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Chemistry, The Central Science, 11th edition Theodore L. Brown, H. Eugene LeMay, Jr., Bruce E. Bursten, and Catherine J. Murphy Dana & Michelle Chatellier University of Delaware © Copyright 2009, Pearson Education Chapter 9 Molecular Geometry and Bonding Theories

Ch 9 review powerpoint

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Page 1: Ch 9 review powerpoint

Chemistry, The Central Science, 11th edition

Theodore L. Brown, H. Eugene LeMay, Jr., Bruce E. Bursten,

and Catherine J. Murphy

Dana & Michelle ChatellierUniversity of Delaware© Copyright 2009, Pearson Education

Chapter 9 Molecular Geometry and Bonding

Theories

Page 2: Ch 9 review powerpoint

The methane (CH4) molecule has what geometry?

a. linear

b. trigonal bipyramidal

c. trigonal planar

d. tetrahedral

Page 3: Ch 9 review powerpoint

The methane (CH4) molecule has what geometry?

a. linear

b. trigonal bipyramidal

c. trigonal planar

d. tetrahedral

Page 4: Ch 9 review powerpoint

The overall shape of a molecule is determined by its:

a. atoms.

b. bond angles.

c. symmetry.

d. electron affinity.

Page 5: Ch 9 review powerpoint

The overall shape of a molecule is determined by its:

a. atoms.

b. bond angles.

c. symmetry.

d. electron affinity.

Page 6: Ch 9 review powerpoint

The phosphorus trichloride (PCl3) molecule has what electron domain geometry?

a. tetrahedral

b. trigonal planar

c. pyramidal

d. trigonal bipyramidal

Page 7: Ch 9 review powerpoint

The phosphorus trichloride (PCl3) molecule has what electron domain geometry?

a. tetrahedral

b. trigonal planar

c. pyramidal

d. trigonal bipyramidal

Page 8: Ch 9 review powerpoint

The phosphorus trichloride (PCl3) molecule has what molecular geometry?

a. tetrahedral

b. trigonal planar

c. trigonal pyramidal

d. trigonal bipyramidal

Page 9: Ch 9 review powerpoint

The phosphorus trichloride (PCl3) molecule has what molecular geometry?

a. tetrahedral

b. trigonal planar

c. trigonal pyramidal

d. trigonal bipyramidal

Page 10: Ch 9 review powerpoint

What is the bond order in O2

2– ?

1. 02. 0.5

3. 1

4. 1.5

5. 2

Page 11: Ch 9 review powerpoint

What is the bond order in O2

2– ?

1. 02. 0.5

3. 1

4. 1.5

5. 2

Page 12: Ch 9 review powerpoint

The hybridization of the oxygen atom in a water molecule is:

a. sp

b. sp2

c. sp3

d. sp3d

Page 13: Ch 9 review powerpoint

The hybridization of the oxygen atom in a water molecule is:

a. sp

b. sp2

c. sp3

d. sp3d

Page 14: Ch 9 review powerpoint

The bromine trifluoride (BrF3) molecule has what geometry?

a. see-saw shaped

b. trigonal planar

c. pyramidal

d. T-shaped

Page 15: Ch 9 review powerpoint

The bromine trifluoride (BrF3) molecule has what geometry?

a. see-saw shaped

b. trigonal planar

c. pyramidal

d. T-shaped

Page 16: Ch 9 review powerpoint

The xenon tetrafluoride (XeF4) molecule has what geometry?

a. square planar

b. tetrahedral

c. see-saw shaped

d. trigonal bipyramidal

Page 17: Ch 9 review powerpoint

The xenon tetrafluoride (XeF4) molecule has what geometry?

a. square planar

b. tetrahedral

c. see-saw shaped

d. trigonal bipyramidal

Page 18: Ch 9 review powerpoint

The most stable geometry for six electron domains is:

a. square planar.

b. octahedral.

c. square pyramidal.

d. tetrahedral.

Page 19: Ch 9 review powerpoint

The most stable geometry for six electron domains is:

a. square planar.

b. octahedral.

c. square pyramidal.

d. tetrahedral.

Page 20: Ch 9 review powerpoint

In the formic acid (HCO2H) molecule, the values of the bond angles, in degrees, are:

a. O–C–O = 180, C–O–H = 120

b. O–C–O = 120, C–O–H = 109

c. O–C–O = 180, C–O–H = 180

d. O–C–O = 109, C–O–H = 109

Page 21: Ch 9 review powerpoint

In the formic acid (HCO2H) molecule, the values of the bond angles, in degrees, are:

a. O–C–O = 180, C–O–H = 120

b. O–C–O = 120, C–O–H = 109

c. O–C–O = 180, C–O–H = 180

d. O–C–O = 109, C–O–H = 109

Page 22: Ch 9 review powerpoint

In which molecule below is the central atom sp3d-hybridized?

a. CH4

b. SO3

c. SeBr4

d. XeOF4

Page 23: Ch 9 review powerpoint

In which molecule below is the central atom sp3d-hybridized?

a. CH4

b. SO3

c. SeBr4

d. XeOF4

Page 24: Ch 9 review powerpoint

How many pi bonds are there in the molecule below? CH3–CH=CH–CH=O

a. 1

b. 2

c. 3

d. 4

Page 25: Ch 9 review powerpoint

How many pi bonds are there in the molecule below? CH3–CH=CH–CH=O

a. 1

b. 2

c. 3

d. 4

Page 26: Ch 9 review powerpoint

Which are polar molecules?

1.a and b 2.a, b, and c 3.a and c4.a, c, and d 5.c and e

Page 27: Ch 9 review powerpoint

Which are polar molecules?

1.a and b 2.a, b, and c 3.a and c4.a, c, and d 5.c and e

Page 28: Ch 9 review powerpoint

What is the molecular geometry of NO2?

1.Linear 2.Bent 3.Trigonal planar 4.Tetrahedral 5.Pyramidal

Page 29: Ch 9 review powerpoint

What is the molecular geometry of NO2?

1.Linear 2.Bent 3.Trigonal planar 4.Tetrahedral 5.Pyramidal

Page 30: Ch 9 review powerpoint

What is the molecular geometry of XeF4?

1.Linear 2.Trigonal planar 3.Square planar4.Tetrahedral 5.Pyramidal

Page 31: Ch 9 review powerpoint

What is the molecular geometry of XeF4?

1.Linear 2.Trigonal planar 3.Square planar4.Tetrahedral 5.Pyramidal

Page 32: Ch 9 review powerpoint

1.sp 2.sp2 3.sp3

4.sp3d5.sp3d2

What is the hybridization of sulfur in

SO42–?

Page 33: Ch 9 review powerpoint

1.sp 2.sp2 3.sp3

4.sp3d5.sp3d2

What is the hybridization of sulfur in

SO42–?

Page 34: Ch 9 review powerpoint

1.sp 2.sp2 3.sp3

4.sp3d5.sp3d2

What is the hybridization of nitrogen in HNO3?

Page 35: Ch 9 review powerpoint

1.sp 2.sp2 3.sp3

4.sp3d5.sp3d2

What is the hybridization of nitrogen in HNO3?

Page 36: Ch 9 review powerpoint

1.sp 2.sp2 3.sp3

4.sp3d5.sp3d2

What is the hybridization of sulfur in methyl mercaptan, CH3SH?

Page 37: Ch 9 review powerpoint

1.sp 2.sp2 3.sp3

4.sp3d5.sp3d2

What is the hybridization of sulfur in methyl mercaptan, CH3SH?

Page 38: Ch 9 review powerpoint

How many sigma and pi bonds are in the molecule acetic acid,

CH3COOH? 1. 6 sigma bonds, 2 pi bonds2. 7 sigma bonds, 1 pi bond3. 7 sigma bonds, 2 pi bonds4. 8 sigma bonds, 0 pi bonds5. 8 sigma bonds, 1 pi bond

Page 39: Ch 9 review powerpoint

How many sigma and pi bonds are in the molecule acetic acid,

CH3COOH? 1. 6 sigma bonds, 2 pi bonds2. 7 sigma bonds, 1 pi bond3. 7 sigma bonds, 2 pi bonds4. 8 sigma bonds, 0 pi bonds5. 8 sigma bonds, 1 pi bond

Page 40: Ch 9 review powerpoint

How many sigma and pi bonds are present in sulfur

trioxide, SO3? 1. 4 sigma bonds, 0 pi bonds2. 4 sigma bonds, 1 pi bond3. 3 sigma bonds, 0 pi bonds4. 3 sigma bonds, 1 pi bond5. 3 sigma bonds, 2 pi bond

Page 41: Ch 9 review powerpoint

How many sigma and pi bonds are present in sulfur

trioxide, SO3? 1. 4 sigma bonds, 0 pi bonds2. 4 sigma bonds, 1 pi bond3. 3 sigma bonds, 0 pi bonds4. 3 sigma bonds, 1 pi bond5. 3 sigma bonds, 2 pi bond