63
Ɏɟɞɟɪɚɥɶɧɨɟ ɚɝɟɧɬɫɬɜɨ ɩɨ ɨɛɪɚɡɨɜɚɧɢɸ Ƚɨɫɭɞɚɪɫɬɜɟɧɧɨɟ ɨɛɪɚɡɨɜɚɬɟɥɶɧɨɟ ɭɱɪɟɠɞɟɧɢɟ ɜɵɫɲɟɝɨ ɩɪɨɮɟɫɫɢɨɧɚɥɶɧɨɝɨ ɨɛɪɚɡɨɜɚɧɢɹ ©Ɉɦɫɤɢɣ ɝɨɫɭɞɚɪɫɬɜɟɧɧɵɣ ɬɟɯɧɢɱɟɫɤɢɣ ɭɧɢɜɟɪɫɢɬɟɬ» ɅɎ. Ʉɚɥɢɫɬɪɚɬɨɜɚ, ɋȼ. Ⱦɚɧɢɥɨɜ, ȼɂ. ɋɭɪɢɤɨɜ, ɇɉ. Ʉɚɥɢɫɬɪɚɬɨɜɚ ɈɋɇɈȼɕ ɎɂɁɂɄɂ ɌȼȿɊȾɈȽɈ ɌȿɅȺ ɤɨɧɫɩɟɤɬ ɥɟɤɰɢɣ Ɉɦɫɤ, 2010 ɝ.

H K G H < U N B A B D B L < ? J > H = H L ? E · 2014-04-24 · I h ^ ] h l h \ e _ g g Z d Z n _ ^ j _ n b a b d b b h ^ h [ j _ g j _ ^ Z d p b h g g h b a ^ Z l _ e v

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Page 1: H K G H < U N B A B D B L < ? J > H = H L ? E · 2014-04-24 · I h ^ ] h l h \ e _ g g Z d Z n _ ^ j _ n b a b d b b h ^ h [ j _ g j _ ^ Z d p b h g g h b a ^ Z l _ e v

»

. , . ,. , .

, 2010 .

Page 2: H K G H < U N B A B D B L < ? J > H = H L ? E · 2014-04-24 · I h ^ ] h l h \ e _ g g Z d Z n _ ^ j _ n b a b d b b h ^ h [ j _ g j _ ^ Z d p b h g g h b a ^ Z l _ e v

2

539.21 (075) 22. 37 73

17

:

. - ., . . . ;. - . .- . , . .

. . , . , . , . . .17 . . - : ,

2010. - 62 .

. .

, 2010

Page 3: H K G H < U N B A B D B L < ? J > H = H L ? E · 2014-04-24 · I h ^ ] h l h \ e _ g g Z d Z n _ ^ j _ n b a b d b b h ^ h [ j _ g j _ ^ Z d p b h g g h b a ^ Z l _ e v

3

, ,,

. , , .

: ,.

, .

. ,

, ,

. () ( -

) ( ).:

), . , .

, ,

.

..

, .

., ,

: ( ). .

,

, , .

.

Page 4: H K G H < U N B A B D B L < ? J > H = H L ? E · 2014-04-24 · I h ^ ] h l h \ e _ g g Z d Z n _ ^ j _ n b a b d b b h ^ h [ j _ g j _ ^ Z d p b h g g h b a ^ Z l _ e v

4

1. .

1.1.

. – , ( , ,

. .) . , ,

, . .

. , ,

. .

. .

.

. , .

. . :

, ,

.

. , .

(, .) :

. – .

, .

, ,

), 10–4 . ,

.

– ( . 1.1).

Page 5: H K G H < U N B A B D B L < ? J > H = H L ? E · 2014-04-24 · I h ^ ] h l h \ e _ g g Z d Z n _ ^ j _ n b a b d b b h ^ h [ j _ g j _ ^ Z d p b h g g h b a ^ Z l _ e v

5

. 1.1

, .

, 10–6 10–8 , – .

, , ,

, , . .

1.2.

. , :

, , , .

, .

1. . ~104 .

. , , , ,

. , , , ,

, .2.

. ,, .

~106 .

.3.

,

Page 6: H K G H < U N B A B D B L < ? J > H = H L ? E · 2014-04-24 · I h ^ ] h l h \ e _ g g Z d Z n _ ^ j _ n b a b d b b h ^ h [ j _ g j _ ^ Z d p b h g g h b a ^ Z l _ e v

6

. , . 106 ,

.4.

. 106 .5. ,

, , , , . . , ,

.

. . , , ,

.

, ,. ,

. .

: )/rexp(U , r – , 053.0 – .

. r :

)/rexp(U , – , .

: F ,

r ;

F , , F ( .1.2).

r0 , ,

, U . , r0,

, r0 ,

– .

0

U

r

r

r0

Uc

F

F

F

F

0

Page 7: H K G H < U N B A B D B L < ? J > H = H L ? E · 2014-04-24 · I h ^ ] h l h \ e _ g g Z d Z n _ ^ j _ n b a b d b b h ^ h [ j _ g j _ ^ Z d p b h g g h b a ^ Z l _ e v

7

, .

, .

1.3.

.

, ( , ,), .

. , x, y, z ( . 1.3):

ox – a, 2a, 3a, … ma; oy – b, 2b, 3b, … nb; oz – c, 2c, 3c, … pc .

cpbnamr .a , b c ,

– ( . 1.4). , ( )

. , a , b c

. . ,

( . 1.3). ( )

. , , .

. . .

: a, b, c , , .

( . 1.4).

a2ama

b 2b nbc2c

pc

x

yr

z

a

b

c

Page 8: H K G H < U N B A B D B L < ? J > H = H L ? E · 2014-04-24 · I h ^ ] h l h \ e _ g g Z d Z n _ ^ j _ n b a b d b b h ^ h [ j _ g j _ ^ Z d p b h g g h b a ^ Z l _ e v

8

, , .

, ( .1.5).

: ,

, , (), ,

.

x, y, z. , : = b = c;

= = = 90 0, , b, - , , -.

. : -

; ( ) - ; ( ) -

( .1.6). 14 ,

.

,

, . : ( ), ( )

) ( .1.7). , .

. , . . 1.8

Page 9: H K G H < U N B A B D B L < ? J > H = H L ? E · 2014-04-24 · I h ^ ] h l h \ e _ g g Z d Z n _ ^ j _ n b a b d b b h ^ h [ j _ g j _ ^ Z d p b h g g h b a ^ Z l _ e v

9

. .

, ,a b ( .1.8).

.

. ., ,

, – ,.

.

, .

( , ) – . ,

, L. , , ( L), – HKL ,

– [[HKL]]..

: x, y, z. :

x = Ha, y = Kb, z = Lc, a, b, c – ; H, K, L – .

, H, K, L.

: [[HKL]]. (–). , x = –2a, y = –1b, z = 3c

: [[ 312 ]]..

, . [[HKL]] , .

[[HKL]] .: [HKL]. ,

, , .

Page 10: H K G H < U N B A B D B L < ? J > H = H L ? E · 2014-04-24 · I h ^ ] h l h \ e _ g g Z d Z n _ ^ j _ n b a b d b b h ^ h [ j _ g j _ ^ Z d p b h g g h b a ^ Z l _ e v

10

. A, B, C, .

: A, B, C , : 1/A, 1/B, 1/C.

. D.A/DH , B/DK , C/DL .

: (HKL).

(100) (110) (111)

, , , A =1/2, B = 2, C =1/3. 1/A = 2, 1/B= 1/2, 1/C = 3. D=2. : H = 4, K = 1, L = 6.

: (416). ( )

222 LKHad , a – ., H, K, L,

. . 1.9.

1.4.

. ,

.

( .1.10).

, ,

, .

, ,

, . , ,

, ,

Page 11: H K G H < U N B A B D B L < ? J > H = H L ? E · 2014-04-24 · I h ^ ] h l h \ e _ g g Z d Z n _ ^ j _ n b a b d b b h ^ h [ j _ g j _ ^ Z d p b h g g h b a ^ Z l _ e v

11

. , Sin2d ( . 1.10).

, , :

Sin2dHKL

dHKL - , - , k - : k = ±1, ±2…

,

, . .

1.5.

: 1) ,; 2)

,. 3) ; 4)

5) .,

, .

, – .

.

. , , .

, :: 13,3 0

, . . ,

, . 13.3 0

,

, . –

, . – C,

Fe, Ni, Co, W, Ti, B, Be ., .

Page 12: H K G H < U N B A B D B L < ? J > H = H L ? E · 2014-04-24 · I h ^ ] h l h \ e _ g g Z d Z n _ ^ j _ n b a b d b b h ^ h [ j _ g j _ ^ Z d p b h g g h b a ^ Z l _ e v

12

. ,

.

1- . . ,

, ,

.

2.

2.1.

, .

, , – .

, , , ,

. .

: dE = TdS – dV + dN ,

– , dN – ; – ; dS dV –

. . . ,

, dS = 0 dV = 0. dE = dN. , dN/dE . ,

.

(x,y, z) (Px, Py, Pz) .

,

. , ( 1023!).

. , , , .

Page 13: H K G H < U N B A B D B L < ? J > H = H L ? E · 2014-04-24 · I h ^ ] h l h \ e _ g g Z d Z n _ ^ j _ n b a b d b b h ^ h [ j _ g j _ ^ Z d p b h g g h b a ^ Z l _ e v

13

. .

: . : S =1/2, 3/2. , , . –

: S = 0, 1. , , ..

« » ( ), « ».

« » . « » . ,

N G , . “ ” N/G.

, N/G << 1. (G>>N).

, ,

. . , N/G << 1

. N/G 1 ( G

N), , ,, . ,

N/G 1, .,

, . ( ),

G . ,, .

. . –,

– .,

N/G<<1. G

, ).

.

Page 14: H K G H < U N B A B D B L < ? J > H = H L ? E · 2014-04-24 · I h ^ ] h l h \ e _ g g Z d Z n _ ^ j _ n b a b d b b h ^ h [ j _ g j _ ^ Z d p b h g g h b a ^ Z l _ e v

14

2.2.

, ,

.

N(E)dE , E E + dE, ,

( - , – ).

g(E)dE, dE, – f(E): N(E)dE = f(E) g(E) dE (2.1)

f(E) . ( ,

). , g(E)

f(E).

2.3.

(x, y, z) (Px, Py, Pz). x, y, z, Px, Py, Pz

(x, y, z, Px, Py, Pz). , .

= V p = dx dy dz dpx dpy dpz. V = dx dy dz

, p = dpx dpy dpz –.

, V, p,

..

, , (x, y, z, Px, Py, Pz) (x+dx, y+dy, z+dz, Px+ dPx, Py+ dPy, Pz+d Pz), dx dy dz dpx dpy dpz < h3.

, ,

, h3.

,

Page 15: H K G H < U N B A B D B L < ? J > H = H L ? E · 2014-04-24 · I h ^ ] h l h \ e _ g g Z d Z n _ ^ j _ n b a b d b b h ^ h [ j _ g j _ ^ Z d p b h g g h b a ^ Z l _ e v

15

= V P = h3.,

, . , ,

V V, . P = h3/V.

(h3

h3/V) .

2.4.

, +d .

+d . ( . 2.1). ,, 4 p2dp.

dpph

V4dpp4 23

p

2

.

, , dp, +d ,

dpph

dppg 23 .

dpmpdE,

m2pE

2

.

dEE)m2(h

V2dE)E(g 23

3.

g(E) ,

E)m2(h

V2)E(g 23

3 .

, E ( . 2.2).

, m

m*.

. –

g(E)

0 E

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16

, , ,

. me

*= me. , , ,

, . , , .

dEE)m2(h

V4dE)E(g 23

3 ;

E)m2(h

V4)E(g 23

3 .

. n 5 1028 -3,m = 9,1 10–31 . n m

105 K. ,

.

, n. n 1022 –3 .

,

. .

f(E) (2.1) , , ,

, – : .

2.5.

f(E): kTE

kT ee)E(f (2.2) k – , - , – .

, :2

32

mkT2h

VNlnkT .

(2.2), :

kTE2

32

M emkT2h

VN)E(f .

Page 17: H K G H < U N B A B D B L < ? J > H = H L ? E · 2014-04-24 · I h ^ ] h l h \ e _ g g Z d Z n _ ^ j _ n b a b d b b h ^ h [ j _ g j _ ^ Z d p b h g g h b a ^ Z l _ e v

17

, fM(E)dE, E E+dE;

. fM(E) .2.3.. E = 0

E . ,

.

. fM(E) g(E)dE,

: dEEee)m2(h

V2dE)E(N kTE

kT23

3

:

dEEe)kT(

N2dE)E(N kTE

3 .

.

.2.4. E

.

2.6.

:

1e

1)E(fkT

E (2.3)

- , .

(2.3) , E= 2/1)(f T 0. –

, 1/2. (2.3) . ,

,,

. . 2.5 .

fM

0 E

kTE

e

kTe

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18

. N,

N/2. .

EF,

. . , E<EF , E>EF . , T = 0 K

E<EF 1, E>EF .

F

F

EE0EE1

)E(f

(2.3), , T = 0 K = EF.

1e

1EfkT

EE F (2.4)

. 2.6.

(2.4) g(E)dE, :

dEE)m2(h

V4dE)E(N 23

3 .

N(E) .2.7.

0 EF, :

23

F2

3

3 E)m2(h3V8N .

EF .

322

F 8n3

m2hE ,

n = V/N - .

N/2

EF

00

0

1

2

-

-

-

-

Page 19: H K G H < U N B A B D B L < ? J > H = H L ? E · 2014-04-24 · I h ^ ] h l h \ e _ g g Z d Z n _ ^ j _ n b a b d b b h ^ h [ j _ g j _ ^ Z d p b h g g h b a ^ Z l _ e v

19

5 . ,

<E0> T = 0 K. , 3E5/3E F0 .

, TF, : F = F/k. ,

, , kT, EF.

TF 104–105 K. , TF,

.

, . , ,

kT EF,

kT,

. ,

kT .

, , EF,,

. . .2.8

T=0 T>0. , kT

“ ” , EF. , E<EF

, EF, : kT 0,025 , N/N ‹ 1 %, T = 1000 K, N/N = (1– 2) %.

, , ,

. 1%

. f (E)g(E)dE

, N:

0 kTE

21

23

30 1e

1dEE)m2(h

V4dE)E(g)E(fN .

.

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20

T:2

F

2

F EkT

121E .

kT<<EF, T

. N/G‹‹1 ,

. f(E)

, : f(E)<<1., )kT/)Eexp(( >> 1.

, E = 0, )kT/exp( ››1. ,

– kT: – >kT.

kT. ,

)kT/)Eexp(( ›› 1 f (E)

kTE

kTkTE

kTE eee

e

1)E(f .

(2.2) – -, , .

, .

2.7.

, , , ,

, « », .

:

1e

1)E(fkT

E .

. , T

.

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21

,. S=1 .

..

1) .2) , c = 3 108 ,

: E = h= ;

cchp , , E = pc.

3) , ,

. ,.

. 4) ( ) ( )

. . V

T N0, .

: 0)dN/dE( T,V . ,

T,V)dN/dE( . , = 0.

. , =0,

, . = 0,

1e

1

1e

1)E(fkTkT

E .

. , E = . ,

, (

).

3.

3.1.

.

. . ,

Page 22: H K G H < U N B A B D B L < ? J > H = H L ? E · 2014-04-24 · I h ^ ] h l h \ e _ g g Z d Z n _ ^ j _ n b a b d b b h ^ h [ j _ g j _ ^ Z d p b h g g h b a ^ Z l _ e v

22

, ,

. . , ,

, 3N, N – .

– , a ,

( .3.1 ) ,

( . 3.1 , 1).,

( 2). , ( 3) .

, , ( . 3.1 ): min=2a.

max, : max= a

vv2

min

, (3.1)

v – .

k , /2k . (3.1) ,

= kv.,

), . k

. 3.1 .

a)

a

0a a

k

)

)

min)

12

3

0a2 a2

k

)

)

1

2

Ma)

2aM Mm m

)

)

a

1 12 2

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23

, , ( . 3.2 ).

M, – m. . 3.2 ). :

k=0, =0. ,

. – , ,

. . , ( . 3.2 )

. ,

. , . .3.2

(1) (2), . ,

k a/2kmax , max

k = 0, k kmax.

, ,

, .2.2 . .

.

3.2.

.

( .3.1)., ,

: n/L2n , (n = 1, 2, 3…N), L – , N –.

Z, n,, , n: n/L2nZ .

V, , . , 3/V4Z .

= 2 v/ , 3

32v2VZ (3.2)

(3.2),

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24

dv2

V3d)(gdZ 232 (3.3)

(3.3) , +d .

232v2

V3ddZ)(g (3.4)

d, , . g( )

. ,

, 3N, g( )

:0

N3d)(g , (3.5)

– , . (3.4) (3.5) ,

N3v2

V32

3

. (3.6)

:3 2 V/N6v ,

k =

: k , k– .

, .

( ) . v3 (3.6) (3.4)

:

3

2

N9)(g . (3.7)

3.3.

. ,

. ,

, . i-, i Ei .. Ei

. , i: Ei .= Ei ., 3N ,

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25

N3

1i..EE . (3.8)

, , N , , 3N

.

N

. ,

, . ,

:)2/1n(En ,

– , n = 0, 1, 2 – ..3.3.

, , .

E .=E ., (3.8), (

) . , ,

.

. , , , – .

, .: kv/P , k = 2 / - , v –

, . – . ,

. – ,

. , .

).,

11

11

kTkT eeEf (3.9)

0

n=0

n=1

n=2n=3

n=4

E0=½

E

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26

f(E) . 3.4. ,

T

kT; ,>kT,

. , T<

, kT.

, f(E), . , (3.9) ,

<E .> , .

1.. kTeE (3.10)

” . 3- ( .3.3), 2/13E3 ;

, “ ” .

( ).

,, ,

.

.

3.4.

, N , 3N ,

, kT (1/2 kT 1/2 kT ).

, , R3NkT3U A . (k – , NA – , R – ).

:

25R3dTdUC /( ).

, CV.

f(E)

0 EkT 2kT 3kT

0,60,16 0,05

8

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27

, (1819 .) ,

25 /( ). . ,

( >1) ( .3.5).

. 3R

0 0.3 0.6 0.9 1.2

. ,

N N, , –

, , – . 3N

. , , ,

. 3N..

U . ,

d g( )d (3.3). (3.10),

, dd)(gEdU .. .

, . 0 , .

0.. d)(gEU .

g( ) (3.7) <E .> (3.10),

0 kT

3

3

1e

dN9U . (3.11)

Page 28: H K G H < U N B A B D B L < ? J > H = H L ? E · 2014-04-24 · I h ^ ] h l h \ e _ g g Z d Z n _ ^ j _ n b a b d b b h ^ h [ j _ g j _ ^ Z d p b h g g h b a ^ Z l _ e v

28

kT/x 1 . (3.11) :

T

0x

34

o 1edxxTR9UU , (3.12)

U = 9R /8 – .

T

0Tx

33

v 1eT3

1exT123RC . (3.13)

CV(T). .

(T<< ) (3.12)

. 0

4

x

3

151edxx

44

0T

5UU

T, CV:3

4

VTR

512C T3 . (3.14)

, .

( >> ) x (3.12) ,

ex = 1+x+… .

T

0

2

4

0 3RTdxxT9RUU T

R3dTdUCV = 25 /( ).

.

, .

, (3.13).

, :

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29

(T<< ) , ,

, . E ., T; ,

, T3. T4,

– T3 ( ).

U T.

, , , ,

T CV T ( ). ,

, .

. .

3.5.

C ,

, :

.

.3.6). r0,

U0 ( abc).

.

O. , 2. ,

O..3.6 E .

2 1

. , E .

r0

a’ ad

c’

c

A’A B’ BO O’

E

2

<x>

x1 x2

1

U0

U(x

)U0

U(x

)

b

U

r

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30

U(x)=E –(U0–U(x)), 2 x1. 2

1 . B,

x2, E , U(x)=E

– (U0–U(x)). 2 ,

, f(x), x,

xf (3.16) U(x)

a bc .3.6), 2/x)x(U 2 (3.17)

bd, U r0. x1 x2

A 0.

, ,

. abc , .3.6,

bd. , .

(3.17) – 3/gx 3 ,. (3.16) (3.17) :

3gx

2 x)x(U

32

(3.18)

2gx xxU)x(f (3.19)

, 2 (x2>x1).

2 ( O ) ( ), .

<x>. ,

, .

. , 2 ,

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31

(3.19) 2xgxf .

<f> = 0, g <x2> = <x>. 2xgx . (3.20)

(3.18),

2

xxU

2

. xU2

x 2 .

(3.20),

: 2

)x(Ug2x .

U(x) E , <U(x)>=<E >. E=<E >+<U(x)>=2<U(x)>.

<x> :2/gEx .

, <x>

, Er

grx

02

0,

V0

20

CdTdE

rg

dTxd

r1

(3.21),

02rg

, dTdECv – , .

, .

1) E = kT, CV = k,

02V rgkC . (3.22)

g, k, , r0 10–4–10–5, .

, .

2) CV:

. , , (3.22)

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32

= V /3V – , V – , –

, 1,5 2,5.

3.6. ( )

, , .

, ,

. , .

, ,.

; .

, (3.19) .,

,.

.

, .

,

. ..

r , 2r . , ,

. ,

g, g: g2.

, < > , . ,

. ,

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33

n1

2gn1

, (3.23)

n – .

:

vCV31

,

V = V .– , < > – , V –.

< > (3.23),

2V

gnVC

. (3.24)

, (3.24).

1) n T,

2V

TgVC

. (3.25)

CV T,

, . (3.25) g V,

, . V , g ,

( )

. (2.25). . ,

, .

. , =550 /( ),

– (407 /( )).2)

T, < /20 ,

. , < >,

.

T CV. CV T3, T3, .

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34

. 3.9. T3.

, . ,

n

< >, .

n T;

n,

, T.

T ( 1/T).

4.

4.1.

. , 1 3 , 1023 – 1024

, . , ,

. . ,

. ,

. : 1)

, , ;

2) ,;

3) ,

. ,

. , ,

( , ), : , –

T,K40

T1

3T

800

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35

. , .

4.2.

, ,

. (Z =11). U r

.4.1 . E . 11

: 1s 2 , 2s

– 2 , 2p – 6 , 3s – 1 . . 1s, 2s, 2p

; 3s – ; , 3s, .

U U

3d 3d 3p 3p 3s 3s

U0

2p 2p 2s 2s

1s 1sl

r>>a

. 4.1

, (r>10–9 ),

. l >> a, a –

. ,, .

. , r = 3 , 3s –

1020 .

r

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36

r < 10-9 (=0,43 ) .

N [N=(1023 - 1024) -3] : l ~

( .4.2). 3s– 3s–

, .

. 105 . ,

10–15 . .

. , –

.

U r

U0

l

r=a. 4.2

,

. : htE , t –

E E E, E .

, E .

t = 10–8 , t/hE

= 6,63·10–34/(10–8 1,6·10–19) ~ 10–7 .

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37

E . , ,

, ( .4.3).

, , D (U0–E) l,

D=Doexp(- E)2m(U2o ). (4.1)

(4.1) D0 . :

m = 9.1 10-31 ; E = 10 ;l = 10-10 ; U0 – E = 10 .

, V 105

, 0 = V/r (, ).

= 0 D = VD/r.

EU2m2expVr

0 .

= 10–15 . , E

1 .,

107 , ( .4.4). ,

.U

U0

E

r r

. 4.3

, ,

l

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38

. , .

, . ,

, . 1s–

1020 , , ,

.

4.3.

, , ), ( ).

, , ,

( . 4.5).

. ,

.

( . 4.6).

r1, r2. r1

. r2 .,

.

E=10-7

10-23

3s -(N )

3s - E

3p

N 3s

2p

2s

1s

6N

2N

2N

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39

, .

, .

, .,

N (N = 1023 – 1024 ). (3s– ) 1 1 /1023 = 10–23 .

, .

, . ,

, 2(2l+1) (l), , , 2N(2l+1) . .4.5

. 1s, 2N ; 2s– , 2N

; 2p– , 6N , . 3s– ( N N/2

). 3p– ., , ,

, - .,

(),

E

r1

c ( )p

r

3s

2p

3s

2p

r2

r2 r1

2s

1s

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40

. .

4.4. , ,

: 1) 2) . ,

,

.

, ( .4.7 ). ,

, ,

( .4.7 ).

=0

, 1 ,

.4.8 ).

1 , ( .4.8 ).

, ,

( ), .

10-23 . , , 10–4 – 10–8 .

. ,

. , .

, .

a)

)

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41

, , . ,

, .

. = 0 .

. ,, .

. , ,

. .

. ( E>1 ),

. .

5. 5.1.

,

2/R3C e . (5.1)

, , ,

: 2/R92/R3R3C .

, ,

R3C .

, , .

, , . ,

. , N,

.

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42

FE2kTNN , EF – .

T 300 K EF = 7 , N/N = 0,002 , . . 1 %. , ,

kT, . , , kT N,

:

Fe E2

kTNkTNkTE .

F

ee E

kTNkdTdE

C .

Ce:F

2e E2

kTNkC . (5.2)

(5.2) :F

2

e TTzR

23C , (5.3)

z , . (5.3) ,

, F.

.

. 5.1. (5.1) (5.2),

Fe

e

EkT

CC

. (5.4)

(5.4) ,

, kT ‹‹ EF.

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43

%1EkT

F, Ce 0,01 .

, .

T3 , Ce,

, C ..5.2 ,

.

.

5.2. ,

. , .

, , .. , .

.,

,.

, :

.V31

,V31

...e..

.

(5.5)

– , <V> -, < > - .

C = (5.2)

e= TVm

Nk3 e

Fn

23

(5.6)

mn – , VF – .

. , (5.6), < e>. n : < e> 1/n .

n T. (5.6), e =const.

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44

, , .

n T3, < e> 1/ T3. (5.6), e 1/ 2. ,

, , ,

.

, ,

, .

< e> 1/nn (nn– )

T:e T.

(T)

. 5.3.

,

. : 01,0C/Ce V , /105V 3 , 10 9 , /10V 6

F , 10 8e .

(5.5) 2. 1010 .

5.3.

, ,

. .

, , ,

, , .

n . V .

iVn1V . (5.7)

T,K20

2T1

T

6040 80 100

const

0

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45

– .

– .

, VrF , (5.8)

r – .

» : VrEedtVd

m , (5.9)

m* – . V .

. (5.9) 0E ,

0VrdtVd

m .

. t

mr

e)0(VV , (5.10))0(V - .

(5.10) , r/me . .

(5.10) (5.8)

VmF

,

: 0VmEe . .

mEeV . (5.11)

Venj , e – , n – , V . –

, (5.11).

Em

nemEenej

2

.

Ej , - , ,

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46

mne 2

(5.12)

: m2ne 0

2

, (5.13)

0 – : V/0 , m – ) . (5.12) (5.13) ,

. , ,

(5.12), .

. , 1/

: T/1 .

5.4.

1911 . , , ,

4,2 . , .

,

, ,

– .

.5.4. , ,

T . 20 .

:1) ,

.2)

T , , .

.

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47

., .

• ,.

• (). ,

, .

, ( =0), ,

.•

( ),.

( ).

. B . B = 0,

B , 0 –

. .5.5.

• , , , I .

. I . B T ( .5.5).

• ,

. ,

, I .

• ,

( ). U,

, = 2eU/h ( ). ,

. 1957 . . , . .

. . (1972 .). . ,

.

B

T0

0B

T

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48

, ,,

.

. , , . , .

, . ,

, , .

. . , ,

( ) . ” ,

. ,

. , ,.

- . ,

, - ., .

, . , ,

. , ,

, . .

. , , 10–4 ,

. 103

, . . .

T, , , .

” , . T T , ,

T=T .

. , , , ,

E .

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49

, . , ,

, E (10–3 – 10–2) , . ,

, . .

, ,

E , . ( I )

, , .

E T=T .

( ) . , ,

, , ,0:

= n 0 ,q/20 .

1961 ..

0, q (q=-2e). ,

, -2e.

.

, 107 . (), ,

, ( ),. ,

, .

5.5.

. , . ,

,

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50

) , .5.6 ).

.

) (). ,

, , ( . 5.6 ).

. ( .5.6 ).

F–

) ) )

, ,

.

A = U – U0 , U – , U0 –

. U0 = 0, A = U. , A < 0, U < 0.

.

( . 5.7 )

F+

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51

() .

, , ( .5.7 ), –

, ( .5.7 ).

, , , .

.

, ,

( .5.8). ,

: A = U – EF.,

, , ,

. (1 10) .

5.6.

, , .

, .

1 2 ( 1 2)

EF

U

eU

1FE

A1A2

2FE

)

eU

1 2

1 2

U

)

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52

( F1 F2) ( . 5.9 ). ,

. 1 2, , ( 1 – 2),

. 1 2 , ,

1 2 2 1.,

, ( F1 < F2). F

F. , – . ,

.

( . 5.9 ), ,, , ,

( . 5.7 5.7 ). , :.

,.

/)(U 21 . ( –

). .

.)/U F1F2

.

, .

. , , ,

, . ,

, , .

6.

6.1.

, .

Page 53: H K G H < U N B A B D B L < ? J > H = H L ? E · 2014-04-24 · I h ^ ] h l h \ e _ g g Z d Z n _ ^ j _ n b a b d b b h ^ h [ j _ g j _ ^ Z d p b h g g h b a ^ Z l _ e v

53

. ( , , .).

. ,

. ,

( 1 %).,

, E ( 1 ). ,

, ,

. ( . 6.1 ). T>0

.6,1 ). , ,

. .

, « ».

– , . ,

. , .

, ,

, . .

E

a) )

E

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54

. ,

( . 6.2). ,

:

*

*

F mm

lnkT43E

21E ,

E – ; m em – . ,

2/EEF . , ., , , E–EF

. .

kTEE F

e)E(f .2/EEE F , ,

kT2E

e)E(f . (6.1)

, , , f(E). .

, f(E). ,,

:

kTE

0e , (6.2)E - , 0 - .

f(E) 1

E

FE

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55

, :

( , ).

. 6.3 6.4. ) R( ) .

(6.2), ln = ln 0 E /2kT. 1/ , ln ( ln(1/R)),

( .6.5). ,

= 2k tg . .

.

. R

.6.3 . 6.4

, :,

. . , .

.

ln lnR1

1/

ln O lnR1

1/T

. 6.5 ,

. : –

. – , – . ,

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56

– .

:

= n + p = q n(<Un> +<Up>) .q – , n – ,

; <Un> <Up> – .

, 1 . –

- , - .

. , ,

, .

6.2.

,

, .

( n – ). ,,

, . , ( ) 5-

. E

. 6.6

. 6.7

. ,

Si

Si

Si

Si

P

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57

, ( .6.6).

,

. ( )

.,

( ) ,

.6.7). , – .

, ( .6.7).

. , – .

«n» – ( negativ – ).

( p – ). ,

, 4- 3-).

.6.8.

E

. 6.8 . 6.9

.

, .

, . .

, – . «p» (

positiv – ).

Si

Si

Si

Si

B

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58

. ( . 6.9).

. , .

.

6.3. ( )

p–n– . ,

. p-n–. p-n–

. , , p-n– , ,

. p- ( ) n- ( ) .6.10 .

, , .

n- , p- – . n- – ,

p- – – , .

,

( .6.10 ). ,

, = eU , U –.

EF

EF

EF

“n” “p” “n”“p”

“n-p”

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59

:

n- p-

. p-n – . ,

, , ,

. ,, ,

. ,

.,

p- , n- ; p- , n- ( . 6.11 ).

, , .

,

I . , – I .

, , « » . (I )

, I , , .

, (I =I ).

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60

p-n , p- , n-

), p- n- ( . 6.11 ).

I . I ( ,

, ). ,,

. , p- n- -n– . -n-

. p-n–

, , » ,

, ( . 6.11 ). p-n– . 6.12.

-n-

.

6.4.

, p-n – . ,

, . ,.

) , ( ) .,

, n-p-n p-n-p . , p-n , ,

; , .

.

, , .

I

U

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n p n

+- + -

n-p-n. (U =U =0),

. .6.13. , ,

. p-n .

E

IK I I

UK U

. 6.13

, .6.14, U ,

– U . .

( ). eU , eU .

.

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I

I 1

U U

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, .

. p-n. ,

. , .

U , U ( .6.14). U U , .

“n”- , . I , I ( .6.15).

, , ..

1. :

12const'u II|I.

.2.

1.

1. . . .: , 1979. . 32. . . .: , 1997. – 542 .3. . . .: . , 1977. –288 .4. ., . . .: . , 1971.

– 224 .

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……………………………………………………………………..31. . .…………………… 1.1. ……………….………. 1.2. ……………… 1.3. ……………………………………….. 1.4. ………………...………………...... 1.5. …………..2. ………………………………………….. 2.1. ………………... 2.2. …………………………………. 2.3. ………………. 2.4. …………………………………………….. 2.5. ……………. 2.6. …. 2.7. ……..3. ……………………………………………

3.1 ………………………………… 3.2. ………………………. 3.3. …………………………………………………………… 3.4. …………………………………….. 3.5. ……………………………… 3.6. …………………………….. …4. ………………………………………………… 4.1. …………………………….. …… 4.2. ………………………………. 4.3. ……………. 4.4. , , …5. . ………………...…………………………………………............ 5.1. ………………...……………. 5.2. …………………………………… 5.3. ………………………………… 5.4. ………………...……………….. 5.5. ………………...………………………………… 5.6. ………………...…………………………..6. . ………………...………………………………………… 6.1. ……………….. 6.2. …………………. 6.3. p-n ………………...………………………………….… 6.4. ……………………………………………………….

…………………………………………………

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