dih/W>

_>KA410.IJATIJFJIMILYS1S.IJ

6/10/87__I_^13:08.

>McPa><

>MCPII

^

-/0-K7

>• 87

A-/O-87

fS.SI

: OS

PQMV 7/W

rti* >KRtioBpk Rb 7119

790O

700O

690O600O

990O900O4900400039003000£900ZOOO

1900

100O

900o

BFB TUNC euc of 4-arB TUNINB SOLUTION sc«n 19160

10.30 Bin.•^0 ( 100 120 f 140 i 1*0 t 180 t £00

F"°'

79/

90

4ih

68- a!60

/

"<

i

C07L x.>. Ill ^

-100

-90

-BO

•70

«o•60

•40

•30

•80'•10

BO ibc i ' ifeb ' 140 " i i o " lab ' abb

>KA610 BFB TUNE191 NRM

File: >KA610 Scan *:

m/z

43.2044.1049.2047.1048.1049.1090.1091.1099.10

Int.

1211

9246

.334

.936

.784

.292

.829

.898

.287

.630

.787

m/z

96.1097.1060.1061.1062.1063.1068.1069.1070.10

191

Int.

23199311101

.079

.982

.166

.380

.169

.791

.989

.788

.011

2uL

Retn.

m/z

72.1073.2074.2079.1076.1977.0978.0979.0980.09

of 4-9FB TUNING SOLUTION

time: 10.30

Int.

.7309.19716.92792.0864.284.744.4393.849.913

m/z

81.0982.0987.0988.0992.1993.1994.1999.19

Int.

4.•

4.4.2.3.10.100.

200716397397444791690000

m/z

96.19141.10143.10174.10179.09176.09177.09207.19

QUANT REPORT

Quant Rev: 6 Quant Time:In jected at

Dilut ion Factor:

•srator ID: USER2tput File: ALB610::D3•ta File: >LB610::L2•me: 50ppb STANDARD•*c: 5mL OFU * 5uL ISStl22 * 2.5uL ea. *115 & f!20

> File: ID_UDS::U1tie: ID FILE FOR DAILY VOLATILE STANDARD^st Calibration: 870608 20:35

870610 14:0:870610 13:21

1.00001

Compound R.T. Scant Area Cone Units

1 )2)3)4)<5)4 )7)1)9)

: 0)1 1)12)13)14)5)'6)T7)-9)9)20)21)22)23)24)25)26)27)28)29)30)31)32)33)34)35)36)37)38)39)40)41)

•BROMOCHLOROMETHANECHLOROMETHANEBROMOME THANEUINYL CHLORIDECHLOROETHANECARBON DISULFIDEMETHYLENE CHLORIDEACETONE1 , 1-D I CHLOROETHENE1,1-0 I CHLOROETHANETRANS- 1 , 2 -D I CHLOROETHENECHLOROFORM1, 2 -D I CHLOROETHANE1 , 2 - D I CHLOROETHANE- D4 SSS• 1 , 4-D I FLUOROBENZENE2-BUTANONE1,1, 1-TR I CHLOROETHANECARBON TETRACHLORIDEUINYL ACETATEBROnOD I CHLOROMETHANE1,2-01 CHLOROPROPANETRANS- 1,3-01 CHLOROPROPENETR I CHLOROETHENE0 I BROMOCHLOROMETHANEBENZENE1 , 1 , 2- TR I CHLOROETHANEC I S- 1 , 3-D I CHLOROPROPENE2-CHLOROETHYLVINYLETHERBROMOFORM•CHLOROBENZENE-D52-HEXANONE4-METHYL-2-PENTANONETETRACHLOROETHENE1,1,2 ,2-TETRACHLOROETHANETOLUENECHLOROBENZENEETHYLBENZENESTYRENEBROHOFLUOROBENZENE SSSTOLUENE-08 SSSTOTAL XYLENES

9.882.073.023.774.658.296.697.389.4610.7111.4312.0012.7212.6520.1912.6814.0514.4314.9814.9616.3216.5917.1617.7617.6517.8817.8818.9420.4625.0422.4620.9922.7722.7324.0629.1627.0930.8829.4823.8732.10

21913385881177135153208241260275294292491293329339343353389396411427424430430458498619591911999998993622673773736988809

1834293959090116626052675582280013002187274061021544474523950543905817761623437176365165660342927249845936731923338077069329797297262080627923739933099939605277994171189292639873036067034606409643390147

90.00 PPB51.92 PPB55.92 PPB52.62 PPB50.12 PPB44.29 PPB47.72 PPB47.72 PPB49.82 PPB47.46 PPB49.02 PPB49.16 PPB49.62 PPB50.69 PPB50.00 PPB36.49 PPB48.50 PPB49.78 PPB47.75 PPB47.68 PPB44.09 PPB45.91 PPB47.82 PPB49.62 PP846.91 PPB47.11 PPB46.71 PPB44.81 PPB47.57 PPB90.00 PPB36.28 PPB37.42 PPB48.60 PPB46.00 PPB47.46 PPB48.21 PPB47.87 PPB48.21 PPB48.81 PPB47.86 PPB47.69 PPB

* Compound is ISTD*

TOTPL ION CHROf1PT08ROf1ril« >LB610 40.0-860.0 MU. SOppb STRNDflHD

200 ,

B«L OFU * QuL ISSwle

'- ' 16 ' "20 ' 24 ' 2'8 ' 32 ' 3'6 '

Data File: >LB610::L2 Quant Output File: *LB61Q::07Nome: SOppb STANDARDMisc: 5mL OFU * 5uL ISSfl22 * 2.5uL ea. #115 & f!20

Id File: ID_UDS::U1Title: ID FILE FOR DAILY VOLATILE STANDARDLast Calibration: 870608 20<79

Operator ID: USER2Quant Time: 870610 14:07Injected at: 870610 13:28

I N I T I A L C A L I B R A T I O NVolatile HSL Compounds

D A T A

Case No.: . . . . . . . . . . . . . . . RegionContractor : Golf Coast Labs

nt ractor No.: ...............

IEPA Instrument ID : 1Calibration Oete : 870515 13:05

RF for SPCC is 0.300( 0.25 for Browfor* )

riaxi«n WSO for CCC is 30k

Laboratory 10 :

CompoundChlorowthaneBrokee* thaneUinyl ChlorideChloroethanerfethylene ChlorideAcetoneDtrbon Oisulfide1,1-Oichloroethene1.1-Dichloroethen«Trans-1 ,2-PichloroetheneOlorofora1.2-OicMoroethane2-Butanone1,1,1-TrichloroethaneCarbon TetrarhlorideUinyl AcetateBroMdichloro*e thane1,7 OichloropropaneTrans-1 ,3-OichloropropeneTriehloroetheneOlbroaoehloroiwthane1,1,2-TnchloroethaneBenzenecis-1, 3-Oichloropropene2-ChloroethylvinylatherBromfora4-Hethyl-2-Pentanone

>Lft515::B5 >LB515::C5 >LC515::D5 >LD515::E5 >LE515::

Tetrachloroethene1,1,2,2-TetraehloroethaneTolueneChlorobtnienaCthylbtnteneStyreneTotal Xylene*

Response FKtor (subscript is the Mount of ug/U

Average Response Factor

Percent Relative Standard Deviation

RF201.0173.7477.8163.3798

1.4474.5577

3.95281.33662 62331.43842.90452.4768

.1959

.5781

.5549.7010.6000.3656.7997.4884.4785.3720

1.0646.4355.2855.3870.5080.3973.5035.5535

1.43411.0582.5058.9813

1.3218

RF501.4883.9890

1.1301.4958

1.2988.7431

5.67481.18312.34481.27762.59702.1480

.2437

.5055.4944.9914.5364.3333.7217.4228.4299.3206.9545.3702.2476.3570.6970.5104.4348.5068

1.2611.9356.4547

1.34551.7913

RF100.9380.5414.7074.3118

1.1692.3750

3.56501.07552.12721.15122.30591.9260

.1479

.4499.4467.6454.4879.3062.6674.3806.3780.2803.8722.3406.2333.3397.4286.3162.3851.4448

1.1450.8413.4103.8521

1.1201

RF150.9854.4116.7003.3023

1.1732.3867

3.59111.08992.15521.16072.2994..9010

.1464

.4438.4348.6377.4837.3029.6560.3659.3622.2643.8618.3302.2353.3406.4592.3417.3745.4534

1.1505.8501.4070.8511

1.1195

RF2001.1477.3553.5272.2840

1.1112.3753

3.6376.9895

1.97121.07592.13361.7389

.1433

.4204.4133.6519.4592.2848.6079.3535.3352.2367.8191.3035.2165.3201.4500.3289.3541.3890

1.1929.8085.3194.8741

1.1528

RF1.11W

.6090.776).3547

1.2400.4879

4.08831.13492.24431.2?072.44812.0381

.1754

.4795.4688.7255.5134.3186.6905.4022.3948.2948.9144.3540.2437.3487.5184.3789.4104.4695

1.2167.8981.4534.9812

1.3889

CCC •WSO SPCC •

19.95 • •42.7828.75 •24.4710.8633.3429.0111.63 •11.14 • •11.5912.45 •13.9925.0213.2012.0720.7710.899.89 •

10.6013.6214.4317.9010.6314.1711.627.20 • •

21.4921.0414.6013.38 • •11.18 •11.21 • •18.N •21.4622.84

CCC • Calibration Check Coepounds ( • )

SPCC - Syete* Performance Check Ceepeunda ( • •

C 0 NT I N U I N 5 C A L I B R A T I O N C H E C KVolatile HSL Coipeunds

"m MO.: !Contractor : 9ulf Coast Libs

Csntrietor No.: 1Instrument 13 : SCI!

Region : IEPA Cilibntion Date : 970608 29:35Tin : 870610 13:28

Laboratory ID : >LB6!0::L2Initial Calib Date : 870515

RF for SPCC is 0.300( 0.23 for Broiofort >

Ffaxiiui ID for CCC is 251

CoipoundChloroiethineBroioiethaneVinyl ChlondiChloroethaneletnylene ChlorideAcetoneCarbon OisulftdeI.i-Dichisroethene1.1-DuhloroithiniTrans-1,2-DichloroetheneChlorofon1.2-Dichlorofthint2-Butanone1,1.1-TruMorotthaneCarson TftrachlflrideVinyl AcetateBrotodicliloroMthine1,2-DichloropropaneTrans-l,3-Dichlor9propeniTrichloroetheneDibroioch lor Methane1,1,2-TrichloroethaneBenzeneci5-1,3-Oichloropropene2-ChloroethylvinyIetherBroMfori4-Hethyl-2-Pentino»e2-HtxanoneTetrachloroethene1,1,2,2-TetrachlorBethaneTolueneChlorobenzeneEthylbenzeneStyrennTotal lylenei

RF30 - Response Factor fro* daily ftandard file_ it 50 «g/LRF - Average Response Factor trot initial Calibration Fort VI

Fere VII

RF1. 1153.6090,7743.35471.2400.48734.09331.13492.24431.22072.44812.0381.1754.4795.4686.7255.5134.3186.6*03.4022.3968.2948.9144.3560.2437.3487.5086.3789.4104.46951.2167

BUBfl• DTOO

.4334

.91121.3009

RF50.5122.4956.4358.32991.2430.7C39

3.LB32.. '02 /'MO1.17*4

2.58..2.1S3B.1985,454fr,446S.6922.5249.3055.6771.3855.4134.3153.8640.3635.2344.3415.5385.4154.3778.56711.1591.8686.4128.91141.2256

1C54.0713.6219.106.9P.24

45.419.9110.041.313.785.68!.68

13.183.194.734.592.254.111.954.164.196.975.512.114.402.085.879.647.9420.794.733.364.767.123.79

CCC SPCCt t

I f

10 - Percent DifferenceCCC - Calibration Check Co*omdi I » >

SPCC • SyitM PrftrMflct Chtci CMp««id( ( • • )

7/83

•a:It »mt

i*':.\

Cat* B.

Lo't''*:'. N;. ___

Ditt Siipl* kccivc

Concwitritioni

D*t( Eitrictid/Prtpiridi

Diti toilyttdi____

N»d»u§ (Circlf DM)

Cone/Dilution Ficteri.

COS

PircMt Noiiturti (Not Dtcinttd).

tig/kgfrclt Ont) __ CAS I cll

74-87-3

74-83-9

73-01-4

73-00-3

75-09-2

47-M-l

73-13-0

75-33-4

73-34-3

134-40-3

47-4A-3

107-04-2

78-93-3

71-SS-4

34-23-3

10I-M-4

75-J7-4

I1

CMorotfthiM ! < 10:

IrcMMthint ! < 1011

Vinvl CDloridt ! < 10!

Chlorotthani ! < 10ii

hitfwlini Chloridf 1 < S

Acitooi i <.(011

Cirfeon Dlulfite ! ( 31

l.l-DichlorotthMt ! < 3!

l.t-DieMorotthMt 1 < 311

Trm-1.2-DlcklvattlMM i < 3!

! Cfclarofori t < 3! !1 1.2-OicklarotthiM ! < 7! !! 2-tutinont ! < 10! !

1 1! Ctrlm Tttracftlorllt ! ( 31 !! Vinvl fcttrti i < 10! !t IrMorflcH— — ffc-ry i ( S1 ~. fe 11 v^ttft |

IJIJ1

178-87-3

10061-02-6

79-01-4

124-48-1

79-00-3

71-43-2

10041-01-3

110-73-fl

73-23-2

591-79-4

108-10-1

r:-:«-479-34-3

1 KM-M-3tI lM-fO-7«I 100-41-4!1 100-43-3J1

1.2-DichloroDronnf

Trim 1,3-DichlofonrMtM

Trlehlorotthini

DibroMcMoroMthini

1.1.2-Trichlorofthani

Bmtint

cli-1.3-DiehloroBroitfli

2-ChlarMthvlvinvlithtr

IroMfori

4-Mtthvl-2-ftntiflont

2-NtlMMI

Titrichloroftktnt

1 .1 .2.2.-TitriehlorofthiM

TBlmt

CklorobMiMi

EthvllMimtJ1 ItWfM11 Tttll IvlMM

< 3

<, 3

< 9

< 3

< 3

< 3

< /

< 10

< 9

^ 19( 10

< 3

f 9Jt < s«i < atM 3i1 < Si1 < IS

r

f*»» Nn

Organict Anilysis Data Sheet(Page 4)

Tentatively Identified Compound*

CASNumbM

i

.,A

R

a

,a

ft

10

11

1114

18

1ft

17

11

JO

99

M

9A

9ft9C

97

>c

2*

M

Compewnd NWIM

UrtlCnoix) r».

.

frcctioA

to A

S*mptf Number

INwmbw

mi/)5".4(

E*tim*l«C0iK«nirai

([( /P«nig/

P9

•

form t.

QUANT REPORT

Quant Ravs 6-rator ID: USER2tput File: ~MCP01::D3ta File: >MCP01::L2•ne: MAECORP 107402^c: 5mL SAMPLE * 5uL ISSfl22

File: ID_VDS::Ultie: ID FILE FOR DAILY VOLATILE STANDARD•st Calibration: 870610 14:59

Quant Time:Injected at:

Dilution Factor:

870610 15:43870610 15:04

1.00000

Compound R.T. Scan! Area Cone Units

) »8ROMOCHLOROMETHANE) 1,2-DICHLOROETHANE-D4) • 1,4- 01 FLUOROBENZENE) »CHLOROBENZENE-05) BROMOFLUOROBENZENE) TOLUENE-08

SSS

ssssss

91220252923

.88

.65

.23

.08

.48

.87

219292492620736588

181814152977900715865831193107

50.47.50.50.49.49.

00710000,40,60

PPB<*rFPBT5PPBPPBPPB?*?PPB ff

Compound is ISTD

ca<Dot-aqXuT0

a0

D

*

J 01. O-

Xg»j

o

o0.

ur.

oH

ft.e3 0J o-JO «•x~el-

s'•

O^ 0*£ Al

1

>*

<H

LJ 1

•«

Z

\j

JTI v»Mir»r)3 ——— — — ~^^^^^~^ i

!i

3IWWMOMC .UvOOMMnS —

"MyunmMfntfyiMUB — — — ^_jw uj MJBU irvwfwm

_^j*iI

_. — — — ~-^~^

o o o o o o o oo o o o o o o oO Al Al Al v* T*

-s.Al

"Al

Al

•

OAl

*

Al'H

•O

"^

a.<••O

^-*•^4

b.««3a3O*>c3a

CM•V)U)•-1.

CM 3-1 CM UN•• O

^ i\ *0 0 Ua. .-• _iu a.E QL r^ QC <E

O 0)•• Ue UJ _J— <I E••< f if\U.

• • *•C t) O-^ E «

Q 2 £

Oa[

oz<rHU)

U

—<E UNJ ••

§ 2> 0

*T

C OOf\

r-l O>

• • ^J ••

- U. cin oOUJ -D-J *-

M 0ou. «-"Q "2.. •— «0 0— .. u-- oU. — *-

*- 0T> — 0"- ^~ «J

CS ^9^ o

UN UN••4 ^4

0 O

a MJNOUl o o(/) f\ l\D CD 09

.. MQ .. *•— 00

t — TJ0 »- 0

0 ** O«. c a0 0 — •>

^(iJS

data file header from : >MCP01

6/10/87 1«^imple: MAECORP 107402 Operator i USER2 MSnc : 5mL SAMPLE * 9uL 195*122js. *: 3 MS model: 96 SW/HUI rev.: IA ALS * I 0Hothod file: JOHN Tuning file: TUNE3 No. of extra records: 2Source temp.: 190 Analyzer tamp.: 180 Transfer line temp. : 280

Chromatographic temperature* : 49. 220. 0. 0. 0.Chromatographic times, min. : 7.0 20.0 0.0 0.0 0.0Chromatographic rate, deg/min: 8.0 0.0 0.0 0.0 0.0

MCP01 MAECORP 107402 9mL SAMPLE * 9uL ISStl2240.01 260.0 ADC TIC

Jpslope: .20 Area Reject! 3.00 * Max Peaks: 7 Bunching: 1Dnslope: 0.00 Results Fila UOIR9? Sorted by Time/Area INT

eak*

123

R *r. • •in in .

5.419.649.92

firstscan

94106214

maxscan

101107220

lastscan

106124230

peakheight

33881889

11918

rawarea

9062932661124389

corr. eorr.area K max.

466997 38.09242693 19 . 78(122714) <& 100.00

Sum of corrected areas: 193678.

10>99 PM UED., 10 JUNE, 1987

O'TT

2MS8Uno311 D(W

TOd3M<

Film >ncpoiBpk Pb 1*81

naccoftp i074ot

i 42

4«.0

n«L SAHPLC * 6uL IfSMtt Scan 101M)0 OVC 8.41 ain.

46

43 44

43.0 44.0 JLJ.48.0 4«.0

Sample file: >MCP01 Spectrum f: 101

No dete base entries were retrieved,

. • >ncpoi<k Ob 894

il« >BI80Bok Ob 9999

J

tlflCCORP 107401 6*sue not4

43

,,,,,,,,,,,1,1,,,,,,,,,.,,.,..,4Z.8 43.0 43.6 44

443

43.8 43.6 43.6 44

L tPtlPLC * 6uL IStMtt tc*n) DVC 6.M

464 x*

.6 ' 44*. 8 4\i.O 48*. 8 4«!.6

rl- <0CI*CI> te«n0.00

4 48

I *.0 44.6 46.0 46.6 4«.0

107• In.

L330

• in.

1. Si lane, methyl- (8CI9CI) 46 CH6Si

Sample file: >MCP01 Spectrum #: 107Search speed: 1 T i l t i n g option: N No. of ion ranges searched:

Prob. CAS * CON t ROOT K DK *FLC TILT * CON C_

1- 28» 992949 330 "BIGDB 21 64 1 0 60 39 II

" i l« >tlCP01Rpk Rb Z669

4

Lrum >BI808Bpk Rb 9999

L

NRCCORP 107402

L9

f , ,50 60 70

n«th*n«,

(9/

51.- - 64 65

80 6*0 7*0

5»L ffltlPLt 4 8uL 1 88*122 88U8 ROO OVC 9.

? w 9/3Vi ^'i'80 90 100 110 120

brooch lore- (8CI9CI) 8c«i0.

**• 9^ ^3 100 116120

80 90 100 lib 120

cvt 2209t min.ISO,(,i

130n 13907)0 Bin.130

lit130

1. Methane, bromoehIOPO- (BC19CI) 128 CH2BrCl

Sample fil e : >MCP01 Spectrum *:Search speed: 1 T i l t i n g option: N

220

1.

No. of ion ranges searched

Prob. CAS * CON * ROOT K DK fFLG TILT * CON C

95« 74975 13907 "B1COB 100 12 1 0 86 6

.<»:. r N*.iD*r

QHMMIC8 ANALYSIS DATA SHEET

Laboratory Mm Bi» Coait LaooratoriH. flic. CM* No.__

Likoritorr 10 NG.

S«tflf Hatrii

K Rtiort No..

Contract No. .

Data Rtltaw Autkorizri k>_ Datt Saaplt Uteri no*.

US I

vaATJJJECWWUNWCoflcentntion: CtoO NHiut (Circlt Ont)

Datf Eitracttd/Prttarrt»

Datf -? 7

Factori tH

Ptrctnt (toistwii (Rot DtcantH).

or 09/Mirclt ttnt)

11

74-B7-3 !tf

74-83-9 !11

73-01-4 !It

73-00-3 !!

73-09-2 !t1

67-64- 1 !

73-15-0

73-3S-*

73-34-3

13A-M-3

47-U-3

107-M-2

7W3-3

71-55-4

54-2M

!M-«S-4

73-27-4

!CMoroMrthaof

vTMOOftnaMf

Vinvl Oilorifc

DilorottkaM

NfthvlfM Oiloridf

Acttont

Carbw DiMlfiff

I.l-Dieklarotti«M

1.1-Hrtlorottfcm

TraM-1.2Hlcklorottk«w

Oilarofort

1-MirMarfltttaBf

2-lntaMM

1.1.1-TricfelfrofthMt

CarbM Tttrackloriff

Viivl Aeftatf

lrM ieklVaHtkaM

(10

(10

<10

(10

< 3

40 206!

< 3

< 3

< S

< 3

< 3

< 3

(10

< 3

< 3

(10

< 3

CAS tof/kg

rdt Ont)

7B-B7-3

! IOM1-02-6

79-01-6

124-«-l

79-00-3

71-43-2

10041-01-3

1 10-75-*

73-23-2

591-71-4

lOt-lO-l

127-11-4

79-34-3

lOt-U-I

10MO-7

100-41H

100-42-5

!! 1.2-9icb]oroorMa*fii! Traat 1.3-Dichlorooroifw!! TrichlorottkntI! libroMchloroMthiMIi

! l.U2-TricMorortkaM11

! IntoM1l

! cii-1.3-tickloroornMflf!! 2-CfelorattbvlvinlfUitr!! IroMfori!! 4-*MM-2-footaMM1! 2-MniMMt1 TttrifkliroftlMtf!I l.l J.-TttradlorottlMM!1 TalMMII CkltrfAMtoM11 CtkvlkMZMM1! ItfTOM11 Tltll Iff 1 MM

< 3

( 3

< 3

( 3

< 3

< 3

< 3

<IO

< 3

(10

(10

1 < 3J1 < 3J> ( 3}> < 3J1 < S1! < 311 US

JS1111111111

Case No

Organic* Analysis Data Sheet(Page 4)

Tentatively Identified Compounds

Sampl* Number

107403

CASNumtet Compound Nam* •tl

V/OA HO1 1 •37

10.1112.13

1S.

It.

27.2t.

Form 1.

QUANT REPORT

aerator ID: USER2Jtput File: ^MCP04::D3*ta File: >MCP04: :L2

MAECORP 1074035mL SAMPLE * 5uL ISS1122

Quant Rev: 6 Quant Time: 870610 18:0Injected at: 870610 17:2

Dilution Factor: 1.0000

isc

D File: ID_UDS::U1'itle: ID FILE FOR DAILY_ast Calibration: 870610

Compound

UOLATILE14:58

STANDARD

R.T. Scant Area Cone Unite

181415303940

)))))))

« BROMOCHLOROMETHANEACETONE1 , 2 -D I CHLOROETHANE- D4• 1 , 4- D I FLUOROBENZENE•CHLOROBENZENE-D5BROMOFLUOROBENZENETOLUENE- D8

SSS

SSSSSS

9.7.12.20.25.29.23.

87376422034785

219153292492619736588

1730149214031775175675215576688366

50.20.48.50.50.50.49.

00066800000991

PPBPPBPPB'PPBPPBPPBPPB

<U

(OCtoe

* Compound is ISTD

TOTPL IONril« >nCP04 40.0-860.0 MIU. HHCCOKP 107403

33000-

28000-

84000-

20000-

16000-

4000-

B»U SRHPLt •»• QuL IS!

. . . . . W . . . . . . .

' 4 ^ k iT^ !'• T 2

Data File: >MCP04::L2Name: MAECORP 107403M i s c s 5mL SAMPLE » 5uL ISS*122

Quant Output File: AHCP04::D3

Id File: IO_UOS::U1T i t l e : ID FILE FOR DAILY UOLATILE STANDARDLast Calibration: 870610 14:58

Operator ID: USER2Quant Time: 870610 18:07Injected at: 870610 17>29

ta f i l e header from : ,--MCP04

-•: MA!-:CORP 107403 Operator i USER2 MS 6/l'Vc37 17:2: 5rv_ SAMPLE + 5uL 135*122

rt: Z MS model: 96 SW/HW rev.: IA ALS # : 0.hod *ilt?: JOHN Tuning file: TUNE3 No. of extra records: 2<-.p *-. "flip.: 15O Analyser te«mp.: 180 Transfer line temp. : 28O

Chr om ni-.oqraphic temperatures : 45. 220. 0. 0. O.Chromatoqraphic times, min. : 3.0 20.0 O.O 0.0 0.0Chrornatographic rate, deg/min: 8.0 O.O 0.0 0.0 O.O

5mL SAMPLE + 5uL ISS*»122•4 MAECORP 1074O3.01 260.0 ADC TICope: .20 Area Reject: 3.00 '/.-pe: 0.00 Results File VDIR86

Max Peaks: 2 Bunching: 1Sorted bv Time/Area INT

min. *~> c: ,•?. n

'v.-r; 92

max•snan

102219

lastscan

1.24

peakheight

21332I 1097

raw.area

3415861 19726

corr .are-?

329431118271 '

corr ."/. max .

100.00SS 35-. 90

•/. otot

73.26.

'ium of corrected -arfvi.s: 4477075.

10:51 PM WED., 10 JUNE, 1987

:?.ta f i l e header -from : 'MCP04

!•?: MAFCOFP 1O7403 Operator: U<3ER2 MS 6/1O/87 17:: : r.m'., SAMPLE + 5uL 155*122. *»: 3 MS model: 96 SW/HW rev.: IA ALS # : O'•:?thod -file: JOHN Tuning -file: TUNE3 No. of extra records: 2•jrce temp.: 15O Analyzer temp.: 18O Transfer line temp. : 28O

Chromatographic temperatures : 45. 220. 0.Chromatoqraphic times, min. : 3.0 2O.O 0.0Chromatoqraphic rate, deg/min: 8.0 O.O O.O

0 .0 . 0O.O

O .0 . O0.0

r04 MAECORP 107403^O.01 260.0 ADC TIClope: .20 Area Reject: 3.OO '/.slope: O.OO Results File VDIR86

5mL SAMPLE 5uL ISS*122

Max Peaks: 2 Bunching: 1Sorted by Time/Area INT

R.T.mi n .

2.21?. 74

•first

1427

max

1731

lastscan

2735

peakheight

7072359

rawarea

939428251

corr .area

878553939

corr.'/. max .

100.004.48

7.t<

9!t

Sum 91794.

1:56 PM THU. , 11 JUNE, 1987

c

<J\o

Cf^• -

o

^1• ™

o

CO• ™

o

• '• —

o

»-*o.•

o

H» ;M_•

O

H* h» M M »-> To roT'.< u 'j. 00 o n.« •& <r- o> o r>jo o o o o o o o o o oo o o o o o o o o o o

f1. i .9. , .9. . .9. i .9. , .9. • .9. . .9. . .9. , .9. . .9. , .9.i1i'

t

\

: _.. ________ ————————— ——— *• K

^_,--~~

>-•"

/

f

(_ >

i'

!

,>

--—___' "' '_.. -=> w

_ _ _ — —— • —— ———

d _*

- to

* *-£o

Aoo

f '-o ro-0 £

•

oV »TO 30 C

•

" I>3. orH» OP!-*. Oo -*o• — •*

- OTJ

l-»H O-^ No *.

OU!

H»-o>O

Ol3

w n-o o,.0 U

3-0r-

ro n

-roCD *

enCr~

ro-A "7,-, >.' <

u-i%MIV

y*^"^

3IP

Q.

5

OJ

oo'

.o

a"CIOfroc o'

CD

l

£ -'i•*

oo4oo oo10

c«C'

c»oOJ

<XJ

, o"" •

Cvl

o.<">cu

o

cu

o

(U

oP)•

cu

ocu•

CO

o•H•

CO

.4 >MCP04 MOECORP 107403 5mL SflttPLE + 5uLAb 11294 SUB ODD DVC

45

] 41 42 43 44

J^ 1 f 142.6 ' 43.6 ' 4'4.0 ' 45".6

.1* >BI6DB Eihanol <fiCNX9CI>. - - v «b 4887

45

j 42 43 44

tH- r| i-TT- -r-n-ri-TTT-i | i i i i | i • i i f i . . . | . . i i i i i i42.0 43.0 44.0 45.0

' F i i « >B16DB M«thana, oxybis- <9CI>c-nk fib 999945

! 42 43 44i _ ^^_ / f

42.0 43.0 44.0 45.0r:l« :'BIi:-De Formic »cid <OOT XOCI9CI >

' J - . i - Pb «i095

jj f4 I

42.0 ' 43.0 ' 44.0 ' 45.0

ISS*122 Scan5.43 n

46' 47

46.0 47.0

0.00 i

y • /"I46.0 47.0Scan0.00 i

46' 47

46.0 47.0Scan0.00

46

47

46.0 ' 47*.Q

102n i n .

0

121oin.

'-0

376• in.

-0

374Min.

9

'-Q

1. Ethanol (ACNM9CI)2. Methane, oxybis- (9CI)3. Formic acid (DOT)(8CI9CI)

46 C2H6O46 C2H6O46 CH202

Sample fllei >MCP04 Spectrum fttSearch speeds 1 Tilting optioni N

102No. of ion rang** »»arCh»d:

Prob. CAS tt CON 41 ROOT K

1. 70* 64173 121 "BIQDB 282. 32* 11S1O6 376 "BIGDB 243. IS* 64186 374 "BIQDB 20

DK #FLG TILT X CON C_l

3962SO

0o0

000

2049159

71857

4:2C

> (1CP04 MSCCORP 107403 5mL SAMPLE * 5uL I6S#122ftb 3937 SUB ADD DVC

44

Scan 172 .21 min .

41 42 43

41.2 41.6 42.0 42.4 42,43.2 43.6 44.0 44.4 44.8f-Q

Sample file: >MCP04 Spectrum #: 17

No data base entries were retrieved.

ji«p,f

Lakoritory HIM

lAoritory II Ml

Suplf Hitrii_

lltl ItlNM

OMMICI MMLrill MTA MIT

Cm fe.__

CASf

74-17-3

74-63-?

73H)M

75- 2

73-15-0

73-35-4

47-U-3

107-04-2

7MM

71-g-A

34-23-3

COKNtritiMI

lltt

Ntl

tac/lilitiit Fictirs.

Nrcmt (Mitarts Utot

rclt ftit)

ChlomtthMi.{! (10

JrojMttkKtf

Viivl DilorKt

Urthvlm Dilnrilt

Octtat

1.1.1-Trichl

TttridilnrKt

Vlivl Aettati

(10

< 3

( 3

< 8

< 3

(10

< 3

Ktaportfc.

CMtrictfc.

lltt iMpIt fcctivrt.

ICirelt OM!

7J-B7-S ! 1.2-HeM

10041-02-4 I Trm 1.3-Mcfcl

79-01-t

124-4J-1

_7tOO"3_

71-41-2 I IMUM

10041-41-

10t-10-l

127-1M

10I-M-3

JOMO-7

100-42-3

1.1.2-Tri

2-Hm

Till

Tttal 1*1i

(Clrtlt htli«! < 3II

<_S__

< 5

< 3

< 8

< S

< 8

< S

< 3

( 3

Cut No

Organics Analysis Data Sheet(Page 4)

Tentatively Identified Compounds

Sample NuT>t>«r

CASCompound Nwnc

Sc.nNumber

I/OA 1Ono

\JOfi

10.11.

IB.16.

1920.

22.23.

2S.

1ft

QUANT REPORT

Operator ID: USER2Dutput File: AMCP05::D3•Data File: >MCP05: :L2'Jame: MAECORP 107404

5mL SAMPLE * 5uL ISS#122

Quant Rev/: 6 Quant Time:In jected at:

Dilut ion Factor:

870610 19:870610 18:

1.000

ID File: IDJJDS::U1Title: ID FILE FOR DAILY VOLATILE STANDARDLast Calibration: 970610 14:58

Compound R.T. Scan* Area Cone Unit

1)8)14)15)30)39)40)

• BROMOCHLOROMETHANEACETONE1 ,2-DICHLOROETHANE-D4

• 1 , 4- D I FLUOROBENZENE•CHLOROBENZENE-D5BROMOFLUOROBENZENETOLUENE- D8

SSS

ssssss

9.7.12.20.25.29.23.

88346422045186

219152292492619737588

16925156173913072178644995324985272

50.65.48.50.50.50.50.

00082900000742

PPBPPBPPB tPPBPPBPPB 10PPBiC

* Compound is ISTD

TOTAL ION CHROflflTOeRflMMl. >HCP05 40.0-360.0 *»u. "BECORP * But 185

zeooo-

34000-

2000

I6or,

1200

8000-

4000-

zyo

1£

600

84 38 3*4

Data File: >MCP05::L2Name; MAECORP 107404Miac: 5mL SAMPLE * 5uL ISSfl22

Quant Output Filet *MCP05i:D3

Id File: ID_UDS:»U1Title: ID FILE FOR DAILf UOLATILE STANDARDLast Calibration! 870610 14:96

Operator ID: USER2Quant Time: 870610 19s00Injected at: 870610 18:22

REFERENCE 5TPNOQRD SPECTRUH

Bpk Rb 73

aooo4

42

QCETONE 860923 12iBl ScanSUB 10.26

98

44 ' 46 ' 48 ' 8*0 ' 8*2 ' 8*4 ' 86 ' 88

216• in.

•100

SRHPLE SPECTRUM <BRCK8ROUNO SUBTRRCTED)FiU >nCP09 tIPECORP 107404 9«L SRtlPLE * 9uL ISSM22 Scan 192

t

1000-

A^

42

/iu

-100

. 4V ' ' 4*' ' 'A' ' '4V ' 'rfo' ' 'rft' ' '44' ' '&' ' '4*~

SflttPLE SPECTRUM <UNRLTERtO>Til* >nCP09 flRECORP 107404 8»L SRHPLE * But 138*122Bpk Rb 11*8

43

1000^

IV

42 44

1ft i» ft ft «f*f ft ' R"» ' ft

Scan 1927.34 min.

r1 ftData File: >MCP09::L2Name: MAECQRP 107404Misc: 5mL SAMPLE * 9uL ISS*122Quant Time: 870610 19:00Injected at: 870610 18:22

Compound No: 8Compound Name: ACETONEScan Number: 192Retention Time: 7.34 min.Quant Ion: 42.8Area: 19617Concentration: 69.08 PP8q-value: 96

Quant Output File: AMCP09t:D3

Quant ID File: IO_UDS::U1Last Calibration: 870610 14:98

at-\ file header from » >MCP05

Die: MAECORP 1O7404 Operator: USER2 MS- : 5mL SAMPLE + 5ul. 133*122. tt: 3 MS model: 96 SW/HW rev.: IA ALS # : 01cthod file: JOHN Tuning file: TUNE3 No. of extra records:'.tree temp.: 150 Analyzer temp.: 180 Transfer line temp. :

6/10/87 18

280

Chromatoqraphic temperatures : 45. 220. 0. 0.Chromatographic times, min. : 3.0 20.0 0.0 0.0Chromatographic rate, deg/min: 8.0 0.0 0.0 O.O

5mL SAMPLE + 5uL ISSM122

0.0.0O.O

MAECORP 107404•10.OI 260.0 ADC TIC-lope: .20 Area Reject: 2.00 7.slope: 0.00 Results File VDIR86

Max Peaks: 5 Bunching:Sorted by Time/Area INT

R.T.min .

2.225.447.34

r-1. 7O9.88

firstscan

1393145184213

maxscan

17102152188219

lastscan

28134162197228

peakheight

13739282731709983

10775

rawarea

2449764173252698614270

1 1 6220

corr. corr.area '/. max .

161199 40.12401752 100.0021359HSL s.3211905 2.96

|Ji482l|fS 28.58

t

25

1

Sum of corrected areas: 711036.

11:11 PM WED., 10 JUNE, 1987

i_» i_ * i - t t - t t - t r u r o i u t o r ua - . o o o ' v > * < 7 » c o o i v - * | J * c oo o o o o o o o o o o oc - o o o o o o o o o o o

_?_., 9 9 . 9. 9 . 9 . 9 . 9 . ? . ? . ?

01

If

Oen

' oifVi

o•o

Leo £o c

OX)- ono

-ro.0

OTJ

ru•oo

CM3

D3-or*m+01

ro "-•-*.o *H

ro

il* >MCPQ5Dk Pb 7686

41

MfiECORP 107404 5mL SOMPLE * 5uL ISS#122SUB POO DVC

44

42 43

?can 17a.£5 min.

45r J T T T T | I I I I j r l » T | n I F |TF I r J ¥ rT^rj^T-IT • I I I I I J I I I I J I I I F J I I T I I I I I I | I F T I f FTrr I • . 1T[ I I I

41.5 42.0 42.5 43.0 43.5 44.0 44.5 45.0

Sample filmt >MCP05 Spectrum #: 17

No data b«»* vntriv* H«r« r»tri»v»d.

nc-* t> 1

0-

: : .-- BI•; '_ • Mt' <•

r i l* >B1Pp i Hb «

P05 MftECORP 107404 5mL SPtlPLE + 5u5201 SUB ODD OVC

4

* **M 43

41 4* / 44

r r .M .Mu f . , , , . . . . , ! . . . , . . . . , " . , . , , . . . , .42.0 43.0 44.0 45.0

QDB Ethanol (OCNX9CI)887

45X

42 J3 44

M ' ' 1 ' M^l i . . .| . . , . |i . i , | . ii , f. , M |i . . . -IT42.0 43.0 44.0 45.0

6DB M«than«, oxybis- <9CI>

45V.

42 43 44^ /

• • . . M " . | . . . . M • ' ' 1 • • ' ' 1 ' " ' 1 ' ' ' • 1 ' ' ' • -»"*•42.0 43.0 44.0 4! .0

iL ISS#1£2 Scan5.44 r

546

,„„„„!,„„„"46.0 47.0

Scan0.00 i

46<^ 47

46.0 47.0

Scan0.00

46' 47

102ttiri .

121nin .

-0

376min.

4*i.O 47.0

1. Ethanol (ACN)(9CI)2. Methane, oxybi»- (9CI)

Sample file: >MCP05 Spectrum *>Search *peedt 1 Tilting option: N

Prob. CAS * CON ft ROOT

64173113106

1O2

46 C2H6046 C2H60

K

No. of ion range* searchedt

DK #FL6 TILT '/. CON C_I R.

"BI6DB 28 39"BIGDB 24 62

0 2OO0

7 4218 20

ZSI £OdOW<

Bfi 9S" .1 •.i•. i . i • , 3S Ofi 8t»i....11... i....n. • 11 • • 111

St-

3STOAQ QOB 8HS 89TT

Fil« >MCP05Bpk fib 753

>U-r^43.2

flflECORP 107404 5mL SfiMPLESUB ADD DVC

44/•4-r

3uL ISS#122 Scan 1888 .70 min.

45

43.6 44.0 44.4 44.8 45.2

Sample fil«i >MCPO5 Spectrum *»: 188

No data b««» »ntri«» w«r» r«tri«v«d.

~ >MCP05 flflECORP 107404 5mLOb 2410 SUB ADD

49

jtH-rif

^51 79 ,

\ 1 150 60 70 80

SfiMPLE * 5uL ISS#122 Scan £19OVC 9.38 min.

3

?1 /3

L30/ -

90 100 110 120 130i* PRIPOL Bromochloromttthan* Sc: Ob 9999

49

an 4430 .00 min .

/ 13'?•

fr '1

91 61.- 64 */•,1 ^-. I.I50 60 70 80

91 93

*^"vl,l

/ :

L._J ^O

90 100 110 120 130" i l e >BIGDB n«th»n«, bromochloro- <8CI9CI) Scan:ci fib 9999

49

0" • ' '

/51

_-- 64 65 81

50 60 70 80

139070.00 min.

91 ^ 100 116 120'1 ViU'i i j ! ! , . , , >• \ i jT, 1 i •

130

190 100 110 120 130

1. Bromochlorofflvthan*

!. Methanv, bromochloro- (8CI9CI)

128 C.H2.BR/CL

90128 CH2BrCl

Sampl* -files >MCP05 Spectrum 4»iSearch »p»»di l Tilting optioni N

219No. of ion rang** a*arch*dt

Prob.

96*95»

CAS I

44874973

CON * ROOT DK *FLG TILT % CON C_I R

20613907

PRIPOL"BIODB

108100

S12

O0

9393

66

6868

OHMICS MMLTSIS MM SOT

JMB fclf Li t L/ ratoritt. he. CM* Ml. ___

UNr«ttry II

fctrli

M

tOaK-f

VOUTILEtacMtratittt LM

litt

latt

tec/Mlititt Facttrt.

Nrcttt Itiitvtt Mtt

PHIr

iTirclt fct)

It.

CMtract H.

htt

(Circlt ON)

CM! ICiitlt

7l-<7-3 ! 1.2-ticHlorMf

10041-02-4 I Trm 1.3-ticblvow

rC*»« No

(Sul-T

Organics Analysis Data Shtet(Page 4)

S*mpl« Number

Tentatively Identified Compounds

CASMumbw

1..2..3

10.11.

IS.

Cempew«d Nwnc

"ft1/flA

Hf «» Sc«n

no/he)

35"

ISO

1. 7 I

QUANT REPORT

Quant Rav« 6oerator 10: USER2File: *MCP06::D3

File: >MCP06::L2MAECORP 107405

Use: 5mL SAMPLE » 5uL 155*122

ID File: ID_VDS::U1Title: ID FILE FOR DAILY VOLATILE STANDARDLast Calibration: 870610 14:56

Quant Timat 870610 19:4:Injactad att 670610 19:0'

Dilution Factor: 1.00001

Compound R.T. Scant Araa Cone Unit*

1)9)14)5)30)39)40)

•BROnOCHLOROMETHANEACETONE1 ,2-DlCHLOROETHANE-D4•1,4-01 FLUOROBENZENE•CHLOROBENZENE-05BROMOFLUOROBENZENETOLUENE-08

SSS

SSSSSS

9,7,12,20.252923

,88,34.64.22.08.51.86

219152292492620737588

168131058213871270424645485272182769

504434850504948

.00

.95

.10

.00

.00

.53

.91

PPBPPBPPBTWPPBPPB ,PPB 97PPB<?*

* Compound is ISTO

r;r"'.:

TOTPL ION CHROHPTOSRPnfilm >MCP06 40.0-260.0 MU. HRECORP 107405 BaL SRHPLE * QuL

32000-

88000-

84000-

80000-

16000-

18000-

8000-

400O-

4 ' k ' S ^ 16 ' 80 ' 8'4 '^8 ' 38 ' 36 '

Data File: X1CP06::L2Name: MAECORP 107405Misc: 5mL SAMPLE * 5uL ISS*122

Quant Output File: AMCP06::D3

Id Tile: ID_UOS::U1T i t l e : ID FILE FOR DAILY VOLATILE STANDARDLast Calibration: 070610 14:58

Operator ID: USER2Quant Time: 870610 19:43Injected at: 870610 19:04

REFERENCE STRNOPRO SPECTRUMfl 1Bpk

• >YBRb 2

~

2000-

>

933 (732

43•v.

42\

42

KETONE 860983 12i91SUB

87\

44 46 48 60 82 84 96

Scan10.26

89

4-

816• in.

•1001

0

SPtlPLE SPECTRUM <BPCK6ROUNO SUBTRPCTEO)FU« >MCP06 MRECORP 107409Bpk Pb 6592

43

8PMPLE SPECTRUM CUNPLTCRCD)fil« >MCP06 MRECORP 107409Bpk Pb 8592

43

5000-

0- . , . , . , . . . , . ,

42\

'"'

44/\

48 ' 44 ' 46 '

9«L SRMPLE * 9uL ISS#122

87\

48 ' ^0 ' B'2 ' ^4 ' ^6 '

Scan IBS7.34 Bin.

88j1 .

•100

,

-O88 '

Data F i l e : >MCP06::L2Name: MAECORP 107405Mtsc: 5mL SAMPLE * 5uL ISS#122Quant Time: 870610 19:43I n j e c t e d at: 870610 19:04

Compound No: 8Compound Name: ACETONEScan Number: 152Retention Time: 7.34 min.Quant Ion: 42.8Area: 105821Concentration: 443.95 PPBq-value: 96

Quant Output F i l e :

Quant ID File: ID_UDS::U1Last C a l i b r a t i o n : 870610 14:58

,. 1 «.? hr-*rj»?r f r om

,.,,_>(. ,:L|F,P tM/405 Operator: USER2 MS"•-i. ::A:-1f-'LF-: » 5ul_ ISSK122

'•1? nu'dpl : ^6 5W/HW rev.: IA ALS # : 01 • : ! < > : JOHN Tuning -file: TUNE3 No. o-f e::tr<a records:tf'rr>f.: lr".O Analvrer temp.: 1^0 Transfer line3 t"?mp. :

ir'-Mr 31-""jr phi c temperatures : 45. 220. 0. O. •'.hr .>ma*: ogr<?phi c times, mm. : 3.O 20.0 0.0 0.0 O.hroin^toqr.sphi c r^te, deq/min: 8.O 0.0 O.O 0.0 0.

MAECORP 107405 5mL SAMPLE + 5uL ISS*»122• 260.0 ADC TIC^: . 21' Area Re.iect: 2.00 "/. Max Pe^ks: 7 Bunching:

Results File VDIR86 Sorted by Time/Area INT

6/IO/87 lc':'"-4

R . 7 .mi n .

2.67^.44T. 34i:3 . 66

9. RO

•f i r ? t

14

lrJ2

214

•/. o-f

1729102J52187

219230

38130166205

226236

4227258951104432334

1O665732

156549377597148939343580

80506367170

338192

21.93100.0038.7272.12

115838 P. 13914\ (S 31.038199 797200% 2.17

12.930.7

10.3

Sum of corrected arras: 1101088.

9:52 AM THU., 11 JUNE, 1987

MCP'^. 40 0-2^0 j amu nP-CCdftP 10740? 5»»L SPMPLE + 5uL 1^5*12,flDC TIC

,•-!<>-

JOO-

000-

0 0 0~

0 0 0-

J 0 0-

• j o •>

40 30 120 160 200 240, ! , , , 1 , , 1 1 1 , 1 1 , 1 . , . 1 1 1 1 1 1 1 1 I .._L. 1 1 1 ..!_.!_ _1 _L_ 1 1 1 1 1 —— 1 —— L__l ——— 1 —— L__

513

1f,i'i 2I I

^ \ A•-:-o^ .V , )

i1t

1 •... | \.

-J "^- .. . .. . ... ....... .Trr*.-"— -x^__J ..

1

i111

1

6

'l

'\ J; i 7c . v ?.0 4.0 5.0 6.0 7.0 8.0 ?.0 10.0 11.0

I

J 4.

5rnL E-PflPLESUB HDD DVC

44

4.3

4 3 . £ 43.6 4 4 . 0 4 4 . 4 4 4 . 3

?«?sP««mf3pB|(pSp»* "**.

Sample -filei >MCP06 Spectrum *: 17

No data base entries were retrieved.

vj(D*

vjuOxlO

MNlNl

=t-tOoOf

~J)1oa•

n(0

*

noz*

aa-i

T 3n "o3" «-*aMTJ -».a £a «M M

*• V3n•oo

HM->-•ft1 U)H-T33 «o n

rt-0 1D Cn- 9**•0 *3 ~••

•

nIDrt-0*1-"aIDT>^

aID* »ooH« >

*-fc

0)n1-4

*Qnt-t^^

z >oo

•n0 5o-f.M-

O

o r

M xN

noo z

nu I

1n

a

nro

CPF 4 ;•ue

5uL

45

4 344

,J4=' .0

<L t h armi • CHIN,- i;?

C 4H 'Jc'5.44 m i ' - , .

47-L-fi

4,1 .0 4 ? . 0 44.0 45.0 46.0 47.0

3 c a n lil0 . 0 0 w l n .

4c'————— , ——— ————— rT_r_j

43 44

————— 1 ——— , | . i . , | , . . ,

46^ 4?

i l i i M i i i j ' i44.0

c' I L-< D E^

-I

4I

•4,1. :>

9C1 '

44.0 45 .0 46.0

scan 3760.00 min.

47.0

fithamol (ACN) < 9 C t )Mfthane, oxybis- <9CI>

46 C2H6046 C2H60

file: >MCPO6 Spectrum *:vpeedt 1 Tilting optiont N

1O2No. o-f ion range* searchedi

1.

Prob.

70#52*

CAB * COM

6417S115106

121376

ROOT

"BIGDB"BIGDB

K

2824

DK »»FLQ TILT V. CON C_I R

3962

00

0 1920 85

816

4220

"•MCP06Mb £££72

J",42

- .-eiGoe•_ _ 3b 9999

: 42o- Vi

42

rlftECOPP 107405SUB

45X

42 I3 44 46' \ S" f

44 46 48

5mL SfiMPLE + 5uLftDO DVC

53/

50 52 54

2-Propanol <flCNX9CI>

45

4^ 44 46

• 1 ' 1 • ' M 1 ' 1 ' 144 46 48 50 ' 52 ' 54

ISS#122 Scan 1873 .66 rn in .

57 58 59 i

56 58 60

Scan 3260.00 win.

55 56 57 58 5960 '.( { ( i 1 V I '?

56 58 60

. 2-Propanol <ACN)(9CI) 60 C3H80

Sample file: >MCPO6 Spectrum #: 187Search speed: 1 Tilting option: N No. o-f ion range* searched:

Prob.

1. 88*CAS * CON ft ROOT K DK #FL8 TILT X CON «..,! F

67630 326 "B1QDB 41 26 0 0 76 3 .»S

C*»» Mo. __

QC R»0ort *o

Contract Ho.

Ditt 5*«clt

VOLATILE CtWOUWSICirclf On»)

Ditp

Coic/Ci lut ion Factor:_

?: (Not

M)/l or if/ifWS I ICirele On*)

> ii i

74-87-J ! Chloroittlianf

7 4 - « 3 - - > ' ProWl^t

7 * -0 ! -< ' V inv ! CM 0' lie

" ^-; ; rvnrwthw

r--"--? »!hr!«-i» OloriO

^ • i i f f f t f ^ f

r ' ' •' ••• - -.-,!',;).

' r ' ! - r -i» fc h n g,

1 ' >. , < -,^,n, ,.,p

,..,....,.; -.i:,,ofo.»fcw

• r ' '!rro(nr«

• • * - ? 1,2-Oithlnr^M.

7B-93-3 2-Bul.W»

71-33-4 l.l.l-Tnehl»-o»th«n»

34-23-3 Carbon T^trtchlofilf

108-^3-4 Vinyl A«Ut»

75-27-4 trotodichlorowthant

JiPJi

4 I< 1

t ,

/O ~ 8 7

C-5 Ji.

COS iuf/1 oriCirclt On»)

11

78-87-3

10041-02-6

79-01-6

12MB-1

77-OC-5

71-43-?

10WI-0]-r,

nci-n-p

73-K-2

391-73-4

1WMO-!

127-n-i

79-J«-3

|ft|!-^-3

|f.fi_!"i-7

•,oo-«i-«

KXK42-3

1

I1

1.2-Dtchloroprown* !

Trint 1.3-Dichloroprog'nt

Trichlorofthw*

Dibro«Khlx(M(th4flf

l,l,2-Tnchloro«t|jM

Bf^lM't

'•;^-|,7-nic*loro«r8Hnf

7 r>!i~r*thYlvinyl|th»f

?ro»;«!5f»

<-^»lKyl-2-Pint»noiit

2-Hfi»noo»

T»tr*chloro*thm

!.l,2,2,-Trtr«hlorofth«nt

TolOfM

Chloro^mtfnt

F.tHrl|t«iw»

StrrtM

! Total Irlmn !

IQUANT PEPQPT

Quan t P«?v: 6

L ISS*122

Quan t TimnInjected at

Di 1ut ion Fac tor

OFU (1:5 DILUTION)

" : : 'J 1fro DAILY 'JOLATILE STANDARD

nn - P 7 0 6 1 0 14:50

R . T . Scan* Area

' • 1Q• . --I'"}

- /- /-

. '" n 'i o o

Uni ts

f'M'

•CHLOPOBENZENE-D5

f f

t; THftNE

FTHONE-D4 SSSprhlTFNFE-D5ENZF.NE SSS

?ss

971220252923

.88

.34

.64

.22

.04

.51

.96

219152292492619737580

160432516837430683406223852025816^7

50.110.49.50.50.50.50.

00657300007003

PPBPPBPPB'PPBPPBPPBPPB

S7

ID/|00

TOTOL ION CHPOnaTOQRPtt40,0-360.0

200TIC400

1»L SPHPUt * BuL ISJ

600 800 ,

Data F i l e t >MCP09s:Ue Quant Output F i l a t ~MCP09::D3Nanr.e: MAECORP 107405Misc: ImL SAMPLE * 5uL ISStl22 * 4ml OFU (1:5 DILUTION)

Id Fila: ID_UDS::U1T i t l ^ i ID FILE FOR DAILY UOLATILE STANDARDLast Calibration: 670610 14:58

Operator ID: USER2Quant Time: 870610 22:00Injected at: 870610 21:22

-.4-

REFERENCE STPNOPRO SPECTRUMFi;« >YB923 PCETOME 860983 18i51 Scan 816Bf>k Rb 2738 SUi 10.86 mln.

43~

2000-

frt

48

C8

'

98• 9 w

/ I' 44 ' ' ' 46 ' ' ' 48 ' ' J 50 ' ' ' 6"a ' ' ' 8*4 ' ' ' 5*6 ' 88

t-100

'

•0

SPflPLE $?CCTRUri <BPCKBftOUNO SUBTRACTED?>ncP09 rmccoRp 107409

Bpk at> 194843

800CH

let SMtPLC * 0uL ISSMJKsue Scan 1587.34 »tn.

^

SflHPLC SPCCTMJH <UMfltTt»CO>m« >ncf>09 nflccoRp 107406 i8pk Pr 1948

438000-

- 48

0-^-r-, . , . , .

r

44

f48 44 44 48

•L <ANPLC * 9uL 158*188 Sc«n 1987.34 *iA.

r9*0 ' 88 ' 9I4 ' S'6 ' 8*8

Data F i l e : >MCP09»:L2 Quant Output File: ys«CP09::D3Name' MAECORP 107405Miac: ImL SAMPLE * 5uL ISSfl?2 * 4ml OFW (1:5 DILUTION)Quant Time: £70610 22:00 Quant 10 File: ID_UDSi:UlInjected at: 870610 21:22 Last Calibration: 070610 14:58

Compound No: 8Compound Name: ACETONEScan Number: 152Retention Time: 7.34 min.Quant Ion: 42.8Area: 25168Concentration: 110.65 PPBq-value: 97

OPS/MI ICS AKW.Y5!!; ?•'"• " "l '

,j^JtyiM, Inc. Cn- *".___

QC »»0ort lo..

Contract do,

Oitt

VOLflTIJLL COHPOWIOS(Lw 0 fluliut ICircl*

~% 7-

C o n c / D i l u t i o n F«tor! JH.

Noiiturf: (Hot D«int*<)

ICirclt

,,.,,.. : rjnoro^thw,

7J,nv, ; 8ro.wfhMf

7 ' i -01 -< ,' " 'dyl Chlorjlf

" n"1-'. 1 CMoroftlUnf

'* f!?-? : "»fhykn» CMorid*

"• ' • ' • * • - ' ! V f t no •

; ' " i 1 r..«rt)(xi SifuHidf

!V« 1 I, j-DicnlorotthMf

"-M-3 1 l,l-Dichlorottli«Mi

!54-M>-5 ; Tr«fti-},2-DicMorottNMf

6/~W*3 I QtlOf 9^0Tlii

107-04-2 ! 1.2-DichloriMthwitl

71-73-3 i 2-tatmmtl

71-39-6 ' 1.1.1-TricMorMtHwr1

M-23-3 ! C^rbow TrtncMoritft*

IW-05-4 ! Vinyl fcititti

79-27-4 ! IriMOdiclilgrowtlKiiff1

(10

(10

(10

(10

< 5

jtwD.(.

< 5

< 3

( 5

( 3

< 3

< 3

(10

< 3

< 3

(10ll

< 3

CflS 1i

78-87-5

IOMJ-02-4

77-01-4

!24-«8-l

77-00-5

7MJ-2

-0,-b

no-Tt-e

75-23-2

371-78-4

108-20-1

127-18-4

77-34-3

lOfr-W-3

10»-tO-7

100-4H

100-42-31t

1,2-Dichlorooropint

Tranj 1,3-OichlorogroiMf

TncMoroftliW

DibrowtMorunthwf

1,1,2-lnchlorotthMl

taZfflf

cii-I.MicMar«roMM

2-CMorotthrlri«vlfthfr

Irotofari

*™flJW Vl 'Z'rWI'fnlOM

2-*f»«mw

Tttr«cHloroetlMii

1 . 1 .2.2.- Tf trial or otthMt

TollfM

DdarofefniMff

Ethyl IMZIM

StrriMl

rclt On»)

( 5

( 5

( 3

< 5

( 3

< 3

< 3

< 3

(10

(10

< 3

< 3

( 3

< 3

< 3

< 3

Trt-1

Organics Analysii Data Shurt(Page 4)

Tentatively identified Compounds

. ,

CV.Compound N»m« Fraction

VOA

• n t '

3V30

(90

Voft

7•9

1C11

1?

IT

14

! 7 '

37

n

7 8S

QUANT REPORT

Quant 9ev: 6ID: USEP21 " : ^hCPO?: :D3

>MCP07::L2107406

» 5uL ISStl22

Pile: ID_UDS::U1ie: ID FILE FOR DAILY UOLATILE STANDARD

-. t C a l i b r a t i o n : 870610 14:58

Quant Time: 8706Injected at: (3706

D i l u t ion Factor:

Compound R.T. Scant Area

10 20:210 19:41. OHOO

•am* _• ACETONE. • *.•.-..;.•-1,2-oicHLOiwef..•1,4-orPLOOROBEN^•CHLOROBENZENE-09BROMOFLUOROBENZENE

' TOLUENE-08

Compound is ISTD

Cone Units

SSSSSS

29.5023.85

737588

5192882591

1.0050.0850.09

PPBppgtOO

'CTRL ION

Data File: >MCP07::L2Name: HAECORP 107406

SAMPLE * 5uL ISStl22

Quant Output File: *MCP07::D3

Id File: ID_UDS::U1T!tM: ID FILE FOR DAILY VOLATILE STANDARDLast 'alibration; 970610 14:58

Operator ID: USER2Quant Tjme: 870610 20:26Injected at: 870610 19:47

!• .>yr,ir;> M..I Scan 315( Kf. V Mr ,J ' c1

j IP1 -) ''.

I 42

>UU iV .Cr> Bin.

[-100

37 39 1

N ' L44 46 40 BO 32 54 56 58

SPECTRUM 'BPCfeROUND SUBTRPCTEO)f i i * >1CPC7 HPECORP 107406 3»L SflHPLE » 3uL ISS0122 Se*n 153Opt Pb 31634 SIB 7.33 min.

43-

30000--41 *?

' j

'

44 57 8f/ 93 58 v ^' I f \ \ .

-100

-043 44 46 48 CO 52 54 56 68

SPHPLE SPECTRUM (UNflLTERED)Ti !• >MCP07 MOECORP 107406 5«L SfiflPLE * 5uL ISS0122 Sc«n 152Ppk Ob 31634 7.33 «ln.

43-

30000--41 4?

/ /

'

44 57 Sfl/ 13 <SG ^ ^' / / N 1

-100

LO' ) " ! ' ) * i " i " i " i ' T " i " i " r " i " j " i " r ' i " i ' i42 44 46 40 90 52 54 56 50

Data File: >MCP07::L2N-5me: MAECORP 107406Mi5C: 5mL SAMPLE * 5uL ISS*122Quant Time: 870610 20:26Injected at: 870610 19:47

Compound No: 8Compound Name: ACETONEncfln Number: 152detention Time: 7.3? min.Quant Ion: 42.8Area: 382934Concentration: 1637.09 PPBq-va1ue: 96

Quant Output File: /NMCP07::D3

Quant ID File: IO_UDS::U1Last Calibration: 870610 14:58

-. t Ml" h«">.io'f-r from : MCP'.'7

M<»! LUr-'r I'.>74'.>6 Operator: L'SER2 MS':-n>. ''.riMM. £ <• i:..il_ 155*122

M'~> model: 96 SW/HW rev.: IA ALS * : 0H Mlr: JOHN Tuning file: TLJNE3 No. of e:-tra records:f^np.: !'JO Analyser temp.: 180 Transfer line? temp. :

c temperatures : 45.1 .hr-.-m.*t oqraphi c times, min. : 3.0Chr m^hographic ratf*, deg/min: 8.0

22O.20. 00.0

<:». o0. 0

O. 00. 0

mL SAMPLE 5uL ISSW122"T'O;* MAECORP 1O7406•K'.'~'' 2(SO.O ADC FIG3lon»: .^O Area Reject: 2.00 7. Max Peaks: 8 Bunching: 1'•slope: O.-I'O Results File VDIR86 Sorted by Time/Area I NT

• \- R'. T. f irstmin. scan

2 . :: i 145.43 917. ;v: i<i4H. .->3 i«;'-'. •?•:• ;:i4

0.:?? 226::.o; :96J . «:>'T 325

ma:r

17102152td7220

2 ""9292329

lastscan

28117172201226

235300335

peakhei ght

70792227144«-»654 I96010944

jci!95171034

rawarea

133537311789540104447761 t f306 1

219259998612739

corr. <area 7.

76660300138527368HSL435192IT137071<S

132619880B5S11830

zorr .ma;: .

14.5456.91100.0082.5221.56

3.4618.742.24

Sum o-f corrected 1581958.

10:20 AM THU., 11 JUNE, 1987

0.0-£60.0 »mu.fiDC TIC

??.-4

440 0 0-

40000-

36C-OC-

35000-

•2SOOO-

£4000;

20000;

1*000-

12000-

3000-

.000-

a

•

1 Ia. i

}< I

t

V. _ I

4

uVj ^i /> ! I 3

S I A I I

Qb

40041

SmL SfltlPLE + 5uL ISS#i22SUB ODD OVC

44

43

:l r, in

41.2 41.« 42.0 4 .4 42.8 43.2 43.6 44.0 44.4 44.3

Sample filei >MCP07 Spectrum 17

No data base entries were retrieved.

ML• D 1

-

,-J

•<::• •

'>

•eiQb •:

-1

(V

F 0 ,' f1 * e 3

41, 4 .-' ,"'

42

y&r

42

• l" •42

GOB) 0 w Ci

42

42

wF<; jRF

41:

. "' 44f

44

4

4J 44

u —— f-^-44

^

43 44

44

107406 5n,L 'SAMPLE * 5'j.L IS'I-.#122 :••: in 1 02SUB ADD DVC 5.4.: r» i r> .

;b

47 5:? t---L, ,

46 4;3 50 52 54 '^ 58

0 . 0 0 'ii i fi .5

f'' 47 48 t'i f* , L-OF • i • i • i • i • i ' i ' i • i • i • i • I • r J

46 4e 50 52 54 56 58

H*tharifc, oxybi*- '. 9C I ) Scan 3760.00 in in.

5

46 T47 4S :

46 43 50 52 54 56 58

Ethanol (ACN)(9CI)tlBth«n», oxybi»- (9CI)

46 C2H6046 C2H60

Sample file: >MCP07 Spectrum 1»:Search speed: 1 Tilting option: N

1O2No. of ion range* searched:

Prob. CAS ft CON ft ROOT K DK #FLQ TILT X CON C_I R

1. 70#52*

64173115106

121376

"BIGDB"BI6DB

2424

4362

00

0 1810 BO

917

4220

* MCP07 tlflECOPP 107. tfb £5053

45x'

41 42 i5 44 46-%. ."'' : * I f" /

42 44 46

SUB fiOC DVC " 8 ".65*

57 56 5«

137it i n .

43 50 52 54 56 5% 60

1* ,-BIGDB 2-Prop»nol <flCNX9CI> Sc *n<• Pb 9999 0.00

45

] •»£ 4^ 44 46 55 56 57 53 5%0•J "* 1 " " • » • " " / / / / / x-s

42 44 46

326mm .

•

-ft49 50 52 54 56 58 60

1. 2-Propanol <ACN>(9CI> 6O C3H80

Sample -filBi >MCPO7 Spvctrum #i5<?arch *p««d> i Tilting options N

187No. of ion r«ng«m ••archvdt

Prob.

1. 88*CAS ft CON # ROOT K DK *FLG TILT X CON C_I

67630 326 "BIQDB 41 26 0 0 81 3 65

.!=/

-i fKPC-r HfiECORP 107406 5mL3b 433 SUB fiDD

4ci_

0-

41 "43 45^ 44 /1 ?' 1

42 44 46 48 50

SfiMPLE + 5uL ISS#122 Scan ££?DVC 10.55 min.

59-

57 59i i

.;to

52 54 56 58 60:* :BI6DB 1-Propanol <ftCNX9CI) Scan 127

fib 10594£

"1 43 ,_j ^ 44 ^ 46

42 44 46 48 50

0.00 min.59' 60 ,

55 56 '7 58

1 i | i l ' \ i \ i ( i 1 ' 1 i • . -

^Fit52 54 56 58 60

le >BIGDB l-Prop«ne, 2-fluoro- <9CI) Scan 18451 fib 9999

-

<y4£ 45 44 45 46

^ -•• ( **

42 44 46 43 50

:* -'BIGOB l-Prop«n«, 3-fflb 9999

0-4£ 43 44 45 46 47 48 49 50

•-- "-.. ^ s^ S S S S f—i — l — ' — i — i — i — i — — i — i — i — i — i — r— • — 1 — r — i —i i i | | i • i • i • i42 44 46 48 50

0.00 min.59

• . .--- -• vt**i™- / . _' 6055 56 5/ 381 ' ' '

N -•

-052 54 56 58 60

luoro- <9CI> Scan 1*430.00 min.59

51 52 55 56 '/ 58' 1 ' ' ' f

•

--052 54 56 58 60

1. 1-Propanol (ACN)(9CI)2. 1-Propene, 2-fluoro- (9CI>'*. 1-Propene, 3—fluoro- <9CI)

60 C3H8060 C3H5F6O C3H5F

Sample filei >MCP07 Spectrum #: 229Search speeds 1 Tilting optioni N No. of ion range* searchedi

1.2.

Prob.70»20*20*

CAS * CON *

712381184607818928

12718431843

ROOT

"BIQDB"BIQDB"BIQDB

322323

DK *FLG TILT X CON C_I

41 167 269 2

00O

7808274

75253

4233

*«vq

88 fS

j|j''~~J SS

•UIMJ frO't-T

06 9<i "Zf. 89 t»9 09 9S 36 8t» t't'1 ' 'X Si

8fi

DAQ coo ans

t*^, r

Ct-tTE qn ^

JJJM8aaaa»MlMilllill'«

OPttMllCS AMUSIS MT« SHEET

e,)M Cn^it UhorjtoriM. Inc. CJM Ho. ___

j » r ; r

K Rtaort Ko..

Contract No.

Dttt Sa*li ftictivri.

VOLATJLLCMPOWBSConcmtntson: C"' LoO

Date

Cone/Dilation Factorr_

Prrctnt Koiiturn (Not

ig/tfOnt)

1

74-87-3

74-83-9

73-01-4

^

73-07-2

7-4M

1-13-0

3-35-<

1-34-3

•4-40-5

S7-44-3

'07-04-2

78-73-3

71-53-4

34-23-S

I09-4S-4

73-27-4

Chlorowthinr

Brototrthanf

Vinyl Chlondi

Qi'orofftluiiff

frthylmt Ch'orifc

/n;/V>/*c»ton» / Jx uC

U-licMorottMM

1 l.l-Oichlorofthaafti

! Trani-1.2-D1cklaroftkifti! Oil or of or •

i 1.2-DichlarottkaM11 2-lutammi

! 1.1.1-TrickloroothantI! Carton Tttrartlorife•i! Vidvl Acttatt1i ar(K-4fcklqrojittkaM!

COS t

(Circlt Ont)

ui/1 or ug/i;tCirclf Ont)

7B-87-3

10061-02-6

77-01-6

124-4I-!

77-00-5

71-43-*

10041-01-3

110-73-9

73-23-2

371-78-4

10t-10-!

127-18-4

77-34-5

10I-K-3

10i-70-7

100-41-4

1 100-42-9!!

I1.2-JkhloroproMfli !

Trim 1.3-0ich3orooroflt»«

TrichlorocthMf

OlbroMckloroMthint

1.1.2-TrichlorNtfeiM

ImztN

cii-1.3-B:cklorotr«imt

2-ttIorMthvlviiivlftlMr

IroMfora

4-Mkvl-2-PMtanoM

2-f(fianont

Tttradilorotthttt

1 . 1 .2.2.-TfftrKklorMtkMff

Tel MM

CklorofemziM

EthflbMZMf

StVTH*

Total 1*1 MM!J

QUANT REPORT

Quant Rev: 6-;- ID: UBL92ri ]*• ~r-!CP10: :D3

i !-: >MCP10: : L2noECORP 10740625Qul o* SAMPLE * 5u I ISS *122 * 4.75ml OFW

Quant TimeIn jected at

D i l u t ion Factor

870610 22:41970^10 22:0'

1.OOOOt

: ID FILE FOP DAILY UOLATILE STANDARDCalibration: 870610 14:58

Compound R.T. Scant Area Lone Units

BROMOCHLOROME7HANEACETONE1 , 2- D I CHLOROETHANE-041 ,4-DIFLUOROBENZENECHLOPOBENZENE-D58ROMOFLUOROBENZENETOLUFMF-OR

SSS

ssssss

9712202l>2923

.90

.36

.67

.21

. 06

.55

.88

220153292492620738589

16139172327714168658635945295003095

50754650505049

.00

.31

.07

.00

.00

.50

.83

PPBPPBPPBPPBPPBPPBPPB

<%

(01100

ompound i^ ISTD

iON C!» >"CP19 40.0-360.0 AMU. F1PECORP 107406

TIC

aeooo-

34000-

20000-

16000-

13000-

6000-

4000-

230ul of SRnPLt *300 300 400 800 fepO 7pO 800

J

8.1.

Data File: >MCP10::L2Name: MAECORP 107406Misc: 250ul of SAMPLE * 5ul ISS #122

Quant Output File: *MCP10::D3

4.75ml OFU

Id File: ID_UDS: :U1T i t l e : ID FILE FOR DAILY VOLATILE STANDARDLast Calibration: 870610 14:58

Operator ID: USER2Quant Time: 870610 22:40Injected at: 870610 22:0?

pp r-ww

GPECTRUH' . \ " • • , " • » * ' ( OCr.TO«r. 860933 18l81 Sc*n 213-- i: (•:•< .-.*.•>? SUB 10.26 »ln .

~

r. oo OH

0-4

4?

\

88

/'I12 ' 44 ' 46 ' 4'e ' 80 ' 82 ' 8*4 ' 86 ' 68

hlOO

-0

(OPCKCROUMO SUBTRRCTED)F i l eBpk

1

>HCP10 nPECORP 107406Ob 1369

43

?00-

o-, . , , , . , . . , ,43

(44

43 44 46

aSOul of SPhPUE + 8ul ISS Scan 133SUB 7.36 nin.

-100

48 ' 8"0 ' rfa ' «J4 ' B1* ' 8*9SflMPLE SPECTRUM <UNRLTERED>n iBpb

•• >nCP10 MRECORP 107406 aSOul o>- SPMPUE + 5ul 1SS Se»n 1B3Rb 1369 7.36 mln .

43•i

100CH

CH

'

42

,x44

I[-100

-0*? 44 46 48 5"0 82 ^4 56 8fl

^i F i l e : >MCP10:=L2 Quant Output File:-.; M^ECORP 107406

MI-.C: 2^0ul of SAMPLE * 5u 1 ISS t!22 * 4.75rrl C1FUQuint Tim's: 970610 22:40 Quant ID File: ID_UDS::U1I n j e c t e d at: 8706JLO 22:05 Last. Calibration: 970610 14:58

Compound No: 8Compound Name: ACETONEScan Number: 153Retention Time: 7.36 min.Quent Ion: 42.9Area: 17232Concentration: 75.31 PPBq-va!ue: 92

W6AKICS ANALYSIS DATA SKIT

Hut fril> Coait Laborttorm. Inc. Caw Bo.__

Likoralory !' No. >/v\CR(2>^________ OC Itoort lo..

CUofer Contract to.

D*ti Author urt §y. Dati SMplt Rtcmtfl'.

CA5 t

Concentration:

Date EitractfflVPreparHi

Date Analyzed:_____

ICirclt Ont)

Cone/Oil«tion Factor: Ji.

Percent Noiiturti (Not Decanted)

ICi clf One) _

74-87-3

74-83-9

75-01-4

75-00-3

75-09 2

47-44-1

73-15-0

73-35-4

75-34-3

154-60-5

47-6*-3

! 107-04-2!! 7I-W-3!.' 71-35-41

> 54-23-3

! 108-03-4

! 75-27-4iiii

DuoroMthani

Irooonthanf

Vinyl Chlorirf*

Chloroctkant

Nfthylwe Chloride

Acctont

Carbon Oiwlfidt

1,1-OicMorottkMt

lil-DichlorottkaN

Trani-1.2-OicHlorwtnffnt

Chlorfforo

1.2-NcklaroftlMM

2-luttMMt

1.1.1-TricblorottNant

Carbon Tttractiloritft

Vinvl Acttati

Irooodickloroottkant

(10

<10

<10

<10

< 5

jMO-0.1

< 5

< 3

< 3

< 5

< 3

< 3

<10

< 3

< 3

<10

< 3

!

CA5Li]/])or uf/k(Circle Ont

78-97-5

10061-M>2-4

79-01-4

124-48-1

7?-00-5

7I-4J-2

10061-01-5

1KH7M

75-25-2

591-7B-4

108-10-1

127-11-4

7t-J4-3

10MI-3

10MO-7

IOM1-4

100-42-3

1.2-DichloroprONnf

Trans 1.3-Dichlorooroiwt

Trjchloro»thf«»

DibroMchloroMthant

1.1.2-Trichloroftliani

Itnitnt

cii-1 .3-BichloroDroMHf

2-OilorotthflnMltth*r

•Votofori

4-NttbvI-2-fMtaiMM

2-Hnanont

TttrackloroftlMN

I . l •2*2rTttricM orettlwui

TolMM

OllVitMZMt

EthvIbMZHM

StvrtM

1 Total IvlMH

< 5

< 5

< 3

< S

< 5

< 5

< 5

<10

< 5

<10

(10

{ s

< g

< 5

< 3

< S

< 5

L<13

C»»» NoN«/mb«f

Organic* Analysis Data Shaat

Tentatively ld*ntHi«d Compounds

CMCompewntfMwM

Eftimti*

\JOt\UOA

L VGA 64VOAVCAVGA H.OV

10.11.

18.1*.17.

99

Ii

I

QUANT REPORT

•rat or ID: USER2put File: ~MCP08::D3« File: >MCP08::L2-.s: MrtECORP 107407c: 5mL SAMPLE * 5uL 155*122

Quant Rev: 6 Quant Time:In jected at:

Dilut ion Factor:

870610 21:0)870610 20:2

1.0000

File: ID_UDS::U1le: ID FILE FOR DAILYt Calibration: 870610

Compound

VOLATILE14:58

STANDARD

R.T. Scan* Area Cone Units

•

**

BROMOCHLOROMETHANEACETONE1 ,2-DICHLOROETHANE-D41 , 4 - D I FLUOROBENZENECHLOROBENZENE-D5BROMOFLUOROBENZENETOLUENE-08

SSS

SSSSSS

9.7.12.20.25.29.23.

88346422085186

219152292492620737588

162665886483846468703601654872180298

50.2552.49.50.50.49.50.

00593900001190

PPBPPB™PPBPPBPPBPPB • »PPB (Do)

Compound is ISTD

L

«o o3 C TJ<-. a a9 3 1o •» a«-» iO H OQ. - T

a a —

( D O C\l MO)OOP]<K» JJ»-» h* NJ

10 roO f

is) o

r H «n ~ a(* rt--^ ~ -n

a —n •• —a a^— i-^ ••- Ocr ^T -n oa «|~ r c- moO (/)3 -n ••

CO l->\JO

o -c

Ml00

2 Z O- Ql ttO 3 ~n a a

vn 3 -3 3> -r m ao ••en oi> TO *3 TJ3-o n

M COO\j 10

enui

IO

rmU)

ZO

o

OC<-r-oC

•n>-•

o

n

*

»-

ro"

S-

s-

2-

r\>_<D

uro"

M rx> u> * 01 o>> -jo o o o o o oo o o o o o oo o o o o o o

?. . . . ? t . . .9. . . .? . . . ,? . . . .9. . . .9. . . . • ? . . .

^—-fr~

*

^ SURROa»TE

. — 1.4-aFUJO)tOBNZE>C

: »• ——— SURROGATE=*—— ——— CKOROBDCDC-Ofl

^==— SUWOQME

i^••^r-oo00

co1

-o S0

c

± 01*-o r0 c

e•vC

•OO

ar0)X

• 3

* sai

-ioD

jOzr>X

oD

Oa>s3

oCO

r

.TPNDPRO SPECTRUMr i 1« >ve^£3Bpk Ob £73?.

43'1 x

200C--t ',

^ J ' - ™

^

PCETONE 860923 12t81 ScanSUB 10.26

87 88\

44 ' 46 ' 48 ' 80 ' 82 ' 84 ' 36 SB ' &

213• in.

kioo

KJJ

PHPLE (BPCKBROUND SUBTRRCTEO)F i l « >nCP'.a HRECORP 107407Bpk Pb 49'j»,6

43-

4000O-"^

^l

42\

44\

42 44 46 48

SaL SPnPLC *SUB

82 83\ \

"sV ' 'rfe' '

SuL I3Stl22

88

84 ' 86

7

87 5(/ r' 88

Scan IB.?.34 »in.

9 g^

jL1-100

•O60

SfttlPLE SPf. CTRUtl <UNPLTEREO)r i l « >MCP08 MPECORP 107407Qp* Pb 49036

43, "v

40000-' 42- \

0- -,. -jL,-, . , . , . , , , .

44

\

42 44 46 48

3«L SPMPLE + SuL

82 83

\\.I ' I ' F ' T ' T T '80 82 84

ISS#122 Scan 182

88/

36

7.34 Mln.

hi 00

87 58 89/I / .88 ' 6*0

Da^fl File: >MCP08::L2Nflrr,-: MAECORP 107407M.-.c: 5mL SAMPLE * 5uL ISS#122Qu"r>» Time: 870610 21:08In.—.fed at: 870610 20:29

Compound No: 8Compound Name: ACETONEScan Number: 152Retention Time: 7.34 min.Quant Ion: 42.8Area! 588648Concentration: 2552.59 PPBq-value: 95

Quant Output File: AMCP08::D3

Quant ID File: ID_UDS::U1Last Calibration: 870610 14:58

f i l e? header -from t >MCP03

6/'<:•/87 20-1«: MAECOPP 1074O7 Operator: USER2 MS: 5mL SAMPLE •«• 5uL ISS#122

. f»: 3 MS model: 96 SW/HW rev.: !A ALS # : O'?thod file: JOHN Tuning file: TUNE3 No. of extra records: 2•jrce temp.: 150 Analyzer temp.: ISO Transfer line temp. : 280

Chrcmatographic temperatures : 45. 220. 0.Chromatographic times, min. : 3.0 20. O 0.0Chromatographic rate, deg/min: 8.0 0.0 0.0

O.0.00.0

0.0.00.0

r:08 MAECORP 1074070.0! 260.0 ADC TICi

5mL SAMPLE •»• 5uL ISS*122

DP:pe:

R.mi

2.5.7.?9.9.

1O.t I.12.14.

•

0.

T.n.

o->4. 4L.

40346688

22?A6408

20 Area Reject: 2.00 Results

first maxscan scan

1392145182214

225249286125

171O1152187219

228253292330

00 V. Max Peaks:File VDIR86 Sorted by

lastscan

26119179205225

235263302338

peakheight

86411229268043364 1 010516

1891284895952516

rawarea

1617871851738339973972701 16025

246*7297679917530918

9 Bunching:Time/Area

corr.area

9955517221481 6520 «'3783851 1030"5\ |

205272734797974 S30031

I NT

corr7. max

12.21.

y. too.46.

5 13.

2.~r•-••

S 12.3.

1

•

•

1909003451

5133OO68

y.t

42

Sum of corrected areas:

11:O3-AM THU. , 11

1752858.

JUNE, 1987

1* -MCP0840.0-260.0 amu. MflECQRP 107407ODC TIC

40

5mL SPMPLE

"0000

•L5000-

60000-4

55000-

50000-

45000-

40000-

35000-

iOOOO-

£5000-

1 0 '.' 0 0

5000- '

80 120 160 200 240

3

,J...U

280

5uL ISS#1£

320

.A A3.0 4.0 5.0 60 ?.0 10.0 11.0 1S.O 13.0 14.0 15.0

• f t C P v S PPECOPP 107407 5rv.L SAMPLE + 5uL ISS*122Mb 4i>d SUB ODD DVC

44

': c an 1 73 . i ii rri i n .

4142 43

C41.2 41.6 42.0 42.4 42.8 43.2 43.6 44.0 ' 44 .4 44.8

Sample filet >MCP08 Spectrum *s 17

No data base entries were retrieved.

I

!« 'HCP08 MftECORP'- fib 6492

41 42n. r"' i

42.0

i« :BIGOBt Pb 4887

"•

: 42/

42.0

107407 5mL SPMPLE + 5uL ISSOSUB POD OVC

4^ 441 xj

43.0 ' 44.0 ' 45.

Ethanol <flCNX9CI)

4!

43 44( /

.. I . . . » 1 i i i . l i i i i 1 ..' n i i i i -43.0 44.0 45.

U22 Scar, 1015.40 nun ,

45^ ,

lun0 46.0

Scan 1210.00 mm.

5

46 "/ ;1 •

0 46.0

1. Ethanol (ACN)(9CI) 46 C2H60

Sample filet >MCP08 Spectrum tttSearch «p»«di 1 Tilting optioni N

101No. o-f ion r*ng«« •••rchvdt

Prob.

1. 70#

CAS 4» CON # ROOT K DK #FLQ TILT Y. CON C_I

64175 121 "BIGDB 23 44 1 0 2O4 7 42

:» :MCP08 HPECORP 107407 5mL SAMPLE + 5uLPb £4970 SUB POO DVC

45. xx

j 41 42 -• 44 46 53

42 44 46 48 50 52 541* ,BIGD8 2-Propanol <PCNX9CI)t fib 9999

45

; 42 4^ 44-> "'} ^i

46

42 44 46 48 50 52 54

ISS#122 Scan 1878.66 «< i n .

57 58 59 :

1 ' 1 i "T • T ' 7"' ' 1"°56 53 60

Scar, 3260 .00 min .

55 56 57 58 59&C '.1 f f I / % •

56 58 60

1. 2-Propanol <ACN)(9CI) 60 C3H80

>*mpl» file» >MCP08 Spectrum #:speed: 1 Tilting option: N

187No. of ion ranges searchedi

Prob.

1. 88*

CAS # CON # ROOT K DK #FLQ TILT 7. CON C_I

67630 326 "BIBDB 41 26 0 0 77 3 63

* -MCPOe flOECORP 107407 5ml SflhPLE * 5uL ISS*122 Swb 493 SUB POO OVC 10.

42 '9500-i 41

r -3 ;5 *r*j i ^ i42 ' 44 ' 46 ' 48 ' 50 ' s'a 5*4 ' «fe 53

. 1* >BI60B l-Prop*nol <PCNX9CI> S^ flb 1059 0

42 «

I 43j -v 44 y> 46 55 56 3? g8J ^ -^ t t .{ /

42 44 46 48 50 52 54 56 58

can ii282i2 win .

-r-r O60)c»n 12700 rain.960 ,

J.60r i l « >BIGDB l-Propan«, 2-fluoro- (9CI> Scan 1845tok fib 9999 , ••«»• 0 .OO tiin.

59: - f6^t: 42 43 44 « 46 55 56 57 53 N F« : > > > < x / < { ( \ En

42 44 46 43 50 52 54 56 58• • l i e >BieOB l-Propene, 3-flucro- <9CI> S

3b ?9-?? 0«•«

: 42 43 44 45 46 47 43 49 50 51 52 55 56 57 58• -^ -^ --^ . x ' ^ ' x ' x - x ' / ' / / / / f /

1 • 1 • 1 • 1 • 1 • 1 • 1 • 1 • 1 • 1 ' 1 ' 1 ' 1 ' 1 ' 1 ' 1 '42 44 46 48 50 52 54 56 58

60can 1343.00 mm.5?'60

Xo60

1. 1-Propanol (ACN)(9CI)2. 1-Propene, 2-fluoro- (9CI)3. l-Prop»n«, 3—fluoro- (9CI)

60 C3HSO60 C3H5F60 C3H5F

Sampla -files >MCP08 Spactrum 4»i 22BSearch •pavdi 1 Tilting option: N NO. of ion rang** Marched!

1.

Prob.

70»20»20#

CAS * CON ft ROOT

712381184607818928

12718451843

"BIGDB"BIQDB"BIGDB

322525

DK *FLB TILT CON C_I F

41 167 269 2

0 8480 1000 89

95354

4255

SS3 BOdOW<

fig

•utw fS'TTT»fi

OAQ oob ans80d3U<

1L 8* OOI O T

I~3 NOD X nil

CB 12 80018,, 9C2I SSZ^Ol

tt NOO ft SW3

uoj

«CZ

N tuof^do T lp««d«80d3W< «»TT*

- I

09H23 8C (106) - •;

«*!*>•• < <**t*S.V JtsUi

6

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9C3T

£

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18 fr8 08 94 ZL 89 fr9 09"'"" " l t l / " " """">"

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18 fr8 08 9«i 3«i 89 fr9 09

1,80't»T OAQ oob ansu*=-S 33T#SSI l ifi + 3HdUbS T"S

94 34 6f frfr. i . i i i . i . i . i . i .

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MMIB MMLTtlS MM MOT

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Cone/tuition Factori.

Nrcnt Mitirti (Not

•l/MrcltJlBfl

: i! 74-17-3 I

74-13-9

73-01-4

73-00-3

73-Of-2

47-44-1

73-15-0 . Carfcaa

IrMMttlHBt

Vinyl Oilofi<t

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JfthrlMtlklariJi.

78-35-4 I 1.1-lidilardrtfcMt

79-34-3 I 1.1-ti

J47-44-3 I

I107-04-2 I 1.2-fictlyntfiajH

I7W3-3 I

J> 1.1.1-TiI

34*23-3 I CarkM Tttriefclvife

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(Clrclt IN)

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Iran 1.3-DicliloroDrMMt

QUANT REPORT

Quant Rev: 6 Quant Time:Injected at:

D i l u t i o n Factor:

•rator 10: USER2'put File: "t1CPll::D3'a File: >MCP11::L2•ne: MAECORP 107407^c: lOOul of SAMPLE * 9ul ISS #122 * 4.9ml OFU (1:90 DILUTION)

j File: IO_VDS::U1tie: 10 FILE FOR DAILY VOLATILE STANDARDst Calibration: 870610 14:98

870610 23:2<870610 22:4!

1.0000(

Compound R.T. Scant Area Cone Units

30:39;40

•BROMOCHLOROMETHANE.ACETONE1,2-DICHLOROETHANE-D4

•1,4-01FLUOROBENZENE•CHLOROBENZENE-D9BROMOFLUOROBENZENETOLUENE-D8

9.89 219 15999 90.00 PPB••««••

SSS

ssssss

12.6920.2329.0929.9223.87

292492619737988

3794470226692739312284832

7.39*. 152*- -10863" -48. 0149.1490.00 PPB90.00 PPB .49.36 PPB1T49..96 PPB^

" Compound it ISTD

TOTAL ION CHROMRTOORPflFilm >ncpn 40.o-2«o.o **u. HRCCORP 107407

T 1ClOOul Of SRflFLE * Si

20000-26000-24000-28000-20000-10000-16000-14000-12000-10000-6000-

«P? W

1Iij

u £8I isJ! !

|i

|

i 11

to a a« a*

Data File! >MCP1H:L2 Quant Output File: AMCP11::D3Namei MAECORP 107407Misd lOOul of SAMPLE * 5ul ISS #122 * 4.9ml OFU (1:90 OILUTIOl

Id F i l e t ID_UOS::U1Tit lei ID FILE FOR DAILY VOLATILE STANDARDLeet Ca l ibra t ion! 870610 14t98

Operator ID: USER2Quant Time: 870610 23:24In jec ted at: 870610 22:49

REFERENCE STRNOARO SPECTRUMFil« >YB923 RCETONE 8*0923 12l91 Sc*n 219Bpk Rb 2732 SUB 10.26 min.

43•

2000-

0^ ,

42/42

s98

/ 1

klOO•

(

•0•44' ' '4'*' ' '48' ' 'oV ' '&' ' '**' ' '&V ' '&

SPtlPLE SPECTRUM <BACK8ROUND SUBTRPCTED)Til* >MCP11 flPECORP 107407 lOOul of SAMPLE * 9ul 1?Bpk Rb 901 BUB

431000;

900-

Q!42

r

42 ' 4*4 ' 46 ' 4'8 ' 9*0 ' 9> ' ^4 '

S 8c«n 1527.39 »in.r& ' g'8

SRMPLE SPECTRUM (UNPLTEREO)Fll« >MCP11 MPECORP 107407Bpk Pb 901

431000:500: 42

(

I4141

4'8 ' 44 ' '4'*" '

lOOul of SPMPLE * 9ul ISS Se*n 1927.39 aln.

j-100

48 ' rfo ' 9'2 ' 9V ' 9-4 ' 'rfB

Data File: >MCPlls:L2 Quant Output File: *MCPll:tD3Name: MAECORP 107407M J S C : lOOul of SAMPLE * 5ul ISS #122 * 4.9ml OFU (1:50 DILUTIOQuant Time! 870610 23:24 Quant 10 File: ID_UDSt:UlIn jected at: 870610 22»45 Last Calibrationi 87*0610 14t9

Compound Not 8Compound Name: ACETONEScan Number! 152Retention Time: 7.35 min.Quant Ion: 42.8Area: 10863Concentration: 48.01 PPBq-value: 91