Era Environmental Risk Analysis

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    Environmental risk assessment

    of industrial accidentsA development project with the aim to:

    propose good practices

    establish simple criteria

    research and develop easy to apply models

    present the state of art of prevention and protection of the

    environment

    for conducting environmental risk analysis at industrial sitesin France.

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    The complexity of the system

    Frequency

    analysis

    Consequence

    analysis

    Hazardidentification

    Riskevaluation

    Acceptancecriteria

    BiologyEcotoxicology

    PhysicsChemistry

    Accidentology

    Statistics

    Economics Sociology

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    The 4 parts of the method

    Part 1 evaluate the harm potential of chemical substances

    Part 2

    evaluate the transportpotential of a pollution towards theenvironmental targets

    Part 3 estimate the vulnerabilityof the environmental targets

    Part 4

    define the principal measures of prevention and protectionfrom accidental environmental pollutions

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    Accidentology:ARIA databasehttp://www.aria.developpement-durable.gouv.fr/

    The study of previous accidental pollutions of soils,

    ground and surface waters can give us useful

    feedback on:

    causes and circumstances of accidents

    routes of contamination

    type of industrial installations and activities

    substances implicated

    consequences and impact

    permitting us to evaluate in a first quick approach

    the danger (frequency&impact) of an industrial

    site or activity.

    No ARIA 15.598

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    The most common routes of

    contamination Discharge offire-fighting waterinto the aquatic environment

    Discharge through the sewage system or cooling water system

    Discharge through the rain drainage system Direct release (e.g. from a ruptured pipeline, or afailed valve)

    Overfilling of a storage vessel

    Release to the atmosphere and then contamination through

    deposition (particles or rain)

    Discharge through theground).

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    Soil

    Unsaturated zone

    Saturated zone

    run off

    infiltration

    Atmosphere

    volatilization

    Environment:humansplants

    animals

    rivers

    torivers, lakes, sea

    human activities:

    fishing, farming

    source

    transport

    target

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    Simplified schema of

    accidental pollution

    TARGET

    TARGET

    SOURCE

    TRANSPORT

    TRANSPORT

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    The 3 modules of the method

    source

    targettransport

    TRANSPORT POTENTIAL

    (physicochemical properties)

    HARM POTENTIAL

    (toxicity, quantity)DANGER

    PHYSICOCHEMICALPROPERTIES(type of soil, vegetation etc.)

    TOPOGRAPHY(distance to water bodies,land inclination etc.)

    VULNERABILITY(endangered species, kids etc.)

    IMPACT MAGNITUDE(area affected, number of species)

    KINETICS DAMAGE

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    Problems:

    interactive relations among the three modules

    complexity of physical phenomena

    diversity of cases

    amount of data needed

    high cost and difficulty of performing an extensive research of the

    surroundings

    domino effects

    objective evaluation of the impact

    How to apply the same method to every case???

    2 phase approach:

    preliminary risk analysisdetailed risk analysis

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    Hazardidentification(SEVESO2 inst.)

    RISK?

    PreliminaryRisk Analysis

    NO

    RISK

    TRIVIAL

    ALARP RISKUNACCEPTABLE

    NOT

    SURE

    DetailedRisk

    Analysis

    YESCosteffectivebarriers?

    YES

    NO

    RISK?

    Possible

    barriers?

    YES

    NO

    NO

    YES

    Basic dataover the 3modules

    Elaboratedata

    over the 3modules

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    STEP 1: SourcePreliminaryanalysis

    Detailedanalysis

    Danger

    exists?

    Substanceidentification

    Basicdata

    available

    ?

    QSARpossible

    ?

    NO NO

    Dangerevaluation

    YES YES

    STOP

    perform

    STEP 2: transport

    YES

    NOTSURE

    NO

    QuantityToxicityMobility

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    STEP 2: TransportPreliminaryanalysis

    Detailedanalysis

    TransportPossible

    ?

    Step1:Substance data

    Datamissing

    ?

    YES

    Transportpotential

    evaluation

    STOP

    perform

    STEP 3: target

    YES

    NOTSURE

    NO

    Site properties

    NOSoil typeDistance to waterbodiesNatural &

    artificial barriers

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    STEP 3: TargetPreliminaryanalysis

    Detailedanalysis

    Impactimportant

    ?

    Step 3:Transport data

    Datamissing

    ?

    YES

    Identification of areaand population

    touched

    STOP

    YES

    NOTSURE

    NO

    Vulnerability ofthe environment

    NO

    Protectionprevention

    possible?

    NOApply

    measures,

    barriers

    YES

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    SOURCE

    Preliminar

    y

    analysis

    Detailed

    analysis

    exact physical and chemical data (Tb, kow, koc, kh, viscosity etc.) reaction chains and products with regard to other substancespresent in the site (factory, soil)use of available software to model the substance behavior in theenvironment

    quantity toxicity basic physical parameters: volatility, viscosity, solubility basic chemical parameters: reactivity(basic products) ,biodegradability, radioactivity, half-life past accidents involving the substance existent methods of post-accidental treatment

    Evaluation of the harm potential with the use of

    classes of danger ( Seveso legislation)Evaluationof mobility

    +persistance

    Protection orprevention possibility

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    Transport

    Preliminar

    y

    analysis

    Detailed

    analysis

    exact data on soil properties (permeability, porosity, vegetation,mineral and chemical composition, water retention) data on dispersion and degradation constants and considerationof other physical and also chemical phenomena during the transport modeling with the use of appropriate software climatic data over the area

    site limits possible pathways presence of natural or artificial barriers distance to water bodies soil types and basic properties consider only advection and dispersion of the substance andestimation of the transport distance and time in order of magnitude

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    Target

    Preliminar

    y

    analysis

    Detailed

    analysis

    soil, air, water and groundwater intake quality post-accidental ways of exposure to the pollution life conditions economical estimation of damage and repair costs societal health effects time of reconstitution of the area use of software to model the impact

    quick estimation of the human population near the area quick estimation of fauna and flora around the area presence of extremely vulnerable populations (Natura 2000) identification of principal human activities that may be affectedfrom a soil or river pollution (land use, potable water quality) use of the impact evaluation table (E.U , BARPI) quick estimation of economical losses

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    Frequency evaluation

    Past accidents inthe specific site

    Past accidents insimilar sites

    Frequencyestimation withthe use of tables

    Possible but

    extremely

    improbableVery

    improbable Improbable Probable

    F6qualitative :

    semi-quantitative:

    FREQUENCY CLASS

    (from F-2 to F6) 10-5 10-4 10-3 10-2 10-1 110-6

    10

    Very

    Probable

    F5 F1 F0F2F3F4 F-2F-110-2 10110-110-310-410-5

    CommonEVENT

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    Measures of prevention and

    protection

    Measures designed to prevent risks of leakage (pipeline, vessel rupture etc.)

    Measures designed to prevent risks of soil infiltration et run off of pollutants Measures of preventing the transport of the pollutant towards the target

    Protection barriers to limit pollution inside the installation's limits

    Treatments for inland waters remediation and pollution control

    Methods of soil remediation and pollution control

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    Summary

    STEP 1source

    STEP 2

    transportSTEP 3target

    PHASE 1:preliminary analysis

    S

    TOP

    PHASE 2: detailed analysis

    STO

    P

    STEP 1source

    STEP 2

    transportSTEP 3target

    COST-EF

    FECTIVE

    MEAS

    URES

    STOP

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    Tasks still to be done

    still simple tools that can be used to estimate the order of magnitude ofthe transport have to be improved ( equations, indicateurs etc)

    need for consequence and danger tables that can be used from everycountry and every industry