Embed Size (px)
Citation preview
LIST OF ANNEXURES
No. Annexure Description
1 Annexure 1 Land Possession Documents
2 Annexure 2 Document of permission from Dantali Industrial Estate
3 Annexure 3 Copy of NA Permission
4 Annexure 4 Name of Industrial Units
5 Annexure 5 Layout Plan
6 Annexure 6 Details of additional infrastructural facilities and plant machineries
7 Annexure 7 List of Specific area near to project site
8 Annexure 8 Google images of project site surrounding area
9 Annexure 9 Undertaking Certificate
10 Annexure 10 List of Hazardous chemicals
11 Annexure 11 Monthly consumption of raw material and product
12 Annexure 12 Manufacturing process
13 Annexure 13 Details of Water consumption and wastewater generation
14 Annexure 14 Sources and disposal of Hazardous waste generation
15 Annexure 15 Details of possibility of chemical seepage
16 Annexure 16 Details of Utility
17 Annexure 17 Work zone environment monitoring report
18 Annexure 18 Measures proposed for noise pollution
19 Annexure 19 Hazardous waste details
20 Annexure 20 Environmental Management Plan
21 Annexure 21 Details of Socio-economic development measures
22 Annexure 22 Undertaking for Green belt development
23 Annexure 23 Details for Greenbelt development
24 Annexure 24 MSDS of all products and raw materials
25 Annexure 25 Details of hazardous characteristics and toxicity of product and raw material
26 Annexure 26 List of control measure proposed to ensure safety and human health
27 Annexure 27 Occupational health impacts and mitigation measures
28 Annexure 28 Details of Risk Assessment
29 Annexure 29 Risk assessment report
30 Annexure 30 Onsite emergency plan
31 Annexure 31 Checklist for preventive measures
32 Annexure 32 CTE Amendment & CCA
33 Annexure 33 Compliance report for CTE conditions
ANNEXURE 2 PERMISSION FROM DANTALI INDUSTRIAL ESTATE
TOR NO.2: Documents of necessary permissions obtained by Dantali Industrial Estate from concern authorities/Departments.
ANNEXURE 3 COPY OF NA PERMISSION
TOR NO. 2(part): Copy of NA permission from the concern authority.
ANNEXURE 4 NAME, LOCATION AND NATURE OF SURROUNDING INDUSTRIAL UNITS
TOR NO. 3 Details of surrounding industrial units within 5 km radius with details like Name and address of the unit, type and nature of industrial activity etc.
No. Company Name Address of the Unit Distance Industry Type
and nature
1 Arvind Mill
Limited Distribution Service Khatrej, Taluka Kalol Gandhinagar, Gujarat 382010
3.37 km (W-SW)
Textile Manufacturing
unit
2 Deepak Poly Plast Pvt. Ltd
Plot No 198/1-2, Dantali GIDC. (via Lapkaman village, Gota vadsar road,
Kalol), Dantali, Gujarat 382721
Testing equipments
3 Shashvat
Infraventure Pvt. Ltd.
Survey No: 224/4, Dantali Industrial Estate, Opp. Jay Water Pump, Besides.
Shilpgram-II, Off. S P Ring Road, Nr. Karnavati Eye Hospital,
Ognaj, Dantali, Ahmedabad - 382721
- Stone Mfg.
4 Siddhi Spingers
Pvt. Ltd.
Plot No, 225, Dantali GIDC, After Lapkaman Gam, Gota-Vadsar Road,
Kalol, 382721 - Cotton
5 Ankur Marbles B-111, Opp Ice Make Refrigeration,Dantali
Industrial,Dantali,Gandhinagar - Stone Mfg.
6 Nand
Equipments Pvt. Ltd.
190/5 Dantali Industrial Estate, Gota-Vadsar Road, At: Dantali TA: Kalol Dist:
Gandhinagar, Ahmedabad, Gujarat 382721
Kitchen
Equipments
7 Moksha
Thermoplastics Pvt. Ltd.
224/3, Dantali Industrial Estate, Village Dantali,
Post. Vadsar - 382721 Dist. Gandhinagar.
- Plastic Moulding
Parts
8 Reliance cylinder
testing
2,Dantali GIDC,Gota-Vadsar Road,Nr Lapkaman Village, Dantali, Ahmedabad,
Gujarat 382721 -
Gas Cylinder Testing
9 Fine Care
Biosystems Pvt. Ltd.
Door no-228/1/4,Dantali industrial Estate Gota-vadsar road, Gandhinagar -
382721, - Lab Equipments
10 Shah Alloys
Shah Industrial Estate, Block No. 2221/2222, Sola- Kalol Road, Santej, Ta.
Kalol Gandhi Nagar Dist. - 382721
Gujarat – India
4.65 km (SW)
Rolled MS Sheets Mfg.
No. Company Name Address of the Unit Distance Industry Type
and nature
11 Shankus
Pharmaceuticals
Milan Industrial Estate, Santej - Vadsar Rd
Santej, Gujarat 380060
3.5 km (SW)
Pharmaceutical Company
12 Balaji Steels
Industry
6, Milan Industrial Estate, Santej-Vadsar Road, Santej, Kalol Taluka,
Gujarat 382721
4.09 km (SW)
Metal Industry
13 Aniket Pharma
(P) Ltd
Plot No.9,10,11, Milan Industrial Estate, Village Santej, Vadsar Road, Kalol, Dist.
Gandhinagar
3.4 km (SW)
Pharmaceutical Company
14 Gunjan Paints
Ltd
Plot no 1162, moti bhoyan, opp. Universal college of engg. And
technology, Nr vadsar air force station, Ta-kalol, Dist- Gandhinagar, Gujarat,
India -382721.
4.91 km (NW)
Paint Industry
15 Sai Italian
Marble
Block No-29, Sub Plot No-4/2, Near Rajkalp Mudralay,
Dantali Ind. Estate Road, Dantali, Ahmedabad - 380060.
Gujarat, India
0.86 km (S) Marble
Manufacturing
16 Laxmi Flora Dantali Ind. Estate Road,
Dantali, Ahmedabad - 380060. Gujarat, India
0.80 km (S) Marble
Manufacturing
17 Sadbhav
Engineering Ltd
Village Ognaj, Tal. Daskroi Ahmedabad District -
Gujarat - India
3.10 km (S-SE)
Construction company
18 Rajkalp
Mudranalaya Pvt. Ltd.
Besides Shilpgram-II, Off S P Ring Road,Near Karnavati Eye Hospital –
Ognaj,Dantali Industrial Estate Road, Lapkaman, Ahmedabad,
INDIA. 380 060.
0.74 km (S) Printing Press
unit
19 Gopala Poly
Plast
Plot No. 485, Santej -Vadsar Road, Dist. Gandhinagar - 382 721,
Gujarat INDIA.
2.58 km (W-SW)
Fabric Manufacturing
ANNEXURE 5
LAYOUT PLAN OF THE FACTORY PREMISES SHOWING THE PROPOSED EXPANSION ACTIVITIES ON
THE SAME.
TOR no. 4 (part): Demarcation of proposed project activities in layout plan.
TOR no. 6: Demarcation of proposed expansion activities in layout of the existing premises.
TOR No. 10: Layout plan of factory premises. Provision of separate entry & exit and adequate
margin all-round the periphery for unobstructed easy movement of emergency vehicle/fire
tenders without reversing back. Mark the same in the layout plan.
The Lay out Plan is placed on page no. 102, at the end of this document.
ANNEXURE 6 DETAILS OF ADDITIONAL INFRASTRACTURAL FACILITIES, PLANT MACHINERIES FOR PROPOSED
EXPANSION
No. Machine Details Qty. Existing
Facilities with Capacity
Qty. Proposed Facilities
with Capacity
1 Bending Machine with Hydraulic Power Pack System
1 3.75 Mtr. - -
2 Shearing Machine with Hydraulic Power Pack System
2 6X3000 MM - -
3 PU Foaming Press with Suction, Blower & Hydraulic Power Pack System
1 4 Bed / 6 Mtr. - -
4 PU Foaming Press with Suction, Blower & Hydraulic Power Pack System
1 2 Bed / 4 Mtr. - -
5 PUF Filling Machine - - 1 200 kg / Min.
9 Bar to 250 bar
6 PUF Filling Machine - - 1 200 FC / 9 Bar to 250
bar
7 PUF Filling Machine - - 1 200 FC / 9 Bar to 250
bar
8 PUF Filling Machine - - 1 100 FC / 9 Bar to 250
bar
9 Hydraulic Press Bed. 1 3 Bed - -
10 Hack Saw Machine 2 14" Blade - -
11 Power Press Machine 1 30 Ton - -
12 Power Press Machine 3 20 Ton - -
13 Turret Machine 1 25 Ton - -
14 Bending Machine with Hydraulic Power Pack System
1 6mm to 2500
mm - -
15 Air cooled Welding Machine 1 200 AMP - -
16 Air cooled Welding Machine 1 250 AMP - -
17 Air cooled Welding Machine 1 400 AMP - -
18 CNC Bending Machine 1 3100 mm X
1000 KN
- -
19 Hydraulic Power Press Machine 1 50 Ton - -
20 Crane 2 5 Ton - -
No. Machine Details Qty. Existing
Facilities with Capacity
Qty. Proposed Facilities
with Capacity
21 Shearing Machine Small 1 6 mm X1500
mm - -
22 Air Compressor 1 3 HP - -
23 Roll Forming Machine 1 Set - -
24 Packing Machine 1 Set - -
25 Forklift 2 3 Ton - -
26 Air Compressor 1 500 Ltr. - -
27 D.G. Set 1 125 KVA - -
28 Solar Panels 36 50 KWhr - -
30 Spot welding Machine 1 10 KVA - -
31 Reject PUF Grinding Machine (Cutter)
1 Set - -
32 Powder Coating 1 3500 cum/hr - -
ANNEXURE 8 Google Image showing specific sites near to project site (5 km radius)
TOR NO.8: Give satellite image of 5 km radius
1. Thol Bird Sanctuary 7.7 km 8. Nearest Railway Station (Khodiyar Railway Station) 5.18 km 2. ECZ Thol Bird Sanctuary 6.49 km 9. Nearest State Highway (SH-4) 7.76 km 3. Lapkaman Lake 1.20 km 10. 5 km distance North from site 4. 5 km distance south from site 11. Nand Equipment Pvt. Ltd. 0.93 km 5. Nearest College 4.20 km 12. Nearest Village- Dantali 0.62 km 6. Nearest School (SGVP) 4.09 km 13. 5 km distance West & Arvind Mill Ltd. 4.74 km 7. 5 km distance East from site 14. Adalaj Stepwell 8.78 km
3
11 13
9 10
8
7
6
5
4
12
1
2
1
Satellite Image showing 5 km Radius
Image showing Dantali Industrial Estate and Unit location within it
Google image showing Dantali Industrial Estate and surrounding area
ANNEXURE 9
UNDERTAKING CERTIFICATE
TOR No. 9 (part): Legal undertaking stating that unit is complying the three conditions [i.e., water consumption less than 25 M3/day: Fuel Consumption less than 25 TPD; and not covered in the category of MAH units as per the amendment to EIA Notification, 2006 vide SO 1599 (E) dated 25.06.2014
ANNEXURE 10
LIST OF HAZARDOUS CHEMICALS TO BE USED
TOR NO.9 (part): Give tabular format for comparison of actual storage of hazardous chemicals and threshold limit prescribed in MSIHC Rules, 1989.
ANNEXURE 10 LIST OF HAZARDOUS CHEMICALS TO BE USED
No. Hazardous Chemical name Falling under category of MSIHC Rules Threshold
Quantity in MT Storage Quantity
details
1 Polyol 1,1-dichloro-1-fluoroethane (HCFC – 141b) Tris (2-chloro-1-methylethyl) phosphate
Schedule 1 Part – 1 (a) Toxic chemicals category 2 Highly toxic: LD50 >2000 mg/kg Schedule 1 Part – 1 (a) Toxic chemicals category 2 Highly toxic: LD50 >5000 mg/kg Schedule 1 Part – 1 (a) Toxic chemicals category 2 Highly toxic: LC50 >4.6 mg/l
- 16 MT
2 Diphenyl Methane Di-isocyanate (MDI)
Sr. No. 109 of Group-2 Toxic Substance in Schedule 3 Part I & Schedule 1 Part – 1 (a) Toxic chemicals category 1 Extremely toxic: LC50 0.49 mg/l
20 T for rule 5,7-9,13-15
18 MT
ANNEXURE 11 MONTHLY CONSUMPTION OF RAW MATERIAL AND PRODUCT
TOR No. 11: Proposed monthly production and monthly consumption of each raw material.
The raw materials consumption is estimated based on the existing and proposed production capacity and the Production summary is mentioned in the table below: Table: Raw Materials Consumption details (existing and proposed)
Raw material Existing (kg/Month) Expansion (kg/Month)
Total (kg/Month)
Polyol (1,1-dichloro-1-fluoroethane (HCFC – 141b) Tris (2-chloro-1-methylethyl) phosphate)
- 26,400 26,400
Diphenyl Methane Di-isocyanate (MDI)
- 34,200 34,200
Table: Product details with capacities (existing and proposed)
Product name Existing capacity, Unit/month
Proposed expansion in Unit/month
Total capacity in Unit/month
All type of Commercial & Industrial Refrigeration Equipment using PUF
200 nos. 1000 nos. 1200 nos.
ANNEXURE 12 MANUFACTURING PROCESS FOR PUF
TOR No.12: Manufacturing process along with chemical reactions, mass balance for each product. Give exact quality of raw materials required in MT/Day.
MANUFACTURING OF POLYURETHANE FOAM (PUF) Polyurethanes are linear polymers that have a molecular backbone containing carbamate groups (-NHCO2). These groups, called urethane, are produced through a chemical reaction between a Diphenyl Methane Di-isocyanate (MDI) and a Polyol (Blending of [1,1-dichloro-1-fluoroethane (HCFC – 141b) and Tris (2-chloro-1-methylethyl)
phosphate]). They are used in thermal insulation, surface coatings, adhesives, solid plastics, and athletic apparel. Liquid chemicals are delivered to the manufacturing facility and stored in large holding tanks. When it’s time to use them, the chemicals are pumped into smaller mixing nozzle to pump in to the panels. Metered pumps measure certain amounts of each chemical which are fed into a mixing head – this is where the chemicals blend and react. The chemical reaction takes place is shown here. We are using the PUF in fixer and Puffing of the panels of cold rooms & doors, commercial freezers etc. (Manufacturing All type of Commercial and Industrial Refrigeration equipment using Poly Urethane Foam [PUF]).
CHEMICAL REACTION OF POLYURATHANE FOAM
MASS BALANCE of Polyurathane foam for One Batch (1 MT)
No. Raw Materials Quantity in kg
1. Polyol 450.0
2. Isocynate 550.0
Total Polyurathane Foam 1000.0
ANNEXURE 13 WATER CONSUMPTION & WASTE WATER GENERATION DETAILS
TOR NO.14 Water balance diagram (including reuse-recycle, if any) along with qualitative and quantitative analysis of each waste stream to be generated. WATER CONSUMPTION DETAILS:
No Description Existing Water Consumption
Liter/day
Proposed Water Consumption
Liter/day
Total Water Consumption
Liter/day
1 Domestic 6,000 5,250 11,250
2 Industrial 600 750 1,350
2.1 Process 500 500 1,000
2.2 Boiler - 100 100
2.3 Cooling 100 150 250
2.4 Washing
- - -
2.5 other use
- - -
3 Gardening 5,400 - 5400
Total 12,000 6,750 18,000
Water Source: Bore well WASTE WATER GENERATION DETAILS:
No Description Existing Wastewater generation Liter/day
Proposed Wastewater
generation Liter/day
Total Wastewater generation Liter/day
1 Domestic 4,200 * 4,800 9,000
2 Industrial 300** (-300) -
2.1 Process 280 (-280) -
2.2 Boiler - - -
2.3 Cooling 20 (-20) -
2.4 Washing - - -
2.5 other use
- - -
Total 4,500 4,500 9,000
* Sewage treated and disposal through septic tank and soak well pit **To ETP, Evaporator
ANNEXURE 14 SOURCES AND DISPOSAL OF HAZARDOUS WASTE GENERATION
TOR NO.18: Plans for management and disposal of waste streams to be generated from spillage, leakages, vessel washing, used container washing etc. Measures propose for preventing effluent discharge during unforeseen circumstances.
Table: Sources and disposal of waste streams generated
No. Sources of leakage/
spillage Leakage/spillage management
1 Polyol and MDI in drums
Separate storage room with covered roof and RCC floor for each raw material
RCC/concrete road/approach from raw material storage area to production area
2 High pressure nozzle assembly with
suction from drums
RCC/concrete floor to control soil contamination at production area
Provision of sand buckets to control spillage/leakage at floor
ANNEXURE 15 POSSIBILITY OF CHEMICAL SEEPAGE AND POSSIBLE MITIGATION MEASURES
TOR NO.20: Details of possibility of chemical seepage & consequent soil contamination & mitigation measure proposed for the same for the proposed project. Details of Possibility of Chemical Seepage & consequent Soil Contamination & mitigation measures for the same MDI & Polyol will be stored at separate storage area having four walls; covered roof and Concrete floor, so there will not be any possibility of chemicals seepage and will be stored with necessary precautions. POSSIBLE MITIGATION MEASURES: Polyol:
Stock of dry sand & lime is kept near the storage area.
Provision of Respiratory protective equipment’s & personal protective equipment’s
Safety shower & eye wash unit installed.
Strict supervision while unloading, regular testing & inspection tanks.
ANNEXURE 16 DETAILS OF UTILITIES
Table: Details of utilities, fuel consumption, air control measures proposed
No Details Qty. Existing
Facilities with capacity
Qty. Proposed
Facilities with capacity
1 Details of utilities required
1) DG Sets
2) Solar Panels
3) Bending Machine with Hydraulic Power Pack System
4) Shearing Machine with Hydraulic Power Pack System
5) PU Foaming Press with Suction, Blower & Hydraulic Power Pack System
6) PUF Filling Machine
7) Hydraulic Press Bed.
8) Hack Saw Machine
9) Power Press Machine
1
36
1
2
2
1
2
1 3
125 KVA
50 KWhr
3.75 Mtr. 6mm to 2500
mm
6X3000 mm
4 Bed / 6 Mtr.
2 Bed / 4 Mtr.
3 Bed.
14" Blade
30 Ton 20 Ton
- - - - - - -
1
1
1
1
Not required
Not required
Not required -
- - -
200 kg / Min. 9 Bar to 250 bar 200 FC / 9 Bar to
250 bar 200 FC / 9 Bar to
250 bar 100 FC / 9 Bar to
250 bar - -
No Details Qty. Existing
Facilities with capacity
Qty. Proposed
Facilities with capacity
10) Turret Machine
11) Air cooled Welding Machine
12) CNC Bending Machine
13) Hydraulic Power Press Machine
14) Crane
15) Shearing Machine Small
16) Air Compressor
17) Roll Forming Machine
18) Packing Machine
19) Forklift
20) Manual Chain Pulley Block
21) Spot welding Machine
22) PUF Grinding Machine
23) ETP
24) Powder Coating Set
1
1 1
1
1
1
2
1
1 1
1
1
2
1
1
1
1
1
25 Ton
200 AMP 250 AMP 400 AMP
3100 mm X
1000 KN
50 Ton
5 Ton
6 mm X1500 mm
3 HP
500 Ltr. - -
3 Ton
2 Ton
10 KVA - -
Set
-
Not Required - - - - - - - - - - - -
Not Required
2 Types of fuel to be used and quantity of each fuel Type of Fuel Quantity / Rate
-
HSD 25 kg/hr (during
Not required Not required
No Details Qty. Existing
Facilities with capacity
Qty. Proposed
Facilities with capacity
emergency period)
3 Reactor Vessels Nil
Not required
4 Chemical Storage area For Polyol For MDI
-
@ 10 sqm area
@ 10 sqm area
5 Air pollution Control Measures (APCM) proposed 1) DG Set 125 KVA
Acoustic Enclosure
and Adequate Stack Height
Not Required
6 Effluent Treatment Plant (ETP) - Not Required
ANNEXURE 17 WORK ZONE ENVIRONMENT MONITORING REPORT
TOR NO.22: Specific details of fugitive emission from the unit along with its quantification and proposed measures to control it along with measures proposed to monitor VOC within work area. Details of ventilation system proposed in the work area. Measures proposed to keep the work area environment as per the norms of GFR.
ANNEXURE 18 MEASURES PROPOSED FOR NOISE POLLUTION
TOR NO.24: Details of measures proposed for noise pollution abatement & its monitoring. Table: List of Sources of noise and its abatement
Source of Noise Receptor (no. of
existing employees exposed)
Receptor (no. of proposed employees
exposed) Abatement
DG Set 01 -
Adequate Ear plugs/Ear muffs are provided to workers who are exposed to
noise
Bending Machine with Hydraulic Power Pack System
02 -
Shearing Machine with Hydraulic Power Pack System
02 -
PU Foaming Press with Suction, Blower & Hydraulic Power Pack System
- 15
Hack Saw Machine 01 -
Power Press Machine 01 -
Torret Machine 04 -
Air cooled Welding Machine
01 -
CNC Bending Machine 02 -
Hydraulic Power Press Machine
01 -
Crane 02 -
Shearing Machine Small
01 -
Air Compressor 01 -
Roll Forming Machine 02 -
Forklift 01 -
Manual Chain Pulley Block
01 -
Total 23 15
According to GFR rules, monitoring of noise is done and workers who are exposed to noise are provided with ear plugs/ear muffs.
ANNEXURE 19 HAZARDOUS WASTE DETAILS
TOR NO.25 (part): Details of management of the hazardous wastes to be generated from the project stating detail of storage area for each type of waste, its handling and its disposal.
Table: Hazardous waste details
No. Waste name and Category
Generation Source
Quantity/year Facility for Disposal Existing Proposed Total
1. Discarded Containers, bags, liners, barrels (33.3)
Process & Utility
840 nos 2160 nos 3000 nos Authorized Recyclers
2 Used spent oil (5.1)
Prime movers and DG set
As & When generated
As & When generated
As & When generated
Authorized Recyclers
3 ETP sludge (34.3) ETP 150 kgs (-150) kgs 0 kgs -
4 Process waste (21.1)
Process As & When generated
As & When generated
As & When generated
TSDF site
ANNEXURE 20 ENVIRONMENT MANAGEMENT PLAN
TOR NO.32: A detailed EMP including the protection and mitigation measures for preventing impacts on human health and environment as well as detailed monitoring plan with respect to various parameters and responsible head for the environmental management cell and environment management cell proposed for implementation and monitoring of EMP
INTRODUCTION M/s. Ice Make Refrigeration Pvt. Ltd is an engineering unit located at Plot no 226, 227, Dantali
Industrial Estate, Gota Vadsar road, village Dantali, Taluka Kalol, District Gandhinagar and
proposes for the modernization of the existing manufacturing capacity and expansion of existing
all type of Commercial and Industrial Refrigeration equipment for current and future demand. We
need to exercise Foam making and charging in fixer and Puffing of the panels of cold rooms &
doors, commercial freezers etc. (Manufacturing All type of Commercial and Industrial
Refrigeration equipment using Poly Urethane Foam [PUF]). Need of the all type of Commercial and
Industrial Refrigeration equipment is high due to National climatic conditions. As a part of
backward integration, we are proposing to manufacture Polyurethane foam from chemicals and to
ensure satisfaction to customer.
The Environmental Management Plan is a site or project specific plan developed to ensure that appropriate Environmental Management Practices are followed during a project construction and or operation phase. An effective EMP should ensure
Application of best practice environmental management to a project
The implementation of project’s EC and consent approval including their conditions
Compliance with environmental legislation, and
That environmental risk associated with a project are properly managed
An Environmental Management Plan (EMP) has been prepared for Ice Make Refrigeration Pvt. Ltd to minimize negative impacts and is formed on the basis of prevailing environmental conditions and likely impacts of this project on various environmental parameters. This plan will also facilitate monitoring of environmental parameters. This EMP includes schemes for proper scientific treatment and disposal mechanism for air, liquid, solid/hazardous pollutants, chemical use Risk. Apart from this, green belt development, safety aspect of the workers, noise control etc. is also included in it.
1. ENVIRONMENT MANAGEMENT DURING CONSTRUCTION
The unit is existing in operations. The engineering sections are in operations. The unit is facilitated by infrastructure facilities, office building, staff, other building structure etc. There is no further
major construction work needed for project activity. The PUF making machines installation is the only activity to make it operational. However, as a part of construction phase, we are summarizing the probable environmental attributes for environmental management during construction phase. There will not any significant environmental impact during construction phase.
1.1 AIR ENVIRONMENT Transportation of vehicles will result in marginal increase in the levels of SO₂, NOx, PM10 & PM2.5, CO and unburnt hydrocarbons. The impact will, however, be marginal, and temporary in nature. However proper maintenance of vehicles can minimize emissions. Dust suppression by covering and water sprinkling and maintenance of vehicles will be carried out to keep air quality to the minimum negative impact on the surroundings. 1.2 WATER ENVIRONMENT
Proper and sufficient sanitary facilities is provided to workers to maintain all hygienic conditions at site. Furthermore, existing sanitary facilities is utilized. Storm water drains compatible with the local hydrological pattern of the area which is provided to carry-off, any run-off or storm water from the premises. Care is taken during construction work and not create any obstruction/dips in the topography which can lead to accumulation of water within premises leading to undesirable consequences like health and hygiene problems etc. 1.3 NOISE ENVIRONMENT
The noise effect on the nearest inhabitants during the construction activity is negligible. However on site workers within high noise producing equipment area will adopt noise protection devices like silencers, earmuffs. Noise prone activities will be avoided to the extent possible during night particularly during a period 9 PM to 6 AM in order to have minimum environmental impact on the neighborhood environment. Overall, the impact of noise generated on the environment is likely to be insignificant, reversible and localized in nature and mainly confined to the day hours. 2. ENVIRONMENT MANAGEMENT DURING OPERATION PHASE 2.1 AIR QUALITY MANAGEMENT: We are proposing the separate storage for Polyol and MDI with all safety precaution. We are proposing to charge both chemicals with control temperature below 20°C to control the VOC. Proposes to charge from one drum each for both materials in small housing facility having suction, high pressure pump and pipe with nozzle to control the VOC. We are proposing to monitor the work zone environment as per GFR.
2.2 WATER AND WASTE WATER MANAGEMENT: 2.2.1 WATER CONSUMPTION Water is required for domestic, Industrial and for gardening purpose. Total water consumption including existing and proposed water consumption is shown in the Table 1: Table 1: Water Consumption details
No Description Existing Water Consumption Liter/day
Proposed Water Consumption Liter/day
Total Water Consumption Liter/day
1 Domestic 6,000 5,250 11,250
2 Industrial 600 750 1,350
2.1 Process 500 500 1,000
2.2 Boiler - 100 100
2.3 Cooling 100 150 250
2.4 Washing - - -
2.5 other use
- - -
3 Gardening 5,400 - 5400
Total 12,000 6,750 18,000
2.2.2 WASTE WATER GENERATION We are proposing zero effluent generation from process/operation. Hence, we are not requiring any incineration or any other operations to treat the industrial effluent. Thus industry will maintain zero discharge. Hence, exiting Effluent Treatment Plant will not be in future. The Domestic Effluent will be generated 9 KL/d and it will be disposed of into septic tank and soak well pit system. Total wastewater generated in the industry including existing and proposed generation is shown in the Table 2 below: Table 2: Wastewater Generation Details
No Description Existing Wastewater generation Liter/day
Proposed Wastewater generation Liter/day
Total Wastewater generation Liter/day
1 Domestic 4,200 * 4,800 9,000
2 Industrial 300** (-300) -
2.1 Process 280 (-280) -
2.2 Boiler - - -
2.3 Cooling 20 (-20) -
2.4 Washing - - -
2.5 other use
- - -
Total 4,500 4,500 9,000
2.3 HAZARDOUS/ SOLID WASTE MANAGEMENT: The objective of waste management is to protect the environment by ensuring that waste does not contaminate the environment at such rate or in such a form to damage the environment or encumber the nature’s assimilative capacity. Waste elimination and minimization program is crucial, both environmentally and economically for reducing waste related liabilities and cost. Part of Cleaner Production activities: We are receiving chemicals in drum and stored in separate storage area with four walls; covered roof and Concrete floor facility. The drums after use will be given to authorized drum processor. 2.4 SOIL: Adequate and appropriate storage area is provided for the storage and handling of the raw materials. There will not be any probability of soil contamination as the entire premises are pavered by RCC or by paver blocks. 2.5 NOISE MANAGEMENT: Some of the design features provided to ensure low noise level shall be given as below: Proper housekeeping of all the noise generating equipment will be done to avoid excessive noise generation. PPE will be provided to the workers exposed to critical noise level source. The noise level will be monitored on regular basis in Preventive maintenance schedule and the corrective feasible action be taken for improvement and reducing the noise level. They shall ensure that during day (6 AM to 10 PM) and night time (10 PM to 6 AM) noise Leq values shall be below 75 and 70 dB (A) at the plant boundary as per the CPCB norms.
2.6 SOCIO ECONOMIC ENVIRONMENT: The unit is committed to upliftment of surrounding region’s socio economy by providing direct and indirect opportunities of employment and business in the region. Further, unit will contribute the aids to education, recreational activities, festivals and social programs etc. To achieve the socio economic upliftment, the Project Proponent is carrying out the Corporate Social Responsibility (CSR) activity in study area. The brief summary is addressed here as part of CSR.
2.6.1 CORPORATE SOCIAL RESPONSIBILITY Corporate Social Responsibility (CSR) is a continuous commitment to behave fairly in contributing to the economic and social development, improving the quality of life of the workforce and peripheral development and also providing respectful treatment to the environment. Community or the society plays a very important role in the success of any organization. Corporate Social Responsibility is the continuing commitment by industry to behave
ethically and contribute to economic development while improving the quality of life of the workforce and their families as well as of the local community and society at large. The project proponent is committed for CSR activity. The project proponent is providing year wise fund for the same and is summarized for different CSR activity as shown in Table 3 below: Table 3: CSR activity and its existing and proposed annual budget
No CSR ACTIVITY Year 2013-2014
Year 2014-2015
Year 2015-2016
1 Blood Donation camp and Cultural activity
Rs. 3,62,350 Rs. 3,80,000 Rs.2,75,000
2 Tree plantation in side our plant campus and also public Approach Road.
Rs. 40,000 Rs. 45,000 Rs.49,500
3 Awareness of the effects of Guthka ,Tobacco
Rs.15,000 Rs. 18,000 Rs.16,500
4 Educational motivational Certificate & Note book Distribution.
Rs. 45,000 Rs. 50,000 Rs.55,000
5 Sports Activity Rs. 40,000 Rs. 44,000 Rs.53,900
6 Independence Day celebration
Rs. 18,380 Rs. 20,000 Rs.22,000
Total Amount Rs. 5,20,730 Rs. 5,57,000 Rs. 4,71,900
2.7 GREEN BELT DEVELOPMENT: The total plot area available is around 10,736.34 sqm, which is already utilized for plant building, road and machineries, so, the unit is developing proposed plant species and also committed to develop within five years by participating in the greenbelt development programs outside the premises at appropriate places in the GIDC industrial area and in nearby villages or schools. They have already planted 150 trees outside the premises. The tolerant species with diversity will be planted which will help in suppression of fugitive dust, attenuate noise levels and provide aesthetic background. Nearly 650 Trees and Shrubs will be planted for the development of green belt in next five years with 150 trees/year with tree guard, sapling, watering etc. for local species like limbdo, Asopalav, Vad, Gulmahor, Nilgiri, piplo, etc. The project proponent is aware of benefits of tree plantation.
The green belt helps to check soil erosion, make the eco-system more sustainable, make the climate more conductive and restore water balance. The green belt helps to capture the fugitive emissions and to attenuate the noise generated apart from improving the aesthetics of the plant site. The project proponent has installed Solar Power Plant of 50 KW capacity. ENVIRONMENTAL MONITORING PROGRAM Area of monitoring like Ambient Air Quality, Water Quality, Hazardous Waste, Noise and Work Zone Environment as mentioned in approvals including CTE, CTO and to incorporate the conditions incorporated in Environmental Clearance. The responsibility of project proponent is to act for the following to maintain the proper environmental management.
1) To maintain storage records of both chemicals Polyol and MDI and to ensure the storage quantity within threshold limit.
2) To form SOPs for receiving, storing, transferring and using both chemicals considering safety and preventive measures suggested in Risk Assessment study and Onsite Emergency Response Plan specially for fire protection spillage control and to define the route of transfer both chemicals from storage to use.
3) The above measures should be made operational for unit to implement as a part of Environment Management Plan.
4) To monitor work zone environment within place to safeguard the exposed workers and to control emission.
5) To monitor the storage facility of both chemicals for safety and risk aspects. 6) To maintain the tree plantation area within and outside the premises. 7) To monitor ambient air quality outside building area within premises. 8) To maintain the D.G. set in good condition and to monitor the emission level once in year
or as suggested in approvals. 9) To train the staff and to dedicate them to handle both hazardous chemicals in safe
manner. 10) To obtain the necessary statutory and regulatory approvals from authorities (Fresh,
Renewal) 11) To comply the conditions provided in the approvals.
ANNEXURE 21 DETAILS OF SOCIO ECONOMIC DEVELOPMENT MEASURES
TOR NO.33: Detailed socio-economic development measures including community welfare program most useful in project area for the overall improvement of the environment.
Table: CSR activities and existing and proposed annual budget
No CSR ACTIVITY Year 2013-2014 Year 2014-2015 Year 2015-2016
1 Blood Donation camp and Cultural activity
Rs. 3,62,350 Rs. 3,80,000 Rs.2,75,000
2 Tree plantation in side our plant campus and also public Approach Road.
Rs. 40,000 Rs. 45,000 Rs.49,500
3 Awareness of the effects of Guthka ,Tobacco
Rs.15,000 Rs. 18,000 Rs.16,500
4 Educational motivational Certificate & Note book Distribution.
Rs. 45,000 Rs. 50,000 Rs.55,000
5 Sports Activity Rs. 40,000 Rs. 44,000 Rs.53,900
6 Independence Day celebration
Rs. 18,380 Rs. 20,000 Rs.22,000
Total Amount Rs. 5,20,730 Rs. 5,57, 000 Rs. 4,71,900
ANNEXURE 22 UNDERTAKING FOR GREEN BELT DEVELOPMENT
ANNEXURE 23 GREEN BELT DEVELOPMENT PLAN
TOR NO. 34: A detailed Green Belt Development Program including annual budget, types &
number of trees to be planted, area under green belt development [with map]; along with
commitment of the management to carry out the tree plantation activities outside the
premises at appropriate places in the GIDC area and elsewhere.
The total plot area available is around 10,736.34 sqm, which is already utilized for plant building, road and machineries, so, the unit will develop proposed plant species within five years by participating in the greenbelt development programs outside the premises at appropriate places in the GIDC industrial area and in nearby villages or schools. The tolerant species with diversity will be planted which will help in suppression of fugitive dust, attenuate noise levels and provide aesthetic background. Nearly 650 Trees and Shrubs will be planted for the development of green belt in next five years with 150 trees/year with tree guard, sapling, watering etc. for local species like limbdo, Asopalav, Vad, Gulmahor, Nilgiri, piplo, etc. The green belt helps to check soil erosion, make the eco-system more sustainable, make the climate more conductive and restore water balance. The green belt helps to capture the fugitive emissions and to attenuate the noise generated apart from improving the aesthetics of the plant site. The published “Guidelines for developing Green belt” by CPCB (2007) will be taken into consideration. Selection of plants for Greenbelts The main limitation for plants to function as scavenger of pollutants are, plant’s interaction to air pollutants, sensitivity to pollutants, climatic conditions and soil characteristics. While making choice of plants species for cultivation in green belts, due consideration has to be given to the natural factor of bio-climate. We must have to select those species which can absorb harmful gases, fast growing and have large canopy. Local species like Limbdo, Vad, Piplo, Gulmahor, Nilgiri, Asopalav, etc. will be planted in next five years with tree guard, sapling, watering, etc. Annual Budget for Green Belt Development Plan
Year Budget
2013-14 Rs. 40,000
2014-15 Rs. 45,000
2015-16 Rs. 49,500
TOTAL Rs. 1,34,500
ANNEXURE 24
MSDS OF ALL RAW MATERIALS AND PRODUCTS
TOR NO.35: MSDS of all the products and raw materials to be used.
Material Safety Data Sheet – Polyol 1. PRODUCT AND COMPANY IDENTIFICATION Manufacturers Name: Development Associates, Inc. Emergency Phone No: Chemtrec (800) 424-9300 24 Hour Product Name: Z7500 Part A Chemical Family/Name: Polyesterglycol,Polypropyleneglycol, and additive mixture.
2. COMPOSITION / INGREDIENT INFORMATION Component CAS # % Exposure limits(source) Polyester polyol trade secret 40-60 none(5) Polyether polyol trade secret 40-60 none(5) Additive Mixture trade secret 0-5 none(5) Source of Exposure Limit Data: 1 ACGIH Threshold Limit Values 2. Federal OSHA Permissible exposure limit 3. DA Exposure Guidelines 4. Chemical Manufacturer Recommended Guidelines 5. None Established
3. HAZARDS IDENTIFICATION HMIS HEALTH 1, FIRE 1, REACTIVITY 0 Threshold Limit Value: Not established by ACGIH or OSHA Routes of Entry: At room temperature by skin absorption or ingestion. If heated or atomized by inhalation. Signs and Symptoms of Exposure: Eyes: Redness and irritation. Skin: Rash, redness Ingestion: Nausea, irritation of digestive track. Inhalation: Irritation of respiratory system. Acute Effects of Overexposure: Eye Contact: May cause severe eye irritation. Ingestion: May cause irritation of gastrointestinal track and nausea. Skin Contact: May cause severe skin irritation. May cause allergic skin reactions in some individuals. Skin Absorption: Slightly toxic by skin absorption. Inhalation: Airborne aerosols or vapors from heated material may cause severe respiratory system irritation. Chronic Effects of Exposure: Constant exposure to skin may cause chronic dermatitis. Other chronic effects are unknown. Conditions Aggravated by Exposure: Respiratory ailments, dermatitis, other conditions unknown. Carcinogenicity: This product and its constituents are not listed as carcinogens by IARC, NTP or regulated as carcinogens by OSHA at this time. Routes of Entry: At room temperature primary routes are ingestion or skin absorption. If the material is heated or atomized the vapors or aerosol may cause exposure via inhalation.
4. FIRST AID MEASURES Emergency and First Aid Procedures: Eyes: Irrigate w/flowing water immediately and continuously for 15 minutes. Obtain medical attention. Swallowing: Give water or milk. Do not induce vomiting. Call a physician. DO NOT GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. Skin Contact: Remove contaminated clothing wash before reusing. Wash affected area well with soap and water. Consult physician.
Inhalation: Remove to fresh air. Obtain medical attention.
5. FIRE AND EXPLOSION DATA Flash Point 350oF (175oC)TCC. Flammable Limits in Air % Volume Upper: n/d Lower: n/d Extinguishing Media: Foam, CO2, or Dry Chemical Unusual Fire and Explosion Hazards: Do not breathe smoke when burning. Irritating and or toxic vapors and gasses when burned. Special Fire Fighting Procedures: Fire fighters should wear full emergency equipment including selfcontained breathing apparatus. Do not direct solid stream of water or foam into hot, burning pools, this may cause frothing and increase fire intensity.
6. ACCIDENTAL RELEASE MEASURES Steps to be Taken in Case Material is Released or Spilled: Contain spills with dams of absorbent material such as Zip Zorb. Absorb material and shovel into drums. Use appropriate safety equipment. Do Not flush to sewers.
7. HANDLING AND STORAGE Precautions to be Taken in Storage and Handling: Avoid skin and eye contact. Avoid breathing vapors if generated. Exercise reasonable care and cleanliness. Storage Temperatures 25-500C (77-1220F). Condition material to 30-600C (86-1400F) before using. Mix well under dry atmosphere before using.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eye Protection: Adequate eye protection as required to prevent contact during handling. i.e. Safety glasses, splash goggles, face shield. Skin Protection: Rubber Gloves, aprons and other protective clothing as required to prevent contact. Remove any contaminated clothing and wash before use. Routinely wash hands, arms and face with soap and water after handling. Do not smoke or eat until hands and face have been washed. Ventilation and Respiratory Protection: Good room ventilation is required. General mechanical ventilation is normally satisfactory. Use organic vapor respirator or supplied air respirator where supplemental protection is needed. Follow OSHA regulations when using personal protective equipment. Other: Eye wash, safety shower.
9. PHYSICAL AND CHEMICAL PROPERTIES Appearance clear liquid Color slight yellow tint Odor mild Boiling Range decomposes over 150oC. Melting Point super cools, sets to glass <10oC. Evaporation Rate(BuAcet=1) not volatile Vapor Density (air=1) n/a Weight per Gallon 8.9 Specific Gravity 1.07 Solubility in Water(%) very slight Percent Volatile negligible
10. STABILITY AND REACTIVITY Stability Stable Conditions to Avoid High heat (over 225oF) Incompatibility (materials to avoid) Oxidizing materials. Hazardous Polymerization Will not occur.
Hazardous Decomposition Products By fire: CO2, CO, partially decomposed hydrocarbons, other undetermined irritating and or toxic fumes or vapors.
11. TOXICOLOGICAL INFORMATION Polyether polyol: Skin rabbit LD50: >2000 mg/kg; dermal rat LD50: >2000 mg/kg; ingestion oral rat LD50: >2000 mg/kg.
12. ECOLOGICAL INFORMATION Data unavailable
13. DISPOSAL CONSIDERATIONS Waste Disposal Method: If discarded in its purchased form, this product is not hazardous waste either by listing or by characteristic. However, processing, use or contamination of this product may change its hazardous waste status. Under RCRA, it is the responsibility of the product user to determine, at the time of disposal, whether a material is a hazardous waste. State and local disposal regulations may differ from federal disposal regulations. Dispose in accordance with all federal, state, and local waste disposal laws and regulations. Incineration is the preferred method.
14. TRANSPORT D.O.T. Shipping Name none Technical Shipping Name Z7500 Part A Polyol, Plastic Related Material D.O.T. Hazard Class not regulated UN/NA Number none NMFC Item Plastic material liquid, NMFC-156240 Class 60
15. REGULATORY All components of this mixture are listed in the TSCA inventory. For details on regulatory requirements you should contact the appropriate agency in your state.
16. OTHER This data is offered in good faith as typical values and not as a product specification. The information in this data sheet was compiled from information supplied by the vendors of the components of this compound. No warranty, either expressed or implied is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate. The information on this data sheet is only to assist in the safe handling of this material, and may contain trade secrets which may not be divulged to anyone except the users of this material and health care and hygiene professionals as required for its safe use. No license or permission to infringe any patent or breach any trade secret is given.
Safety data sheet – MDI Product: ISOCYANATE B1001
1. Substance/preparation and company identification
ISOCYANATE B1001 Use: Chemical Manufacturer/supplier: BASF India Ltd 1st Floor, VIBGYOR Towers, Plot No. C – 62, ‘G’ Block, Bandra Kurla Complex, Mumbai – 400051, INDIA Telephone: +91 22 6661-8000 Telefax number: +91 22 6758-2753 Emergency information: International emergency number: Telephone: +49 180 2273-112
2. Composition/information on ingredients Chemical nature P-MDI (Content (W/W): 100 %) CAS Number: 9016-87-9
3. Hazard identification Harmful by inhalation. Irritating to eyes, respiratory system and skin. Limited evidence of a carcinogenic effect. May cause sensitization by inhalation and skin contact. Harmful: Danger of serious damage to health by prolonged exposure through inhalation.
4. First-Aid Measures General advice: Immediately remove contaminated clothing. If inhaled: Keep patient calm, remove to fresh air, seek medical attention. On skin contact: After contact with skin, wash immediately with plenty of water. Consult a doctor if skin irritation persists. On contact with eyes: Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist. On ingestion: Immediately rinse mouth and then drink plenty of water, do not induce vomiting, seek medical attention. Note to physician: Symptoms: tightness in the chest, coughing, difficulty breathing Hazards: Symptoms can appear later. Information on: Diphenylmethane-4,4'-diisocyanate (MDI) Hazards: Respiratory sensitization may result in allergic (asthma-like) signs in the lower respiratory tract including wheezing, shortness of breath and difficulty breathing, the onset of which may be delayed. Repeated inhalation of high concentrations may cause lung damage, including reduced lung function, which may be permanent. Substances eliciting lower respiratory tract irritation may worsen the asthma-like reactions that may be produced by product exposures. Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote, administer corticosteroid dose aerosol to prevent pulmonary odema.
5. Fire-Fighting Measures Suitable extinguishing media: dry powder, carbon dioxide, alcohol-resistant foam, water spray Specific hazards:
carbon dioxide, carbon monoxide, hydrogen cyanide, nitrogen oxides, isocyanate The substances/groups of substances mentioned can be released in case of fire. Special protective equipment: Wear self-contained breathing apparatus and chemical-protective clothing. Further information: Keep containers cool by spraying with water if exposed to fire. Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
6. Accidental Release Measures Personal precautions: Use personal protective clothing. Ensure adequate ventilation. Use breathing apparatus if exposed to vapours/dust/aerosol. Environmental precautions: Do not empty into drains. Do not discharge into the subsoil/soil. Methods for cleaning up or taking up: For large amounts: Pump off product. For residues: Pick up with absorbent material (e.g. sand, sawdust, general-purpose binder). Dispose of absorbed material in accordance with regulations. Neutralize with a solution of 5 - 10 % Sodium carbonate, 0,2 - 2 % detergents and 90 - 95 % water.
7. Handling and Storage Handling Provide suitable exhaust ventilation at the processing machines. Ensure thorough ventilation of stores and work areas. Avoid aerosol formation. When handling heated product, vapours of the product should be ventilated, and respiratory protection used. Wear respiratory protection when spraying. Danger of bursting when sealed gastight. Protect against moisture. Products freshly manufactured from isocyanates can contain incompletely reacted isocyanates and other dangerous substances. Clean up contamination as soon as they occur. Provide basic employee training to prevent/minimize exposures. Storage Keep away from water. Segregate from foods and animal feeds. Segregate from acids and bases. Suitable materials for containers: carbon steel (iron), High density polyethylene (HDPE), Low density polyethylene (LDPE), tin (tinplate), Stainless steel 1.4301 (V2) Further information on storage conditions: Keep container tightly closed in a cool, well-ventilated place. Protect against moisture. Formation of CO2 and build up of pressure possible. Danger of bursting when sealed gastight.
8. Exposure controls and personal protection Components with occupational exposure limits Diphenylmethane-4,4'-diisocyanate (MDI), 101-68-8; Personal protective equipment Respiratory protection: Respiratory protection in case of vapour/aerosol release. Combination filter for gases/vapours of organic compounds and solid and liquid particles (f.e. EN 14387 Type A-P2) Hand protection: Chemical resistant protective gloves (EN 374) Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): butyl rubber (butyl) - 0.7 mm coating thickness nitrile rubber (NBR) - 0.4 mm coating thickness chloroprene rubber (CR) - 0.5 mm coating thickness Unsuitable materials polyvinylchloride (PVC) - 0.7 mm coating thickness Polyethylene-Laminate (PE laminate) - ca. 0.1 mm coating thickness Eye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Body protection: safety shoes (e.g. according to EN 20346) General safety and hygiene measures: Do not breathe vapour/spray. With products freshly manufactured from isocyanates body protection and chemical resistant protective gloves is recommended. Wearing of closed work clothing is required additionally to the stated personal protection equipment. No eating, drinking, smoking or tobacco use at the place of work. Take off immediately all contaminated clothing. Hands and/or face should be washed before breaks and at the end of the shift. At the end of the shift the skin should be cleaned and skin-care agents applied.
9. Physical and Chemical Properties Form: liquid Colour: brown Odour: earthy, musty pH value: not applicable Melting point: < 0 °C Boiling point: 200 °C (1,013 mbar) Flash point: > 204 °C Flammability: not flammable Lower explosion limit: For liquids not relevant for classification and labelling., The lower explosion point may be 5 – 15 °C below the flash point. Upper explosion limit: For liquids not relevant for classification and labelling. Ignition temperature: > 600 °C Explosion hazard: not explosive Vapour pressure: < 0.01 Pa (25 °C) Density: 1.22 g/cm3 (25 °C) Relative density: approx. 1.22 (20 °C) Relative vapour density (air): 8.5 (20 °C) Solubility in water: Reacts with water., hydrolyzes Miscibility with water: Reacts with water. Partitioning coefficient n-octanol/water (log Pow): not applicable Viscosity, dynamic: 100 - 250 mPa.s (25 °C) Other Information: If necessary, information on other physical and chemical parameters is indicated in this section.
10. Stability and Reactivity Conditions to avoid: Temperature: < 15 °C Avoid moisture. Thermal decomposition: > 230 °C Substances to avoid: acids, alcohols, amines, water, Alkalines Corrosion to metals: No corrosive effect on metal. Hazardous reactions: Reacts with water, with formation of carbon dioxide. Risk of bursting. Reacts with substances which contain active hydrogen. No hazardous decomposition products if stored and handled as prescribed/indicated.
11. Toxicological Information Acute toxicity Assessment of acute toxicity: Virtually nontoxic after a single ingestion. Virtually nontoxic after a single skin contact. Of moderate toxicity after short-term inhalation. LD50 rat (oral): > 10,000 mg/kg LC50 rat (by inhalation): approx. 0.493 mg/l 4 h LD50 rabbit (dermal): > 10,000 mg/kg
Irritation Assessment of irritating effects: Eye contact causes irritation. Skin contact causes irritation. Primary skin irritation: Irritant. Primary irritations of the mucous membrane: Irritant.
Assessment other acute effects Assessment other acute effects: Causes temporary irritation of the respiratory tract.
Sensitization Assessment of sensitization: The substance may cause sensitization of the respiratory tract. Sensitization after skin contact possible.
Repeated dose toxicity Assessment of repeated dose toxicity: The substance may cause damage to the lung even after repeated inhalation of low doses, as shown in animal studies.
Genetic toxicity Assessment of mutagenicity: The substance was mutagenic in various test systems with microorganisms and cell cultures; however, these results could not be confirmed in tests with mammals.
Carcinogenicity Assessment of carcinogenicity: Indication of possible carcinogenic effect in animal tests. However, the relevance of this result for humans is unclear. The substance was tested in form of respirable aerosols.
Reproductive toxicity Assessment of reproduction toxicity: Repeated inhalative uptake of the substance did not cause damage to the reproductive organs.
Developmental toxicity Assessment of teratogenicity: Animal studies gave no indication of a developmental toxic effect at doses that were not toxic to the parental animals.
Experiences in humans coughing, dyspnea, tightness in the chest, temporary influenzal symptoms: Can severely irritate the eyes and respiratory tract depending upon the concentration.
12. Ecological Information Ecotoxicity Assessment of aquatic toxicity: There is a high probability that the product is not acutely harmful to aquatic organisms. No toxic effects occur within the range of solubility. Toxicity to fish: LC0 (96 h) > 1,000 mg/l, Fish (other) Aquatic invertebrates: EC0 (24 h) > 500 mg/l, daphnia (other) Aquatic plants: EC0 (72 h) 1,640 mg/l, Scenedesmus subspicatus (OECD Guideline 201)
Mobility Assessment transport between environmental compartments: Adsorption to solid soil phase is not expected.
Persistence and degradability Assessment biodegradation and elimination (H2O): Poorly biodegradable. Elimination information: < 10 % BOD of the ThOD (28 d) (OECD Guideline 302 C) (aerobic, activated sludge) Under test conditions no biodegradation observed.
Bioaccumulation potential Assessment bioaccumulation potential: Does not significantly accumulate in organisms.
Bioaccumulation potential: Accumulation in organisms is not to be expected.
Other adverse effects Adsorbable organically-bound halogen (AOX): This product contains no organically-bound halogen.
Additional information Other ecotoxicological advice: Do not release untreated into natural waters. Do not allow to enter soil, waterways or waste water channels.
13. Disposal Considerations Incinerate in suitable incineration plant, observing local authority regulations. Dispose of isocyanate waste in dry containers and never mix together with other wastes (reaction, dangerous pressure build up). Contaminated packaging: Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.
14. Transport Information Domestic transport: Not classified as a dangerous good under transport regulations Sea transport IMDG Not classified as a dangerous good under transport regulations Air transport IATA/ICAO Not classified as a dangerous good under transport regulations
15. Regulatory Information Regulations of the European union (Labelling) Regulation 1272/2008/EC on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation 1907/2006/EC: Hazard symbol(s) Xn Harmful. R-phrase(s) R20 Harmful by inhalation. R36/37/38 Irritating to eyes, respiratory system and skin. R40 Limited evidence of a carcinogenic effect. R42/43 May cause sensitization by inhalation and skin contact. R48/20 Harmful: Danger of serious damage to health by prolonged exposure through inhalation. S-phrase(s) S23.3 Do not breathe vapour/spray. S36/37 Wear suitable protective clothing and gloves. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Hazard determining component(s) for labelling: P-MDI Other regulations If other regulatory information applies that is not already provided elsewhere in this safety data sheet, then it is described in this subsection.
16. Other Information Recommended use: polyurethane component, industrial chemicals Vertical lines in the left hand margin indicate an amendment from the previous version. The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. The data do not describe the product's properties (product specification). Neither should any agreed property nor the suitability of the product for any specific purpose be deduced from the data contained in the safety data sheet. It is the
responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.
ANNEXURE 25 DETAILS OF HAZARDOUS CHARACTERISTICS AND TOXICITY OF PRODUCTS AND RAW MATERIALS
TOR NO.36 (part): Details of hazardous characteristics and toxicity of raw materials and products to be handled Table: Hazardous characteristics details
No Products and Raw Materials
Hazards Identification Exposure Control
1 MDI
Inhalation Harmful by inhalation, May cause sensitization by inhalation, Danger of
serious damage to health by prolonged exposure through inhalation. Respiratory Protection
Respirators
Skin Contact
Limited evidence of a skin contact. Skin Protection Gloves,
Eye Contact
Irritation, Eye Protection Safety goggles
Ingestion Limited evidence of a carcinogenic effect. Ventilation requirements
Provide local exhaust
2 Polyol .
Inhalation Nausea, irritation of digestive track. Irritation of respiratory system. Airborne aerosols or vapors from heated material may cause severe respiratory system irritation.
Gas Mask
Skin Contact
Rash, redness, may cause severe skin irritation, may cause allergic skin reactions in some individuals. Slightly toxic by skin absorption, Constant exposure to skin may cause chronic dermatitis. Other chronic effects are unknown.
Avoid direct contact, hand gloves
Eye Contact
Redness and irritation, may cause severe eye irritation Safety goggles
Ingestion May cause irritation of gastrointestinal track and nausea. Hand gloves , cleaning facility
ANNEXURE 26 CONTROL MEASURES PROPOSED TO ENSURE SAFETY AND AVOID HUMAN HEALTH
IMPACTS
TOR NO.36 (part): The control measures proposed to ensure safety and avoid the human
health impacts.
Table: Proposed control measures
No Exposure Source Control Measures
1 Respiratory Protection Wear NIOSH approved Respirator
2 Skin Protection Gloves, Flame retardant antistatic protective clothing
3 Eye Protection Dust proof goggles
4 Engineering Controls Provide local exhaust, dust collection system
5 Specific Hygiene Measures Washing after handling the material and before eating, drinking. No smoking. Routinely wash work clothing and protective equipment to remove contaminants
ANNEXURE 27 OCCUPATIONAL HEALTH IMPACTS AND MITIGATION MEASURES
TOR NO.40: Occupational health impacts on the workers and mitigation measures proposed to avoid the human health hazards along with the personal protective equipment to be provided to the workers. Provision of industrial hygienist and monitoring of the occupational injury to workers as well as impact on the workers. Plan for periodic medical checkup of the workers exposed. Details of work place ambient air quality monitoring plan as per Gujarat Factories Rules.
M/s. ICE Make Refrigeration Pvt. Ltd. Dantali Industrial Estate, Dist. Gandhinagar is committed towards the Health and Safety of workers and provided a facility of pre medical and regular medical check-up of employees for detecting any kind of adverse effect on the health of employee due to the chemical or work place condition and providing opportunity to improve the working condition.
The workers exposed to fugitive emission will be provided with some protective devices like dust mask to prevent respiratory disorders. The workers exposed to higher noise level will be provided with ear muffs/ ear plugs.
The protective devices will be provided to the employees handling hazardous substances. Proper handling of the hazardous chemicals and the maintenance of Material Safety Data Sheet (MSDS) will be followed to ensure safety within the plant area.
Drinking water supply for the employees will be provided by the project proponent and the standard of the drinking water will be per WHO guidelines. Proper sanitary facilities will be made available by the project proponent so that employees do not suffer from any health ailments. The employees will be made aware of general sanitary practices. Periodical training programme to inform the employees about their task, associated risk, and safe-working practices will be undertaken. Training will also include information on accident prevention, proper control and maintenance of equipment and safe material handling practices.
A regular monitoring of the Occupational Health and Safety will reduce the chances of accidents hence all the records of job related accidents and illness should be maintained as per the requirements of factory act. This information will be reviewed and evaluated to improve the effectiveness of Environmental Health and Safety programme.
The following occupational measures will be adopted:
The workers will be provided with personal protective equipment’s such as gloves, goggles, safety shoes, helmets and dust masks.
Periodic medical checkup of the workers for audiometric, blood tests, physical examination, etc. as per applicable rules.
First aid medical facility will be made available at the site and medical kit will be made available at strategic location and plant personnel will be trained for first aid medical treatment. Dispensary and medical facility is available in the nearby GIDC area and that will be utilized in the case of emergency. The company will appoint one doctor for further consultation and treatment in case of emergency. Plan will be made and sufficient fund will be allocated to ensure the occupational health & safety of all contract and casual workers. Details of exposure specific health status evaluation of worker, if required. workers' health will be evaluated by pre designed format, chest x rays, Audiometry, Spirometry, Vision testing (Far & Near vision, color vision and any other ocular defect) ECG, during pre-placement and periodical examinations by qualified person. Details of existing Occupational & Safety Hazards – As there is no any such chemical hazard, involved. Only material handling and mechanical and electrical hazards involved, which is covered under existing health hazards and illness, as per OHSAS requirement. Exposure levels of hazards and whether they are within Permissible Exposure level (PEL). If these are not within PEL, what measures the company has adopted to keep them within PEL so that health of the workers can be preserved – Work place monitoring is carried out to check exposure level as per Factory Act , Form no.37 , and will also be carried out after expansion.
Annual report of health status of workers with special reference to Occupational Health and Safety, submitted to Factory inspector office in prescribed format.
ANNEXURE 28
DETAILS OF RISK ASSESSMENT
TOR NO.41: Risk assessment including prediction of the worst case scenario and maximum
creditable accident should be carried out. The worst-case scenario should take into account
the maximum inventory of storage at site at any point of time. The risk contours should be
plotted on the map clearly showing which of the facilities and surrounding units would be
affected in case of an accident taking place.
Risk Assessment including prediction of worst case scenario and Maximum Credible
Accident (MCA) Scenario: (Reference Annexure Risk Assessment Page no. 29)
We have considered or assumed worst case scenario modeling for preparedness of
Emergency situation only. Polyol will be stored at separate storage area, so there will
not be any possibility of seepage and polyol will be stored with provision of four
walls facility and separate storage tank, and necessary precautions.
Polyol:
Spare tank provided to transfer the material in case of leak.
Stock of dry sand and lime is kept near the storage area.
Provision of Respiratory protective equipment and personal protective
equipment.
Safety shower and eye wash unit installed.
Strict supervision while uploading, regular testing and inspection of tanks.
The worst-case scenario including the maximum inventory of storage at site at any
point of time: (Reference Annexure Risk Assessment Page no. 24)
Possible Accident Scenarios
Scenario* MCL Pressure Temp. Qty.
1 Release of Polyol Ambient Ambient 225 liters
Worst Case Scenario
Scenario MCL Red
Zone,meter
Orange
Zone, meter
Yellow
Zone, meter Remarks
1 Release of Polyol 82 114 155
The risk contours map clearly showing which of the facilities and surrounding units
would be affected in case of an accident taking place is as below: (Reference
Annexure Risk Assessment Page no. 25 )
(Reference Annexure Risk Assessment Page no. 25)
ANNEXURE 29 REPORT ON RISK ASSESSMENT & DISASTER MANAGEMENT PLAN
TOR NO.41 (part): Risk assessment including prediction of the worst case scenario and maximum creditable accident should be carried out. The worst-case scenario should take into account the maximum inventory of storage at site at any point of time. The risk contours should be plotted on the map clearly showing which of the facilities and surrounding units would be affected in case of an accident taking place. Attached in the Risk Assessment Folder online.
ANNEXURE 30 ON SITE EMERGENCY PLAN
TOR NO.41 (part): Proposed safeguard measures including On-site /Off-site Emergency plan should be provided. The Report on On-Site Emergency Plan is uploaded with Risk Assessment Report.
ANNEXURE 31 CHECKLIST FOR HANDLING OF CHEMICALS, MATERIAL HANDLING, FIRE PREVENTION &
HOUSEKEEPING
TOR No.31: Submit checklist in the form of Do’s & Don’ts of preventive maintenance, strengthening of HSE, manufacturing utility staff for safety related measures
ANNEXURE 32 CTE AMENDMENT & CCA REPORT
TOR NO.44 (part): In case the existing project has not obtained environment clearance, reasons for not taking EC under the provisions of the EIA Notification 1994 and/or EIA Notification 2006shall be provided. Copies of Consent to Establish/ No objection Certificate and consent to operate(in case of units operating prior to EIA Notification 206, CTE and CTO of FY 2005-2006) obtained from the SPCB shall be submitted
ANNEXURE 33 COMPLIANCE REPORT OF CTE CONDITIONS
TOR NO 44 (part): Compliance report to the conditions of consents from the SPCB shall be submitted. TOR NO.45: Consent to Establish, Consent to Operate orders obtained in past along with point wise compliance status of all the conditions stipulated therein.
CTE COMPLIANCE REPORT
No. CTE Condition Compliance/Status
CTE – 43067 dated: 25/08/2011
CONDITIONS UNDER THE WATER ACT:
1 Qty. of Trade Effluent < 300 l/day. Complied
2 Qty. of industrial effluent discharged from the manufacturing process and other ancillary operations shall be NIL as the generated effluent completely evaporated in well design evaporation pan.
Complied
3 Qty. of Sewage Effluent < 4.2 m3/day. Complied
7 Domestic effluent shall be disposed off through septic tank/soak pit system.
Complied
CONDITIONS UNDER THE AIR ACT:
8 The Qty. of fuel in Boiler/ Furnace / Heater i.e. Diesel shall be 10 L/Hr.
Complied
9 The applicant shall install & Operate Air pollution Control system in order to achieve norms prescribed by the Board.
Not Concerned but agree to do so if required.
10 The flue gas emission through stack attached to Boiler / Furnace / Heater shall conform to GPCB standards.
Complied
11
The process emission through various stacks/vents of reactors, process, and vessel shall conform to GPCB standards.
Complied
12 SMF’s like Portholes, ladder, platform etc. at chimney shall be provided for monitoring and the same shall be open for inspection.
Complied
13 The concentration of Suspended Particulate Matter (PM 10), Particulate Matter (PM 2.5), Oxides of Sulphur and Oxides of Nitrogen & Respirable Suspended Particulate Matter in ambient air shall not exceed the limit of 100, 60, 80, 80 microgram per cubic meter respectively.
Agree to comply
14 All measures for control of environmental pollution shall be provided before commencing production.
Agreed
CONDITIONS UNDER HAZARDOUS WASTE:
15 Applicant shall have to comply with provisions of Hazardous Waste (M, H & Trans boundary movement) Rule – 2008.
Agreed
15.1 The applicant shall obtain membership of common TSDF site for disposal of Hazardous
Agreed
Waste (Management, Handling & Trans boundary movement) Rule – 2008.
15.2 The applicant shall obtain membership of CHWIF for disposal of Incinerable waste.
Agreed
15.3 The applicant shall provide temporary storage facilities for each type of hazardous waste as per Haz. Waste (M, H & Trans boundary movement) Rule – 2008.
Complied
CTO COMPLIANCE REPORT
No. CTE Condition Compliance/Status
CC&A No.: AWH - 14760 dated: 10/01/2014
2 CONDITIONS UNDER THE WATER ACT:
2.1 Qty. of Trade Effluent < 300 L/day. Complied
2.2 Qty. of industrial effluent discharged from the manufacturing process and other ancillary operations shall be NIL as the generated effluent completely evaporated in well design evaporation pan.
Complied
2.3 Qty. of Sewage Effluent < 4200 L/day. Complied
2.4 Domestic effluent shall be disposed off through septic tank/soak pit system.
Complied
3 CONDITIONS UNDER THE AIR ACT:
3.1 The Qty. of fuel in Boiler/ Furnace / Heater i.e. Diesel shall be 10 L/Hr.
Complied
3.2 The applicant shall install & Operate Air pollution Control system in order to achieve norms prescribed by the Board.
Complied
3.3 The flue gas emission through stack attached to Boiler / Furnace / Heater shall conform to GPCB standards.
Complied
3.4
The process emission through various stacks/vents of reactors, process, and vessel shall conform to GPCB standards.
Complied
3.5 The concentration of Suspended Particulate Matter (PM 10), Particulate Matter (PM 2.5), Oxides of Sulphur and Oxides of Nitrogen & Respirable Suspended Particulate Matter in ambient air shall not exceed the limit of 100, 60, 80, 80 microgram per cubic meter respectively.
Agree to comply
3.6 The applicant shall operate industrial plant / APCM very efficiently and continuously so that gaseous emission conforms to the standards specified by the Board.
N C
3.7 The consent to operate the plant shall lapse if at any time the parameters of gaseous emission are not within the tolerance limits specified in the order.
Agreed
3.8 Adequate measures shall be taken for control of noise levels, to maintain air quality standards in respect of noise to less than 75 dB (a) during day time and 70 dB (A) during night time.
Complied
3.9 The applicant shall at his own cost get samples of Complied
AAQ collected & analyzed from an approved laboratory once in 3 months.
5. CONDITIONS UNDER HAZARDOUS WASTE:
5.1 The unit is hereby granted to an authorization to operate facility for the Hazardous wastes as mentioned in the Order.
Complied
5.2 The authorization is granted to operate a facility for collection, storage and disposal to authorized decontamination facility, recycler & registered refiner, TSDF site and reuse within premises.
Complied
5.3 The authorization shall be in force up to 20-10-2018
Agreed
5.4 The authorization is subject to the conditions stated below and such other conditions as may be specified in the rules under the EPA – 1986.
Plant Lay Out
