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Actlabs Group of Companies
Quality Analysis . . .Innovative Technologies
Revised Sept. 4/11
www.actlabs.com
LAB 266
E87979
2011 EuroSchedule of Services
and Fees
PAGE 2
Table of Contents
Useful Information
Common Tyler Sieve Sizes
Mesh Aperature (µm)
10 1,680
20 841
35 420
60 250
80 177
100 149
150 105
170 88
200 74
250 63
270 53
325 44
400 37
Chemical Conversions
Element Compound Factor
Al Al2O3 1.889
Ba BaSO4 1.699
Ca CaO 1.399
CaO CaCO3 1.785
CaO CaSO4 3.397
Ca CaF2 1.948
CaO CaF2 1.392
Cr Cr2O3 1.462
Fe FeO 1.286
FeO Fe2O3 1.111
Fe Fe2O3 1.43
K K2O 1.205
Mg MgO 1.658
Mn MnO 1.291
Mo MoS2 1.668
Na Na2O 1.348
P P2O5 2.291
S SO4 2.996
Sr SrSO4 2.096
Th ThO2 1.138
Ti TiO2 1.668
U U3O8 1.179
W WO3 1.261
V V2O5 1.785
Zr ZrO2 1.35
Gold Conversion Factors
1 ppb 0.001 g/tonne
1 ppm 1 g/tonne
1 oz/ton 34.286 grams/tonne
1 gram/tonne 0.0292 oz/ton
1 gram/m3 0.0421oz/yd3
Ore Content
1% Cu 2.89% CuFeS2 (chalcopyrite)
1% Mo 1.67% MoS2 (molybdenite)
1% Pb 1.15% PbS (galena)
1% U 1.18% U3O8 (pitchblende)
1% W 1.26% WO3 (scheelite)
1% Zn 1.49% ZnS (sphalerite)
1% Fe 2.15% FeS2 (pyrite)
1% Fe 1.57% FeS (pyrrhotite)
1% Fe 1.38% Fe3O4 (magnetite)
0.1% U3O8 2 lbs/ton U3O8
Grain Size (Diameter)
Gravel 2 to 4 mm
Sand 63 µm - 2 mm
Silt 4-63 µm
Clay <4 µm
Common Drill Core Sizes
Size Core Diameter Core Volume Per
(mm) Meter Length
(m3x10-3)
AQ 27.0 0.57
TT 35.0 0.96
BQ 36.4 1.04
NQ 47.6 1.78
HQ 63.5 3.17
BQ3 33.5 0.88
NQ3 45.1 1.6
HQ3 61.1 2.93
Core weight per metre (kg) = core volume per metre xspecific
gravity
PAGE 3
Page 2 Locations Map
Page 3 Table of Contents and
Useful Information
Page 4, 5 Corporate History - ACTLABS
Group of Companies
Page 6 General Information
Page 7 Sample Preparation and
Sample Storage & Disposal
Page 8 Precious Metal Geochemistry
Page 9 Assay Products
Page 10 - 12 Exploration Techniques for
Specific Deposit Types
Page 13 Geometallurgy (MLA)
Page 14, 15 Trace Element Geochemistry
Page 16, 17 Lithogeochemistry
Page 18 Biogeochemistry
Page 19 Heavy Mineral Concentrates
Page 20, 21 Hydrogeochemistry
Page 22, 23 Soil Gas Hydrocarbons (SGH)
Page 24 Enzyme LeachSM
Page 25 Bioleach and SRMs
Page 26 Sequential Leaches
Page 27 XRD and
Laser Ablation HR-ICP/MS
Page 28 Isotopic Analysis and
Geochronology
Page 29 Enviromining and
Miscellaneous Methods
Page 30 Periodic Table
Page 31, 32 Request for Analysis
1987-1993
Activation Laboratories Ltd. (ACTLABS) was established in 1987 by Dr. Eric Hoffman, an economic geochemist. The laboratory began by providing
Instrumental Neutron Activation Analysis (INAA) to the academic, government and mineral exploration sectors. The INAA technique which involves
bombarding samples with neutrons from a nuclear reactor and measuring the induced gamma-ray "fingerprint" from the sample, non-destructively, was
enthusiastically embraced by all as a highly accurate and cost-effective, analytical technique for analysis of geological samples. Dr. Hoffman had
effected the transfer of INAA technology from university to industry in 1978, where it became widely accepted. Although excellent, the INAA technique
could not analyze all elements in the periodic table to the detection limits required by our clientele. Unfortunately, no one analytical technique can
achieve this distinction. As a result, ACTLABS added Atomic Absorption Spectroscopy (AA), Inductively Coupled Plasma-Optical Emission
Spectroscopy (ICP/OES), X-ray Fluorescence Spectroscopy (XRF), Fire Assay, Infrared technology for carbon and sulphur, Ion Chromatography,
Capillary Electrophoresis (CE), Autoanalyzers, Inductively Coupled Plasma Emission Mass Spectrometry (ICP/MS), High Resolution ICP/MS, Gas
Chromatography-Mass Spectrometry (GC/MS), High Performance Liquid Chromatography-Mass Spectrometry (HPLC, LC/MS/MS) and Coulometry.
Some of the analytical innovations of using modern instrumentation to solve geochemical problems included the development of methods for analysis
of rocks, soils, stream sediments, humus and vegetation samples for "Au+34" elements, the analysis of fire assay doré beads for Au, the analysis of
the whole platinum group of elements by NiS fire assay combined with INAA and heavy mineral concentrate analysis by INAA. Our
hydrogeochemistry and lithogeochemistry packages marry the needs of research and exploration geologists and environmental chemists with modern
ICP/MS technology. These packages are still unrivaled in elements offered, detection limits achieved, highest quality of data, and cost, anywhere in
the world. High-level Rare Earth Element Analysis using our robotic sample preparation is unrivalled anywhere in the world for accuracy and reliability.
ACTLABS introduced Enzyme LeachSM in 1993. This selective extraction on surface soil had the ability to "see through" cover and find blind ore
deposits buried below several hundred metres of overburden and cover rock. This was clearly an order of magnitude better than conventional
geochemistry. ACTLABS acquired its first ICP/MS in 1993 and pioneered large-scale ICP/MS analyses. We have maintained our commitment to
advanced technology with the newest quadruple ICP/MS technology and we are the only commercial laboratory serving the mineral industry with high-
resolution magnetic sector ICP/MS technology. This technology allows us to have better detection limits than a quadruple ICP/MS by 1 - 2 orders of
magnitude and resolves most interferences.
1996-2006
In 1996, ACTLABS took over the WMC Exploration division laboratory in Kalgoorlie, Australia and built a new lab in Perth. Also in 1996, ACTLABS
Organics Division began research, led by Dale Sutherland, into the use of soil gas hydrocarbons for mineral exploration. A CAMIRO sponsored research
program ensued to test the technology. In 2001, the new SGH technology became widely available to the mineral exploration industry. As a result of
the first CAMIRO project proving to be so successful, a second CAMIRO project was funded and completed to better understand why SGH was so
successful. The results of this project are now available as the confidentiality period has ended. The SGH technique promises to become one of the
most important technologies for finding blind, deeply buried mineral deposits.
A new state-of-the-art LIMS (Laboratory Information Management System) was completed in 2005 which now provides a tool to improve service to our
clients. The same LIMS system now links all of our labs worldwide. Our customers can now track their orders through WEBLIMS.
In 2003-2006, the lab in Ancaster was expanded to 50,000 sq. ft. Sample preparation facilities were greatly increased and were further expanded in
2007. We have added more fire assay capability and have added several new Thermo 6500 state-of-the-art ICPs. New automated titration
equipment will allow more rapid and accurate titrations. The INAA capability was increased 30%. Automated fusion capacity for XRF was doubled in
2006 and increased again in 2009, 2010 and 2011.
Also in 2006, ACTLABS established a full laboratory, including fire assay and ICP using state-of-the-art ICP technology, in Nuuk, Greenland. A state-
of-the-art laboratory was also commissioned in Ulaan Baatar, Mongolia and was headed by Douglas Read. This lab provides fire assay, leachwell
cyanide technology, state-of-the-art fast sequential atomic absorption analysis and x-ray fluorescence methods on site as well as the full range of
ACTLABS methodologies.
2007-Present
In 2007, two more Varian 735 ICPs and three more Perkin Elmer Sciex ELAN 9000s were added in Ancaster. A new Panalytical Expert Pro XRD
system was installed and a new Panalytical Axios Advanced XRF was commissioned. A third Panalytical Axios Advanced XRF was added in 2009.
Sample preparation facilities in Happy Valley-Goose Bay, Labrador and Fredericton, New Brunswick for rock and soils became fully operational in
June 2007. In August 2007 the new high-volume sample preparation-fire assay laboratory became fully operational in Tumeremo, Venezuela. This
facility is headed by Kevin Gomez.
In 2008, a new carbon sulphur analyzer, additional fume hoods and AA capacity was added to the laboratory in Mongolia. A new coal laboratory was
also commissioned.
Corporate History - ACTLABS Group of Companies
PAGE 4
Corporate History - ACTLABS Group of Companies
In 2008, our new full-service lab became fully operational in Thunder Bay, Ontario. This facility provides large volume sample preparation, fire assay
with both gravimetric and atomic absorption, as well as multielement ICP analysis and assays. Additional sample preparation and ICP capabilities were
also added in 2008. 2010 and 2011 saw a major expansion with the acquisition of an additional 36,000 sq. ft. of space which allowed us to centralize
the Thunder Bay lab facilities into the new modern lab with greatly expanded wet chemistry and instrumental capabilities. Two new PE-Sciex Elan 9000
ICP/MS were added as well as two new Panalytical Axios Advanced XRFs, two more Agilent 735 ICPs (now 4) and a third Varian 240 AAS.
In late 2008, our new Guyana sample preparation facility became operational.
2008 also saw the completion of our Ancaster expansion with 36,000 sq. ft. of laboratory space added. The Materials Testing, Forensic and
Pharmaceutical labs were moved to this facility allowing our ICP and Preparation departments to expand.
2009 also saw ACTLABS opening a new sample preparation facility in Geraldton, Ontario. This was expanded in 2010 to include fire assay, atomic
absorption and gravimetric.
A new high-technology lab was also commissioned in Coquimbo, Chile in 2009 with the sample preparation, fire assay, atomic absorption and ICP and
ICP/MS laboratory. Other additional technologies are currently in the planning stage for this lab. Macarena Mery provides the technical leadership at
this facility. A new sample preparation lab was added in 2010 in Antofagasta.
In 2009 a new Field Emission Gun Scanning Electron microscope with 2 Energy Dispersive Xray Analyzers and Mineral Liberation Analyzer software
was added (FEG SEM-MLA). This instrument is unique in North America (FEI-FEG QUANTA 650 MLA). This new facility marks the beginning of
ACTLABS entry into the Geometallurgy market and is headed by Chris Hamilton.
Internationally in 2010, ACTLABS opened new full-service labs in Zacatecas, Mexico (fire assay, atomic absorption, gravimetric and ICP) as well a
sample preparation in Chihuahua, Mexico. A preparation facility was added in Choibalsan, Mongolia. A new full-service lab became operational in
Windhoek, Namibia and includes ICP and XRF facilities (Dr. Claus Wibbelmann - Manager). A new, very high-volume fire assay/atomic absorption,
gravimetric and cyanide lab is due to open in Ougadougu, Burkina Faso in early 2011 in a new building under construction.
In 2010 in Canada, Techni-labs in Quebec was purchased and modernized with ICP being added in Ste. Germaine and high-volume fire assay/atomic
absorption and gravimetric added in Val-d’Or along with enlarged sample preparation facilities. New high-volume fire assay/atomic absorption-
gravimetric labs were built in Timmins (Sarah Albert - Manager) and Red Lake, Ontario (Dr. Evgueni Terentiev - Manager). Our Thunder Bay lab was
considerably expanded to 80,000 sq. ft. and now includes a new, much enlarged wet chemistry, ICP/MS, XRF, expanded ICP and atomic absorption
facilities in a fourth building. A new fire assay, atomic absorption and ICP lab will be ready in the spring of 2011 with sample preparation operational now
in Stewart, BC.
Our Ancaster lab expanded further with the addition of a new robotic fusion process established for our lithogeochemistry department. In addition, new
ICP/MS (three) and ICP/OES (three) were added to increase capacity substantially. In 2011 we added 2 more PE Elan 9000 DRC ICP/MS and still
more ICPs. Due to increased demand and additional services, five more GC/MS were added as well as two additional HPLCs, DNA instrumentation.
Construction will start in 2011 on a fourth building to add additional lab space and new services. This new facility will add approximately 300,000 sq. ft.
to the Ancaster facility.
ACTLABS is committed to bringing the most modern technologies and a higher level of competencies to the analytical laboratory for the mineral industry.
In little over a decade, the ACTLABS Group has become the world’s leading laboratory group providing Neutron Activation and ICP/MS services. We
continue to invest heavily in Research and Development of new products so that our clients can be at the forefront of exploration technology.
PAGE 5
Analytical Methodologies
High Resolution Inductively Coupled Plasma-Mass Spectrometry (HR-ICP/MS)
Inductively Coupled Plasma-Mass Spectrometry (ICP/MS)
Instrumental Neutron Activation Analysis (INAA)
Inductively Coupled Plasma-Optical Emission Spectrometry (ICP/OES)
Atomic Absorption (AA)
Gas Chromatography-Mass Spectrometry (GC/MS + GC/MS/MS)
High Performance Liquid Chromatography (HPLC)
Liquid Chromatography Triple Quad Mass Spectrometry (LC/MS/MS)
Cold Vapour-Flow Injection Mercury System (CV-FIMS)
Fourier Transform Infrared (FTIR)
Combusion-Infrared
Gravimetric
Ion chromatography (IC)
X-Ray Fluorescence (XRF)
X-Ray Diffraction (XRD)
Titration
Fire Assay
Capillary Electrophoresis (CE)
SKALAR Autoanalyzer
Coulometry McMaster Nuclear Reactor
Terms and Conditions
All prices in this pricelist are in Euros and are applicable for samples received in Canada from clients
within the European Union. These prices apply to most geological materials for routine analyses. A
surcharge may apply for abnormal matrices or non routine analytical requirements. The client will be
advised of any such conditions prior to performing the analytical work. A minimum charge of €100.00
will be effective on all orders. A fee of €75.00 will be charged if a Chain of Custody form is required.
Payment should accompany the order unless credit has been established. Terms are net 30 days.
Prices and packages are subject to change without notice. Customers are responsible for paying bank
charges and should not be deducted from the total amount of the invoice. We reserve the right to
subcontract work to affiliated laboratories. Clients can pay invoices by Visa, MasterCard, AMEX or by
wire transfer (we do not accept bank drafts/cheques in Euros). To pay by credit card, a signature is required - either in the original paperwork or sent by fax
or e-mail. We also require the security code found on the card.
Quality Assurance/Quality Control (QA/QC)
Activation Laboratories Ltd. has achieved the ultimate accreditation to international standards, the ISO 17025 standard for specific registered tests. ISO
17025 evaluates the quality system and specific analytical methodologies through proficiency testing and routine audits of the laboratory. In addition, we
have achieved accreditation to CAN-P-1579, specific to mineral analysis laboratories. We are one of the few commercial laboratories which have achieved
this distinction. Activation Laboratories Ltd. can also advise on methods you can use to ensure security of samples during transport to the laboratory. We
have a rigorous chain of custody protocol in place to ensure security of your samples once we receive them. Analytical uncertainty is available on request.
In 2007, Activation Laboratories Ltd. became accredited to NELAP in the USA.
Liability
Any analysis, testing, inspection or investigation in connection with any work performed by Activation Laboratories Ltd. shall be conducted inaccordance with recognized professional analytical standards. Neither Activation Laboratories Ltd., nor its subcontractors, consultants, agents,officers or employees shall be held responsible for any loss or damage resulting directly or indirectly from any default, negligence, error oromission. While every effort will be taken to store the unused portion of your samples, Activation Laboratories Ltd. cannot bear anyresponsibility for loss or damage, regardless of the cause. The liability, if any, of Activation Laboratories Ltd. shall be limited to the cost ofperforming the analyses.
Sample Packaging and Shipping Instructions
For convenience and to improve turnaround time, a sample submittal sheet can be filled out on-line and e-mailed. Make sure to include date of shipment,
carrier or shipment method and the waybill number so that we can track delayed shipments. An accurate sample list can be sent as an e-mail attachment
and will speed up order processing. Please ensure all samples are identified clearly with sample numbers. This can be accomplished with waterproof ink on
the sample bags or with sample tags in the sample bags. Turnaround time will be improved by packaging samples in order, neatly in shipping containers
and providing a list of all sample numbers, preferably with a hard copy or by e-mail. If using pop top vials or glass bottles, ensure that they are taped shut
and protected from breakage. Sealed plastic bags are best for shipping pulps. For most efficient delivery, we recommend the use of couriers, or transport
companies for heavier shipments.
Samples should be shipped to:
Activation Laboratories Ltd.
1428 Sandhill Drive
Ancaster, Ontario
Canada L9G 4V5
Tel +1 (905) 648-9611
Fax +1 (905) 648-9613
E-mail [email protected]
Waybill Instructions: Mineral Samples for Analysis, No Commercial Value
Canadian Customs Tariff (Harmonized Code) 2617.90.00.90
Value for Customs: €5.00
Customs Broker: Thompson Ahern & Co Ltd
Sample Storage
When submitting samples, please indicate on the Request for Analysis form if you require sample storage, disposal or if you require samples to be returned
after analysis. For returns, please include all necessary shipping information e.g., courier, account number, etc. Return of samples is done at cost. The
reject portion of samples prepared by Actlabs will be retained for a period of not more than 90 days from the date of final report. Pulps (prepared material)
will also be kept for a period of 90 days. Crusher reject or oversized sieve rejects will be saved on request only. Pulps and rejects stored at the customers
request will be subject to a storage charge (see sample submittal sheet for charges) billed quarterly. Irradiated material will be discarded after 30 days
unless prior arrangements are made. Return of radioactive material requires a Nuclear Safety Commission licence. Cost per shipment of radioactive
materials is €100.00 plus shipping costs. Disposal of soil, sediment or vegetation samples, which have entered Canada under a CFIA permit, will incur a
disposal cost for larger sample volumes.
Return of Data
Analytical reports can be returned via hard copy, CD-ROM, electronic mail (internet) or fax copy at the customers’ discretion for no additional charge. Data
is normally available in Excel format. Other formats are available on request. We have implemented a Laboratory Information Management System
(LIMS). Clients can track samples from sample reception and logging through to preparation, analysis and reporting.
Turnaround Time
Please enquire regarding turnaround time. Normal turnaround depends on the analytical package, sample volume as well as time of year. Excessively wet
samples may slow turnaround time, as will undocumented and unorganized shipments. RUSH Analysis: If you require analyses by a certain date, please
ensure that this is clearly noted on the Request for Analysis form. We will make every effort to meet your requirements, however, rush conditions will
require payment of a surcharge (i.e., 3 days – 200%, 1 week – 100%, 2 weeks – 50%). We can establish a WEBLIMS account for following the progress of
your sample analysis requests.PAGE 6
General Information
Instructions for report and invoice distribution should be included with each shipment, or can
be sent to our e-mail address [email protected]. Complimentary shipping labels are
available upon request. Heavy duty plastic sample bags, cloth sample bags, soil envelopes
and sample books are available at cost. Filling out a Request for Analysis form will provide all
of the information required. Sample submissions poorly labelled or packaged, or having
incomplete or no submission sheets may not be processed until adequate written instructions
are received from the client and may incur additional sorting charges.
For wire transfer, please pay to:
Royal Bank of Canada
180 Wellington St. West
3 Floor, Foreign Exchange
Toronto, Ontario CANADA
SWIFT: ROYCCAT2
Transit: 09211
Favour: Activation Laboratories Ltd.
Account: 863-979-4
Sample PreparationTo obtain meaningful analytical results, it is imperative that sample collection and preparation be done properly. ACTLABS can
advise on sampling protocol for your field program if requested. Once the samples arrive in the laboratory, ACTLABS will
ensure that they are prepared properly. As a routine practice with rock and core, the entire sample is crushed to a nominal
minus 10 mesh (1.7 mm), mechanically split (riffle) to obtain a representative sample and then pulverized to at least 95% minus
150 mesh (105 microns). All of our steel mills are now mild steel and do not induce Cr or Ni contamination.
As a routine practice, we will automatically use cleaner sand between each sample at no cost to the customer. Quality of
crushing and pulverization is routinely checked as part of our quality assurance program. Randomization of samples in larger
orders (>100) provides an excellent means to monitor data for systematic errors. The data is resorted after analysis according
to sample number. Please request Code Random (additional €1.50/sample) if you prefer randomization.
Samples submitted in an unorganized fashion will be subject to a sorting surcharge and may substantially slow turnaround time.
Providing an accurate detailed sample list by e-mail will also aid in improving turnaround time and for Quality Control purposes.
Additional charges may apply for poorly organized batches. Code CP2 - Sample list not provided for orders over 25 samples
(€0.30/sample); Code CP3 - Sorting chaotic shipments (€0.55/sample).
All soil, sediment and vegetation coming from outside Canada require incineration prior to disposal under CFIA regulations. All pulps
and rejects will be returned to the client at cost. Disposal costs are additional. Pulps and rejects will incur a storage fee after the free
period listed below.
PAGE 7
Pulverization Contaminants Added(amount added depends on hardness of material
and particle size required)
Mill Type Contaminant Added
Mild Steel (best choice) Fe (up to 0.2%)
Hardened Steel Fe (up to 0.2%), Cr (up to 200 ppm),
trace Ni, Si, Mn and C
Ceramic Al (up to 0.2%), Ba, trace REE
Tungsten Carbide W ( up to 0.1%), Co, C, Ta, Nb and Ti
Agate Si (up to 0.3%), Al, Na, Fe, K, Ca,
Mg, Pb
Soils, Stream and Lake Bottom Sediments
code S1 drying (60ºC) and sieving (-80 mesh) save all portions €3.50
code S1 DIS drying (60ºC) and sieving (-80 mesh), discard oversize €2.75
code S1-230 drying (60ºC) and sieving (-230 mesh), save oversize €4.25
code S1-230 DIS drying (60ºC) and sieving (-230 mesh), discard oversize €4.00
code S2 lake bottom sediment preparation crush & sieve (-80 mesh) €6.50
code S3 alternate size fractions and bracket sieving, add €2.25
code S4 Enzyme LeachSM or SGH drying (40ºC) & sieving (-60 mesh) €3.50
code S5 wet or damp samples submitted in plastic bags, add €1.75
code S6 separating -2 micron material €62.00
code S7 methylene iodide heavy mineral separation €47.75
specific gravity of 3.3 (250 grams)
code S8 sieve analysis (4 sieve sizes) €30.25
Biogeochemical Samples
code B1 drying and blending humus €4.00
code B2 drying and macerating vegetation €5.25
code B3 dry ashing €7.50
code B4 washing vegetation €3.50
code B5 samples submitted in plastic bags, add €1.75
Special Digestion Procedures
code MDI Microwave digestion - closed vessel €46.75
Rock, Core and Drill Cuttings
code RX1 crush (< 5 kg) up to 90% passing 2 mm, split (250 g) €8.25
and pulverize (hardened steel) to 95% passing 105μcode RX1+500 500 grams pulverized add €2.00
code RX1+800 800 grams pulverized add €3.50
code RX1+1.3 1.3 kg pulverized add €4.50
code RX2 crush (< 5 kg), split and pulverize with mild steel €8.00
(100 g) (best for low contamination)
code RX3 oversize charge per kilogram for crushing €2.00
code RX4 pulverization only (mild steel) €5.75
(coarse pulp or crushed rock) (< 800 g)
code RX5 pulverize ceramic (100 g) €13.75
code RX6 hand pulverize small samples (agate mortar & pestle) €13.75
code RX7 crush and split (< 5 kg ) €4.00
code RX8 sample prep only surcharge, no analyses €3.50
code RX9 compositing (per composite) dry weight €2.25
code RX10 dry drill cuttings in plastic bags €2.00
code RX11 checking quality of pulps or rejects €7.50
prepared by other labs and issuing report
Note: Larger sample sizes than listed above can be pulverized at additional cost.
Sample Storage and Disposal
RTRN Return of all reject portions and/or pulps At cost
INCIN Incineration of soil, sediment and vegetation samples from outside Canada €0.30
(for samples up to 0.5 kg; samples over 0.5 kg will have higher incineration costs)
H&R Handling and retrieval of stored pulps and core €47.50/hour to end of
rock core and drill cuttings
sample storage & disposal
DISP Disposal of pulps and reject to landfill site €0.25
STORE 1 Monthly storage of reject after 60 days €0.30
STORE 2 Monthly storage of pulps after 90 days €0.15
STORE 3 Monthly storage of sieve rejects after 3 months €0.20
Note: Use of 50 gram sample for fire assay may not provide optimum recovery.
1 oz/ton = 34.2857 grams/metric tonne.
We participate in numerous proficiency testing programs including the CANMET PTP-MAL for ISO 17025, OREAS,
GEOSTANDARDS, AMIS and USGS.
Blanks duplicates and standards are reported in all sample batches.
Gold and Silver Analyses
Code Method Sample Metric Range Price
Weight
1A1 Au Fire Assay-INAA (geochem) 30 g 1-20,000 ppb €15.25
1A2 Au Fire Assay-AA (geochem) 30 g 5-3,000 ppb €13.00
1A2-50 Au Fire Assay-AA (geochem) 50 g 5-3,000 ppb €14.75
1A3-30 Au Fire Assay-Gravimetric (Assay) 29.16 g 0.03-1,000 g/mT €16.75
1A3-50 Au Fire Assay-Gravimetric (Assay) 50 g 0.02-1,000 g/mT €18.00
1A3-Ag Au, Ag Fire Assay-Gravimetric (Assay) 29.16 g 0.03-1,000 g/mT (Au) €19.25
3-1,000 g/mT (Ag)
**1A4 Au Fire Assay-Metallic Screen (Assay) 500 g 0.03 g/mT €71.50
**1A4-1000 Au Fire Assay-Metallic Screen (Assay) 1,000 g 0.03 g/mT €95.25
1A6 Au BLEG-ICP/MS (geochem) 1,000 g 0.1-10,000 ppb €44.00
1A8 Au Aqua Regia-ICP-MS (geochem) 30 g 0.2-2,000 ppb €14.50
1E-Ag Ag Aqua Regia-ICP (geochem) 5 g 0.2-100 ppm €5.00
8-Ag Ag Fire Assay-Gravimetric (assay) 29.16 g 3-1,000 g/mT €13.75
Sample size used for analysis can be varied.
The price may be higher or lower depending
on sample size. For gold and silver by
INAA - see Codes 1D, 1D enhanced, 1EPI,
1EPI/MS, 1H or 1H2.
Gold, Platinum, Palladium and Rhodium - all ppb, except where noted
Code Method Sample Range Price
Weight Au Pt Pd Rh
1C-exploration Fire Assay-ICP/MS 30 g 2-30,000 1-30,000 1-30,000 €16.75
1C-EXP 2 Fire Assay-ICP/MS 30 g 1-30,000 0.5-30,000 0.5-30,000 €19.25
1C-research Fire Assay-ICP/MS 30 g 1-30,000 0.1-30,000 0.1-30,000 €27.00
1C-Rhodium Fire Assay-ICP/MS 30 g 5-10,000 €33.50
1C-OES Fire Assay-ICP/OES 30 g 2-30,000 5-30,000 5-30,000 €15.00
8 Au Pt Pd Fire Assay-ICP 30 g 0.001 - 0.001 - 0.001 - €38.25
1000 g/mT 1000 g/mT 1000 g/mT
Platinum Group Elements (NiS Fire Assay - 50 g) - all ppb (range)
Os Ir Ru Rh Pt Pd Au Re Price
Code 1B1 1-2 samples €261.50
INAA Finish 2 0.1 5 0.2 5* 2 0.5 5 3+ samples €142.75
Code 1B2 1-2 samples €261.50
ICP/MS Finish - 1 1 1 1 1 1 1 3+ samples €142.75
Notes:
• ** Code 1A4 or 1A4-1000 - A representative 500 gram or 1000 gram sample split is sieved at 100 mesh (150 micron),
with assays performed on the entire +100 mesh fraction and two splits of the -100 mesh fraction. It is important not to
overpulverize the sample too finely, as tests have shown gold will plate out on the mill and be lost. When assays have
been completed on the coarse and fine portions of the bulk sample, a final assay is calculated based on the weight of
each fraction. Price includes sample screening but not crushing and pulverizing.
• * Code 1B - Detection limits for Pt are increased with high Au/Pt ratios and limits for other elements will be affected by
abnormally high Au, Sb and Cu content. Samples with high Au can be reanalyzed by Code 1C exploration or research.
Zn concentrates are not amenable to the nickel sulphide fire assay.
Au results by Code 1B1 or 1B2 can be low by nickel sulphide fire assay. For accurate Au values, please request Code
1C-exploration.
Precious Metal Geochemistry
PAGE 8
When submitting
samples for Gold
and Silver analysis
or Gold, Platinum,
Palladium and
Rhodium analysis,
please try to ensure
you send two-times
the listed weight.
When submitting
organic samples for
fire assay analysis,
a €1.25/sample
surcharge will be
charged.
Assay ProductsCode 8 - Assay Products
Assays provide quantitative determinations of elements in non-processed geological materials. Assays are usually required only
when the client knows or suspects higher levels of metals in samples. Geochemical methods generally provide lower detection
limits than assays. For lower levels, geochemical methods should be used. All assays are traceable to international reference
standards. Prices listed in our fee schedule are for normal geologic materials and are not for metallurgical products. Metallurgical
products such as heads and concentrates are handled separately to prevent contamination in the laboratory. These materials are
charged at five times the prices listed in our fee schedule.
Element Price Element Price
Alumina - Al2O3 €19.25 Magnesium (oxide) - MgO €19.25
Antimony - Sb €19.25 Moisture - H2O €9.75
Arsenic - As €19.25 Molybdenum (total) - Mo €9.75
Barium (Instrumental) - Ba €19.25 Molybdenum (oxide) €19.25
Barium (Gravimetric) - Ba €29.00 Molybdenum (sulfide) €19.25
Beryllium - Be €24.00 Nickel - Ni €9.75
Bismuth - Bi €19.25 Nickel - Ni Sulphide €19.25
Boron - B €24.00 Niobium - Nb €19.25
Bromine - Br €19.25 Phosphorous (oxide) - P2O5 €19.25
Cadmium - Cd €17.50 Platinum-Palladium-Gold (Pt-Pd-Au) €38.25
Calcium (oxide) - CaO €19.25 Potassium (oxide) - K2O €19.25
Cerium - Ce €19.25 Rhenium - Re (Mo concentrates) €36.50
Chlorine - Cl €24.00 Rhodium - Rh See Code 1C-Rh
Chromium - Cr €19.25 Selenium - Se €19.25
Cobalt - Co €9.75 Silicon (oxide) - SiO2 €19.25
Copper (total) - Cu €9.75 Silver - Ag €13.75
Copper (CN soluble) €10.75 Sodium (oxide) - Na2O €19.25
Copper (Acid soluble) €9.75 Specific Gravity - S.G. €21.50
Copper (Ferric sulfate soluble) €10.75 Strontium - Sr €14.50
Copper (Sequential Oxide Analysis) €29.00 Sulfur (Infrared) €24.00
Fluorine - F €24.00 Sulfur (Gravimetric) - S €24.00
Gold - Au See Code 1A3 Sulfate - SO4 €19.25
Gold-Silver (Au-Ag) See Code 1A3-Ag Tantalum - Ta €19.25
Gallium - Ga €24.00 Tellurium - Te €19.25
Germanium - Ge €33.50 Thallium - Tl €19.25
Insolubles €17.50 Thorium - Th €19.25
Iron (oxide) - Fe2O3 €14.50 Tin - Sn €19.25
Lanthanum - La €14.50 Titanium (oxide) - TiO2 €19.25
Lead (total) - Pb €9.75 Tungsten (oxide) - WO3 €19.25
Lead (oxide) - PbO €19.25 Uranium (oxide) - U3O8 €19.25
Lithium - Li €19.25 Vanadium (oxide) - V2O5 €19.25
Loss on ignition - LOI €9.00 Zinc (total) - Zn €9.75
Mercury - Hg €19.25 Zinc (oxide) - ZnO €19.25
Manganese (oxide) - MnO €19.25
Code 8 - AR ICP - Assay package for base metals, aqua regia digestionPrice
Copper - Cu Lead - Pb Zinc - Zn Cadmium - Cd Iron - Fe Manganese - Mn One element €9.75
Cobalt - Co Nickel - Ni Silver - Ag Mercury - Hg Each additional €3.50
Code 8 - 4 Acid ICP - Assay package for base metals, 4 acid digestionPrice
Copper - Cu Lead - Pb Zinc - Zn Manganese - Mn Lithium - Li Iron - Fe One element €12.75
Cobalt - Co Nickel - Ni Silver - Ag Molybdenum - Mo Cadmium - Cd Each additional €3.50
PAGE 9
Code 8 - Peroxide ICP Code 8 - Peroxide ICP/MS
Sodium peroxide fusion, acid dissolution followed by ICP/OES. Sodium peroxide fusion, acid dissolution followed by ICP/MS.
Elements and Detection Limits (%) Elements and Detection Limit (%)
Al 0.01 Mg 0.01 As 0.001 Se 0.001
As 0.01 Mn 0.01 Bi 0.001 Sn 0.001
Be 0.001 Ni 0.005 Cs 0.001 Te 0.001
Ca 0.01 Pb 0.01 Ga 0.001 Th 0.001
Co 0.002 S 0.01 Ge 0.001 Tl 0.001
Cr 0.01 Si 0.01 In 0.001 U 0.001
Cu 0.005 Ti 0.01 Re 0.001
Fe 0.05 Zn 0.01
K 0.1 Zr* 0.001 Price: One element - €16.25; Each additional - €3.50
Li 0.001
Price: One element - €13.75; Each additional - €3.50* If P2O5 > 0.3%, then fusion XRF is recommended.
PAGE 10
Exploration Techniques for Specific Deposit Types
Code 8 - REE Assay Package. Rare Earth Element-Niobium-Zirconium-Yttrium-Tantalum-Uranium-
Thorium-Beryllium-Phosphate-Tin Assay ICP and ICP/MS Package
Rare earths and rare elements are among the most difficult to analyze properly. It is essential that the sample be ground to 95%-200 mesh to ensure
complete fusion of resistate minerals. The analysis requires a lithium metaborate/tetraborate fusion with subsequent analysis by ICP and ICP/MS.
Mass balance is requried as an additional quality control technique and elemental totals of the oxides should be between 98 to 101%. In certain
circumstances the presence of small amounts of phosphate will have very severe consequences to Nb2O5 assays by this method with results being
very low for Nb2O5. Reanalysis is required for Nb2O5 by fusion XRF. In many cases these types of deposits may contain high amounts of fluorite. This
should be noted on the Request for Analysis form or F assays should be requested. This will speed up processing as mass balance won’t be achieved
otherwise and a delay in returning results will ensue as samples get repeated. IN NO CIRCUMSTANCES SHOULD AN ACID DIGESTION OF ANY
TYPE BE USED TO EVALUATE THE ABOVE ELEMENTS AS THEY WILL ONLY BE PARTIAL ANALYSIS.
Fusion ICP & ICP/MS, Elements and Detection Limits (ppm, except where noted) Price: €69.50
Al2O3 0.01% Be 1 Rb 2 La 0.1 Volume discounts are available.
CaO 0.01% Bi 0.4 Sb 0.5 Ce 0.1
Fe2O3 0.01% Co 1 Sc 1 Pr 0.05
K2O 0.01% Cr 20 Sn 1 Nd 0.1
MgO 0.01% Cs 0.5 Sr 2 Sm 0.1
MnO 0.001% Cu 10 Ta 0.1 Eu 0.05
Na2O 0.01% Ga 1 Th 0.1 Gd 0.1
P2O5 0.01% Ge 1 Tl 0.1 Tb 0.1
SiO2 0.01% Hf 0.2 U 0.1 Dy 0.1
TiO2 0.001% In 0.2 V 5 Ho 0.1
LOI 0.01% Mo 2 W 1 Er 0.1
Ag 0.5 Nb 1 Y 2 Tm 0.05
As 5 Ni 20 Zn 30 Yb 0.1
Ba 3 Pb 5 Zr 4 Lu 0.04
If samples contain >0.3% P2O5 then Nb2O5 and ZrO2 is recommended to be replaced by fusion XRF as ICP/MS results may be very low.
Code 8 - XRF Nb2O5, ZrO2 & Ta2O5 Option Price: €17.50
Code 8 - F Option Price: €13.25
Code 8 - Niobium-Zirconium-Yttrium-Tantalum-Uranium-Thorium-Phosphate-Tin Assay XRF Package
Samples not requiring rare earths can be analyzed by fusion with lithium metaborate/tetraborate in platinum crucibles with the molten glass cast into a
glass disc in platinum crucibles. These glass discs are analyzed by XRF. Generally low Ta2O5 detection limits can’t be achieved with this package and
the INAA technique is recommended for tantalum.
Elements Detection Limit (%) INAA Option: Elements Detection Limit (ppm)
Ta2O5 0.003 Ta 0.5
Nb2O5 0.003 Th 0.2
U3O8 0.005 U 0.5
ThO2 0.005 La 0.5
ZrO2 0.003 Ce 3
Fe2O3(T) 0.01 Nd 5
P2O5 0.01 Sm 0.1
SnO2 0.003 Eu 0.2
Y2O3 0.003 Yb 0.2
Lu 0.05
Price: €34.75, Volume discounts are available. Price: First element - €16.00; each additional - €1.10
Major Oxide Option: €17.50
Code 8 - Chromite/PGE Assay XRF Package
Chromite assays are usually combined with major oxide analysis as other elements are required for the metallurgical use of the chromite. Cr/Fe ratios
are very important in assigning value to chromite as well as other deleterious elements.
Elements Detection Limits Elements Detection Limits Price: €30.25
Al2O3 0.01% MnO 0.01% Volume discounts are available.
CaO 0.01% Na2O 0.01%
Cr2O3 0.01% NiO 0.01%
Co3O4 0.01% P2O5 0.01%
CuO 0.01% SiO2 0.01%
Fe2O3 0.01% TiO2 0.01%
K2O 0.01% V2O5 0.01%
MgO 0.01% LOI 0.01%
PGE (ICP/OES) Option: Au 2 - 30,000 ppb PGE Option: €18.25
Pt 5 - 30,000 ppb Volume discounts are available.
Pd 5 - 30,000 ppb
PAGE 11
Code 8 - Uranium Assay Package
Total uranium can be determined by delayed neutron counting using an automated system at a nuclear reactor. The principle advantage of this is to
provide very rapid and accurate assays for high volumes of samples at a very low cost. The upper limit of this technique is 1%U. Results can be
reported as U or U3O8. From 1 to 10% U3O8 fusion XRF will provide the best quality assay results and above 10% U3O8 titration is recommended for
accuracy.
Acid digestion using both aqua regia and “4 acid near total” digestion with ICP/MS is also possible but uranium in resistate phases (zircon, monazite,
etc) may not be included in the assays. “Near Total” digestions may not be total for uranium depending on mineralogy. Hydroflouric acid is used in the
digestion and some uranium may be volatilized due to combination with the HF.
Code 5D - U3O8 Assay DNC (0.1 ppm - 1% U3O8) Price: €13.75
Code 8 - U3O8 Aqua Regia by ICP/MS Price: €14.00
Code 8 - U3O8 Assay by XRF (0.005%- 10% U3O8) Price: €19.25
Code 8 - U3O8 “Near Total” by ICP/MS Price: €16.00
Code 8 - U3O8 Titration (>10% U3O8) Price: €30.25
Geochem V, U by XRF Pressed Pellet Price: €10.50
Code 8 - Potash Assay Package
Prepared samples are analyzed by dissolution in water at 30°C. KCl or Sylvite is dissolved as well as other soluble salts. K, Mg, Na and Ca salts are
solubilized leaving insoluble salts (e.g. anhydrite, kieserite) as a residue which is dried and weighed.
Package includes: Sample preparation Price: €60.50
ICP (K, Mg, Na, Ca, Cl, S as water soluble) Volume discounts may be applicable.
Insoluble residue - included in ICP
Moisture
Options: Soluble Br, Cl Price: €26.25
Soluble carbonate Price: €21.75
Total Br - INAA Price: €17.50
Total Cl - INAA Price: €26.25
Code 8 - Oil Shale Package
These analytical methods are used in exploration programs to determine the anticipated shale oil yield and to better delineate core characteristics.
Analytical Method Description Price/sample
Rock-Eval 2 Pyrolysis Total organic carbon (wt%) €108.00
Non-pyrolysed organic carbon (wt%)
Total mineral carbon (wt%)
S1 - hydrocarbons evolved at 300°C (mg/g)
S2 - hydrocarbons evolved between 300 and 600°C (mg/g) heating at 25°C/min
S3 - organic carbon dioxide evolved at 300°C and up to 390°C (mg/g)
Production Index, Hydrogen Index and Oxygen Index
Rock-Eval 6 Pyrolysis Programmed pyrolysis + TOC + CO2 €216.25
Fischer Assay-ASTM D3904 Free water - moisture (wt%) by oven drying €151.25
Retort water (wt% and L/tonne)
Oil yield (wt% and L/tonne)
Gas yield (wt% and L/tonne)
Spent shale (wt%)
Gas average molecular weight
Oil relative density
GC Scan GC scan of shale gas to include as a minimum: H2, N2, CO, CO2, C1, C2, C3, C4, C5+ €259.50
Elemental Analysis Total carbon, sulphur €19.25
Total organic carbon €30.25
Total oxygen €69.50
Hydrogen €33.50
Nitrogen €33.50
Pyritic sulfur €26.25
Sulfate sulfur €21.25
Mercury €9.00
Fluoride €9.75
Mineral Identification €157.00
Whole Rock Analysis A whole rock analysis is performed to provide chemical analysis of inorganic components €39.00
of the rock.
Trace Metal Analysis Near total digestion is performed and a full trace metal scan by ICP shall be conducted to €30.25
include at least the following elements:
Cu, Pb, Zn, Fe, W, Mo, Sn, In, Bi, Cd, Sb, F, Nb, Ta, Th, Cs, Y, As, Ag, U and V.
PAGE 12
Code 8 - Coal Package
Parameter ASTM Method Price
Sample Preparation D-2013 €14.00
Dry Screen Analysis (1 kg) (first fraction) D-4749 €34.75
Specific Gravity (Relative Density) D-167 €25.50
Total Moisture (TM) D-3302 €21.75
Proximate Analysis (Ash, Inherent Moisture, Volatile Matter) D-3172 €34.75
Free Swelling Index D-720 €17.50
Calorific Value (CV) D-5865 €34.75
Total Sulphur D-4239 €23.00
Forms of Sulphur D-2492 €53.75
(including Sulphates, Pyritic Sulphur and Organic C)
Mercury D-6414 €21.75
Equilibrium Moisture D-1412 €39.00
Ash Fusion Temperature (Reducing, Oxidizing, Combined) D-1857 €108.00
Ultimate Analysis: D-3176
Carbon €47.75
Hydrogen €52.75
Carbon + Nitrogen €82.25
Nitrogen D-5373 €47.75
Bulk Density €29.00
F in coal ASTM 5987-96 €67.00
Cl in coal €38.25
Loss on Ignition 750°C ASTM D7348-08 €21.75
Hardgrove Grindability ASTM D409/D409 M-09 €65.00
Major and trace elements on ash: Price: €141.00
Elements and Detection Limits (ppm, except where noted)
SiO2 0.01% Bi 0.4 In 0.2 Sn 1
Al2O3 0.01% Br 0.5 Ir 5 ppb Sr 2
Fe2O3 0.01% Ce 0.1 La 0.1 Ta 0.1
MgO 0.01% Cd 0.5 Lu 0.04 Tb 0.1
MnO 0.001% Co 1 Mo 2 Th 0.1
CaO 0.01% Cr 5 Nb 1 Tl 0.1
TiO2 0.001% Cs 0.5 Nd 0.1 Tm 0.05
Na2O5 0.01% Cu 1 Ni 1 U 0.1
K2O 0.01% Dy 0.1 Pb 5 V 5
P2O5 0.01% Er 0.1 Pr 0.05 W 1
LOI 0.01% Eu 0.05 Rb 2 Y 2
Ag 0.5 Ga 1 S 0.001% Yb 0.1
As 0.5 Gd 0.1 Sb 0.2 Zn 1
Au 2 ppb Ge 1 Sc 0.1 Zr 4
Ba 3 Hf 0.2 Se 3
Be 1 Ho 0.1 Sm 0.1
Code 8 - Iron Ore Analysis XRF
Oxides and Detection Limits (%) Price: €34.50 Volume discounts are available
SiO2 0.01 MnO 0.001 K2O 0.01 Davis tube magnetic separation Price: €93.50
TiO2 0.01 MgO 0.01 P2O5 0.01 Sulphur Price: €16.00
Al2O3 0.01 CaO 0.01 Cr2O3 0.01 TGA Analysis Price: €34.75
Fe2O3 0.01 Na2O 0.01 LOI 0.01 Satmagan Test Price: €23.00
Code 8 - Lithium Ore Analysis
Li assays by Peroxide Fusion ICP/OES (detection limit 0.001%) Price: €15.50
Li assays by 4-Acid Digestion ICP/OES (detection limit 0.001%) Price: €13.75
Li assays on brines by ICP/OES (detection limit 0.05 mg/L) Price: €13.75
Add-ons:
Any of the above packages can be converted to multielement analysis. Common elements requested are K, Mg, B, Na and Ca. Price: €7.75
F assay by ISE. Price: €14.50
Notes:For geochemical packages, see Code 1F2 for 4-Acid Digestion ICP or Code Ultratrace 7 for Peroxide Fusion ICP+ICP/MS. Multielement brine
package is Code 6MB.
Volume discounts are available.
PAGE 13
Geometallurgy (Automated Quantitative Mineralogy - MLA)Geometallurgy is an integrated methodology and multi-disciplinary field which aims to add value to a mineral deposit or resource while looking ahead at risk-
reduction and improved decision-making and cost-effective down-stream activities (e.g. development, pre-feasibility, feasibility and production). The objective of
successful Geometallurgy is quality ore-characterization and establishing links and relationships between geology, mineralogy and processing characteristics. In
this regard, quantitative mineralogy is key to this process.
MLA – Mineral Liberation Analyser
The Quanta 600F MLA Instrument at Actlabs is a state-of-the-art MLA system with superior resolution and performance over typical Scanning Electron
Microscope systems. The Field Emission Gun electron source makes for significantly higher resolution analysis relative to regular MLA and QemSCAN
technology. The system is equipped with specialized software and Energy Dispersive Spectrometers, and is capable of providing reliable numeric data on:
• Mineralogical composition (mineral identities and proportions)
• Distribution and deportment of elements of interest among host minerals
• Mineral grain size distributions
• Mineral association information
• Particle compositions and population distributions (with colour coded particle images)
• Mineralogically Limiting Grade-Recovery Curves
Services and Fees
Mineralogical sample preparation and methods differ from assay sample preparation in that features of particles and rock-fragments are measured as a matter of
routine. As a result, sample particle size distributions are typically coarser, sampling efficiency and protocols are different and often require greater time for
appropriate sub-sampling and measurement. In addition, the complexity of ores and the fact that element and mineral grade relationships are unknown prior to
analysis, means that the detection limits for minerals are not fixed. As a result, prices are presented as unit costs based on a standard, 30 mm diameter
polished section. Similarly, thin section analysis is presented for samples without any guarantee of representivity.
Actlabs offers mineralogical analysis of assay rejects, drill core, RC drilling chips, plant samples and most other forms of man-made and natural materials.MLA
can be applied to precious metals (Au, Pt, Pd, Ag), base metals (Cu, Ni, Co, Pb, Mo, Zn), ferrous and non-ferrous raw materials (Fe, Sn, Mn, W, Ta, Nb, U and
REE) and mineral sands.
For more details, please contact Chris Hamilton, Manager Geometallurgy, tel: +1 (905) 648-9611, ext. 170 or [email protected].
Experimental Description Detection Limit Information Price
SAMPLE PREPARATIONAND SET-UP SCHEDULEBasic Modal Analysis Rapid modal analysis for exploration samples. 0.1 %* €267.50
Polished section preparation Unit sub-sample, represented by a 30 mm, €39.00
epoxy-mounted, particulate section for MLA
analysis. The price of one section is included
in the basic modal cost.
Sizing Sieve-sizing, including cyclosizing, or alternate, By quotation
into discrete size fractions.
Crushing/Milling Size reduction; dependant on mass of sample, By quotation
study objective and as-received sample form.
Collection of Mineral Collection and Validation of an Ore Mineral List Dependant on grain €314.50
Reference Standards List for a new Project. size and grade*
ANALYSIS/MEASUREMENTSEM Analysis Use of SEM in ad-hoc, manual mode. €275.00/hr
(SEM-EDS and photomicrography)
Thin Section Analysis - Basic Modal analysis of thin section. 0.1%* €188.75
Thin Section Analysis - Advanced As above, but with grain size and association 0.1%* €314.50
data.
Ore Characterization - Standard Analysis of coarsely crushed sample for the 0.1 %** €471.75
determination of mineral suite, proportions,
grain size and association data. (duplicate
sections)
Ore Characterization - Advanced High-resolution option; involves analysing two 0.1 %** €943.00
size fractions and/or higher resolution
measurement.
Coarse Precious Metal Determination of discrete PGM mineralogy, Grain Size of €220.00
Mineralogy speciation, grain size and association on ores, > 1.5 microns
process samples and tailings. (per section)
Fine Precious Metal Mineralogy Determination of discrete PGM mineralogy, Grain Size of €440.00
(High Resolution) speciation, grain size and association on ores, < 1.5 microns
process samples and tailings. (per section)
REPORTINGReporting Formal presentation and reporting of results, Depends on volume By quotation
either in tabulated form or including discussion of samples
and interpretation. Usually a fixed % of
experimental.
* Unit cost based on a single polished section. (Discounts available for batch submissions)
** Depends on target grade and complexity of mineralogy.
Trace Element Geochemistry
Au+34
Aqua Regia Extraction Near Total Metals
All elements are in ppm except where noted.
Code 1EPI
The “Au+14” group of elements provides a high quality, low cost package for epithermal gold exploration [by INAA (Au, As, Sb, Ba, Hg and W),
aqua regia ICP (base metals and sulphur) and optional cold vapour FIMS (Hg)]. A sample of ~30 g is used for Au analysis. An enhanced package
(Code 1EPI enhanced) with better detection limits for Au (2 ppb) and As (0.5 ppm) also is available for an additional €2.25 per sample. (35 g
required). Sulphur (+) from barite will not be reported. If total S is required, see Code 4F-S. See Code 1E for notes on base metals.
Au+14 Au+23 ICP/MS ICP+ICP/MS Near Total Au+49 Au+53 Au+63 ICP/MS INAA+ICP/MS
Code 1EPI 1EPI/MS 1D 1D enh. 1E 1E1 1E2 1E3 Ultratrace 1 Ultratrace 2 1F 1F2 1H 1H2 Ultratrace 3 Ultratrace 4 Ultratrace 5
Ag 0.2 0.2 5 5 0.2 0.2 0.2 0.2 0.002 0.002 0.3 0.3 0.3 0.3 0.05 0.05 0.05
Al *0.01% *0.01% *0.01% *0.01% *0.01% *0.01% *0.01% *0.01% *0.01% *0.01% *0.01%
As 2 2 2 0.5 *10 *3 *2 *0.1 *0.1 3 0.5 0.5 0.5 *0.1 *0.5
Au 5 ppb 5 ppb 5 ppb 2 ppb *5 ppb *5 ppb 2 ppb 2 ppb 2 ppb 2 ppb
B *5 *10 *1 *1
Ba 100 100 100 50 *1 *1 *10 *0.5 *0.5 *7 50 50 *1 *1 *1
Be *1 *1 *0.5 *0.1 *0.1 1 1 1 1 0.1 0.1 0.1
Bi 0.1 10 2 2 0.02 0.02 2 2 2 0.1 0.02 0.02 0.02
Br 1 0.5 0.5 0.5 0.5 0.5
Ca *0.01% 1% 1% *0.01% *0.01% *0.01% *0.01% *0.01% 0.01% 0.01% 0.01% 0.01% 0.01% 0.01% 0.01%
Cd 0.5 0.5 0.5 0.5 0.5 0.5 0.01 0.01 0.3 0.3 0.3 0.3 0.1 0.1 0.1
Ce 3 3 *0.01 *0.01 3 3 *0.1 *0.1 *0.1
Co 5 1 *1 *1 *1 *0.1 *0.1 1 1 1 1 0.1 0.1 1
Cr 10 5 *2 *2 *1 *0.5 *0.5 1 2 2 1 *0.5 *2
Cs 0.05 2 1 *0.02 *0.02 1 1 0.05 0.05 0.05
Cu 1 1 1 1 1 1 0.01 0.01 1 1 1 1 0.2 0.2 0.2
Dy *0.1 *0.1 *0.1 *0.1 *0.1
Er *0.1 *0.1 *0.1 *0.1 *0.1
Eu 0.2 0.2 *0.1 *0.1 0.2 0.2 *0.05 *0.05 *0.05
Fe 0.02% 0.02% 0.01% *0.01% *0.01% *0.01% *0.01% *0.01% *0.01% 0.01% 0.01% 0.01% 0.01% *0.01% *0.01%
Ga *1 *10 *0.02 *0.02 *1 0.1 0.1 0.1
Gd *0.1 *0.1 *0.1 *0.1 *0.1
Ge 0.1 *0.1 *0.1 0.1 0.1 0.1
Hf 1 1 *0.1 *0.1 1 1 *0.1 *0.1 *1
Hg 1 1 1 1 1 1 1 1 1 1
**Hg-CV (5 ppb) (5 ppb) (5 ppb) (5 ppb) (5 ppb) (5 ppb) (5 ppb) (5 ppb) (5 ppb) (5 ppb) (5 ppb) (5 ppb) (5 ppb) (5 ppb) (5 ppb) (5 ppb) (5 ppb)
Ho *0.1 *0.1 *0.1 *0.1 *0.1
In *0.02 *0.02 0.2 0.1 0.1
Ir 5 ppb 5 ppb 5 ppb 5 ppb 5 ppb
K *0.01% *0.01% *0.01% *0.01% *0.01% *0.01% 0.01% 0.01% 0.01% 0.01% 0.01% 0.01% 0.01%
La 1 0.5 *1 *10 0.5 *0.5 0.5 0.5 *0.1 *0.1 0.1
Li *0.1 *0.1 1 1 0.5 0.5 0.5
Lu 0.05 0.05 *0.1 *0.1 0.05 0.05 *0.1 *0.1 *0.1
Mg *0.01% *0.01% *0.01% *0.01% *0.01% 0.01% 0.01% 0.01% 0.01% 0.01% 0.01% 0.01%
Mn 2 2 *2 *2 *1 *5 *1 *1 1 1 1 1 1 1 1
Mo 2 2 5 1 *2 *2 *2 *1 *0.01 *0.01 1 1 1 1 1 0.1 0.2
Na 0.05% 0.01% *0.01% *0.001% *0.001% *0.001% *0.001% 0.01% 0.01% 0.01% 0.01% 0.01% 0.01% 0.01%
Nb *0.1 *0.1 *0.1 *0.1 *0.1
Nd 5 5 *0.02 *0.02 5 5 *0.1 *0.1 *0.1
Ni *1 *1 50 20 *1 *1 *1 *1 *0.1 *0.1 1 1 1 1 0.5 0.5 0.5
P *0.001%*0.001% *0.001% *0.001% 0.001% 0.001% 0.001% 0.001% 0.001%
Pb 2 2 2 2 2 2 *0.01 *0.01 3 3 3 3 0.5 0.5 0.5
Pr *0.1 *0.1 *0.1 *0.1 *0.1
Rb 30 15 *0.1 *0.1 15 15 0.2 0.2 0.2
Re 0.001 0.001 0.001 0.001 0.001
S +0.01%+0.01% +0.01% +0.01% +0.01% +0.01% +0.001% +0.01% +0.01% +0.01% +0.01% +0.01%
Sb 0.2 0.2 0.2 0.1 *10 *5 *2 *0.02 *0.02 5 0.1 0.1 0.1 0.1 0.1
Sc 0.1 0.1 *1 *0.1 *1 *0.1 *0.1 4 0.1 0.1 0.1 0.1
Se 0.1 5 3 *0.1 *0.1 3 3 0.1 0.1 0.1
Sm 0.1 0.1 *0.1 *0.1 0.1 0.1 *0.1 *0.1 *0.1
Sn 0.05% 0.02% *10 *5 *0.05 *0.05 0.01% *1 *1 *1 *1
Sr 0.1% 0.05% *1 *1 *1 *0.5 *0.5 1 1 1 1 0.2 0.2 0.2
Ta 1 0.5 *0.05 *0.05 0.5 0.5 *0.1 *0.1 *0.1
Tb 0.5 0.5 *0.1 *0.1 0.5 0.5 *0.1 *0.1 *0.1
Te 0.1 *1 *1 0.02 0.02 2 0.1 0.1
Th 0.5 0.2 *0.1 *0.1 0.2 0.2 *0.1 *0.1 *0.1
Tl *0.1 *2 *2 *0.02 *0.02 5 0.05 0.05 0.05
Ti *0.01% *0.01% *0.01% *0.01% 0.01% 0.01% 0.01% 0.01% 0.01%
Tm *0.1 *0.1 *0.1 *0.1 *0.1
U 0.5 0.5 10 *0.1 *0.1 *10 0.5 0.5 0.1 0.1 0.1
V *1 *1 *1 *1 *1 2 2 2 2 1 1 1
W 4 4 4 1 *10 *1 *10 *0.1 *0.1 *5 1 1 1 *0.1 *1
Y *1 *1 *1 *0.01 *0.01 *1 *1 *1 *1 *0.1 *0.1 *0.1
Yb 0.2 0.2 *0.1 *0.1 0.2 0.2 *0.1 *0.1 *0.1
Zn *1 *1 50 50 *1 *1 *1 *2 *0.1 *0.1 1 1 1 1 0.5 0.2 0.5
Zr *1 *1 *1 *0.1 *0.1 *5 *1 *1 *1
Price €20.50 €27.75 €15.25 €17.50 €9.25 €9.75 €10.50 €10.50 €17.05 €22.25 €13.50 €15.25 €25.00 €35.50 €37.50 €19.25 €29.00
* Partial extraction only Elements in brackets are optional - see notes, page 10-11** Hg add on by cold vapour FIMS (CODE 1G), add €7.50 + only sulphide sulphur is extracted
ICP/OES
PAGE 14
Which digestion do I use?1. AQUA REGIA DIGESTION - This leach uses a combination of concentrated hydrochloric and nitric acids to leach sulphides,
some oxides and some silicates. Mineral phases which are hardly (if at all) attacked include barite, zircon, monazite,
sphene, chromite, gahnite, garnet, ilmenite, rutile and cassiterite. The balance of silicates and oxides are only slightly to
moderately attacked, depending on the degree of alteration. Generally, but not always, most base metals and gold are
usually dissolved if the sample is ground finely enough.
2. “TOTAL” DIGESTION - This acid attack is the most vigorous used in geochemistry. It will employ hydrochloric, nitric,
perchloric and hydrofluoric acids. Even with this digestion, certain minerals (barite, gahnite, chromite and cassiterite) may
not go into solution. Other minerals including zircon, sphene and magnetite may not be totally dissolved. Most other
silicates will be dissolved, however some elements will be erratically volatilized, including Si, As, Sb, Cr, U and Au. Total
digestions cannot be used for accurate determinations of REE, Ta, Nb, As, Sb, Sn, Hf, Cr, Au and Si.
3. FUSION TECHNIQUE - The most aggressive fusion technique employs a lithium metaborate/tetraborate fusion. The resulting
molten bead is rapidly digested in a weak nitric acid solution. The fusion ensures that the entire sample is dissolved. It is
only with this attack that major oxides including SiO2 , REE and other high field strength elements are put into solution.
High sulphide bearing rocks may require different treatment, but can still be adequately analyzed.
NOTE: Results from aqua regia or total digestions may be lab dependent or lab operator dependent. Actlabs has automated this
aspect of digestion using a microprocessor designed hotbox to accurately reproduce digestion conditions every time.
Trace Element Geochemistry
Code 1EPI/MS - The “Au+23” group of elements is similar to Code 1EPI but includes a suite of elements by ICP/MS to provide virtually all
elements used for epithermal gold exploration. The multielement acid attack will only dissolve the soluble forms of barium, while INAA will
provide the total barium concentration. The total Ba to soluble Ba ratio will be a direct indicator of barite concentration. Code 1EPI/MS
Enhanced is available which offers Au - 2 ppb, As - 0.5 ppm, Sb - 0.1 ppm for an additional €2.50 per sample (35 g required). See
Code 1E for notes on base metals.
Code 1D - The sample is encapsulated, irradiated and measured in a multielement mode by INAA for Au+34 elements. The elements in this
package are determined non-destructively and the total metals help the geologist determine rock types, alteration and pathfinder elements.
The 30 g aliquot provides a representative sample size for gold analysis (0.5 to 30 g required).
Code 1D enhanced - This INAA package is similar to Code 1D but has enhanced detection limits. This package has become very popular for
rock, soil, lake sediment and stream sediment samples (0.5 to 30 g required).
Code 1E - This package determines a base metal suite and sulphide sulphur by an aqua regia extraction with an ICP/OES finish.
If accuracy better than +/- 10-15% is required for higher level samples we recommend assays (Code 8) (+/- 3%) for Cu, Zn and Ni over
10,000 ppm and certainly over 50,000 ppm. Assays are also recommended for Pb >5000 ppm and Ag >100 ppm due to potential solubility
problems. Values exceeding these limits are estimates and are provided for information only. (0.5 g of sample required).
Prices: first element €6.00; each additional element €2.50.
Code 1E1 - This analytical package uses the same digestion as Code 1E. The same comments apply as in Code 1E for base metals. In
addition, a variety of other elements are obtained non-quantitatively since chromite, barite, silicates, magnetite, sphene and some other
mineral phases are not soluble with this digestion. Zinc in gahnite or sphene will not be soluble in aqua regia and all Ni in silicate phases
may not be totally leachable. (0.5 g of sample required).
Code1E2, 1E3 - These are similar to Code 1E1, but offer an enhanced list of analytes. (0.5 g of sample is required).
Code 1F, 1F2 - These packages uses a “near total” digestion employing HF, HClO4, HNO3 and HCl to get as much of the sample into solution
as possible without fusing the sample. The resulting metals are determined by ICP/OES. Sulphide sulphur is included. The sulphur
associated with barite will not be dissolved. Other phases which may not be totally digested include zircon, monazite, sphene, gahnite,
chromite, magnetite, barite, cassiterite, ilmenite and rutile. The same comments apply as in Code 1E for base metals. (0.25 g of sample
required).
Code ULTRATRACE-1 - This partial extraction is analyzed by ICP/MS to provide lower detection limits. Upper limits are up to
20,000 times the detection limits. Au is semi-quantitative. (0.5 g of sample is required).
Code ULTRATRACE-2 - This combines ULTRATRACE-1 with Code 1E2 to provide a few additional elements from the ICP/OES
as well as extend the upper limits of the ULTRATRACE-2 elements. Au is semi-quantitative. (0.5 g of sample is required).
Code 1H “Au+49” - This package provides a trace element scan for virtually all types of economic mineralization. It also provides useful
information on alteration, rock types, and pathfinder elements. The Code 1D enhanced (INAA) and Code 1F (4-acid digestion ICP
technique) provide 49 elements. The elements determined by INAA are Au, As, Ba, Br, Ce, Co, Cr, Cs, Eu, Fe, Hf, Hg, Ir, La, Lu, Na, Nd,
Rb, Sb, Sc, Se, Sm, Sn, Ta, Th, Tb, U, W and Yb. The remaining elements are determined by the 4 acid ICP (Code 1F above) technique.
SiO2 is not analyzed due to volatilization. (0.75 - 35 g required depending on sample size you wish to be analyzed for Au).
Code 1H2 “Au+53” - This package is similar to Code 1H but also uses ICP/MS on an acid digest solution to obtain additional elements. If Au is
important, a larger sample size (up to 35 g) should be submitted.
Code ULTRATRACE-3 - This combines INAA, 4-acid digestion ICP and ICP/MS analysis to provide the most comprehensive
near total metal package available using an acid digestion. Note that this package is not suitable for chrondrite plots
as not all REE are quantitatively extracted from zircon, monazite, etc. (1.0 to 35 g of sample required).
Code ULTRATRACE-4 - Near total digestion employing an ICP/MS finish (0.5 g of sample required) This digestion may not be
completely total if resistate minerals are present. As, Sb and Cr may be partially volatilized.
Code ULTRATRACE-5 - Combines INAA with a 4-acid digestion (HF, HClO4, HNO3 and HCl) to attempt to give as total metal as is
possible with acids. Some of the resistate elements are provided by INAA.
Code ULTRATRACE-6 - Combines the 4-acid digestion (HF, HClO4, HNO3 and HCl) with analysis by ICP and ICP/MS. Resistate minerals are
not digested.
Code ULTRATRACE-7 - Combines a sodium peroxide Fusion with ICP and ICP/MS. All metals are solubilized
ICP+ICP/MS ICP+ICP/MS
Ultratrace 6 Ultratrace 7
Ag 0.05 10
Al 0.01% 0.01%
As 0.1 5
B 10
Ba 1 3
Be 0.1 3
Bi 0.02 2
Ca 0.01% 0.01%
Cd 0.1 2
Ce 0.1 0.8
Co 0.1 0.2
Cr 0.5 30
Cs 0.05 0.1
Cu 0.2 2
Dy 0.1 0.3
Er 0.1 0.1
Eu 0.05 0.1
Fe 0.01% 0.05%
Ga 0.1 0.2
Gd 0.1 0.1
Ge 0.1 0.7
Hf 0.1 10
Ho 0.1 0.2
In 0.1 0.2
K 0.01% 0.1%
La 0.1 0.4
Li 0.5 3
Lu 0.1
Mg 0.01% 0.01%
Mn 1 3
Mo 0.1 1
Na 0.001%
Nb 0.1 2
Nd 0.1 0.4
Ni 0.5 10
P 0.001% 0.005%
Pb 0.5 0.8
Pr 0.1 0.1
Rb 0.2 0.4
Re 0.001
S 0.01% 0.01%
Sb 0.1 2
Sc 1
Se 0.1 0.8
Si 0.01%
Sm 0.1 0.1
Sn 1 0.5
Sr 0.2 3
Ta 0.1 0.2
Tb 0.1 0.1
Te 0.1 6
Th 0.1 0.1
Tl 0.05 0.1
Ti 0.0005% 0.01%
Tm 0.1 0.1
U 0.1 0.1
V 1 5
W 0.1 0.7
Y 0.1 0.1
Yb 0.1 0.1
Zn 0.2 30
Zr 1
Price €29.25 €33.00
Total Digestion Na-Peroxide
PAGE 15
Lithogeochemistry for Exploration and ResearchAll elements are in ppm except where noted.
XRF
INAA INAA WRA-ICP Trace Element WRA+trace Trace Element WRA+trace WRA-XRF XRF pressed pellet
Code 4A-expl 4A-research 4B 4B2-std 4Litho 4B2 -research 4Lithoresearch 4C 4C Laterite 4C1
Al2O3 0.01% 0.01% 0.01% 0.01% 0.01%
CaO 0.01% 0.01% 0.01% 0.01% 0.01%
Cr2O3 0.01% 0.01%
Co3O4 0.01%
CuO 0.01%
Fe2O3 0.01% 0.01% 0.01% 0.01% 0.01%
K2O 0.01% 0.01% 0.01% 0.01% 0.01%
MgO 0.01% 0.01% 0.01% 0.01% 0.01%
MnO 0.001% 0.001% 0.001% 0.001% 0.01%
Na2O 0.01% 0.01% 0.01% 0.01% 0.01%
NiO 0.01%
P2O5 0.01% 0.01% 0.01% 0.01% 0.01%
SiO2 0.01% 0.01% 0.01% 0.01% 0.01%
TiO2 0.001% 0.001% 0.001% 0.01% 0.01%
V2O5 0.003% 0.003%
LOI 0.01% 0.01% 0.01% 0.01% 0.01%
Ag 5 2 (0.5+) 0.5 0.5 0.5 0.5
As 2 1 (0.5++) 5 (0.5++) 5 (0.5++) 5 (0.5++) 5 (0.5++)
Au 5 ppb 2 ppb (2 ppb++) (2 ppb++) (2 ppb++) (2 ppb++) (2 ppb++)
Ba 100 20 3 3 3 3 3 5*
Be 1 1 1
Bi (10+) 0.4 0.4 0.1 0.1
Br 1 0.5 (0.5++) (0.5++) (0.5++) (0.5++) (0.5++)
Ca 0.5% 0.2%
Cd (0.5+) (0.5+) (0.5+) (0.5+) (0.5+)
Co 1 0.1 (1++) 1 1 1 1 5**
Cr 2 0.5 (5++) 20 (5++) 20 (5++) 20 (5++) 20 (5++) 5**
Cs 0.5 0.2 (1++) 0.5 0.5 0.1 0.1
Cu (1+) 10 (1+) 10 (1+) 10 (1+) 10 (1+) 5**
Fe 0.02% 0.005% (0.01%++) (0.01%++)
Ga 1 1 1 1 5*
Ge 1 1 0.5 0.5
Hf 0.5 0.2 (1++) 0.2 0.2 0.1 0.1
In 0.2 0.2 0.1 0.1
Ir 5 ppb 2 ppb (5 ppb++) (5 ppb++) (5 ppb++) (5 ppb++) (5 ppb++)
Mo 5 2 (5++) 2 2 2 2
Na 0.01% 0.001% (0.01%++) (0.01%++)
Nb 1 1 0.2 0.2 1*
Ni 100 50 (1+) 20 (1+) 20 (1+) 20 (1+) 20 (1+) 4**
Pb (5+) 5 5 5 5 5**
Rb 20 10 (20++) 2 2 1 1 2*
S (100+) (100+) (100+) (100+) (100+)
Sb 0.2 0.1 (0.2++) 0.5 (0.2++) 0.5 (0.2++) 0.2 0.2
Sc 0.1 0.01 1 (0.1++) 1 (0.1++) (0.1++) 1 (0.1++)
Se 3 0.5 (3++) (3++) (3++) (3++) (3++)
Sn 1 1 1 1 5
Sr 500 100 2 2 2 2 2 2*
Ta 1 0.3 (0.5++) 0.1 0.1 0.01 0.01
Th 0.5 0.1 (0.2++) 0.1 0.1 0.05 0.05
Tl 0.1 0.1 0.05 0.05
U 0.5 0.1 (0.5++) 0.1 0.1 0.01 0.01
V 5 5 5 5 5 5 **
W 3 1 (1++) 1 1 0.5 0.5
Y 2 1 2 0.5 0.5 2*
Zn 40 10 (1+) 30 (1+) 30 (1+) 30 (1+) 30 (1+) 5**
Zr 4 5 4 1 1 5*
La 0.2 0.05 (0.5++) 0.1 0.1 0.05 0.05
Ce 3 1 (3++) 0.1 0.1 0.05 0.05
Pr (†0.01 ) 0.05 0.05 0.01 0.01
Nd 5 1 (5++) 0.1 0.1 0.05 0.05
Sm 0.1 0.01 (0.1++) 0.1 0.1 0.01 0.01
Eu 0.1 0.05 (0.2++) 0.05 0.05 0.005 0.005
Gd (†0.01 ) 0.1 0.1 0.01 0.01
Tb 0.5 0.1 (0.5++) 0.1 0.1 0.01 0.01
Dy (†0.01 ) 0.1 0.1 0.01 0.01
Ho (†0.01 ) 0.1 0.1 0.01 0.01
Er (†0.01 ) 0.1 0.1 0.01 0.01
Tm (†0.01 ) 0.05 0.05 0.005 0.005
Yb 0.1 0.05 (0.2++) 0.1 0.1 0.01 0.01
Lu 0.05 0.01 (0.05++) 0.01 0.04 0.002 0.002
1-10 samples €25.00 €57.25 €33.50 €47.75 €65.00 €76.50 €92.50 €34.50 €42.00 See Code 4C1
11+ samples €23.00 €54.50 €29.00 €43.00 €55.50 €67.00 €78.50 €30.00 €37.00 adjacent page
(†) Optionalelements, seeCode 4A
(++) Optionalelements by INAA,Code 4BINAA
(+) Optionalelements bymultiacid digestionICP, Code 4B1
PAGE 16
Notes:
Code 4A - Both the exploration and research grades are determined by INAA.
A minimum sample weight of 2 g is recommended. REE chondrite plots are
provided at no charge with the research grade or at €1.50 per sample for the
exploration grade. For elements indicated with † (Code 4A RES/MS) by fusion
ICP/MS, add €27.00.
Codes 4B, 4B2-STD, 4B2-RESEARCH, 4LITHO, 4LITHORESEARCH - Actlabs has
developed a lithium metaborate/tetraborate fusion ICP Whole Rock Package Code
4B and a trace element ICP/MS package Code 4B2 which is unique for scope of
elements and detection limits. The two packages are combined for Code 4Litho
and Code 4Lithoresearch. The quality of whole rock data in Code 4B meets or
exceeds quality of data by fusion XRF Code 4C, the old standard in whole rock
analysis. The fusion process ensures total metals particularly for elements like REE
in resistate phases. (This may not be the case for acid digestions, particularly for
heavy rare earths and other elements contained in refractory minerals like zircon,
sphene, monazite, chromite, gahnite and several other phases. If refractory
minerals are not digested, a bias may occur for certain REE and HFSE with acid
digestions). Quality of data is exceptional and can be used for the most exacting
applications. The trace element package by ICP/MS, Codes 4B2-STD or 4B2-
RESEARCH, on the fusion solution provides research quality data whether using
standard or research detection limits. Eu determinations are semiquantitative in
samples having extremely high Ba concentrations (greater than 1%). This
package is intended primarily for unmineralized samples. Mineralized samples canbe analyzed, however, data may be semiquantitative for chalcophile elements (Ag,As, Bi, Co, Cu, Mo, Ni, Pb, Sb, Sn, W and Zn). When quantitative values for thechalcophile elements are required on mineralized samples, please indicate asCode 4B2-STDQUANT, 4B2-RESEARCHQUANT, 4LITHOQUANT or4LITHORESEARCHQUANT, and a surcharge of €20.50 per sample will apply. Aminimum sample weight of 5 g is required. Elements with (+) are available (Code
4B1) for an additional €8.25 per sample. Those indicated with (++) are available
by INAA (Code 4B-INAA) for an additional €14.75 per sample. Please add 0.5
to 30 g depending on sample size you prefer to analyze for Au with this option.
Values on replicates and standards are provided at no cost, as are REE plots.
Code 4C, 4C Laterite - The tried and true fusion XRF whole rock package. Samples
containing high barite or high sulphide (greater than 1%) should be analyzed with
Code 4B. A minimum sample weight of 3 g is required. We reserve the right to
change analytical method to Code 4B if required by the sample composition.
Code 4C1 - This XRF pressed pellet method requires a minimum sample weight of 6 g.
The XRF pressed pellet method is only suitable for low metal content of below
1% for each element listed.
Prices: 1st element - €9.75; each additional - €3.50; ** lot - €17.50; * lot -
€17.50. Each element not in * or **, add €3.50 per element.
Code 4E - This unique package uses ICP, INAA, ICP/MS and XRF technologies to
completely characterize geological samples. Two different grades of analysis
(exploration and research) are provided depending upon your requirements.
This package is not suitable for analyzing concentrates or mill products. A
minimum sample weight of 5 g is required).
Code 4E Options
• Ga, Pb, Sn, Nb and Rb (Code 4E-XRF) indicated by (***) by Pressed Pellet XRF
add €17.50. This package can be added to Code 4E exploration or Code 4E
research (please add 6 g of sample).
• The Code 4E ICP/MS add-on option (detection limits indicated by +++) can only
be added to Code 4E research grade at an additional cost of €29.00.
• Any selections from Code 4F can be added to Code 4E exploration or research
Code 4F - Other analyses associated with WRA (can be added to any
Code 4 package). Add 1 gram for each option chosen.
FeO (0.1%) by Titration €14.75 CO2 (0.01%) by Coulometry €14.75
S (0.01%) by Infrared €14.75 H2O +/- (0.1%) by Gravimetric €19.25
SO4 (0.3%) by Infrared €19.25 C, S (0.01%) by Infrared €19.25
Cl (0.01%) by INAA €21.25 B (0.5 ppm) by PGNAA €27.00
Hg by Cold Vapour FIMS €7.50 B (2 ppm) by PGNAA €17.50
F (0.01%) by ISE €12.00 N (total) Thermal Conductivity €33.50
Lithogeochemistry for Exploration and Research
Total IDENT Total IDENT
Code 4E-expl. Code 4E-research
Al2O3 0.01% 0.01%
CaO 0.01% 0.01%
SiO2 0.01% 0.01%
Fe2O3 0.01% 0.01%
K2O 0.01% 0.01%
TiO2 0.005% 0.005%
MgO 0.01% 0.01%
MnO 0.01% 0.01%
Na2O 0.01% 0.01%
P2O5 0.01% 0.01%
LOI 0.01% 0.01%
Ag 0.5 0.5
As 2 1
Au 5 ppb 1 ppb
Ba 3 1
Be 1 1
Bi 10 10 (0.1+++)
Br 1 0.5
Cd 0.5 0.5
Co 1 0.1
Cr 1 0.5
Cs 0.5 0.2 (0.1+++)
Cu 1 1
Ga (5***) (5***) (1+++)
Ge (0.5+++)
Hf 0.5 0.2 (0.1+++)
In (0.1+++)
Ir 5 ppb 1 ppb
Mo 5 2
Nb (2***) (2***) (0.2+++)
Ni 1 1
Pb 5 5
Rb 20 (2***) 10 (2***) (1+++)
Sb 0.2 0.1
Sc 0.1 0.01
Se 3 0.5
Sn (5***) (5***) (1+++)
Sr 2 2
Ta 1 0.3 (0.01+++)
Th 0.5 0.1 (0.05+++)
Tl (0.05+++)
U 0.5 0.1 (0.01+++)
V 5 5
W 3 1
Y 1 1
Zn 1 1
Zr 4 4 (1+++)
La 0.5 0.05 (0.05+++)
Ce 3 1 (0.05+++)
Pr (0.01+++)
Nd 5 1 (0.05+++)
Sm 0.1 0.01
Eu 0.1 0.05 (0.005+++)
Gd (0.01+++)
Tb 0.5 0.1 (0.01+++)
Dy (0.01+++)
Ho (0.01+++)
Er (0.01+++)
Tm (0.005+++)
Yb 0.1 0.05 (0.01+++)
Lu 0.05 0.01 (0.002+++)
# Samples
1-10 €46.75 €103.25
11+ €43.00 €95.25
PAGE 17
Code 2A - HumusCode 2B - Vegetation
INAA provides a very cost effective,rapid means of analyzing humus orvegetation to very low detection limitsfor gold and many other elementsuseful for geochemical exploration.The organic material is dried below60°C, macerated and a 15 g aliquot iscompressed into a briquette andanalyzed using Code 2A or Code 2Bdepending on whether the material ispurely organic (Code 2B) or containsmineral matter (Code 2A). Thesebriquettes are irradiated and theirgamma ray spectra are measured andquantified. The advantages of thistechnique are simplicity (less chanceof human error and contamination,ashing is costly and the results in lossof gold) and INAA is the techniquewith ultimate sensitivity for gold andother trace elements. Prices listed inCodes 2A and 2B are for standard 15g briquettes. Selected elements maybe available at lower costs.
Code 2C - Vegetation Ash INAACode 2C1 - Vegetation Ash-ICP/OESCode 2D - Vegetation Ash-ICP/MS
Some geologists prefer ashingsamples at low temperature (480°C)and determining metals on the ash.This may be advantageous,particularly if base metals are alsorequired for your gold project or forbase metal exploration. Note whensamples are ashed, there may bevolatile loss of certain elements (Au, As, Br, Hg, Cd, etc). Results arereported on an ash weight basis.Code 2D uses a proprietary aciddigestion on the ash followed byICP/MS and extends the list ofelements which are available. Not allelements may be total. This packagecan be quite useful for diamondexploration. Prices for Code 2C1 forsingle element is €5.00 with eachadditional element costing €2.25.
Code 2EThis package is similar to Code 2Dbut requires a different digestion of theplant ash to obtain Au, Pt and Pd tolow levels. This method has beenshown to be very effective for PGEexploration.
Code 2FDry vegetation samples are dissolvedin acid and analyzed by HighResolution ICP/MS.
Code 2F-PGEActlabs has developed a new packagecapable of detecting the PGE invegetation at the sub-ppb level bymicrowave digestion, ion exchangeand High Resolution ICP/MS. Thismethod eliminates interferences.
Actlabs only ashes vegetation indedicated vegetation ashing furnaces
to avoid contamination.
Biogeochemistry - Humus & Vegetation
Humus Vegetation Ash Base Metal Ash Package Ash Package Vegetation Vegetation
INAA INAA Package Vegetation Digestion ICP/MS Unashed Unashed
INAA Aqua Regia-ICP ICP/MS Au+Pt+Pd HR-ICP/MS
Code 2A Code 2B Code 2C Code 2C1 Code 2D Code 2E Code 2F (all ppb) Code 2F-PGE
Ag 2 0.2 2 0.2 0.2 0.2 1
Al 2 2
As 1 0.01 0.5 1 3 5
Au 1 ppb 0.1 ppb 5 ppb 5 ppb 0.1
B *(2) 5 5 200
Ba 100 5 50 3 3 1 ppm
Be 0.005 0.08 0.1
Bi 0.05 0.05 1
Br 1 0.01 1
Ca 0.5% 0.01% 0.2% 0.1% 0.1% 2 ppm
Cd 0.01 0.01 0.1
Ce 1 0.1 3 0.01 0.01 0.5
Co 1 0.1 1 0.01 0.01 0.5
Cr 1 0.3 1 1 10 10
Cs 0.5 0.05 0.5 0.001 0.001 0.1
Cu 1 0.2 0.2 20
Dy 0.001 0.001 0.05
Er 0.001 0.001 0.05
Eu 0.2 0.05 0.01 0.001 0.001 0.1
Fe 0.05% 0.005% 0.05% 0.01% 0.01% 0.5 ppm
Ga 0.1 0.1 0.5
Gd 0.01 0.01 1
Ge 0.1 0.1 10
Hf 0.5 0.05 0.5 0.01 0.01 2
Hg 0.5 0.05 1 5
Ho 0.001 0.001 0.01
In 1 ppb 1 ppb 0.1
Ir 5 ppb 0.1 ppb 2 ppb 0.2 ppb
K 0.01% 0.05% 0.01% 0.01% 10 ppm
La 0.1 0.01 0.1 0.002 0.002 0.2
Li 0.5 0.5 5
Lu 0.1 0.001 0.05 0.001 0.001 0.2
Mg 0.01% 0.01% 0.5 ppm
Mn 1 0.1 0.1 10
Mo 0.5 0.05 2 1 0.1 0.1 1
Na 100 1 10 0.01% 0.01% 10 ppm
Nb 0.005 0.005 0.5
Nd 3 0.3 5 0.002 0.002 0.2
Ni 10 2 50 1 5 5 0.1 ppm
Pb 1 0.1 0.1 10
Pr 0.002 0.002 0.5
Pt 2 ppb 0.2 ppb
Pd 3 ppb 0.1 ppb
Rb 20 1 5 0.01 0.01 10
Re 0.1 ppb 0.1 ppb 0.1
Rh 0.1 ppb
Ru 10 ppb 0.2 ppb
Sb 0.1 0.005 0.1 0.02 0.02 0.2
Sc 0.1 0.01 0.1 0.5 0.5 1
Se 2 0.1 2 1 10 0.2 ppm
Si 0.2% 0.2%
Sm 0.1 0.001 0.1 0.001 0.001 0.1
Sn 1 40
Sr 100 10 300 0.1 0.1 20
Ta 0.5 0.05 0.5 0.001 0.001 0.1
Tb 0.2 0.1 0.5 0.001 0.001 0.02
Te 0.01 0.01 1
Th 0.5 0.1 0.1 0.001 0.001 5
Ti 1 1 20
Tl 0.001 0.001 0.5
Tm 0.001 0.001 0.05
U 0.1 0.01 0.1 0.001 0.001 1
V 1 10 10
W 1 0.05 1 0.5 0.5 5
Y 0.001 0.001 0.2
Yb 0.1 0.005 0.05 0.001 0.001 0.4
Zn 20 2 50 1 1 1 0.2 ppm
Zr 0.5 0.5 5
Price €16.00 €18.75 €17.05 €9.50 €23.25 €29.00 €53.75 €100.25
All elements are in ppm except where noted and Code 2F and Code 2F-PGE which are in ppb, except where noted.
PAGE 18
Heavy Mineral Concentrates
Why HMC?
Heavy minerals can be concentrated from glacial till
samples or from stream sediments. The theory behind
the use of heavy mineral concentrates relies on the fact
that by concentrating the heavy mineral fraction from the
sample, the dilutant light minerals which may obscure an
anomaly derived from a deposit are eliminated, providing
a clearer picture. This allows the minerals to be
examined under a binocular microscope, SEM or
electron microprobe for particle shape or composition.
Particle shape of gold grains will commonly identify
distance to source. Very abraded grains may have
travelled a good distance whereas delicate grains are
probably more local. Similarly for diamond exploration,
the presence of certain mineral phases may indicate
distance to source kimberlites. Bulk analysis of heavy
minerals provides a rapid, low cost method to screen
large volumes of samples. Samples with appropriate
chemistry can then be further evaluated as the INAA
technique is non-destructive.
Heavy mineral concentrates are usually prepared by
tabling or wet sieving a very large sample of till or
stream sediments (up to 20 kg may be routine). The
heavy mineral concentrate collected at this stage is then
further processed with heavy liquids using
methylene iodide (SG = 3.3). The resultant concentrate
then is separated into magnetic and non-magnetic
fractions and it is the non-magnetic fraction which is
usually analyzed. In some cases more elaborate
separations include separating paramagnetic fractions
and sieving to various particle sizes before analysis.
This may provide further insight into identifying the
source of the heavy minerals. Both gold and diamond
mines have been discovered using this technology.
HMC Thermal HMC Base Metals
Code 3A Code 3C
Ag 5 0.2
As 2
Au 5 ppb
Ba 200
Br 5
Ca 1%
Cd 0.5
Ce 3
Co 5
Cr 10
Cs 2
Cu 1
Eu 0.2
Fe 0.02%
Hf 1
Hg 5
Ir 50 ppb
La 1
Lu 0.05
Mn 2
Mo 20 2
Na 0.05%
Nd 10
Ni 200 1
Pb 2
Rb 50
S 100
Sb 0.2
Sc 0.1
Se 20
Sm 0.1
Sr 0.2%
Ta 1
Tb 2
Th 0.5
U 0.5
W 4
Yb 0.2
Zn 200 1
All elements are in ppm except where noted.
Code 3A - Heavy Mineral Concentrates
(Thermal Irradiation)
Heavy mineral concentrates prepared from reverse
circulation drilling samples or from panned concentrates
are expensive to collect. The nugget effect may require
that the entire sample be analyzed to ensure that the few
particles of gold which may be present can be measured.
With INAA the whole concentrate can be analyzed without
grinding the samples. The sample is therefore preserved
for other chemical or mineralogical work. Actlabs only
irradiates with thermal neutrons so as to avoid low gold
values due to self shielding effects from irradiation with
epithermal neutrons. The price varies depending on the
volume of concentrate to be analyzed. There are 3 vial
sizes available: small (2 g), medium (20 g) or large (60 g).
Actual weight may vary depending on mineralogy.
Code 3C - HMC Base Metals by Aqua Regia ICP
When the analyses by INAA are completed, the sample is
available to determine additional elements by other
analytical techniques. Code 3C is a frequently requested
Aqua Regia extraction ICP/OES package (0.5 g required).
First element price for Code 3C is €5.00 with each
additional element costing €2.25. Code 3C may
require the sample to be pulverized finer, if coarser than
80 mesh, (+175 micron) at an additional cost.
Prices:
Small vial (2 g) €16.00 €9.50
Medium vial (20 g) €18.00
Large vial (60 g) €21.50
PAGE 19
PAGE 20
Code 6 is applicable only to natural waters with low total dissolved solid content (<0.05%). We must reanalyze samples with >25ppm
Na, K and Sr and >100 ppm of Ca, Mg and Si if quantitative numbers are required for these elements (Code 6-ICP/OES Overrange -
€16.50). Any individual cations greater than the limit above will be reported as (>) unless the ICP/OES option is chosen. Samples
submitted under all Code 6 packages (with exception of Code 6 Dissolved and Code 6 Total Recoverable mentioned below) will be
analyzed on the supernatant portion of waters as received, acidified to pH <2 without filtration or digestion. The Code 6 Dissolved
package includes filtration with 0.45µ filters while the Code 6 Total Recoverable Natural Waters package include water digestion
according to EPA protocols. Samples will be analyzed on the supernatant portion of waters as received, acidified to pH <2 without
filtration. Analysis of waste waters and other solutions are available, but at varying costs. Please inquire. Samples submitted as
natural waters, but with elevated total dissolved solids (TDS >0.05%) will be charged as marine waters. Waters from experimental
studies should be analyzed as Code 6 EXPER. Detection limits for samples with high dissolved solids such as marine waters or
brines, may be elevated by a factor of 10-1000†.
ACTLABS has a High Resolution Magnetic Sector ICP/MS (Finnegan Mat ELEMENT 2). This instrument allows detection of
most elements one to two orders of magnitude lower than conventional quadrupole ICP/MS. In addition, use of high resolution
technology eliminates most interferences. Code 6 HR-ICP/MS provides better detection limits than Code 6 ICP/MS. Other
elements are also available with 1-2 orders of magnitude lower detection limits than Code 6 ICP/MS. Many elements can be
analyzed on brines to low detection limits by eliminating the matrix. This is indicated as Code 6 Ion exchange. Please inquire.
HydrogeochemistryAll detection limits are in µg/L except where noted.
PGE Au
ICP/MS ICP/OES HR-ICP/MS HR-ICP/MS HR-ICP/MS
Ag 0.2 5 0.002
Al 2 0.1 mg/L 0.5
As 0.03 30 0.02
Au 0.1 ng/L
B 1 ** 0.1
Ba 0.1 20 0.01
Be 0.1 2 0.001
Bi 0.3 20 0.001
Ca 700 0.1 mg/L 5
Cd 0.01 2 0.001
Ce 0.001 30 0.001
Co 0.005 2 0.001
Cr 0.5 20 0.01
Cs 0.001 0.001
Cu 0.2 2 0.05
Dy 0.001 0.0005
Er 0.001 0.00005
Eu 0.001 0.00005
Fe 10 0.01 mg/L 1
Ga 0.01 0.001
Gd 0.001 0.00005
Ge 0.01 0.001
Hf 0.001 0.00005
Hg (0.006+) 0.05
Ho 0.001 0.00001
In 0.001 0.0001
Ir 1 ng/L
K 30 0.1 mg/L 1
La 0.001 0.001
Li 1 0.05 mg/L 0.05
Lu 0.001 0.00005
Mg 2 0.1 mg/L 0.2
Mn 0.1 0.01 mg/L 0.05
Mo 0.1 5 0.005
Na 5 0.1 mg/L 5
PGE Au
ICP/MS ICP/OES HR-ICP/MS HR-ICP/MS HR-ICP/MS
Nb 0.005 0.0001
Nd 0.001 0.0001
Ni 0.3 5 0.05
Os 0.002
P 0.02 mg/L
Pb 0.01 10 0.005
Pr 0.001 0.00005
Pd 1 ng/L
Pt 0.5 ng/L
Rb 0.005 0.005
Re 0.0001
Rh 0.5 ng/L
Ru 3
S 1 mg/L
Sb 0.01 10 0.001
Sc 1 0.01
Se 0.2 20 5
Si 200 0.1 mg/L
Sm 0.001 0.0005
Sn 0.1 10 0.01
Sr 0.04 10 0.01
Ta 0.001 0.0005
Tb 0.001 0.00002
Te 0.1 10 0.001
Th 0.001 0.00002
Ti 0.1 10 0.01
Tl 0.001 10 0.0001
Tm 0.001 0.0001
U 0.001 0.05 mg/L 0.0001
V 0.1 10 0.001
W 0.02 10 0.001
Y 0.003 10 0.0005
Yb 0.001 0.00005
Zn 0.5 5 0.5
Zr 0.01 0.001
** Optional element
+ Hg - cold vapour - FIMS
Detection Limit
Analyte (mg/L)
Fluoride (F) 0.01
Chloride (Cl) 0.03
Bromide (Br) 0.03
Nitrite (NO2) 0.01
Nitrate (NO3) 0.01
Phosphate (PO4) 0.02
Sulphate (SO4) 0.03
First analyte €21.25
Each additional €14.75
All analytes €52.50
Code 6B - Ion Chromatography
Code 6C
pH €6.50
Total Suspended Solids (TSS) €19.25
Total Dissolved Solids (TDS) €17.50
Conductivity €6.50
Salinity €17.50
Acidity €17.50
Turbidity €9.75
Oil and Grease (Total) €47.75
Oil and Grease (Mineral) €33.50
Oil and Grease (Vegetable) €33.50
Reactive Silica €19.25
Total Phosphorous €14.75
NH3 + NH4 €29.00
Colour €14.75
Ra-226 €119.25
Perchlorate (EPA 331.0) €190.50
Code 6 - Hydrogeochemistry
Code 6 - Natural Waters with low TDS (<0.05%) 1-50 samples as received €37.50
Code 6 - Natural Waters with low TDS (<0.05%) 51+ samples as received €32.50
Code 6 - Total Recoverable Natural Waters with low TDS (<0.05%) 1-50 samples €53.75
Code 6 - Total Recoverable Natural Waters with low TDS (<0.05%) 51+ samples €49.00
Code 6 - Dissolved Natural Waters with low TDS (<0.05%) 1-50 samples €53.75
Code 6 - Dissolved Natural Waters with low TDS (<0.05%) 51+ samples €49.00
†Code 6 MB - Marine Water, Brines or other aqueous solutions with TDS > 0.05% €64.25
Code 6 ICP/OES Overrange - Overrange elements reanalyzed by ICP/OES add €16.50
Code 6 ICP/OES - Hydrogeochemistry ICP/OES for 36 elements €21.25
Code 6 Hg - Hg(+) option on separate sample by FIMS add €20.50
Code 6 Boron - Boron add-on by ICP/MS add €6.00
Code 6 EXPER - Where % RSDs are required (1-4 elements only) €52.50
Code 6 ENVIR - Where Chain-of Custody for legal defense is required €67.00
Code 6 Ion Exchange - Separating base metals from brines €81.25
Code 6 INAA - Gold analysis by INAA on activated charcoal €36.75
Code 6 Au HR-ICP/MS - Au by High Resolution ICP/MS €52.50
Code 6 HR-ICP/MS - Water analysis by High Resolution ICP/MS €44.00
Code 6 PGE HR-ICP/MS - PGE by High Resolution ICP/MS €95.25
Code 6 Acidify - With ultrapure nitric to pH <2 €3.50
Hydrogeochemistry
Metal Speciation in Water
Our research activities over the last few years have allowed us to link the capillary electrophoresis and HPLC techniques to
conventional ICP/MS or High Resolution ICP/MS. Using as little as 5 µg/L of solution, we can conveniently speciate a number of
metals for their inorganic or organic metal species. This allows determination of a number of metal species sequentially. ACTLABS
can consult on the best ways to preserve samples for speciation analysis.
Pore Water Extraction (from sediment core) €95.25
As speciation (As3+, As5+, MMA, DMA, Arsenobetaine) €166.50
Sn speciation (Tripropylpentyl; Tributylpentyl; Dibutyldipentyl; Monobutyl,tripentyl; Monophenyl,tripentyl; Diphenyl,tripentyl; Triphenyl,tripentyl) On request
Fe Speciation (Fe3+, Fe2+) €90.50
Se Speciation (Se6+, Se4+, Se-Methionine, Se-Cystine) €166.50
Cr Speciation (Cr3+, Cr6+) €90.50
Note - Minimum of 10 samples.
Helpful Hints
The conventional method of preservation of water for analysis is 0.2% (2 mL/L) of concentrated ultra pure nitric acid. This may be inadequate in
alkaline environments. The acid should be added only after the sample has been collected, and not as precharged acid in bottles which may leach
metals from the bottle. When filling the bottle, it should be rinsed with the sample water twice before retaining the sample. It should then be acidified.
A test of pH using pH paper will indicate if the pH after acidification is adequate (pH 2). Depending on the sample composition, preservation with nitric
may invalidate Ag, As, Br and I analyses. Preservation with acetic acid should be used in that case, however acetic acid can invalidate results for Cr.
Some customers do not add any stabilizing agents, since this has the potential for adding trace contaminants to the samples and causing analytical
problems. A study conducted by the Geological Survey of Canada (GSC) has indicated that low cost, high-density screw cap polyethylene bottles
(rinsed with water) are best. We require 30 mL of water for analysis. Conventional wisdom recommends storage at 4ºC. Studies by the GSC
indicate that this may not be necessary where samples are acidified < pH 2. Samples for Hg should be preserved with 0.5% BrCl as the GSC study
indicates the conventional preservation method of K2Cr2O7 in 0.1% HNO3 may be inadequate to keep Hg in solution. We require 30 mL of water for
Hg. Do not freeze water as it will cause precipitation of some elements. Samples should be shipped to the lab as soon as possible for analysis.
Stability tests indicate most samples are stable for at least 30 days and can be stable for a year or more (British Columbia Geological Survey) even
when stored at room temperature. Gold unfortunately is not stable and will be adsorbed onto the sides of the bottle within a short period of time
(hours). Addition of activated charcoal sachets can collect the gold which can then be analyzed by INAA. Further information is available from
ACTLABS on request. Samples for ion chromatography should not be preserved at all. Code 6 HR-ICP/MS method removes these metals from the
plastic bottle and puts it back into solution for analysis directly by HR-ICP/MS.
Radioactivity (gross alpha-beta) €94.75
Hardness (must also do Code 6 ICP/OES) €9.75
Cyanide (Total CN) €29.00
Cyanide (Free CN) €29.00
Cyanide (Weak Acid Dissociable - WAD CN) €29.00
Total organic carbon (TOC) €29.00
Biological oxygen demand (BOD) €29.00
Chemical oxygen demand (COD) €29.00
Total kjeldahl nitrogen (TKN) €29.00
Total petroleum hydrocarbon (TPH) - heavy oil €76.50
Total petroleum hydrocarbon (TPH) - gas/diesel €95.25
Dissolved oxygen (DO) €24.00
Alkalinity (CaCO3) [includes carbonate (CO3) & bicarbonate (HCO3)] €17.50
Microbiology (E.coli, Total Coliforms, Fecal Coliforms, €33.50
Heterotrophic Plate Count)
BTEX (Benzene Toluene Ethylbenzene Xylene) €34.75
PAGE 21
PAGE 22
Soil Gas Hydrocarbons (SGH) Geochemistry
Sample Type and Survey Design: It is highly recommended that at least a minimum of 50 sample “locations” is used in a survey to obtain
enough samples into background areas on both sides of small targets (wet gas plays, Kimberlite pipes, Uranium Breccia pipes, veins, etc.).
More samples are recommended for large targets. SGH must have enough samples over both the target and background areas in order to
fully study the dispersion patterns or geochromatography of the SGH Pathfinder Classes of compounds. For the ideal survey we further
suggest that all samples be evenly spaced with about one-third of the samples over the target and one-third on each side of the target or into
background areas in order for SGH to be used for exploration.
SGH has been shown to be very robust to the use of different sample types even “within” the same survey or transect. It is far more
important to the interpretation to take a complete sample transect or grid than to skip samples due to different sample media. It is beneficial
to take a consistent type of samples when possible such as in colour and texture and from similar depth. It is suggested that the survey
design use evenly spaced samples from 15 metres to 200 metres and line spacing from 50 metres to 500 metres depending on the size and
type of target. A 4:1 ratio has shown excellent results. SGH can also be used in larger regional surveys. Individual samples taken at
significant distances from the main survey area to represent background are not of value in the SGH interpretation as SGH results are not
background subtracted. Samples should be “fist” sized (50-100 grams), can be drip dried in the field and do not need special preservation
for shipping.
SGH Price: €42.00 per sample. (Code SGH)
A minimum of 50 sample locations per target is required to obtain the best results.
Volume discounts may apply, please enquire.
Relative or UTM coordinates must accompany the samples when submitted.
Sample preparation charges are additional (Code S4). Sample disposal charges also apply.
This pricing includes an interpretation and an SGH Interpretation Report for your survey(s) against one SGH target template. Additional
interpretations for other target types can be made using the same SGH data at a price of €880.00 per survey. Requests for SGH
interpretations requiring the combination of multiple surveys from different submissions will be at a price of €880.00 per survey. The typical
turnaround time for SGH results, including the SGH interpretation report, is three weeks for one survey against one SGH target template.
For more information, please contact Mr. Dale Sutherland ([email protected]) or 1.905.648.9611 x 114.
• SGH is deep penetrating, detecting mineral targets at over 500 metres and petroleum targets at over 1000 metres in
depth to date. Relatively shallow targets of 10 metres can be delineated equally as well.
• SGH detects heavier, unique, and more robust hydrocarbon based compounds in the C5 to C17 carbon number range
and not the gaseous C1 to C4 hydrocarbons that the name implies. The SGH compounds provide a signature directly
related to bacteriological interaction with the target at depth. These unique and specific compounds have also been
selected to essentially eliminate interferences and effects of cultural activity.
• SGH can be conducted on a wide range of sample types, not just soils. Successful surveys have used soil from a
variety of horizons, as well as sand, humus, peat, till, submerged lake-bottom sediments and even snow. This flexibility
is vital in areas that are challenging to sample and ensures that none of the intended samples in a planned survey are
missed.
• SGH interpretation templates have been defined and include SGH Pathfinder Classes for Copper, Gold, Nickel, Zinc, and
Uranium targets; VMS, SEDEX, Polymetallic, IOCG and PGE based deposits, as well as for Kimberlites. SGH is also an
excellent geochemistry for petroleum based targets such as oil plays, wet gas, and coal. These general templates have
also been applicable to a wide variety of lithologies; e.g. sediment-hosted, massive-sulphide, epithermal, vein and
disseminated, porphyry, placer, and polymetallic type deposits.
• SGH is discriminating. This geochemistry has been said to be a “REDOX cell locator” but has also been proven to be
able to discriminate between ore-bearing vs barren conductors; between mineral targets and granitic or graphitic
magnetic anomalies.
• SGH has been directly linked to geophysical results such as from airborne magnetic surveys, and induced potential
surveys (e.g. IP, CSAMT).
• SGH is blind to the inorganic content of samples and thus does not reflect mobilized anomalies or any nugget effects.
• SGH has been thoroughly researched in three CAMIRO (Canadian Mining Industry Research Organization) projects as
well as projects conducted by Geoscience-BC; the Ontario Geological Survey (OGS); USGS; AMIRA; CSIRO; University
based projects; and individual company sponsored projects. These studies have demonstrated that SGH is capable of
providing clear, easily identifiable, target related anomalies even in surveys where no other geochemistry has been of
value.
• SGH results are delivered in an Excel spreadsheet accompanied by an SGH Interpretation Report (> 20 pages). The
report includes a comparative rating of your results against research over similar target types.
• SGH has been used successfully to discover several new, previously un-drilled mineral deposits.
This is an “organic” based geochemistry that has been researched and refined since 1996. It has been found to have a high level of
performance and success. A large number of clients that use SGH for the first time send in orientation surveys over known mineralization to
test this organic geochemistry. These clients have observed excellent correlation as 80% of them have returned as repeat clients and
submit larger exploration surveys. SGH is a dual purpose geochemistry as it locates and identifies the target at depth as a vertical
projection.
SGH has some unique and powerful traits such as:
PAGE 23
SGH Case Studies:
SGH Zinc Case Study SGH VMS Case Study
SGH Gold Case Study SGH Kimberlite Case Study
SGH Nickel Case Study SGH Copper-Nickel-PGE Case Study
SGH Rare-Earth Pegmatite Case Study SGH Copper Case Study
Many ore bodies are buried beneath thick sequences of exotic overburden, lake beds, barren
bedrock or younger volcanic rocks. Exploration geologists require a cost-effective method of
finding blind mineralisation through deep cover. Enzyme LeachSM, and TerraSolSM, and our other
selective extraction products provide the means to do this.
Enzyme Leach SM is one of the most discriminating of the selective analytical extractions in use
today. It is capable of detecting extremely subtle geochemical anomalies developed in B-horizon
soils over and around blind deposits. Conventional partial leaches, like aqua regia extraction-ICP,
extract metals from sulphides, oxides and silicates, providing a partial composition of the
overburden. Enzyme LeachSM on the other hand, tends to detect the very subtle trace element
signatures that have been added to the soil by elements migrating to the surface through a variety
of mechanisms. Trace amounts of amorphous mixed-oxide coatings in soil act as an effective
long-term integrating collector of this subtle flux of cations, anions and polar molecules passing
through the soil. By selectively removing the amorphous manganese dioxide from these coatings,
the mixed oxide coatings collapse, releasing trapped trace elements. Thus, Enzyme LeachSM
provides an effective method of detecting the most subtle signatures of blind deposits in the
subsurface without swamping the signal by dissolving the major components of the overburden.
At this time, the greatest depth of penetration for Enzyme LeachSM for a mineral deposit is greater
than 800 metres.
TerraSol SM is a more aggressive leach that attacks all components of amorphous mixed-oxide
coatings and certain crystalline iron and manganese oxides. TerraSolSM performs best over
shallower mineral deposits.
Pattern recognition is the key to proper interpretation of Enzyme LeachSM and TerraSolSM data,
since anomaly patterns can be different from conventional geochemical data. Selective
extractions have been shown to work effectively in both acidic and alkaline environments, and
have been used successfully in desert, tropical, glacial and permafrost terrains.
Preparation and AnalysisAfter B-horizon soil materials are collected, they are air dried or dried in special rooms kept below
40°C. It is imperative that the samples not be placed in drying ovens as it is impossible to
guarantee consistency of drying temperature even in temperature controlled ovens. Samples
then undergo the proprietary Enzyme LeachSM and TerraSolSM under rigidly controlled conditions.
The resultant solutions are analyzed by ICP/MS.
Code 7 majors is an option for those wishing data on major elements and S in the leach solution. The request for Code 7 MAJORS must be made atthe same time as the selective extraction. Detection limits shown in ppm.
Price: Code 7MAJ €7.00/sample
Add-ons: Final pH of leach solution €7.00
Conductivity of leach solution €7.00
pH and conductivity €10.50
Enzyme LeachSM Services
7 7EnhEL 7SaltEL 7TS
Enzyme Enhanced High TerraSolSM
LeachSM Enzyme Salt (ppb)
(ppb) LeachSM Samples
(ppb) (ppb)
Ag 0.2 0.1 0.2 300
As 1 0.1 5 40
Au 0.05 0.005 0.1 5
Ba 1 0.5 1 20
Be 2 0.1 20 20
Bi 0.8 0.5 1 1
Br 5 1 30 300
Cd 0.2 0.1 0.2 10
Ce 0.1 0.01 1 2
S.Q.Cl 2000 1000 3000 15000
Co 1 0.2 1 5
Cr 20 3 50 200
Cs 0.1 0.01 1 0.5
Cu 3 1 5 20
Dy 0.1 0.01 1 2
Er 0.1 0.01 1 2
Eu 0.1 0.01 1 0.5
Ga 1 0.3 1 5
Gd 0.1 0.01 1 20
Ge 0.5 0.05 1 2
Hf 0.1 0.01 1 1
S.Q.Hg 1 0.1 1 10
Ho 0.1 0.01 1 0.5
I 2 1 10
In 0.1 0.01 0.2 2
La 0.1 0.01 1 10
Li 2 0.5 10 500
Lu 0.1 0.01 1 0.5
Mn 1 0.4 10 100
Mo 1 0.1 1 5
Nb 1 0.1 1 0.2
Nd 0.1 0.01 1 6
Ni 3 1 5 100
Os 1 0.5 1 10
Pb 1 0.1 1 5
Pr 0.1 0.01 1 2
Pt 1 0.5 1 10
Pd 1 0.5 1 20
Rb 1 0.1 1 5
Re 0.01 0.005 0.1 0.5
Ru 1 0.5 1 10
Sb 0.1 0.01 1 2
S.Q.Sc 100 10 1000 300
Se 5 1 30 100
Sm 0.1 0.01 1 2
Sn 0.8 0.2 1 5
Sr 1 0.1 1 5
Ta 0.1 0.02 1 1
Tb 0.1 0.01 1 30
Te 1 0.5 1 60
Th 0.1 0.01 1 1
S.Q.Ti 100 10 1000 1000
Tl 0.1 0.005 1 40
Tm 0.1 0.01 1 1
U 0.1 0.01 1 0.5
V 1 0.1 5 100
W 1 0.1 1 10
Y 0.5 0.05 1 0.2
Yb 0.1 0.01 1 2
Zn 10 5 10 40
Zr 1 0.1 1 1
Price: €27.00 €33.50 €33.50 €27.00
Al 0.5Ca 0.5Fe 1K 5Mg 2Na 5S 10P 1
NOTE: If prewash is required, add €2.75 per sample.
For Humus samples, please add €3.50 per sample.
PAGE 24
PAGE 25
NEWNEW Bioleach Through years of research by ACTLABS supported by CAMIRO (Canadian Mineral
Research Organization) with our SGH technology, ACTLABS has proven that
microbiological processes are exceptionally important for the mobilization of metals from
a mineral deposit to the surface. The exact mobilization mechanisms are still under
debate however a wide variety of mechanisms including mobilization and fixation as a
result of redox conditions, migration as a gas, hydromorphic transport are some of the
most quoted possibilities. Specific bacteria feed off the redox cell established at the
mineral deposit. SGH provides a unique ability to identify the location of the redox cell
(The Use and Misuse of Soil Geochemistry in Mineral Exploration - Dr. Stewart Hamilton
OGS-2007 Powerpoint presentation).
Code 7 Bioleach 7 Bioleach-HR
Ag 0.2 0.3
As 0.5 6
Au 0.05 1
B 36
Ba 1 1
Be 0.07 0.1
Bi 0.1 0.04
Br 5 75
Ca 1
Cd 0.05 0.04
Ce 0.02 0.3
Co 0.1 0.1
S.Q.Cr 2 1
Cs 0.01 0.1
Cu 0.5 1
Dy 0.01 0.004
Er 0.01 0.003
Eu 0.01 0.004
Fe 15
Ga 0.1 0.1
Gd 0.03 0.004
Ge 0.05 0.1
Hf 0.04 0.01
S.Q.Hg 0.05 6
Ho 0.01 0.001
I 1 3
In 0.1 0.01
K 149
La 0.01 0.3
S.Q.Li 0.2 4
Lu 0.01 0.001
Mg 30
Mn 0.1 15
Mo 2 0.6
Nb 0.2 0.01
Nd 0.03 0.01
Ni 0.2 7
Os 1
Pb 0.1 0.4
Pr 0.01 0.004
Pt 0.5
Pd 0.5
Rb 0.1 0.7
Re 0.01 0.01
Ru 0.05
Sb 0.2 0.1
S.Q.Sc 0.5 1
Se 1 22
Sm 0.03 0.04
Sn 1
Sr 0.1 1
Ta 0.01 0.1
Tb 0.01 0.003
Te 1 0.1
Th 0.02 0.003
Ti 1
Tl 0.2 0.01
Tm 0.01 0.01
U 0.01 0.01
V 1 0.06
W 0.01 0.1
Y 0.02 0.04
Yb 0.02 0.007
Zn 2 60
Zr 0.5 0.1
Price: €24.50 €43.50
Code 7 Bioleach majors is an option for those wishing data on major elementsand S in the leach solution. The request for Code 7 BIOLEACH MAJORSmust be made at the same time as the selective extraction. Detection limitsshown in ppm.
Price: Code 7BIOLEACH MAJORS €7.00/sample
Add-ons: Final pH of leach solution €7.00
Conductivity of leach solution €7.00
pH and conductivity €10.50
Al 0.5Ca 0.5Fe 1K 5Mg 2S 10
ACTLABS new BIOLEACH technology has been designed
to digest remnant bacteria which will help to potentially
identify the metals associated with the SGH anomalies.
Bioleach-HR has also now been used very successfully in analysis of vegetation. The
very low detection limits are achievable using our High-Resolution ICP/MS technique.
All elements are in ppb.
Standard Reference MaterialsDo you always send control standards along with your samples to the lab?
Standard Reference Materials (SRM) of known elemental composition play an important roll in the
quality assurance (QA) of grass roots exploraiton programs and development projects. SRMs are
developed to meet measurement needs and as control samples. They provide a known, well
characterized entity to compare and evaluate laboratory anaysis results. Unfortunately not all
laboratory results are the same despite the fact they may be generated by the same analytical
method such as fire assay with an atomic absorption finish. There are variations to the technique
that each lab uses as well as a variety of calibration procedures which may lead to vastly different
results on your samples. Some of these differences include amount of litharge in the flux, the flux to
sample ratio, reuse of the same crucibles, age and state of repair of instrumentation, diligence of
analysts in calibration, age of standards, sample preparation, etc. Using hidden SRMs with values
only known to you on your standards provides an excellent means to judge accuracy and precision
of the labs you are using. This is critical for the QP to avoid future embarassment and undermine
confidence in results in the investor’s mind on the reliability of results.
In order to provide the exploration market with SRMs, Actlabs has developed a set of rigorous sample
preparation procedures. We can use natural soils, rock, ores or sediments collected by the client
from their project area so their matrix is matched (best case scenario on your samples). Samples
from 1 and up to 125 kg can be prepared as an SRM. The whole sample is dried at 60 degrees, then
is crushed, pulverized and screened with a #200 mesh stainless-steel sieve. The resulting pulp goes
through a blending step using a Stainless Steel V industrial blender. The blend is achieved by the
constant dividing and inter-meshing particle movement by the two connected cylinders. Inside the
blender is a high-speed agitator bar to thoroughly mix the sample. Each cylindrical leg has an access
cover for easy material loading and cleaning.
A homogeneity test will show that all elements in the mixture were distributed evenly within the
material. After results of the homogeneity testing are determined, the mixed material is packed in
plastic bottles or in sealed foil pouches under nitrogen (to prevent oxidation of sulphides).
Any suggested elements or group of elements can be certified. Actlabs can certify concentration of
elements by using any digestion you will use for your projects or for total metals. As we have perhaps
the most diverse lab with virtually all instrumentation including fire assay (nickel sulphide and lead),
atomic absorption, gravimetric, ICP, ICP/MS, HR-ICP/MS, XRF, INAA, CNHS analyzers and many
more, we can develop values or can go round robin to other labs to certify values.
Major, minor and trace elements can be determined, and the results will be tabulated together with
the analytical methods and the outline of sample treatment procedures as well as accepted limits for
the standards.
For more information, please call or email us with your request using Code 20-Std as a reference.
* * * * *
PAGE 26
Sequential Leaches
Sequential leaches can target specific soil or rock phases and allow a better
interpretation of the geochemical processes involved. There is a static and
dynamic approach to the leaching. With the static approach, a sample will
undergo sequentially a leaching process starting with the weakest leach to the
strongest leach with subsequent analysis of each of the leachates by ICP/MS.
Some of the potential leaches which can be combined sequentially include from
the weakest to the strongest:
Code 7 - Water A distilled water leach to extract the water soluble
component
Code 7 - Enhanced Selectively goes after amorphous Mn oxides
Enzyme Leach
Code 7 - Bioleach A leach proprietary to ACTLABS that has been
designed to extract dead bacterial remnants
Code 7 - Sodium Acetate For exchangeable cations adsorbed by clay and
Leach pH 5 elements co-precipitated with carbonates
Code 7 - Sodium 0.1M leach for elements adsorbed by organic
Pyrophosphate material (humic and fulvic components)
Leach
Code 7 - Hydroxylamine For amorphous Fe oxides and crystalline Mn
Leach cold oxides
Code 7 -Hydroxylamine For amorphous and crystalline Fe oxides and
Leach hot crystalline Mn oxides.
Code 7 - Aqua Regia Will leach sulphide species and clay minerals
Code 7 - Four Acid Will dissolve silicate remnant material remaining
Digestion
Price: €33.50 per leach chosen with a €166.50 setup charge per leach chosen
if there are under 10 samples.
The dynamic approach involves sequential leaching on a sample packed
column on-line with one leach following the other in close succession and then
graphically examining the leaches (costs are dependant on the required
protocol and number of leaches).
Sodium Sodium Sodium Hydro-
Pyro- Pyro- Acetate xylamine
phosphate phosphate Leach Leach
Leach HR-Leach (ppb) (ppb)
(ppb) (ppb)
Ag 500 8 5 10
As 300 160 30 40
Au 5 28 5 5
B 970
Ba 300 16 1000 50
Be 50 4 10 20
Bi 40 1 10 100
Br 300 2009 500 2000
Ca 20
Cd 20 1 10 5
Ce 40 8 3 2
Co 50 4 5 5
S.Q.Cr 500 24 100 5000
Cs 2 4 2 5
Cu 600 40 100 40
Dy 5 0.1 2 1
Er 1 0.1 1 1
Eu 5 0.1 1 0.5
Fe 400
Ga 20 4 10 5
Gd 5 0.1 1 1
Ge 300 4 5 10
Hf 5 0.4 2 5
S.Q.Hg 200 160 20 20
Ho 1 0.04 0.5 0.5
I 1000 80 100 200
In 2 0.4 1 0.5
K 4000
La 20 8 2 2
S.Q.Li 1000 120 100 50
Lu 1 0.04 0.5 0.5
Mg 800
Mn 300 400 100 40
Mo 40 16 20 20
Nb 20 0.4 1 0.5
Nd 20 0.4 2 2
Ni 1000 200 30 80
Os 100 100 100
Pb 1000 12 40 20
Pr 5 0.1 0.5 0.5
Pt 100 100 100
Pd 100 100 100
Rb 20 20 20 10
Re 1 0.4 0.5 0.5
Ru 100 100 100
Sb 20 4 5 5
S.Q.Sc 300 40 200 200
Se 700 600 600 200
Sm 10 1 2 2
Sn 24 10 100
Sr 100 40 100 100
Ta 3 2 1 0.5
Tb 1 0.1 1 0.5
Te 200 4 50 10
Th 100 0.1 1 0.5
S.Q.Ti 40 400 500
Tl 100 0.4 0.5 1
Tm 1 0.4 1 0.5
U 200 0.4 1 0.5
V 200 2 20 500
W 30 4 10 5
Y 10 1 1 0.5
Yb 2 0.2 3 0.5
Zn 1000 1600 2000 500
Zr 100 4 80 400
PAGE 27
XRD - X-Ray DiffractionMineralogy by Powder X-ray Diffraction (XRD) - Major Phases PresentPowder X-ray diffraction is one of the most powerful techniques for the identification of minerals in geological and industrial samples and the technique
of choice for: Whole rock mineral identification, Clay speciation, Identification of crystalline forms of silica - Alpha Quartz and Christobalite.
Mineral IdentificationMost Minerals are crystalline and therefore scatter X-rays in a regular, characteristic way dependant on their crystal structure. Each mineral producesa unique diffraction pattern and can be recognized from that pattern like a fingerprint.
Identification of minerals is made by comparing their diffraction patterns with a library of over 17,000 mineral patterns stored in the International Centre
for Diffraction Data (ICDD).
Detection limits depend on the sample. For geological material, it is estimated that the minerals present in less than 3% of the sample might not be
detected.
The samples for X-ray diffraction analysis are ground or milled to a fine powder and then hand pressed into the sample holder. Approximately 1 cm3 of
the material is sufficient for rock mineral analysis but smaller amounts can also be accommodated by using a low background holder.
Clay SpeciationX-ray diffraction, combined with dedicated sample preparation, is the most effective technique for precise identification of clay minerals.
For speciation, the clay fraction is separated from the whole rock sample and the clay is deposited on a substrate. Due to their plate morphology, clay
particles spontaneously orient themselves along the basal planes, thus reinforcing characteristic reflections and allowing preliminary identification of
the mineral group(s). The oriented clay sample is then treated in various ways: exposed to ethylene glycol, glycerol or heated, to identify the clay
minerals with precision. The swelling and non-swelling clays react differently to ethylene glycol; the swelling clays accommodate the glycol molecules
between the atomic layers with simultaneous increase in distances between the layers. Since the X-ray diffraction is very sensitive to changes in the
interlayer distances, shifts in the peak positions are observed in the swelling clays. Upon heating to various temperatures the layers collapse and the
peak positions change again. Since clays respond differently to these diagnostic treatments, they can be identified.
Our routine clay speciation includes: clay separation, examination of oriented dry clay fraction, ethylene glycol treatment, heating to 400°C, heating to
550°C, examination of random dry powder. If necessary, additional treatments can be performed at additional costs.
The amount of sample required for clay speciation depends on the amount of clay fraction present. Since several oriented mounts have to be
prepared, the required amount of sample is typically 10 - 15 g, or more. Unprepared samples are required.
Alpha QuartzThe quantification of crystalline silica phases (Alpha Quartz) in bulk samples is carried out as an extension of the usual quantitative XRD procedures(absorption correction, internal/external standard methods and whole pattern analysis) depending on the sample. Several grams of sample arerequired.
In cases where industrial applications may cause silica to become airborne, the samples are collected and analyzed on filter membranes, following the
guidelines of NIOSH 7500 or OSHA ID-142 Methods for respirable Alpha Quartz.
Determination of concentration of amorphous silica is performed following NIOSH Method 7501. The method uses the property that most amorphous
forms of silica transform to cristobalite with heat treatment at 1100°C or 1500°C. After firing, the sample is analyzed for cristobalite following steps
similar to Method 7500.
Code 9 Price
Mineral Identification (semi quantitative) €157.00
Mineral Identification (quantitative) - rietveld €216.25
Clay Speciation €442.25
Alpha Quartz €95.25
Mineral Identification + Clay Speciation €570.75
Laser Ablation - High Resolution ICP/MSActlabs now offers services using our New Wave Research 213 nanometer laser which is linked to our Thermo Finnigan-High Resolution ICP/MS.
Using our Super Cell, this provides the ultimate in sensitivity. The laser beam can analyze spots from 5 microns to 100 microns. Usually polished thin
sections or polished thin sections can be analyzed. Scans across sections can be run on a programmed grid pattern as well. A number of elements
can be scanned at the same time.
Some applications include: U/Th dating in Ziron from rim to core, Lead isotopic ratios in minerals, Analysis of trace elements in carbonate-rich matrices
such as mussel shells, otholites, etc., Evaluation of impurities in metal samples, Rare earth elements scan in minerals, Selective extraction analysis of
soils, Forensic analysis of plastics, ceramics, paint and glass, Analysis of metal contents in tree rings.
Electron Microprobe Analysis (EMPA)
Actlabs offers polished thin section preparation - €43.50
Analysis of selected material - on a per project basis.
Costs will be determined after consultation.
A mineral grain and
the scan over it.
Isotopic Analysis
Services Offered
CODE 10A - When submitting samples, please supply details on rock or mineral type and alteration.
Parameter Amt. Required Precision Price
Pb - Isotopic analysis by HR-ICP/MS (Pb >15ppm) (1-10 samples) ~ 1 g 0.4 - 0.5% €159.50Pb - Isotopic analysis by HR-ICP/MS (Pb >15ppm) (>10 samples) ~ 1 g 0.4 - 0.5% €121.00Pb - Isotopic analysis by TIMS ~ 1 g 0.1 - 0.2% €375.00Nd - Isotopic Analysis by TIMS ~ 1 g €375.00Sr - Isotopic Analysis by TIMS ~ 1 g €375.00Sm-Nd - Isotopic Analysis by TIMS ~ 1 g €511.50Rb-Sr - Isotopic Analysis by TIMS ~ 1 g €511.50Hg - Isotopic Analysis by multicollector ICP/MS ~ 1 g On requestδ13C – Graphite or Organic Material 1 mg C 0.2 ‰ €157.00δ13C and δ18O – Carbonates 1 mg C 0.2 ‰ €128.75δ13C and δ18O – Siderite, Magnesite, Dolomite 1 mg C 0.2 ‰ €157.00Nitrogen Isotopes - Organic Material €130.00Deuterium Isotopic Analysis – Water 20 ml 3.0 ‰ €152.50Deuterium Isotopic Analysis – Minerals 1 mg 0.2 ‰ €238.25δ18O – Water 20 mL 0.2 ‰ €133.75δ18O – Silicates 15 mg 0.3 ‰ €228.25δ18O – Sulphates 25 mg 0.3 ‰ €152.50δ18O – Organics 10 mg N 0.2 ‰ €166.50δ34S – Sulphate 10 mg 0.2 ‰ €95.25δ34S – Sulphate in water €152.50δ34S – Sulphide 5 mg 0.2 ‰ €95.25δ34S – Sulphide-bearing material which contains carbonate 100 mg 0.2 ‰ €133.50δ34S – Silicate rocks with contain sulphur €133.503H – Direct 20 mL 8.0 TU €133.503H – Enriched 1L 0.8 TU €356.753H – Accelerator Mass Spectrometry (AMS) €605.00
10 B - Analysis Description Price
K-Ar dating Rock fractions, clay fractions and separated minerals On request
(e.g., biotite, hornblende, sericite, K-feldspar, illite, glauconite, etc.)
K-Ar dating in duplicate Two independent measurements on one sample On request40Ar-39Ar step heating dating Rock fractions, clay fractions or separated minerals On request
(e.g., biotite, hornblende, sericite, K-feldspar, illite, glauconite, etc.)
U-Pb dating by TIMS Single grain analysis (e.g., zircon, monazite, titanite, apatite) On request
U-Pb isochron dating by SHRIMP Single grain analysis On request
Rb-Sr dating by TIMS Isochron dating whole rock and minerals On request
Sm-Nd dating by TIMS Isochron dating whole rock and minerals On request
Re-Os dating Re-Os dating On request
Petrographic description Includes thin section preparation On request
Mineral Separation Specific mineral phases are separated to provide best data for age dating On request
Geochronology
Advice concerning dating strategies and interpretation of data is provided, as required. Discounts may be applicable for large dating programs.
For more information, please contact Dr. Yakov Kapusta ([email protected]) or at (905) 648-9611.
CODE 10B - Ages of geological formations or secondary events (i.e. alteration or metamorphism) can be determined through using K-Ar,
(Ar-Ar), U-Pb, Rb-Sr or the Sm-Nd dating methods. These analytical procedures include several steps:
(i) dating method selection
(ii) sample collection
(iii) sample preparation, mineral separation and treatment
(iv) irradiation of the samples in a nuclear reactor for the Ar-Ar technique
(v) high precision determination of the concentration of the mother and daughter isotopes by TIMS
(thermal ionization mass spectrometry)
(vi) apparent age calculation and interpretation of the results
The dating strategy depends on the type of formation (magmatic, metamorphic or sedimentary), the sample composition and the age of the formation. The
concentration of the mother and the daughter isotopes, as well as the apparent age can be determined with high precision. In many cases, however, the
determined age may not be the real age of the geological event. The apparent age may be affected by the post-depositional or post-formation history of the
rocks. Natural contamination of chemical sediments with detrital material can also affect the results of dating of diagenesis.
There are some techniques and calculations which can "look through" the post formation event. These include isochron dating (K-Ar, U-Pb, Rb-Sr and Sm-
Nd) or the step heating Ar-Ar technique of the K-Ar method. In the Ar-Ar technique, the K and Ar are measured on the same sample aliquot. First the
sample is irradiated in a nuclear reactor, where fast neutrons convert some of the 39K to 39Ar. After irradiation, the Ar is released fractionally by incremental
heating. The result is a series of apparent ages from which useful information about the geologic history and the age of the sample can be inferred.
Specific techniques for dating clay fractions have also been developed.
Our geochronological services provide dating methods for all types of geological samples through use of modern analytical facilities. We can advise on
selecting the method of dating, sampling and interpretation of the data so that meaningful geological results are obtained.
For the dating of a monomineralic sample only tens of milligrams of sample are required. For rocks, a few hundred milligrams are typically used for analysis.
Size of the rock sample required will vary considerably for mineral separation depending on which minerals must be separated and the amount and type of
the accessory minerals present.
PAGE 28
Miscellaneous MethodsAll element are in ppm exept where noted.
Code 5G - Carbon & Sulphur/Metallurgical Balance Package
Element Detection Limit
C-Total 0.01% Price: €71.50/sample
C-Graphitic 0.05%
C-Organic 0.05%
CO2 0.01%
S 0.01%
SO4 0.3%
Enviromining
Code S9 Particle Size Analysis (Laser) €71.50
Code 11 - Acid/Base Accounting
Acid/Base Includes sulphur (total), Net NP, AP, NP and paste pH €71.50
Acid/Base Enhanced Includes sulphur (total), Net NP, AP, NP, paste pH, acid soluble sulphate and sulphide €90.50
Acid/Base Supreme Includes sulphur (total), sulphate (total and acid soluble), sulphide, CO2, paste pH, Net NP, AP and NP €100.25
Code 12 - Leachate Quality
Leachate Extraction Procedure SWEP, TCLP, EPA, MWEP (leach only for metals) €74.50
Leachate Analysis SWEP, TCLP, EPA (includes metals and Hg) €81.25
Leachate Extraction Procedure For Organics - please enquire for price for organic analysis €90.50
Code 13 - Vegetation Growth Potential
Gradation (% clay, % silt, % sand, % gravel) €57.25 N - NH3 €14.75
Paste pH €6.25 N - NH4 €14.75
Conductivity €12.00 N - NH4 + NH3 €22.50
Sodium adsorption (SAR) €71.50 Total Nitrogen (LECO) €14.75
Organic carbon (LECO) €24.00 Total Nitrogen - Nitrate KCl extractable €14.75
Meteoric Water Mobility Test On request S - Leach ICP €29.00
Humidity Cells On request K - Ammonium acetate leach €9.00
P - Sodium bicarbonate leach €9.00
Code 5 - Other Elements - INAA
1 g sample required.
Basic Improved
Code 5A Code 5B
As 2 1
Au 5 ppb 2 ppb
Ba 200 100
Br 2 0.5
Ce 5 3
Co 2 0.5
Cr 10 1
Cs 2 0.5
Eu 0.2 0.2
Fe 0.02% 0.01%
Hf 1 0.5
La 1 0.1
Lu 0.1 0.05
Mo 5 2
Na 500 100
Nd 10 5
Rb 50 20
Sb 0.2 0.1
Sc 0.5 0.1
Se 5 2
Sm 0.1 0.01
Ta 2 0.5
Th 1 0.1
U 2 0.2
W 5 2
Yb 0.5 0.2
Price: First element €11.50 €15.25
Each additional €2.25 €2.25
Code 5D - Elements & Specific Methods
Element Detection Limit Price
B-Total (PGNAA) 0.5 €27.00
B-Total (PGNAA) 2 €17.50
C-Total (Infrared) 0.01% €15.75
C-Graphitic (Infrared) 0.05% €24.00
C-Organic (Infrared) 0.05% €24.00
F (ISE) 100 €13.75
Li (“total” digestion) 1 €9.75
Sn (XRF) 5 €9.75
Tl (“total” digestion) 0.2 €9.75
U-Total (DNC) 0.1 €13.75
Code 5S - Short Lived Isotopes - INAA
Al 1
Br 5
Cl 100 Price:
Cu 100 First element €33.50
Dy 0.5 Each additional €6.00
Ga 10
I 0.5
In 0.1
Mg 0.05%
Mn 0.1
Na 50
Re 1
Ti 50
V 0.1
PAGE 29
PAGE 30
Li 6.94
1+13
Lithium
1.0
H 1.007
9
+11 Hyd
roge
n2.2
-1
IA1
12
(1c)
(2c) IIA Be 9.0122
+24 Be
ryllium
1.5
2
Na
22.99
+1 So
dium
0.9
113
Mg
24.305
+2 Mag
nesium1.4
12
K 39.098
+1 Potassium0.
7
194
Ca 40.078
+2 Ca
lcium1.0
20
Rb
85.468
+1 Rub
idium0.
7
37
5Sr 87.62
+2 Strontium1.0
38
Cs 132.91
+1 Ca
esium0.6
556
Ba 137.33
+2 Ba
rium
0.9
56
Fr 223
+1 Fran
cium
0.7
87*
7Ra
226
+2 Rad
ium0.9
88*
3 IIIB Sc 44.956
+3 Scan
dium1.3
21
Y88
.906
+3 Yt
trium1.2
39 +2
La 138.91
+3 Lantha
num1.1
57
Ac
227
+3 Actinium1.1
89*
Ti 47.867
+4 Titanium
1.5
22 +2
+3
Zr 91.224
+4 Zircon
ium1.4
40
Hf
178.49
+4 Hafnium
1.3
72
RRfff
261
+4
Rutherfordium
104
*
4 IVB
5 VB V
50.942
+5 Vana
dium1.6
23 +2
+4
+3
Nb
92.906
+5 Niobium
1.6
41 +3
Ta 180.95
+5 Tantalum
1.5
73
DDbbb
262
+5 Dub
nium
105
*
6 VIB Cr 51.996
Chromium1.6
24 +2
+6
+3
Mo
95.96
Molyb
denu
m1.8
42 +6+3
+5
+4
+2
W 183.84
Tung
sten
1.7
74 +6+3
+5
+4
+2
SSggg 266
+6
Seab
orgium
106
*
7VIIB Mn
54.938
Man
gane
se1.5
25 +2
+6
+4
+3
+7
TTccc+7
Techne
tium1.9
43*
98 Re
186.21
Rhe
nium
1.9
75 +7+3
+6
+4
+2
BBhhh 264
+7 Bo
hrium
107
*
8VIIIB
Fe 55.845
Iron
1.8
26 +3
+2
Ru
101.0
7
Ruthe
nium2.2
44 +8
+3
+6
+4
+2
Os
190.23
Osm
ium2.2
76 +8+3
+6
+4
+2
HHsss
270
Hassium
108
*
9 Co 58.933
Coba
lt1.8
27 +3
+2
Rh
102.91
Rho
dium2.2
45 +3
+4
+2
Ir192.22
Iridium
2.2
77 +6
+2
+4+3
MMttt
268
Meitnerium
109
*
10 Ni
58.693
Nicke
l1.8
28 +3
+2
Pd 106.42
Palladium2.2
46 +2
+4
Pt 195.08
Platinum
2.2
78 +4+2
DDsss
281
Darmstad
tium
110
*
IB11 Cu 63.546
Copp
er1.9
29 +2+1
Ag
107.87
Silver
1.9
47 +1
Au
196.97
Gold
2.4
79 +3+1
RRggg
272
Roe
ntge
nium
111
*
IIB12 Zn 65.38
Zinc
1.6
30 +2
Cd 112.41
Cadm
ium1.7
48 +2
Hg
200.59
Mercury1.9
80 +2+1
IIIA13 B 10.811
+35
Boron
2.0
Al
28.982
+313 Aluminium1.6
Ga
69.723
Gallium2.0
31 +3+1
+2
In 114.82
Indium
1.8
49 +3+1
+2
Tl 204.38
Thallium2.
0
81 +3
+1
IVA14 C 12.011
+46
Carbon
2.5
+2-4
(3c)
(4c) Si 28.086
+414
Silicium2.3
-4
Ge
72.64
+432 German
ium2.3
+2
Sn 118.71
+450
Tin
2.2
+2
Pb 207.2
Lead
2.4
82 +5
+2
VA15 N
-37
Nitrog
en
+1
+2
(1p3c)
+3
+4
+5
P 30.974
+515 Phosph
orou
s2.3
-3 +3
+4
As
74.922
+333
Arsen
ic2.3
+3 -5
Sb 121.7
6+351 Antim
ony2.
1
+3
+5
Bi 208.98
Bism
uth2.
1
83 +5
+3
VA15 14.007 2.9
+1
+2
(1p3c)
+3
VIA16 O 15.999
Oxyge
n3.4
-1 -2
(2p2c)
+28
S 32.065
+616
Sulphu
r2.7
-2 +2
+4
Se 78.96
+434 Se
lenium
2.5
-2 +6
+2
Te 127.60
+452 Telluriu
m2.4
-2 +6
+2
PoPo
lonium
2.1
84 +4+2
209
*
VIIA17 F 18.998
Fluo
rine3.
9-1
(3p1c)
9
Cl 35.453
+717
Chlore
3.1
-1 +1
+3
+5
Br 79.904
35
Brom
e3.0
-1 +1
+5
+7
I 126.90
+753
Iodine
2.7
-1 +1
+3
+5
At
+785
Astatine2.
5
-1 +1
+3
+5
210
*
VIIIA
18 He
4.00
26
2
Helium Ne
20.18
10
Neo
n Ar
39.948
18
Argon Kr 83.798
36
Kryp
ton
Xe 131.2
9
54
Xeno
n Rn
86
Rad
on
222
*
Ce 140.12
+3 Ce
rium
1.1
58
Th 232.04
+4 Th
orium1.3
90+4
*
Pr 140,91
+3
Praseo
dymium
1.1
59
Pa 231.0
4+5 Proa
ctinium1.4
91+4
*+4
Nd
144.24
+3 Neo
dymium1.1
60
U 238.03
+6 Uranium
1.4
92 +3
*+4
+5
PPmmm+3 Prom
ethium1.1
61
NNppp
+6 Nep
tunium1.4
93 +3
*+4
+5
*
145
237
Sm 150.36
+3 Samarium1.1
62
PPuuu+6 Pluton
ium1.3
94 +3
*+4 +5
244
+2
Eu 151.9
6+3 Eu
ropium
1.1
63
AAmmm
+6 Americium1.3
95 +3
*+4 +5
243
+2
Gd
157.25
+3 Gad
olinium1.1
64
CCmmmCu
rium
1.3
96*
+3
247
Tb 158.93
+3 Te
rbium
1.2
65
BBkkkBe
rkelium1.3
97*
+3 +4
247
+4
Dy
162.5
+3 Dysprosium1.2
66
CCfffCa
lifornium1.3
98*
+3
251
Ho
164.93
+3 Holmium1.2
67
EEsssEinsteinium1.3
99*
+3
252
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Authorized Signature:
Return (at cost) Dispose (€0.20/sample) Store
Rejects After Analysis After 60 days After 60 days €0.30/sample/month
Pulps After Analysis After 90 days After 90 days €0.15/sample/month
Sieve After Analysis After 3 months After 3 months €0.20/sample/month
Irrads After Analysis After 30 days After 30 days €0.20/sample/month
Return Samples To:Company:
Address:
Attn : Phone:
Request for Analysis
Carrier: Waybill #: # of Packages: # of Samples:
Date Received: Time Received: Initial:
Implement Environmental Sample Acceptance Form Yes N/A Invoice #:
Priority: Normal (may vary depending on package and time of year - please enquire)
RUSH (required by)
(Note: subject to surcharge, method dependent)
Confirmation of Sample Receipt: Yes No
By: E-mail:
or Fax:
Client Info:
Quote #, PO #, Proforma #: Project:
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Storage:
Please Note: License required for the return of
radioactive material - cost per shipment is
€100.00 + shipping. Under CFIA regulations,
soil, sediment and vegetation samples from
outside Canada require incineration prior to
disposal; additional charges will apply.
Method of Sample Return:At cost (client will be invoiced)
Our Carrier Account:
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Account #:
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Special Instructions/Comments:
For samples requiring Geochronology and/or Isotopic Geochemistry, please be sure to include the following information:
• Rock type:
• Minerals to be separated, specify:
• Estimated age:
Activation Laboratories Ltd.
1428 Sandhill Drive l Ancaster, ON l L9G 4V5 l Tel: (905) 648-9611 l Fax: (905) 648-9613 l Toll Free: 1-888-ACTLABS l E-mail: [email protected]
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Page 1 of
Client Name:
# ofsamples Sample Numbers (list all or range)
Sample Code(see below)
Prep. Code(if required)
Pkg. Code /Elements
Page of
Sample Codes: R – Rock H – Humus B – Brine C – Ore Conc. LS – Lake Sediment
CR – Crushed Rock S – Soil MW – Marine Water O – Other (specify) SS – Stream Sediment
HMC – Heavy Minerals V – Vegetation W – Water P – Pulp
Please copy page for additional sample lists.
Sample Preparation Charges: Contact me if sample preparation is required. I authorize any required sample preparation charges.