percent LOU A Over 10 000 [45401 3.0 2.5 maximum S54.2

NO’FICl: This standard has either been superccded and replaced by a new version or discontinued.Contact ASTM Iuternaiioiial (www.astm.org) for the latesl inforniatiun.

• A 27/A 27M

Copper, max, % 0.50Nickel, max, % 0 50Molybdenum, max, % 025Chromium, max, % 0.50

The Amencan Society for Testing and Materia’s takes no position respecting the validity of any patent rights asserted in connectionwith any itent mentioned in this standard Users of this standard ale expressly advised that determination of the validity of any suchpatent rights, and the nsk of infringement of such rights. are entirely their own responsibility

This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five yeats andif not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standardsand shoutd be addressed to ASTM Headquarte,s. Your comments will receive careful consideration at a meeting of the responsibletechnical committee, which you may attend. If you feel that your comments have not received a fair hearing you should make yourviews known to the ASTM Committee on Standaros, at the address shown betow

This standard is copyrighted by ASTM, 100 Barr Harbor Onve, P0 BOX 0700, West Conshohocken, PA 19428-2959, United States.Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the above address or at610-832-9585 (phone), 610-832-9555 (fax), or [email protected] (e-mail); or through the ASTM website (wwwastm.org).

Speci lication A 78 I/A 781 M. ‘I’he chenucal analysis thus detot-mined shall coniorm to the lol]owitig requirements:

S54.2 Fotal content of these residual elements. maximumpercent LOU

TABLE 5 Allowable Deviation’ from Average Casting Weight

Casting Weight, lb [kg) Positive NegativeDeviation, % Deviation, %

Up to 100 [451, nd 80 8.0Over 100 to 500 [45 to 230] nd 65 50Over 500 to 10 000 [230 to 4540], md 50 3 0Over 10 000 [45401 3.0 2.5

A Deviations do not apply to mass as calculated from a design drawing

4

fr A 148/A 148M—02

TABLE 2 Tenstle Requirements

Grade Tensile strength mm, Yield point mm, Elongalion in 2lcsi [MPe] ksi [MPa] in. or 50 n,m, Reduction of Area, mm, %

win, %‘°

80-40 1550-2751 80 [550] 40 [275] 18 30

80-50 [550-3451 80 [550] 50 [345] 22 35

90-60 [620-415) 90 [620] 60 [415] 29 40

105-85 [725-585] 105 [725] 85 [585] 17 35

115-95 [795-655] 115 [795] 95 [655] 14 30

130-115 [895-795] 130 [895] 115 [795] ii 25

135-125 [930-860] 135 1930] 125 [860] 9 22

150-135 [1035-930] 150 [1035] 135 [930] 7 18

160-145[1105-1000] 160(1105] 145(10001 6 12

165-150[1140-1035] 165[1140] 150[1035] 5 20

165-150L [1140-1035L]° 165 [1140] 150 [1035] 5 20

210-18011450-12401 210[1450J 180]240] 4 15

210-180L[1450-1240L]° 210 [1450] 180 [1240] 4 15

260-210 [1795-1450] 260 [1795] 210 [1450] 3 6

260-210L [1795-1450Ll° 260 [1795] 210 (1450] 3 6

A When ICI test bars are used in tensile testing as provided for in this specification, the gage length to reduced aection diameter ratio shall be 4 to 1.

eThese grades must be charpy impact tested as prescnbed in Section 9, and with minimum values as shown in Table 3.

7. Chemical Composition

7.1 The steel shall coniomi to sulfur and phosphorus requirements as prescribed in Table 1.

7.2 The content of carbon, manganese. silicon, and alloying

elements may, by agreement. be prescribed by thc purchaser. Ifnot specified, the content may be selected by tile manufacturerto obtain the required mechanical properties.

7.3 When the analysis of carbon. manganese, silicon, or anyintentionally added alloying element is specilcally requestedin the contract or order, it shall be made by the manufacturer

and reported to the purchaser. The results of these analysesshall not be used as a basis for rejection except by prioragreement.

8. Tensile Requirements

8.! One tension test shal] be made from each heat and shallconform to the tensile requirements specified iii Table 2.

8.2 The test coupons and specimens shall confbrrn torequirements specified in Section 11.

8.3 Tension test coupons shall he machined to the form anddimension shown in Fig. 5 of Test Methods and i)efinitions

A 370 and tested in accordance with those test methods.8.4 To determine conformance with the tension test require

nients, an observed value or calculated value shall be roundedoff in accordance with Practice E 29 to the nearest 50(1 psi [5MPaj for yield point and tensile strength and to the nearest 1 %for elongation and reduction of area.

9. Charpy Impact Requirements

9.1 This section is applicable only to grades 165-150L{1140-1035L], 210-180L [1450-1240L], and 260-2101, [1795-

1450L1.

NOTE I—Other grades may be ordered to charpy impact test require

ments in accordance with Supplementary Requirement S9 of Specilication

A 781/A 781M.

9.2 The notched bar impact properties of each heat shall bedetermined by testing one set of three Charpy V-notch impactspecimens at —40° 2°F [—40° ± 1°Ci. The energy value ofthe three specimens shall not be less than shown in Table 3.

TABLE 3 Impact Requirements

Grade 165-150L 210-180L 260-210L[1140- [1450- [1795-1035L] 1240L] 1450L]

Impact Requirements 20 [27] 15 [20] 6 [8]Charpy V-notch

Energy value, ftlbf [J], mv-t value fortwo spedmens and mini mum average of three spedmans

Energy value, ftlbf [J], mm for single 16 [22] 12 [16] 4 [5]

specimen

9.3 Test coupons and specimens shall conform to therequirements specified in Section 11.

9.4 Impact test specimens shall be machined to the form anddimensions shown in Test Methods and Definitions A 370,Type A, Charpy V-notch specimen, Fig. 11, and tested inaccordance with thosts test methods.

10. Retests

10.1 If the results of the tensile or charpy teSts do notcontbrm to the requirements specified, heat-treated castingsmay, at the manufacturer’s option, be reheat treated. Testingafter reheat treatment shall consist of the full number ofspecimens complying with the specification or order.

ii. Test Coupons and Specimens

11.1 ‘Pest bars shall be poured from the same heat as thecastings represented. ‘Test coupons may be cast integrally withthe castings or as separate blocks similar to those shown in Fig.1 of Specification A 781/A 781M.

11.1.1 In the case cf quenched and tempered castings wherethe ruling section of the casting exceeds three inches, supplementaiy requirementS l5ofSpeciflcationA 781/A 781M shallapply.

11.2 The bar from vhich the test piece is taken shall be heattreated in production furnaces with the castings or to the sameprocedure as the castings it represents.

11.2.] When the bar from which the test piece is taken is notheat treated as part of the same heat treatment load as the

2

A 1481A 148M —02

SUMMARY OF CHANGES

Subcommittee AOL 18 has identified the location of selected changes to this standard since the last issue

(A 148/A 148M 01) that may impact the use of this standard.

(I) Added UNS DXXXX equivalents to Table 1.

ASTM International takes no position respecting the validity of any patent rights asserted in connection with any item mentioned

in this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the risk

of infringement of such rights, are entirely their own responsibility.

This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years and

if not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standards

and should be addressed to ASTM International Headquarters. Your comments will receive careful consideration at a meeting of the

responsible technical committee, which you may attend. if you feel that your comments have not received a fair hearing you should

make your views known to the ASTM Committee on Standards, at the address shown below.

This standard is copyrighted by ASTM International. 100 Barr Harbor Drive. PD Box C700, West Conslmohocken, PA 19428-2959,

United Slates, Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the above

address or at 610-832-9585 (phone). 610-832-9555 (fax), or sendceastm.org fe-mail); or through the ASTM website

(wwwastm org)

4

Ect

c;:

Cr3

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E—

E]

ITestAmericaTHE LEADER IN ENVIRONMENTAL TESTING

ANALYTICAL REPORTTestAmerica Laboratories, Inc.TestAmerica Savannah5102 LaRoche AvenueSavannah, GA 31404Tel: (912)354-7858

TestAmerica Job ID: 680-70758-2Client Project/Site: Hercules Hattiesburg APIX 7/26/11

For:Ashland Inc.Ashland Hercules Research Center500 Hercules Rd Bldg 8139Wilmington, Delaware 19808

Attn: Timothy Hassett

2 €—_

Authorized for release by:08/10/2011 06:12:29 PM

Lidya GuliziaProject Manager IIiidya.guliziatestamericainc.com

cc: Craig Derouen Chris Waters Charlie Jordan

Results relate only to the items tested and the sample(s) as received by the laboratory.The test results in this report meet alt 2003 NELAC and 2009 TN! requirements for accreditedparameters, exceptions are noted in this reporl This report may not be reproduced exceptin full, and with written approval from the laboratory For questions please contactthe Project Manager at the e-mail address or telephone nwnber listed on this page

This report has been electronically signed and authorized by the signatory Electronic signatureis intended to be the legally binding equivalent of a traditionally handwritten signature

Page 1 of 18

Case NarrativeClient: Ashland Inc. TestAmerica Job ID: 680-70758-2Project/Site: Hercules Hattiesburg APIX 7/26/11

)Job ID: 680-70758-2

Laboratory: TestAmerica Savannah

Narrative

Job Narrative

680-70758-2

Receipt

U All samples were received in good condition within temperature requirements.

GC!MS VOA

No analytical or quality issues were noted.

VOA PrepNo analytical or quality issues were noted.

U CommentsNo additional comments.

‘ED

IIU

nU

n

TestAmerica Savannah

Page 3 of 18

Method SummaryClient: Ashland Inc.Project/Site: Hercules Hattiesburg APIX 7/26/11

Method Method Description

___________

82608 Volatile Organic Compounds (GC!MS) -

Protocol References:

SW846 = “Test Methods For Evaluating Solid Waste, PhysicallChemical Methods”, Third Edition, November 1986 And Its Updates.

Laboratory References:

TALSAV=TestAmerica Savannah, 5102 LaRoche Avenue, Savannah, GA 31404, TEL (912)354-7858

U

0CED

UU

nUU

C

E

TestAmerica Job ID: 680-70758-2

Protocol Laboratory

SW846 TALSAV


Client Sample ResultsClient: Ashland Inc. TestAmerica Job ID: 680-70758-2Project/Site: Hercules Hattiesburg APIX 7/26/11

Client Sample ID: ASH-MW2I-072611 Lab Sample ID: 680-70758-8

O Date Collected: 07/26/11 15:03 Matrix: WaterDate Received: 07127111 09:20

Method: 82608 - Volatile Organic Compounds (GCIMS)Analyte Result Qualifier RL MDL Unit 0 Prepared Analyzed - DII FacAcetone <1300 1300 ug/L 07/30/11 07:05 50

Acetonhtrile <2000 2000 ug/L 07/30/11 07:05 50

Acrolein <1000 1000 ug/L 07/30/11 07:05 50

Acrylonitrile <1000 1000 ug/L 07/30/11 07:05 50

Benzene 3200 50 ug/L 07/30/11 07:05 50

Dichlorobromomethane <50 50 ug/L 07/30/11 07 05 50

[ I Bromoform <50 50 ug/L 07/30/11 07 05 50

Bromomethane <50 50 ug/L 07/30/11 07:05 50

2-Butanone (MEK) <500 500 ug/L 07/30/11 07:05 50

carbon disultide <100 100 ug/L 07/30/11 07:05 50

carbon tetrachloride <50 50 ug/L 07/30/11 07:05 50

Chlorobenzene 150 50 ug/L 07/30/11 07:05 50

2-Chloro-i,3-butadiene <50 50 ug/L 07/30/11 07:05 50

Chloroethane <50 50 ug/L 07/30/11 07:05 50

Chloroform 4300 50 ugIL 07/30/11 07:05 50

Chloromethane <50 50 ug/L 07/30/11 07:05 50

3-Chloro-1-propene <50 50 ug/L 07/30/11 07:05 50

Chlorodibromomethane <50 50 ug/L 07/30/11 07:05 50

1,2-Dibromo-3-Chloropropane <50 50 ug/L 07/30/11 07:05 50

Ethylene Dibromide <50 50 ug/L 07/30/11 07:05 50

Dibromomethane <50 50 ug/L 07/30/11 07:05 50

trans-1,4-Dichloro-2-butene <100 100 ug/L 07/30/11 07:05 50

Dichlorodifluoromethane <50 50 ug/L 07/30/11 07:05 50

1,1-Dichloroethane <50 50 ug/L 07/30/11 07:05 50

1,2-Dichloroethane <50 50 ug/L 07/30/11 07:05 50

cis-i,2-Dichloroethene <50 50 ug/L 07/30/11 07:05 50

trans-1,2-Dichloroethene <50 50 ug/L 07/30/11 07:05 50

U 1,1-Dichloroethene <50 50 ug/L 07/30/11 07:05 50

1,2-Dichloropropane <50 50 ug/L 07/30/11 07:05 50

cis-i,3-Dichloropropene <50 50 ug/L 07/30/11 07:05 50

Utrans-i ,3-Dichloropropene <50 50 ug/L 07/30/11 07:05 50

Ethylbenzene <50 50 ug/L 07/30/11 07:05 50

Ethyl methacrylate <50 50 ug/L 07/30/11 07:05 50

2-Hexanone <500 500 ug/L 07/30/11 07:05 50

lodomethane <250 250 ug/L 07/30/11 07:05 50

Isobutyl alcohol <2000 2000 ug/L 07/30/11 07:05 50

Methacrylonitrile <1000 1000 ug/L 07/30/11 07:05 50

Methylene Chloride <250 250 ug/L 07/30/11 07:05 50

Methyl methacrylate <50 50 ug/L 07/30/11 07:05 50

4-Methyl-2-pentanone (MIBK) <500 500 ug/L 07/30/11 07:05 50

Pentachloroethane <250 250 ug/L 07/30/il 07:05 50

B Propionhtrile <1000 1000 ug/L 07/30/11 07:05 50

Styrene <50 50 ug/L 07/30/il 07:05 50

1,i,i,2-Tetrachloroethane <50 50 ug/L 07/30/il 07:05 50

1,1,2,2-Tetrachloroethane <50 50 ug/L 07/30/11 07:05 50

Telrachloroetherre <50 50 ugJL 07/30/il 07:05 50

Toluene 2600 50 ugIL 07/30/il 07:05 50

i,1l-Trichloroethane <50 50 ug/L 07/30/il 07:05 50

l,1,2-Tnchloroethane <50 50 ug/L 07/30/11 0705 50

Trichloroethene <50 50 ug/L 07/30/11 07.05 50


Page 7 of 18

Surrogate SummaryClient: Ashland Inc. TestAmerica Job ID: 680-70758-2Project/Site: Hercules Hattiesburg APIX 7/26/11

Method: 8260B - Volatile Organic Compounds (GC/MS)Matrix: Water Prep Type: Total/NA

Percent Surrogate Recovery (Acceptance Limits)

BFB IJBFM TOL

Lab Sample ID Client Sample ID (70-130) (70-130) (70-130) — —

680-70758-8 AS1-l-MW21-072611 92 107 100

LCS 680-210543/4 Lab Control Sample 104 108 101

LCSD 680-210543/5 Lab Control Sample Dup 102 103 101

MB 680-210543/7 Method Blank 93 107 100

Surrogate Legend

BFB = 4-Bromofluorobenzene

DBFM = Dibromotluoromethane

TOL = Toluene-d8 (Surr)


Page 9 of 18

Analyte

Trichloroethene

Trichiorofluoromethane

1,2,3-Trichloropropane

Vinyl acetate

Vinyl chloride

Xylenes, Total

Surrogate

O4—Bromofluorobenzer,e

Dibmmofluoromefhane

To!uene-d8 (Surr)

% Recovery Qualifier Limits

93 7O13O

107

100

70- 130

70 130

Client Sample ID: Method BlankPrep Type: Total/NA

Prepared Analyzed

07/30/11 0043

07/30/11 00.43

07/30/11 00:43

Dii Fac

QC Sample ResultsClient: Ashland Inc.Project)Site: Hercules Hattiesburg APIX 7/26/11

I: 8260B - VoIatie Organic Compounds (GC/MS) (Continued)

Lab Sample ID: MB 680-210543(7Matrix: WaterAnalysis Batch: 210543

MB MB


Result

<1.0

<1.0

<1 0

Qualifier RL

1.0

1.0

1.0

<2.0 2.0

<1.0 1.0

<2.0 2.0

MB MB

MDL Unit D Prepared Analyzed Dii Facug/L 07/30/11 00:43 - 1

uglL 07/30/11 00:43 1

ug/L 07/30/11 00:43 1

ug/L 07/30/11 00:43 1

ugIL 07/30/11 0043 1

uglL 07/30/11 00:43 1

Client Sample ID: Lab Control SamplePrep Type: Total/NA

Lab Sample ID: LCS 680-21 054314Matrix: WaterAnalysis Batch: 210543

L Analyte

Acetone

Benzene

DDichlorobromomethane

Bromolorm

Bromoniethane

2-Butanone (MEK)

Carbon disulfide

Carbon tetrachloride

Chlorobenzene

Chloroethane

Chloroform

Chioromethane

Chlorodibromomethane

B. 1,2-Dibromo-3-Chloropropane

Ethylene Dibromide

Dibromomethane

Dichlorodifluoromethane

1,1-Dichloroethane

1 ,2-Dichloroethane

cis-1 ,2-Dichloroethene

n

trans-i ,2-Dichloroethene

1,1-Dictiloroethene

1 ,2-Dichloropropane

cis-1 ,3-Dichloroprupene

B trans-i ,3-Dichloropropene

Ethylbenzene

2-Hexanone

Methylene Chloride

4-Methyl-2-pentanone (MlBK)

Styrene

1.1,1 ,2-Tetrachloroethane

1,1 ,2,2-Tetrachloroethane

Spike LCS LCS % Rec.Added Result Qualifier Unit 0 % Rec limits

100 129 uglL 129 26-180

50.0 500 ug/L 100 70.130

50.0 46.3 ugIL 93 70 130

50.0 38.1 ug/L 76 70 130

50.0 25.4 ugIL 51 23- 165

100 111 ugIL 111 49_172

50.0 48.0 ug/L 96 54. 132

50.0 41.3 ug/L 83 70. 130

50.0 52.5 ugIL 105 70. 130

50.0 50.0 ugIL 100 56. 152

50.0 52.0 ug/L 104 70.130

50.0 50.7 ug!L 101 70_ 130

50.0 43.3 ug/L 87 70. 130

50.0 41.0 ug!L 82 70-130

50.0 49.6 ug/L 99 70 130

50.0 51.6 uglL 103 70130

50.0 49.9 ug/L. 100 44-146

50.0 49.8 ug/L 100 70 130

50.0 50.7 ug/L 101 70. 130

50.0 51.7 uglL 103 70.130

50.0 51.5 ug/L 103 70-130

50.0 52.0 ugIL 104 66-131

50.0 49.4 ug/L 99 70. 130

50.0 45.8 ug/L 92 70 130

50.0 43.9 ug/L 88 70. 130

50.0 51.1 ug/L 102 70130

100 114 ug/L 114 42_185

50.0 53.2 ugIL 106 67_ 130

100 94.4 ug/L 94 70130

50.0 54,3 ug/L 109 70_ 130

50.0 46.0 ugIL 92 70. 130

500 51 3 ug/L 103 70- 130


Page 11 of 18

QC Sample ResultsClient: Ashland Inc. TestAmerica Job ID: 680-70758-2

ProjectlSite: Hercules Hattiesburg APIX 7/26/11

QMethod:_8260B-VolatiIe_Organic Compounds (GC/MS) (Continued)

Lab Sample ID: LCSD 680-21054315 Client Sample ID: Lab Control Sample Dup

Matrix: Water Prep Type: TotalINA

Analysis Batch: 210543Spike LCSD LCSD % Rec. RPD

Analyte Added Result Qualifier Unit D % Rec Limits RPD Limit

4-Methyl-2-pentanone (MIBK) —— - — 100 98.5 ug/L 98 70.. 130 4 30

UStyrene 50.0 53.6 ugIL 107 70- 130 1 30

1,1,12-Tetrachloroethane 50.0 44.8 ugIL 90 70-130 3 30

1,1,2,2-Tetrachloroethane 50.0 509 ugIL 102 70. 130 1 30

Tetrachloroethene 50.0 51.6 uglL 103 70. 130 6 30

Toluene 50.0 49.1 ugIL 98 70- 130 1 30

1,1,1-Tnchloroethane 50.0 467 ugIL 93 70. 130 3 30

1,1,2-Trichloroethane 50.0 51 6 ugIL 103 70. 130 6 30

Trichloroethene 50.0 50.5 ugIL 101 70-130 5 30

fl Trichlorofluoromethane 50.0 48.3 ug/L 97 55-156 8 30

1,2,3-Trichloropropane 50.0 53.3 ugIL 107 70- 130 0 30

Vinyl acetate 100 94.3 ug/L 94 60.176 1 30

3Vinyl chloride 50.0 47.8 ugIL 96 67. 134 6 30

Xylenes, Total 150 153 ugIL 102 70-130 4 30

LCSD LCSD

Surrogate % Recovery Qualifier Limits

4-Bromofiuorobenzene 102 70. 130

Oibmmofluoromethane 103 70 130

Toluene-dB (Surr) 101 70- 130


Page 13 of 18

Lab ChronicleClient: Ashland Inc.Project/Site: Hercules Hattiesburg APIX 7/26/11

()CIient Sample ID: ASH-MW2I -072611

fT Date Collected: 07126111 15:03

{J Date Received: 07I27/11 09:20

Batch

Prep Type

______

Type

______ _____

Total/NA Analysis

Laboratory References:TAL SAV = TestAmerica Savannah, 5102 LaRoche Avenue, Savannah, GA 31404, TEL (912)354-7858

Lab Samp’e ID: 680-70758-8Matrix: Water

Batch Prepared

Number OrAnalyzed Analyst Lab

210543 07/30/11 07:05 AJMC TAL SAV



Batch Dii Initial

Method Run Factor Amount

82608 50 5 mL

Final

Amount

5 mL

Page 15 of 18

Login Sample Receipt Checklist

(lient: Ashland Inc. Job Number: 680-70758-2

- Login Number: 70758 List Source: TestAmerica Savannah

List Number: I

Creator: Barnett, Eddie T

Question Answer Comment

Radioactivity either was not measured or, if measured, is at or below N/A

O background

The cooler’s custody seal, if present, is intact. True

The cooler or samples do not appear to have been compromised or True

Otampered with.

Samples were received on ice. True 8 coolers rec’d on ice

Cooler Temperature is acceptable. True

Cooler Temperature is recorded. True Temp range 2.0 through 5.6 C

CCC is present. True

CCC is filled out in ink and legible. True

UCOC is filled out with all pertinent information. True

Is the Field Sampler’s name present on CCC? N/A

There are no discrepancies between the sample IDs on the containers and True

the CCC.

Samples are received within Holding Time. True

Sample containers have legible labels. True

Containers are not broken or leaking. False Samples -2, -5 and -6 had broken Liter Ambercontainers associated with them.

iSample collection date/times are provided. True

Appropriate sample containers are used. True

Sample bottles are completely filled. True

Sample Preservation Verified. True

There is sufficient vol. for all requested analyses, md. any requested True Insufficient volume received for MS/MSD.

MSIMSDs

fl VCA sample vials do not have headspace or bubble is <6mm (1/4’) in Truediameter.

Multiphasic samples are not present. True

USamples do not require splitting or compositing. True

Residual Chlorine Checked. N/A

Test.America Savannah

Page 17 of 18

CC

tEE

CEDc

CC

C

TestAmericaTHE LEADER IN ENVLRONMENTAL TESTING

ANALYTICAL REPORTTestfrnerica Laborato1es, Inc.TestAmerica Savannah5102 LaRoche AvenueSavannah, GA 31404Tel:(912)354-7858

For:Ashland Inc.Ashland Hercules Research Center500 Hercules Rd Bldg 8139Wilmington, Delaware 19808

Attn: Timothy Hassett

1’-Lfp-

Authorized for release by:08/25/2011 02:07:34 PM

Lidya GuliziaProject Manager [email protected]

cc: craig Derouen chris Waters

II

UsAmca .oD ID: 68O-7C18-i

Client Project/Site: Hercules Hattiesburg APIX 7/27/11

•............ LINKS

Review your projectresults through

TotalAccess

charlie Jordan

[Have a Question?

u4pJ

Results relate only to the items tested and the sample(s) as received by the laboratory.The test results in this report meet all 2003 NELAC and 2009 TNt requirements for accreditedparameters, exceptions are noted in this report. This report may not be reproduced exceptin full, and with written approval from the laboratory. For questions please contactthe Project Manager at the e-mail address or telephone number listed on this page.

This report has been electronically signed and authorized by the signatory. Electronic signatureis intended to be the legally binding equivalent of a traditionally handwritten signature.

Page 1 of 95

Case Narrative

[ Client: Ashland Inc. TestAmerica Job ID: 680-70818-1

( Project/Site: Hercules Hattiesburg APIX 7/27/11

Job ID: 680-708Th-I

___ __

Laboratory: TestAmerica Savannah

Narrative

Job Narrative

68 0-708 18-1

Receipt

All samples were received in good condition within temperature requirements.

UGCIMSVOA

Method(s) 8260B: A full list spike was utilized for this method. Due to the large number of spiked analytes, there is a high probability that

one or more analytes will recover outside acceptance limits. The laboratory’s SOP allows for 4 analytes to recover outside criteria for this

method when a full list spike is utilized. The LCS associated with batch 210665 had 3 analytes outside control limits; therefore,

re-extraction/re-analysis was not performed. These results have been reported and qualified.

Method(s) 826DB: A full list spike was utilized for this method. Due to the large number of spiked analytes, there is a high probability that


method when a full list spike is utilized. The LCSD associated with batch 210908 had 2 analytes outside control limits; therefore,


Method(s) 826DB: The matrix spike! matrix spike duplicate (MS/MSD) recoveries for batch 210908 were outside control limits. The

associated laboratory control sample (LCS) recovery met acceptance criteria.

Method(s) 8260B: The matrix spike! matrix spike duplicate (MS!MSD) precision for batch 210908 was outside control limits. The

associated laboratory control sample! laboratory control sample duplicate (LCS!LCSD) precision met acceptance criteria.

Method(s) 826DB: The following compound was outside control limits in the continuing calibration verification (CCV) associated with batch

210624: iodomethane. This compound is not classified as a Calibration Check Compound (CCC) in the reference method, and the

laboratory defaults to in-house and/or project-specific criteria for evaluation. There is insufficient holding time remaining for re-analysis;

therefore, the data have been reported. The associated samples were non-detect for the affected analyte.

No other analytical or quality issues were noted.

GC/MS Semi VOA

Method(s) 8270C: The laboratory control sample (LCS) for batch 210688 exceeded control limits for the following analyte(s): Famphur.

Famphur has been identified as a poor performing analyte when analyzed using this method; therefore, re-extraction/re-analysis was not

performed.

Method(s) 8270C: A full list spike was utilized for this method. Due to the large number of spiked analytes, there is a high probability that


method when a full list spike is utilized. The LCS associated with batch 210688 had 3 analytes outside control limits; therefore,


Method(s) 827DC: The matrix spike/matrix spike duplicate (MS/MSD) recoveries and precision for batch 210688 were outside control

limits. The associated laboratory control sample (LCS) recovery met acceptance criteria.


GCSemiVOA

Method(s) 8151A: This method incorporates the use of second column confirmation. Corrective action for unacceptable percent recovery

is not taken for surrogate or spike compounds unless the results from both columns are outside criteria. Any results which fall outside

criteria are qualified and reported.


MetalsNo analytical or quality issues were noted.

TestAmerica SavannahPage 3 of 95

Sample SummaryClient: Ashland Inc.Project/Site: Hercules Hattiesburg APIX 7/27/11


Lab Sample ID Client Sample ID

680-70818-1 ASH-MW24-07271 1

O680-70818-2 ASH-MW22-07271 1

680-70818-3 ASH-M Wi 8-07271 1

680-70818-4 ASH-MW2O-07271 1

680-70818-5 ASH-M Wi 2-07271 1

U680-70818-6 ASH-MWO2-072711

680-70818-7 ASH-MWO4-07271 1

680-70818-8 ASH-MW1 1-072711

680-70818-9 ASH-M Wi 0-07271 1

El 680-70818-10 ASH-MWO3-072711

680-70818-11 ASH-DUP-07271 1

680-70818-12 Trip Blank 063011

Matrix

Water

Water

Water

Water

Water

Water

Water

Water

Water

Water

Water

Water

Collected Received

07127/11 08:20 07/28/11 14:09

07/27/11 08:55 07/28/11 14:09

07/27/11 09.23 07/28/11 14:09

07/27/11 10:00 07/28/11 14:09

07/27/11 10:14 07/28/11 14:09

07/27/11 12:10 07/28/11 14:09

07/27/11 12:55 07/28/11 14:09

07/27/11 14:55 07/28/11 14:09

07/27/11 14:40 07/28/11 14:09

07/27/11 13:40 07/28/11 14:09

07/27/11 00:00 07/28/11 14:09

07/27/11 0000 07/28/11 14:09

Page 5 of 95TestAmerica Savannah

Definitions/GlossaryClient: Ashland Inc.Project/Site: Hercules Hattiesburg APIX 7/27/11

Qualifier Description

LCS or LCSD exceeds the control limits

The %RPD between the primary and confirmation column/detector is >40%. The lower value has been reported.

RPD of the MS and MSD exceeds the control limits

Surrogate is outside control limits

TestAmerica Job ID: 680-7081 8-1

LIGlossary

Abbreviation

%R

DL, RA, RE, IN

EDL

EPA

MDL

ML

ND

PQL

RL

b RPD

TEF

TEQ

These commonly used abbreviations may or may not be present In this report.

Listed under the “D’ column to designate that the result is reported on a dry weight basis

Percent Recovery

Indicates a Dilution, Reanalysis, Re-extraction, or additional Initial metals/anion analysis of the sample

Estimated Detection Limit (Dioxin)

United States Environmental Protection Agency

Method Detection Limit

Minimum Level (Dioxin)

Not detected at the reporting limit (or method detection limit if shown)

Practical Quantitation Limit

Reporting Limit

Relative Percent Difference, a measure of the relative difference between two points

Toxicity Equivalent Factor (Dioxin)

Toxicity Equivalent Quotient (Dioxin)

Qualifiers

_____

GC/MS VOA

Qualifier Qualifier Description* LCS or LCSD exceeds the control limits

F MS or MSD exceeds the control limits

F RPD of the MS and MSD exceeds the control limits

GCIMS Semi VOA

Qualifier Qualifier Description* LCS or LCSD exceeds the control limits

F MS or MSD exceeds the control limits

F RPD of the MS and MSD exceeds the control limits

E Result exceeded calibration range.

GC Semi VOA

Qualifier

p

F

x

Page 7of95TestAmerica Savannah

Detection Summary

El

El

El

El

U

El

D

El

U

El

El

Client: Ashland Inc.Project/Site: Hercules Hattiesburg APIX 7/27/11

Client Sample ID: ASH-DUP-07271

No Detections

1 Lab Sample ID: 680-70818-11

Client Sample ID: Trip Blank_063011

r No Detections


______

Lab Sample ID: 680-70818-12


Client Sample ResultsClient: Ashland Inc. TestAmerica Job ID: 680-70818-1

Project/Site: Hercules Hattiesburg APIX 7/27/11

Client Sample ID: ASH-MW24-072711 Lab Sample ID: 680-7081 8-1

Date Collected: 07127/11 08:20 Matrix: Water

Date Received: 07126111 14:09

Method: 8260B - Volatile Organic Compounds (GCIMS) (Continued)Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dii Fac

Trichlorofluoromethane <1 0 1.0 ug/L 07/30/11 15:23 1

123-Trichloropropane <1.0 1.0 ug/L 07/30/11 15:23 1

Vinyl acetate <2.0 2.0 ug/L 07/30/11 15:23 1

Vinyl chloride <1.0 1 0 ug/L 07/30/11 15:23 1

Xylenes, Total <2.0 2.0 ug/L 07/30/11 15:23 1

Surrogate % Recovery Qualifier Limits__- Prepared Analyzed DII Fac

4-Bromofluorobenzene 92 70- 130 07/30/11 15:23 1

Dibromofluoromethane 106 70- 130 07/30/11 15:23 1

Toluene-dB (SurF) 101 70. 130 07/30/11 15:23 1




Client Sample ID: ASH-MW22-072711 Lab Sample ID: 680-70818-2

Date Collected: 07/27/11 08:55 Matrix: Water


Method: 8260B - Volatile Organic Compounds (GCIMS) (Continued)Analyte Result Qualifier RL MDL unit o Prepared Analyzed Dli Fac

UTrichlorofluoromethane <1.0 1.0 ug/L 07/30/11 16:37 1

123-Tiichloropropane <1.0 1.0 ug/L 07/30/11 16:37 1

Vinyl acetate <2.0 2.0 ug/L 07/30/11 1637 1

Vinyl chloride <1.0 1.0 uglL 07/30/11 16:37 1

Xylenes, Total <20 2.0 ugIL 07/30/11 16:37 1

Surrogate % Recovery Qualifier Limits Prepared Analyzed Dii Fac

I 4-Bromofluombenzene 104 70. 130 — 07/30/11 16:37

Dibromofluoromefhane 105 70 130 07/30/11 16:37 1

102 70. 130 07/30/11 16.37 1

TestAmerica SavannahPage 13of95



Client Sample ID: ASH-MWI8-072711 Lab Sample ID: 680-70818-3


Date Received: 07/28/11 14:09

Method: 826DB - Volatile Organic Compounds (GCIMS) (Continued)Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dii Fac

Trichlorofluoromethane

<1.0 1.0 uglL 07I30/11 15:53 1

123-Trichloropropane <1.0 1.0 ugIL 07130111 15:53 1

Vinyl acetate <2.0 2.0 uglL 07/30/11 15:53 1

I Vinylchioride <1.0 1.0 ugIL 07/30/11 15:53 1


Surrogate % Recovery Qualifier Limits Prepared Analyzed Oil Fac

4-Bromofluorobenzene 96 70 130 07/30/11 15:53

Dibromofluoromethane 106 70 130 07/30111 15;53

Toluene-d8 (Surr) 100 70- 130 07/30/11 15:53 1

TestAnierica SavannahPage 15of95



Client Sample ID: ASH-MW2O-072711 Lab Sample ID: 680-70818-4

Date Collected: 07127111 10:00 Matrix: Water


Method: 826DB - Volatile Organic Compounds (GCIMS) (Continued)Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dii Fac

Thchlorofluoromethane <1.0 1.0 ug/L 07/30/11 20:46 1

12,3-Trichloropropane <1.0 1.0 ug/L 07/30/11 20:48 1

Vinyl acetale <2.0 2 0 ug/L 07/30/11 20:48 1

Vinyl chloride <1.0 1.0 ugiL 07/30/11 20:48 1

Xylenes, Total <2.0 20 ugIL 07/30/11 20:48 1

Surrogate % Recovery Qualifier Limits Prepared Analyzed Dii FacI

4-Bmmofluorabenzerie 94 70- 130 07/30/11 20:48 1

fl Dibromofluoromefhane 105 70- 130 07/30111 20:48 1

LT0t-d8 (Surr) 102 70- 130 07/30/11 20:48 1


Client Sample ResultsClient: Ashland Inc.



Client Sample ID: ASH-MWI 2-072711

Date Collected: 07/27/11 10:14


Lab Sample ID: 680-70818-5Matrix: Water

Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)

Analyte Result Qualifier RL MDL Unit D Prepared Analyzed DII Fac

Trichlorofluoromethane <1.0 1.0 ug!L 07/30111 16:23 1

1,2,3-Thchloropropane <1.0 1.0 ugiL 07/30/11 16:23 1

Vinyl acetate <2.0 2,0 ug/L 07/30/11 16:23 1

Vinyl chloride <1.0 1.0 ugIL 07/30/11 16:23 1



4-Bromofluorobenzene 99 70- 130 07/30/11 16:23 1[] Dibromofluoromethane 107 70- 130 07/30/11 16.23 1

L Toluene-d8 (Surr) 99 70- 130 07/30/11 16:23 1

UrMethod: 8270C - Semivolatile Organic Compounds (GC/MS)

, Anatyte Result Qualifier RL MDL Unit 0 Prepared Analyzed DII Fac

Acenaphthene <12 12 ug/L 08)02/11 15:02 08/05/11 17:00 1

Acenaphthylene

-<12 12 ug/L 08/02/11 1 5:02 08/05/11 17:00 1

Acetophenone <12 12 ugIL 08/02(11 15:02 08/05/11 17:00 1

2-Acetylaminofluorene <12 12 ug/L 08/02/11 15:02 08/05/11 17:00 1

alphaalpha-Dimethyl phenethylamine <2500 2500 ugIL 08/02/11 15:02 08(05/11 17:00 1

4-Aminobiphenyl <12 12 ugIL 08/02/11 15:02 08/05/11 17:00 1

D Aniline <25 25 ug/L 08/02/11 15:02 08/05/11 17:00 1

. Anthracene <12 12 ug/L 08/02/11 15:02 08/05/11 17:00 1

Aramite, Total <12 12 ug/L 08/02)11 15:02 08/05(11 17:00 1

Benzo[alanthracene <12 12 ug& 08/02111 15:02 08(05/11 17:00 1

Benzo[ajpyrene <12 12 ug/L 08/02)11 15:02 08(05/11 17:00 1

Benzo[blfluoranthene <12 12 ugIL 08/02)11 15:02 08/05/11 17:00 1

Benzo[g,h,ijperylene <12 12 ugIL 08(02/11 15:02 08/05/11 17:00 1

Benzo[kJfluoranthene <12 12 ug/L 08/02/11 15:02 08/05/11 17:00 1

Benzyl alcohol <12 12 ug/L 08/02/11 15:02 08/05/11 17:00 1

1,1-Biphenyl <12 12 ug(L 08)02/11 15:02 08/05/11 17:00 1

Bis(2-chloroethoxy)methane <12 12 ug/L 08/02/11 15:02 08/05/11 17:00 1

UBis(2-chloroethyl)ether <12 12 ugIL 08/02/11 15:02 08/05/11 17:00 1

. bis(chloroisopropyl) ether <12 12 ug/L 08/02/11 15:02 08(05(11 17:00 1

Bis(2-ethylhexyl) phthalate <12 12 ug/L 08/02/11 15:02 08(05(11 17:00 1

4-Bromophenyl phenyl ether <12 12 ugIL 08/02/11 15:02 08/05111 17:00 1

Butyl benzyl phthalate <12 12 ug/L 08/02/11 15:02 08/05/11 17:00 1

4-chloroaniline <25 25 ug/L 08/02/11 15:02 08/05(11 17:00 1

I 4-Chloro-3-methylphenol <12 12 ugIL 08/02/11 15:02 08/05/11 17:00 1

U2-Chloronaphthalene <12 12 ug/L 08/02/11 15:02 08/05/11 17:00 1

2-Chlorophenol <12 12 ug/L 08/02/11 15:02 08/05/11 17:00 1

4-chlorophenyl phenyl ether <12 12 ug/L 08(02/11 15:02 08/05/11 17:00 1

Chrysene <12 12 ugIL 08/02/11 15:02 08/05/11 17:00 1

[1 Diallate <12 12 ugIL 08/02/11 15:02 08(05(11 17:00 1

[J Dibenz(a,h)anthracene <12 12 ugIL 08/02)11 15:02 08/05/11 17:00 1

Dibenzofuran <12 12 ugIL 08/02/11 15:02 08/05(11 17:00 1

J 1,2-Dichlorobenzene <12 12 ug/L 08/02/11 15:02 08/05/11 17:00 1

U 1,3-Dichlorobenzene <12 12 ugIL 08/02)11 15:02 08/05/11 17:00 1

1,4-Dichlorobenzene <12 12 ug/L 08/02/11 15:02 08/05/11 17:00 1

3,3-Dichlorobenzidine <75 75 ug/L 08(02/11 15:02 08105/11 17:00 1

2,4-Dichlorophenol <12 12 ugIL 08/02)11 15:02 08/05/11 17:00 1

r’ 2,6-Dichlorophenol <12 12 ugIL 08/02)11 15:02 08/05/11 17:00 1

Page 19of95TestAmerica Savannah






Method: 8270C - Semivolatile Organic Compounds (GCIMS) (Continued)

Analyte Result Qualifier RL MDL Unit 0 Prepared — Analyzed Dii Fac

N-Nitrosodimethylamine <12 12 ug/L 08/02/11 1502 08/05/11 17:00 1

N-Nitrosodi-n-butylamine <12 12 ug/L 08/02/11 15:02 08/05/11 17:00 1

N-Nitrosodi-n-propylamine <12 12 ugIL 08/02111 15:02 08/05/11 17:00 1

I N-Nitrosodiphenylamine <12 12 ugIL 08/02/11 15:02 08/05/11 17:00 1

N-Nitrosomethylethylamine <12 12 ug!L 08/02/11 15:02 08/05/11 17:00 1

N-Nitrosomorpholine <12 12 ug/L 08/02/11 15:02 08/05/11 17:00 1

N-Nitroaopiperidine <12 12 ug/L 08/02/11 15:02 08/05/11 17:00 1

N-Nitrosopyrrohdine <12 12 ug/L 08/02/1115:02 08/05/11 17:00 1

o,oo-Triethylphosphorothioate <12 12 ugIL 08/0211115:02 08/05/11 17:00 1

p-Dimethylaminoazobenzene <12 12 ug/L 08/021111502 08/05/11 17:00 1

Pentachlorobenzene <12 12 ugIL 08/0211115:02 08/05/11 1700 1

Pentachloronitrobenzene <12 12 ug/L 08/02/11 15:02 08/05/11 17:00 1

Pentachlorophenol <62 62 ug/L 08/02/11 15:02 08/05/11 17:00 1

Phenacetin <12 12 ug/L 08/0211115:02 08/05/11 17:00 1

Phenanthrene -<12 12 ug/L 08/02/11 15:02 08/05/11 17:00 1

Phenol <12 12 ug/L 08/02/11 15:02 08/05/11 17:00 1

Phorate <12 12 ug/L 08102/11 15:02 08/05/11 17:00 1

2-Picoline <12 12 ug/L 08/02/11 15:02 08/05/11 17:00 1

p-Phenylenediamine <2500 2500 ug/L 08/02/11 15:02 08/05/11 17:00 1

Pronamide <12 12 ug/L 08/02/11 15:02 08/05/11 17:00 1

Pyrene <12 12 ug/L 08/0211115:02 08/05/11 17:00 1

Pyridine <62 62 ugIL 08/02/11 15:02 08105/11 17:00 1

Safrote, Total <12 12 ug/L 08/02111 15:02 08/05/11 17:00 1

Sulfotepp <12 12 ug/L 08/02/11 15:02 08/05/11 17:00 1

1,2,45-Tetrachlorobenzene <12 12 UgIL 08/0211115:02 08105/11 17:00 1

2.3,4,6-Tetrachlorophenol <12 12 ugIL 08/0211115:02 08/05/11 17:00 1

Thionazin <12 12 ug/L 08/02/11 15:02 08/05/11 17:00 1

2-Toluidine <12 12 ug/L 08/02/11 15:02 08/05/11 17:00 1

1,2,4-Trichlorobenzene <12 12 ug!L 08/0211115:02 08/05111 17:00 1

2.4,5-Trichlorophenol <12 12 ug/L 08/02/11 15:02 08/05/11 17:00 1

2,4,6-Trichlorophenol <12 12 ugIL 08/0211115:02 08/05/11 17:00 1

1,3,5-Trinitrobenzene <12 12 ug/L 08/02/1115:02 08/05/11 17:00 1

Surrogate % Recovery Qualifier Limits Prepared Analyzed DII Fac

2-Fluorobiphenyl 74 38 130 08/02/11 15:02 08105/11 17:00 1

2-Fluorophenol 57 25- 130 08102111 15:02 08105/1117:00 1

Nitrobenzene-d5 71 39 130 08/02/11 15:02 08105/11 17:00 1

Phenol-d5 46 25- 130 08102/11 15:02 08105/11 17:00 1

Terphenyl-d14 90 10- 143 08102/11 15:02 08105/11 17:00 1

L2,4,6-Tmm0phb01 91 31- 141 08/02111 15:02 08105111 17:00 1

U rMethod: 8081 A_8082 - Organochiorine Pesticides & PCBs (GC)Analyte Result Qualifier RL MDL Unit 0 Prepared Analyzed Dli Fac

Aldrin <0050 0.050 ug/L 07/29111 14:35 08/08(11 06:07 1

alpha-BHc <0.050 0.050 ug/L 07/29/11 14:35 08/08/11 06:07 1

L beta-BHC <0.050 0.050 ug/L 07/29/11 14:35 08/08(11 06:07 1

cnlordane (technical) <0.50 0.50 ug/L 07/29/11 14:35 08/08111 06:07 1

Chlorobenzilate <0.50 0.50 ugIL 07/29(11 14:35 08/08/11 06:07 1

4,4-ODD <0.099 0.099 ug/L 07/29/11 14:35 08/08/11 06:07 1

44-DDE <0.099 0.099 ug/L 07(29/11 14:35 08(08/11 06:07 1

Page 21 of95TestAmerica Savannah





Date Received: 07/28111 14:09

Internal Standard % Recoveiy Qualifier - Limits Prepared Analyzed Dii Fac

L13C-2,3,7,8-TCDD 85 40-135 07/29/11 09:00 07/30/11 0144 0.98

13C-1,2,3,7,8-Pe000 85 40-135 07/29/11 09.00 07/30/11 01:44 0.98

130-1,2,3,6,7,8-HxCDD 85 40- 135 07/29/11 09:00 07/30/11 01:44 0.98

13C-237,8-TCDF 89 40- 135 07/29/11 09:00 07/30/1101:44 0.98

U 13C-123,7,8-PeCDF 84 40- 135 07/29/11 09:00 07/30/11 01:44 0.98

13C-123,478-HxCDF 78 40- 135 07/29/1109:00 07/30/1101:44 0.98

L.

rMethod: 6020 - Metals (ICPIMS)

I Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dii Fec

Antimony <5.0 5.0 ugIL 08/01/11 08:48 08/07111 00:12 1

Arsenic <2.5 2.5 ugIL 08/01/11 08:48 08/07/11 00:12 1

Barium 120 5.0 ug/L 08/01/11 08:48 08/07/11 00:12 1

Beryllium <0.50 0.50 ug/L 08/01/11 08:48 08/07/11 00:12 1

cadmium <0.50 0.50 ug/L 08/01111 08:48 08/07/11 00:12 1

Chromium --<5.0 5.0 ugIL 08101/11 08:48 08/07/11 00:12 1

Cobalt 34 0.50 ug/L 08/01/11 08:48 08/07/11 00:12 1

Copper <5.0 5.0 ug/L 08/01/11 08:48 08/07/11 00:12 1

I Lead <1.5 1.5 ugIL 08/01/11 08:48 08/07/11 00:12 1

Nickel 9.7 5.0 ug/L 08/01/11 08:48 08/07/11 00:12 1

Selenium <2.5 2.5 ug/L 08/01/11 08:48 08/07/11 00:12 1

Silver <1.0 1.0 ugiL 08/01/11 08:48 08/07/11 00:12 1

Thallium <1.0 1.0 ug/L 08/01/11 08:48 08/07/11 00:12 1

Tin <5.0 5.0 ug/L 08/01/11 08:48 08/07/11 00:12 1

Vanadium <10 10 ug/L 08/01/11 08:48 08/07/11 00:12 1

LZinc 34 20 ug/L 08/01/11 08:48 08/07/11 00:12 1

rMethod: 7470A - Mercury (CVAA)Analyte Result Qualifier — RL — MDL Unit D Prepared Analyzed Dii Fac

<0.20 0.20 ug/L 08/03/11 17:01 08/04/11 18:43 1

r

UGeneral ChemistryAnalyte Result Qualifier RL MDL Unit 0 Prepared Analyzed Oil Fec

Cyanide Total <0.010 0.010 mg/L 08/01/11 07:51 08/02I11 06:56 1

Analyte Result Qualifier RL RL Unit 0 Prepared Analyzed Oil Fac

Lsu1 <1.0 1.0 mg/L 07/29/11 13:06 1


Client Sample ResultsClient; Ashland Inc. TestAmerica Job ID: 680-70818-1


Client Sample ID: ASH-MWO2-072711 Lab Sample ID: 680-70818-6



D

Method: 8260B - VolatUe Organic Compounds (GCIMS) (Continued)

Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dii Fac

Trichlorofluoromethane <1.0 1.0 ug/L 07/30/11 16:52 i

1,2,3-Trichloropropane <1.0 1.0 ug/L 07/30111 16:52 1

Vinyl acetate <2.0 20 ugIL 07/30/11 16:52 1

Vinyl chlonde <1.0 1.0 ug/L 07/30/11 16:52 1

Xylenes, Total <20 2.0 ug/L 07/30/11 16:52 1

Surrogate % Recove,y Qualifier Limits Prepared Analyzed Oil Fac

4-Bromofluorobenzene 95 70 130 07/30/11 16:52 1

Dibromofluoromethane 107 70- 130 07/30/11 16:52 1

-,

. Toluene-dd(Surr) 98 70- 130 07/30/11 16:52 1

UMethod: 8270C - Semivolatile Organic Compounds (GCIMS)

Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dii Fac

.

Acenaphthene <9.9 9.9 ugIL 08/02(11 15.02 08105(11 16:01 1

Acenaphthylene <99-- 9.9 ug/L 08/02111 15:02 08/05/11 16:01

Acetophenorie <9.9 9.9 ug/L 08/02/11 15:02 08(05/11 16:01 1

2-Acetylaminofluorene <9.9 9.9 ugIL 08/02/11 15:02 08/05/11 16:01 1

alpha,alpha-Dimethyl phenethylamine <2000 2000 ug/L 08/02/11 15:02 08/05/11 16:01 1

4-Aminobiphenyt <9.9 9.9 ugIL 08/02/11 15:02 08/05/11 16:01 1

Aniline <20 20 ug!L 08/02111 15:02 08/05/11 16:01 1

Anthracene <9.9 9.9 ug/L 08102/11 15:02 08/05(11 16:01 1

Aramite, Total <9.9 9.9 ugIL 08/02/11 15:02 08/05/11 16:01 1

Benzofa]anthracene <9.9 9.9 ug/L 08/02/11 15:02 08/05/11 16.01 1

Benzo[apyrerie <9.9 9.9 ug/L 08/02/11 15:02 08/05/11 16:01 1

I Benzo[b]fluoranthene <9.9 9.9 ug/L 08/02111 15:02 08/05/11 16:01 1

Benzo[g,h,ilperylene <9.9 9.9 ug/L 08/02/11 15:02 08(05(11 16:01 1

I Benzo[klfluoranthene <9.9 9.9 ug/L 08/02/11 15:02 08/05/11 16:01 1

., Benzyl alcohol <9.9 9.9 ug/L 08/02/11 15:02 08/05/11 16:01 1

1,1-Biphenyl <9.9 9.9 ug!L 08/02/11 15:02 08/05/11 16:01 1

. Bis(2-chtoroethoxy)methane <9.9 9.9 ug/L 08102111 15:02 08/05/11 16:01 1

, Bis(2-chloroethyl)ether <9.9 9.9 ug/L 08/02/11 15:02 08/05/11 16:01 1

- bis(chloroisopropyl) ether <9.9 9.9 ug/L 08/02/11 15:02 08/05/11 16:01 1

Bis(2-ethylhexyl) phthalate <9.9 9.9 ug/L 08/02/11 15:02 08/05/11 16:01 1

4-Bromophenyl phenyl ether <9.9 9.9 ugIL 08/02111 15:02 08/05/11 16:01 1

Butyl benzyi phthalate <9.9 9.9 ug/L 08/02/11 15:02 08/05/11 16:01 1

4-Chloroaniline <20 20 ug/L 08/02/11 15:02 08/05/11 16:01 1

4-Chloro-3-methylphenol <9.9 9.9 ug/L 08/02111 15:02 08/05/11 16:01 1

2-Chloronaphthalene <9.9 9.9 ug/L 08/02/11 15:02 08/05/11 16:01 1

2-Chlorophenol <9.9 9.9 ug/L 08/02111 15:02 08/05/11 16:01 1

‘ 4-Chlorophenyl phenyt ether <9.9 9.9 ugIL 08/02/11 15:02 08/05/11 16:01 1

Chrysene <9.9 9.9 ug/L 08/02/11 15:02 08/05/11 16:01 1

Fl Diallate <9.9 9.9 ugIL 08/02/11 15:02 08/05/11 16:01 1

[J Dibenz(a,h)anthracene <9.9 9.9 ug/L 08/02/11 15:02 08/05/11 16:01 1

Dibenzofuran <9.9 9.9 ug/L 08/02/11 15:02 08/05/11 16:01 1

U1,2-Dicttlorobenzene <9.9 9.9 ugIL 08/02/11 15:02 08/05/11 16:01 1

1,3-Dichlorobenzene <9.9 9.9 ug/L 08/02/11 15:02 08/05/11 16:01 1

1,4-Dichiorobenzene <9.9 9.9 ug/L 08/02/11 15:02 08/05/11 16:01 1

( ‘“)3,3’-Dictilorobenzidine <59 59 ug/L 08/02111 15:02 08/05/11 16-01 1

(___/24-Dichlorophenol <9.9 9.9 ug/L 08/02111 15:02 08(05/11 16:01 1

2,6-Dictilorophenol <9.9 9.9 ug/L 08/02111 15:02 08/05/11 16:01 1







Method: 8270C - Semivolatile Organic Compounds (GC/MS) (Continued)

Analyte Result Qualifier - RL MDL Unit D — Prepared Analyzed Dilfac

fl N-Nitrosodimethylamine <9.9 9.9 Ug/L 08/02111 15:02 08)05/11 16:01 1

[j N-Nitrosodi-n-butylamine <9.9 9.9 ug/L 08/02/11 15:02 08/05/11 16:01 1

N-Nitrosodi-n-propylamine <9.9 9.9 ug/L 08/02/11 15:02 08/05/11 16:01 1

N-Nitrosodiphenylamine <9.9 99 ugIL 08/02/11 15:02 08/05/11 16:01 1

N-Nitrosomethylethylamine <9.9 9.9 ug/L 08/02/11 15:02 08/05/11 16:01 1

N-Nitrosomorpholine <9.9 9.9 ug/L 08/02/11 15:02 08/05/11 16:01 1

N-Nitrosopiperidine <9.9 9.9 ug/L 08/02/11 15:02 08/05/11 16:01 1

N-Nitrosopyrrolidine <99 9.9 ug/L 08/02)11 15:02 08)05/11 16:01 1

I o,o,o-Triethylphosphorothioate <9.9 9.9 ug/L 08/02/1115:02 08(05(11 16:01 1

p-Dimethylamino azobenzene <9.9 9.9 ug)L 08/02/11 15:02 08/05/11 16:01 1

Pentachlorobenzene <9.9 9.9 ug)L 08/02/11 15:02 08/05/11 16:01 1

Q Pentachloronitrobenzene <9.9 9.9 ug)L 08)02/11 15:02 08/05/11 16:01 1

Pentachlorophenol <49 49 ug/L 08/02/11 15:02 08/05/11 16:01 1

Phenacetin <9.9 9.9 ug/L 08/02/11 15:02 08/05/11 16:01 1

Phenanthrene <9.9 9.9 ug/L 08/0211115:02 08/05/11 16:01 1

I Phenol <9.9 9.9 ug/L 08/02/1115:02 08/05/11 16:01 1

Phorate <9.9 9.9 ug/L 08/02111 15:02 08/05/11 16:01 1

2-Picoline <9.9 9.9 ug/L 08/02/1115:02 08/05/11 16:01 1

Dp-Phenylenediamine <2000 2000 ug/L 08/02/11 15:02 08/05/11 16:01 1

Pronamide <9.9 9.9 ug/L 08(02/1115:02 08/05(11 16:01 1

Pyrene <9.9 9.9 ug/L 08/02/11 15:02 08/05/11 16:01 1

Pyridine <49 49 ugIL 08102/1115:02 08/05/11 16:01 1

Safrole Total <9.9 9.9 ug!L 08/02/11 15:02 08)05/11 16:01 1

Sulfotepp <9.9 9.9 ug/L 08/02/1115:02 08/05/11 16:01 1

1,2,4,5-Tetrachlorobenzene <9.9 9.9 ug/L 08102/1115:02 08/05/11 16:01 1

2,3,4,6-Tetrachlorophenol <9.9 9.9 ug/L 08/0211115:02 08/05/11 16:01 1

Thionazin <9.9 9.9 ugIL 08/02/11 15:02 08/05111 16.01 1

2-Toluidine <9.9 9.9 ug/L 08/02/1115:02 08)05(11 16:01 1

1,2,4-Trichlorobenzene <9.9 9.9 ug/L 08(02/1115:02 08/05/11 16:01 1

2,4.5-Tnchlorophenol <9.9 9.9 Ug/L 08/0211115:02 08/05111 16:01 1

2,4,6-Trichlorophenol <9.9 9.9 ug/L 08/02/1115:02 08/05/11 16:01 1

1,3,5-Trinitrobenzene <9.9 9.9 ugIL 08(02/1115:02 08/05/11 16:01 1

Surrogate % Recove,y Qualifier Limits - Prepared Analyzed DII Fec

2-Fluorobiphenyl 63 38- 130 08/02/11 15:02 08/05(1116:01 1

2-Fluorophenol 58 25-130 08/02/11 15:02 08/05(1116:01 1

Nitrobenzene-d5 65 39- 130 08/02/11 15:02 08/05(1116:01 1

U Phenol-d5 54 25- 130 08/02/11 15:02 08/05/11 16:01 1

Teipheny(-d14 80 /0- 143 08/02/1115:02 08/05(1116:01 1

[ 2,4,6-Thbromophenol 80 31- 141 08/02/1115:02 08/05/11 16:01 1

Method: 8081A_8082 - Organochlorine Pesticides & PCBs (GC)

[j I Analyte Result Qualifier RL MDL Unit D Prepared Analyzed DII Fac

AIdrin <0,050 0.050 ug/L 07/29111 14:35 08/08/11 06:26 1

alpha-BI-IC <0.050 0.050 ugIL 07129/11 14:35 08/08/11 06:26 1

beta-el-ic <0.050 0.050 ugIL 07/29/11 14:35 08/08111 06:26 1

Chlordane (technical) <0.50 0.50 ug/L 07/29/11 14:35 08/Ô8,’ll 06:26 1

Chlorobenzilate <050 0.50 ug(L 07/29/11 14:35 08/08/11 06:26 1

L)44-DOD <0.099 0.099 ugIL 07/29/11 14:35 08108/11 06:26 1

4.4-DDE <0.099 0.099 uglL 07/29111 14:35 08)08/11 06:26 1


Client Sample ResultsClient: Ashland Inc TestAmerica Job ID: 680-70818-1




Date Received: 07128/11 14:09

Internal Standard % Recove,y Qualifier Limits Prepared Analyzed Dii Fac

13C-237,8-TCOD 87 40- 135 07/29/11 09:00 07/30/11 02:29 1.01

13C-1Z3,7,8-PeCDD 89 40. 135 07/29/11 09:00 07/30/11 02:29 107

13C-1,2,36,78-HxCDD 85 40- 135 07/29/11 09:00 07/30/11 02:29 1.01

13C-23,7,8-TCDF 90 40-135 07/29/11 09:00 07/30/110229 1.01

13C-1,2.3,78-PeCDF 88 40- 135 07/29/11 09:00 07/30/11 02:29 1.01

13C-12,3,47,8-HxCDF 75 40 135 07/29/11 09:00 07/30/11 02.29 1.01

I Method: 6020 - Metals (ICPIMS)Analyte Result Qualifier RL MDL unit 0 Prepared Analyzed Oil Fac

Antimony —— <5.0 5.0 ug/L — 08103111 09:07 08/07/11 0638 1

Arsenic 2.9 2.5 ug/L 08/03111 09:07 08/07/11 06.38 1

Barium 76 5.0 ug/L 08/03/11 09:07 08/07/11 06:38 1

Beryllium <0.50 0.50 ug/L 08/03/11 09:07 08/07/11 06:38 1

Cadmium <0.50 0.50 ug/L 08/03/11 09:07 08/07/11 06.38 1

Chromium <5.0 50 ugJL 08/03/11 09:07 08/07/11 06:38 1

Cobalt 4.2 050 ug/L 08/03/11 09:07 08/07/11 06:38 1

Copper <5.0 5.0 ug/L 08/03/11 09:07 08/07/11 06:38 1

Lead <1.5 1.5 ug/L 08/03/11 09:07 08/07/11 06:38 1

Nickel <5.0 5.0 ug/L 08/03/11 09:07 08/07/11 06:38 1

Selenium <2.5 2.5 ug/L 08/03/11 09:07 08/07/11 06:38 1

) Silver <1.0 1.0 ug/L 08/03/11 09:07 08/07/11 06:38 1

Thallium <1.0 1.0 ug/L 08/03/11 09:07 08/07/11 06:38 1

Tin <5.0 5.0 ugIL 06/03/11 09:07 08/07/11 06:38 1

Vanadium <10 10 ug/L 08/03/11 09:07 08/07/11 06:38 1

Lz <20 20 ug/L 08/03/11 09:07 08/07/11 06:38 1

BrMethod: 7470A - Mercury (CVAA)

Analyte Result Qualifier RL MDL Unit 0 Prepared Analyzed DO Fac

<0.20 0.20 ug/L 08/03/11 17:01 08/04/11 18:53 1

rGeneral ChemistryAnalyte Result Qualifier RL MDL Unit 0 Prepared Analyzed Dii Fac

Cyanide Total <0.010 0.010 mg/L 08/01/11 07:51 08/02111 06.57 1

Analyte Result Qualifier RL RL Unit B Prepared Analyzed Oil Fac

Sulfide <1.0 1.0 mglL 07/29/11 13:06 1


Client Sample ResultsClient: Ashland Inc.Project/Site: Hercules Hattiesburg APIX 7/27/11


C(ient Sample ID: ASH-MWO4-07271 I Lab Samp’e ID: 680-70818-7Date Collected; 07/27)11 12:55 Matrix: WaterDate Received: 07/28/11 14:09

Method: 8260B - Volatile Organic Compounds (GCIMS) (Continued)Analyte Result Qualifier RL MDL Unit D Prepared — Analyzed Dii Fac

O Triclorofluorornethane — <10 - 1.0 - ug/L — 07/30/11 21:48 1

12,3-Thchloropropane <1 0 1.0 ug/L 07/30/11 21:48 1


Vinyl chIode <1 0 1.0 ug/L 07/30/11 21:48 1Xylenes, Total <20 2.0 ug/L 07/30/11 21:48 1

Surrogate % Recovery Qualifier Limits - Prepared - Analyzed Dii Fac

U4-Bromofluorobenzene 102 70- 130 07/30/11 21:48 1

Dibromofluoromethane 109 70 130 07/30/11 21.48 1

Toiuene-d8(Surr) 100 70130 07/30/1121.48 1

c

Method: 8270C - Semivolatile Organic Compounds (GC1MS)Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dii Fac

Acenaphthene <10 10 ug/L 08/02/11 15:02 08/05/11 16:30 1

Acenaphthylene . — -. <10 - - ..- 1.0 .ugIL 08)02111 18)02 .08108)11.16:30 1

Acetophenone <10 10 ug/L 08/02/11 15:02 08/05/11 16:30 1

2-Acetylaminofluorene <10 10 ug/L 08/02/11 15.02 08/05/11 16:30 1

alpha,alpha-Dimethyl phenelhylamine <2100 2100 ugIL 08/02)11 15:02 08/05/11 16:30 1

4-Amiflobiphenyl <10 10 ug/L 08/02111 18:02 08/05/11 16:30 1

Aniline <21 21 ugIL 08/02/11 15:02 08/05/11 16:30 1

. Anthracene <10 10 ug/L 08/02/11 15:02 08/05/11 16:30 1

Aramite, Total <10 10 ug/L 08/02/11 15:02 08/05/11 16:30 1

Benzo[a]anthracene <10 10 ug/L 08/02/11 15:02 08/05/11 16:30 1

Benzo[alpyrene <10 10 ug/L 08/02/11 15:02 08/05/11 16:30 1

Benzo[b)fluoranthene <10 10 ug/L 08/02111 15:02 08/05/11 16:30 1

Benzo[g,h,i]perylene <10 10 ug/L 08/02/11 15:02 08/05/11 16:30 1

Benzo[k]tluoranthene <10 10 ug/L 08/02/11 15:02 08/05/11 16:30 1

Benzyl alcohol <10 10 ug/L 08/02/11 15:02 08/05/11 16:30 1

1,1’-Biphenyl <10 10 ug/L 08/02/11 15:02 08/05/11 16:30 1

Bis(2-chloroethoxy)methane <10 10 ug/L 08/02/11 15:02 08105111 16:30 1

Bis(2-chloroethyl)ether <10 10 ug/L 08/02/11 15:02 08/05/11 16:30 1

bis(chloroisopropyl) ether <10 10 ug/L 08/02/11 15:02 08/05/1 1 16:30 1

Bis(2-ethylhexyl) phthalate <10 10 ug/L 08/02/11 15:02 08/05/11 16:30 1

4-Bromophenyl phenyl ether <10 10 ug/L 08/02/11 15:02 08/05/11 16:30 1

Butyl benzyl phthalate <10 10 ug/L 08/02/11 15:02 08/05/11 16:30 1

4-Chloroaniline <21 21 ug/L 08/02/11 15:02 08/05/11 16:30 1

4-Chloro-3-methylphenol <10 10 ug/L 08/02/11 15:02 08/05/11 16:30 1

2-chloronaphthalene <10 10 ug/L 08/02/11 15:02 08/05/11 16:30 1

2-Chlorophenol <10 10 ug/L 08/02/11 15:02 08/05/11 16:30 1

4-Chlorophenyl phenyl ether <10 10 ug/L 08/02/11 15:02 08/05/11 16:30 1

Chrysene <10 10 ug/L 08/02/11 15.02 08/05/11 16:30 1

Diallate <10 10 ug/L 08/02/11 15:02 08/05/11 16:30 1

Dibenz(a,h)anthricene <10 10 ug/L 08/02/11 15:02 08/05/11 16:30 1

Dibenzofuran <10 10 ug/L 08/02/11 15:02 08/05/11 16:30 1

1,2-Dichlorobenzerie <10 10 ug/L 08)02/11 15:02 08/06/11 16:30 1

1,3-Dictilorobenzene <10 10 ug/L 08/02/11 15:02 08/06/11 16:30 1

1,4-Dichlorobenzene <10 10 ugIL 08/02)11 15:02 08/05/11 16:30 1

3,3’-Dichlorobenzidine <63 63 ug/L 08/02/11 1502 08/05/11 16:30 1

2,4-Dichlorophenol <10 10 ug/L 08/02)11 15:02 08/05/11 16:30 1

2,6-Dichlorophenol <10 10 ug/L 08/02/11 15:02 08/05/11 16:30 1

Page 31 of95TestAmerica Savannah

Client Sample ResultsCHent: Ashland Inc.Project/Site: Hercules Hattesburg APIX 7/27/11

TestAmerica Job ID: 680-70818-1Client Sample ID: ASH-MWO4-072711

Lab Sample ID: 680-70818-7

Date Collected: 07/27/11 12:55

Matrix: Water

Date ReceIved: 07128111 14:09

2-Picoline

p-Phenylene diaminePronamide

Pyridine

Safrole, TotalSulfotepp1 ,2,4,5-Tetrachlorobenzene2,3,4,6-TetrachiorophenolThionazin2-Toluidine1 ,2,4-Trichlorobenzene2,45-Thchlorophenol2,4,6-Thchlorophenol1 ,3,5-Trinhtrobenzene

0 Prepared08/02)11 15.0208/02)11 15:0208/02/11 15.0208/02/11 15:0208/02111 150208/02/11 15:0208/02111 15:0208/02/11 15:0208)02111 15:0208/02/11 15:0208/02/11 15:0208/02)11 I08102/11 15:0208/02/11 15:0208/02/11 15:0208/02/11 15:0208/02/11 15:0208/02/11 15:0208/02/11 15:0208/0211115:0208/02/11 15:0208/02)11 15:0208/02/11 15:0208/02/11 15:0208/0211115:0208/0211115:0208/02/11 15:0208/0211115:0208/02)1115:0208102111 15:0208/02/11 15:0208/02/11 15:02

Analyzed DII Fac08/05/11 1630 108/05/11 16:30 108/05/11 16:30 108/05/11 16:30 108/05/11 16:30 108/05/11 16:30 108/05/11 16:30 108/05/11 16:30 108/05/11 16:30 108/05/11 16:30 108/05111 16:30 108)05/11 16:30 108/05/11 16:30 108/05/1116:30 108/05/11 16:30 108/05(11 16:30 108/05/11 16:30 108/05/11 16:30 108/05/11 16:30 108/05/11 16:30 108/05/11 16:30 108/05/11 16:30 108/05/11 16:30 108/05)11 16:30 108/05/11 16:30 108)05/11 16:30 108/05(11 16:30 108/05/11 16:30 108/05/11 16:30 108)05/11 16:30 108/05111 16:30 108/05/11 16:30 1

I o,o,o”-Triethylphosphorothioatep-Dimethylamino azobenzenePentachlorobenzenePentachloronitrobenzenePentachiorophenolPhenacetinPhenanthrene

Method: 8270C - Semivolatile Organic Compounds (GCIMS) (Continued)

Analyte

Result Qualifier RL MDL Unft

N-Nitrosodirnethylarnine-

. . <.-.

ug/L

N-Nitrosodi-n-butylamine<10

10ug/L

N-Nitrosodi-n-propylamine<10

10ug/L

N-Nitrosodiphenylamine<10

10ug/L

N-Nitrosomethylethylamine<10

10ug/L

N-Nitrosomorphohne<10

10ug/L

N-Nitrosopiperidine<10

10ug/L

N-Nitrosopyrrolidine<10

10ug(L22

10ug)L<10

10ug!L<10

10ugIL<10

10uq/L<52

52ug/L

—

-— <1010

ug/L<1010

ugIL

Phenol

<1010

ug/L

Phorate

<1010

ug/L<1010

ug/L<21002100

ug/L<1010

ugiL

Pyrene

<1010

ug!L<5252

ug/L<1010

ug/L<1010

ug/L<1010

ug/L<1010

ug/L<1010

ug/L<1010

ug/L<1010

ug!L<1010

ugIL<1010

ug/L<1010

ug/LSurrogate

% Recovery Qualifier Limits

Prepared Analyzed DII Fac

2-Fluorobiphenyl

7138- 130

08102111 15:02 08105111 16:30 1

2-Fluorophenol

6025 130

08102/11 15:02 08105111 16:30 1

Nitrobenzene-d5

6739 130

08102111 15:02 08105111 16:30 1

Phenol-d5

5625 130

08102111 15.02 08105111 16.30

Terphenyl-d14

3710 143

08/02/11 15:02 08/05111 16:30 1

2,4,6-Tribromophenol88

31 14108102111 15:02 08105/11 16:30 1

Method: 8081A 8082 - Organochlorine Pesticides & PCBs (GC)Analyte

Result Qualifier RL MDL Unit D Prepared-

- Analyzed DII Fac

Aldrin

<0.0510.051

ug(L07/29/11 14:35 08(08/11 06:45 1

alpha-BHC

<0.0510.051

ug/L07/29/11 14:35 08/08111 06:45 1

beta-BHC

<0.0510.051

ug/L07/29/11 14:35 08/08/11 06:45 1

Chlordarte(tecttnical)<0.51

0.51ug/L

07/29111 14:35 08/08(11 06:45 1

Chlorobenzitate<0.51

0.51ug/L

07/29(11 14:35 08/08)11 06:45 1

4,4-ODD

<0.100.10

ug)L07/29/11 14:35 08(08/11 06:45 1

4,4-DDE

<0.100.10

ug/L07/29/11 14:35 08/08/11 06:45 1

Page 33 of 95 TestAmerica Savannah



Client Sample ID: ASH-MWO4-07271 I Lab Sample ID: 680-70818-7



Internal Standard % Recovery Qualifier Limits Prepared Analyzed Dii Faa

O,13C-23, 7 8-TCDD 86 40- 135 07/29/11 09.00 07/30/11 03:14 1

13C-1,2,3,7,8-PeCDD 85 40 135 07/29/11 09:00 07/30/11 03:14 1

I 13C-1,2,3,67,8-HxCDD 84 40- 135 07/29/11 09:00 07/30/11 03:14 1

13C-2,3,7,8-TCDF 89 40 135 07/29/11 09:00 07/30/11 03:14 1

i:i 13C-1:2:3:7,8-PeCDF 84 40135 07/29/1109:00 07/30/1103.14 1

13C 1234 781-IxCDF 82 40 135 07/29/110900 07/30/110314 1

Method: 6020 - Metals (ICP/MS)Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dii Fac

Antimony <5.0 5.0 ugiL 08103111 09:07 08/07/11 06:44 1

Arsenic <2.5 2.5 ug/L 08/03111 09:07 08/07/11 06:44 1

Barium 110 5.0 ug/L 08/03/11 09:07 08/07/11 06:44 1

Beryllium <0.50 0.50 ug/L 08/03/11 09:07 08/07111 06:44 1

Cadmium <0.50 0.50 ug/L 08/03/11 09:07 08/07/11 06:44 1

Chromium <5.0 5,0 ug/L 06/03/11 09:07 08/07/11 06:44 1

Cobalt <0.50 0.50 ug/L 08/03/11 09:07 08/07/11 06:44 1

Copper <5.0 5.0 ugIL 08/03/11 09:07 08/07/11 06:44 1

Lead <1.5 1.5 ug/L 08/03/11 09:07 08/07/11 06:44 1

Nickel <5.0 5.0 ug/L 08/03/11 09:07 08/07/11 06:44 1

Selenium <2.5 2,5 ug/L 08)03/11 09:07 08/07/11 06:44 1

Silver <1.0 1.0 ug/L 08/03/11 09:07 08/07/11 06:44 1

Thallium <1.0 1.0 ug/L 08/03/11 09:07 08/07/11 06:44 1

Tin <5.0 5.0 ug/L 08/03/11 09:07 08/07/11 06:44 1

Vanadium <10 10 ug/L 08103/11 09:07 08/07/11 06.44 1

Zinc <20 20 ugIL 08/03/11 09:07 08/07/11 06:44 1

Method: 7470A - Mercury (CVAA)Analyte Result Qualifier RL MDL Unit D Prepared Analyzed -_Dii Fac

<0.20 0.20 ug/L 08/03/11 17:01 08/04/11 18:56 1

O rGeneral ChemistryAnalyte Result Qualifier RL MDL Unit 0 Prepared Analyzed Oil Fac

Cyanide, Total <0.010 0.010 mg/L 08/01/11 07:51 08/02/11 06:58 1

Analyte Result Qualifier RL RL Unit 0 Prepared Analyzed Dii Fac

SuIfide 1.1 1.0 mg/L 07/29/11 13:06 1




Client Sample ID: ASH-MWII-072711 Lab Sample ID: 680-70818..8

Date Coilected; 07/27/11 14:55 Matrix: Water


Method: 82608 - Volatile Organic Compounds (GC/MS) (Continued)Analyte Result Qualifier RL MDL Unit - - 0 Prepared Analyzed Dii Fac

Trichlorofluoromethafle <1 0 1 0 ug/L 08/01/11 19:52 1

I 1,2,3-TrichloroproPafle <i.o 1.0 ug/L 08/01/11 19:52 1

Vinyl acetate <20 20 ug/L 08/01/11 19:52 1

Vinyl chloride <1.0 1 0 ug/L 08/01/11 19:52 1

Xylenes, Total <2.0 20 ug/L 08/01/11 1952 1

Surrogate % Recovery Qualifier Limits - - Prepared Analyzed- DII Fac

O4-Bromofluorobenzene - — 97 -- --

08/01/11 /9:52 1

I Dibromofluoromefhane 110 70 130 08/01/11 19:52 1

Toluene-d8(Surr) 104 70- 130 08/01/11 19:52 1




Client Sample ID: ASH-MWIO-072711 -- Lab Sample ID: 68O7O818-9

Date Collected: 07127111 14:40 Matrix: WaterDate Received: 07/28/11 14:09

Method: 8260B - Volatile Organic Compounds (GCIMS) (Continued)Analyte Result Qualifier RL MDL Unit 0 Prepared Analyzed Dii Fac

O Trichlorofluoromethane <1.0 1 0 ugIL 07130/11 20:19 1

1,2,3-Trichloroproparie <1.0 1.0 ug/L 07130/11 2019 1


Vinyl chloride <1.0 1.0 ug/L 07/30/11 20:19 1

Xylenes, Total <2.0 2.0 ugIL 07/30/11 20:19 1


O4-Bromofluorobenzene 94 70- 130 07/30/11 20:19 1

Dibromofluoromefhane 107 70- 130 07/30/11 2019 1

Toluene-d8 (Surr) 99 70- 130 07/30/11 20:19 1


Client Sample ResultsClient: Ashland Inc TestAmerica Job ID. 680-70818-1



Date Collected: 07/27)11 13:40 Matrix: Water


Method: 82608 - Volatile Organic Compounds (GCIMS) (Continued)Analyte Result Qualifier RL MDL Unit D Prepared — Analyzed Dii Fac

Trichlorofluoromethane <1.0 1.0 ug/L 07/30/11 19:49 1

12,3-Trichloropropane <1.0 1.0 ug/L 07/30/11 19:49 1

Vinyl acetate <2.0 2.0 ugiL 07/30/11 19:49 1


Xyienes. Total <2.0 2.0 ug/L 07/30/11 19.49 1

Surrogate % Recovery Qualifier - Limits -- Prepared -. Analyzed Dii Fac

4-Bromofluorobenzene 93 70. 130 07/30/11 19:49 1

fl Dibromofluoromethane 104 70- 130 07/30/11 19:49 1

LT01ued8(sL’ 100 7o 130 07/3011119:49 1




Client Sample ID: ASH-DUP-072711 Lab Sample ID: 680-70818-11Date Collected: 07/27/11 00:00 Matrix: WaterDate Received: 07/28/11 14:09

Method: 8260B - Volatile Organic Compounds (GCIMS) (Continued)Analyte Result Qualifier RL MDL Unit D Prepared Analyzed DII Fac

Trichlorofluoromethane <1.0 1.0 ugIL 07/30/11 21:18 1

1,2,3-Trichloropropane <1.0 1.0 ugiL 07/30111 21:18 1

Vinyl acetate <2.0 2.0 ugIL 07/30111 21:18 1


Xylenes, Total <2.0 2.0 ugIL 07/30/11 21:18 1

Surrogate % Recoveiy Qualifier Limits Prepared Analyzed Dii Fac

fl4-Bromofluorobenzene 98 70- 130 07/30/11 21:18 1

Dibmmofluoromethane 106 70 130 07/30/11 21:18 1

Toluene-d8(Surr) 99 70 130 07/30/1121:18 1


Client Sample ResultsClient: Ashland Inc. TestAmerica Job ID: 680-7081 8-1


Client Sample ID: Trip B’ank 063011 Lab Sample ID: 680-70818-12



Method: 8260B - Volatile Organic Compounds (GCIMS) (Continued)Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dii Fac

Trichlorotluoromethane <1.0 1 0 ug/L 07/30/11 14:24 1

1,2,3-Trichloropropane <1.0 to ug/L 07/30/11 14:24 1


Vinyl chloride <1.0 1.0 ug/L 07/30/11 14;24 1



4-Bromofluorobenzene - 93 70 130 07/30/11 14:24

Dibmmofluoromethane 109 70 130 07/30/lI 1424 1

I-) Toluene-d8 (Surr) 98 70 l30 07/30/11 14:24 1


QC Sample ResultsClient: Ashland Inc. TestAmerica Job ID: 680-70818-1


Method: 8270C - Semivoatiie Organic Compounds (GCIMS) (Continued)

Lab Sample ID: MB 680-210688/9-A Client Sample ID: Method Blank

Matrix: Water Prep Type: TotalINA

Analysis Batch: 211110 Prep Batch: 210688MB MB

Analyto Result Qualifier RL MDL Unit 3 Prepared Analyzed Dii Fac

Benzyl alcohol <10 10 ug/L 08/02/11 15:02 08/05/11 1234 1

11-Biphenyl <10 10 ug/L 08/02/11 15:02 08/05/11 12:34 1

Bis(2-chloroethoxy)methane <10 10 ug/L 08/02/11 1502 08/05/Il 12:34 1

I Bis(2-chloroethyl)ether <10 10 ug/L 08/02/11 1502 08105/11 1234 1

bis(chloroisopropyl) ether <10 10 ug/L 08/02/11 1502 08/05/11 1234 1

Bis(2-ethylhexyl) phthalate <10 10 ug/L 08/02/11 15:02 08/05/11 1234 1

4-Bromophenyl phenyl ether <10 10 ug/L 08/02)11 15:02 08/05/11 12:34 1

Butyl berizyl phthalate <10 10 ug)L 08)02/11 15:02 08/05/11 12.34 1

4-chioroanIne <20 20 ug/L 08/02/11 15:02 08/05/11 12:34 1

4-chloro-3-methylphenol <10 10 ug/L 08/02/11 15:02 08/05/11 12:34 1

2-Chloronaphthalene <10 10 ug/L 08/02/11 15:02 08/05/11 12:34 1

2-Chlorophenol <10 10 ug/L 08/02/11 15:02 08/05/11 1234 1

4-chiorophenyl phenyl ether <10 10 ug/L 08/02/11 15:02 08/05/11 12.34 1

Chrysene <10 10 ug/L 08/02/11 15:02 08/05/11 12:34 1

DialIate <10 10 ug/L 08/02/11 15:02 08/05/11 12.34 1

Dibenz(ah)anthracene <10 10 ug/L 08/02/11 15:02 08/05/11 12:34 1

Dibenzofuran <10 10 ug/L 08/02/11 15:02 08/05/11 12:34 1

1,2-Dichlorobenzene <10 10 ug/L 08/02)11 15.02 08105/11 12:34 1

1,3-Dichtorobenzene <10 10 ugiL 08/02/11 1502 08/05/11 12:34 1

1,4-Dichlorobenzene <10 10 ug/L 08/02/11 15:02 08/05/11 12:34 1

3,3-Dichloroberzidine <60 60 ug/L 08/02/11 15:02 08/05/11 1234 1

24-Dichlorophenol <10 10 ug/L 08/02/11 15:02 08/05/11 12:34 1

26-Dichlorophenol <10 10 ugIL 08/02/11 15:02 08/05/11 12:34 1

Diethyl phthalate <10 10 ug/L 08/02/11 15:02 08/05/11 12:34 1

Dimethoate <10 10 ug/L 08/02/11 15:02 08/05/11 12:34 1

7,12-Dimethylbenz(a)anthracene <10 10 ug/L 08102/1115:02 08/05/11 12:34 1

3,3-Dimethylberzidine <20 20 ug/L 08/02)1115:02 08105/1112:34 1

24-Dimethylphenol <10 10 ug/L 08/02/11 15:02 08/05/11 12:34 1

Dimethyl phthalate <10 10 ug/L 08/02/11 15:02 08105/11 12:34 1

Di-n-butyI phthalate <10 10 ug)L 08/02)11 15:02 08/05111 12:34 1

13-0introbenzere <10 10 ug/L 08/02/1115:02 08/05/11 12:34 1

4,6-Dinitro-2.methylphenol <50 50 ug/L 08/02/11 15:02 08/05/11 12:34 1

24-Dinitrophenol <50 50 ug/L 08/02/11 15:02 08/05/11 12:34 1

24-Dinitrotoluene <10 10 ug/L 08/02/11 15:02 08/05/11 12:34 1

26-Dinitrotoluene <10 10 ug/L 08/02/1115:02 08/05/11 12:34 1

Di-n-oclyl phthalate <10 10 ug/L 08/02/1115:02 08/05/11 12:34 1

i Dinoseb <10 10 ug/L 08/02/1115:02 08/05/11 12:34 1

I 1,4-Dioxane <10 10 ug/L 08/02/1115:02 08/05/11 12:34 1

Disulfoton <10 10 ug/L 08/02/11 15:02 08/05/11 12:34 1

Ethyl methanesulfonate <10 10 ug/L 08/02)1115:02 08/05/11 12:34 1

Ethyl Parathion <10 10 ug/L 08/02)1115:02 08105/1112:34 1

Famphur <10 10 ug/L 08/02/11 15:02 08/05/11 12:34 1

Fluoranthene <10 10 ug/L 08/02/1115:02 08/05/11 12:34 1

Fluorene <10 10 ug/L 08/02)1115:02 08/05/11 12:34 1

l-lexachlorobenzene <10 10 ugIL 08/02/11 15:02 08/05/11 12:34 1

Hexachlorobutadiene <10 10 ug/L 08/02/11 15:02 08/05/11 12:34 1

Hexachlorocyclopentadiene <10 10 ug/L 08/02/11 15:02 08/05/11 12:34 1

Hexachloroethane <10 10 ugIL 08/02/1115:02 08/05/11 12:34 1

[-fexachlorophene <5000 5000 ugIL 08102/1115:02 08105/1112:34 1

Hexachloropropene <10 10 ugIL 08/02/1115:02 08/05/11 12.34 1


Documents

percent LOU A Over 10 000 [45401 3.0 2.5 maximum S54.2