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  • 20

  • Molar Mass Water 18.0153 g.mol-1 Molar Volume

    HMI 99.176 g.mol-1

    x H2O Density g/cc Density mol/ccV cc VE VE cal

    0.0000 111.43621 0.000 0.00000

    0.0199 0.89147 0.00914 109.44157 -0.139 -0.11414

    0.0395 0.89256 0.00930 107.52235 -0.224 -0.22079

    0.0821 0.89527 0.00968 103.33907 -0.432 -0.43071

    0.1198 0.89759 0.01003 99.65903 -0.586 -0.59419

    0.1594 0.90005 0.01044 95.81577 -0.730 -0.74591

    0.1994 0.90285 0.01088 91.92423 -0.886 -0.88211

    0.2498 0.90632 0.01149 87.05761 -1.043 -1.03417

    0.3000 0.90981 0.01216 82.24551 -1.166 -1.16700

    0.3499 0.91373 0.01291 77.45622 -1.290 -1.28104

    0.4000 0.91767 0.01376 72.69685 -1.373 -1.37460

    0.4529 0.92226 0.01478 67.67674 -1.449 -1.44591

    0.5008 0.92661 0.01583 63.16670 -1.487 -1.48099

    0.5041 0.92661 0.01590 62.87747 -1.468 -1.48227

    0.5508 0.93105 0.01709 58.50249 -1.476 -1.48366

    0.5992 0.93570 0.01851 54.01786 -1.444 -1.45129

    0.6500 0.94101 0.02027 49.33349 -1.385 -1.38110

    0.6990 0.94642 0.02230 44.84761 -1.291 -1.28169

    0.7496 0.95251 0.02485 40.24938 -1.163 -1.15208

    0.7994 0.95933 0.02797 35.75221 -1.010 -1.00298

    0.8398 0.96550 0.03113 32.12558 -0.861 -0.86701

    0.8799 0.97262 0.03503 28.54424 -0.696 -0.71503

    0.9200 0.98118 0.04003 24.97822 -0.516 -0.53544

    0.9599 0.99153 0.04663 21.44764 -0.315 -0.30885

    0.9600 0.9916 0.04663 21.44397 -0.316 -0.30868

    0.9699 0.99444 0.04862 20.56922 -0.260 -0.24112

    0.9800 0.9971 0.05077 19.69568 -0.194 -0.16722

    1.0000 18.021 0.000 0.00000

    NEXP 26

    O.F

    No.of parameters= 7

    A0= -5.923

    A1= -0.845

    A2= 1.031

    A3= 1.456

    A4= -2.619

    A5= -2.221

    A6= 0.000

    -1.600

    -1.400

    -1.200

    -1.000

    -0.800

    -0.600

    -0.400

    -0.200

    0.000

    0.0000 0.2000 0.4000

    Ex

    ce

    ss

    Vo

    lum

    e

    Mol. fractionX1

  • Water 18.021 cc/mol 0.999699

    HMI 111.436 cc/mol 0.88998

    Ecart Ecart

    0.00000 0.00000

    0.00062 -0.02496

    0.00001 -0.00316

    0.00000 -0.00126

    0.00007 0.00815

    0.00025 0.01586

    0.00002 -0.00430

    0.00009 -0.00930

    0.00000 0.00086

    0.00007 -0.00859

    0.00000 0.00133

    0.00001 -0.00262

    0.00004 -0.00639

    0.00020 0.01413

    0.00006 0.00757

    0.00005 0.00733

    0.00001 -0.00376

    0.00009 -0.00969

    0.00011 -0.01071

    0.00005 -0.00724

    0.00004 0.00647

    0.00036 0.01910

    0.00038 0.01947

    0.00004 -0.00601

    0.00005 -0.00739

    0.00034 -0.01856

    0.00070 -0.02646

    0.00000 0.00000

    0.00369

    0.01393

    0.6000 0.8000 1.0000

    Mol. fractionX1

  • 10.00 15.00 20.00 25.00 30.00 35.00

    M1 0.5041 0.4959 0.92661 0.92223 0.91782 0.91338 0.90891 0.90440

    M2 0.3000 0.7000 0.90981 0.90538 0.90091 0.89642 0.89191 0.88738

    M3 0.6990 0.3010 0.94642 0.94229 0.93812 0.93390 0.92963 0.92532

    M4 0.1594 0.8406 0.90005 0.89561 0.89115 0.88667 0.88219 0.87768

    M5 0.8398 0.1602 0.96550 0.96188 0.95820 0.95447 0.95068 0.94683

    M6 0.4000 0.6000 0.91767 0.91325 0.90879 0.90432 0.89981 0.89528

    M7 0.5992 0.4008 0.93570 0.93142 0.92709 0.92272 0.91831 0.91386

    M8 0.1198 0.8802 0.89759 0.89316 0.88870 0.88423 0.87975 0.87526

    M9 0.8799 0.1201 0.97262 0.96930 0.96590 0.96245 0.95891 0.95531

    M10 0.2498 0.7502 0.90632 0.90188 0.89741 0.89292 0.88842 0.88390

    M11 0.7496 0.2504 0.95251 0.94850 0.94446 0.94036 0.93622 0.93202

    M12 0.0395 0.9605 0.89256 0.88813 0.8837 0.87925 0.8748 0.87034

    M13 0.9599 0.0401 0.99153 0.98932 0.98699 0.98454 0.98198 0.97929

    M14 0.6500 0.3500 0.94101 0.93679 0.93253 0.92822 0.92388 0.91949

    M15 0.3499 0.6501 0.91373 0.9093 0.90484 0.90036 0.89585 0.89132

    M16 0.7994 0.2006 0.95933 0.95551 0.95164 0.94771 0.94373 0.93969

    M17 0.1994 0.8006 0.90285 0.8984 0.89394 0.88946 0.88496 0.88045

    M18 0.9200 0.0800 0.98118 0.97828 0.9753 0.97224 0.9691 0.96586

    M19 0.0821 0.9179 0.89527 0.89084 0.88639 0.88194 0.87747 0.87299

    M20 0.5508 0.4492 0.93105 0.92672 0.92234 0.91793 0.91348 0.909

    M21 0.4529 0.5471 0.92226 0.91786 0.91342 0.90896 0.90446 0.89994

    M22 0.9800 0.0200 0.9971 0.99556 0.9938 0.99186 0.98975 0.98748

    M23 0.0199 0.9801 0.89147 0.88705 0.88262 0.87818 0.87374 0.86929

    M24 0.9600 0.0400 0.9916 0.98939 0.98706 0.98461 0.98204 0.97935

    M25 0.5008 0.4992 0.92661 0.92224 0.91783 0.91338 0.90891 0.9044

    M26 0.9699 0.0301 0.99444 0.99249 0.9904 0.98816 0.9858 0.9833

    Systme H2O/Hexamethyleneimine

    xH2OTemperature

    xHMI

    0.80000

    0.85000

    0.90000

    0.95000

    1.00000

    1.05000

    0.0000 0.2000 0.4000 0.6000 0.8000 1.0000

    Den

    sit

    y (

    wate

    r +

    HM

    I) g

    /cc

    X1=mol fraction of water

  • X1=mol fraction of water

  • 40.00 45.00 50.00 55.00 60.00 65.00 70.00 75.00

    0.89986 0.89528 0.89068 0.88603 0.88135 0.87663 0.87187 0.86707

    0.88283 0.87826 0.87367 0.86905 0.86440 0.85973 0.85503 0.85031

    0.92096 0.91655 0.91210 0.90759 0.90303 0.89842 0.89376 0.88904

    0.87316 0.86863 0.86408 0.85951 0.85493 0.85032 0.84570 0.84106

    0.94292 0.93893 0.93488 0.93076 0.92657 0.92230 0.91797 0.91357

    0.89072 0.88614 0.88152 0.87688 0.87221 0.86750 0.86276 0.85799

    0.90937 0.90485 0.90028 0.89567 0.89102 0.88632 0.88158 0.87678

    0.87075 0.86623 0.86170 0.85715 0.85259 0.84800 0.84340 0.83879

    0.95163 0.94787 0.94403 0.94012 0.93613 0.93206 0.92791 0.92342

    0.87935 0.87479 0.87021 0.86560 0.86098 0.85633 0.85165 0.84694

    0.92777 0.92347 0.91911 0.91470 0.91024 0.90571 0.90113 0.89649

    0.86587 0.86139 0.8569 0.8524 0.8479 0.84337 0.83884 0.8343

    0.97648 0.97355 0.9705 0.96734 0.96406 0.96066 0.95832 0.95448

    0.91505 0.91058 0.90606 0.90149 0.89687 0.89221 0.8875 0.88274

    0.88676 0.88218 0.87758 0.87294 0.86828 0.86359 0.85887 0.85412

    0.93559 0.93144 0.92723 0.92295 0.91861 0.91421 0.90974 0.90521

    0.87592 0.87137 0.86681 0.86222 0.85762 0.85299 0.84834 0.84367

    0.96253 0.95911 0.95559 0.95198 0.94828 0.94447 0.9429 0.93807

    0.86849 0.86399 0.85948 0.85495 0.85041 0.84586 0.84128 0.83669

    0.90448 0.89993 0.89533 0.8907 0.88603 0.88131 0.87655 0.87176

    0.89539 0.8908 0.88619 0.88154 0.87687 0.87215 0.86739 0.8626

    0.98506 0.9825 0.9798 0.97698 0.97402 0.97094 0.96774 0.96439

    0.86483 0.86037 0.8559 0.85142 0.84692 0.84242 0.83791 0.83338

    0.97654 0.97361 0.97056 0.9674 0.96412 0.96072 0.9584 0.95496

    0.89986 0.89529 0.89068 0.88604 0.88136 0.87663 0.87187 0.86708

    0.98066 0.9779 0.97501 0.972 0.96888 0.96563 0.96325 0.96276

    Systme H2O/Hexamethyleneimine

    Temperature

    0.80000

    0.85000

    0.90000

    0.95000

    1.00000

    1.05000

    0.0000 0.2000 0.4000 0.6000 0.8000 1.0000

    Den

    sit

    y(w

    ate

    r+H

    MI)

    (g

    /cc)

    X2=Mol.Fraction of HMI

    Series1

    Series2

    Series3

    Series4

    Series5

  • X2=Mol.Fraction of HMI

  • 80.00

    0.86222

    0.84554

    0.88427

    0.83638

    0.90909

    0.85318

    0.87195

    0.83414

    0.91878

    0.84220

    0.89179

    0.82973

    0.95636

    0.87792

    0.84932

    0.90062

    0.83895

    0.93373

    0.83207

    0.86692

    0.85776

    0.9611

    0.82884

    0.96083

    0.86224

    0.9626

    Systme H2O/Hexamethyleneimine

    Temperature

    Series1

    Series2

    Series3

    Series4

    Series5

    Series6

  • T Density Density.ExpDensity.Calulated Difference Diffrnc^2 Density cal.

    K g/cc cm3.mol-1 cm3.mol-1 % % g/cc

    273.16 0.89881 110.341 110.49584 -0.001399 0.00000 0.89755

    273.66 0.89836 110.40 110.54621 -0.001354 0.00000 0.89715

    274.16 0.89792 110.45 110.59667 -0.001320 0.00000 0.89674

    274.66 0.89748 110.50 110.64720 -0.001287 0.00000 0.89633

    275.16 0.89704 110.56 110.69781 -0.001254 0.00000 0.89592

    275.66 0.89660 110.61 110.74849 -0.001221 0.00000 0.89551

    276.16 0.89616 110.67 110.79925 -0.001188 0.00000 0.89510

    276.66 0.89572 110.72 110.85008 -0.001156 0.00000 0.89469

    277.16 0.89528 110.78 110.90100 -0.001124 0.00000 0.89428

    277.66 0.89484 110.83 110.95199 -0.001092 0.00000 0.89386

    278.16 0.89440 110.89 111.00305 -0.001060 0.00000 0.89345

    278.66 0.89396 110.94 111.05420 -0.001029 0.00000 0.89304

    279.16 0.89351 111.00 111.10542 -0.000986 0.00000 0.89263

    279.66 0.89307 111.05 111.15672 -0.000955 0.00000 0.89222

    280.16 0.89263 111.11 111.20810 -0.000924 0.00000 0.89181

    280.66 0.89219 111.16 111.25955 -0.000894 0.00000 0.89139

    281.16 0.89175 111.22 111.31109 -0.000864 0.00000 0.89098

    281.66 0.89131 111.27 111.36270 -0.000834 0.00000 0.89057

    282.16 0.89087 111.32 111.41440 -0.000804 0.00000 0.89015

    282.66 0.89042 111.38 111.46617 -0.000763 0.00000 0.88974

    283.16 0.88998 111.44 111.51802 -0.000734 0.00000 0.88933

    283.66 0.88954 111.49 111.56995 -0.000705 0.00000 0.88891

    284.16 0.88910 111.55 111.62196 -0.000676 0.00000 0.88850

    284.66 0.88866 111.60 111.67405 -0.000648 0.00000 0.88808

    285.15 0.88822 111.66 111.72518 -0.000610 0.00000 0.88768

    285.66 0.88777 111.71 111.77848 -0.000581 0.00000 0.88725

    286.16 0.88733 111.77 111.83081 -0.000553 0.00000 0.88684

    286.66 0.88689 111.82 111.88323 -0.000525 0.00000 0.88642

    287.16 0.88645 111.88 111.93572 -0.000498 0.00000 0.88601

    287.66 0.88600 111.94 111.98830 -0.000460 0.00000 0.88559

    288.16 0.88556 111.99 112.04096 -0.000433 0.00000 0.88518

    288.66 0.