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f Moharram or any festival season is prevalent in India and Pakistan when hundreds of thousands of people come out on the streets holding the Alam in their hands. Alams taken out during celebration are usually green in color and the ones taken out during mourning procession are mostly either black or red in color, black signifies grief while red reminds of revenge for martyrs of Karbala still remaining. Alams i
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Boiling Water Reactor Basics
Larry Nelson
November 2008
GE Global Research
2GE Global Research
Big Picture - BWR PlantsMajor ComponentsBWR EvolutionBWR Features vs. PWR FeaturesElectrochemical Potential (ECP) ConceptECP Monitoring & NobleChemTM
Overview
3GE Global Research
The Big Picture
4GE Global Research
Primary Containment
5GE Global Research
BWR Power Cycle
ReactorVessel
Core
RecircPump
RecircPump
FeedPumps
DrainPumps
Heaters
Heaters
CondensatePumps
Demineralizers
Generator
Condenser
LP LPHPTurbine
Moisture Separatorand Reheater
Steam
Feedwater
Separatorsand Dryers
Extraction Steam
Extraction Steam
NUCLEAR STEAM SUPPLYSYSTEM (NSSS)
BALANCE OFPLANT (BOP)
6GE Global Research
ABWR Power Cycle
SuppressionPool
MainSteam
Feedwater
MoistureSeparatorReheater
LowPressureTurbine
Generator
Stack
OffgasSystem
Steam JetAir Ejector
High PressureFeedwater Heater
Feed-waterPump
HighPressureTurbine
Condenser
CP
CBP
Low PressureFeedwater Heaters
Gland SteamCondenser
CondensatePurificationSystem
ReactorVessel
Condenser
NUCLEAR STEAM SUPPLYSYSTEM (NSSS)
BALANCE OFPLANT (BOP)
BWR MajorComponents
8GE Global Research
BWR Jet Pump
Provide core flow to control reactor power which yields higher power level without increasing the Rx sizeProvide part of the boundary required to maintain 2/3 core height following a recirculation line break event
9GE Global Research
Lower Plenum
CRD Guide TubesCRBsCRD housingsStub TubesIn-core HousingsGuide TubesFlux monitor dry tubes
10GE Global Research
BWR Core Shroud
Stainless Steel CylinderSurrounds the Core
– Separates upward flow through the core from downward flow in the downcomer annulus
– Provides a 2/3 core height floodable volume
Core SpraySpargers
EcentricAligner
EcentricAligner
Core Plate
CoreShroud
CorShro
TopGuide
Shroud and Sep
Stud(Typical)
hroudabilizeryp of 4)
11GE Global Research
Fuel Assembly & Control Blade
12GE Global Research
Steam Separator
Turning vanes impart rotation to the steam/water mixture causing the liquid to be thrown to the outside163 standpipes
WetSteam
RetW
S
Stan
ingr
Toecirc
T(
13GE Global Research
Steam Dryer
Provides Qsteam dryer = 99.9% to the Main TurbineWet steam is forced horizontally through dryer panels
– Forced to make a series of rapid changes in direction
– Moisture is thrown to the outside
Initial power uprateplants experiences FIV – minimized by design improvements
BWR Evolution
15GE Global Research
BWR Reactor Evolution
Oyster Creek
KRBDresden 1
ABWRDresden 2
ESBWR
16GE Global Research
BWR Development
VBWR (Vallecitos Boiling Water Reactor)
– 1st General Electric BWR power plant
– Built in 1957 (near San Jose, California)
– 1st commercial BWR; 5 MWe supplied to Pacific Gas & Electric grid (through 1963)
– 1000 psig (66.7 atm) operating pressure
17GE Global Research
BWR Development
BWR1Introduced in 1955
1st commercial plant in 1960 (Dresden 1)8 plants
Characteristics:– External or Internal steam
separation– Low power density core
BWR2Introduced in 1963
3 plantsCharacteristics:– Internal steam separation– Low power density core– 5 Recirculation loops– Flow control load following
18GE Global Research
BWR3Introduced in 1965
First Jet Pump application
9 plantsCharacteristics:– Low power density core– Internal Jet Pumps– 2 Recirculation loops
BWR Development
BWR4Introduced in 1966
Increased power density
25 Plants Characteristics:– High power density core– Mark I or II containment
19GE Global Research
BWR5Introduced in 1969Improved safeguards (ECCS)Recirculation flow control valves8 plants
Characteristics:– Valve flow control load
following– ECCS injects into core shroud
BWR Development
BWR6Introduced in 1972Added fuel bundles; increased output; Improved fuel safety marginsImproved Recirc system performance8 plants
Characteristics:– Valve flow control– 8 x 8 fuel bundle
20GE Global Research
ABWRIntroduced in 1991Blend of best features: operating BWRs, available new technologies, & modular construction techniques4 plantsCharacteristics:
– Safety improvements (reduced core damage frequency)
– Design life 60 years– No external Recirc Loops;
Reactor Internal Pumps
BWR Development
ESBWRCurrently in licensing and designCharacteristics:
– Passive Safety– Natural Circulation; No Recirc
Loops or Pumps– Safety improvements (reduced
core damage frequency)– Design life 60 years– Larger Main Generator (~1600
MWe)
21GE Global Research
Parameter BWR/4(Browns Ferry 3)
BWR/6(Grand Gulf 1)
ABWR ESBWR
Power (MWt / MWe) 3293/1098 3900/1360 3926/1350 4500/1590
Vessel height / diameter (m) 21.9/6.4 21.8/6.4 21.1/7.1 27.6/7.1
Fuel Bundles (number) 764 800 872 1132
Active Fuel height (m) 3.7 3.7 3.7 3.0
Power density (kW/l) 50 54.2 51 54
Recirculation pumps 2 (large) 2 (large) 10 zero
Number of CRDs / type 185/LP 193/LP 205/FM 269/FM
Safety system pumps 9 9 18 zero
Safety Diesel Generator 2 3 3 zero
Core damage freq./yr 1E-5 1E-6 1E-7 1E-8
Safety Bldg Vol (m3/MWe) 120 170 180 135
Operating Parameters for Selected BWRs
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ESBWR Reactor Pressure Vessel
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ESBWR Passive Safety
24GE Global Research
• Simple design• Simple analyses
• Extensive testing• Large safety margins
Gravity driven flow keeps core covered
ESBWR Gravity Driven Cooling System
Before
After
BWR vs. PWR
26GE Global Research
BWR and PWR… the main differencesPressurized Water Reactor
Condenser Condenser
Steam Generator
TurbineGenerator
ReactorPressureVessel
T/G
Pre
ssur
e/Te
mpe
ratu
re
2 loops heat balance/heat transfer
1 loop heat balance/heat transfer
Pressurizer
Chemical &Volume Control
ReactorPressureVessel
Boiling Water Reactor
T/G
TurbineGenerator
27GE Global Research
Principle of Steam Generation
BWRRPV Pressure ~7 MPa (1020 psig)RPV Temperature 288 oC (550 ºF)Steam Generated in RPV (with Separator & Dryer)Bulk Boiling Allowed in RPV
PWRRPV Pressure ~15 MPa (~2240 psig)RPV Temperature 326 oC (~618 ºF)Steam Generated in Steam Generator (via Second Loop)No Bulk Boiling in RPV
BWR has Lower RPV Pressure and Simplified Steam CycleBWR has Lower RPV Pressure and Simplified Steam Cycle
28GE Global Research
Major NSSS Components
BWRRPV (with Dryer & Separator)No Steam GeneratorNo PressurizerNatural Circulation (ESBWR)RPV mounted pumps (ABWR)Bottom Entry Control Rod Drives
PWRRPV2 - 4 Steam Generators1 PressurizerReactor Coolant Pumps outside of RPVTop Entry Control Rod Clusters
Electrochemical Potential(ECP) Concept
30GE Global Research
Stress Corrosion Cracking History• 1969 1st detected in sensitized SS• 1970s Stainless steel welded
piping• 1980s BWR internals• 1990s Low stress BWR internals
Stress Corrosion Cracking History in BWRs
# of BWRs
Operating BWRsN. America Europe Asia Total
GE 34 4 11 49Non-GE 0 16 21 3880,000 MWe installed
Repair costs>$1B / BWR
31GE Global Research
“Nuclear Chain Reactions on One Slide”
X,Yhigh energy
neutronlow energy
neutronRadioactiveby-products
e.g. Kr, Cs, I, Ba, Th, Np
235U
n
X
Y
U238
Pu239
HEAT
n
n
n
U235
E=mc2HEAT
Etc.
“Moderator”
Wateror
Graphite
235U
n
X
Y
U238
Pu239
HEAT
n
n
n
U235
E=mc2HEAT
Etc.
“Moderator”
Wateror
Graphite
H20 H+ + OH-n
32GE Global Research
H2O
n
γ
H* H2
OH* H2O2
H2O+O2
OH-
HO2-
HO2*
Water Radiolysis Generates Species Harmful to Materials
Oxidant (H2O2 and O2) Generation By Water Radiolysis
eN2
NO2-
NO3-
(n,p)
Commonly Observed species
33GE Global Research
Weld
Cr depletion occurs during welding of
stainless steels with high carbon levels
Stress Corrosion Cracking
Outside
0
5
10
15
20
25
30
-25 -20 -15 -10 -5 0 5 10 15 20 25
Relative Distance From Weld Fusion Line (mm)
Plas
tic S
trai
n (%
)
GE1 Scan B 600AGE1 Scan D 600AGE2 Scan C 600AGE2 Scan D 600AGE3 Scan D 600AGE3 Scan C 600AGE8 Scan C 400AGE8 Scan D 400AGE9 Scan D 300AGE9 Scan C 300AGE4 Scan C 600AGE4 Scan D 600A
1.E-09
1.E-08
1.E-07
1.E-06
1.E-05
-0.6 -0.5 -0.4 -0.3 -0.2 -0.1 0.0 0.1 0.2 0.3 0.4
Corrosion Potential, Vshe
Cra
ck G
row
th R
ate,
mm
/s
Sensitized 304 Stainless Steel30 MPa√m, 288C Water0.06-0.4 μS/cm, 0-25 ppb SO4SKI Round Robin Datafilled triangle = constant loadopen squares = "gentle" cyclic
42.5
28.3
14.2μin/h
GE PLEDGE Predictions30 MPa√m 0.5Sens SS 0.25
0.1
0.06 μS/cm
← 2
00 p
pb O
2←
500
ppb
O2
←20
00 p
pb O
2
2000 ppb O2
Ann. 304SS 200 ppb O2
316L (A14128, square ) 304L (Grand Gulf, circle ) non-sensitized SS50%RA 140 C (black )10%RA 140C (grey )
CW A600
CW A600
GE PLEDGE Predictions for UnsensitizedStainless Steel (upper curve for 20% CW)
Plastic strain occurs during welding and leads to cracking in stainless steels with low carbon
(L-grade SS)
Environment Stress
Microstructure
Environment Stress
Microstructure
34GE Global Research
Stress Corrosion Cracking Prediction & Application
Complex phenomenon must beunderstood mechanistically as“crack tip system” processes
Lab understanding & data must be verifiedby plant data before use in BWR prediction
Insights yieldnovel technologylike NobleChem
LAB
PLANTPREDICTION
35GE Global Research
Crack Growth Response
NobleChem™ Basics
• With excess H2, O2 is consumed & its level at the surface is zero
• H2 + O2 reaction is catalyzed with NobleChem particles
• Hydrogen added is more effective – lower radiation fields
- 200
0
200
- 400
- 600
EC
P, m
V (S
HE
)
Hydrogen Injection Rate (ppm)2.01.0 1.50.5
NWC - Piping
NobleChemHWC
NWC – In-core
//
- 200
0
200
- 400
- 600
EC
P, m
V (S
HE
)
Hydrogen Injection Rate (ppm)2.01.0 1.50.5
NWC - Piping
NobleChemHWC
NWC – In-core
//
- 200
0
200
- 400
- 600
EC
P, m
V (S
HE
)
Hydrogen Injection Rate (ppm)2.01.0 1.50.5
NWC - Piping
NobleChemHWC
NWC – In-core
//
- 200
0
200
- 400
- 600
EC
P, m
V (S
HE
)
Hydrogen Injection Rate (ppm)2.01.0 1.50.5
NWC - Piping
NobleChemHWC
NWC – In-core
//
• High crack growth rates at high corrosion potential (ECP)
• ECP is a dominant variable effecting SCC response
• Hydrogen injection results in an increase in main steam line radiation fields
Electro Chemical Potential (ECP) Response
Feedwater Hydrogen Concentration (PPM)
Normalized Main Steam Line Activity
LowHydrogen
ModerateHydrogen
HighHydrogen
Feedwater Hydrogen Concentration (PPM)
Normalized Main Steam Line Activity
LowHydrogen
ModerateHydrogen
HighHydrogen
Radiation Field Response
Mai
n S
team
Rad
iatio
n Fi
eld
Stress Corrosion Cracking Mitigation
ECP Monitoring &NobleChemTM
37GE Global Research
Modified LPRM Assemblyfor Bottom-of-Core ECP Monitoring(3 ECP Sensors)
Recirculation\Decon FlangeAssembly (4 ECP Sensors)
Full FunctionData AcquisitionSystem
Drain Line Flange Assembly(4 ECP Sensors)
Modified LPRM Assemblyfor Lower Plenum ECP Monitoring(2 or 3 ECP Sensors)
CorePlate
EDM one newhole in GuideTube
Inlet to LPRM(ECP sensors
inside and above)
Drywell
Personal ComputerAir Conditioner
Digital Multimeter
MultiplexerDeskjet Printer
AC Line Conditioner
SimplifiedData AcquisitionSystem
Multimeter/Multiplexer
PersonalComputer
BWR ECP Monitoring Locations
38GE Global Research
Core Plate
Local Power Range Monitor Assembly
1/2” diameter Inlet Cooling Hole in In Core Monitor Housing
Lower Cooling Holes in LPRM Cover Tube, ECP Sensors Inside and Above Holes
Lower Plenum ECP MonitoringFe/Fe3O4
Platinum
Inlet Cooling Holes in LPRM Cover Tube
2.75 in.(70 mm)
Noble Metal Treated SS Electrode
High Temperature Prefilm (in laboratory)
39GE Global Research
Bottom Plenum ECP Response
FEEDWATER HYDROGEN (ppm)
-500
-400
-300
-200
-100
0
100
200
0 0.5 1 1.5 2 2.5
ECP
(mV
SHE)
Middle
Bottom
IGSCC Mitigation Potential-230 mV(SHE)
Lower Plenum ECP
Core Plate ECP
HWC is EffectiveIn Mitigating IGSCCBut…Lower PlenumRequires More H2
40GE Global Research
1.0 2.0(ppm)
Basis for NobleChemTM Technology
41GE Global Research
BWR/4 Low ECP After NobleChemTM and Low Hydrogen
-600
-400
-200
0
200
0 0.4 0.8 1.2 1.6 2Feedwater H2 (ppm)
ECP
mV(
SHE)
Before NobleChemTM - 1994
After NobleChemTM - 1999 -230 mV(SHE)
IGSCC Mitigation
HWC vs. NobleChemTM Technology
42GE Global Research
-600
-500
-400
-300
-200
-100
0
100
200
300
0 0.5 1 1.5 2 2.5
Feedwater Hydrogen, ppm
ECP
mV(
SHE)
Upper Core - UC
Lower Core - LC
Lower Plenum - LP
RRSNobleChem Plant Data for UC, LC, LP, RRS
Non-NobleChem Plant Data
-230 mV(SHE)
Provides Low ECPs At All Internal Locations
ECP Reduction With NobleChemTM
43GE Global Research
Noble Metal Distribution After On-Line Application
100 nm
Pt PARTICLE SIZE DISTRIBUTION(based on number)
0%
5%
10%
15%
20%
25%
30%
0.5 1.5 2.5 3.5 4.5 5.5 6.5 7.5 8.5 9.5 10.5 11.5 12.5 13.5 14.5 15.5 16.5 17.5 18.5 19.5
Particle Diameter (nm)
Rel
ativ
e N
umbe
r Fre
quen
cy
0%
10%
20%
30%
40%
50%
60%
70%
80%
90%
100%
Cum
ulat
ive
Num
ber
STATISTICSM ean : 6.1 nm
Std . De v. : 2.3 nmMinim um : 2.1 nm
Maxim um : 21.8 nmObject Count : 17331
(b ased on num b er)
Nano-particle Pt Generation By On-Line NobleChemTM
44GE Global Research
Summary
Reactor operation at low ECP is essential for minimizing component degradation in all BWR designs including the ESBWRESBWR is GEH’s latest evolution in BWR design
– 4500 MWt/~1575MWe– Natural circulation– Passive safety features– Significant simplification
ESBWR is under licensing review by USNRCESBWR chosen by NuStart, Dominion and Exelon as reference design