Upload
others
View
0
Download
0
Embed Size (px)
Citation preview
BOOKBACKONEMARKS
STD:XII SUB:CHEMISTRY
I.Choosethebestanswer:
1.AtomicStructure-II
2.Dualcharacterofanelectronwasexplainedby
a)Bohr b)Heisenberg c)de-Broglie d)Pauli
3.de-Broglieequationis
4.ThevalueofBohrradiusforhydrogenatom is
a)0.528×10-8cm b)0.529×10-10cm c)0.529×10-9cm d)0.529×10-12cm
5.Whichofthefollowingparticlehavingsamekineticenergy,wouldhavethemaximum de-
Broglie
wavelength
a)α-particle b)proton c)β-particle d)neutron
6.IftheenergyofanelectroninthesecondBohrorbitofH-atom is-E,whatistheenergyofthe
electronintheBohr’sfirstorbit?
a)2E b)-4E c)-2E d)4E
8.Thebondorderofoxygenmoleculeis
www.Padasalai.Net www.TrbTnpsc.com
http://www.trbtnpsc.com/2013/07/latest-12th-study-materials-2013.html
www.Padasalai.Net
a)2.5 b)1 c)3 d)2
9.ThehybridisationinSF6moleculeis
a)sp3 b)sp3d2 c)sp3d d)sp3d3
10.Theintramolecularhydrogenbondingispresentin
a)o-nitrophenol b)m-nitrophenol c)p-nitrophenol d)p-hydroxybenzaldehyde
2.PeriodicClassification–II
11.ThevalueofC-Cdistancefoundexperimentallyinasaturatedhydrocarbonis
a)1.34Å b)1.36Å c)1.54Å d)1.56Å
12.Onmovingdownthegroup,theradiusofanion
a)Decreases b)Increases c)Nochange d)Noneofthese
13.Effectivenuclearcharge(Z*)canbecalculatedbyusingtheformula
a)Z*=Z–S b)Z*=Z+S c)Z*=S–Z d)Z=Z*-S
14.Pickthecorrectstatement
a)Carbonhavingmorenuclearchargethanboron
b)Thesizeofcarbonatomsislargerthanboron
c)Carbonformselectrondeficientcompounds
d)Carbonformsioniccompounds
15.Comparingtheionizationenergyoffluorinewithcarbon,fluorinehas
a)higherionizationenergy b)lowerionizationenergy
c)sameionisationenergy d)noneofthese
16.Amongthefollowingwhichhasthemaximum ionizationenergy
a)Alkalielements b)Alkalineelements c)Halogens d)Noblegases
17.Theelectronaffinityofanatom is
www.Padasalai.Net www.TrbTnpsc.com
http://www.trbtnpsc.com/2013/07/latest-12th-study-materials-2013.html
www.Padasalai.Net
a)directlyproportionaltoitssizeb)inverselyproportionaltoitssize
c)isindependentofitssize d)noneofthese
18.Amongthefollowingwhichhashigherelectronaffinityvalue?
a)Fluorine b)Chlorine c)Bromine d)Iodine
19.Thescalewhichisbasedonanempiricalrelationbetweentheenergyofa
bondandtheelectronegativitiesofbondedatomsis……..scale
a)Pauling b)Mulliken’s c)Sanderson’s d)Alfredand
Rochow’s
20.Electronaffinityisexpressedin
a)kJ b)J c)kJmol d)kJmol-1
21.ThebondlengthofCl2moleculeis
a)0.74 b)1.44 c)1.98 d)2.28
22.Theorderofionizationenergy
a)s<p<d<f b)s>p>d>f c)s>d>p>f d)s<d<p<f
23.Acrosstheperiod,electronaffinity
a)decreases b)increases c)decreasesandtheincreases d)increases
andthendecreases
24.Noblegaseshave……………..electronaffinity.
a)High b)Low c)Zero d)Verylow
25.WhenXA>>XB,A–Bbondis
a)polarcovalent b)non-polarcovalentc)Ionic d)metallic
3.p–BlockElements
26.Whichofthefollowingdoesnotbelongtogroup13?
a)B b)Al c)Ge d)In
27.Whichofthefollowingismostabundantinearth’scrust?
www.Padasalai.Net www.TrbTnpsc.com
http://www.trbtnpsc.com/2013/07/latest-12th-study-materials-2013.html
www.Padasalai.Net
a)C b)Si c)Ge d)Sn
28.AnelementwhichwasburntinlimitedsupplyofairtogiveoxideAwhichontreatmentwith
water
givesanacid.B.AcidBonheatinggivesacidCwhichgivesyellowprecipitatewithAgNO3
solutionAis
a)SO2 b)NO2 c)P2O3 d)SO3
29.Thecompoundwithgarlicodouris
a)P2O3 b)P2O5 c)H3PO3 d)H3PO4
30.TheshapeofPCl5is
a)pyramidal b)trigonalbipyramidal c)linear d)tetrahedral
31.Thecompoundusedassmokescreen
a)PCl3 b)PCl5 c)PH3 d)H3PO3
32.Whichshowsonly-1oxidationstate?
a)fluorine b)bromine c)chlorine d)iodine
33.Onecandrawthemapofbuildingonaglassplateby
a)HI b)HF c)HBr d)HCl
34.Amongthehalogenacid,theweakestacidis
a)HF b)HCl d)HBr d)HI
35.Halogensbelongtothegroupnumber
a)14 b)15 c)17 d)18
36.Thenoblegasesareunreactivebecausethey
a)havesamenumberofelectrons b)haveanatomicityofone
c)aregaseswithlowdensities d)havestableelectronicconfiguration
37.TheshapeofXeF4withoutlonepairis
a)tetrahedral b)octahedral c)squareplanar d)pyramidal
38.Whichisnotknown?
www.Padasalai.Net www.TrbTnpsc.com
http://www.trbtnpsc.com/2013/07/latest-12th-study-materials-2013.html
www.Padasalai.Net
a)XeF6 b)XeF4 c)XeO3 d)ArF6
39.Thelightestgaswhichisnon-inflammableis
a)He b)H2 c)N2 d)Ar
40.Whichofthefollowinghashighestfirstionizationenergy?
a)He b)Ne c)Ar d)Kr
4.d-BlockElements
41.Thecorrectstatementinrespectofd-blockelementsis
a)Theyareallmetals b)Theyshowvariablevalency
c)Theyform colouredionsandcomplexslats d)allabovestatementarecorrect
42.Thegeneralelectronicconfigurationofd-blockelementsis
a)(n-1)d1-10ns0-2 b)(n-1)d1-5ns2 c)(n-1)d0ns1 d)(n-1)d1-10
ns1-2
43.d-blockelementsform colouredionsbecause
a)Theyabsorbsomeenergyford-stransition b)Theyabsorbsomeenergyforp-d
transition
c)Theyabsorbsomeenergyford-dtransition d)Theydonotabsorbanyenergy
44.Thecorrectelectronicconfigurationofcopperatom is
a)3d104s1 b)3d104s2 c)3d94s2 d)3d54s24p4
45.Copperisextractedfrom
a)cuprite b)copperglance c)malachite d)copperpyrites
46.Sodium thiosulphateisusedinphotographybecauseofits
a)Oxidizingbehaviour b)Reducingbehaviour
c)Complexingbehaviour d)Photochemicalbehaviour
47.Whichoftheionswillgivecolourlessaqueoussolution? a)Ni2+ b)Fe2+ c)
Cu2+ d)Cu+
48.Whichofthefollowingcompoundsisnotcoloured?
www.Padasalai.Net www.TrbTnpsc.com
http://www.trbtnpsc.com/2013/07/latest-12th-study-materials-2013.html
www.Padasalai.Net
a)Na2[CuCl4] b)Na2[CdCl4] c)K4[Fe(CN)6] d)K3[Fe(CN)6]
49.IntheextractionofCu,thereactionwhichdoesnottakeplaceintheBessemerconverteris
a)2CuFeS2+O2àCu2S+FeS+SO2 b)2Cu2S+3O2à2Cu2O+2SO2
c)2Cu2O+Cu2Sà6Cu+SO2 d)2FeS+3O2à2FeO+2SO2
50.Foratransistionmetalion,theeffectivemagneticmomentinBM isgivenbytheformula
a)Ön(n–1) b)Ön(n+1) c)Ön(n+2) d)
Ön(n+1)(n+2)
51.WhichcompoundisformedwhenexcessofKCNisaddedtoanaqueoussolutionofcopper
sulphate
a)Cu2(CN)2 b)K2[Cu(CN)6] c)K[Cu(CN)2] d)Cu2(CN)2+(CN)2
52.Thechemicalcompositionofslagformedduringthesmeltingprocessintheextractionof
copperis a)Cu2O+FeS b)FeSiO3 c)CuFeS2 d)
Cu2S+FeO
53.Thetransitionelementwiththelowestatomicnumberis
a)Scandium b)Titanium c)Zinc d)Lanthanum
54.Whichtransitionelementshowhighestoxidationstate a)Scb)Ti c)Os d)Zn
55.Theelectronicconfigurationofchromium is
a)3d64s0 b)3d54s1 c)3d44s2 d)3d34s24p1
56.Paramagnetism isthepropertyof
a)pairedelectrons b)completelyfilledelectronicsubshells
c)unpairedelectrons d)completelyvacantelectronicsubshells
57.Silversaltusedinphotographyis a)AgCl b)AgNO3 c)AgF d)
AgBr
58.Whichofthefollowinghasthemaximum numberofunpairedelectrons?
a)Mn2+ b)Ti3+ c)V3+ d)Fe2+
59.Amongthefollowingstatement,theincorrectoneis
a)Calmineandsideritearecarbonates b)Argentiteandcupriteareoxides
www.Padasalai.Net www.TrbTnpsc.com
http://www.trbtnpsc.com/2013/07/latest-12th-study-materials-2013.html
www.Padasalai.Net
c)Zincblendeandpyritesaresulphides d)Malachiteandazuriteareoresof
copper
60.Selectthecorrectstatement
a)Allcuproussaltsareblueincolour b)Transitionmetalsarehighlyreactive
c)Allcuproussaltsarewhiteincolour d)Mercuryisaliquidmetal
61.ChoosethewrongstatementregardingK2Cr2O7
a)Itisapowerfuloxidizingagent b)Itisusedintanningindustry
c)Itissolubleinwater d)itreducesferricsulphatetoferroussulphate
62.Excessofsodium hydroxidereactswithzinctoform
a)ZnH2 b)Na2ZnO2 c)ZnO d)Zn(OH)2
63.Whichofthefollowingcompoundswillnotgivepositivechromylchloridetest?
a)CuCl2 b)HgCl2 c)ZnCl2 d)C6H5Cl
64.Formationofcolouredionsispossiblewhencompoundscontains
a)pairedelectrons b)unpairedelectrons
c)lonepairsofelectrons d)noneoftheabove
65.Paramagnetism iscommonin…………elements.
a)p-block b)d-block c)s-block d)f-block
66.ThecolourofTi(H2O)63+ionisdue
a)d-dtransition b)Presenceofwatermolecules
c)Interatomictransferofelectrons d)Noneoftheabove
5.f-BlockElements
67.TheelectronicconfigurationofLanthanidesis
a)[Xe]4f05d06s0 b)[Xe]4f1-75d16s1 c)[Xe]4f1-145d16s2 d)[Xe]4f1-14
5d1-106s2
www.Padasalai.Net www.TrbTnpsc.com
http://www.trbtnpsc.com/2013/07/latest-12th-study-materials-2013.html
www.Padasalai.Net
69.TheelectronicconfigurationofActinidesis
a)[Rn]5f0-146d07s0 b)[Rn]5f0-146d0-27s0 c)[Rn]5f0-146d0-27s1 d)
[Rn]5f0-146d0-27s2
70.Thelanthanidecontractionisresponsibleforthefactthat
a)ZnandYhaveaboutthesameradius b)ZrandNbhavesimilaroxidationstate
c)ZrandHfhaveaboutthesameradius d)ZrandZnhavethesameoxidationstate
71.Themostcommonoxidationstateoflanthanidesis a)+2 b)+1 c)+3
d)+4
72.Lanthanidesareextractedfrom
a)Limonite b)Monazite c)Magnetite d)Cassiterite
73.Theelementsinwhichtheextraelectronenters(n-2)forbitalsarecalled…….elements
a)sblock b)pblock c)dblock d)fblock
74.TheLanthanidescontractionisdueto
a)Perfectshieldingof4felectron b)Imperfectshieldingof4felectron
c)Perfectshieldingof3delectron d)Imperfectshieldingof3delectron
75.Ceriaisusedin
a)toys b)tracerbullets c)gaslampmaterials d)
noneoftheabove
76._______isusedingaslampmaterial a)MnO2 b)CeO2 c)N2O5 d)Fe2O3
77.AlloysofLanthanidesarecalledas
a)Mish-metals b)Metalloids c)Platemetals d)Actinides
78.MetallothermicprocessesinvolvingLanthanidesarecalledas……..process.
a)Aluminothermic b)Lanthanido-thermic c)Reductionprocess d)Oxidation
process
79._______form oxocations
a)Lanthanides b)Actinides c)Noblegases d)
Alkalimetals
www.Padasalai.Net www.TrbTnpsc.com
http://www.trbtnpsc.com/2013/07/latest-12th-study-materials-2013.html
www.Padasalai.Net
80.Maximum oxidationstateexhibitedbyLanthanidesis a)+1b)+2 c)+3 d)+4
81.Lanthanidesareseparatedby
a)Fractionaldistillation b)Steam distillation c)FractionalCrystallisationd)Sublimation
6.CoordinationandBioCoordinationCompounds
82.Whichadoublesalt
a)K2SO4.Al2(SO4)3.24H2O b)NaCl c)K4[Fe(CN)6] d)KCl
83.Anexampleofacomplexcompoundhavingcoordinationnumber4.
a)K4[Fe(CN)6] b)[Co(en)3]Cl3 c)[Fe(H2O)6]Cl3 d)[Cu(NH3)4]Cl2
84.Thegeometryof[Cu(NH3)4]2+complexion
a)Linear b)Tetrahedral c)Squareplanar d)Angular
85.Anexampleofachelatingligandis a)NO-2 b)Chloro c)Bromo d)en
86.Whichisnotananioniccomplex?
a)[Cu(NH3)4Cl2 b)K4[Fe(CN)6] c)K3[Fe(CN)6] d)[NiCl4]2-
87.Thegeometryof[Ni(CN)4]2-is
a)Tetrahedral b)Squareplanar c)Triangular d)Octahedral
88.Anexampleofanambidentateligandis a)CN- b)Cl- c)NO2- d)I-
89.[FeF6]4-isparamagneticbecause
a)F-isaweakerligand b)F-isastrongligand c)F-isaflexidentateligand d)F-is
achelatingligand
90.In[FeII(CN)6]4-,thecentralmetalionis a)Fe b)Fe+2 c)Fe+3 d)CN-
91.ThecoordinationnumberofNi(II)in[Ni(CN)4]2-is a)2 b)4 c)5
d)6
92.Thegeometryofcomplexion[Fe(CN)6]4-is
a)tetrahedral b)squareplanar c)Octahedral d)triangular
93.TheoxidationnumberofNickelinthecomplexion,[NiCl4]2-is a)+1b)-1 c)+2 d)-2
www.Padasalai.Net www.TrbTnpsc.com
http://www.trbtnpsc.com/2013/07/latest-12th-study-materials-2013.html
www.Padasalai.Net
94.Thenameof[PtIV(NH3)2Cl2)2+is
a)Diamminedichloroplatinum (IV)ion b)Diamminedichloroplanitate(IV)
c)Diamminedichloroplatinum d)Dichlorodiammineplatinum(IV)ion
95.ForacompoundK4[Fe(CN)6]à4K++[Fe(CN)6]4-,thecomplexionis
a)K+ b)CN- c)Fe2+ d)[Fe(CN)6]4-
96.Ametalionfrom thefirsttransitionseriesformsanoctahedralcomplexwithmagnetic
momentof
4.9BM andanotheroctahedralcomplexwhichisdiamagnetic.Themetalionis
a)Fe2+ b)Co2+ c)Mn2+ d)Ni2+
97.Paramagneticmomentisexpressedin a)Debyeunitb)KJoules c)BM d)ergs
98.Thetypeofisomerism foundinthecomplexes[Co(NO2)(NH3)5]SO4and[Co(SO4)(NH3)5]NO2
a)Hydrateisomerism b)Coordinationisomerism
c)Linkageisomerism d)Ionisation
99.Valencebondtheorydoesnotexplainthepropertyofcomplexcompound
a)geometry b)magnetic c)natureofligand d)colour
7.NuclearChemistry
100.Inthenuclearreaction,92U238à82Pb206,thenumberofaandbparticlesemittedare
a)7a,5b b)6a,4b c)4a,3b d)8a,6b
101.Lossofab-particleisequivalentto
a)Increaseofoneprotononly b)Decreaseofoneneutrononly c)Both(a)and(b)
d)Noneofthese
102.Radioactivityisdueto
a)Stableelectronicconfiguration b)Stablenucleus
c)Unstablenucleus d)Unstableelectronconfiguration
103.Whichoneofthefollowingparticlesisusedtobombard13Al27togive15p30andaneutron
www.Padasalai.Net www.TrbTnpsc.com
http://www.trbtnpsc.com/2013/07/latest-12th-study-materials-2013.html
www.Padasalai.Net
a)aparticle b)deuteron c)proton d)neutron
104.Inthefollowingradioactivedecay,92X232à89Y220,howmanyaandbparticlesareejected.
a)3aand3b b)5aand3b c)3aand5b d)5aand5b
105.Thephenomenonofradioactivitywasdiscoveredby
a)Madam curie b)Pierrecurie c)HenryBecquerrel d)Rutherford
108.Thereaction5B8à4Be8takesplacedueto
a)adecay b)bdecay c)γ-emmision d)positron
decay
109.92U235nucleusabsorbsaneutronanddisintegratesinto54Xe139,38Sr94andx.Whatwillbe
the
productx?
a)3neutrons b)2neutrons c)aparticle d)bparticle
110.Whichofthefollowingisusedasneutronabsorberinthenuclearreactor?
a)Water b)Deuterium c)Somecompound d)Cadmium
111.Themostpenetratingradiationsare
a)arays b)brays c)grays d)allareequallypenetrating
8.SolidState-II
112.ThecrystalstructureofCsClis
a)Simplecubic b)face-centredcubicc)Tetragonal d)Bodycentredcubic
113.Semiconductorsareusedas
a)rectifiers b)transistors c)solarcells d)alltheabove
114.IntheBragg’sequationfordiffractionofX-rays,‘n’represents
a)Thenumberofmoles b)Avogadronumber
c)Aquantum number d)Orderofreflection
115.Semiconductorswhichexhibitconductivityduetotheflowofexcessnegativeelectrons
arecalled
www.Padasalai.Net www.TrbTnpsc.com
http://www.trbtnpsc.com/2013/07/latest-12th-study-materials-2013.html
www.Padasalai.Net
a)Superconductors b)n-typesemiconductors
c)p-typesemiconductos d)Insulators
116.Anexampleofmetaldeficiencydefect a)NaCl b)AgCl c)CsCl
d)FeS
117.ThenumberofchlorideionsthatsurroundsthecentralNa+ioninNaClcrystalis………….
a)12 b)8 c)6 d)4
118.Aregularthreedimensionalarrangementofidenticalpointsinspaceiscalled
a)Unitcell b)Spacelattice c)Primitive d)
Crystallography
119.Thesmallestrepeatingunitinspacelatticewhichwhenrepeatedoverandagainresultsin
thecrystal
ofthegivensubstanceiscalled
a)Spacelattice b)Crystallattice c)Unitcell d)Isomorphism
120.AnexampleforFrenkeldefectis a)NaCl b)AgBr c)CsCl d)FeS
121.Thecrystalswhicharegoodconductorsofelectricityandheatare
a)Ioniccrystals b)Molecularcrystals
c)Metalliccrystals d)Covalentcrystals
122.Inasimplecubiccell,eachpointonacornerissharedby
a)Oneunitcell b)Twounitcell c)8unitcell d)4unitcell
123.Theabilityofcertainultracoldsubstancestoconductelectricitywithoutresistanceis
called
a)Semiconductor b)Conductor c)Superconductor d)Insulator
124.Thetotalnumberofatomsperunitcellisbccis a)1 b)2 c)3 d)4
125.Rutileis a)TiO2 b)Cu2O c)MoS2 d)Ru
126.TheBragg’sequationis a)l=2dSinq b)nd=2lSinq c)2l=ndSinq
d)nl=2dSinq
127.Thenumberofcloseneighboursinabodycentredcubiclatticeofidenticalspheresis
a)6 b)4 c)12 d)8
www.Padasalai.Net www.TrbTnpsc.com
http://www.trbtnpsc.com/2013/07/latest-12th-study-materials-2013.html
www.Padasalai.Net
9.Thermodynamics-II
128.Theamountofheatexchangedwiththesurroundingatconstanttemperatureandpressure
iscalled
a)ΔE b)ΔH c)ΔS d)ΔG
129.Allthenaturallyoccuringprocessesproceedspontaneouslyinadirectionwhichleadsto
a)decreaseofentropy b)increaseinenthalpy c)increaseinfreeenergy d)
decreaseoffreeenergy
130.Inanadiabaticprocesswhichofthefollowingistrue?
a)q=w b)q=0 c)ΔE=q d)PΔV=0
131.Whenaliquidboils,thereis
a)anincreaseinentropy b)adecreaseinentropy
c)anincreaseinheatofvapourisation d)anincreaseinfreeenergy
132.IfΔGforareactionisnegative,thechangeis
a)Spontaneous b)Non-spontaneous c)Reversible d)Equilibrium
133.Whichofthefollowingdoesnotresultinanincreaseintheentropy?
a)crystallisationofsucrosefrom solution b)rustingofiron
c)conversionoficetowater d)vaporisationofcamphor
134.Inwhichofthefollowingprocess,theprocessisalwaysnon-feasible?
a)ΔH>0,ΔS>0 b)ΔH<0,ΔS>0 c)ΔH>0,ΔS<0 d)ΔH<0,ΔS<0
135.ChangeinGibb’sfreeenergyisgivenby
a)ΔG=ΔH+TΔS b)ΔG=ΔH–TΔS c)ΔG=ΔH×TΔS d)Noneoftheabove
136.Forthereaction2Cl(g)→ Cl2(g),thesignsofΔHandΔSrespectivelyare
a)+,– b)+,+ c)–,– d)–,+
10.ChemicalEquilibrium
www.Padasalai.Net www.TrbTnpsc.com
http://www.trbtnpsc.com/2013/07/latest-12th-study-materials-2013.html
www.Padasalai.Net
137.Stateofchemicalequilibrium is
a)dynamic b)stationery c)none d)both
138.Iftheequilibrium constantsofthefollowingreactionsare2A«BisK1andB«2AisK2,then
a)K1=2K2 b)K1=1/K2 c)K2=1/K2 d)K1=1/K22
139.Inthereversiblereaction2HI«H2+I2,Kpis
a)greaterthanKc b)lessthanKc c)EqualtoKc d)Zero
140.Intheequilibrium N2+3H2«2NH3,themaximum yieldofammoniawillbeobtainedwiththe
processhaving
a)lowpressureandhightemperature b)lowpressureandlowtemperature
c)hightemperatureandhighpressure d)highpressureandlowtemperature
141.Forthehomogeneousgasreactionat600K 4NH3(g)+5O2(g)«4NO(g)+6H2O(g)the
equilibrium constantKchastheunit
a)(moldm-3)-2 b)(moldm-3) c)(moldm-3)10 d)(moldm-3)-9
142.Twomolesofammoniagasareintroducedintoapreviouslyevacuated1.0dm3vesselin
whichit
partiallydissociatesathightemperature.Atequilibrium 1.0moleofammoniaremains.The
equilibrium constantKcforthedissociationis
a)27/16(moledm-3)2 b)27/8(moledm-3)2 c)27/4(moledm-3)2 d)
None
143.Anequilibrium reactionisendothermicifK1andK2aretheequilibrium constantsatT1
andT2
temperaturesrespectivelyandifT2isgreaterthanT1then
a)K1islessthanK2 b)K1isgreaterthanK2 c)K1isequaltoK2 d)Noneof
these
11.ChemicalKinetics-II
144.HydrolysisofanesterbydiluteHClisanexamplefor
www.Padasalai.Net www.TrbTnpsc.com
http://www.trbtnpsc.com/2013/07/latest-12th-study-materials-2013.html
www.Padasalai.Net
a)secondorderreaction b)zeroorderreaction
c)pseudofirstorderreaction d)firstorderreaction
145.Theunitofzeroorderrateconstantis
a)litremol-1sec-1 b)mollitre-1sec-1 c)sec-1 d)litre2sec-1
146.Theexcessenergywhichamoleculemustpossesstobecomeactiveis knownas
a)kineticenergy b)thresholdenergy c)potentialenergy d)activation
energy
147.Arrheniusequationis
a)k=Ae-1/RT b)k=Ae-RT/Ea c)k=Ae-Ea/RT d)k=AeEa/RT
148.Theterm AinArrheniusequationiscalledas
a)Probabilityfactor b)Activationofenergy c)Collisionfactor
d)Frequencyfactor
149.Thesum ofthepowersoftheconcentrationtermsthatoccurintherateequationiscalled
a)molecularity b)order c)rate d)rateconstant
150.Reactionsinwhichthereactingmoleculesreactinmorethanonewayyieldingdifferent
setof
productsarecalled
a)consecutivereactionsb)parallelreactions c)opposingreactions d)
chainreactions
151.Thehalflifeperiodofafirstorderreactionis10minutes.Theitsrateconstantis
a)6.93x102min-1 b)0.693x10-2min-1 c)6.932x10-2min-1 d)
69.3x10-1min-1
152.Forareaction:aA-----àbB,therateofreactionisdoubledwhentheconcentrationofAis
increasedbyfourtimes.Therateofreactionis
a)k[A]a b)k[A]1/2 c)k[A]1/a d)k[A]
153.2N2O5-----à4NO2+O2,d[N2O5]/dt=kl[N2O5],d[NO2]/dt=k2[N2O5]andd[O2]/dt=k[N2O5],the
relationbetweenk1,k2andk3is
www.Padasalai.Net www.TrbTnpsc.com
http://www.trbtnpsc.com/2013/07/latest-12th-study-materials-2013.html
www.Padasalai.Net
a)2k1=4k2=k3 b)k1=k2=k3 c)2k1=k2=4k3 d)2k1=k2=k3
154.Forareaction,Ea=0andK=4.2x105sec-1at300K,thevalueofkat310Kwillbe
a)4.2105sec-1 b)8.4x105sec-1 c)7.4x104sec-1 d)unpredictable
12.SurfaceChemistry
155.Themigrationofcolloidalparticlesundertheinfluenceofanelectricfieldisknownas
a)electroosmosis b)cataphoresis c)electrodialysis d)
dialysis
156.Whichoneisthecorrectfactorthatexplainstheincreaseofrateofreactionbyacatalyst
a)shapeselectivity b)particlesize
c)increaseoffreeenergy d)loweringofactivationenergy
157.Fogisacolloidalsolutionof
a)gasinliquid b)liquidingas c)gasinsolid d)solidingas.
158.ThephenomenonofTyndall’seffectisnotobservedin
a)emulsion b)colloidalsolution c)truesolution d)None
159.TheTyndall’seffectassociatedwithcolloidalparticlesisdueto
a)presenceofcharge b)scatteringoflight c)absorptionoflight d)
reflectionoflight
160.Incaseofphysicaladsorption,thereisdesorptionwhen
a)temperatureincreases b)temperaturedecreases
c)pressureincreases d)concentrationincreases
161.Colloidalmedicinesaremoreeffectivebecause
a)theyareclean b)theyareeasytoprepare
www.Padasalai.Net www.TrbTnpsc.com
http://www.trbtnpsc.com/2013/07/latest-12th-study-materials-2013.html
www.Padasalai.Net
c)theyaresolubleinwater d)theyareeasilyassimilatedandadsorbed
162.Oilsolubledyeismixedwithemulsionandemulsionremainscolourlessthen,theemulsion
is
a)O/W b)W/O c)O/O d)W/W
163.Forselectivehydrogenationofalkynesintoalkenethecatalystusedis
a)Niat250°C b)Ptat25°C
c)Pd,partiallyinactivatedbyquinoline d)Raneynickel
164.Forchemisorption,whichiswrong
a)irreversible b)itrequiresactivationenergy
c)itformsmultimolecularlayersonadsorbate d)surfacecompoundsareformed
165.Anemulsionisacolloidalsolutionof
a)twosolids b)twoliquids c)twogases d)onesolidandone
liquid
166.Colloidsarepurifiedby
a)precipitation b)coagulation c)dialysis d)
filtration
13.ElectroChemistry-I
167.Theprocessinwhichchemicalchangeoccursonpassingelectricityistermedas.
a)neutralization b)hydrolysis c)electrolysis d)ionization
168.Thelawsofelectrolysiswereenunciatedfirstby...............
a)Dalton b)Faraday c)Kekule d)Avogadro
169.Whenonecoulombofelectricityispassedthroughanelectrolyticsolution,themass
depositedonthe
electrodeisequalto...............
a)equivalentweight b)molecularweight c)electrochemicalequivalentd)onegram
170.Faraday’slawsofelectrolysisarerelatedto...............
www.Padasalai.Net www.TrbTnpsc.com
http://www.trbtnpsc.com/2013/07/latest-12th-study-materials-2013.html
www.Padasalai.Net
a)atomicnumberofthecation b)atomicnumberoftheanion
c)equivalentweightoftheelectrolyte d)speedofthecation
171.Thespecificconductanceofa0.01M solutionofKClis0.0014ohm-1cm-1at250C.Its
equivalent
conductanceis...............
a)14ohm–1cm2eq–1 b)140ohm–1cm2eq–1 c)1.4ohm–1cm2eq–1 d)0.14ohm–1
cm2eq–1
172.TheequivalentconductivityofCH3COOHat250Cis80ohm-1cm2eq-1andatinfinitedilution
400ohm-1cm2eq-1.ThedegreeofdissociationofCH3COOHis.............
a)1 b)0.2 c)0.1 d)0.3
173.Whensodium acetateisaddedtoaceticacid,thedegreeofionisationofaceticacid....
a)increases b)decreases c)doesnotchange d)becomes
zero
174.NH4OHisaweakbasebecause...............
a)ithaslowvapourpressure b)itisonlypartiallyionised
c)itiscompletelyionised d)ithaslowdensity
176.Ostwald’sdilutionlawisapplicableinthecaseofthesolutionof...............
a)CH3COOH b)NaCl c)NaOH d)H2SO4
177.Whichoneofthefollowingrelationshipiscorrect?
a)pH=1/[H+] b)pH=log10[H+] c)log10pH=[H+] d)pH=log101/[H+]
178.When10–6moleofamonobasicstrongacidisdissolvedinonelitreofsolvent,thepHof
thesolution
a)6 b)7 c)lessthan6 d)morethan7
179.WhenpHofasolutionis2,thehydrogenionconcentrationinmoleslitre-1is....
www.Padasalai.Net www.TrbTnpsc.com
http://www.trbtnpsc.com/2013/07/latest-12th-study-materials-2013.html
www.Padasalai.Net
a)1x10–12 b)1x10–2 c)1x10–7 d)1x10–4
180.ThepHofasolutioncontaining0.1NNaOHsolutionis.......... a)1 b)10–1
c)13 d)10–13
181.AsolutionwhichisresistanttochangesofpHonadditionofsmallamountsofanacidor
abaseis
knownas.............
a)buffersolutionb)truesolution c)isohydricsolution d)idealsolution
182.Thehydrogenionconcentrationofabuffersolutionconsistingofaweakacidanditssalt
isgivenby
a)[H+]=Ka[Acid]b)[H+]=Ka[salt] c)[H+]=Ka[Acid] d)[H+]=Ka [salt]
[salt] [acid]
183.Indicatorsusedinacid-basetitrationsare...........
a)strongorganicacids b)strongorganicbases
c)weakorganicacidsorweakorganicbases d)non-electrolyte
184.Forthetitrationbetweenoxalicacidandsodium hydroxide,theindicatorusedin...........
a)potassium permanganate b)phenolphthalein c)litmus d)methyl
orange
16.HydroxyDerivatives
185.Whichhasthehighestboilingpoint? a)CH3CH3 b)CH3OH c)C2H5OH d)C3H8
186.WhichissolubleinH2O?
a)Phenol ` b)Alkanes c)Alcohols d)Alkenes
187.Orderofreactivityofalcoholtowardssodium metalis
a)primary<secondary>tertiary b)primary>secondary>tertiary
c)primary<secondary<tertiary d)primary>secondary<tertiary
188.Theboilingpointofethylalcoholshouldbelessthanthatof
www.Padasalai.Net www.TrbTnpsc.com
http://www.trbtnpsc.com/2013/07/latest-12th-study-materials-2013.html
www.Padasalai.Net
a)propane b)formicacid c)dimethylether d)Noneofthe
above
189.EthylalcoholcannotbeusedasasolventforCH3MgIbecause
a)CH3MgIreactswithalcoholgivingmethane
b)Thereactionbetweenthem isexplosiveinnature
c)CH3MgIisconvertedtoC2H5MgI d)AlcoholisimmiciblewithCH3MgI
190.Whenalcoholsareconvertedtoalkylchloridesbythionylchlorideinpresenceofpyridine
the
intermediateformedis
a)sulphonium ion b)chlorosulphonicacid
c)alkylchlorosulphite d)chlorosulphite
191.Onoxidationofanalcoholgivesanaldehydehavingthesamenumberofcarbonatomsas
thatofalcohol.Thealcoholis
a)1oalcohol b)2oalcohol c)3oalcohol d)None
192.Acompoundthatgivesapositiveiodoform testis
a)1-pentanol b)2-pentanone c)3-pentanone d)
pentanal
193.ThecompoundthatreactsfastestwithLucasreagentis
a)butan-1-ol b)butan-2-ol c)2-methylpropan-1-ol d)2-methylpropan-2-ol
194.Theionizationconstantofphenolishigherthanthatofethanolbecause
a)phenoxideionisbulkierthanethoxide b)phenoxideionisstrongerbasethan
ethoxide
c)phenoxideionisstablizedthroughdelocalization
d)phenoxideionislessstablethanethoxideion
195.Amongthefollowingcompoundsstrongestacidis
a)CH≡CH b)C6H6 c)C2H6 d)
CH3OH
www.Padasalai.Net www.TrbTnpsc.com
http://www.trbtnpsc.com/2013/07/latest-12th-study-materials-2013.html
www.Padasalai.Net
196.p-nitrophenolishavinglowerpKavaluethanphenolbecause
a)phenolismoreacidicthanp-nitrophenol
b)anionofp-nitrophenolismorestabilisedbyresonancethanthatofphenol
c)degreeofionisationofp-nitrophenolislessthanthatofphenol
d)anionofp-nitrophenolislessstablethanthatofphenol
197.ThereactionofLucasreagentisfastwith
a)(CH3)3COH b)(CH3)2CHOH c)CH3(CH2)2OH d)CH3CH2OH
198.WhenphenolisdistilledwithZndustitgives
a)benzaldehyde b)benzoicacid c)toluene d)benzene
199.Acompoundthatundergoesbrominationeasilyis
a)benzoicacid b)benzene c)phenol d)toluene
200.Isomerism exhibitedbyethyleneglycolis……….isomerism
a)position b)chain c)functional d)both(a)
and(c)
201.Ethylenediamineisconvertedtoethyleneglycolusing
a)Na2CO3solution b)nitrousacid c)NaHCO3(aqueous) d)Baeyer’sreagent
202.Ethyleneglycolformsterylenewith
a)adipicacid b)phthalicanhydride c)terephthalicacid d)oxalicacid
203.1-propanoland2-propanolcanbebestdistinguishedby
a)oxidationwithKMnO4followedbyreactionwithFehlingsolution
b)oxidationwithacidicdichromatefollowedbyreactionwithFehlingsolution
c)oxidationbyheatingwithcopperfollowedbyreactionwithFehlingsolution
d)oxidationwithconcentratedH2SO4followedbyreactionwithFehlingsolution
204.Glycerolisused
a)asasweeteingagent b)inthemanufactureofgoodqualitysoap
c)inthemanufactureofnitroglycerin d)inalltheabove
www.Padasalai.Net www.TrbTnpsc.com
http://www.trbtnpsc.com/2013/07/latest-12th-study-materials-2013.html
www.Padasalai.Net
205.Thealcoholobtainedbythehydrolysisofoilsandfatsis
a)pentanol b)propanol c)glycerol d)glycol
206.Thenumberofsecondaryalcoholicgroupinglycerolis a)1 b)2 c)3
d)0
207.Theactivecomponentofdynamiteis
a)Keiselghur b)Nitroglycerine c)Nitrobenzene d)Trinitrotoluene
208.ThereactionofethyleneglycolwithPI3gives
a)ICH2CH2I b)CH2=CH2 c)CH2=CHI d)ICH=CHI
PickOuttheincorrectstatements:
209.a)Secondaryalcoholwithheatedcopperat570Kgivesketone
b)IsobutylalcoholinVictorMeyer’stestgivesbluecolour.
c)Methylalcoholismoretoxicthanethylalcohol d)Methylalcoholisusedinalcoholic
beverages
210.a)Theintermediatecompoundinthepreparationofethylenefrom ethylalcoholand
con.H2SO4is
C2H5.HSO4.
b)Anorganicacidreactswithalcoholtoform anester.
c)Theacidityofphenolisduetothepresenceofbenzenering
d)Tertiaryalcoholscannotbeeasilyoxidised
211.a)BenzylalcoholandphenolcanbedistinguishedbyusingBr2/H2Oreagent.
b)Formationofphenolfrom chlorobenzeneisanexampleofelectrophilicaromatic
substitution.
c)TheIUPACnameofethyleneglycolisethane1,2-diol
d)whenethyleneglycolisheatedto773Kdehydrationreactiontakesplace.
212.a)EthyleneglycolreactswithCon.H2SO4toform ethyleneoxide.
b)Whenacidifiedpotassium permanganatereactswithethyleneglycolC–Cbondcleavage
takesplace.
www.Padasalai.Net www.TrbTnpsc.com
http://www.trbtnpsc.com/2013/07/latest-12th-study-materials-2013.html
www.Padasalai.Net
c)GlycerolondehydrationformsCH2=CH–CHO d)Ethylenedecolourisesbromine
water.
17.Ethers
213.Etherisformedwhenalkylhalideistreatedwithsodium alkoxide.Thismethodisknown
a)Hoffmannreaction b)Williamson’ssynthesis
c)Wurtzsynthesis d)Kolbe’sreaction
214.WhenethylIodideistreatedwithdrysilveroxideitforms
a)Ethylalcohol b)diethylether c)silverethoxide d)ethylmethylether
215.Williamson’ssynthesisisanexampleof
a)nucleophilicaddition b)electrophilcaddition
c)electrophilicsubstitution d)Nucleophilicsubstitutionreaction
216.Oxygenatom ofetheris
a)veryactive b)Replacable c)oxidizing d)Comparativelyinert
217.Theisomerism exhibitedbyC2H5OC2H5andCH3–O–CH– CH3is
CH3
a)Functional b)metamerism c)position d)chain
218.Whichoneofthefollowingissimpleether?
a)CH3–O–C2H5 b)C2H5–O–CH3 c)C2H5–O–C2H5 d)C3H7–O–
C2H5
219.AccordingtoLewisconceptofacidsandbases,ethersare
a)Neutral b)Acidic c)Basic d)Amphoteric
220.Whenetherisexposedtoairforsometimeanexplosivesubstanceproducedis
a)peroxide b)oxide c)TNT d)superoxide
221.Diethylethercanbedecomposedwith a)HI b)KMnO4 c)NaOH
d)H2O
www.Padasalai.Net www.TrbTnpsc.com
http://www.trbtnpsc.com/2013/07/latest-12th-study-materials-2013.html
www.Padasalai.Net
222.Intermolecularhydrogenbondsarenotpresentin
a)CH3COOH b)C2H5OC2H5 c)CH3CH2OH d)C2H5NH2
18.CarbonylCompounds
223.Thechainisomerof2-methylpropanalis
a)2-butanone b)butanal c)2-methylpropanold)but-3-ene-2-ol
224.Schiffsreagentgivespinkcolourwith
a)acetone b)acetaldehyde c)ethylalcohol d)
methylacetate
225.Isopropylalcoholvapourswithairoversilvercatalystat520Kgive
a)tert.butylalcohol b)acetaldehyde c)acetone d)2-propanol
226.Methylketonesareusuallycharacterisedby
a)theFehling’ssolutionb)theiodoform test c)theSchiff’stest d)theTollen’s
reagent
227.Whichofthefollowingcompoundsisoxidisedtogiveethylmethylketone?
a)2-propanol b)2-pentanone c)1-butanol d)2-butanol
228.Formaldehydepolymerisestogive
a)paraldehyde b)paraformaldehydec)formalin d)formicacid
229.Tollen’sreagentis
a)ammoniacalcuprouschloride b)ammoniacalcuprousoxide
c)ammoniacalsilvernitrate d)ammoniacalsilverchloride
230.WhenacetaldehydeisheatedwithFehlingsolution,itgivesaprecipitateof
a)Cu2O b)CuO c)CuO+Cu2O d)Cu
231.ThecompoundthatdoesnotundergoCannizzaroreactionis
a)formaldehyde b)acetaldehyde c)benzaldehyde d)trimethyl
acetaldehyde
www.Padasalai.Net www.TrbTnpsc.com
http://www.trbtnpsc.com/2013/07/latest-12th-study-materials-2013.html
www.Padasalai.Net
232.Theformationofcyanohydrinfrom aketoneisanexampleof
a)electrophilicaddition b)nucleophilicaddition
c)nucleophilicsubstitution d)electrophilicsubstitution
233.HydrogenationofbenzoylchlorideinthepresenceofPdonBaSO4gives
a)phenol b)benzoicacid c)benzylalcohol d)
benzaldehyde
234.From whichofthefollowing,tertiarybutylalcoholisobtainedbytheactionofmethyl
magnesium
iodide?
a)HCHO b)CH3CHO c)CH3COCH3 d)CO2
235.DuringreductionofaldehydeswithhydrazineandC2H5ONatheproductformedis
a)R–CH=N–NH2 b)R–CN c)R–CO–NH2 d)R–CH3
236.Aldolobtainedfrom acetaldehydeis
a)2-hydroxybutanol b)3-hydroxybutanolc)3-hydroxybutanald)2-hydroxybutanal
237.InthereductionofacetaldehydeusingLiAlH4thehydrideionactsas
a)electrophile b)nucleophile c)both(a)and(b) d)afreeradical
238.Whichofthefollowingstatementiswrong?
a)2-pentanoneand3-pentanonearepositionisomers
b)aqueoussolutionofformaldehydeisknownasformalin
c)aldehydesandketonesundergonucleophilicsubstitution
d)aldehydesactasreducingagents
239.AcyanohydrinofacompoundXonhydrolysisgiveslacticacid.TheXis
a)HCHO b)CH3CHO c)(CH3)2CO d)C6H5CH2CHO
240.TheIUPACnameofCH3–C=CH–C–CH3is
| ||
CH3 O
www.Padasalai.Net www.TrbTnpsc.com
http://www.trbtnpsc.com/2013/07/latest-12th-study-materials-2013.html
www.Padasalai.Net
a)4-methylpent-3-en-2-one b)2-methylpent-3-en-2-one
c)3-methylpent-2-en-1-one d)Noneofthese
241.Whichofthefollowingdoesnotgiveiodoform test?
a)acetophenone b)benzophenone c)CH3–CHCH3 d)CH3–CH–CH2
CH2–CH3
| |
OH OH
242.ThecompoundwhichdoesnotreduceFehlingsolutionis
a)formaldehyde b)acetaldehyde c)benzaldehyde d)propionaldehyde
Conc.H2SO4
243.CH3COCH3 Theproductis
a)mesitylene b)mesityloxide c)phorone d)paraldehyde
244.Whichcompoundonstrongoxidationgivespropionicacid?
a)CH3–CH–CH3 b)CH3–CO–CH3 c)CH3 d)CH3CH2CH2OH
| |
OH CH3–C–OH
|
CH3
245.Thecompoundusedinthepreparationofthetranquilizer,sulphonalis
a)acetone b)acetophenone c)isopropylalcohol d)glycol
246.Calcium acetate+calcium benzoateondistillationgives
a)benzophenone b)benzaldehyde c)acetophenone d)phenyl
benzoate
247.Bakeliteisaproductofreactionbetween
a)formaldehydeandNaOH b)phenolandmethanal
c)anilineandNaOH d)phenolandchloroform
www.Padasalai.Net www.TrbTnpsc.com
http://www.trbtnpsc.com/2013/07/latest-12th-study-materials-2013.html
www.Padasalai.Net
19.CarboxylicAcids
248.Whichofthefollowingisleastacidic
a)C2H5OH b)CH3COOH c)C6H5OH d)ClCH2COOH
249.Weakestacidamongthefollowingis
a)Aceticacid b)Phenol c)Water d)Acetylene
250.Esterformationinvolvesthereactionof
a)analdehydeandaketone b)AnalcoholwithRMgX
c)Twomoleculesofanacidwithdehydratingagent d)Anacylhalidewithanalcohol
251.Heatingamixtureofsodium acetateandsodalimegives
a)methane b)ethane c)aceticacid d)benzene
252.TheacidwhichreducesTollen'sreagentis
a)aceticacid b)benzoicacid c)formicacid d)oxalicacid
CH3
|
253.TheIUPACnameofCH3–CH2–CH–COOHis
a)a-methylbutricacid b)3-methylbutanoicacid
c)2-methylbutanoicacid d)Isopentanoicacid
254.TheIsomerism exhibitedbyCH3CH2COOHandCH3COOCH3is
a)metamerism b)position c)chain d)functional
255.TheacidthatcannotbepreparedbyGrignardreagent
a)aceticacid b)formicacid c)butyricacid d)benzoicacid
256.Whichorderofarrangementiscorrectintermsofthestrengthoftheacid
a)CH3–CH2COOH>CH3COOH<HCOOH<ClCH2COOH
www.Padasalai.Net www.TrbTnpsc.com
http://www.trbtnpsc.com/2013/07/latest-12th-study-materials-2013.html
www.Padasalai.Net
b)ClCH2COOH<HCOOH<CH3COOH<CH3CH2COOH
c)CH3–CH2COOH<CH3COOH<HCOOH<ClCH2COOH
d)HCOOH>CH3CH2COOH<CH3COOH>ClCH2COOH
257.ThecompoundwhichundergoesintramoleculardehydrationwithP2O5is
a)aceticacid b)formicacid c)propionicacid d)Butyricacid
H
258. C=O160C ?Theproductis
HO
a)CO+H2O b)HCOOH c)H2+CO2 d)HCHO+O2
260.WhenchlorineispassedthroughaceticacidinpresenceofredP,itforms.
a)acetylchloride b)Trichloroacetaldehyde c)Trichloroaceticacid d)Methyl
chloride
261.WhichofthefollowingcompoundswillreactwithNaHCO3solutiontogivesodium saltand
CO2?
a)aceticacid b)n-hexanol c)phenol d)both(a)and(c)
262.Whenpropanoicacidistreatedwithaqueoussodium -bicarbonatate,CO2isliberated.The
"C"of
CO2comesfrom
a)methylgroup b)carboxylicacidgroup c)methylenegroup d)bicarbonate
263.Carboxylicacidsaremoreacidicthanphenolandalcoholbecauseof
a)intermolecularhydrogenbonding (b)formationofdimers
c)highlyacidichydrogen d)greaterresonancestabilisationoftheir
conjugatebase
264.Amongthefollowingthestrongestacidis
a)ClCH2COOH b)Cl3CCOOH c)CH3COOH d)Cl2CHCOOH
265.Whichofthefollowingcompoundisopticallyactive?
a)CH3CH2COOH b)HOOC–CH2–COOH c)CH3CH(OH)COOH d)Cl2CHCOOH
www.Padasalai.Net www.TrbTnpsc.com
http://www.trbtnpsc.com/2013/07/latest-12th-study-materials-2013.html
www.Padasalai.Net
266.CH3CH(OH)COOH ?Theproductis
H2O2/Fe2+
a)CH3COCOOH b)CH3CH2COOH c)CH3CHOHCHO d)COOHCH2COOH
267.Thecompoundfoundinsomestonydepositinkidneysis
a)potassium oxalate b)oxalicacid c)potassium succinate d)calcium
oxalate
268.Ethylenecyanideonhydrolysisusingacidgives
a)oxalicacid b)succinicacid c)adipicacid d)propionicacid
20.OrganicNitrogenCompounds
269.Bromoethanereactswithsilvernitritetogive
a)C2H5NO2 b)C2H5–O–NO c)C2H5Ag+NaBr d)C2H5NC
270.Theisomerism exhibitedbyCH3CH2–NO2andCH3CH2–O–N=Ois
a)position b)chain c)functional d)
tautomerism
280.Innitroalkanes–NO2groupisconvertedto–NH2groupbythereactionwith
a)Sn/HCl b)Zndust c)Zn/NH4Cl d)Zn/NaOH
281.WhennitromethaneisreducedwithZndust+NH4Clinneutralmedium,weget
a)CH3NH2 b)C2H5NH2 c)CH3NHOH d)C2H5COOH
282.Thecompoundthatismostreactivetowardselectrophilicnitrationis
a)Toluene b)benzene c)benzoicacid d)
nitrobenzene
283.Nitromethanecondenseswithacetaldehydetogive
a)nitropropane b)1-nitro-2-propanolc)2-nitro-1-propanold)3-nitropropanol
284.Whichofthefollowingcompoundshasthesmellofbitteralmonds?
a)aniline b)nitromethane c)benzenesulphonicacid d)nitrobenzene
285.Nitrationofnitrobenzeneat373Kresultsin
www.Padasalai.Net www.TrbTnpsc.com
http://www.trbtnpsc.com/2013/07/latest-12th-study-materials-2013.html
www.Padasalai.Net
a)o-dinitrobenzene b)1,3,5-trinitrobenzene c)p-dinitrobenzene d)m-dinitro
benzene
286.Nitrobenzeneonelectrolyticreductionincon.sulphuricacid,theintermediateformedis
a)C6H5NH–NHC6H5 b)C6H5–NHOH c)C6H5–N=N–C6H5 d)C6H5.HSO4
287.Electrophileusedinthenitrationofbenzeneis
a)hydronium ion b)sulphonicacid c)nitronium ion d)bromideion
288.ThereductionofCH3–CH2–C≡ Nwithsodium andalcoholresultsintheformationof
a)CH3–CH-CH3 b)CH3–CH2–CH2–OH+N2
|
NH2
c)CH3–CH2–CH2–NH2 d)CH3–CH2–NH2
289.Thebasiccharacterofaminesisduetothe
a)tetrahedralstructure b)presenceofnitrogenatom
c)lonepairofelectronsonnitrogenatom d)highelectronegativityofnitrogen
290.Theorganiccompoundthatundergoescarbylaminereactionis
a)(C2H5)2NH b)C2H5NH2 c)(C2H5)3N d)(C2H5)4N+I–
291.Primaryamineactsas
a)Electrophile b)Lewisbase c)Lewisacid d)Freeradical
292.Oxidationofanilinewithacidifiedpotassium dichromategives
a)p-benzoquinone b)benzoicacid c)benzaldehyde d)
benzylalcohol
293.Whichoneofthefollowingisasecondaryamine?
a)aniline b)diphenylamine c)sec.butylamine d)tert.butylamine
NaNO2/HClO0c
294.C6H5NH2 X.IdentifyX.
a)C6H5Cl b)C6H5NHOH c)C6H5N2Cl d)C6H5OH
www.Padasalai.Net www.TrbTnpsc.com
http://www.trbtnpsc.com/2013/07/latest-12th-study-materials-2013.html
www.Padasalai.Net
295.Whichofthefollowingwillnotundergodiazotisation?
a)m-toluidine b)aniline c)p-aminophenol d)benzylamine
296.Anilinediffersfrom ethylaminebythereactionwith
a)metallicsodium b)analkylhalide c)chloroform andcausticpotash d)
nitrousacid
297.Whenaqueoussolutionofbenzenediazonium chlorideisboiledtheproductformedis
a)benzylalcohol b)benzene+N2 c)phenol d)phenylhydroxylamine
21.BioMolecules
298.Whichisamonosaccharideamongthefollowing?
a)Sucrose b)Cellulose c)Maltose d)Glucose
299.Identifythereducingsugar.
a)Sucrose b)Cellulose c)Starch d)Glucose
300.Sucroseisnot
a)adisaccharide b)anon-reducingsugar.
c)hydrolysedtoonlyglucose d)hydrolysedtoglucose&fructose
301.Sucrosecontainsglucoseandfructoselinkedby
a)C1–C1 b)C1–C2 c)C1–C4 d)C1–C6
302.Glucoseisnotoxidisedtogluconicacidby
a)Br2/H2O b)Fehlingsolutions c)Tollen’sreagent d)Conc.HNO3
303.Inversionofsucroserefersto
a)oxidationofsucrose b)reductionofsucrose
c)hydrolysisofsucrosetoglucoseandfructose d)polymerisationofsucrose.
304.Glucoseforms___________withaceticanhydrideandsodium acetate.
a)diacetate b)tetraacetate c)pentaacetate d)hexaacetate
305.Theaminoacidwithoutchiralcarbonis
www.Padasalai.Net www.TrbTnpsc.com
http://www.trbtnpsc.com/2013/07/latest-12th-study-materials-2013.html
www.Padasalai.Net
a)Glysine b)Alanine c)Proline d)Thyrosine
306.Thebuildingblockofproteinsare
a)α-hydroxyacids b)α-aminoacids c)β-hydroxyacids d)β-aminoacids
307.Whichisnottrueofaminoacid?
a)aminoacidformsZwitterion b)hasisoelectricpoint
c)dualbehavior d)aminoacidisinsolubleinNaOHsolution
308.TwoaminoacidssayA,B-reacttogive
a)twodipeptides b)threedipeptides c)fourdipeptides d)onlyone
309.Adipeptidedoesnothave
a)twopeptideunits b)portionsoftwoaminoacids
c)anaminogroup d)saltlikestructure
310.Proteinsarenotsensitiveto
a)acids b)bases c)elevatedtemperature d)
water
311.Denaturationdoesnotinvolve
a)breakingupofH–bondinginproteins b)thelossofbiologicalactionofenzyme
c)thelossofsecondarystructure d)lossofprimarystructureofproteins
312.Specificityofenzymeisdueto
a)thesequenceofaminoacids b)secondarystructure
c)tertiarystructure d)alloftheabove
313.Ultimateproductsofhydrolysisofproteinsis
a)aniline b)aliphaticacid c)aminoacid d)aromaticacid
314.Proteinsare
a)polypeptides b)polyacids c)polyphenols d)polyesters
315.Whichofthefollowingcontainsalipid?
a)starch b)mineraloil c)edibleoil d)peptide
www.Padasalai.Net www.TrbTnpsc.com
http://www.trbtnpsc.com/2013/07/latest-12th-study-materials-2013.html
www.Padasalai.Net
316.Whichamongthefollowingcontainstriglyceride?
a)Wax b)Cookingoil c)Essentialoil d)Albumin
317.Whichcontainsalongchainester?
a)wax b)cookingoil c)turpentineoil d)cellulose
318.Anexampleofafattyacidobtainedfrom acookingoilis
a)aceticacid b)stearicacid c)benzoicacid d)
oxalicacid
319.Whichisnotasaturatedfattyacid?
a)Palmiticacid b)Stearicacid c)Oleicacid d)Glyceric
acid
320.Alkalinehydrolysisofcookingoilgives
a)soap b)glycerol c)fattyacid d)both(a)and(b)
321.Hairandnailcontains
a)cellulose b)fat c)keratin d)lipid
322.Importantconstituentofcellwallis
a)lipid b)cellulose c)protein d)vitamin
ALLTHEBEST
A.Karuppasamy,
PGassistantinChemistry,
Theni,
Cell:8144870086
www.Padasalai.Net www.TrbTnpsc.com
http://www.trbtnpsc.com/2013/07/latest-12th-study-materials-2013.html
www.Padasalai.Net