annex_3_a.pdf

ANNEX III: COMPARISON OF AGGREGATED TABLES OF ELV AT POLLUTANT LEVEL EXPLANATORY NOTES CONCERNING THE AGGREGATED TABLES OF ANNEX III Notes on Remarks or text: Stricken-through text means that this text (remarks or ELV) was not comprised

anywhere in the new reports of the Member States (MS). They are usually highlighted in yellow colour, but in some occasions in green colour as well (there is no difference concerning these colours)

Yellow highlighted text means that this text (either remark or ELV) needs to be checked for small differences that are met between the two articles.

Yellow highlighted remarks under the label FOE. These remarks were made by the person that has checked the aggregated tables, in order to provide additional information.

Green highlighted text means that this text (either remark or ELV) was found in the new reports of the Member States (MS) and added to the tables.

Notes on Pollutants Cells: Brown cells in general indicate that new or different ELV are found in the new

reports (under Article 16(3)) comparing to the old aggregated tables (Article 16(1)). Therefore, in most cases, there are two cells per pollutant, the one comprising the old ELV (where the values are stricken-through) and another one that comprises the new ELV. However, in some cases, the old values are not stricken through and placed in a white, indicating that the new ELV (in brown cell) are additional ELV and do not replace the old ELV.

Brown rows in particular, indicate that the comprised pollutants were not included in the old aggregated tables and are considered in the present tables, under Article 16(3).

Notes on columns: The columns referring to UKs ELV are in a pale-green colour that indicates the

submission of ELV by this MS, for the first time.

ANNEX III.a: COMPARISON OF AGGREGATED TABLES OF ELV AT POLLUTANT LEVEL EXISTING INSTALLATIONS

Existing installations 1.1.1

3

1.1.1 Combustion installations using solid fuels with a rated thermal input exceeding 50 MW Air pollutant AA1 B DKDK1 MAV FIN MAV F F1 DD1 D2 EL EL1 IRL

50 FIN1 100 1, 2 50 3

Particulates 50 50

60 FIN1, 5 70 FIN2, 6

42.5 7, 8

50 DAV,HHAV 100 / 1504 50or 100

No I.

(mg/m3) (mg/Nm3) (mg/m3(n)) (mg/m3) (mg/m3) (mg/m3) (mg/Nm3)

CO 250

None None None 250 DAV HHAV None No I.

(mg/m3) (mg/m3) 15013 YAV 650 14, 15 NOx 6009

45010 30011 20012

200

None 1000 (360-1300) 18, 19

40016 DAV HHAV 20017 DAV HHAV

650-1300 No I.

(mg/m3) (mg/Nm3) (mg/MJ) (mg/m3) (mg/m3) (mg/Nm3) 14022 YAV

mg/MJ

400 23 , 24

200025 DAV HHAV 2000 and 60%26 DAV HHAV 400 and 85%27 DAV HHAV

SOx 1000 600 / 20020 400 / 20021

400

840 FIN1, 28 1005 (320-2000) 29, 30

400 and 95%31 DAV HHAV

400-2000 No I.

(mg/m3) (mg/Nm3) (mg/m3(n)) (mg/m3) (mg/m3 and ROD32)

(mg/Nm3)

A1 Reference conditions: 6% O2 DK1 Reference conditions: 6% O2 F1 Reference conditions: 273 K, 101.3 kPa, 6%O2 D1 Reference conditions: 5%, 6% or 7% O2; O2% depending on combustion technology D2 Where waste is co-incinerated mixed ELVs apply. EL1 Reference conditions: 6% O2 1 If P < 500MW 2 if P > 300 MW continued surveillance otherwise trimestriel surveillance 3 if P>= 500 MW 4 MW>= 500, MW< 500 FIN1 Reference conditions: 6% O2 5 390 MW, main boiler FIN2 Reference conditions: 3% O2 6 2*10.6 MW, secondary boiler 7 The values depend on the power of the installation 8 if P > 300 MW continued surveillance otherwise trimestriel surveillance 9 50-150 MW 10 150-300 MW 11 300-500 MW 12 > 500 MW 13 mg/MJ energy input of fuel into boiler 14 1300 mg/m3 if the content of volatile elements of the fuel > 10% 15 if P > 300 MW continued surveillance otherwise trimestriel surveillance 16 MW > 50 to 300 17 MW > 300 18 The values depend on the power of the installation 19 if P > 300 MW continued surveillance otherwise trimestriel surveillance 20 lignite / hard coal; 150-300 MW 21 lignite / hard coal; > 300 MW 22 mg/MJ energy input of fuel into boiler 23 if the power of the installation > 500 MW; if 100 MW < P < 500 MW = 2400-4xP 24 if P > 300 MW continued surveillance otherwise trimestriel surveillance 25 MW > 50 to 100 26 MW > 100 to 300 27 MW > 300 28 390 MW, main boiler 29 The values depend on the power of the installation 30 if P > 300 MW continued surveillance otherwise trimestriel surveillance 31 combustion of brown coal with a high sulfur content 32 ROD: rate of desulfurization


4

Air pollutant AA1 B DKDK1 MAV FIN MAV F F1 DD1 D2 EL EL1 IRL Metals and their compounds (Cu, Pb, As, Ni, Cd, Zn, Cr, Hg, Sn)

None Cd/Hg 0.1 None None 0.533 HHAV 10 / 2034 No I.

(mg/Nm3) (mg/m3) (mg/Nm3) PCDD/PCDF None None None None None35 None No I. PCB None None None None None None No I. NH3 5-10 or

none None None None None None No I.

(mg/m3)

33 As+Pb+Cd+Cr+Co+Ni 34 for PB, AS and Cd 35 target value: 0.1 ng/m3; minimisation obligation; only relevant for combustion of wood and wood residues containing chlorinated compounds


5

Air pollutant II1 L NLNL1 P P3 E S UK

5-50 HHAV 137P1 Particulates 50 5-20 HHAV No data

100-350 E1 E2

50 S1 MAV 140

(mg/m3) (mg/m3) (mg/Nm3) (mg/Nm3) (mg/m3) (mg/m3) 1000P1 CO 250

None

No data 500 E2 90 DAV

180 HAV None

(mg/m3) (mg/m3) (mg/Nm3) ppm (mg/MJ) 800P2 NOx 20036

65037 100-65038,

HHAV 200-40039, HHAV

No data

650 100 YAV 650UK1

(mg/m3) (mg/m3) (mg/Nm3) (mg/Nm3) (mg/MJ) (mg/m3) 400P2 SOx 40040

170041 70042, DAV

200-40043, DAV 85 35, DAV

No data

5000 E1 E2 44 750-1500

80 YAV 3000

(mg/m3) (mg/m3) (%)

(mg/Nm3) (mg/Nm3) (mgS/MJ) (mg/m3)

P1

547 0.248 149

Metals and their compounds (Cu, Pb, As, Ni, Cd, Zn, Cr, Hg, Sn)

0.245, 46 None

No data

None None None

(mg/m3) (mg/Nm3) PCDD/PCDF 0.0150 None No data None None None (mg/m3) PCB 0.551 None No data None None None (mg/m3) NH3 100 None No data None None None (mg/m3)

I1 Reference conditions: %O2: 6% for coal and 11% for other fuels NL1 Reference conditions: standard, 6%O2; for SOx (85% - reduction effic.) P3 Portugal sets Emission Limit Values for water pollutants on a case by case basis, for air pollutants limit values are set according to categories. No representative data for sectors exists (categories 2.1.1 5.2) as traditionally ELVs were not considered as part of the permits. Recent legislation (adoption water 1990 and air 1993) introduces limit values, it is only being implemented since 2000 as a phase of transition was necessary. Values quoted for existing installations are not representative for the entire sector. P1 Reference conditions: 8% O2 E1 Reference conditions: 6% O2 E2 Combustion of soft coal and anthracite S1 Reference conditions: 13% CO2 36 MWth > 500 37 MWth < 500 38 < 300 MW 39 300 MW P2 Reference conditions: 6% O2 UK1 Reference conditions: 6% O2, dry 40 MWth > 500 41 MWth < 500 42 < 300 MW 43 300 MW 44 combustion of national lignites 90% desulphurization 45 Cd, Hg, Tl 46 mass flow 1 g/h 47 Pb+Cr+Cu 48 Hg+Cd 49 As+Ni 50 mass flow 0.02 g/h 51 mass flow 0.2 g/h


6

Water pollutant

A B DK FINFIN2 F D EL EL2 IRL

65 Suspended solids

30 None None 30

5052 30 53

30-40 No I.

(mg/l) (mg/l) (mg/l) (mg/l) 225 COD 90-150

None None

90

3054 4055 5056 8057 15058

120-180 No I.

(mg/l) (mg/l) (mg/l) (mgr/l) 75 BOD None None None 30

None 20-60 No I.

(mg/l) (mg/l) None TOC 30-50 None None 40

None None No I.

(mg/l) 20 Total N None None None 30

1059 0.6 (NO2) 20 (NO3)

No I.

(mg/l) (mg/l) (mg/l) 10 Total P 2 None None 2

1.560 361

None No I.

(mg/l) (mg/l) (mg/l) Halogenated organic compounds

0.1 None None None 62 0.2 63 1 64 0.15 65 0.15 66 0.5 67

1 68 No I.

(mg/l) (mg/l) (mg/l) Metals and their compounds

Cd: 0.05 Hg: 0.01 Ni: 0.5 Pb: 0.5

None None 15 As: 0.1 69 Cr, Cu, Ni: 0.5 70 18 (mg/kg CL-) 71 1 (g/(h 300MW) 72 Cd, Hg: 0.05 73 1.8 (mg/kg CL-) 57 0.1 (g/(h 300MW)58 Pd: 0.156 3.6 (mg/kg CL-) 57 0.2 (g/(h 300MW) 58 V: 4 56 Zn: 1 56 3.6 (mg/kg CL-) 57 0.2 (g/(h 300MW) 58

None No I.

FIN2 The waste waters are mainly cooling waters from indirect cooling. There are no permit conditions but the content of the wastewater must be measured. EL2 The quality limits for discharges of liquid industrial effluent into natural recipients are those specified in the Prefectural decisions for specific recipients. The values are from the Prefectural decisions concerning 7 prefectures where large combustion plants operate. 52 waste water from water treatment; there are some exceptions to the requirements 53 waste water from the flue gas cleaning 54 waste water from cooling systems; flushing water from recirculation cooling systems 55 waste water from flushing of other coating circuits 56 waste water from other sources in the generation of steam, 80 mg/l for waste water from condensate desalination 57 in the application of quicklime; after subtraction of the pre-load of COD added by the service water 58 in the application of limestone; after subtraction of the pre-load of COD added by the service water 59 TIN; sum of ammonium, nitrite and nitrate nitrogen; waste water from other sources in the generation of steam 60 waste water from cooling systems; waste water from recirculation cooling systems; if only inorganic P is used, the value for P is increased to 3 mg/l 61 waste water from other sources in the generation of steam; waste water from flushing of other coating circuits 62 AOX 63 waste water from water treatment; there are some exceptions to the requirements; if the parameter is to be expected in the waste water 64 waste water from water treatment; there are some exceptions to the requirements; AOX in regeneration water from ion exchangers 65 waste water from cooling systems; water from single-pass or open-ended fresh water cooling systems 66 flushing water from recirculation cooling systems 67 waste water from flushing of other coating circuits (waste water from other sources in the generation of steam) 68 Cl solvents 69 waste water from water treatment; there are some exceptions to the requirements; if the parameter is to be expected in the waste water


7

Water pollutant

A B DK FINFIN2 F D EL EL2 IRL

(mg/l) (mg/l) (mg/l)

70 waste water from other sources in the generation of steam; if the parameter is to be expected in the waste water 71 valid for hard-coal-fired power stations; the relative load levels for chloride may be determined by the following information: burned hard coal under full load (t/h) and the chloride content of the hard coal used; where the waste water chloride concentration from the service water exceeds 2 g/l, the excess chloride content is added to the chloride load calculated from the hard coal burned. 72 valid for lignite-fired power stations; ELV specified as the load in grammes per hour and per 300 MW of installed electric power 73 waste water from other sources in the generation of steam; there are some exceptions to the requirements; if the parameter is to be expected in the waste water


8

Water pollutant

II2 3HAV L NLDAV P P4 EE3 S UK

Suspended solids

80 None 60 30-90 1074 50

(mg/l) (mg/l) (mg/l) (mg/l) (mg/l) COD 160

None 150 160-500 None None

(mg/l) (mg/l) (mg/l) BOD 40 None 40 5-72 None None (mg/l) (mg/l) (mg/l) TOC None None No data None None None Total N 75 None 15 15-5076 None None (mg/l) (mg/l) Total P 10 None 10 10-2077 None None (mg/l) (mg/l) (mg/l) Halogenated organic compounds

178 None No data 79 0.5-4 None 80

(mg/l) (mg/l) Metals and their compounds

None 0.0581 0.0282 0.0183

Hg: 0.05 Ni: 2 Pb: 1

84 Al: 1-2 As: 0.5-1 Ba: 20 2-1085 Cd: 0.1-0.5 Crtot: 2.21 Cr(III): 2-4 Cr(VI): 0.2-0.5 0.286 Fe: 2 Hg: 0.005-0.1 Se: 0.03-0.1

None Cd: 0.1 Cr: 1.0 Hg: 0.05

I2 Valid for discharges in surface water P4 Portugal sets Emission Limit Values for water pollutants on a case by case basis, for air pollutants limit values are set according to categories. No representative data for sectors exists (categories 2.1.1 5.2) as traditionally ELVs were not considered as part of the permits. Recent legislation (adoption water 1990 and air 1993) introduces limit values, it is only being implemented since 2000 as a phase of transition was necessary. Values quoted for existing installations are not representative for the entire sector. E3 Valid only for discharges in rivers and streams. 74 When using flue gas condensation (biomass). 75 N-NH4 = 15 mg/l, N-NO2 = 0.6 mg/l, N-NO3 = 20 mg /l 76 This ELV must be lower than 10 mg/l (total N as N2) in lakes and similars. 77 This ELV is lower (0.5) in lakes and similars to avoid eutrophic problems. 78 Chlorinated solvent 79 AOX, EOX, VOX 80 Trichloroethylene. Perchloroethylene, Tetrachloroethylene: monitoring but no limits specified


9

Water pollutant

II2 3HAV L NLDAV P P4 EE3 S UK

Sn: 10 Zn: 3

(mg/l) (mg/l) (mg/l) (g/l)

81 Ni, Pb, Zn 82 As, Cr, Cu 83 Cd, Hg 84 toxic elements (As, Cd, Cr(VI), Ni, Hg, Pb, Se, Cu, Zn) must be < 3 85 B, Mn, Ni 86 Cu, Pb


10

1.1.2 Combustion installations using liquid fuels with a rated thermal input exceeding 50 MW Air pollutant AA1 B DKDK1 FIN F F1 DD1, D2 EL EL3 IRL IRL1

None Particulates 5087 3088 11089

50

40

50 90 50 DAV HHAV

100 / 150 5091 100 92

50 HHAV

(mg/m3) (mg/Nm3) (mg/MJ) (mg/m3) (mg/m3) (mg/Nm3) (mg/m3) None CO 175

None None

100 175 DAV HHAV

None None

(mg/m3) (mg/m3) (mg/m3) NOx 45093

30094 20095 15096 90097

225 None 450 98 30099 DAV HHAV 150 DAV HHAV100

450 750 HHAV

(mg/m3) (mg/Nm3) (mg/m3) (mg/m3) (mg/Nm3) (mg/m3) 400 105, 106 SOx 1100101

350102 200103 800104

400 None

1700 (300-3400) 113, 114

1700107 DAV HHAV 1700 and 60%DAV HHAV108 400 and 85%DAV HHAV109

400-1700 1000 110

5100111 HHAV 1700112 HHAV

(mg/m3) (mg/Nm3) (mg/m3) (mg/m3, ROD115)

(mg/m3)

None Metals and their compounds (Cu, Pb, As, Ni, Cd, Zn, Cr, Hg, Sn)

None Cd/Hg 0.1 None

Cd: 0.15 Pb: 5,0

2116 HHAV None None

(mg/Nm3) (mg/m3) (mg/m3) None PCDD/PCDF None None

None

0.1 None None None

(ng/m3)

A1 Reference conditions: 3% O2 DK1 Reference conditions: 3% O2 F1 Reference conditions: 273 K, 101.3 kPa, 3% O2 D1 Reference conditions: 3% O2 D2 Where waste is co-incinerated mixed ELVs apply. EL3 3% O2 IRL1 272K, 101.3kPa, dry gas 6% O2 87 Heavy fuel oil 88 Gas oil 89 fuel: liquid residues of refineries 90 if P > 300 MW: continued surveillance, otherwise trimestriel surveillance 91 general case 92 ash content >= 0.06 % 93 50-150 MW 94 150-300 MW 95 300-500 MW 96 > 500 MW 97 fuel: liquid residues of refineries 98 if P > 300 MW: continued surveillance, otherwise trimestriel surveillance 99 MW > 50 to 300 100 MW > 300 101 50-150 MW 102 150-300 MW 103 > 300 MW 104 fuel: liquid residues of refineries 105 if P > 300 MW: continued surveillance, otherwise trimestriel surveillance 106 if P>500 MW: limit value = 400 mg/m3, if 300500MW: limit value = 3650-6.5xP 107 MW > 50 to 100 108 MW > 100 to 300 109 MW > 300; 400 mg/m3 and 85% ROD or use of light oil 110 refineries mixed combustion 111 150 MW plant operating on HFO 3 % S until 01.01.03 112 > 300 MWth 113 if P > 300 MW: continued surveillance, otherwise trimestriel surveillance 114 The values depend on the power of the installation 115 ROD: rate of desulfurization 116 As+Pb+Cd+Cr+Co+Ni; valid for fuels with more than 12 ppm Ni and liquid fuels without norm only


11

Air pollutant AA1 B DKDK1 FIN F F1 DD1, D2 EL EL3 IRL IRL1 PCB None None None None None None None NH3 None None None None None None None


12

Air pollutant II1 L NLNL1 P P5 EE1 S UKUK1 Particulates 50 50-100117

HAV No data 150 0.5-1 100

(mg/m3) (mg/m3) (mg/Nm3) (g/kg of oil)

(mg/m3)

CO 250

None No data None None None

(mg/m3) (mg/m3) NOx 200118

650119 120-450120

HAV No data 470121 120 1800

(mg/m3) (mg/m3) (mg/Nm3) (mg/MJ) (mg/m3) SOx 400122

1700123 1700124 DAV

200-400125 DAV 85 126, DAV

No data FOE 5500127 5000128

100 400

(mg/m3) (mg/m3, %)

(mg/Nm3) (mg/MJ) (mg/m3)

Metals and their compounds (Cu, Pb, As, Ni, Cd, Zn, Cr, Hg, Sn)

0.2129, 130 None No data None None None

(mg/m3) PCDD/PCDF 0.01131 None None None None None (mg/m3) PCB 0.5132 None No data None None None (mg/m3) NH3 100 None No data None None None (mg/m3)

I1 Reference conditions: 3 %O2 NL1 Reference conditions: standard, 3%O2; for SOx (85% - reduction effic.) P5 non-representative data, also see comment on P in category 1.1.1 E1 Reference conditions: 3% O2 UK1 Reference conditions: 273 K, 101.3 kPa, 15% O2 117 50 mg/Nm3 when ash concentration is below 0.06% or capacity > 500 MW 118 MWth > 500 119 MWth < 500 120 standard depending on age of combustion installation 121 low sulphur content fuels 122 MWth > 500 123 MWth < 500 124 < 300 MW 125 300 MW; standard depending on age of combustion installation 126 300 MW FOE In Art-16(1) the remark was placed at the value 5500 mg/l 127 low sulphur content fuels 128 low sulphur content fuels 129 Cd, Hg, Tl 130 mass flow 1 g/h 131 mass flow 0.02 g/h 132 mass flow 0.2 g/h


13

Water pollutant A B DK DK1 FIN F D EL EL4 IRL

100 Suspended solids 30 None None 35

50133 30 134

30-40 320 DAV, 135

(mg/l) (mg/l) (mg/l) (mg/l) (mg/m3) 300 COD 90

None None

510

30136 40137 50138 80 139 150 140

120-180 None

(mg/l) (mg/l) (mg/l) (mg/l) 100 BOD 20141 None None 40

None 20-60 None

(mg/l) (mg/l) (20-60) None TOC 30 None None 40

None None None

(mg/l) (mg/l) None Total N 25142 None None 30

10143 0.6 144 20 145

24 DAV

(mg/l) (mg/l) (mg/l) (mg/l) None Total P 2 None None 6.5

1.5146 3147

None None


0.1 None None None 148 0.2149 1150 0.15151 0.15152 0.5153

1 154 None

(mg/l) (mg/l) (mg/l) None Metals and their

compounds

None None None

15

(mg/l) (mg/l) (mg/l) (mg/l)

DK1 no waste water is produced. EL4 The quality limits for discharges of liquid industrial effluent into natural recipients are those specified in the Prefectural decisions for specific recipients. The values are from the Prefectural decisions concerning 7 prefectures where large combustion plants operate. 133 waste water from water treatment; there are some exceptions to the requirements 134 waste water from the flue gas cleaning 135 emission from water treatment only not cooling water 136 waste water from cooling systems; flushing water from recirculation cooling systems 137 waste water from flushing of other coating circuits 138 waste water from other sources in the generation of steam, 80 mg/l for waste water from condensate desalination 139 in the application of quicklime; after subtraction of the pre-load of COD added by the service water 140 in the application of limestone; after subtraction of the pre-load of COD added by the service water 141 direct discharge 142 direct discharge 143 TIN; waste water from other sources in the generation of steam; sum of ammonium, nitrite and nitrate nitrogen 144 NO2 145 NO3 146 waste water from cooling systems; waste water from recirculation cooling systems; if only inorganic P is used, the value for P is increased to 3 mg/l 147 waste water from other sources in the generation of steam; waste water from flushing of other coating circuits 148 AOX 149 waste water from water treatment; there are some exceptions to the requirements; if the parameter is to be expected in the waste water 150 waste water from water treatment; there are some exceptions to the requirements; AOX in regeneration water from ion exchangers 151 waste water from cooling systems; water from single-pass or open-ended fresh water cooling systems 152 flushing water from recirculation cooling systems 153 waste water from flushing of other coating circuits 154 Cl solvents


14

Water pollutant

II2 3HAV L NL P P6 EE2 SS1 UK

Suspended solids

80 None 60 80-300 None 100

(mg/l) (mg/l) (mg/l) (mg/l) COD 160

None 150 160-500 None None

(mg/l) (mg/l) (mg/l) BOD 40 None 40 40-300 None 100 (mg/l) (mg/l) (mg/l) (mg/m3)

None TOC None None 10

None None None

(mg/l) 15 Total N 155 None No data

10-20156 None None

(mg/l) (mg/l) Total P 10 None 10 10-20157 None None (mg/l) (mg/l) (mg/l)

0.1DAV Halogenated organic compounds

1158

None

No data 159 None None

(mg/l) (mg/l) (mg/l) None None Metals and

their compounds

None None

2160 1161

162 Al: 1-2 As: 0.5-1 Ba: 20 2-10163 Cd: 0.1-0.5 Cr(III): 2-4 0.2-0.5164 Fe: 2 Hg: 0.005-0.1 Se: 0.03-0.1 Sn: 10 Zn: 3-20

None None

(mg/l) (mg/l)

I2 Valid for discharges in surface water P6 non-representative data, also see comment on P in category 1.1.1 E2 Valid only for discharges in rivers and streams. S1 no wet scrubbing systems in operation 155 N-NH4 = 15 mg/l, N-NO2 = 0.6 mg/l, N-NO3 = 20 mg /l 156 This ELV must be lower than 10 mg/l (total N as N2) in lakes and similars. 157 This ELV is lower (0.5) in lakes and similars to avoid eutrophic problems. 158 Chlorinated solvent 159 ELV in accordance to specific EU Directives 160 Fe+Cr+Ni 161 Cu 162 toxic elements (As, Cd, Cr(VI), Ni, Hg, Pb, Se, Cu, Zn) must be < 3 163 B, Mn, Cu, Fe, Ni 164 Cr(VI), Pb


15

1.1.3 Combustion installations using gaseous fuels with a rated thermal input exceeding 50 MW Air pollutant A B DKDK1 FIN F F1 DD1 D2 EL EL5 IRL

35 165 166 Particulates 5-10A1 A2

5 None

10 172 173

5167 HHAV 10 HHAV168 50 HHAV169

5 170 10 / 50 171

None

(mg/m3) (mg/m3) (mg/m3) (mg/m3) (mg/Nm3) PM10 None None None None None None None

None None CO 100/80 A1 35 A2 A3 A4

500

None

150

100174 DAV HHAV

None None

(mg/m3) (mg/m3) (mg/m3) (mg/m3) 80

NOx 300 A1 175 200 A1 176 150 A1 177 80 A2 178 35 A2 179

225

40184

350 180 200181 HHAV 100182 DAV HHAV

350 183

None

(mg/m3) (mg/m3) (mgNO2 / MJ)

(mg/m3) (mg/m3) (mg/Nm3)

5 185 186 SOx None 35 None

35 195 196

35187 HHAV 5188 HHAV 100189 HHAV 200-800190 HHAV

35 191 5 192 800 193

50194

(mg/m3) (mg/m3) (mg/m3) (mg/Nm3) (mg/m3)

DK1 Reference conditions: 3% O2 F1 273K, 101.3 kPa, 3% O2 D1 Reference conditions: 3% O2 D2 Where waste is co-incinerated mixed ELVs apply. EL5 Reference conditions: 3% O2 A1 Reference conditions: 3% O2 A2 Reference conditions: 15% O2; gas turbine 165 5 mg/m3 for the installations using GPL, 800 mg/m3 for installations using gases of weak calorific value 166 if P > 300 MW: continued surveillance, otherwise trimestriel surveillance 167 gaseous fuels in general 168 blast furnaces 169 industrial off-gases from steel-production 170 general case 171 special cases (88/609/EC) 172 The values depend on the power of the installation 173 if P > 300 MW: continued surveillance, otherwise trimestriel surveillance A3 gasturbines 50-200 MW permitted after January 1989 A4 gasturbines > 200 MW permitted after January 1989 174 gaseous fuels in general 175 50-150 MW 176 150-300 MW 177 > 300 MW 178 50-200 MW; gasturbines 179 > 200 MW; gasturbines 180 if P > 300 MW: continued surveillance, otherwise trimestriel surveillance 181 MW > 50 to 300 182 MW > 300 183 general case 184 target value 185 5 mg/m3: general case, 10 mg/m3: gas of melting ovens, 50 mg/m3 : iron and steel industry gas 186 if P > 300 MW: continued surveillance, otherwise trimestriel surveillance 187 gaseous fuels in general 188 liquid gas 189 coke-oven gas 190 combustion gases used jointly at steel works and coking plants 191 general case 192 LPG combustion 193 special cases (88/609/EC) 194 -272K, 101.3 kPa, dry gas 15% O2 for gas turbine 195 The values depend on the power of the installation 196 La valuer de 5 mg/m3 indiquee dans la precedente response etait un erreur. En effet la VLE nationale est en fait 35 mg/m3


16

Air pollutant A B DKDK1 FIN F F1 DD1 D2 EL EL5 IRL None metals and

their compounds (Cu, Pb, As, Ni, Cd, Zn, Cr, Hg, Sn)

None None None

20 (Pb: 5 Zn: 2)

None None None

(mg/m3) None PCDD/PCDF None None None 0.1

None None None

(ng/m3) PCB None None None None None None None NH3 10 or

none A1 None None None None None None


17

Air pollutant I I1 L NLHHAV P P7 EE1 S UK

5P1 200 Particulates 50 5NL1, 197, HAV 20 NL1, 198 10 NL1, 199

10

5 25201

None 20

(mg/m3) (mg/m3) (mg/Nm3) (mg/Nm3) (mg/m3) PM10 None None No data None None 20 (mg/m3)

1000P2 CO 250

None No data

None None 100

(mg/m3) (mg/m3) (mg/Nm3) (mg/m3) 350P1 NOx 200202, 203

650204, 35 70-350 NL1,

205, HAV 45-200NL2 206 HAV 100-500 NL2 207 HAV

150

75208 120 209 210

70 YAV 220

(mg/m3) (mg/m3)211 (mg/Nm3) (mg/Nm3) (mg/MJ) (mg/m3) 35P1 SOx 400212

1700213 35-800 NL1

214 DAV 200-400 NL1, 215 120-150 NL1, 216 35 NL1, 217 5 NL1, 218

250

11219 111220 221

None 100

(mg/m3) (mg/m3) (mg/Nm3) (mg/Nm3) (mg/m3) P2

5224 0.2225 1226

metals and their compounds (Cu, Pb, As, Ni, Cd, Zn, Cr, Hg, Sn)

0.2222, 223 None

No data

None None None

(mg/m3) (mg/Nm3)

I1 Reference conditions: 3 %O2 P7 non-representative data, also see comment on P in category 1.1.1 E1 Reference conditions: 15% O2 NL1 Reference conditions: standard, 3% O2 197 refinery gas, LPG, other gas (incl. natural gas) 198 coke oven gas, oxygen steel furnace gas 199 blast furnace gas P1 Reference conditions: 3% O2 200 General fuel gas 201 auxiliary fuel: gasoil P2 Reference conditions: 8% O2 202 MWth > 500 203 combined single plants fuelled with gas are normally authorised with a limit of 50 mg/m3 204 MWth < 500 205 process furnaces and boilers NL2 Reference conditions: 15% O2, ISO 206 gas turbine 207 gas engine 208 NOx as NO2 209 NOx as NO2 210 auxiliary fuel: gasoil 211 second and third line are in g/GJ 212 MWth > 500 213 MWth < 500 214 refinery gas 215 coke oven gas 216 blast furnace gas 217 oxygen steel furnace gas, other gas (incl. natural gas) 218 LPG 219 SOx as SO2 220 auxiliary fuel: gasoil 221 SOx as SO2 222 Cd, Hg, Tl 223 mass flow 1 g/h 224 Pb+Cr+Cu 225 Hg+Cd 226 As+Ni


18

Air pollutant I I1 L NLHHAV P P7 EE1 S UK PCDD/PCDF 0.01227 None No data None None None (mg/m3) PCB 0.5228 None No data None None None (mg/m3) NH3 100 None No data None None 20 (mg/m3) (mg/m3)

227 mass flow 0.02 g/h 228 mass flow 0.2 g/h


19

Water pollutant

A B DKDK3 FINFIN1 F D EL EL6 IRL

100 Suspended solids

30 None 35

50229 30 230

30-40 30 DAV

(mg/l) (mg/l) (mg/l) (mg/l) 300 COD 90

None

125

30231 40232 50233 80 234 150 235

120-180 None

(mg/l) (mg/l) (mg/l) (mg/l) 100 BOD None None 45

None 20-60 None

(mg/l) (mg/l) None TOC 30 None 40

None None None

(mg/l) (mg/l) None Total N None None 30

10236 0.6 237 20 238

1 DAV, 239

(mg/l) (mg/l) (mg/l) (mg/l) None Total P 2 None 10

1.5240 3241

None None


0.1 None None 242 0.2243 1244 0.15245 0.15246 0.5247

1 248 None

(mg/l) (mg/l) (mg/l) (mg/l) Metals and their compounds (Cd, Hg, Ni, Pb)

None None 15 None None None

(mg/l)

DK3 no waste water is being produced FIN1 No limit values. It is stipulated that waste waters should be treated and that sour and alcalic waste water should be neutralised. EL6 The quality limits for discharges of liquid industrial effluent into natural recipients are those specified in the Prefectural decisions for specific recipients. The values are from the Prefectural decisions concerning 7 prefectures where large combustion plants operate. 229 waste water from water treatment; there are some exceptions to the requirements 230 waste water from the flue gas cleaning 231 waste water from cooling systems; flushing water from recirculation cooling systems 232 waste water from flushing of other coating circuits 233 waste water from other sources in the generation of steam, 80 mg/l for waste water from condensate desalination 234 in the application of quicklime; after subtraction of the pre-load of COD added by the service water 235 in the application of limestone; after subtraction of the pre-load of COD added by the service water 236 TIN; sum of ammonium, nitrite and nitrate nitrogen; waste water from other sources in the generation of steam 237 NO2 238 NO3 239 neutralised water and ammonia only 240 waste water from cooling systems; waste water from recirculation cooling systems; if only inorganic P is used, the value for P is increased to 3 mg/l 241 waste water from other sources in the generation of steam; waste water from flushing of other coating circuits 242 AOX 243 waste water from water treatment; there are some exceptions to the requirements; if the parameter is to be expected in the waste water 244 waste water from water treatment; there are some exceptions to the requirements; AOX in regeneration water from ion exchangers 245 waste water from cooling systems; water from single-pass or open-ended fresh water cooling systems 246 flushing water from recirculation cooling systems 247 waste water from flushing of other coating circuits 248 CL solvents


20

Water pollutant

II2 3HAV L NL P P8 E S UK

Suspended solids

80 None 60 750E2 200E3 80-300E4

None 45UK1

(mg/l) (mg/l) (mg/l) 150 COD 160

None

No data

1500 E2 500 E3 160-500 E4

None 5000 UK1

(mg/l) (mg/l) (mg/l) 40 BOD 40 None No data

200 E3 40-300 E4

None 30 UK1

(mg/l) (mg/l) (mg/l) TOC None None No data None None None Total N 249 None 15 10-20 E4 250 None None (mg/l) (mg/l)

10 Total P 10 None No data

50 E2 251 10-20 E4 252

None None


1253 None No data None None 5254 5255

(mg/l) (g/l)

I2 Valid for discharges in surface water P8 non-representative data, also see comment on P in category 1.1.1 E2 discharges to WWTP E3 discharges to sea E4 valid only for discharges to rivers and streams UK1 direct to water 249 N-NH4 = 15 mg/l, N-NO2 = 0.6 mg/l, N-NO3 = 20 mg /l 250 This ELV must be lower than 10 mg/l (total N as N2) in lakes and similars 251 This ELV is lower (0.5) in lakes and similars to avoid eutrophic problems. 252 This ELV is lower (0.5) in lakes and similars to avoid eutrophic problems. 253 Chlorinated solvent 254 Pentachlorphenol to water 255 Gamma-HCH


21

Water pollutant

II2 3HAV L NL P P8 E S UK

Metals and their compounds (Cd, Hg, Ni, Pb)

None 0.01256 0.02257 0.05258

Fe: 2 259 Al: 1-2, 30E2 As: 0.5-1 Ba: 20 2-10260 Cd: 0.1-0.5 Crtot: 10 Cr(III): 2-4 0.2-0.5261 Pb: 2 E2 Cu: 5 E2 Fe: 2, 20 E2 Hg: 0.005-0.1 Se: 0.03-0.1 Sn: 10 Zn: 3-20

None As: 1 Cd: 5 Cr: 50 Cu: 60 Fe: 5000 Ni: 10 Hg: 1 Zn: 340

(mg/l) (mg/l) (mg/l) (g/l)

256 Cd, Hg 257 As, Cr, Cu 258 Ni, Pb, Zn 259 toxic elements (As, Cd, Cr(VI), Ni, Hg, Pb, Se, Cu, Zn) must be < 3 260 B, Mn, Cu, Fe, Ni 261 Cr(VI), Pb

Existing installations 1.2

22

1.2 Mineral oil refineries Air pollutant AA1 B DKDK1 FIN FIN1 F F1 D EL IRL IRL2

None 5264 DAV HHAV 30265 , DAV HHAV 50-150 DAV HHAV

Particulates 50 A2 HHAV 35A2 DAV

5

100 267

100 262 HHAV 40 263

268 5269 DAV HHAV 50270 DAV HHAV 150271 HHAV

100 / 150 100 266

None

(mg/m3) (mg/Nm3) (mg/m3) (mg/m3) (mg/m3) (mg/m3) 50272 DAV HHAV 80273 DAV HHAV 100274 DAV HHAV

CO 2000 A2 HHAV None None None

276 50277 DAV HHAV 80278 100279

0.05%vol 275

100

(mg/m3) (mg/m3) (mg/m3) 100280 80281

100283 DAV HHAV 150284 DAV HHAV 200285 DAV HHAV 300286 DAV HHAV 500287 DAV HHAV

NOx None A2 225

1000 (t/a)

500 282

290 100291 DAV HHAV 150292 200293 300294 500295

100 288, 289 450

A1 Reference conditions: 3% O2 DK1 Reference conditions: 3% O2 FIN1 Reference conditions: 3% O2 F1 Reference conditions: 273 k, 101.3 kPa IRL2 for non combustion gases 273 K, 101.3 kPa, no correction for water or oxygen; for combustion gases 273K, 101.3kPa, dry gas, 3% O2 for liquid and gas fuels, 6 % O2 for gas turbines and compression ignition engines. 15% O2 for gas turbines and compression ignition engines A2 fluid catalytic cracking 262 For the flows < 1 kg/h 263 For flows > 1 kg/h 264 combustion plants, gaseous fuels 265 calcination plants 266 FCC installations only 267 boiler of the waste water plant 268 reference conditions: 3% O2 269 if mass flow > 0.5 kg/h, special regulation for combustion plants for gaseous fuels 270 if mass flow > 0.5 kg/h 271 if mass flow < 0.5 kg/h 272 FCC 273 combustion plants, gaseous fuels 274 combustion plants, liquid fuels 275 FCC installations only 276 reference conditions: 3% O2 277 special regulation on FCC (FCC: fluidized catalytic cracker) 278 special regulation for combustion plants for gaseous fuels 279 special regulation for combustion plants for liquid fuels 280 limit value for gas turbine 281 limit value for boiler 282 for flows> 1kg/h 283 combustion plants, gaseous fuels; > 300 MW 284 combustion plants, liquid fuels; > 300 MW 285 combustion plants, gaseous fuels; 50 to 300 MW 286 FCC; combustion plants, liquid fuels; 50 to 300 MW 287 calcination plants 288 15 %O2 content 289 gas turbine exhaust gases 290 reference conditions: 3% O2 291 if mass flow > 5 kg/h, rated thermal input > 300 MW, special regulation for combustion plants for gaseous fuels 292 if mass flow > 5 kg/h , special regulation for combustion plants for liquid fuels, rated thermal input > 300 MW 293 if mass flow > 5 kg/h, special regulation for combustion plants for gaseous fuels, rated thermal input 50 to 300 MW 294 if mass flow > 5 kg/h, special regulation on FCC (FCC: fluidized catalytic cracker), special regulation for combustion plants for liquid fuels, rated thermal input 50 to 300 MW


23

Air pollutant AA1 B DKDK1 FIN FIN1 F F1 D EL IRL IRL2 (mg/Nm3) (mg / MJ) (mg/m3) (mg/m3) (mg/m3)

None 5-100296 DAV HHAV 350-1700 DAV HHAV 297 500298 DAV HHAV 1700299 DAV HHAV

SOx 1700 A2 HHAV 1000

2000300 1700 301

1700 HHAV

302 5 100303 DAV HHAV

350 1700304 500305 and 85% (ROD) 1700306

None 1700

(mg/m3) (mg/Nm3) (t/a) (mg/m3)

(mg/m3) (mg/m3) (mg/m3)

H2S 10 A3 HHAV None None 307 , HHAV 10308 DAV HHAV 10 None

(mg/m3) (mg/m3) (mg/m3) (mg/Nm3) NH3 None None None 50 HHAV None309 None 8.5

(mg/m3) (mg/m3) kg/hour PCDD/PCDF None None None None None310 None None (mg/m3) Metals and their compounds (Cu, Pb, As, Ni, Cd, Zn, Cr, Hg, Sn)

1 311, A2 HHAV 1 312, A2 0.5 313, A2

None All 314

5315 1316 0.2317

None None318 None None

(mg/m3) (mg/m3) VOC None None 2800 319 None 20320 HHAV

100321 150322 150323

None None

(mg/m3) (t/a) (mg/m3) Benzene None None None None 1 - 5324 HHAV None None (mg/m3)

295 special regulation for calcination plants, if mass flow > 5 kg/h 296 combustion plants, gaseous fuels; > 50 MW 297 combustion plants, liquid fuels; > 50 MW 298 calcination plants; sulphur recovery units 299 FCC 300 oil refineries; target value 301 boiler of the waste water plant 302 reference conditions: 3% O2 303 special regulation for combustion plants for gaseous fuels, rated thermal input 50 to 300 MW, rated thermal input > 300 MW 304 special regulation for combustion plants for liquid fuels, rated thermal input > 300 MW, rated thermal input 50 to 300 MW 305 ROD = rate of desulphurisation 306 special regulation on FCC (FCC: fluidized catalytic cracker) A3 claus plant 307 Discharge expressed in SO2 and includes 1700mg/m3 of SOx 308 if mass flow > 0.05 kg/h 309 general ELV exists, but is not relevant, as real emissions are far below 310 minimisation obligation 311 Pt and compounds 312 V and compounds 313 Ni and compounds 314 boiler of the waste water plant 315 Pb, Cu, Cr, V 316 Ni 317 Cd 318 general ELV exists, but is not relevant, as real emissions are far below 319 target value 320 sum of class I organic compounds if their mass flow is > 0.1 kg/h; see class definition in Annex E of GBR 1 321 sum of class II organic compounds if their mass flow is > 2 kg/h; also valid for sum of coinciding class I and II organic compounds 322 sum of class III organic compounds if their mass flow is > 3 kg/h; also valid for sum of coinciding class I to III organic compounds 323 special regulation for petrol 324 sum of class III carcinogenic compounds if their mass flow > 25 g/h; also valid for sum of coinciding class I to III carcinogenic compounds According to the minimisation obligation for carcinogenic compounds, the ELV has been set to 1 mg/m3 in many permits instead of the 5 mg/m3 prescribed in GBR 1.


24

Air pollutant II1 L NLNL1 P E S UK Particulates 80 100325 HHAV

5326 HHAV 50327 HHAV

No data 100-180328 75329 90

(mg/m3) (mg/Nm3) (mg/Nm3) (mg/Nm3) (mg/m3) CO 250 None No data 500330

1500331 None 100

(mg/m3) (mg/Nm3) (mg/m3) NOx 500 120-700332

HHAV 120-500333 HHAV 70-500334 HHAV

No data 200-1000 82 YAV 600

(mg/m3) (mg/Nm3) (mg/Nm3) (tonne / Mtonne crude)

(mg/m3)

SOx 1700335 1000336 DAV No data 1700-3100337 1700338

96 3YAV 500339

1700 (range 200-4000)

(mg/m3) (mg/Nm3) (mg/Nm3) (tonne / Mtonne crude)

(mg/m3)

H2S 5 10340 No data 10 None None341 (mg/m3) (mg/Nm3) (mg/Nm3) NH3 30 None No data None None None (mg/m3) PCDD/PCDF 0.01342 None No data None None None343 (mg/m3) Metals and their compounds

0.3344 10345

None No data None None None

(mg/m3) VOC 300 None No data None None None (mg/m3) Benzene 5346 5 No data None None None (mg/m3) (mg/Nm3)

I1 Reference conditions: O2: 3% for gaseous and liquid fuels, 6% for coal, 11% for other solid fuels NL1 Reference conditions: 3%O2, standard; H2S only standard 325 liquid fuels 326 gaseous fuels 327 cat cracker 328 boilers and furnaces 329 FCCU 330 catalyzers regeneration 331 other units 332 liquid fuels; process furnace; steam boiler 333 gaseous fuels; process furnace 334 gaseous fuels; steam boiler 335 maximum sulphur percentage allowable: 3% 336 bubble for all installations in refinery 337 SOx as SO2; data from measurement are lower than 2800 mg/Nm3 338 SOx as SO2; ELV to get in 2003 339 SRU; unit = tonnes per year at a sulphur production of 50000 tonnes per year. ELV shall be increased or decreased by 25 tonnes S/year for S production levels higher or lower in intervals of 5000 tonnes 340 SCOT unit 341 monitoring but no limits specified 342 mass flow 0.02 g/h 343 monitoring but no limits specified 344 Cd, Hg, Tl 345 Cu, Pb, Sn, Cr 346 mass flow 25 g/h


25

Water pollutant

A B DK FIN F D EL IRL

Suspended solids

30A4 A6 30 None 5-12.5 347 DAV

20348

None 349 , 350 60 DAV

(mg/l) (mg/l) (g/t) (mg/l) 75000 COD 75 A4 A6 A7

185

60.1

20-50 351 DAV

80 352 80 100353

354 , 355 450 DAV

(kg/month) (mg/l) (mg/l) (g/t)

(g/t) (mg/l) (mg/l)

BOD 20 A4 A6 15 A4 A7

None None 5-12.5 356 DAV 20 357

25358

359 , 360 150 DAV

(mg/l) (g/t) (mg/l) (mg/l) TOC None None None None None None None

10000 Total N 3 A4 A6 361 5 A4 A7 362

10

8

5-12.5 363 DAV 20 364 DAV

40365 366 20367 DAV



400 Total P 0.8 A4 A7 368 1.5 0.3

10 369 DAV 1.5 370 , 371 None


(mg/l) (mg/l)

A4 direct discharge (Danube) A6 surface and cooling water 347 simple refinery, or simple refinery incl. Catalytic cracking, or thermic and/or hydro-cracking 348 simple refinery, or simple refinery incl. Catalytic cracking, or thermic and/or hydro-cracking, and/or vapo-cracking or oil or one of the above with conversion or deep desulfurisation. 349 Presidential Decree No 1180/81 states that the guide values are based on the amount of pollution resulting after proper processing of effluent with an efficiency of 85% taking the average of values over 30 consecutive days. This percentage is calculated on the pollutant load of untreated waste. 350 The quality limits for discharges of liquid industrial effluent into natural recipients are those specified in the prefectural decisions for specific recipients. A7 after biological treatment of waste water 351 simple refinery, or simple refinery incl. Catalytic cracking, or thermic and/or hydro-cracking 352 simple refinery, or simple refinery incl. Catalytic cracking, or thermic and/or hydro-cracking, and/or vapo-cracking or oil or one of the above with conversion or deep desulfurisation. 353 if 80% or more of COD load are minimised at WWTP 354 Presidential Decree No 1180/81 states that the guide values are based on the amount of pollution resulting after proper processing of effluent with an efficiency of 85% taking the average of values over 30 consecutive days. This percentage is calculated on the pollutant load of untreated waste. 355 The quality limits for discharges of liquid industrial effluent into natural recipients are those specified in the prefectural decisions for specific recipients. 356 simple refinery, or simple refinery incl. Catalytic cracking, or thermic and/or hydro-cracking 357 simple refinery, or simple refinery incl. Catalytic cracking, or thermic and/or hydro-cracking, and/or vapo-cracking or oil or one of the above with conversion or deep desulfurisation. 358 BOD5 359 Presidential Decree No 1180/81 states that the guide values are based on the amount of pollution resulting after proper processing of effluent with an efficiency of 85% taking the average of values over 30 consecutive days. This percentage is calculated on the pollutant load of untreated waste. 360 The quality limits for discharges of liquid industrial effluent into natural recipients are those specified in the prefectural decisions for specific recipients. 361 NH4-N 362 NH4-N 363 simple refinery, or simple refinery incl. Catalytic cracking, or thermic and/or hydro-cracking 364 simple refinery, or simple refinery incl. Catalytic cracking, or thermic and/or hydro-cracking, and/or vapo-cracking or oil or one of the above with conversion or deep desulfurisation. 365 TIN; sum of ammonia-, nitrite- and nitrate nitrogen; if the elimination of nitrogen > 75% in the WWTP, higher limit values are possible 366 expressed as NO2 NO3, total nitrogen except NO2, NO3 367 ammonia N only 368 PO4-P 369 flow >15 kg/day : 10mg/l; flow > 40 kg/day : 2mg/l; flow > 80 kg/day : 1 mg/l 370 Presidential Decree No 1180/81 states that the guide values are based on the amount of pollution resulting after proper processing of effluent with an efficiency of 85% taking the average of values over 30 consecutive days. This percentage is calculated on the pollutant load of untreated waste. 371 The quality limits for discharges of liquid industrial effluent into natural recipients are those specified in the prefectural decisions for specific recipients.


26

Water pollutant



None None None 372 DAV None 373 , 374 Cd 0.05 DAV Hg 0.01 DAV Zn 0.5 DAV

(mg/l) 1000 1

Hydrocarbons 10 A4 A6 50 A5

5

0.8

1-2.5 375 3 376

2 377 , 378 50 DAV

(kg/month) (g/t input)

(mg/l) (mg/l)

(g/t)

(g/t) (mg/l) (mg/l)

150 phenol 0.1 A4 A6 0.1

0.1

0.05-0.125 379 DAV 2 380

0.15 381 , 382 1 DAV



benzene None None None 1.5 None None None (mg/l) cyanide None None None 1.5 0.1 None None

(mg/l) (mg/l) sulfide 0.1 A4 None None 1.5 0.6383 None None

(mg/l) (mg/l) (mg/l) MTBE None None None 1.5 None None None (mg/l)

372 Cr hexavalent: 0.1 mg/l; Pb: 0.5 mg/l; Zn: 2 mg/l, Mn: 1 mg/l, Sn: 2mg/l, Cu: 0.5 mg/l, Cr: 0.5 mg/l, Ni : 0.5 mg/l,Fe+Al:5mg/l 373 Presidential Decree No 1180/81 states that the guide values are based on the amount of pollution resulting after proper processing of effluent with an efficiency of 85% taking the average of values over 30 consecutive days. This percentage is calculated on the pollutant load of untreated waste. 374 The quality limits for discharges of liquid industrial effluent into natural recipients are those specified in the prefectural decisions for specific recipients. A5 indirect discharge 375 simple refinery, or simple refinery incl. Catalytic cracking, or thermic and/or hydro-cracking 376 simple refinery, or simple refinery incl. Catalytic cracking, or thermic and/or hydro-cracking, and/or vapo-cracking or oil or one of the above with conversion or deep desulfurisation. 377 Presidential Decree No 1180/81 states that the guide values are based on the amount of pollution resulting after proper processing of effluent with an efficiency of 85% taking the average of values over 30 consecutive days. This percentage is calculated on the pollutant load of untreated waste. 378 The quality limits for discharges of liquid industrial effluent into natural recipients are those specified in the prefectural decisions for specific recipients. 379 simple refinery, or simple refinery incl. Catalytic cracking, or thermic and/or hydro-cracking 380 simple refinery, or simple refinery incl. Catalytic cracking, or thermic and/or hydro-cracking, and/or vapo-cracking or oil or one of the above with conversion or deep desulfurisation. 381 Presidential Decree No 1180/81 states that the guide values are based on the amount of pollution resulting after proper processing of effluent with an efficiency of 85% taking the average of values over 30 consecutive days. This percentage is calculated on the pollutant load of untreated waste. 382 The quality limits for discharges of liquid industrial effluent into natural recipients are those specified in the prefectural decisions for specific recipients. 383 sum of sulphides and of mercaptanes


27

Water pollutant

II2 3HAV L NL P E S UKUK1

No data Suspended solids

80 40-100 20-60 DAV 60

80-300E1 E2 18 E1, E2

None None

(mg/l) (mg/l) (mg/l) (mg/l) No data COD 160

100-1000

100-150 DAV 150

160-500 E1 800 E2 68

25 YAV 100 MAV

6000

(mg/l) (mg/l) (mg/l) (mg/l) (tonne / Mtonne crude) (mg/l)

(kg/day)

No data BOD 40 50 20 DAV 40

40-300 E1 350 E2 19

None 1000

(mg/l) (mg/l) (mg/l) (mg/l) (kg/day) TOC None None No data None None None Total N 384 40-100

15-25 DAV No data 10-20 E1 385 1.5 YAV

15 MAV None

(mg/l) (mg/l) (tonne / Mtonne crude) (mg/l)

Total P 10 None No data 10-20 E1 386 30 E2 0.41

0.1 YAV 0.5 MAV

None

(mg/l) (mg/l) (tonne / Mtonne crude) (mg/l)

None None No data 387 As 0.5-1 E1; Cd 0.1-0.5 E1, < 0.02 E1; Crtot < 0.1 E1 E2; Cr (VI) 0.2-0.5 E1; Cu 2-10E1, 4 E2; Hg 0.005-0.1 E1; Ni 2-10 E1,


28

Water pollutant

II2 3HAV L NL P E S UKUK1

0.5 0.02

(mg/l) (mg/l) (mg/l) (mg/l) (kg/day) benzene None 0.1 No data None None None (mg/l) cyanide None None 0.5 0.5-1 E1


29

2.1.1 Copper ore roasting or sintering installations Air pollutant A B DK FIN F D EL IRL Particulates No I. No I. 90391

10392 1393 40394

No I. No I. No I. No I.

See footnotes

CO No I. No I. None No I. No I. No I. No I. NOx No I. No I. None No I. No I. No I. No I. SOx No I. No I. 4500395

2.7396 No I. No I. No I. No I.

See footnotes

VOC No I. No I. None No I. No I. No I. No I. PCDD/PCDF No I. No I. None No I. No I. No I. No I. metals and their compounds (Cu, Pb, As, Ni, Cd, Zn, Cr, Hg, Sn)

No I. No I. Cu 12; Ni 5; Zn 10; Pb 5; As 2; Cd 0.5; Hg 20


(t/a; except Hg kg/a)

391 Total emissions of particulates; unit = t/a 392 Emissions from Cu- and Ni-concentrate dryer; unit = mg/m3(n) 393 Ventilation gases from the smelter and converter areas; unit = mg/m3(n) 394 Emissions from combustion installations; ; unit = mg/MJ 395 Total emissions of SO2; unit = t SO2/a 396 Limit value for sulphur acid plants; unit = kg SO2/t 100% acid


30

Air pollutant I L NL P E S UK

None Particulates 20 No I. No I. 150 75397 YAV/MAV

(mg/m3) (mg/Nm3) (t/year) CO None No I. No I. 500 None

ppm None NOx 500398 No I. No I. 616 250 YAV

(mg/m3) (mg/Nm3) (t/year) None SOx 800399 No I. No I. 400

1500 450-1200

4500 YAV/MAV

(mg/m3) (mg/Nm3) (t/year) 5-600401 VOC 5402 20403 150404 300405 600406

No I. No I. None None

(mg/m3) None PCDD/PCDF 0.01407 No I. No I. None 0.5 YAV

(mg/m3) (g/year) None metals and

their compounds (Cu, Pb, As, Ni, Cd, Zn, Cr, Hg, Sn)

5408, 409 0.2410, 411 1412, 413

No I. No I. None YAV/MAV Cu: 8 Pb: 12 As: 1 Ni: none Cd: 0.3 Zn: 20 Cr: none Hg: 0.2 Sn: none

(mg/m3) (t/year)

397 Dust emissions also controlled by Guideline values of:

Fabric filter = 5 mg/Nm3 ESP (fuming plant) = 20 mg/Nm3 ZnO Plant scrubber = 35 mg/Nm3

398 mass flow 5 kg/h 399 mass flow 5 kg/h 400 SOx as SO2 401 Valid for substances of different classes 402 valid for substances of class I and mass flow 25 g/h 403 valid for substances of class II and mass flow 0.1 kg/h 404 valid for substances of class III and mass flow 2 kg/h 405 valid for substances of class IV and mass flow 3 kg/h 406 valid for substances of class V and mass flow 4 kg/h 407 mass flow 0.02 g/h 408 Metals Cu, Pb, V, Rh, Pd, Pt, Mn, Sb, CN, Cr(III), Sn 409 mass flow 25 kg/h 410 Cd+Hg+Tl 411 mass flow 1 g/h 412 As+Ni+Cr(VI)+Co 413 mass flow 5 g/h


31

Water pollutant


Suspended solids

No I. No I. None No I. No I. No I. No I.

COD No I. No I. None No I. No I. No I. No I. TOC No I. No I. None No I. No I. No I. No I. Hydrocarbons No I. No I. None No I. No I. No I. No I. Metals and their compounds (Cu, Pb, As, Ni, Cd, Zn, Cr, Hg)

No I. No I. Cu 10; Ni 10; Zn 10; Pb 3; As 5; Cd 0.3; Hg 10


(kg/d; except Hg kg/a) FOE

FOE In REPORTING TOOL the same value is given in kg/d and not in kg/a


32

Water pollutant

II1 3HAV L NL P E S UK

Suspended solids

80 No I. No I. 80-300E1, E2 300

None

(mg/l) (mg/l) COD 160

No I. No I. 160-500 E1 E2

450 None

(mg/l) (mg/l) TOC None No I. No I. None E2

150 None

(mg/l) Hydrocarbons 5 No I. No I. 20-40 E1 None (mg/l) (mg/l)

E1 414 As 0.5-1 E2 Cd 0.1-0.5 E2; Cr(III) 2-4 Cr(VI) 0.2-0.5 E2 Crtot 0.2-0.5E2; Cu 2-10 E2 Hg 0.005-0.1E2 Ni 2-10 E2 Pb 0.2-0.5E2 Sn 10 Zn 3- 20 3E2

None metals and their compounds (Cu, Pb, As, Ni, Cd, Zn, Cr, Hg)

Cu 0.1; Ni 2; Zn 0.5; Pb 0.2; As 0.5; Cd 0.02; Crtot 2; Cr(VI) 0.2; Hg 0.005

No I. No I.

Al: 1-2 Ba: 20 Se: 0.03-0.1E1 Pb: 2E2,


33

2.1.2 Zinc ore roasting or sintering installations Air pollutant A B DK FIN F F1 HHAV D EL IRL

None 40 416 Particulates No I. No I. 600 40-100 417

50 Dav HHAV No I. No I.

(kg/a) (mg/m3) (mg/m3) CO No I. No I. None None None No I. No I.

500 418 NOx No I. No I. None 500 419

500 DAV HHAV No I. No I.

(mg/m3) (mg/m3) 300 420 SOx No I. No I. None 300 421


(mg/m3) (mg/m3) 0.1 PCDD/PCDF No I. No I. None None

0,1 422 No I. No I.

(ng/m3) (ngTE/m3) None HHAV

Zn none 5424 1425 Cd 0.1 0.2426


No I. No I.

1400427 5.2428 700429 130430 0.5431 30432 0.1433

423 HHAV

HHAV

Hg 0.2434 As 1435 Ni 1436 Cr 1437 5438 Pb,Cu,Sn 5439

No I. No I.

F1 Reference conditions: 273 k, 101.3 kPa, 7% O2 416 for flows > 1 kg/h 417 40 mg/m3 for flows > 1 kg/h, 100 mg/m3 for flows 1 kg/h 418 for flows > 1 kg/h 419 for flows > 25 kg/h 420 for flows > 1 kg/h, 421 for flows > 25 kg/h 422 target value 423 Cd+Hg+Ti = 0.2 mg/m3 As+Te+Se= 1 mg/m3, Pb + Zn + Cu + Co + Sb + Cr + Mn + Ni + V + Sn = 5 mg/m3 424 Sum of Sb, Pb, Cr, CN, F, Cu, Mn, Pt, Pd, Rh, V, Sn 425 Sum of As, Co, Ni, Se, Te 426 Sum of Cd, Hg, Tl 427 As in kg/a 428 As in g/t 429 As in kg/a target value 430 Cd in kg/a 431 Cd in g/t 432 Zn in t/a 433 Zn in kg/t 434 sum of Cd, Hg, Th (class I particulate inorganic compounds) at a mass flow of 1g/h or more 435 sum of As, Co, Ni, Se, Te (class II particulate inorganic compounds) at a mass flow of 5 g/h or more, If compounds of several classes are present, the mass concentration in the clean gas shall not exceed a total of 1 mg/m for coinciding class I and II compounds as well as a total of 5 mg/m for coinciding class I and III or class II and III compounds. 436 sum of As, Co, Ni, Se, Te (class II particulate inorganic compounds) at a mass flow of 5 g/h or more, If compounds of several classes are present, the mass concentration in the clean gas shall not exceed a total of 1 mg/m for coinciding class I and II compounds as well as a total of 5 mg/m for coinciding class I and III or class II and III compounds, Ni: limit value is depending on type of Ni compounds: * carcinogenic Ni-compounds as sum of carcinogenic As, Cr-VI, Co and Ni and their compounds, 3,3-dichlorobenzidine,

dimethyl sulfate, ethyleneimine (class II carcinogenic compounds) at a mass flow of 5 g/h or more; also valid for coinciding classes I and II; minimisation obligation

* Ni and its compounds as sum of As, Co, Ni, Se, Te (class II particulate inorganic compounds) see remark 3, 5 437 Cr: limit value is depending on type of Cr compounds: * carcinogenic Cr-VI-compounds as sum of carcinogenic As, Cr-VI, Co and Ni and their compounds, 3,3-

dichlorobenzidine, dimethyl sulfate, ethyleneimine (class II carcinogenic compounds) at a mass flow of 5 g/h or more; also valid for coinciding classes I and II; minimisation obligation

* Cr and its compounds as sum of Sb, Pb, Cr, Cu, Mn, Pt, Pd, Rh, V, Sn (class III particulate inorganic compounds) 438 sum of Sb, Pb, Cr, CN,F, Cu, Mn, Pt, Pd, Rh, V, Sn (class III particulate inorganic compounds) at a mass flow of 25 g/h or

more, If compounds of several classes are present, the mass concentration in the clean gas shall not exceed a total of 1 mg/m for coinciding class I and II compounds as well as a total of 5 mg/m for coinciding class I and III or class II and III compounds, Cr: limit value is depending on type of Cr compounds:


34

Air pollutant A B DK FIN F F1 HHAV D EL IRL See

footnotes (mg/m3) (mg/m3)

* carcinogenic Cr-VI-compounds as sum of carcinogenic As, Cr-VI, Co and Ni and their compounds, 3,3-


* Cr and its compounds as sum of Sb, Pb, Cr, Cu, Mn, Pt, Pd, Rh, V, Sn (class III particulate inorganic compounds) 439 sum of Sb, Pb, Cr, CN,F, Cu, Mn, Pt, Pd, Rh, V, Sn (class III particulate inorganic compounds) at a mass flow of 25 g/h or more, If compounds of several classes are present, the mass concentration in the clean gas shall not exceed a total of 1 mg/m for coinciding class I and II compounds as well as a total of 5 mg/m for coinciding class I and III or class II and III compounds.


35

Air pollutant I L NLNL1 P E SS1 UK Particulates 20 10-25440

HHAV No I. 50

(mg/m3) (mg/m3) (mg/Nm3) CO None None No I. 500 (mg/Nm3) NOx 500441 150442 HHAV

200443 HHAV No I. 616

(mg/m3) (mg/m3) (mg/Nm3) SOx 800444 None No I. 1425445 (mg/m3) (mg/m3) (mg/Nm3) PCDD/PCDF 0.01446 None No I. None (mg/m3) metals and their compounds (Cu, Pb, As, Ni, Cd, Zn, Cr, Hg, Sn)

5447, 448 0.2449, 450 1451, 452

Cd 0.2 HHAV Pb 1 HHAV

No I. None

(mg/m3) (mg/m3)

NL1 Reference condition: standard S1 Limit values equal those for copper ore roasting or sintering installations, category 2.1.1. Integrated plant for both categories. 440 Various sources 441 mass flow 5 kg/h 442 Various sources; boilers (combustion installations) 443 Various sources; burners (process installations) 444 mass flow 5 kg/h 445 SOx as SO2 446 mass flow 0.02 g/h 447 Metals Cu, Pb, V, Rh, Pd, Pt, Mn, Sb, CN, Cr(III), Sn 448 mass flow 25 g/h 449 Cd+Hg+Tl 450 mass flow 1 g/h 451 As+Ni+Cr(VI)+Co 452 mass flow 5 g/h


36

Water pollutant

A B DK FIN FF2 D EL IRL

30 HHAV Suspended solids

No I. No I. None 35 453 HHAV 100454 HHAV 150455 HHAV (600)456 HHAV

50D1 D2 No I. No I.

(mg/l) (mg/l) 100 HHAV COD No I. No I. None 125457 HHAV 300458 HHAV 2000459 HHAV

1.5 D1 No I. No I.

(mg/l) (kg/t) TOC No I. No I. None None None No I. No I.

20 HHAV Hydrocarbons No I. No I. None 10

None No I. No I.

(mg/l) None 460 D3

As 0.1; Cd 0.2; Cr 0.5; Cu 0.5; Hg 0.05; Ni 0.5; Pb 0.5; Zn 1

Metals and their compounds (Cu, Pb, As, Ni, Cd, Zn, Cr, Hg)

No I. No I.

50461 0.19462 100463 0.37464 15465 55.6466 700467 2.6468 100469 370470 5471 0.02472 5473 18.5474

None

Hg 0.05475 (mg/l) 1476 (g/tzinc) As 0.1477 (mg/l) 2478 (g/tzinc) Cd 0.2479 (mg/l) 3480 (g/tzinc) Pb,Cu,Cr,Ni 0.5481 (mg/l) Cr,Cu 10482 (g/tzinc) Pb,Ni 15483 (g/tzinc) Zn 1484 (mg/l) 30485 (g/tzinc) Fe 100486 (g/tzinc)

No I. No I.

F2 discharges are collected and treated in a station dimensioned for treating all discharges from the installation D1 requirements for waste water at the point of discharge D2 waste water from water treatment 453 if flow > 15 kg/d 454 if maximum daily flow 15 kg/d 455 si epuration par lagunage 456 if connected to WWTP 457 if flow > 100 kg/d 458 if flow 100 kg/d 459 if connected to WWTP 460 Hg 1 g/t; As 2 g/t; Cd 3 g/t; Cr, Cu 10 g/t; Pb, Ni 15 g/t; Zn 30g/t D3 requirements for waste water prior to blending 461 As in kg/a 462 As in g/t 463 Cd in kg/a 464 Cd in g/t 465 Co+Ni in t/a 466 Co+Ni in g/t 467 Cu in kg/a 468 Cu in g/t 469 Fe in t/a 470 Fe in g/t 471 Hg in kg/a 472 Hg in g/t 473 Zn in t/a 474 Zn in g/t 475 requirements for waste water prior to blending


37

Water pollutant

A B DK FIN FF2 D EL IRL

See footnotes

476 requirements for waste water prior to blending, add. valid if the production capacity on zinc and by-products amounts to more than 10 tons per day 477 requirements for waste water prior to blending 478 requirements for waste water prior to blending, add. valid if the production capacity on zinc and by-products amounts to more than 10 tons per day 479 requirements for waste water prior to blending 480 requirements for waste water prior to blending, add. valid if the production capacity on zinc and by-products amounts to more than 10 tons per day 481 requirements for waste water prior to blending 482 requirements for waste water prior to blending, add. valid if the production capacity on zinc and by-products amounts to more than 10 tons per day 483 requirements for waste water prior to blending, add. valid if the production capacity on zinc and by-products amounts to more than 10 tons per day 484 requirements for waste water prior to blending 485 requirements for waste water prior to blending, add. valid if the production capacity on zinc and by-products amounts to more than 10 tons per day 486 requirements for waste water at the point of discharge


38

Water pollutant

II1 3HAV L NL P E E1 SS1 UK

Suspended solids

80 5 DAV No I. 80-300

(mg/l) (mg/l) (mg/l) COD 160

50 DAV No I. 160-500

(mg/l) (mg/l) (mg/l) TOC None None No I. None (mg/l) Hydrocarbons 5 None No I. 20-40 (mg/l) (mg/l)

487 As 0.5-1; Cd 0.1-0.5; Cr(III) 2-4; Cr (VI) 0.2-0.5; Cu 2-10 ; Hg 0.005-0.1; Ni 2-10; Pb 0.2-0.5; Sn 10; Zn 3-20

Metals and their compounds

Cu 0.1; Pb 0.2; As 0.5; Ni 2; Cd 0.02; Zn 0.5; Crtot 2; Cr(VI) 0.2; Hg 0.005

DAV Cu 0.03; Ni 0.03; Zn 0.3; Pb 0.02; As 0.01; Cd 0.01; Cr 0.03; Hg 0.0003

No I.

Al: 1-2 Ba: 20 Se: 0.03-0.1 2-10488


I1 valid for discharges in surface waters E1 valid only for discharges to rivers and streams 487 toxic elements (As, Cd, Cr(VI), Ni, Hg, Pb, Se, Cu, Zn) must be < 3 488 B, Mn, Fe


39

2.1.3 Iron ore roasting or sintering installations Air pollutant A B DK FIN F F1 D EL IRL

50 100 HHAV Particulates 50-150 HHAV No I. 10489 50490 50491

85 HHAV 50 DAV HHAV No I. No I.

150 A1 HHAV 50 A2 HHAV

(mg/m3)

(mg/m3) (mg/m3) (mg/m3)

400 750 HHAV NOx 350-400 HHAV mg/m3

No I. None 500 HHAV


400 A1 HHAV mg/m3 350 A2 HHAV mg/m3 300 A2 DAV kg/h

(mg/m3) (mg/m3) (mg/m3)

500 A2 HHAV 500 (mg/m3)

750 1 HHAV SOx

350 A1 kg/h

No I.

8000 (t/a) 5000 (t/a)492

300 493 HHAV

500 DAV HAVV No I. No I.

(mg/m3) (mg/m3) (mg/m3)

150 2 HHAV VOC None No I. None 50 494 HHAV

none No I. No I.

(mg/m3) None-0.4 0.1 PCDD/PCDF None A1 0.4 A2

No I. None

None 0,1 495 No I. No I.

(ng/m3) (ng/m3) (ngTE/m3) None-0.5 5 Fluoride None A1 5 A2

No I. None

10 HHAV 5 HHAV No I. No I.

(mg/m3) (mg/m3) (mg/m3) (mg/m3) 0.1 None 0.1496 HHAV Polycyclic

aromatic hydrocarbons

None No I.

None 4.5 0.1497 HAAV No I. No I.

(mg/m3) (mg/m3) (mg/m3) PCB None No I. None None None498 No I. No I. Chloride None No I. None None None No I. No I. Metals and their compounds (Cu, Pb, As, Ni, Cd, Zn, Cr, Hg, Sn)

None No I. None 499 HHAV HHAV Cd 0.1 Hg 0.2500 As 1501 Ni 1502 Cr 1503, 5504 Pb,Cu,Sn 5505 Zn None

No I. No I.

F1 Reference conditions: 273 k, 101.3 kPa 489 smelting plant 490 sintering, 15% O2 491 coke plant A1 Plant I A2 Plant II A1 Plant I A2 Plant II A2 Plant II 492 Target value 493 Reference XPX43310, FDX 20351 to 55 ET 57 494 for flows > 0.2kg/h except for methane 495 target value 496 valid only for benzo(a)pyrene 497 determined as benzo(a)pyrene and dibenzo(a,h)anthracene;

sum of Be and its compounds, asbestos, benzo(a)pyrene, dibenzo(a,h)anthracene and 2-naphthylamine (class I carcinogenic compounds) at a mass flow of 0.5 g/h or more; minimisation obligation

498 minimization obligation 499 Cd+Hg = 0.2 mg/m3, Pb + Zn + Cu + Co + Sb + Cr + Mn + Ni + V + Sn = 5 mg/m3


40

See footnotes (mg/m3)

500 sum of Cd, Hg, Th (class I particulate inorganic compounds) at a mass flow of 1g/h or more 501 sum of As, Co, Ni, Se, Te (class II particulate inorganic compounds) at a mass flow of 5 g/h or more; also valid for sum of

coinciding classes I and II 502 sum of As, Co, Ni, Se, Te (class II particulate inorganic compounds) at a mass flow of 5 g/h or more; also valid for sum of

coinciding classes I and II, Ni: limit value is depending on type of Ni compounds: * carcinogenic Ni-compounds as sum of carcinogenic As, Cr-VI, Co and Ni and their compounds, 3,3-dichlorobenzidine,

dimethyl sulfate, ethyleneimine (class II carcinogenic compounds) at a mass flow of 5 g/h or more; also valid for coinciding classes I and II; minimisation obligation

* Ni and its compounds as sum of As, Co, Ni, Se, Te (class II particulate inorganic compounds) 503 Cr: limit value is depending on type of Cr compounds: * carcinogenic Cr-VI-compounds as sum of carcinogenic As, Cr-VI, Co and Ni and their compounds, 3,3-


* Cr and its compounds as sum of Sb, Pb, Cr, Cu, Mn, Pt, Pd, Rh, V, Sn (class III particulate inorganic compounds) 504 sum of Sb, Pb, Cr, CN,F, Cu, Mn, Pt, Pd, Rh, V, Sn (class III particulate inorganic compounds) at a mass flow of 25 g/h or

more; also valid for sum of coinciding classes I to III Cr: limit value is depending on type of Cr compounds: * carcinogenic Cr-VI-compounds as sum of carcinogenic As, Cr-VI, Co and Ni and their compounds, 3,3-


* Cr and its compounds as sum of Sb, Pb, Cr, Cu, Mn, Pt, Pd, Rh, V, Sn (class III particulate inorganic compounds) 505 sum of Sb, Pb, Cr, CN,F, Cu, Mn, Pt, Pd, Rh, V, Sn (class III particulate inorganic compounds) at a mass flow of 25 g/h or more; also valid for sum of coinciding classes I to III


41

Air pollutant I L NLNL1 NL2 P E S UK

None Particulates 50506 150507 40-75 HAV No I. 150 0.1508 YAV

0.25 509 YAV

10

(mg/m3) (mg/m3) (mg/Nm3) (kg/t pellets)

(mg/m3)

NOx 400 450 HAV No I. 616510 None None

(mg/m3) (mg/m3) (mg/Nm3) None SOx 500511, 512 165-380

DAV No I. 2400

15513 YAV 20514 MAV

None

(mg/m3) (mg/m3) (mg/Nm3) (gSO2/t pellets)

5-600515 VOC 5517 20518 150519 300520 600521

100516 No I. None None None

(mg/m3) (mg/m3) PCDD/PCDF 0.01522 0.5 DAV No I. None None None (mg/m3) (ng I-

TEQ/m3)

None Fluoride 5523, 524 1525 DAV 5 HAV

No I. None 6526 YAV 150527

None

(mg/m3) (mg/m3) (gF/t pellets) (tF/year)528

Polycyclic aromatic hydrocarbons

None529 None No I. None None None

PCB

0.5530 None No I. None None None (mg/m3) Chloride

None None No I. None 6531 YAV None (g HCl/t

pellets)

NL1 Reference condition: 12% O2, standard NL2 sinter plant 506 mass flow 0.5 kg/h 507 mass flow 0.1 kg/h and < 0.5 kg/h 508 Grate kiln process 509 Straight grate process 510 when gas fuel is not used 511 SOx+NOx 512 mass flow 5 kg/h 513 Grate kiln process 514 Straight grate process 515 Valid for substances of different classes 516 as total CxHy 517 valid for substances of class I and mass flow 25 g/h 518 valid for substances of class II and mass flow 0.1 kg/h 519 valid for substances of class III and mass flow 2 kg/h 520 valid for substances of class IV and mass flow 3 kg/h 521 valid for substances of class V and mass flow 4 kg/h 522 mass flow 0.02 g/h 523 +others 524 mass flow 50 g/h 525 as HF 526 Grate kiln process 527 Straight grate process 528 150 tF/year correspond to 22 gF/t pellets at full production 529 LV for single substances 530 mass flow 0.5 kg/h 531 Grate kiln process


42

Air pollutant I L NLNL1 NL2 P E S UK Metals and their compounds (Cu, Pb, As, Ni, Cd, Zn, Cr, Hg, Sn)

5532, 533 0.2534, 535 1536, 537

None No I. None None None

(mg/m3)

532 Metals Cu, Pb, V, Rh, Pd, Pt, Mn, Sb, CN, Cr(III), Sn 533 mass flow 25 g/h 534 Cd+Hg+Tl 535 mass flow 1 g/h 536 As+Ni+Cr(VI)+Co 537 mass flow 5 g/h


43

Water pollutant

A B DK FIN F DD1 538 EL IRL

None-50 None Suspended solids 50 A1

None A2

No I. 4000 1300539

None None No I. No I.

(mg/l) (kg/d) COD None No I. None None None No I. No I. TOC None No I. None None None No I. No I.

None Hydrocarbons None No I. 60 30540 200541 90542


(kg/d) None Metals and

their compounds (Cu, Pb, Ni, Cd, Zn, Cr, Hg)

None No I.

25 8543


(kg/d)

D1 waste water of sintering installation is not discharged 538 According to GBR 8-24a, waste water from sintering installation must not be discharged into water bodies generally 539 target value 540 target value 541 emissions to bay 542 emissions to bay; target value 543 target value


44

Water pollutant


Suspended solids

80 20-40 10-20 DAV

No I. 30-40 E1 E2 None None

(mg/l) (mg/l) (mg/l) COD 160

None No I. 160-500 E1 E2

450 None None

(mg/l) (mg/l) TOC None None No I. 150 E2 None None (mg/l) Hydrocarbons 5 None No I. 20-40E1 None None (mg/l) (mg/l)

E1, 544 Cd 0.1-0.5 E2; Crtot 0.2-0.5E2; Cr(III) 2-4; Cr(VI) 0.2-0.5 E2 Cu 2-10 E2; Hg 0.005-0.1E2; Ni 2-10 E2; Pb 0.2-0.5E2; Zn 10, 3E2

Metals and their compounds (Cu, Pb, Ni, Cd, Zn, Cr, Hg)


Cu 0.1; Ni 0.1; Zn 0.15; Pb 0.1; Cd 0.01; Cr 0.1; Hg 0.005

No I.

Al: 1-2 As: 0.5-1 E2 Ba: 20 Hg: 0.05 E2 Se: 0.03-0.1 Sn: 10 Ti: 1 2-10545

None None


I1 valid for discharges in surface waters E1 valid only for discharges to rivers and streams E2 discharges to sea 544 toxic elements (As, Cd, Cr(VI), Ni, Hg, Pb, Se, Cu, Zn) must be < 3 545 B, Mn, Fe


45

2.2 Installations for the production of pig iron or steel (primary or secondary fusion) with a capacity exceeding 2.5 tonnes per hour Air pollutant AA1 A2

HHAV B DK FINFIN1 F F1 D EL IRL

None 10546 50547 12000548

Particulates 20

5 10552 50553 50554

20 549 HHAV 80 550

50 DAV HHAV 20551 DAV HHAV

100 / 150 No I.

(mg/m3) (mg/m3) (mg/m3) (mg/m3) (mg/m3) (mg/Nm3) PM10 None None None None None None No I. CO 100A3

175A4 None None None None None No I.

(mg/m3) NOx 250 A3

350 A4 None None 500 555

HHAV 500 HHAV None No I.

(mg/m3) (mg/m3) (mg/m3) None SOx 300 A3

300 A4 None

8000 5000 556

300 HHAV 500 HHAV None No I.

(mg/m3) (t/a) (mg/m3) (mg/m3) 560 metals and

their compounds (Pb, Zn, Hg)

5 557 1 558 0.2 559

None None 561 Hg 0.2562 HHAV Pb 5563 HHAV Zn none

10 or 20 (Pb)

No I.

(mg/m3)

564

(mg/m3) (mg/Nm3) H2S None None None None 5 HHAV None No I. (mg/m3) Polycyclic aromatic hydrocarbons

None None None None 0.1565 HHAV None No I.

(mg/m3) PCDD/PCDF 0.25 A5 None None None 0.1566 None No I. (ng/m3) (ng/m3)

A1 Reference conditions: 3% O2 A2 the given values are applied to single plant. To a second plant the ELVs will be applied after transition period of GBR (in 2002). (this comment does not appear in the report). FIN1 Reference conditions: 15% O2 F1 Reference conditions: 273 k, 101.3 kPa 546 Emissions from furnace; unit = mg/m3(n) 547 Emissions from sinter plant; unit = mg/m3(n) 548 Emissions from the whole integrate; unit = t/a 549 for electric ovens 550 for oxygen converters 551 valid only for electric arc furnaces and induction furnace 552 smelting plant 553 sintering, 15% O2 554 coke plant A3 For use of gaseous fuels A4 For use of liquid fuels 555 For electric ovens 556 target value 557 sum of Pb, Cr (excluded Cr (VI)), Cu, Mn, V, Sn and their compounds, expressed as elements 558 sum of As, Co, Ni, Cr(VI), Se, Te and their compounds, expressed as elements 559 sum of Cd, Hg, Tl and their compounds, expressed as elements 560 Pb+Cr+Mn+Sn=5mg/m3, Cd= 02.mg/m3 561 Pb 0.15 g/t; Zn 0.6 g/t 562 sum of Hg, Tl, Cd 563 sum of Sb, Pb, Cr, Cu, Mn, Pt, Pd, Rh, V, Sn 564 Sb+Cr+Co+Cu+Sn+Mn+Ni+V+Zn = 5 mg/m3, Cd= 0.05 mg/m3, Cd+Hg+Tl = 0.1 mg/m3 565 valid only for benzo(a)pyrene A5 Reference conditions: 6% O2. 566 target value, minimisation obligation


46

Air pollutant I L NLNL1 P E S UKUK1

None Particulates 20-40567 5-50NL2 DAV 5-15NL3

150568 50569 0.07571 YAV

0.15572 YAV 0.1573 MAV 0.3574 MAV 10575

50-100570

(mg/m3) (mg/m3) (mg/Nm3) (kg/t steel) (mg/m3) PM10 None None 150 None None (mg/Nm3)

600-750NL2 None NL3 (kg/charge)

CO 1000576

5-50 NL2 None NL3

500 None None

(mg/m3) (mg/m3) (ppm) NOx 500577, 578 5-15 NL2

40-70 NL3 DAV

616 20-75

None None

(mg/m3) (mg/m3) (g/GJ)

(mg/Nm3)

None SOx 15 NL2 DAV None NL3

20579 5580 MAV 60581 MAV

None

(mg/m3) (mg/Nm3) (kg/t H2SO4)

metals and their compounds (Pb, Zn, Hg)

5582, 583 0.2584, 585

None None None Pb: 1-2586

(mg/m3) (mg/m3) None H2S 5587, 588 None 10 0.8589 MAV

None

(mg/m3) (mg/Nm3) (g/m3 gas) Polycyclic aromatic hydrocarbons

None590 None None None None

PCDD/PCDF 0.01591 None None None None (mg/m3)

NL1 Reference conditions: standard UK1 Standard Temp and Pressure without correction for CO2 or water vapour 567 mass flow 0.5 kg/h NL2 oxygen steel furnace (BOF) NL3 blast furnace tapping/roof 568 furnace and old rolling mill 569 new rolling mill 570 Median range 571 Blast furnace etc.; Total 572 Basic oxygen furnace and skylights 573 Electric arc furnace; Total 574 Electric arc furnace + ingot casting; Total 575 Basic oxygen furnace; Desulphurisation 576 only for Hot blast cupola with recovery 577 NOx + SOx 578 mass flow 5 kg/h 579 SOx as SO2 580 Coke oven (SO3); H2S into H2SO4 581 Coke oven (SO2); H2S into H2SO4 582 Cu, Pb, V, Rh, Pd, Pt, Mn, Sb, CN; Cr(III), Sn 583 mass flow 25 g/h 584 Cd+Hg+Tl 585 mass flow 1 g/h 586 Median range 587 H2S + others 588 mass flow 50 g/h 589 Coke oven gas 590 LV for single substances 591 mass flow 0.02 g/h


47

Water pollutant

A B DK DK1 FIN MAV F D EL IRL

4000 MAV Suspended solids

50 6.7 YAV 596 4000 1300

30 592 , DAV 35 593 , DAV

50 D1 594 595 No I.

(mg/l) (kg/1000t)597 (kg/d) (mg/l) (mg/l) COD None 24 YAV None 90 598, DAV

125 599 , DAV

600

200 D1 601 100 D1 602 50 D1 603

No I.

(kg/1000t) (mg/l) TOC None None None None None No I.

60 MAV 200 MAV

Hydrocarbons None 0.8 YAV

60 30606 200607 90608

30 604, DAV 10 605, DAV

None No I.

(kg/1000t) (kg/d) 25MAV D2 611

0.5612 Pb 1.0; Cu 0.6; Ni 0.8; Zn 2-4613

metals and their compounds (Cu, Pb, Ni, Cd, Zn, Cr, Hg)

None Ni 0.006; Cr 0.004; Cu 0.07; Zn 0.03; Pb 0.03 Cd: 0.00035 All YAV 25

8614

609, 610, DAV

Fe 10615 2616 (g/tpig iron)

No I.

(kg/1000t) (kg/d) (mg/l) (mg/l)

DK1 The ELVs have been converted to units specific to ELV reporting exercise. Values are not exactly ELVs, not fixed in the permit. 592 for oxygen coverters 593 for electric ovens D1 requirements for waste water at the point of discharge 594 waste water from water treatment 595 The quality limits for discharges of liquid industrial effluent into natural recipients are those specified in the Prefectural Decisions for specific recipients. 596 target value 597 The unit kg/1000 t means: kg per produced thousand tons of crude steel. 598 for oxygen coverters 599 for electric ovens 600 15-60 g/t 601 discharge from blast furnaces with direct injection of coal 602 discharge from blast furnaces and slag granulations 603 discharge from crude steel production, only gas cooling and secondary metallurgy; add from flue gas treatments, if BOF gas can not be treated dry. 604 for oxygen coverters 605 for electric ovens 606 target value 607 emissions to bay 608 emissions to bay; target value 609 Pb: 0.5 mg/l, Zn: 2 mg/l, Cd : 0.2 mg/l, As : 0.5 mg/l 610 for electric ovens D2 requirements for waste water prior to blending; discharge from blast furnaces and slag granulations 611 Pb 0.15 g/t; Cu 0.09 g/t; Ni 0.12 g/t; Zn 0.6 g/t 612 Cr, Ni, Pb; discharge from blast furnaces and slag granulations 613 Zn 2: discharge from blast furnaces and slag granulations 614 target value 615 requirements for waste water at the point of discharge, discharge from blast furnaces and slag granulations 616 requirements for waste water at the point of discharge, discharge from blast furnaces and slag granulations


48

Water pollutant


500-700 E1 80-300 E2 E3

None Suspended solids

80 50 25 DAV

500-750 E1 20617 10618 10619

None

(mg/l) (mg/l) (mg/l) (mg/l) None COD 160 50

40 DAV 1500 E1

100-200 E2 E3 400620

None

(mg/l) (mg/l) (mg/l) (mg/l) None None TOC None None 150 700621

None

(mg/l) (mg/l) None Hydrocarbons 5 None 20-40E2 1622 5623

None

(mg/l) (mg/l) (mg oil/l) 624 Cr(III) 2-4 E2; Cr(VI) 0.2-0.5 E2, E3 Crtot 3-10 E1, 0.2-0.5 E2, E3; Cd 0.1-0.5 E2; Cu 3-5 E1 0.2-10 E2 Hg 0.05 E2 Ni 2-10 E2 1 E3 Pb 1-2 E1 0.2-0.5 E2 Zn 10E2, 3 E1

None metals and their compounds (Cu, Pb, Ni, Cd, Zn, Cr, Hg)


DAV Cu 0.03; Ni 0.1; Zn 0.5; Pb 0.1; Cd 0.005; Cr 0.05; Hg 0.0002

Al: 1-2 E2, 20-30 E1 As: 0.5-1 E2 Ba: 20 E2 Bo: 2-10 E2 Fe: 2-10 E2, 5-20 E1 Mn: 2-10 E2 Se: 0.03-0.1 E2 Sn: 10 E2 Ti: 1 E2

MAV Pb: 0.2625 Zn: 0.5

None

(mg/l) (mg/l) (mg/l) (mg/l)

I1 valid for discharges in surface waters E1 indirect releases to WWTP E2 valid only for discharges to rivers and streams E3 discharges to sea E1 indirect releases to WWTP 617 Coke oven plant 618 Blast furnace 619 Continuous casting and hot rolling 620 Coke oven plant 621 Coke oven plant 622 Coke oven plant 623 Continuous casting and hot rolling 624 toxic elements (As, Cd, Cr(VI), Ni, Hg, Pb, Se, Cu, Zn) must be < 3 625 Blast furnace


49


50

2.3 Installations for the processing of ferrous metals in hot-rolling mills with a capacity exceeding 20 tonnes of crude steel per hour Air pollutant AA1 B DK FIN FF1 D EL IRL

50 None Particulates 20

2-5626 30627 40628

30 HHAV 50 HHAV 100 / 150 No I.

(mg/m3) (mg/Nm3) (mg/MJ) (mg/m3) (mg/m3) (mg/Nm3) 750 NOx 750 629 500 630

None None 500 HHAV 500D1 DAV HHAV

None No I.

(mg/m3) (mg/m3) (mg/m3) -631 0.1632

SOx

300 634

None None 300 HHAV 500633 DAV HHAV

None No I.

(mg/m3) (mg/m3) (mg/m3) None None 0.2635 HHAV

5636 HHAV metals and their compounds (Pb, Zn, Cr, Hg)

5 638 1 639 0.2 640

None None

HHAV

Cr 1642 5643 Pb 5644

10 or 20 637 No I.

(mg/m3)

641

(mg/m3) (mg/Nm3) PCDD/PCDF 0.4 None None None 0.1645 None No I. (ng/m3) (ng/m3)

A1 Reference conditions: 3%, 6% O2. F1 Reference conditions: 273 k, 101.3 kPa 626 dry gas 627 for boiler 25 MW 628 for boiler 5 MW D1 Reference conditions: 5% O2 629 with preheating of combustion air 630 without preheating of combustion air 631 gaseous fuel 632 gas oil; unit = (%S) 633 when utilising of coke stove gas, sulphur oxide emission shall not exceed 800 mg/m3 634 for use of coke-oven gas 635 sum of Hg, Tl, Cd 636 sum of Sb, Pb, Cr, Cu, Mn, Pt, Pd, Rh, V, Sn 637 Pb 638 sum of Pb, Cr (excluded Cr (VI)), Cu, Mn, V, Sn and their compounds, expressed as elements 639 sum of As, Co, Ni, Cr(VI), Se, Te and their compounds, expressed as elements 640 sum of Cd, Hg, Tl and their compounds, expressed as elements 641 Sb+Cr+Co+Cu+Sn+Mn+Ni+V+Zn = 5 mg/m3 642 Cr: limit value is depending on type of Cr compounds: * carcinogenic Cr-VI-compounds as sum of carcinogenic As, Cr-VI, Co and Ni and their compounds, 3,3-


* Cr and its compounds as sum of Sb, Pb, Cr, Cu, Mn, Pt, Pd, Rh, V, Sn (class III particulate inorganic compounds) 643 sum of Sb, Pb, Cr, Cu, Mn, Pt, Pd, Rh, V, Sn, (class III particulate inorganic compounds) at a mass flow of 25 g/h or more; additionally valid for coinciding compounds of classes I to III, Cr: limit value is depending on type of Cr compounds: * carcinogenic Cr-VI-compounds as sum of carcinogenic As, Cr-VI, Co and Ni and their compounds, 3,3-


* Cr and its compounds as sum of Sb, Pb, Cr, Cu, Mn, Pt, Pd, Rh, V, Sn (class III particulate inorganic compounds) 644 sum of Sb, Pb, Cr, Cu, Mn, Pt, Pd, Rh, V, Sn, (class III particulate inorganic compounds) at a mass flow of 25 g/h or more;

additionally valid for coinciding compounds of classes I to III 645 targel value; minimisation obligation


51

Air pollutant I L NLNL1 P E S UK

None Particulates 50646 150647 5-10648 HHAV

None649

No I. 50 20 1650 MAV

10651

10

(mg/m3) (mg/m3) (mg/Nm3) (g/kg consumed oil) (mg/m3)

(mg/m3)

None NOx 500 I1, 652 450-525653 HHAV 240-320654 HHAV

No I. 600

100655 150656

400

(mg/m3) (mg/m3) (mg/Nm3) (mg/MJ) (mg/m3) SOx 1700 I1 657

800658 None No I. 1000659 None 100

(mg/m3) (mg/Nm3) (mg/m3) metals and their compounds (Pb, Zn, Cr, Hg)

5660, 661 0.2662, 663

None No I. None None Pb: 0.2-1.5664

(mg/m3) (g/m3) PCDD/PCDF 0.01665 None No I

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