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FORM-I for PROPOSED EXPANSION OF SPECIALTY CHEMICALS, BULK DRUGS, BULK DRUG INTERMEDIATES MANUFACTURING AND PESTICIDES FORMULATION UNIT of M/s. WANKSONS CHEMICAL INDUSTRIES PVT. LTD. Plot No. 518, GIDC Industrial Estate, Panoli - 394 116, Taluka: Ankleshwar, Dist. Bharuch, Gujarat, INDIA. NABL Accredited Testing Laboratory ISO 9001:2008 Certified Company Aqua-Air Environmental Engineers P. Ltd. 403, Centre Point, Nr. Kadiwala School, Ring Road, Surat - 395002 Prepared By: NABL Accredited Testing Laboratory ISO 9001:2008 Certified Company Aqua-Air Environmental Engineers P. Ltd. 403, Centre Point, Nr. Kadiwala School, Ring Road, Surat - 395002 NABL Accredited Testing Laboratory ISO 9001:2008 Certified Company Aqua-Air Environmental Engineers P. Ltd. 403, Centre Point, Nr. Kadiwala School, Ring Road, Surat - 395002 Prepared By:

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Page 1: FORM-Ienvironmentclearance.nic.in/writereaddata/Online/TOR/23_May_2017... · the machineries & equipments to reduce noise generation. • Use of PPEs like ear plugs and ear muffs

FORM-I

for

PROPOSED EXPANSION OF SPECIALTY CHEMICALS, BULK

DRUGS, BULK DRUG INTERMEDIATES MANUFACTURING

AND PESTICIDES FORMULATION UNIT

of

M/s. WANKSONS CHEMICAL INDUSTRIES PVT. LTD.

Plot No. 518, GIDC Industrial Estate, Panoli - 394 116,

Taluka: Ankleshwar, Dist. Bharuch, Gujarat, INDIA.

NABL Accredited Testing Laboratory

ISO 9001:2008 Certified Company

Aqua-Air Environmental Engineers P. Ltd.

403, Centre Point, Nr. Kadiwala School, Ring

Road, Surat - 395002

Prepared By:

NABL Accredited Testing Laboratory

ISO 9001:2008 Certified Company

Aqua-Air Environmental Engineers P. Ltd.

403, Centre Point, Nr. Kadiwala School, Ring

Road, Surat - 395002

NABL Accredited Testing Laboratory

ISO 9001:2008 Certified Company

Aqua-Air Environmental Engineers P. Ltd.

403, Centre Point, Nr. Kadiwala School, Ring

Road, Surat - 395002

Prepared By:

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APPENDIX I

FORM 1 (I) Basic Information

Sr.

No.

Item Details

1. Name of the Project/s M/s. Wanksons Chemical Industries Pvt. Ltd.

2. S. No. in the Schedule 5(f)

3. Proposed capacity / area / length /

tonnage to be handled/command

area/lease area/number of wells to be

drilled

• Existing Production Capacity:

� Specialty Chemicals & Bulk Drug Intermediates:

286 MT/Month

� Pesticides Formulation: 1150 MT/Month

• Total Production Capacity after Proposed

Expansion:

� Specialty Chemicals, Bulk drugs & Bulk Drug

Intermediates: 576 MT/Month

� Pesticides Formulation: 1150 MT/Month

- Reference: Annexure-1.

• Total Plot Area: 10,290 m2

• No bore well is and will be drilled within the

premises.

4. New/Expansion/Modernization Expansion

5. Existing capacity/area etc. • Existing Production Capacity:

� Specialty Chemicals & Bulk Drug Intermediates:

286 MT/Month

� Pesticides Formulation: 1150 MT/Month

• Existing Plot Area: 10,290 m2

6. Category of project i.e. ‘A’ or ‘B’ ‘A’

7. Does it attract the general condition?

If yes, please specify.

Yes. Located within 5 km of critically polluted area

(Ankleshwar).

8. Does it attract the specific condition?

If yes, please specify.

No.

9. Location

Plot/Survey/Khasra No. Plot. No. 518

Village GIDC Industrial Estate, Panoli - 394 116

Tehsil Ankleshwar

District Bharuch

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State Gujarat

10. Nearest railway station/airport along

with distance in kms.

By road distance:

Nearest Railway Station: Panoli = 2.5 km (approx.)

Nearest Airport : Surat = 60 km (approx.)

11. Nearest Town, city, District

Headquarters along with distance in

kms.

By road distance: Nearest Town : Panoli = 2 km (approx.)

Nearest District Head Quarter : Bharuch = 15 km

(approx.)

12. Village Panchayats, Zilla Parishad,

Municipal corporation, Local body

(Complete postal addresses with

telephone nos. to be given)

Notified Area Authority, Panoli

13. Name of the applicant M/s. Wanksons Chemical Industries Pvt. Ltd.

14. Registered address Plot. No. 518, GIDC Industrial Estate, Panoli -394 116,

Tal: Ankleshwar, Dist: Bharuch, Gujarat.

15. Address for correspondence:

Name Mr. Indrasinh H. Parmar

Designation (Owner/Partner/CEO) GM (Production)

Address M/s. Wanksons Chemical Industries Pvt. Ltd.

Plot. No. 518, GIDC Industrial Estate, Panoli -394 116,

Tal: Ankleshwar, Dist: Bharuch, Gujarat.

Pin Code 394 116

E-Mail [email protected]

Telephone No. Tel: +91-7490032431/9427178117

Mob.: +91 9724302128

Fax No. --

16. Details of Alternative Sites examined,

if any location of these sites should be

shown on a topo sheet.

No

17. Interlinked Projects No

18. Whether separate application of

interlinked project has been

submitted?

No interlinked project has been submitted.

19. If Yes, date of submission Not applicable

20. If no., reason Not applicable

21. Whether the proposal involves

approval/clearance under: If yes,

details of the same and their status to

be given.

(a) The Forest (Conservation) Act,

1980?

(b) The Wildlife (Protection) Act,

1972?

Not applicable as proposed expansion activity will be

within GIDC Industrial Estate, Panoli, Taluka

Ankleshwar, Dist. Bharuch, Gujarat.

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(c) The C.R.Z Notification, 1991?

22. Whether there is any Government

order/policy relevant/relating to the

site?

No

23. Forest land involved (hectares) No

24. Whether there is any litigation

pending against the project and/or

land in which the project is propose to

be set up?

(a) Name of the Court

(b) Case No.

(c) Orders/directions of the Court,

if any and its relevance with the

proposed project.

No

(II) Activity

1. Construction, operation or decommissioning of the Project involving actions, which

will cause physical changes in the locality (topography, land use, changes in water

bodies, etc.)

Sr.

No.

Information/Checklist confirmation Yes

/No?

Details thereof (with approximate

quantities / rates, wherever possible)

with source of information data

1.1 Permanent or temporary change in land

use, land cover or topography including

increase in intensity of land use (with

respect to local land use plan)

No --

1.2 Clearance of existing land, vegetation

and buildings?

No --

1.3 Creation of new land uses? No Land is for industrial purpose. Proposed

expansion activity will be carried out

within existing site which is located on

level ground does not require any land

filling for area grading work.

1.4 Pre-construction investigations e.g. bore

houses, soil testing?

No As any kind of construction activity won’t

require in proposed expansion activity,

pre-construction investigations are not

required.

1.5 Construction works? No No, any kind of construction works is not

required. Existing infrastructures and

ancillary facilities are adequate for

proposed expansion activity.

- Reference: Annexure - 2.

1.6 Demolition works? No --

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1.7

Temporary sites used for construction

workers or housing of construction

workers?

No --

1.8 Above ground buildings, structures or

earthworks including linear structures,

cut and fill or excavations

No As existing infrastructures are adequate

for proposed expansion activity, no kind of

excavation work is required.

- Reference: Annexure - 2.

1.9

Underground works including mining or

tunneling?

No --

1.10 Reclamation works? No --

1.11 Dredging? No --

1.12 Offshore structures? No --

1.13 Production and manufacturing

processes?

Yes Reference: Anneure-3.

1.14 Facilities for storage of goods or

materials?

Yes Existing storage facilities/area is available

as an existing infrastructure for storage of

existing raw materials, finished products,

hazardous/solid wastes, etc.

Existing infrastructure for storage of raw

materials, finished products,

hazardous/solid wastes, etc. are adequate

for storage of additional raw materials,

finished products, hazardous/solid wastes,

etc.

1.15

Facilities for treatment or disposal of

solid waste or liquid effluents?

Yes • Water consumption & Waste water

generation details

– Reference: Anneure-4.

• Effluent Treatment Plant details

– Reference: Anneure-5.

• Hazardous/Solid wastes generation and

disposal mode details

– Reference: Anneure-6.

1.16

Facilities for long term housing of

operational workers?

No --

1.17 New road, rail or sea traffic during

construction or operation?

No --

1.18 New road, rail, air waterborne or other

airports etc?

No The proposed expansion activity will be

carried out within existing site located in

well developed Industrial Estate having all

infrastructural facilities. Existing

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transportation system is adequate too.

1.19 Closure or diversion of existing

transport routes or infrastructure

leading to changes in traffic

movements?

No --

1.20 New or diverted transmission lines or

pipelines?

No --

1.21

Impoundment, damming, converting,

realignment or other changes to the

hydrology of watercourses or aquifers?

No --

1.22 Stream crossings? No --

1.23

Abstraction or transfers or the water

form ground or surface waters?

Yes • No ground water is and shall be used.

• Raw water requirement is met through

GIDC water supply and will be met

through same source after proposed

expansion.

1.24

Changes in water bodies or the land

surface affecting drainage or run-off?

No --

1.25

Transport of personnel or materials for

construction, operation or

decommissioning?

Yes Transportation of personnel or raw

materials/finished products is primarily by

road only & it will be done through the

same way after proposed expansion.

1.26 Long-term dismantling or

decommissioning or restoration works?

No --

1.27 Ongoing activity during

decommissioning which could have an

impact on the environment?

No --

1.28

Influx of people to an area in either

temporarily or permanently?

No --

1.29 Introduction of alien species? No --

1.30 Loss of native species of genetic

diversity?

No --

1.31 Any other actions? No --

2. Use of Natural resources for construction or operation of the Project (such as land, water,

materials or energy, especially any resources which are non-renewable or in short supply):

Sr.

No

Information/checklist confirmation Yes/

No?

Details there of (with approximate

quantities/rates, wherever possible) with

source of information data

2.1 Land especially undeveloped or

agriculture land (ha)

No --

2.2 Water (expected source & competing Yes • Raw water requirement is met through

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users) unit: KLD GIDC water supply and will be met

through the same source after proposed

expansion.

• Water consumption & Waste water

generation details

– Reference: Anneure-4.

2.3 Minerals (MT) No --

2.4

Construction material - stone,

aggregates, sand / soil (expected source

MT)

No --

2.5 Forests and timber (source - MT) No --

2.6

Energy including electricity and fuels

source, competing users Unit: fuel (MT),

energy (MW)

Yes Reference: Anneure-7.

2.7 Any other natural resources (use

appropriates standard units)

No --

3. Use, storage, transport, handling or production of substances or materials, which could be

harmful to human health or the environment or raise concerns about actual or perceived

risks to human health.

Sr.

No.

Information / Checklist confirmation Yes/

No?

Details thereof (with approximate

quantities / rates wherever possible) with

source of information data

3.1 Use of substances or materials, which are

hazardous (as per MSIHC rules) to human

health or the environment (flora, fauna,

and water supplies)

Yes

Reference: Annexure -8.

3.2 Changes in occurrence of disease or

affect disease vectors (e.g. insect or

water borne diseases)

No --

3.3 Affect the welfare of people e.g. by

changing living conditions?

No --

3.4

Vulnerable groups of people who could

be affected by the project e.g. hospital

patients, children, the elderly etc.,

No

--

3.5 Any other causes No --

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4. Production of solid wastes during construction or operation or decommissioning

MT/month)

Sr.

No.

Information/Checklist confirmation Yes/

No?

Details thereof (with approximate

quantities / rates, wherever possible)

with source of information data

4.1 Spoil, overburden or mine wastes No --

4.2

Municipal waste (domestic and or

commercial wastes) No --

4.3

Hazardous wastes (as per Hazardous

Waste Management Rules)

Yes Reference: Anneure-6.

4.4 Other industrial process wastes Yes Reference: Anneure-6.

4.5 Surplus product No --

4.6

Sewage sludge or other sludge from

effluent treatment

Yes Reference: Anneure-6.

4.7 Construction or demolition wastes No --

4.8 Redundant machinery or equipment No --

4.9 Contaminated soils or other materials No --

4.10 Agricultural wastes No --

4.11 Other solid wastes Yes Reference: Anneure-6.

5. Release of pollutants or any hazardous, toxic or noxious substances to air (Kg/hr)

Sr.

No.

Information/Checklist confirmation Yes/

No?

Details thereof (with approximate

quantities/rates, wherever possible) with

source of information data

5.1 Emissions from combustion of fossil

fuels From stationary or mobile sources

Yes Reference: Annexure -9.

5.2 Emissions from production processes Yes Reference: Annexure -9.

5.3 Emissions from materials handling

including storage or transport.

Yes • Raw materials receive in

drums/carboys/bags/tankers and handled

in closed charging system with proper

ventilation and charged through close

pipeline in to reactors/treatment units. It

will be done through same way after

proposed expansion.

• Thus there won't be any kind of emission

through storage and transport.

5.4 Emissions from construction activities

including plant and equipment

No --

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5.5

Dust or odours from handling of

materials including construction

materials, sewage and waste

No --

5.6 Emissions from incineration of waste No --

5.7 Emissions from burning of waste in

open air (e.g. slash materials,

construction debris)

No --

5.8 Emissions from any other sources No --

6. Generation of Noise and Vibration, and Emissions of Light and Heat:

Sr.

No.

Information/Checklist confirmation Yes/

No?

Details there of (with approximate

Quantities /rates, wherever possible) With

source of source of information data

6.1

From operation of equipment e.g.

engines, ventilation plant, crushers

Yes • There are few activities due to which noise

generates. The equipments resulting in

noise generation are machineries of plant

and diesel generator. Adequate noise

controls measures are provided.

• Proper and timely oiling, lubrication and

preventive maintenance is carried out for

the machineries & equipments to reduce

noise generation.

• Use of PPEs like ear plugs and ear muffs are

made compulsory near the high noise

generating machines.

• Noise monitoring is done regularly in plant

area.

• D.G. Set is installed in a closed room and

provided with acoustic enclosure.

• Above system will be followed after

proposed expansion to prevent/reduce

noise to be generated.

• The unit has developed plantation within

the premises which helps to prevent the

noise pollution within site as well as

surrounding area.

6.2 From industrial or similar processes Yes • All machinery/equipment is well

maintained, have proper foundation with

anti vibrating pads wherever applicable and

thus, noise levels is within permissible

limits.

• An acoustic enclosure is provided for D.G.

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set.

• Above system will be followed after

proposed expansion to prevent/reduce

noise to be generated.

6.3 From construction or demolition No --

6.4 From blasting or piling No --

6.5 From construction or operational traffic No --

6.6 From lighting or cooling systems No --

6.7 From any other sources No --

7. Risks of contamination of land or water from releases of pollutants into the ground or

into sewers, surface waters, groundwater, coastal waters or the sea:

Sr.

No

Information/Checklist confirmation Yes/

No?

Details thereof (with approximate

quantities / rates, wherever possible) with

source of information data

7.1

From handling, storage, use or spillage

of hazardous materials

Yes • All hazardous materials are stored safely &

separately in designated storage area.

• Dyke walls are provided around

raw/hazardous materials storage tanks.

• Materials stored in bags / drums keep on

pallets with concrete flooring and company

takes preventive action for no spillage likely

to occur.

• Above system will be followed after

proposed expansion.

• Reference: Annexure -8.

7.2

From discharge of sewage or other

effluents to water or the land

(expected mode and place of

discharge)

Yes Sewage is disposed of through septic

tank/soak pit & to be done through same

way after proposed expansion.

7.3

By deposition of pollutants emitted to

air into the land or into water

No --

7.4 From any other sources No --

7.5 Is there a risk of long term build up of

pollution in the environment from

these sources?

Yes

• Environmental Management System (EMS)

is installed i.e. ETP, Air Pollution Control

systems, Hazardous Waste Handling and

Management system as per rules, etc.

which eliminates the possibility of building

up of pollution.

• In proposed expansion activity, additional

EMS will be implemented, if required.

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8. Risks of accident during construction or operation of the Project, which could affect

human health or the environment:

Sr.

No

Information/Checklist confirmation

Yes/

No?

Details thereof (with approximate

quantities / rates, wherever possible) with

source of information data

8.1 From explosions, spillages, fires etc.

from storage, handling, use or

production of hazardous substances

Yes Reference: Annexure -8.

8.2 From any other causes No --

8.3 Could the project be affected by natural

disasters causing environmental damage

(e.g. floods, earthquakes, landslides,

cloudburst etc)?

No --

9. Factors which should be considered (such as consequential development) which could lead

to environmental effects or the potential for cumulative impacts with other existing or

planned activities in the locality

Sr.

No.

Information/Checklist confirmation Yes/

No?

Details thereof (with approximate

quantities / rates, wherever possible) with

source of information data

9.1 Lead to development of supporting.

laities, ancillary development or

development stimulated by the project

which could have impact on the

environment e.g.:

* Supporting infrastructure (roads,

power supply, waste or waste water

treatment, etc.)

• housing development

• extractive industries

• supply industries

• other

Yes • Plot is located within GIDC, Panoli, Taluka:

Ankleshwar, having entire required

infrastructural facility i.e. road

infrastructure, water supply, power supply,

etc.

• Local people are employed and no housing

is required.

• Reference: Annexure – 10.

9.2

Lead to after-use of the site, which

could have an impact on the

environment

No

--

9.3 Set a precedent for later developments No --

9.4 Have cumulative effects due to

proximity to Other existing or planned

projects with similar effects

No --

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(III) Environmental Sensitivity

Sr.

No

Information/Checklist confirmation Name /

Identity

Aerial distance (within 25 km). Proposed

Project Location Boundary.

1 Areas protected under international

conventions national or local

legislation for their ecological,

landscape, cultural or other related

value

No Plot is located in GIDC, Panoli, Taluka:

Ankleshwar, Dist. Bharuch, Gujarat.

2 Areas which are important or sensitive

for Ecological reasons - Wetlands,

watercourses or other water bodies,

coastal zone, biospheres, mountains,

forests

No Plot is located in GIDC, Panoli, Taluka:

Ankleshwar, Dist. Bharuch, Gujarat.

3 Areas used by protected, important or

sensitive species of flora or fauna for

breeding, nesting, foraging, resting,

over wintering, migration

No Plot is located in GIDC, Panoli, Takula:

Ankleshwar, Dist. Bharuch, Gujarat.

4 Inland, coastal, marine or

underground waters

Yes • Sea Coast : 20 Km (approx.)

• River Narmada : 14.6 Km (approx.)

• Amla Khadi : 5.5 Km (approx.)

5 State, National boundaries No --

6 Routes or facilities used by the public

for to recreation or other tourist,

pilgrim areas.

No --

7 Defense installations No --

8 Densely populated or built-up area Yes Ankleshwar city: 2 Lakh population

(approx.)

9 Areas occupied by sensitive man-

made land community facilities)

No

10 Areas containing important, high

quality or scarce resources (ground

water resources, surface resources,

forestry, agriculture, fisheries,

tourism, tourism, minerals)

Yes

• No ground water will be used.

• Plot is located in industrial area & does

not affect agricultural land.

11 Areas already subjected to pollution

or environmental damage. (those

where existing legal environmental

standards are exceeded)

Yes Plot is located in GIDC, Panoli, Taluka:

Ankleshwar, Dist. Bharuch, Gujarat.

12 Are as susceptible to natural hazard

which could cause the project to

present environmental problems

(earthquakes, subsidence ,landslides,

No --

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flooding erosion, or extreme or adverse

climatic conditions)

IV). Proposed Terms of Reference for EIA studies: Please refer Annexure – 11.

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23/05/2017

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ANNEXURES

ANNEXURE

NO.

PARTICULARS

1 List of Products with their Production Capacity and Raw Materials Consumption

2 Plot layout

3 Brief Manufacturing Process Description

4 Details of water consumption & waste water generation

5 Description of Effluent Treatment Plant

6 Details of Hazardous/Solid Wastes Generation, Management and Disposal Mode

7 Power and Fuel Requirement

8 Hazardous Chemicals Storage and Handling Details

9 Details of Sources of Emissions and Air Pollution Control Equipments (APCM)

10 Socio - Economic Impacts

11 Proposed Terms of References

12 Copy of Land Possession/Plot Allotment Letter

13 Copy of CETP and Spray Dryer Membership Letter

14 Copy of Common TSDF & HWIF Membership Letter

15 Toposheet

16 Copy of GIDC Letter for Water Supply

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ANNEXURE – 1

LIST OF PRODUCTS WITH THEIR PRODUCTION CAPACITY

Sr.

No.

Products CAS No. Production Capacity

(MT/Month)

Existing Total after Proposed

Expansion

1 Chloral (Trichloro

Acetaldehyde)

75-87-6 213 400

2 Meta Chloro Propio

Phenone (3-cpp)

936-59-4 10 15

3 Dichlorovos Technical

(DDVP)

62-73-7 20 50

4

3-(Bromo ethyl)-2-chloro-4-

(methyl sulfonyl) Benzoic

Acid (PIA-4)

53250-83-2 25 Nil

5 S-Benzyl O, O Diisopropyl

Phosphorothioate (PIZ)

26087-47-8 10 Nil

6 Dimethyl Amine

Hydrochloride

(DMA - HCl)

506-59-2

10

25 7

Iso Propyl Alcohol

Hydrochloride

(IPA HCL)

7647-01-0

8 Methanolic Hydrochloride 9004-54-0

9 Ethyl Acetate Hydrochloride 5407-04-5 -

10 Ethyl Alcohol Hydrochloride 9004-54-0 -

11 Propionyl chloride 79-03-8 - 24

12 Propiophenone 93-55-0 - 30

13 2-Bromo 3-Chloro

Propiophenone

34911-51-8 - 4

14 3-Methoxy Propiophenone 37951-49-8 - 4

15 3-Hydroxy Propiophenone 13103-80-5 - 4

16 Cyano Acetic Acid 372-09-8 - 10

17 7-Ethyl Tryptophol (7-ETP) 41340-36-7 - 5

18 Closantel Amine 57808-65-8 - 5

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Total 286 576

Formulations

19 Fanvalrate 20% EC 51638-58-1 100 100

20 Chloropyriphos 20% EC 2921-88-2 100 100

21 Chloropyriphos 48% EC 2921-88-2 100 100

22 Cypermetherin 25% EC 52315-07-8 100 100

23 Monocrotophos 36% EC 6923-22-4 100 100

24 Cypermetherin 10% EC 52315-07-8 100 100

25 Dichlorovos Technical

(DDVP) 76% EC

62-73-7 100 100

26 2,4,D Ethyl Ester 38% EC 94-75-7 100 100

27 Imida Chlopride 17.8% SL 138261-41-3 100 100

28 Methyl Parathion 50 % EC 298-00-0 100 100

29 Mancozeb 75 % WP 8018-01-7 75 75

30 Acephate 75 % SP 30560-19-1 75 75

Total 1150 1150

LIST OF BY-PRODUCTS WITH THEIR PRODUCTION CAPACITY

Sr.

No.

By-Products CAS No. Production Capacity

(MT/Month)

Existing Total after Proposed

Expansion

1 Regenerated Sulfuric Acid

(72%)

7664-93-9 283.75 533

2 Dilute Hydrochloric Acid (30-

32%)

7647-01-0 656* 1200*

Dilute Hydrochloric Acid

(20%)

0.723** 1.257**

3 Ethyl Chloride 75-00-3 95.83 180

4 Methyl Chloride 74-87-3 2.29# 4.58

#

5 HBr 10035-10-6 6.45 6.45

6 Poly Aluminium Chloride 1327-41-9 7.5 46

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(PAC) – 100%

7 Sodium Hypochlorite (10%) 7681-52-9 90 120

8 Spent H2SO4 7664-93-9 90 120

* Existing: (656 - 11.5 = 644.5 MT). 11.5 MT converts to HCl gas & Consumes as raw material in

existing products i.e. DMA – Hydrochloride, IPA HCL and Methaonolic Hydrochloride.

* Total after Proposed Expansion: (1200 – 25 = 1175 MT). 25 MT will be converted to HCl gas

& Consumed as raw material in existing products i.e. 3-CPP, DMA – Hydrochloride, IPA HCL

and Methaonolic Hydrochloride and Propiophenone.

** HCl (20%) converts and to be converted to HCl (30-32%) and sell to actual user.

RAW MATERIAL CONSUMPTION:

Raw Material Consumption Quantity

(MT/MT)

Chloral

Ethyl Alcohol 0.624

Chlorine 1.925

Sulfuric Acid (98%) 1.223

Meta Chloro Propio Phenone (3-cpp)

Benzene 1.078

Aluminium Chloride 0.105

Propionyl Chloride 0.816

Ethylene Dichloride 0.5

Chlorine 0.421

HCl 0.025

Dichlorovos Technical (DDVP)

Chloral 0.668

Tri Methyl Phosphate 0.561

3-(Bromo ethyl)-2-chloro-4-(methyl sulfonyl) Benzoic Acid (PIA-4)

2-Chloro-6-(methyl thio) Toluene (PIO) 0.535

Ethylene Dichloride 2.25

Aluminium Chloride 0.3

Acetyl Chloride 0.25

Methanol 1.5

Hydrogen Peroxide 0.315

Catalyst 0.054

HCl 0.05

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Bromine 0.49

ODCB 1.0

S-Benzyl O, O Diisopropyl Phosphorothioate (PIZ)

Ammonium Salt 0.64

Benzyl Chloride 0.36

Toluene 0.33

Dimethyl Amine Hydrochloride

DMA Soln. (40%) 1.11

Dry HCl gas 0.56

Iso Propyl Alcohol Hydrochloride

IPA 0.75

Dry HCl gas 0.25

Methaonolic Hydrochloride

Methanol 0.75

Dry HCl gas 0.25

Ethyl Acetate Hydrochloride

Ethyl Acetate 0.671

Hydrochloric Acid 0.329

Ethyl Alcohol Hydrochloride

Ethyl Alcohol 0.411

Hydrochloric Acid 0.59

Propionyl chloride

Propionic Acid 0.8

Thionyl Chloride 1.46

Propiophenone

Propionyl Chloride 0.76

Benzoic Acid / Benzene 0.91 / 0.74

Catalyst / AlCl3 0.042 / 1.18

2-Bromo 3-Chloro Propiophenone

Bromin Soln. 1.05

3-CPP 0.64

Sodium Thiosulphate Soln. 3.19 KL

MDC 2.78 KL

3-Methxy Propiophenone

3- Chloropropiophenone 1.02

Methanol 0.2

3-Hydroxy Propiophenone

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3- Chloropropiophenone 1.12

Sodium Hydroxide 0.27

Cyano Acetic Acid

Mono Chloro Acetic Acid 1.11

NaCN 0.576

H2SO4 1.153

Carbon 0.141

MIBK 1.178

7-Ethyl Tryptophol (7-ETP)

EPH 1.0

2,3-dihydro furan 0.44

Methanol 0.2

Toluene 7.0

Catalyst 0.04

Closantel Amine

4-Chloro Benzyl Cyanide 0.52

4-Chloro 2 Nitro Toluene 0.59

Methanol 0.11

KOH 0.193

NaHS 0.193

Toluene 0.316

Activated Carbon 0.041

Fanvalrate 20% EC

Fanvalrate Tech. 0.225

Solvent 0.61

Emulsifier 0.165

Chloropyriphos 20% EC

Chloropyriphos (T) 0.215

Solvent Aromax 0.725

Emulsifier 0.06

Chloropyriphos 48% EC

Chloropyriphos (T) 0.511

Solvent Aromax 0.409

Emulsifier 0.08

Cypermetherin 25% EC

Cypermetherin (T) 0.27

Solvent Aromax 0.253

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Emulsifier 0.478

Monocrotophos 36% EC

Monocrotophos (T) 0.53

Solvent 0.47

Cypermetherin 10% EC

Cypermetherin 0.093

Solvent Aromax 0.384

Emulsifier 0.524

Dichlorovos Technical (DDVP) 76% EC

Dichlorvos 0.83

Solvent Aromax 0.099

Emulsifier 0.07

Dye 0.001

2,4,D Ethyl Ester 38% EC

2,4,D Ethyl Ester 0.4

Solvent Aromax 0.55

Emulsifier 0.05

Imida Chlopride 17.8% SL

Imidachlorprid (T) 0.178

Solvent 0.752

Emulsifier 0.07

Methyl Parathion 50 % EC

Methyl Parathion (T) 0.625

Solvent 0.205

Emulsifier 0.17

Mancozeb 75 % WP

Mancozeb (T) 0.882

Suspensioning Agent 0.06

China Clay 0.0577

Acephate 75 % SP

Acephate 0.75

Acrosol OTB 0.005

Fine Silica 0.245

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ANNEXURE-2

PLOT LAYOUT

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ANNEXURE-3

BRIEF MANUFACTURING PROCESS DESCRIPTION

Chloral:

Process Description:

Ethyl alcohol charge in to glass line reactor and chlorine is pass under control temp. condition.

HCl gas is being produced as a by-product which further react with ethyl alcohol and ethyl

chloride is being produced. HCl gas is being scrub into series of scrubber and ten in to caustic

scrubber to get ethyl chloride. Ethyl Chloride then condenses in minus temp and cylinders are

being filled to sale as by-product HCl 30% is also being recovered and sale as a by-product.

Chlorinated mass alcoholate is treated with sulfuric acid 98% for getting pure chloral. Sulfuric

Acid is being regenerated as 75% acid and sale as by-product.

Chemical Reaction:

Mass Balance:

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Meta Chloro Propio Phenone (3-cpp):

Process Description:

Stage-1:

Friedel Craft Reaction – Charge Benzoic Acid / Benzene and catalyst in GLR and cool at 10-12

0C. Add propionyl chloride slowly keep temperature at <12

0C.

Distillation – Apply vaccum and distill propiophenone.

Stage-2:

Chlorination – Charge required quantity of solvent (EDC) cool to 10 0C then charged reactant

propiophenone and again chilled to 4 0C then start slow addition of catalyst AlCl3 with

controlling temperature after completion of catalyst charging purged chlorine with control rate

and temperature then quench the reaction in dilute HCl maintaining temperature belo 20 0C.

Solvent recovery & Fraction Distillation – Washed neutral organic layer to be taken for

atmosphere solvent recovery after completion of solvent recovery start & complete high

vaccum, high temperature fraction distillation to get dilute MCPP.

Centrifugation – Dilute MCPP is centrifuge to get wet cake of crude MCPP and after drying get

pure product.

Chemical Reaction:

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Mass Balance:

Stage-1

506 kg Water

217 kg HCl

795 kg Propiophenone 723 kg

500 kgEthylene

dichloride30-33% HCl solution

55 kg Catalyst-1

421 kg Chlorine

1554 kg

100 kg Water / Ice

25 kg HCl

1679 kg

100 kg Hexane 55 kg

1724 kg

Recover EDC 95% 475 kg

EDC loss 25 kg

Recover Hexane 98% 98 kg

Hexane loss 2 kg

Water Recovered &

Reuse50 kg

Wetcake 1074 kg

Drying loss 74 kg

1000 kg 3CPP

Catalyst-1 recover &

recycle

Sent to centrifuge

if required

Chlorination

Quenching

Centrifuge

Scrubber

Distillation

Drying

Benzoic Acid /

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Dichlorovos Technical (DDVP):

Process Description:

Charge chloral required quantity and addition of Trimethyl phosphate slowly at 50 0C. After

addition of TMP charge epichlorohydrine and maintain the reaction mass under vaccum for

about 3 hrs. until impurities are within specification. Then pack the material.

Chemical Reaction:

Mass Balance:

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3-(Bromo ethyl)-2-chloro-4-(methyl sulfonyl) Benzoic Acid (PIA-4)

Process Description:

Charge (EDC) in GLR. Check sample for m/c. Charge catalyst cool the mass with CHW up to 10-

15 0C and start addition of Acetyl Chloride. Maintain temp. under stirring and start feeding of

PIA. Stir the mass for 3.0 hrs. at same temp. Send sample for QC. After confirming result quench

the mass in other GLR.

Receive concentrate organic mass from SSR. Charge (catalyst) soln. Apply heating. Do the

addition of H2SO4 by maintaining temp. at 65-65 0C. Give sample after getting result start

cooling transfer mass to GLR. Flush reactor to GLR.

Receive organic mass from GLR in crystallizer. Cool the mass and maintain temp. to 32-35 0C.

Start addition of HCl. Do the sample for pH it should be < 1.0. Do the centrifuging lot. Collect

aqueous in tank for recovery. Give the wash of DM Water. Unload wet cake. Do the drying in

RVD after drying fill up the drums in 50 Kg.

Chemical Reaction:

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Mass Balance:

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S-Benzyl O, O Diisopropyl Phosphorothioate (PIZ):

Process Description:

Charge PIZ-001 (Ammonium Salt) in GLR maintain temp. 25 to 30 oC by chilling water to adjust

pH by PIZ-002 (HCl) to 6.5 to 6.8 – maintain for 1.3 hr.-charge PIZ-003 & 004 (Toluene and

Benzyl Chloride) – heat the mass upto 80-85 oC – maintain it for 2.3 to 3 hr – send sample for

GC – settle the mass for 1.0 hr at 75 to 8 oC – separate the bottom aqueous – retain organic

mass in GLR – Charge DM water under agitation – settle mass for 1 hr – separate bottom

organic mass in GLR – start vacuum and heating to recovered PIZ-003 (Toluene) by maintain

temp and vacuum – send sample to QC – fill up the drums for final packing.

Chemical Reaction:

Mass Balance:

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Dimethyl Amine Hydrochloride:

Process Description:

Take 40 % solution of DMA in GLR and start Dry HCL gas Purging at Room temperature

and adjust pH 5.5 keep 1 hour stirring then distilled Out water from Reaction mixture

after water distillation residual Reaction Mass to be Crystallized . Centrifuge and Dry the

material till moisture level Comes below 0.10 %. Final product will be packed in LDPE Bags

having PVC auto sealed Liner inside.

Chemical Reaction:

(CH3)2.N + HCl(g) (CH3)2.NHCl

Mass Balance:

40 % DMA solution 500 kg Dry HCL gas 250 kg

Wet cake 475 kg

Dry weight 450 kg DMA.HCl

GLR

Crystaliser SSTD

Tray

Dryer

This water will be

feed to scrubber

system 275 kg water

for HCl

Drying Loss 25 kg

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Iso Propyl Alcohol Hydrochloride (IPA HCL):

Process Description:

Dry HCL gas is injected to IPA to get IPA HCl and monitoring the Assay by Keeping Law

temperature of Reaction mass. After achieving Desired Results material is packed in HDPE

Drums and sealed with Plaster of Paris.

Chemical Reaction:

(CH3)2.CHOH + HCl(g) CH3.CH2.CH2.OH .HCl

Mass Balance:

IPA Dry HCL gas of chloral

1200 kg plant 400 kg

Assay 18 % to 25 %

As per Demand

GLR

25% IPA.HCl

1600 kg

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Methanolic Hydrochloride:

Process Description:

Dry HCL gas is injected to Methanol to get Methaonolic HCL and monitoring the Assay by

Keeping Law temperature of Reaction mass. After achieving Desired Results material is packed

in HDPE Drums and sealed with Plaster of Paris.

Chemical Reaction:

CH3OH + HCl(g) CH3OH .HCl

Mass Balance:

Methanol Dry HCL gas of chloral

1200 kg plant 400 kg

Assay 18 % to 25 %

As per Demand

GLR

25% MeOH.HCl

1600 kg

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Ethyl Acetate Hydrochloride:

Process Description:

Dry HCL gas Is injected to Ethylacetate to get Ethylacetate Hydrochloride and monitoring the

Assay by Keeping low temperature of Reaction mass. After Achieving of desire results Material

is packed in HDPE Drums and sealed with Plaster of paris.

Chemical Reaction:

+ HCl (g) C4H8O2 .HCL

C4H8O2 Hydrogen chloride gas Ethylacetate Hydrochloride

Ethylacetate

Mass Balance:

Ethyl Acetate (671 kg)

Hydrochloric acid (329 kg)

Ethylacetate Hydrochloride

(1000 kg)

REACTION

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Ethyl Alcohol Hydrochloride:

Process Description:

Dry HCL gas Is injected to Ethyl alcohol to get Ethyl alcohol Hydrochloride and monitoring the

Assay by Keeping low temperature of Reaction mass. After Achieving of desire results Material

is packed in HDPE Drums and sealed with Plaster of Paris.

Chemical Reaction:

C2H5OH + HCl (g) C2H5OH.HCl

Ethyl Alcohol Hydrogen chloride gas Ethyl Alcohol Hydrochloride

M.W. = 46 M.W. = 36.5 M.W = 82.5

Mass Balance:

Ethyl Alcohol (460 kg)

Hydrochloric acid (658 kg)

Ethyl Alcohol Hydrochloride

(1118 kg )

REACTION

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Propionyl chloride:

Process Description:

Propionic acid reacted with thionyl chloride produce propionyl chloride and sulfuric acid.

Chemical Reaction:

O

OHCH3 +2

SO2Cl2

O

ClCH32 + H2SO4

Propionic AcidM.W. 74

Thionyl ChlorideM.W. 135

Propionyl Chloride M.W. 92.5

Sulfuric AcidM.W. 98

Mass Balance:

Propionic Acid (296 Kg) H2SO4 (392 Kg)

Thionyl Chloride (540 Kg)

Propionyl Chloride (370 Kg)

REACTION

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Propionyl Chloride (900 Kg)

Addition of PC Hcl gas (322kg)

Benzoic acid / Benzene

(1078 kg / 875 kg)

Catalyst / Alcl3

(50 kg / 1400 kg) 30 to32% Hcl Soln Bi product(Qty 976 kg)

Chilled water (250kg) Co2 gas (388 kg)

Catalyst for Re use

Water (250 kg) - Reuse

Propiophenone (1184 kg)

GLR – 301

(3KL)

GLR – 211 (4 KL)

GLR-03 (10 KL)

Quenching

SSR-01 (5 KL)

Distillation (1434 kg)

Scrubber

(Water)

654 kg

C/F (for

Catalyst

Recovery &

Re use)

HDPE Tank-1.5 KL

(Product) - 1434 kg

Propiophenone:

Process Description:

Charge Propionyl chloride and Benzoic acid / Benzene in to GLR. In presence of aluminium

chloride they reaction occur. It generates HCl gas which scrubs in water scrubber. Reaction

mass is quenched with chilled water which further goes for catalyst recovery. Thereafter

distillation is carried out to distilled water and remaining is product.

Mass Balance:

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2-Bromo 3-Chloro Propiophenone:

Process Description:

Dissolved 3’-Chloropropiophenone in Dichloromethane and stirring the Reaction mass for 10-15

min.at 25-35°C temperature. Then add prior prepared bromine solution to reaction mass

within 3-4 hours with temperature control.then maintain the reaction mass 45 min.with

temperature control.

Then wash with process water and separate the bottam organic layer in RBF and discard the

aq.layer. then wash with sodium thiosulphate solution and agains separate the bottam organics

layer in RBF and discard the aq.layer. then wash the reaction mass with process water and

separate the bottam organic layer and discard the aq.layer.

Filter the reaction mass through celite bed and wash with Dichloromethane. Then distilled out

dichloromethane atmospherically completely.

Then apply the vacuum for removal of traces of solvent for 45 min. at 50°C and get the final

product 2-Bromo-3’-chloropropiophenone then packed in HDPE drums

Chemical Reaction:

+ Br2 Br + HBr

Cl Cl

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Mass Balance:

Bromin soln. 190 kg Process Water 500 lit.

3-CPP 115 kg MDC 460 lit.

Recovery and recycle

Sodium Thiosulphate Aq.layer 550 lit.

Solution 575 lit.

ETP

Process water 500 lit. Aq.layer 575 lit.

ETP

ETP

Aq.layer 575 lit.

MDC 510 lit.

Distilled MDC

510 lit.

180 kg 2-Bromo-3-chloropropiophenone

Reactor

Separator

Reactor

Separator

Reactor

Separator

Organic layer

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O

CH3

Cl

3'- ChloropropiophenoneM.W.168.62

C9H9ClO

+ CH3OH

Metanol M.W.32.04

- HCl

3-Methoxy Propiophenone:

Process Description:

3- Chloropropiophenone reacts with methanol generates 3- Methoxy propiophenone and HCl.

Chemical Reaction:

Mass Balance:

3- Chloropropiophenone (674.48 Kg)

Methanol (128.16 Kg) HCl (18.04 Kg)

3’- Methoxy propiophenone (656.08 Kg)

REACTION

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3-Hydroxy Propiophenone:

Process Description:

3- Chloropropiophenone reacts with NaOH generates 3- Hydroxy propiophenone and NaCl.

Chemical Reaction:

O

CH3

Cl

+ NaOH

O

CH3

OH

+ NaCl

3'- ChloropropiophenoneM.W.168.62

C9H9ClO

Sodium hydroxideM.W. 40

3'- Hydroxy ChloropropiophenoneM.W.150.12

C9H9O2H

Sodium chlorideM.W. 58.5

Mass Balance:

3- Chloropropiophenone (674.48 Kg)

Sodium hydroxide (160 Kg) NaCl (234 Kg)

3’- Hydroxy Chloropropiophenone (600.48 Kg)

REACTION

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Cyano Acetic Acid:

Process Description:

Monochloro acetic acid is taken into reactor. Add water to make liquid. Heat mass to 50 oC.

Then add sodium cyanide cake slowly. Keeping temp. below 70 oC. Check absence of sodium

cyanide by TLC. Also check cyanide content is nil through cyanide test. Once reaction is

completed, cool the mass. The mass is washed with sulfuric acid to remove impurities. Take

organic layer for extraction using MIBK as solvent to receive pure CAA in MIBK leaving sodium

Chloride in aqueous soln. MIBK containing CAA is distilled to remove MIBK. Cool and chill mass

up to 10 oC. Centrifuge pure crystals. Recycle ML for next batch. Dry crystals.

Chemical Reaction:

NaCN + + NaCl

O Cl

OH

O CN

OH

H2SO4

MIBK

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Mass Balance:

Charging Vessels

Carbon Treatment

Extraction

ETP

1000 Kg

Solvent Recovery

Crystallizer

C/F

ETP

773 Kg

Mono Chloro Acetic Acid 1110 Kg

NaCN 576 Kg

H2SO4 1153 Kg

Carbon 141 Kg

MIBK 1178 Kg

Recycle

1175 Kg

CAA

1000 Kg

Dyer Loss

210 Kg

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NHNH2HCl

O+ DMAC

NH

H2O

OH

+ HCl + NH 3

2-Ethyl phenyl hydrazine HCl 2,3-Dihydrofuran 7-Ethyl Tryptophol

7-Ethyl Tryptophol (7-ETP):

Process Description:

To stirred solution of 2-ethyl phenyl hydrazine HCl and DMAc-H2O. Dropwise add 2,3 dihydro

furan at 25-30 oC. Heat the mass upto 50 oC and stirred for 30 min. Completion of reaction is

monitored by TLC. Add conc. H2SO4 at 50 oC and maintain reaction mass for 3-4 hrs. After

completion of reaction mixure is allowed to cool to RT. Adjust pH 4-5 by using dilute Na2CO3

soln. and then extract with MDC. Crude distilled out and cool to get yellow colour product.

Chemical Reaction:

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Mass Balance:

D. M. water 500 lit. EPH 250 kg

2,3-dihydro furan Toluene 1750 lit.

110 kg Methanol 50 kg Catalyst 10 kg

Layer separation

Recovery and recycle

Tar layer 2170 lit. Aq. layer 500 lit.

Toluene 600 lit.

Organic layer Aq. layer 500 lit.

Toluene 2300 lit.

Recycle

Recycle

Inter Cut 140 kg

7-ETP 250 kg

Reactor

Reactor

Separator

Extracture

Solvent recovery

Fractional distillation

Lower cut 80

kg.

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Cl

N

+

ClN+

O + CH3OH + KOHCH3OH

+ NaHS

Cl Cl

CN

CH3

NH2

+ O2

4-Chloro Benzyl 4-Chloro-2-nitro- Closantel Amine Cyanide toluene

M.W. 151.59 171.58 291.14 32

C8H6ClN C 7H6ClNO2 C15H12N2Cl2

Closantel Amine

Process Description:

4-Chlorobenzyl Cyanide and 4-Chloro Nitro Toluene is added into reactor. Methanol is added

and heat upto 50 oC. Add solution of hydrosulfite powder as catalyst slowly. Keeping temp

below 50 oC. Add potassium hydroxide flakes into reactor and reflux mass for 12 hrs. Check

completion of reaction. If traces of PCBC seen, further reflux till it is absent. Cool product and

add DM water into it. Stir the product and then centrifuge product. Allow to settle layer.

Remove organic layer and filter mass. Collect filtrate in distillation vessel. Remove toluene by

distillation. Centrifuge the mass. Collect wet cake and dry it.

Chemical Reaction:

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Mass Balance:

SS Reactor

4-Chloro Benzyl Cyanide 520 Kg

4-Chloro 2 Nitro Toluene 590 Kg

SS Reactor Methanol 110 Kg

KOH 193 Kg

NaHS 193 Kg

Centrifuge DM Water 62 Kg

SS Reactor Toluene 316 Kg

Activated Carbon 41 Kg

Filter

SS Crystallizer Toluene 311 Kg Recovered

Dryer

Closantel Amine

1000 Kg

Loss 100 Kg

Aq. Layer 573 Kg

Activated Carbon 41 Kg

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Fanvalrate 20% EC

Process Description:

Charge solvent & add emulsifier stirr well & charge Fanvalrate [T] to uniform mix for 2.0 hr and

check Q.C. for base & other parameter to pack 200.0 kg net wt.

Mass Balance:

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Chloropyriphos 20% EC

Process Description:

Charge solvent & add emulsifier stirr well & charge Chloropyriphos [T] to uniform mix for 2.0 hr

and check Q.C. for base & other parameter to pack 200.0 kg net wt.

Mass Balance:

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Chloropyriphos 48% EC

Process Description:

Charge solvent & add emulsifier stirr well & charge Chloropyriphos [T] to uniform mix for 2.0 hr

and check Q.C. for base & other parameter to pack 200.0 kg net wt.

Mass Balance:

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Cypermetherin 25% EC

Process Description:

Charge solvent & add emulsifier stirr well & charge Cypermetherin [T] to uniform mix for 2.0 hr

and check Q.C. for base & other parameter to pack 200.0 kg net wt.

Mass Balance:

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Monocrotophos 36% EC

Process Description:

Charge solvent stirr well & charge Monocrotophos[T] to uniform mix for 2.0 hr and check Q.C.

for base & other parameter to pack 200.0 kg net wt.

Mass Balance:

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Cypermetherin 10% EC

Process Description:

Charge solvent & add emulsifier stirr well & charge Cypermetherin [T] to uniform mix for 2.0 hr

and check Q.C. for base & other parameter to pack 200.0 kg net wt.

Mass Balance:

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Dichlorovos Technical (DDVP) 76% EC

Process Description:

Charge solvent & add emulsifier stirr well & charge Dichlorvos[T] to uniform mix & add Dye mix

for 6.0 hr and check Q.C. for base & other parameter to pack 200.0 kg net wt.

Mass Balance:

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2,4,D Ethyl Ester 38% EC

Process Description:

Charge solvent & add emulsifier stirr well & charge 2,4,D Ethyl Ester[T] to uniform mix for 2.0 hr

and check Q.C. for base & other parameter to pack 200.0 kg net wt.

Mass Balance:

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Imida Chlopride 17.8% SL

Process Description:

Charge solvent & add emulsifier stirr well & charge Imidachlorprid [T] to uniform mix for 2.0 hr

and check Q.C. for base & other parameter to pack.

Mass Balance:

Product 1000 Kg

178 Kg

752 Kg

70 Kg

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Methyl Parathion 50 % EC

Process Description:

Charge solvent & add emulsifier stirr well & charge Methyl Parathion [T] to uniform mix for 2.0

hr and check Q.C. for base & other parameter to pack.

Mass Balance:

Product 1000 Kg

625 Kg 205 Kg

170 Kg

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Mancozeb 75 % WP

Process Description:

Charge Mancozeb (T), Suspensioning Agent & China Clay in blender, mixed well to uniform mix

for 4.0 hr and check Q.C. for base & other parameter to pack.

Mass Balance:

Product 1000 Kg

Mancozeb (T) 882.3 Kg

Suspensioning Agent 60 Kg

China Clay 57.7 Kg

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Acephate 75 % SP

Process Description:

Charge Acephate (T), Acrosol OTB & Fine Silica in blender, mixed well to uniform mix for 4.0 hr

and check Q.C. for base & other parameter to pack.

Mass Balance:

Acephate (T) 750 Kg

Acrosol OTB 5 Kg

Fine Silica 245 Kg

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ANNEXURE-4

DETAILS OF WATER CONSUMPTION & WASTE WATER GENERATION

SR.

NO.

DESCRIPTION EXISTING (KL/Day) TOTAL AFTER PROPOSED

EXPANSION (KL/Day)

WATER

CONSUMPTION

WASTE WATER

GENERATION

WATER

CONSUMPTION

WASTE WATER

GENERATION

1 Process 0.01 0.008* 22.5 12.0

2 Boiler 15.0 3.5 15.0 3.5

3 Cooling & Chilling 5.0 1.274 25.0 6.5

4 Washing 1.6 1.6 5.0 5.0

5 Scrubber/APCM 23.09 -- 54.0 --

Total Industrial

44.7 6.382 – 0.008 =

6.374

121.5 27.0

7 Domestic 5.5 5 # 24.5 23.5

#

8 Gardening -- -- 10.5 --

Grand Total 50.2 11.374 156.5 50.5

* Water is reused in process (Product: Meta Chloro Propio Phenone).

# Domestic waste water is & will be disposed of through septic tank & soak pit.

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ANNEXURE-5

EFFLUENT TREATMENT PLANT

In existing, M/s. Wanksons Chemical Industries Pvt. Ltd. has an Effluent Treatment Plant (ETP)

of primary treatment (neutralization) facility. Treated effluent sends to Common Effluent

Treatment Plant (CETP) of M/s. Panoli Enviro Technology Ltd. (PETL), Panoli for further

treatment and disposal.

EXISTING ETP FLOW DIAGRAM:

5 KL

Equalization cum

Neutralization Tank

Raw Effluent

5 KL

Equalization cum

Neutralization Tank

5 KL

Equalization cum

Neutralization Tank

Caustic

Filter Press

30 KL

Raw Effluent Storage

Tank

Near 3-CPP Plant

10 KL

Treated Effluent

Storage Tank

10 KL

Treated Effluent

Storage Tank

10 KL

Treated Effluent

Storage Tank

PETL, Panoli

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After proposed expansion, M/s. Wanksons Chemical Industries Pvt. Ltd. is going to discontinue

two existing 5 KL Equalization cum Neutralization Tanks and proposes 3 nos. of 60 KL

Equalization cum Neutralization Tanks. Other treatment facilities and disposal mode will remain

same as existing.

PROPOSED ETP FLOW DIAGRAM:

5 KL

Equalization cum

Neutralization Tank

Raw Effluent

Caustic

Filter Press

30 KL

Raw Effluent Storage

Tank

Near 3-CPP Plant

10 KL

Treated Effluent

Storage Tank

10 KL

Treated Effluent

Storage Tank

20 KL

Treated Effluent

Storage Tank

PETL, Panoli

60 KL

Equalization cum

Neutralization

Tank

60 KL

Equalization cum

Neutralization

Tank

60 KL

Equalization cum

Neutralization

Tank

10 KL

Treated Effluent

Storage Tank

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ANNEXURE-6

DETAILS OF HAZARDOUS/SOLID WASTE GENERATION, MANAGEMENT AND DISPOSAL

SR.

NO.

TYPE OF WASTE CATEGORY

NO.

QUANTITY MODE OF DISPOSAL

EXISTING

(As per

current

CC&A)

TOTAL

AFTER

PROPOSED

EXPANSION

1 Used oil 5.1 0.008

MT/Month

0.092

MT/Month

Collection, Storage & sell

to MoEF/GPCB approved

vendor.

2 Discarded

Drums/Carboys/

HDPE

Bags/liners

33.1 1.6

MT/Month

(30 #/Month)

92

Nos./Month

Collection, Storage,

Decontamination & sell

to GPCB authorized

vendor.

3 ETP sludge 34.3 0.41

MT/Month

2.91

MT/Month

Collection, Storage &

send to common TSDF

site of M/s. BEIL, or M/s.

SEPPL.

4 Distillation

Residue

36.4 -- 9.16

MT/Month

Collection, Storage &

send to CHWIF of M/s.

BEIL or M/s. SEPPL.

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ANNEXURE-7

POWER AND FUEL REQUIREMENTS

• Power Requirement

Sr.

No.

Requirement Source

Existing Total After

Proposed

Expansion

Existing After Proposed Expansion

1. 1000 KVA 1000 KVA • DGVCL (GEB)

• D.G. Set - 1 no.

- 350 KVA capacity

(emergency standby)

• DGVCL (GEB)

• D.G. Sets - 3 nos.

- 350 KVA capacity (1 Nos.)

- 380 KVA capacity (1 Nos.)

- 250 KVA capacity (1 Nos.)

(emergency standby)

• Fuel Requirement

Sr.

No.

Fuel Requirement (to be used in emergency only)

Existing Total After Proposed

Expansion

1. Natural Gas 2290 SM3/day*

(206 SM3/day)**

2490 SM3/day

2. Diesel 90 Liter/hr.*

(20 Liter/hr.)**

235 Liter/hr.

* Actual quantity used

** Typographic error in current CC&A valid up to 4/4/2019.

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ANNEXURE-8

HAZARDOUS CHEMICAL STORAGE AND HANDLING DETAILS

Sr.

No.

Name of

Hazardous

chemical

Quantity Places of its

Storage

(Storage

tank

/drums

/cylinders

/barrels)

No. of

Storages

Places of its

Storage State

Type of

Hazards

Control measures

provided Max. that

Can be

Stored

Actually

stored

(Including in

process

& handling)

1. Toluene 10 KL 8 KL Tank 1 Tank Farm

Area

Liquid Flammable/

Toxic

• Closed handling and

transferring systems

for Hazardous

chemicals.

• Dyke walls and

material collection

systems are provided

to all material storage

tanks.

• Fire Extinguishers and

absorbents will be

available near storage

tanks and storage area.

• Drums to be stored on

pallet with the suitable

trap.

2. Methanol 12 KL 12 KL Drums 60 # Storage Area Liquid Flammable

3. Chlorine 900 Kg (60 x 900 Kg) Tonner 60 #

(54 MT)

Storage Area Liquid Flammable

4. Sodium

Methoxide

4 MT 4 MT Bags 80 # Storage Area Liquid Flammable

5. Bromine 3 MT 3 MT Glass Bottle 1000 # Storage Area Liquid Toxic &

Corrosive

6. HCl

(30-32%)

125 KL 125 KL PP Storage

Tank

5 Tank Farm

Area

Liquid Corrosive

7. H2SO4 (98%) 40 KL 40 KL Storage

Tank (20 KL)

2 Tank Farm

Area

Liquid Corrosive

8. Ethyl

Alcohol

330 KL 256 KL Storage

Tank

5 Tank Farm

Area

Liquid Flammable

9. Thionyl

Chloride

5 MT 5 MT Drums 25 # Storage Area Liquid Toxic &

Corrosive

10 Benzene 10 KL 10 KL Tank 1 Tank Farm

Area

Liquid Flammable

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11 IPA 10 MT 10 MT Drums 50 # Storage Area Liquid Flammable

12 o-Xylene 1 MT 1 MT Drums 5 # Storage Area Liquid Flammable

13 MDC 3 MT 3 MT Drums 15 # Storage Area Liquid Flammable

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ANNEXURE-9

DETAILS OF SOURCE OF EMISSION

Sr.

No.

Stack/Vent attached

to

Stack

Height

(meter)

Stack

Diameter

(meter)

Fuel name &

Quantity

Type of

Emission

APCM

Existing

1 Boiler

(3 TPH)

30 # 0.406 Natural Gas

2290 SM3/day*

(206

SM3/day)**

PM

SO2

NOx

--

2 Process Vent

(Chlorinator &

Distillation Reactor)

13 0.15

-- HCl

Cl2

Existing

Water Scrubbers

(4 Nos.) + Caustic

Scrubber (1 Nos.)

+

Additional (Proposed)

Water Scrubber

(1 Nos.) + Caustic

Scrubber (1 Nos.)

3 Dust Collector

(Power –

Formulation Unit)

20 0.15 -- PM

SO2

NOx

--

4 D.G. Set

(350 KVA)

(Use in emergency

only.)

-- -- Diesel

90 Liter/hr.*

(20 Liter/hr.)**

PM

SO2

NOx

--

Proposed

5 Thermc Fluid Heater

(4 Lac Kcal/hr)

30 # 0.406 Natural Gas

(200 SM3/day)

--

6 D.G. Set

(380 KVA)

(To be use in

emergency only.)

-- -- Diesel

90 Liter/hr.

PM

SO2

NOx

--

7 D.G. Set

(250 KVA)

(To be use in

emergency only.)

-- -- Diesel

55 Liter/hr.

PM

SO2

NOx

--

* Actual quantity used.

** Typographic error in current CC&A valid up to 4/4/2019.

# Common stack between existing boiler and proposed thermic fluid heater.

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ANNEXURE - 10

SOCIO - ECONOMIC IMPACTS

1) EMPLOYMENT OPPORTUNITIES

The manpower requirement is expected to generate some permanent jobs and secondary jobs

for the operation and maintenance of plant. This will increase direct/indirect employment

opportunities and ancillary business development to some extent for the local population. This

phase is expected to create a beneficial impact on the local socio-economic environment.

2) INDUSTRIES

Require raw materials and skilled & unskilled laborers will be utilized maximum from local area.

The increasing industrial activity will boost the commercial and economical status of the locality,

to some extent.

3) PUBLIC HEALTH

The company will regularly examine, inspects and tests its emission from sources to make sure

that the emission will keep below the permissible limit. Hence, there will not be any significant

change in the status of sanitation and the community health of the area, as sufficient measures

will be taken under the EMP.

4) TRANSPORTATION AND COMMUNICATION

Since the existing Panoli GIDC estate is having proper linkage for transport and communication,

the development of this project will not cause any additional impact.

In brief, as a result of the proposed project, there will be no adverse impact on sanitation,

communication and community health, as sufficient measures will be proposed to be taken

under the EMP. Hence, proposed project is not expected to make any significant change in the

existing status of the socio - economic environment of this region.

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ANNEXURE – 11

PROPOSED DRAFT TERMS OF REFERENCE

1. Project Description

• Justification of project.

• Promoters and their back ground

• Project site location along with site map of 10 km area and site details providing various

industries, surface water bodies, forests etc.

• Project cost

• Project location and Plant layout.

• Infrastructure facilities

• Water source and utilization including water balance.

• List of Products & their production capacity

• Details of manufacturing process of proposed products

• List of hazardous chemicals

• Storage and Transportation of raw materials and products.

2. Description of the Environment and Baseline Data Collection

• Micrometeorological data for wind speed, direction, temperature, humidity and rainfall in 5 km

area.

• Other industries in the impact area

• Prevailing environment quality standards

• Existing environmental status vis a vis air, water, noise, soil in 10 km area from the project site.

• Ground water quality at 5-6 locations within 10 km.

• Complete water balance

3. Socio Economic Data

• Existing socio-economic status, land use pattern and infrastructure facilities available in the study

area were surveyed.

4. Impacts Identification and Mitigatory Measures

• Identification of impacting activities from the proposed project during construction and

operational phase.

• Impact on air and mitigation measures including green belt

• Impact on water environment and mitigation measures

• Soil pollution source and mitigation measures

• Noise generation and control.

• Hazardous/Solid waste quantification and disposal.

• Control of fugitive emissions

5. Environmental Management Plan

• Details of pollution control measures

• Environment management team

• Proposed schedule for environmental monitoring including

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6. Risk Assessment

• Objectives, Philosophy and methodology of risk assessment

• Details on storage facilities

• Process safety, transportation, fire fighting systems, safety features and emergency capabilities to

be adopted.

• Identification of hazards

• Consequence analysis

• Recommendations on the basis of risk assessment done

• Disaster Management Plan.

7. Information for Control of Fugitive Emissions

8. Information on Rain Water Harvesting

9. Green Belt Development plan

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ANNEXURE – 12

COPY OF LAND POSSESSION / PLOT ALLOTMENT LETTER

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ANNEXURE – 13

COPY OF CETP AND SPRAY DRYER MEMBERSHIP LETTER

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ANNEXURE – 14

COPY OF COMMON TSDF & HWIF MEMBERSHIP LETTER

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ANNEXURE – 15

TOPOSHEET

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ANNEXURE – 16

COPY OF GIDC LETTER FOR WATER SUPPLY