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Direct enantio-convergent transformation of
racemic substrates without
racemization or symmetrization
Table of Contents
1. THE CHIRAL COMPOUND
– Synthesis or Resolution?
2. BORON CHEMISTRY
– Electrophile or Nucleophile?
3. ARTICLE R&D – Direct Enantio-Convergent
Transformation (DECT)
SUGA/ITOH Lab. Literature Seminar@2o12-06-07
M2 Kaoru ARISUE
Nature Chem. 2010, 2, 972.
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解説記事 月刊化学 有合化
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Kinetic Constant (A vs. B)
Calcd: kA/kB 98.4 : 1.6
Exptl: er 99.5 : 0.5
Kinetic Constant (C vs. D)
Calcd: kC/kD 91 : 9
Exptl: er 94 : 6
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