Europyro11th International GTPS Seminar

41st International Pyrotechnics Seminar

2015

to be held in TOULOUSE - FRANCECentre de Congrs Pierre Baudis from 4 to 7 May 2015

Programand Registration

EUROPYRO 2015 will focus on current status and improvements in explosives and pyrotechnic fi elds for defence, space, industry and safetyapplications.

SEMINAR TOPICS

Papers are requested on the following topics: Energetic materials and molecules including environmental friendly products, nano-scale raw ingredients, manufacturing and control processes.

New explosive devices and systems including: - Initiation and ignition technologies and systems EFI, laser, SCB, MEMS, - Miniaturisation and nanotechnologies, - Ordnance, industry and space applications,...

Insensitive explosives and munitions.

Applications to solid propulsion for small rocket motors and gas generators.

Industrial explosives and fi ring systems for blasting, new technologies and developments.

Improvised Explosive Devices (IEDs) : Countering, Detection.

Methodologies for design, reliability and lifetime demonstration, IMness justifi cations: - Modelling and simulation, - Testing methodologies and procedures.

Studies on shock wave and detonics relevant to the previous CEA managed High Dynamics Pressure workshop: - Shockwave fl ow in explosives, - Transition to detonation and advanced studies on reaction zone, - Laser induced fl ows and pulsed high powers, - Microstructural effects, behaviour laws in materials, damages, - Modelling and simulation.

Hazard, safety and risk management - Hazard assessment, - Accidental events analysis, - Explosive safety in industry and for environment.

Regulations, friendly environment design and disposal - European directives (CE 2013/29, CE2014/28, REACH, GHS and CLP, etc.), implementation to commercial explosives and pyrotechnics, - Green design, green pyrotechnic, - Disposal and recycling technologies.

Europyro2015

Poster sessionPoster session will be held permanently during the entire seminar.Panels will be provided.Posters must be displayed on Monday evening before 8.00 pm

Present your products and technologiesExhibitionBooths still available on site including advertising in proceedings and seminar attendance.Booths must be ready for visit before end of early registration (Monday 8.00 pm) and open until Thursday noon.

For more information, please contact the organi-sation at : secretariat@afpyro.org

Companions activitiesA program, referring to companions activities can be proposed on demand at registration desk.

More than 100 papers presented during plenary and posters sessions. Offi cial language is English. No simultaneous translation. Proceedings will be printed in English.

Europyro2015

41st IPS

2

Europyro2015 SEMINAR CHAIRMANDenis DILHAN: Senior Expert for Space PyrotechnicsCNES Toulouse Space CentreAirbus Defence & Space

ARIANESPACEIPE

DGA/DT/STDGA TT/SDT/AM

DGA /DT/ST/MAN/PENEXTER Munitions

INERISISL

EPC GroupeDASSAULT Aviation

EURENCOCEA

CNES CST CNES DLA

E. LACROIXHERAKLES

PYROALLIANCEINSA Val de Loire

TDA Armements SAS TITANOBEL SOFITER

MBDAENSTA Bretagne

Davey BickfordNOBELSPORT Pont de Buis

Herv GILIBERTLouis LAURENTIGA Pierre LUSSEYRANIGA Mireille CARLIER Serge ROQUESPascal VAN MELEMichel VATREYRaymond COINTEChristian de VILLEMAGNELouis CASAGRANDELaurent GATHIERDominique GUILLETDaniel VERWAERDEMarc PIRCHERMichel EYMARDEtienne BARESHerv AUSTRUYGilles FONBLANCJean Marie CASTELAINPierre BENARDHerv de SAINT-PIERREEric Louis RIBADEAU DUMASPatrick PUYHABILIERStphane PHELEP Jean Pierre GUIAVARCH

AIDICO Beatriz COLLADO Spain MSIAC Dr Michael W. SHARP Belgium - NATO ICT Dr. Manfred BOHN Germany DSTL James CALLAWAY UK TNO Ing. Wim DE KLERK Netherlands Semenov Institute of Chemical Physics Dr. Alla PIVKINA Russia MUT Technical University Prof. Dr. Stanislaw CUDZILO Poland TDW Dr. Werner ARNOLD Germany DSTO Dr. Ken SMIT Australia US Army ARDEC Jay PORET USA National Defense Academy Shingo DATE Japan

FRENCH STEERING COMMITTEE

INTERNATIONAL STEERING COMMITTEEIPS CHAIRMAN

Ernst-Christian KOCH: Defense Academy of the United Kingdom - Cranfi els University

33

Europyro2015

Europyro2015

MSIAC Energetic Materials Dr Matthew ANDREWS Belgium - NATO ICT Fraunhofer Volker WEISER Germany SANDIA National Lab. Alexander TAPPAN USA TNO Dr. Joost van LINGEN Netherland Purdue university Steven SON USA U.S. Army RDECOM ARDEC Dr. Jesse SABATINI USA SEMENOV Institut of Chemical Physics Dr Alla PIVKINA Russia ISL Christophe TAMISIER France CNES Denis DILHAN France NEXTER Munitions Frantz CAILLAU France AIRBUS Defence & Space Jean-Yves COUSIN France Herakles Sbastien VEYRY France EURENCO Serge LECUME France MBDA Michel VIVES France DGA/TT Alain YODO France E .LACROIX Dominique MEDUS France TDA Armements SAS Jean-Claude MEUNIER France

SCIENTIFIC COMMITTEEJehan VANPOPERYNGHE: Deputy Director of CEA/VALDUC

ChairmanSecretary: Anne DELMAS, CNES CST

ORGANISING COMMITTEE Joseph REFOUVELET: A3FP VicePresident Events

REGISTRATION FEES (all prices include VAT) Early registration Late Registration (Until 5th April) (From 6th April) Standard 900 1000 Speaker 800 800

The registration fees include: admission to the Welcome reception on Monday, May 4, 2015. access to all sessions of the Scientifi c Program. 3 lunches from Tuesday, May 5 until Thursday, May 7, 2015. Access to the Gala dinner on Wednesday, May 6, 2015.

PLEASE NOTE that there is a special rate for accompanying person. Lunches 25 Gala dinner 120 (including visit tour, transport and dinner)Access to hotel reservations is available on registration website after end of registration.

CANCELLATION CONDITIONSAny cancellation request must be sent to : contact@europyro.cborg.net The following cancellation fees will be applied: 50% of the registration fees for cancellations received between 8 March and 5 April 2015 included 100% of the registration fees for cancellations received after 5 April 2015

REGISTRATION FORM : Register on internet : http://itcborg.info/EUROPYRO2015 YOUR CONTACTS : for any request on registration, accomodations, travel, payments, Exhibition contact : secretariat@afpyro.org or contact@europyro.cborg.net For invitations letter to attend the Europyro (visa request), contact : secretariat@afpyro.org

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Tuesday 05th May 2015

CASSIOPE

Session S1aEnergetic materials and molecules

TBDTBD

Key notes

D. SPITZER - French-German Research Institute of Saint-louisEnergetic nanomaterials :

opportunities to enhance performancesfulfi lling at the same time environnemental requirements

W. ARNOLD - MBDA-TDWTesting and modelling the initiation of insensitive explosives

by projectile impact

C. FOURNIER - TDA Armements SASNew melt-cast high explosive tailored to large-series insensitive

ammunition

A. HAHMA - DIEHL BGT DefenceAdvanced black body fl are compositions with multiple

combustion zones

J. GLAVIER - LAAS-CNRSPrediction of pressure, temperature and reaction end products of

Al-based thermite using a local thermodynamics equilibrium

ARIANE 1

Session S2a Methodologies for design, safety, reliability

and lifetime demonstrationTBDTBD

KK. RINK - Rink International LLCUse of the krypton-85 radioisotope technique to assess non-hermetic

energetic devices

F. CHASSAGNE - DGA Missiles TestingComplete numerical simulation of the Fast-Cook-Off Test applied

to a Solid Rocket Motor (SRM)

L. COURTY - Universit dOrlansExperimental characterization of the thermal degradation

of low vulnerability propellants

J. CORBEL - ISLUnderstanding the effect of RDX particle shape on shock sensitivity

J. DILGER - Naval Surface Warfare CenterPreliminary investigation into Pyrotechnic chemical products via

Mass Spectrometry Techniques

M. DOUET - Federal Institute for Materials Research and Testing

Explosive properties of mixtures of black and fl ash powders

ARIANE 2

Session S3a High Dynamic Pressures

TBDTBD

CD. YARRINGTON - Sandia National LaboratoriesPorosity effects on the initiation of CL-20

V. CHUZEVILLE - CEADetonation initiation of heterogeneous melt-cast high explosives

L. BLANC - INSA Centre Val de LoireA compressed balloon approach for the simplifi ed modeling

of a blast wave

A. LEFRANCOIS - CEALow amplitude shock initiation experiments on TATB base composition

tested with inverse particle velocity

F. BALLANGER - CEASmall scale blast experiments in dry aqueous foam

PA. FRUGIER - CEALaser Imaging : principles and application, picturing detonation

waves in ns regime

EUROPYRO CONFERENCE INTRODUCTIONWelcome adress and seminar arrangements: Joseph REFOUVELET, Organisation Committee Chairman

Welcome adress and seminar opening: Denis DILHAN, Seminar chairmanKeynote address: Jehan VANPOPERYNGHE Scientifi c Committee chairman

Key notes J. PORET - US Army ARDEC

Coffee Break

9h00 - 09h30

9h30 - 10h00

10h00 - 10h30

Room

Tuesday 05/05/2015 (AM)

CHAIRPERSON 1CHAIRPERSON 210h30 - 11h10

10h50 - 11h10

11h10 - 11h30

11h30 - 11h50

11h50 - 12h10

12h10 - 12h30

12h30 - 14h00

EuropyroDay 1 2015

5

Lunch Break

Session S1bEnergetic materials and molecules

TBDTBD

MK ATAMANOV - Institute of Combustion ProblemsDevelopment and investigation of pyrotechnic compositions for green

colored lights based on B2O3 and H3BO3

JD. MORETTI - US Army RDECOM-ARDECDevelopment of Next-Generation Pyrotechnic Illuminants

for Military Applications

C. MIRO SABATE - CNRS University Claude Bernard of LyonMethylated 2 -tetrazenes and hydrazines

AP. SHAW - US Army RDECOM-ARDECMetal-element compounds of titanium, zirconium,

and hafnium as pyrotechnic fuels

P. SHAWCROSS - Battelle Memorial InstitutePyrotechnic formulations containing potassium ferrate

JS. BRUSNAHAN - Weapons and Combat System DivisionIRCM pyrotechnic formulations based on boron carbide as the fuel

C. MARTIN - ISLEnergetic nanocompositions : smart materials, effects and applications

P. GIBOT - ISLElectrostatic discharge desensitization of AI/WO3 nanothermites

by means of a conductive material

L. GLAVIER - LAAS CNRSDevelopment of new nanothermite based mixtures for

pyrotechnical impact micro-initiator

Session S2bMethodologies for design, reliability and lifetime demonstration,

IMness justifi cationsTBDTBD

N. FORICHON - N. CHAUMET - NEXTER MunitionsHow Nexter Munitions takes into account the reach obsolescences :

from the formulation to the production line

D. MAILLET - RoxelUnderwater demilitarisation : a safe and effi cient way to eliminate solid

propellant

Ch. MARRAUD - HeraklesAdvanced biological treatment for solid propulsion - LICORNE

E. PRADINES - Etienne LacroixApproach for the assessment of acute inhalation toxicity of smoke

ammunitions by in silico, in vitro and in vivo modelling

E. SCHULTZ - MSIACIntegrated munition health management cooperative demonstration

of technology

M. MEKKI - Universit de RouenCharacterization and toxic assessment of smoke aerosols and aerosols

produced by fi ring small caliber ammunition: a comparative study

C. MORRIS - US Army Research LaboratoryModeling the combustion of micrometer scale porous silicon channels

E. MIKLASZEWSKI - Naval Surface Warfare CenterElimination of perchlorate oxidizers from yellow pyrotechnic

fl are compositions

Session S3b High Dynamic Pressures

TBDTBD

G. ZANIOLO - CEADetonation products

Air turbulent mixing and combustion for various oxygen balances : analysis and modelling

H. TAO - Institute of Applied Physics and Computational Mathematics

Numerical simulation of detonation in suspended mixed RDX and aluminum dust

Y. KATO - Nippon Koki Co. LtdDevelopment of crater forming device for the asteroid explorer

Hayabusa2

G. PRUDHOMME - CEAStudy of particle coulds ejected under shock : the contributions

of photonic doppler velocimetry

O. BOZIER - CEACharacterization of thin detector shielding against explosion

F. BALLANGER - CEASmall scale blast experiments in dry aqueous foam

B. CHAMAYOU - Airbus Defence & SpaceOpto-pyro trains for Space Systems

H. LE BRETON - Nexter MunitionsOpto-pyro detonator for Space Systems

J. NICOLOSO - Airbus Defence & SpaceStudies on combustion of confi ned explosive in an Opto-Pyrotechnic

Detonator (DOP)

Coffee Break

Tuesday 05th May 2015EuropyroDay 1 2015

Tuesday 05/05/2015 (PM)CHAIRPERSON 1CHAIRPERSON 214h00 - 14h20

14h20 - 14h40

14h40 - 15h00

15h00 - 15h20

15h20 - 15h40

15h40 - 16h00

16h00 - 16h40

16h40 - 17h00

17h00 - 17h20

17h20 - 17h40

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Room CASSIOPE ARIANE 1 ARIANE 2

Wednesday 06th May 2015

CASSIOPE

Session S1cEnergetic materials and molecules

TBDTBD

JY. AHN - Pusan National UniversityTuning the explosive reactivity of nanoenergetic materials on a chip by

controling the strucutre of Al and CuO multilayers

K. WOIRIN - HeraklesVery low critical diameter explosive composition formulation

and characterization

NV. AVERIANOVA - Kasan National Research Technological University

Nanofi brillar cellulose nitrate

F. PESSINA - ISLUltimate size explosives obtained by SFE process

ARIANE 1

Session S2b Methodologies for design, safety, reliability

and lifetime demonstrationTBDTBD

MM. NARDAI - Fraunhofer Intitute of Chemical TechnologyInteraction energies between binder polymers and crystalline surfaces in composite materials determined by solution microcalorimetry and

computer simulation

R. SORIN - CEANumerical simulation of embedded electromagnetic particle velocity

gauges in 2D fl ows

JM. SIBEAUD - CEAFull scale Experiments and Modelling of ground burst effects

on buildings

J. BENIER - CEADevelopment of optical fi ber sensor for detonation velocity measurement

ARIANE 2

Session S4aNew explosive devices and systems

TBD TBD

G. DEMEZON - HeraklesThermal modelling of a medium energy electro-pyrotechnic initiator

S. CHEN - Nanjing University of Science and TechnologyInitiation of HNS-IV explosive using laser-driven fl yers

G. PEDROZA - AlphanovEvaluation of laser diode reliability risks associated with optical feed-

back within an optopyro ignition line

L. SOULIE - HeraklesDesign and experimental evaluation of a secured multi-point

opto-pyrotechnic train

EuropyroDay 3 2015

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Key notes M. CARLIER - DGA - Technical Directorate - Head of missiles, weapons and ammunitions branch

Coffee Break

8h00 - 08h30

Room

Wednesday 06/05/2015 (AM)

CHAIRPERSON 1CHAIRPERSON 2

8h40 - 9h00

9h00 - 9h20

9h20 - 9h40

9h40 - 10h00

Wednesday 06/05/2015(AM)10h30 - 10h50

10h50 - 11h10

11h10 - 11h30

11h30 - 11h50

11h50 -12h10

12h10 - 12h30

12h30 - 14h00

Wednesday06/05/2015(PM)

Session S1cEnergetic materials and molecules

M. COMET - ISLNanothermites : a toolbox for solving contemporary challenges

in pyrotechnics

F. STA - Nexter MunitionsPresentation of a doctoral thesis which studies the rheology

of energetic concentrated suspensions used as melt-cast formulations

M. GUERAIN - CEAX-Ray diffraction studies of HMX and TATB after processing operations

and thermo-mechanical testing

A. PIVKINA - Semenov Institute of Chemical PhysicsSynergistic interaction of ammonium perchlorate and HMX

at thermolysis and combustion

K. IKEDA - National Defense AcademyBurning mechanism of some azodicarbonamide/ammonium nitrate/

copper (II) oxide mixtures

MA. BOHN - Fraunhofer Institute of Chemical TechnologyReview of some peculiarities of the stability and

decomposition of HNF and ADN

Session S2c Methodologies for design, safety, reliability

and lifetime demonstration

N. DAVIOT - Autoliv-LivbagMethodology for predicting safe functioning of airbag infl ators during

fi re test using fast

Y. GUENGANT - HeraklesAssessment of thermal fl ux effects generated by accidental combustion

of pyrotechnic materials

G. BAILLEAU - DGA Techniques TerrestresAKTS Thermokinetics : Evaluation, Limits, Perspectives

T. SEYIDOGLU - Fraunhofer Intitute of Chemical TechnologyCharacterization of butacene based composite propellants by loss factor

curves determined with DMA

W. LIZHI - Nanjing University of Science & TechnologyStudy on The Propulsion Performance of GAP with Laser Micro Ablation

M. COTTREL-BUSSENAULT - HeraklesReliability : GTPS methods

Session S4aNew explosive devices and systems

S. H. KIM - Pusan National UniversityFlash ignition and controlled-underwater explosion reactivity

of carbon nanotube/nanoenergetic composite materials

C. VALANCIUS - Sandia National LaboratoriesHMX Hotwire initiation and Performance Criteria

N. RUMEAU - RoxelNew innovative anti-tank solid rocket motor design

R. LAFONT - Nexter MunitionsXfoil-Init

R. LAFONT - Nexter MunitionsPyroMEMS In-It

E. GIRAUD - HeraklesContinuous gas generant innovation the reason for airbag technology

success

Lunch BreakTour of Airbus A380 fi nal assembly line & AEROSCOPIA Museum

Dr. Bernard E. Douda Young Scientist Award and Prix Paul VIEILLEDINNER GALA AT DOMAINE DE PREISSAC

Wednesday 06th May 2015EuropyroDay 3 2015

8

Room CASSIOPE ARIANE 1 ARIANE 2

CASSIOPE

Session S1dEnergetic materials and molecules

TBDTBD

VP. SINDITSKII - Mendeleev University of Chemical Technology of Russia

Burning behavior and combustion mechanism of explosive coordination compounds

S. KNAPP - Fraunhofer Institute of Chemical TechnologyHot-Spot Modelling of Thermite Mixtures

D. DYE - Naval Surface Warfare CenterInvestigation into blue light emissionfor cooper-containing pyrotechnics

D. TRACHE - Ecole Militaire PolytechniqueSynthesis and characterization of nitrocellulose microcrystalline

from soft wood using organosolv process

S. COMTE - HeraklesNitropyrazole synthesis : synthesis fo formulation

M. GOZIN - Tel Aviv UniversityNitration of 3,6-Bis(aminoazole)-1,2,4,5-tetrazine Derivatives Towards

More Oxygen-balanced Nitrogen-rich Energetic Materials

F. DAVID QUILLOT - CEATowards low-cost TATB based formulations

V. SIZLOV - Mendeleev University of Chemical Technology of Russia

Catalyst action zones at combustion of low-calorie propellants

N. RUMEAU - RoxelResonantAcoustic Mixing - Processing and formulation challenges

for cost effective manufacturing

ARIANE 1

Session S2b Methodologies for design, safety, reliability

and lifetime demonstrationTBDTBD

M. SKAGGS - Sandia National LaboratoriesAssessing Post-Ignition Pyrotechnic Behavior

C. FRENOIS - CEADetection of vapour of explosives by a multi-sensor prototype

V. KALENDER - Tubitak SageCharacterisation of electrolyte and pyrotechnic pellets in thermal

batteries

JL. DEQUIEDT - CEACrystalline plasticity and the elasto-plastic behavior of ductile materials

ARIANE 2

Session S4cNew explosive devices and systems

TBD TBD

E. LIEBENS - Herakles / G. GONTHIER - HeraklesAircraft safety devices

B. HAGUENAUER - PYROALLIANCEGreen high performance Linear Shaped Charge

L. KURTH - Federal Institute for Materials Research and TestingAssessment of Explosives in pyrotechnic articles for special effect

(Squibs)

P. SHISHKOV - University of Mining and GeologyObtaining of rocket engine from waste material

W. WEISER - Fraunhofer Institute of Chemical TechnologyPyroorganic Flares - State of the Art and Progress

Thursday 07th May 2015EuropyroDay 3 2015CNES - Directorate of Launchers

9

EUROPYRO 2015 CONFERENCE CONCLUSION ANNOUNCEMENTS : 15th International Symposium on Fireworks - 42nd International Pyrotechnics Seminar

Lunch Break

Coffee Break

Nitration of 3,6-Bis(aminoazole)-1,2,4,5-tetrazine Derivatives Towards

8h20 - 08h50

Room

Thursday 07/05/2015 (AM)

CHAIRPERSON 1CHAIRPERSON 29h00 - 9h20

9h20 - 9h40

9h40 - 10h00

10h00 - 10h20

10h20 - 10h40 10h40 - 11h00

11h00 - 11h30

11h30 - 11h50

11h50 - 12h10

12h10 - 12h30

12h30 - 12h50

12h50 - 14h30

GTPS Working GroupReliability Workshop

EuropyroPoster session

Poster n 1 K. KATOH - Faculty of Engineering, Fukuoka University Study on the dismantlable adhesives containing an oxidative inorganic salt

Poster n2 JM. CHEVALIER - CEA/CESTA Study of a debris shield limiting projection effects associated with a pyrotechnic accident. Numerical experiments and simulations related

Poster n3 S. NAGAYAMA - Fukuoka University Investigation of thermal behavior and surface condition of ammonium nitrate/ammonium perchlorate particles prepared by spray drying

Poster n4 JM. CHEVALIER - CEA/CESTA Dynamic behaviour of two adhesive materials

Poster n5 JM. CHEVALIER - CEA/CESTA Transverse shadowgraphy and newrecovery technique to investigate dynamic fragmentation of laser shock-loaded metals

Poster n6 A. MARAVAL - Etienne Lacroix Advanced on new pyrotechnic compositions free chlorine for multispectral masking

Poster n7 A. MOULOUD - Ecole Militaire Polytechnique Effect of nanoparticles on reaction kinetic data of composite rocket propellants based on epoxy binder

Poster n8 D. HEBERT - CEA/CESTA Hypervelocity impacts into porous graphite : experiments and simulations

Poster n9 A. MEZROUA - Ecole Militaire Polytechnique Kinetic study of the thermal degradation of composite rocket propellant based of porous ammonium perchlorate

Poster n10 S. CAMUS - CEA Low velocity impact simulations on HMX-bases PBXs using adaptive meshing

2015

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