Pembahasan Van Winkle

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    Oleh:

    Dwi Ratna Ning Tyas 2306.100.035

    Choiruddin Sinaga 2306.100.077

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    % F

    0 95

    5 125

    10 150

    20 210

    30 255

    40 290

    50 330

    60 37070 410

    80 455

    90 510

    End Pt. 98 580

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    the Tabulation of Edmister and Okamoto [7]is followed in solving for the atmosphericEFV curve.

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    Vol %distilled

    ASTM EFV

    t, F Interval, % t t t, F

    0 95 - - - 150

    - - 0-10 55 25 -10 150 - - - 175

    - - 10-30 105 75 -

    30 255 - - - 250

    - - 30-50 75 47 -

    50 330 - - - 297

    - - 50-70 80 48 -

    70 410 - - - 345

    - - 70-90 100 62 -

    90 510 - - - 407

    - - 10-100 87 42 -

    100 597 - - - 449

    The ASTM 30-10 % temperature difference is 105 F.

    The EFV 50% temperature is read from Fig. 3.17. temperature difference ( functionof percent distilled) are read from Fig. 3.18.

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    % distilled TBP760 mmHg,

    t, F

    EFV, 760 mmHg,t F EFV, 10 mmHg,t, F

    Uncorr. Corr Uncorr. Corr.

    Initial 105 - -212 428

    498

    -212 28610 290 - -184 456 -184 314

    30 510 - -98 542 -98 400

    50 650 640 +5 645 +5 503

    70 760 - +93 733 +93 591

    90 830 - +168 808 +168 666

    End pt. 950 - +190 830 +190 688

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    %/8,760

    290760

    TBPslope

    Interrelationship between ASTM and TBp distillationcurve data are necessary for transposition from onetype of distillation curve to the other if completeexperimental data are not available. Correlationrelating the 50 % temperatures and slopes have beenreported for atmospheric pressure [18] andsubatmospheric pressure [27]