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SiC Membranes for Pre-RO Filtration: Case Study

SiC Membranes Pre-RO Treatment of Scrubber Effluent: Case Study

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Page 1: SiC Membranes Pre-RO Treatment of Scrubber Effluent: Case Study

SiC Membranes forPre-RO Filtration:

Case Study

Page 2: SiC Membranes Pre-RO Treatment of Scrubber Effluent: Case Study

Reverse Osmosis

• Technology used to remove dissolved solids and impurities from water using semi-permeable membrane.• RO membrane requires water to

be under high pressure• Industrial RO systems can

remove up to 99.5% of dissolved salts/suspended solids from feedwater

Page 3: SiC Membranes Pre-RO Treatment of Scrubber Effluent: Case Study

RO can remove key contaminants

• Dissolved salts• Colloids• Organics• TSS

Page 4: SiC Membranes Pre-RO Treatment of Scrubber Effluent: Case Study

RO Pre-Treatment

• Performance of RO System depends highly on quality of pre-filtration

• Without proper pretreatment, fouling, scaling can occur causing membrane failure

• Increases cleaning requirements and OPEX

Page 5: SiC Membranes Pre-RO Treatment of Scrubber Effluent: Case Study

Why Pre-Treatment?

1. Improved pre-filtration with more efficient removal of suspended solids results in longer operating intervals of RO system before chemical cleaning.

2. Reduced chemical cleaning means prolonged lifetime for RO membranes and reduced OPEX.

3. Prior removal of TSS reduces fouling of RO membrane.

4. Quality and capacity of RO membrane is seen.

Page 6: SiC Membranes Pre-RO Treatment of Scrubber Effluent: Case Study

Our Solution

SiC Ceramic Membranes Ideal in scenarios with bio-fouling potential

Can be cleaned with any chemicals (pH 0-14), strong oxidziers (e.g. ozone) and have high mechanical strength enabling high pressure back flush

Ensures efficient cleaning and membrane selectivity at high temperatures

Page 7: SiC Membranes Pre-RO Treatment of Scrubber Effluent: Case Study

What can I remove?

• Oil • Grease• Iron• TSS• Bacteria • Algae• Organic Matter

Page 8: SiC Membranes Pre-RO Treatment of Scrubber Effluent: Case Study

Why SiC Membranes

• Oil repelling• Inert• Less Footprint• Longer lifetime• High Recovery• Self-cleaning

All this filtration can be accomplished in 1 single

step!

Page 9: SiC Membranes Pre-RO Treatment of Scrubber Effluent: Case Study

Why SiC over traditional methods

POLYMERIC MEMBRANES ARE • Not as chemically or temperature resistant as not good (ecspecially at high temperatures of oil&gas industry)

• Handle oil very poorly Polymeric membranes are

• Expensive • Low water flux

Page 10: SiC Membranes Pre-RO Treatment of Scrubber Effluent: Case Study

0.04 Micron 3,000 L/(m2hr)

4,000 L/(m2hr)

10,000 L/(m2hr)

>12,000 L/(m2hr)

FluxPore size

0.1 Microns

1 Microns

3 Microns

Filtration capability

Page 11: SiC Membranes Pre-RO Treatment of Scrubber Effluent: Case Study

How it works

Feed flow is tangential to the surface of the membrane in order to sweep rejected particles and solutes away

CROSS FLOW FILTRATION

Page 12: SiC Membranes Pre-RO Treatment of Scrubber Effluent: Case Study

Case Study: Filtration of

Scrubber Water

Application:• Wet scrubbers used for cleaning exhaust gases to reduce air pollution

• Harmful particles transferred from gas phase to scrubbing solution

• Liquid solution contains high amount of heavy metals -> must be removed to meet discharge limits

Challenge: • Scrubber water has fluctuating heavy metal conc.

• High T• Acidic or alkaline feedwater• High fouling potential due to scaling

Page 13: SiC Membranes Pre-RO Treatment of Scrubber Effluent: Case Study

Case Study: Filtration of

Scrubber Water

Test:H2O Systems to use SiC membranes to treat scrubber wastewater at Danish Biomass Fired Powerplant with 2 objectives:• Fulfill discharge requirements• Re-use scrubber wastewater as RO feedwater

Results:

Page 14: SiC Membranes Pre-RO Treatment of Scrubber Effluent: Case Study

Conclusion• SiC membrane installation capable of providing treated

water that meets discharge legislation requirements

• RO feed water quality is met (SDI <3)

• Improved quality of treated water (Table 1)

• Reduced footprint of filtration unit (35 m3/h system is 8 m2 with a height of 2.2 m)

• No need for chemical dosing/sludge disposal

• Chemical resistance of membrane protects against highly corrosive scrubber water

Page 15: SiC Membranes Pre-RO Treatment of Scrubber Effluent: Case Study

Future Outlook• SiC membranes allow for reduced installation costs with a smaller footprint and can meet future legislation requirements.

• Re-use of treated water in a closed loop reduces OPEX and environmental impact

• Polluted liquid treated by SiC membranes followed by RO membrane -> enables re-use of treated water

• 80% reduction of clean water use• Operating costs associated with waste discharge/sludge handling reduced by 90%

Page 16: SiC Membranes Pre-RO Treatment of Scrubber Effluent: Case Study

Next Steps• Meeting• Submit water analysis • Proposal and savings • Trial• Full systems intergration

Page 17: SiC Membranes Pre-RO Treatment of Scrubber Effluent: Case Study

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