Upload
others
View
6
Download
0
Embed Size (px)
Citation preview
A R C H I V E S o f
F O U N D R Y E N G I N E E R I N G
Published quarterly as the organ of the Foundry Commission of the Polish Academy of Sciences
ISSN (1897-3310) Volume 10
Special Issue 2/2010 123 – 128
23/2
ARCHIVES OF FOUNDRY ENGINEERING Vo lume 10 , Spec ia l I ssue 2 /2010 , 123-128
123
Possibilities of Pelletizing and Briquetting of Dusts from Castings Grinding
A. Pribulová a,*, D. Baricová a, P. Futaš a, P. Gengeľ a
a Department of Iron Metallurgy and Foundry, Technical University of Košice , Faculty of Metallurgy, Park Komenského 14, 042 00 Košice, Slovakia
*Corresponding author. E-mail address: [email protected]
Received 20.05.2010; accepted in revised form 05.06.2010
Abstract Foundry dust can be divided into three groups: metallic dust with Fe content over 70%, mixed dust with Fe or SiO2 content between 10 – 70% and sand wastes with minimum content of SiO2 about 70%. Dust from castings grinding with high Fe content (87.9%) is still landfill in Slovakia. The aim of experiments with dust from grinding has been to find the cheapest way of dust agglomeration with minimum amount of binder because of melting in the electric induction furnace. The dust was pelletized and briquetted and as binders bentonite, water glass and cement were used. Briquettes made from dust from grinding with addition of water glass got compression strength after three months on the air about 82 kPa. Briquettes with addition of water glass were melted together with cast iron in electric induction furnace. Yield of metal from briquettes was around 80% and slag quantity around 4% (without briquettes the slag quantity was 1.4%). Keywords: Environment Protection, Mechanical Properties, Dust from Castings Grinding, Pelletizing and Briquetting, Electric Induction Furnace.
1. Introduction Metallurgy and Foundry Engineering belong to industrial
sectors which use metal wastes (reversible material, iron scrap and steel scrap) in maximal degree but despite of the huge quantity of rich metallic wastes they are still landfill. Dusts from some foundry machines and works belong to these kinds of wastes. In spite of the increased attention that is dedicated this problem, the foundry wastes are still put on the landfill. It causes not only metal losses and degradation of environmental in the dumping place but too a taking of agricultural land.
Authors [1] divide foundry wastes into three basic groups: • Metallic dusts, they include dusts with Fe content over 70%. • Metallic dusts with variable Fe and SiO2 content, the content
of single components is in the interval 10 – 70%.
• Sand wastes with minimum content of SiO2 about 70% and Fe content can not exceed 10%.
From the view of metal content in wastes, the most interesting
are wastes from the first group. To wastes with Fe content higher then 70% belongs dust from grinding of castings. The wastes from castings cleaning is possible to categorize in to the second group. In to the third category the dust from moulding, from sand and core mixtures preparation belong.
The most suitable aggregate for using of foundry dust wastes with Fe content is cupola furnace [2 - 4].
Authors [5] describe experiments with dust collected from more foundry plants. The dust was pelletized and as a binder material a bentonite was used. The most effective content of bentonite was 5 – 6% because of pellets manipulation. The pellets were put in to the cupola furnace charge in the quantity of 1.77 – 3.54%. Achieved results showed that the iron yield was more then
124
50%putt
papedustgrin
cupoironbetw•
•
2. R
was
TabFe 88.5 contnext Tab
has ghavegrainFig.grain
withPellehigh
3. Dres
3.1
mate
% and the cupoting within probThe main goaler has been to ft from castings
nding in to the cThere are onlyola furnaces in
n melting electriween cupola and
Cupola furnacelectric inducmildly oxidaabsence. Pellets or brinduction furn
Realizes eThe dust from caused for experim le 1. Chemical
FeO Fe58 0.72 87
The basic comtent was minimt melting in the Sieve analyse o
le 2. Sieve analGrain s
0.0.10.0.0
< 0
It follows from tgot a grain size ue got only 4.23%ned material with1 shows an appens from grindingAgglomeration
h addition of netizing was realih of walls about 2The same mixtu
Descriptiosearches
1. Pelletizin By using of thierials that are a
ARCHIVES
ola furnace woblems. l of experimentfind the most sus grinding with charge of electriy four foundrie
Slovakia and tic induction furd electric induc
ce usually workction furnaces ation atmosphe
riquettes are nace and a reel g
experimenastings grinding
ments.
composition ofemetal SiO2 7.91 8.44
mponent of dust mum only 0.72 electric inductiof the dust is in
lyze of the dustsize, mm .18 125 .09 063 .063
the sieve analyzeunder 0.063 mm % of the dust. h very unsuitable
earance of dust ang is very irregularof dust was ma
next binders: beized in pelletizin235 mm. ures were used fo
on of achi
ng of dust fris technology itable after wate
OF FOUNDR
orked during th
ts realized in tuitable agglomepurpose to reu
ic induction fures that produce the other foundrnaces. There arction furnaces [5ks with reductio
work with aere in conseq
less ferromagngenerates less o
nts
with chemical co
f dust from grinCaO MgO0.19 0.13
was iron in m2% that was veion furnace. Tab.2.
t Amount the d
4.28 11.03 21.37 21.26 41.62
e that the biggest(41.62%), grainDust from grin
e shape of grainsnd the shape of gr with sharp edgeade by briquettentonite, water ng dish with diam
or briquetting .
ieved resu
rom grindit is possible to r addition to cr
RY ENGINEE
he time of pell
the frame of teration methoduse the dust frornace. a cast iron in t
dries use for care two differenc5]:
on atmosphere aalmost neutral quence of co
netic in electof heat.
omposition , Tab
nding in % O MnO C
0.53 3.9
metallic form, Fery important
dust,%
t amount of the dn size over 0.18 mnding is quite fis for agglomeratigrains. The shapees. ting and pelletizglass and ceme
meter 1020 mm a
ults of ow
ng treat fine grain
reate the comp
ERING Vo lum
lets
his d of om
the ast-ces
and or
oke
tric
b.1,
6
eO for
dust mm ine-ion. e of
zing ent. and
n
ned act
pelletspelletsmoistugrindiof pelvery q
Fig. 1
Fig.
Thgranuaccomabout create
me 10 , Spec i
s. The most is quality are: mure of pelletizeing, bentonite alletizing the smquickly, Fig.2.
1. Appearance (
2. Creation an
he result of pelllated material.
mpanied this p50°C and it
ed pellets.
a l Issue 2 /2
mportant parammineralogical cod material. Theand water was
mall pellets start
a)
b)
(a), shape (b) of
d disintegration
letizing was thaThe increasing
process, the mprobably coul
010 , 123-12
meters that caomposition, grae mixture contaipelletized. In t
ted to create bu
)
)
f grains from ca
n of pellets in p
at the dust fromg of mixture te
mixture temperd make the d
8
an influence onanulometry andining dust fromhe first minute
ut they crumbled
astings grinding
elletizing dish
m grinding is nonemperature wa
rature increaseddisintegration o
n d
m es d
g
n as d
of
3.2
6, 8briq
are istart
air, expewate
very
putttheywere
Fig
bentfromThe comusin
Fig.
grinmad
2. Briquetti Bentonite, cem
8% from weigquetting mixtureCement is a hyits active compts after half of hThe water glaschemical hard
eriments realizeer glass were haBentonite is u
y often burned. After mixing
ting the mixtury were left on the put in to the f
g.3 Moulds pre
After 48 hourstonite that wer
m the furnace h moulds prep
mparison with bng of water glas
4 Briquette pre On the base o
nding and 6% de on equipme
ARCHIVES
ng of dust
ment and water gght of dust froe. ydraulic binder,onents. The solhour and finishss can be indur
dening – CO2, ed in this workardened only bysually use for
(dust from grres were comphe air for 48 ho
furnace by temp
epared from dus
s the samples wre left on the airhad very hard „cared with cembentonite. The ss as the binder.
epared from dus
f achieved resuof water glassnt which is
OF FOUNDR
from grind
glass in differeom grinding) w
, CaO, SiO2, Allidification by uhes after 12 hourate by dehydracement, slag o
k the briquettingy dehydrating ometallurgical p
rinding and biacted in the mours. The moulperature 500°C.
st and different
were unmoulder started to crumcrust“ but an in
ment were mobest results w
.
st from grinding
ults the mixturs was preparedused for sand
RY ENGINEE
ding
ent quantity (2,were put in to t
l2O3 and Fe2O3using of cemen
urs. ating (cold or hor esters). Durig mixtures won the air. pellets which a
inder) and wamoulds, Fig.3 alds with benton.
kinds of binder
ed . Samples wmble, the sampnterior crumbl
ore compact were achieved
g and water glas
re with dust frod. Briquettes we
mixture samp
ERING Vo lum
, 4, the
nt
hot ing
with
are
ater and nite
rs
with ples ed. by by
ss
om ere
ples
preparcomprcomprshowsThere
Thinduct 3.3.
Th
furnacbriquein Tab Table
NocabrFeslayiebramthe
Br
seriougeneranecessand th
Ex
grindifurnacfurnaccomprwater while insert
me 10 , Spec i
ration given ression strengtression strengths briquette prepe is seen the wathese briquettestion furnace.
Melting of
hree charges foce were prepaettes in the charb.3.
3. Characterizao. of melt st-iron, g ch
coiquettes,g eSi, g ag quantity,%eld of metal froiquettes, %
mount of brique charge, %
riquettes additiously problems ated the highersary to increasehird melt contai
Fig. 5. Slag
xcept water ging dust with ce. Both of mence. The briquetression strengthglass hardenedthe briquettes
.
a l Issue 2 /2
for mechanicth of green brh after 3 monthpared from theter glass on the s were used
f briquettes
or cast iron prodared. The charge, slag quanti
ation of melts w1
harge omposition
4091
om 0
uettes in 0
on in to the casby melting. B
r amount of slae the furnace ouined higher qua
from the third m
glass some briaddition of be
ntioned kinds ottes got a form h was more timd on the air. The
from water gla
010 , 123-12
cal propertiesriquettes was s on the air was
e dust and 6% surface of briqinto the char
s
duction in the elarge compositiity and yield of
with briquettes 1 2 4900 7000 0 850 98 152 1.4 3.74 0 76.55
0 10.62
st iron charge diBigger quantityag and by the thutput. The slag fantity of metal, F
melting with piec
iquettes were entonite and duf briquettes weof compacted
me higher then eir “break downass crumbled b
8 125
s testing. Th 20,5 kPa ands 81,3kPa. Fig.4of water glass
quette. rge for electri
lectric inductionon, amount o
f metal are given
3 4020 1115 102 4,58 83.68
21.3
id not cause anyy of briquettehird melt it wafrom the secondFig. 5.
es of metal
prepared fromust from cupolere burned in th
metal and theibriquettes with
n test” was zeroby fall on meta
5
e d 4 s.
c
n of n
y es as d
m a e ir h o al
ARCHIVES OF FOUNDRY ENGINEERING Vo lume 10 , Spec ia l I ssue 2 /2010 , 123-128 126
4. Conclusions
Dust from grinding of castings with high Fe content (89%) is still landfill in Slovakia. The aim of experiments has been to find the cheaper way of agglomeration with minimum amount of binder because of melting in the electric induction furnace.
The results follow from experiments: • Pelletizing with addition of bentonite, water glass and cement
was not successfully. • Briquettes made from dusts from grinding with addition of
water glass got compression strength of 90 kPa but briquettes were very fragile and they were not suitable for transport and handling.
• Melting of briquettes together with cast iron in the electric induction furnace is possible. Iron yield was quite high and quantity of slag was adequate but experiments were made in small induction furnace (10 kg) and it is necessary to make experiments in bigger furnace.
• Briquettes from dust from grinding with bentonite or cupola furnace dust addition that were burnt. Their mechanical properties were excellent but their production would need higher charges.
Acknowledgements This work was supported by the Slovak Research and Development Agency under the contract No.APVV-0180-07
References [1] Melecký J., Petříková R.: Technologie zkusovění
a zpracovaní kovonosných slévarenských odpraškú při výrobě oceli, Slévarenství XXXVIII (1990), z. 6, str. 362 – 368.
[2] Holtzer M., Niesler M., Podrzucki C., Rupniewski M.: Wykorzystanie żeliwiaka do recyklingu pyłów odlewniczych, Archiwum Odlewnictwa, 2006, 6, Nr 20, str. 111 – 121.
[3] Holtzer M.: Możliwości wykorzystania w procesie żeliwiakowym odpadów odlewniczych zawierających żelazo. Przegląd Odlewnictwa 2000, nr 6, str. 236 – 238.
[4] K. Smyksy, M. Holtzer, Possibilities of briquetting process using for cupola dust utilisation, Archiwum Odlewnictwa, 2002, 2, Nr 3, str. 121 – 128.
[5] J.D. Sharp, Recyklace odpadů s obsahem železa ze slévaren litiny, Slévarenství, XLVI, 1998, č. 7 – 8, str. 247 – 250.
Możliwości peletyzacji i brykietowania pyłów
pochodzących ze szlifowania odlewów Streszczenie Pyły generowane w odlewni można podzielić na 3 grupy: pyły metaliczne zawierające ponad 70% Fe, pyły stanowiące mieszaninę Fe i SiO2 w ilości 10-70% oraz pyły o minimalnej zawartości SiO2 około 70%, będące odpadem. Pyły ze szlifowania zawierające około 88% żelaza na Słowacji wciąż są wywożone na składowisko. Celem pracy było opracowanie taniej metody aglomeracji tych pyłów, aby można je było przetapiać w piecu indukcyjnym. Pyły poddawano paletyzacji i brykietowaniu, a jako spoiwa stosowano szkło wodne, bentonit ora cement. W wyniku przeprowadzonych badan stwierdzono, że paletyzacja pyłów z proponowanymi spoiwami nie spełniła swojego zadania. Brykiety sporządzane z pyłów ze szlifowania odlewów z dodatkiem szkła wodnego uzyskiwały wytrzymałość na ściskanie rzędu 90 kPa, ale były bardzo kruche i nie nadawały się do transportu. Możliwe jest stosowanie dodatku brykietów do wsadu przy topieniu żeliwa w piecu indukcyjnym uzyskując stosunkowo wysoką wydajność (piec o pojemności 10 kg). Jednak należy przeprowadzić próby w piecu o większej pojemności.